JPH04330457A - Capsule toner - Google Patents
Capsule tonerInfo
- Publication number
- JPH04330457A JPH04330457A JP3213177A JP21317791A JPH04330457A JP H04330457 A JPH04330457 A JP H04330457A JP 3213177 A JP3213177 A JP 3213177A JP 21317791 A JP21317791 A JP 21317791A JP H04330457 A JPH04330457 A JP H04330457A
- Authority
- JP
- Japan
- Prior art keywords
- core material
- capsule
- red
- capsule toner
- manufactured
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002775 capsule Substances 0.000 title claims abstract description 65
- 239000005062 Polybutadiene Substances 0.000 claims abstract description 27
- 229920002857 polybutadiene Polymers 0.000 claims abstract description 27
- 239000011162 core material Substances 0.000 claims abstract description 26
- 150000001875 compounds Chemical class 0.000 claims abstract description 22
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 7
- 239000002904 solvent Substances 0.000 claims description 21
- 238000009835 boiling Methods 0.000 claims description 15
- 239000011257 shell material Substances 0.000 claims description 12
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 8
- 229920006395 saturated elastomer Polymers 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 7
- 239000003086 colorant Substances 0.000 claims description 5
- 239000000049 pigment Substances 0.000 abstract description 6
- 229920000642 polymer Polymers 0.000 abstract description 5
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 abstract description 3
- LVGLBCQZYRCDFB-UHFFFAOYSA-N 10,10-dibromoanthracen-9-one Chemical compound C1=CC=C2C(Br)(Br)C3=CC=CC=C3C(=O)C2=C1 LVGLBCQZYRCDFB-UHFFFAOYSA-N 0.000 abstract description 2
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 abstract description 2
- 239000006229 carbon black Substances 0.000 abstract description 2
- 235000012730 carminic acid Nutrition 0.000 abstract description 2
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 abstract description 2
- PLYDMIIYRWUYBP-UHFFFAOYSA-N ethyl 4-[[2-chloro-4-[3-chloro-4-[(3-ethoxycarbonyl-5-oxo-1-phenyl-4h-pyrazol-4-yl)diazenyl]phenyl]phenyl]diazenyl]-5-oxo-1-phenyl-4h-pyrazole-3-carboxylate Chemical compound CCOC(=O)C1=NN(C=2C=CC=CC=2)C(=O)C1N=NC(C(=C1)Cl)=CC=C1C(C=C1Cl)=CC=C1N=NC(C(=N1)C(=O)OCC)C(=O)N1C1=CC=CC=C1 PLYDMIIYRWUYBP-UHFFFAOYSA-N 0.000 abstract description 2
- FPVGTPBMTFTMRT-NSKUCRDLSA-L fast yellow Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 FPVGTPBMTFTMRT-NSKUCRDLSA-L 0.000 abstract description 2
- 235000019233 fast yellow AB Nutrition 0.000 abstract description 2
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 abstract description 2
- 239000001023 inorganic pigment Substances 0.000 abstract description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- ZZSIDSMUTXFKNS-UHFFFAOYSA-N perylene red Chemical compound CC(C)C1=CC=CC(C(C)C)=C1N(C(=O)C=1C2=C3C4=C(OC=5C=CC=CC=5)C=1)C(=O)C2=CC(OC=1C=CC=CC=1)=C3C(C(OC=1C=CC=CC=1)=CC1=C2C(C(N(C=3C(=CC=CC=3C(C)C)C(C)C)C1=O)=O)=C1)=C2C4=C1OC1=CC=CC=C1 ZZSIDSMUTXFKNS-UHFFFAOYSA-N 0.000 abstract description 2
- 125000003367 polycyclic group Chemical group 0.000 abstract description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 239000011258 core-shell material Substances 0.000 abstract 1
- 230000006866 deterioration Effects 0.000 abstract 1
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052755 nonmetal Inorganic materials 0.000 abstract 1
- 229960003351 prussian blue Drugs 0.000 abstract 1
- 239000013225 prussian blue Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 description 34
- 239000011347 resin Substances 0.000 description 34
- 239000002245 particle Substances 0.000 description 26
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 24
- 238000012360 testing method Methods 0.000 description 16
- 239000003208 petroleum Substances 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000000203 mixture Substances 0.000 description 13
- 239000007788 liquid Substances 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 10
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 9
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 9
- 238000005452 bending Methods 0.000 description 8
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 8
- 108091008695 photoreceptors Proteins 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 235000010724 Wisteria floribunda Nutrition 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000006228 supernatant Substances 0.000 description 6
- 239000001993 wax Substances 0.000 description 6
- -1 pentaerythritol ester Chemical class 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- QTKPMCIBUROOGY-UHFFFAOYSA-N 2,2,2-trifluoroethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)F QTKPMCIBUROOGY-UHFFFAOYSA-N 0.000 description 4
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 4
- 238000005562 fading Methods 0.000 description 4
- 239000006247 magnetic powder Substances 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005538 encapsulation Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- XFNGYPLLARFULH-UHFFFAOYSA-N 1,2,4-oxadiazetidin-3-one Chemical compound O=C1NON1 XFNGYPLLARFULH-UHFFFAOYSA-N 0.000 description 2
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 description 2
- 229910002012 Aerosil® Inorganic materials 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 2
- 206010068516 Encapsulation reaction Diseases 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- 238000012695 Interfacial polymerization Methods 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- HSHXDCVZWHOWCS-UHFFFAOYSA-N N'-hexadecylthiophene-2-carbohydrazide Chemical compound CCCCCCCCCCCCCCCCNNC(=O)c1cccs1 HSHXDCVZWHOWCS-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 229920002396 Polyurea Polymers 0.000 description 2
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000004490 capsule suspension Substances 0.000 description 2
- OZECDDHOAMNMQI-UHFFFAOYSA-H cerium(3+);trisulfate Chemical compound [Ce+3].[Ce+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O OZECDDHOAMNMQI-UHFFFAOYSA-H 0.000 description 2
- 238000007872 degassing Methods 0.000 description 2
- QXYJCZRRLLQGCR-UHFFFAOYSA-N dioxomolybdenum Chemical compound O=[Mo]=O QXYJCZRRLLQGCR-UHFFFAOYSA-N 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 2
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 2
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 229920005749 polyurethane resin Polymers 0.000 description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- HBKBEZURJSNABK-MWJPAGEPSA-N 2,3-dihydroxypropyl (1r,4ar,4br,10ar)-1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylate Chemical class C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(=O)OCC(O)CO HBKBEZURJSNABK-MWJPAGEPSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- CNPVJWYWYZMPDS-UHFFFAOYSA-N 2-methyldecane Chemical compound CCCCCCCCC(C)C CNPVJWYWYZMPDS-UHFFFAOYSA-N 0.000 description 1
- CGLVZFOCZLHKOH-UHFFFAOYSA-N 8,18-dichloro-5,15-diethyl-5,15-dihydrodiindolo(3,2-b:3',2'-m)triphenodioxazine Chemical compound CCN1C2=CC=CC=C2C2=C1C=C1OC3=C(Cl)C4=NC(C=C5C6=CC=CC=C6N(C5=C5)CC)=C5OC4=C(Cl)C3=NC1=C2 CGLVZFOCZLHKOH-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 235000010650 Hyssopus officinalis Nutrition 0.000 description 1
- 240000001812 Hyssopus officinalis Species 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropanol acetate Natural products CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 description 1
- 229940011051 isopropyl acetate Drugs 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Landscapes
- Developing Agents For Electrophotography (AREA)
Abstract
Description
【０００１】0001
【産業上の利用分野】本発明は、電子写真装置に用いら
れる現像剤に関するもので、詳しくは定着方式として圧
力で定着を行なわせる装置に適合したカプセルトナーに
関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a developer used in an electrophotographic device, and more particularly to a capsule toner suitable for a device that uses pressure as a fixing method.
【０００２】0002
【従来の技術】従来、芯物質と殻物質よりなるカプセル
トナーについては種々のものが提案されており、例えば
、特開昭５１−１３２８２８号公報には、芯物質として
軟質固体を有機溶剤に溶解または分散させたカプセルト
ナーが記載され、また、特開昭５８−１４５９６４号お
よび同６０−８３９５８号公報には、芯物質に少なくと
も高沸点溶剤と重合体とを含有するカプセルトナーが開
示されている。また、特開昭６３−１６３３７３号公報
には、特定の塩素化パラフィンを芯材中の高沸点溶剤と
して用いる発明が開示されている。[Prior Art] Various capsule toners consisting of a core material and a shell material have been proposed. For example, Japanese Patent Application Laid-open No. 132828/1983 discloses a method in which a soft solid as a core material is dissolved in an organic solvent. JP-A-58-145964 and JP-A-60-83958 disclose capsule toners in which the core material contains at least a high boiling point solvent and a polymer. . Further, Japanese Patent Application Laid-Open No. 163373/1983 discloses an invention in which a specific chlorinated paraffin is used as a high boiling point solvent in the core material.
【０００３】0003
【発明が解決しようとする課題】しかしながら、従来提
案されているカプセルトナーは、未だ十分満足の行くも
のではなかった。例えば、特開昭５８−１４５９６４号
および同６０−８３９５８号公報に記載の場合には、使
用される高沸点溶剤が、いわゆる可塑剤であって、樹脂
に対する溶解力が大きく、したがって、感光体として有
機感光体を用いた場合、カプセルが損傷を受けたり、殻
の薄いカプセルから滲み出したり、或いは揮発したりす
る高沸点溶剤により、感光体が変質するという欠点があ
ることがわかった。また、特開昭６３−１６３３７３号
公報に記載の場合には、高沸点溶剤として使用する塩素
化パラフィンが、アクリル樹脂、ポリカーボネート樹脂
、ポリエステル樹脂等の汎用樹脂に対して本質的に溶解
力を持つため、有機感光体を変質させるという問題があ
る。これに変わる手段として、溶剤として、飽和脂肪族
炭化水素系溶剤を用いることも知られているが、例えば
特開昭５１−１３２８２８号公報に記載の場合は、使用
する重合体がアクリル酸の長鎖アルキルエステル重合体
或いは石油樹脂であり、比較的低いＴｇを有し、脆い樹
脂が使用されているため、定着画像は、指こすり等によ
り容易に画像が流れて文字が判読できなくなる等の問題
がある。したがって、圧力定着によって紙にしっかりと
定着するためには、強力に圧力（例えば２００〜３００
ｋｇ／ｃｍ２ ）を加える必要がある。そのため、定着
器が大きくて重いものになるという問題があった。[Problems to be Solved by the Invention] However, the capsule toners proposed in the past have not yet been fully satisfactory. For example, in the cases described in JP-A-58-145964 and JP-A-60-83958, the high boiling point solvent used is a so-called plasticizer, which has a large dissolving power for resin, and therefore is suitable for use as a photoreceptor. It has been found that when an organic photoreceptor is used, the photoreceptor is deteriorated due to damage to the capsule, high-boiling solvent that oozes out of the thin-shelled capsule, or evaporates. Furthermore, in the case described in JP-A No. 63-163373, chlorinated paraffin used as a high-boiling solvent essentially has a dissolving power for general-purpose resins such as acrylic resin, polycarbonate resin, and polyester resin. Therefore, there is a problem that the organic photoreceptor is altered in quality. As an alternative to this, it is known to use a saturated aliphatic hydrocarbon solvent as the solvent, but for example, in the case described in JP-A-51-132828, the polymer used is a long acrylic acid. Chain alkyl ester polymers or petroleum resins are used, which have a relatively low Tg and are brittle, resulting in problems such as the fixed image easily smearing due to finger rubbing, etc., making characters illegible. There is. Therefore, in order to firmly fix the paper by pressure fixing, it is necessary to use strong pressure (for example, 200 to 300
kg/cm2). Therefore, there is a problem that the fixing device becomes large and heavy.
【０００４】本発明は、上記のような従来のカプセルト
ナーにおける問題点を解決することを目的とするもので
ある。即ち、本発明の目的は、有機感光体を変質させる
ことがなく、定着性に優れ、小型の定着器で定着するこ
とができるマイクロカプセルトナーを提供することにあ
る。The object of the present invention is to solve the problems with conventional capsule toners as described above. That is, an object of the present invention is to provide a microcapsule toner that does not alter the quality of an organic photoreceptor, has excellent fixing properties, and can be fixed using a small fixing device.
【０００５】[0005]
【課題を解決するための手段】本発明の電子写真用カプ
セルトナーは、芯物質と該芯物質を被覆する殻物質から
なるものであって、その第１のカプセルトナーにおいて
は、芯物質が、溶剤の不存在または低沸点溶剤の存在下
に、少なくとも着色材と、下記一般式（Ｉ）で示される
分岐ビニル基を有するポリブタジエン化合物を含有する
ことを特徴とし、また、第２のカプセルトナーにおいて
は、芯物質が、少なくとも着色材と、下記一般式（Ｉ）
で示される分岐ビニル基を有するポリブタジエン化合物
と、該ポリブタジエン化合物を溶解または膨潤する作用
を有する飽和脂肪族炭化水素系の高沸点溶剤とを含有す
ることを特徴とする。[Means for Solving the Problems] The capsule toner for electrophotography of the present invention is composed of a core material and a shell material covering the core material, and in the first capsule toner, the core material is The second capsule toner is characterized by containing at least a colorant and a polybutadiene compound having a branched vinyl group represented by the following general formula (I) in the absence of a solvent or in the presence of a low boiling point solvent. , the core substance contains at least a colorant and the following general formula (I)
It is characterized in that it contains a polybutadiene compound having a branched vinyl group represented by: and a saturated aliphatic hydrocarbon-based high boiling point solvent that has the function of dissolving or swelling the polybutadiene compound.
【０００６】[0006]
【化３】[C3]
【０００７】以下、本発明について詳細に説明する。本
発明のカプセルトナーにおいて、芯物質に使用される着
色材としては、カーボンブラック、ベンガラ、紺青、酸
化チタン等の無機顔料、ファストイエロー、ジスアゾイ
エロー、ピラゾロンレッド、キレートレッド、ブリリア
ントカーミン、パラブラウン等のアゾ顔料、銅フタロシ
アニン、無金属フタロシアニン等のフタロシアニン顔料
、フラバントロンイエロー、ジブロモアントロンオレン
ジ、ペリレンレッド、キナクリドンレッド、ジオキサジ
ンバイオレット等の縮合多環系顔料があげられる。また
分散染料、油溶性染料などを用いることもできる。更に
また、磁性１成分トナーとして使用する場合には、黒色
着色材の全部又は一部を磁性粉で置き換えることができ
る。磁性粉としては、マグネタイト、フェライト、又は
コバルト、鉄、ニッケル等の金属担体又はその合金を用
いることができる。The present invention will be explained in detail below. In the capsule toner of the present invention, coloring materials used in the core substance include inorganic pigments such as carbon black, red iron oxide, navy blue, and titanium oxide, fast yellow, disazo yellow, pyrazolone red, chelate red, brilliant carmine, and para brown. Examples include azo pigments, copper phthalocyanine, phthalocyanine pigments such as metal-free phthalocyanine, and condensed polycyclic pigments such as flavanthrone yellow, dibromoanthrone orange, perylene red, quinacridone red, and dioxazine violet. Further, disperse dyes, oil-soluble dyes, etc. can also be used. Furthermore, when used as a magnetic one-component toner, all or part of the black colorant can be replaced with magnetic powder. As the magnetic powder, magnetite, ferrite, or a metal carrier such as cobalt, iron, or nickel, or an alloy thereof can be used.
【０００８】また、上記一般式（Ｉ）で示される分岐ビ
ニル基を有するポリブタジエン化合物は、常温で液状の
もの或いは固体状のものが使用され、そしてそれらは、
単独で使用してもよいが、定着速度及び定着強度を向上
させる目的で、石油樹脂またはロジン系樹脂を併用して
もよい。上記ポリブタジエン化合物が液状の場合には、
それと併用する石油樹脂またはロジン系樹脂は、ポリブ
タジエン化合物中に溶解するか、ポリブタジエン化合物
により膨潤するものが好ましく使用することができる。[0008] The polybutadiene compound having a branched vinyl group represented by the above general formula (I) is used in a liquid state or a solid state at room temperature, and they are
Although it may be used alone, a petroleum resin or a rosin resin may be used in combination for the purpose of improving fixing speed and fixing strength. When the above polybutadiene compound is liquid,
The petroleum resin or rosin resin to be used in combination with the resin is preferably one that dissolves in the polybutadiene compound or swells with the polybutadiene compound.
【０００９】本発明において上記ポリブタジエン化合物
と併用できる石油樹脂としては、脂肪族系石油樹脂、芳
香族系石油樹脂、共重合系石油樹脂、脂環式水添石油樹
脂、アルキルフェノール樹脂、クマロン−インデン樹脂
等があげられる。中でも、芳香族系石油樹脂が、上記ポ
リブタジエン化合物との相溶性が良好であるので好まし
い。また、ロジン系樹脂としては、ロジン、変性ロジン
、該ロジンのグリセリンエステル、該ロジンのペンタエ
リスリトールエステル等があげられる。Petroleum resins that can be used in combination with the polybutadiene compound in the present invention include aliphatic petroleum resins, aromatic petroleum resins, copolymer petroleum resins, alicyclic hydrogenated petroleum resins, alkylphenol resins, and coumaron-indene resins. etc. can be mentioned. Among these, aromatic petroleum resins are preferred because they have good compatibility with the polybutadiene compound. Examples of the rosin resin include rosin, modified rosin, glycerin ester of the rosin, and pentaerythritol ester of the rosin.
【００１０】本発明において、上記ポリブタジエン化合
物が常温で液状の場合には、芯物質に溶剤を含有させる
必要はないが、所望により粘度調整等の目的で、上記ポ
リブタジエン化合物と相溶性の低沸点溶剤を少量使用し
てもよい。また、上記ポリブタジエン化合物が固体状の
場合には、ポリブタジエン化合物を溶解または膨潤する
ために溶剤を使用することが必要であるが、溶剤として
は、感光体の変質を生じさせないようにするために、低
沸点溶剤または飽和脂肪族炭化水素系の高沸点溶剤が好
ましく使用できる。In the present invention, when the polybutadiene compound is liquid at room temperature, it is not necessary to include a solvent in the core material, but if desired, for the purpose of viscosity adjustment, a low boiling point solvent compatible with the polybutadiene compound is added. may be used in small amounts. In addition, when the polybutadiene compound is in a solid state, it is necessary to use a solvent to dissolve or swell the polybutadiene compound. A low boiling point solvent or a saturated aliphatic hydrocarbon type high boiling point solvent can be preferably used.
【００１１】本発明において使用することができる低沸
点溶剤としては、沸点４０〜１２８℃の範囲で、例えば
、酢酸メチル、酢酸エチル、酢酸ブチル、酢酸イソプロ
ピル、メチルイソブチルケトン、メチルｎ−ブチルケト
ン、ヘキサン、ヘプタン、ｎ−オクタン、塩化メチレン
、クロロホルム等があげられる。また、飽和脂肪族炭化
水素系の高沸点溶剤としては、沸点１４０℃、好ましく
は１６０℃以上の飽和脂肪族炭化水素またはそれを主成
分とする液体であって、具体的には、エクソン化学社製
のＩｓｏｐｅｒ Ｈ、Ｉｓｏｐｅｒ Ｌ、Ｉｓｏｐ
ｅｒ Ｍ、ＥＸＸＳＯＬ Ｄ４０４、ＥＸＸＳＯＬ
Ｄ８０、ＥＸＸＳＯＬＤ１１０などをあげることが
できる。Examples of low boiling point solvents that can be used in the present invention include methyl acetate, ethyl acetate, butyl acetate, isopropyl acetate, methyl isobutyl ketone, methyl n-butyl ketone, and hexane. , heptane, n-octane, methylene chloride, chloroform and the like. The saturated aliphatic hydrocarbon-based high boiling point solvent is a saturated aliphatic hydrocarbon with a boiling point of 140°C, preferably 160°C or higher, or a liquid containing it as a main component, and specifically, Exxon Chemical Co., Ltd. Isoper H, Isoper L, Isop manufactured by
er M, EXXSOL D404, EXXSOL
Examples include D80 and EXXSOLD110.
【００１２】また、本発明のカプセルトナーにおいては
、オフセット防止の目的で、芯物質の一成分として上記
ポリブタジエン化合物および石油樹脂或いはロジン系樹
脂類の他に、ワックスを含有させることもできる。ワッ
クスとしては、パラフィンワックス、マイクロクリスタ
リンワックス、モンタンワックス、カルナバワックス、
キャンデリラワックス、密ロウのごとき天然ワックス、
ポリエチレンワックス、変性ワックス、セチルアルコー
ル、ステアリン酸等の合成ワックスがあげられる。Further, in the capsule toner of the present invention, in addition to the polybutadiene compound and petroleum resin or rosin resin, a wax may be contained as a component of the core material for the purpose of preventing offset. Waxes include paraffin wax, microcrystalline wax, montan wax, carnauba wax,
Natural waxes such as candelilla wax and beeswax,
Examples include synthetic waxes such as polyethylene wax, modified wax, cetyl alcohol, and stearic acid.
【００１３】一方、外殻は、樹脂成分により構成される
が、樹脂成分としては、カプセル化において公知のもの
ならば如何なるものでも使用することができる。例えば
、ポリウレア樹脂、ポリウレタン樹脂、ポリアミド樹脂
、ポリエステル樹脂、エポキシ樹脂またはエポキシウレ
ア樹脂、エポキシウレタン樹脂が好ましく、その中でも
特に、ポリウレア樹脂またはポリウレタン樹脂の単独か
、もしくは両者の混合物、あるいはエポキシウレア樹脂
またはエポキシウレタン樹脂の単独か、もしくは両者の
混合物であることがより好ましい。また、外殻の表面は
、例えば、アクリル酸エステルまたはメタクリル酸エス
テル等のビニル単量体によってグラフト重合させて、グ
ラフト化を行ってもよい。外殻は、圧力定着を目的とし
た場合と加熱定着を目的とした場合とでは、厚みを変え
ることが望ましく、また構成成分の種類あるいは組成比
を変えてもよい。On the other hand, the outer shell is composed of a resin component, and any resin component known for encapsulation can be used. For example, polyurea resins, polyurethane resins, polyamide resins, polyester resins, epoxy resins, epoxyurea resins, and epoxyurethane resins are preferred, and among these, polyurea resins or polyurethane resins alone, or a mixture of both, or epoxyurea resins or It is more preferable to use an epoxy urethane resin alone or a mixture of both. Further, the surface of the outer shell may be grafted, for example, by graft polymerization with a vinyl monomer such as an acrylic ester or a methacrylic ester. The thickness of the outer shell is desirably different depending on whether it is intended for pressure fixing or heat fixing, and the types or composition ratios of the constituent components may also be varied.
【００１４】本発明のカプセルトナーを製造する場合、
カプセル化の方法には、特に制限はなく、公知の方法な
らば如何なる方法でも使用できるが、被覆の完全さ、お
よび外殻の機械的強度を考えると、界面重合によるカプ
セル化方法が優れている。界面重合によるカプセルの製
造は、公知の方法を用いることができる（例えば特開昭
５７−１７９８６０号、同５８−６６９４８号、同５９
−１４８０６６号および同５９−１６２５６２号公報）
。圧力定着を目的としたカプセルを製造する場合には、
芯物質として、圧力定着性を有する成分を主体とする芯
物質が用いられ、また、加熱定着を目的とした場合には
、加熱定着性を有する成分を主体とする芯物質が用いら
れる。When producing the capsule toner of the present invention,
There are no particular restrictions on the encapsulation method, and any known method can be used; however, considering the completeness of the coating and the mechanical strength of the outer shell, an encapsulation method using interfacial polymerization is superior. . Capsules can be manufactured by interfacial polymerization using known methods (for example, Japanese Patent Application Laid-open Nos. 179860/1986, 66948/1983, and 59/1982).
-148066 and 59-162562)
. When manufacturing capsules for pressure fixing,
As the core material, a core material mainly consisting of a component having pressure fixing properties is used, and when heat fixing is intended, a core material mainly containing a component having heat fixing properties is used.
【００１５】本発明のカプセルトナーには、外添剤が添
加されてもよい。外添剤としては、従来一般的に使用さ
れているステアリン酸等の長鎖脂肪酸及びそのエステル
、アミド、金属塩、更には二酸化モリブデン、窒化ホウ
素、シリカ、酸化アルミニウム、二酸化チタン、酸化亜
鉛等の微粉末、フッ素系樹脂等の微粉末、多環芳香族化
合物、ワックス状物質、架橋又は非架橋型脂微粉末等が
あげられ、通常、低表面エネルギーを有するか、摩擦係
数の低い平滑な表面を有する固体微粒子、或いは非粘着
性、若干の研磨性を有する微粒子が好ましく使用される
。External additives may be added to the capsule toner of the present invention. External additives include conventionally commonly used long-chain fatty acids such as stearic acid, their esters, amides, and metal salts, as well as molybdenum dioxide, boron nitride, silica, aluminum oxide, titanium dioxide, zinc oxide, etc. Fine powders, fine powders such as fluororesins, polycyclic aromatic compounds, waxy substances, crosslinked or non-crosslinked fat fine powders, etc., and usually have low surface energy or a smooth surface with a low coefficient of friction. Preferably, solid fine particles having the following properties or fine particles having non-adhesive properties and some abrasive properties are used.
【００１６】[0016]
【実施例】以下、本発明を実施例によって説明する。
実施例１
（カプセル粒子の作製）ブタジエンホモポリマー（Ｂ−
１０００：日本曹達社製）７５ｇおよび石油樹脂（ＦＴ
Ｒ６１２５：三井油化学社製）１５ｇを、酢酸エチル３
０ｇの混合液に溶解させた。得られた溶液に、磁性粉（
ＥＰＴ−１０００：戸田工業社製）５５ｇを入れ、ボー
ルミルにて２４時間分散処理した。次に、この分散液１
００ｇに対して、イソシアナート（スミジュールＬ：住
友バイエルウレタン社製）１５ｇおよび酢酸エチル１５
ｇを加え充分混合した（この液をＡ液とする。）。一方
、イオン交換水２００ｇに、ヒドロキシプロピルメチル
セルロース（メトロース６５ＳＨ５０：信越化学社製）
１０ｇを溶解させ、５℃まで冷却した（この液をＢ液と
する。）。[Examples] The present invention will be explained below with reference to Examples. Example 1 (Preparation of capsule particles) Butadiene homopolymer (B-
1000: Nippon Soda Co., Ltd.) 75g and petroleum resin (FT
R6125: manufactured by Mitsui Oil Chemicals Co., Ltd.) 15g, ethyl acetate 3
It was dissolved in 0 g of the mixed solution. Add magnetic powder (
55 g of EPT-1000 (manufactured by Toda Kogyo Co., Ltd.) was added thereto and subjected to a dispersion treatment for 24 hours in a ball mill. Next, this dispersion 1
00g, 15g of isocyanate (Sumidur L: manufactured by Sumitomo Bayer Urethane) and 15g of ethyl acetate.
g was added and thoroughly mixed (this liquid is referred to as liquid A). On the other hand, add 200 g of ion-exchanged water to hydroxypropyl methylcellulose (Metrose 65SH50: Shin-Etsu Chemical Co., Ltd.)
10 g was dissolved and cooled to 5°C (this liquid is referred to as liquid B).
【００１７】乳化機（オートホモミクサー：特殊機化工
業製）でＢ液を撹拌し、この中にＡ液をゆっくり投入し
て乳化を行った。このようにして乳化液中の油滴粒子の
平均粒径が約１２μｍのＯ／Ｗエマルジョンを得た。つ
ぎに、乳化機に代えて、プロペラ型の撹拌羽根を備えた
撹拌機（スリーワンモータ：新東科学社製）を使用し、
４００回転／分で撹拌した。１０分後、この中に５％の
ジエチレントリアミン水溶液１００ｇを滴下した。滴下
終了後、６０℃に加温し、酢酸エチルを脱気させながら
３時間カプセル化反応を行った。反応終了後、２リット
ルのイオン交換水にあけ、充分撹拌し静置した。カプセ
ル粒子が沈降した後、上澄みを取り除いた。この操作を
あと７回繰り返して、カプセル粒子を洗浄した。このよ
うにして、本発明のカプセル粒子を得た。カプセル粒子
にイオン交換水を加え、固形分濃度４０％の懸濁液を調
製した。Solution B was stirred using an emulsifier (auto homo mixer: manufactured by Tokushu Kika Kogyo), and solution A was slowly added thereto to effect emulsification. In this way, an O/W emulsion in which the average particle size of oil droplets in the emulsion was about 12 μm was obtained. Next, instead of the emulsifier, a stirrer equipped with propeller-type stirring blades (three-one motor: manufactured by Shinto Kagakusha) was used.
Stirring was carried out at 400 rpm. After 10 minutes, 100 g of a 5% diethylenetriamine aqueous solution was added dropwise thereto. After the dropwise addition was completed, the mixture was heated to 60° C., and the encapsulation reaction was carried out for 3 hours while degassing the ethyl acetate. After the reaction was completed, the mixture was poured into 2 liters of ion-exchanged water, thoroughly stirred, and allowed to stand still. After the capsule particles had settled, the supernatant was removed. This operation was repeated seven more times to wash the capsule particles. In this way, capsule particles of the present invention were obtained. Ion-exchanged water was added to the capsule particles to prepare a suspension with a solid content concentration of 40%.
【００１８】調製したカプセル粒子の懸濁液１２５ｇ（
カプセル粒子５０ｇに相当）に、イオン交換水１２５ｇ
を加え、プロペラ型の撹拌羽根を備えた撹拌機（スリー
ワンモータ：新東科学社製）にて２００回転／分で撹拌
した。これに１Ｎの硝酸５ｇ、１０％の硫酸セリウム水
溶液４ｇを加えた後、ジメタクリル酸エチレングリコー
ルを０．５ｇを加え、１５℃で３時間反応を行った。
反応終了後１リットルのイオン交換水にあけ、充分撹拌
し静置した。カプセル粒子が沈降した後、上澄みを取り
除いた。この操作をあと２回繰り返して、カプセル粒子
を洗浄した。このようにしてジメタクリル酸エチレング
リコールがカプセル外殻の表面にグラフト重合したカプ
セル粒子を得た。これを再びイオン交換水に再懸濁し、
プロペラ型の撹拌羽根を備えた撹拌機（スリーワンモー
タ：新東科学社製）にて２００回転／分で撹拌した。次
にこの中に０．４ｇの過硫酸カリウム、トリフルオロエ
チルメタクリレート１ｇ、０．１６ｇの亜硫酸水素ナト
リウムを順次添加し、２５℃で３時間反応を行った。反
応終了後、２リットルのイオン交換水にあけ、充分撹拌
し静置した。カプセル粒子が沈降した後、上澄みを取り
除いた。この操作をあと４回繰り返して、カプセル粒子
を洗浄した。このようにしてトリフルオロエチルメタク
リレートがカプセル外殻の表面にグラフト重合したカプ
セルトナーを得た。得られたカプセル懸濁液をステンレ
ス鋼のバットにあけ、乾燥機（ヤマト科学社製）にて６
０℃で１４時間乾燥した。125 g of the prepared capsule particle suspension (
(equivalent to 50g of capsule particles), 125g of ion exchange water
was added and stirred at 200 rpm using a stirrer equipped with a propeller-type stirring blade (Three-One Motor: manufactured by Shinto Kagakusha). After adding 5 g of 1N nitric acid and 4 g of 10% cerium sulfate aqueous solution to this, 0.5 g of ethylene glycol dimethacrylate was added, and the reaction was carried out at 15° C. for 3 hours. After the reaction was completed, the mixture was poured into 1 liter of ion-exchanged water, thoroughly stirred, and allowed to stand still. After the capsule particles had settled, the supernatant was removed. This operation was repeated two more times to wash the capsule particles. In this way, capsule particles in which ethylene glycol dimethacrylate was graft-polymerized on the surface of the capsule shell were obtained. Resuspend this in ion-exchanged water again,
Stirring was carried out at 200 revolutions/min using a stirrer equipped with a propeller-type stirring blade (Three-One Motor: manufactured by Shinto Kagakusha Co., Ltd.). Next, 0.4 g of potassium persulfate, 1 g of trifluoroethyl methacrylate, and 0.16 g of sodium bisulfite were sequentially added to the mixture, and the reaction was carried out at 25° C. for 3 hours. After the reaction was completed, the mixture was poured into 2 liters of ion-exchanged water, thoroughly stirred, and allowed to stand still. After the capsule particles had settled, the supernatant was removed. This operation was repeated four more times to wash the capsule particles. In this way, a capsule toner in which trifluoroethyl methacrylate was graft-polymerized on the surface of the capsule shell was obtained. The obtained capsule suspension was poured into a stainless steel vat and dried in a dryer (manufactured by Yamato Kagaku Co., Ltd.) for 6 hours.
It was dried at 0°C for 14 hours.
【００１９】次に、このカプセルトナー１００部に対し
て、疎水性シリカ（Ｒ９７２：日本アエロジル社製）を
０．７部添加し、充分混合した後、温度２０℃、湿度５
０％の環境下で評価を行った。使用した装置は、富士ゼ
ロックス社製の４１０５プリンターをカプセルトナー用
に改造したもので、定着圧力１２０ｋｇ／ｃｍ２ の圧
力定着器を装着したものであった。帯電性を測定した結
果、平均帯電量：−８μｃ／ｇ、逆極性トナー量：７重
量％であり、画像もかぶりのない鮮明な物であった。ま
た、定着性については、２４時間後測定したところ、指
でこすっても、消ゴムで消しても、画像流れや消えるこ
とは全くなかった。また、折り曲げテストを行って、画
像は剥がれ落ちることはなかった。Next, 0.7 parts of hydrophobic silica (R972: manufactured by Nippon Aerosil Co., Ltd.) was added to 100 parts of this capsule toner, and after thorough mixing, the mixture was heated at a temperature of 20°C and a humidity of 5.
The evaluation was performed under a 0% environment. The apparatus used was a Fuji Xerox 4105 printer modified for use with capsule toner, and was equipped with a pressure fixing device with a fixing pressure of 120 kg/cm2. As a result of measuring the charging property, the average charge amount was -8 μc/g, the amount of reverse polarity toner was 7% by weight, and the image was clear without fogging. Regarding the fixability, measurements were taken after 24 hours, and there was no image fading or fading even when rubbed with a finger or erased with an eraser. In addition, the image did not peel off during the bending test.
【００２０】実施例２
実施例１におけるブタジエンホモポリマーの代わりに、
α，ω−ポリブタジエンジカルボン酸（Ｃ−１０００：
日本曹達社製）を用いて、同様にカプセルトナーを作成
し、実施例１と同様のテストを行った。その結果、平均
帯電量：−１２μｃ／ｇ、逆極性トナー量：５重量％で
あり、画像もかぶりのない鮮明な物であった。また、定
着性については、１０分、３０分、１時間、５時間、１
２時間、２４時間、１週間、１か月後に、指こすり、消
ゴム、折り曲げの各テストを実施した。その結果、１０
分および３０分後で、消ゴムでこすった場合、僅かに画
像が剥がれる他は、何ら変化もなく、一定した定着性を
示した。Example 2 Instead of the butadiene homopolymer in Example 1,
α,ω-Polybutadiene dicarboxylic acid (C-1000:
Capsule toner was prepared in the same manner using Nippon Soda Co., Ltd.), and the same test as in Example 1 was conducted. As a result, the average charge amount was -12 .mu.c/g, the amount of reverse polarity toner was 5% by weight, and the image was clear with no fog. Regarding fixing properties, 10 minutes, 30 minutes, 1 hour, 5 hours, 1
After 2 hours, 24 hours, 1 week, and 1 month, finger rubbing, eraser, and bending tests were performed. As a result, 10
When the image was rubbed with an eraser after 30 minutes and 30 minutes, there was no change other than slight peeling of the image, indicating constant fixing performance.
【００２１】実施例３
実施例１におけるブタジエンホモポリマーの代わりに、
マレイン化ポリブタジエン樹脂（ＢＮ−２０１０：日本
曹達社製）８０ｇを用い、石油樹脂の変わりにロジン系
樹脂（エステルガムＨＰ：荒川化学社製）２０ｇを用い
て、同様にカプセルトナーを作成し、実施例１と同様の
テストを行った。その結果、平均帯電量：−９μｃ／ｇ
、逆極性トナー量：３重量％であり、画像もかぶりのな
い鮮明な物であった。繰り返しプリントを行ったところ
、２０，０００枚のプリント後でも、鮮明なプリント画
像が得られた。また、定着性については、３０分間以降
は、安定しており、指こすり、消ゴム、折り曲げの各テ
ストに対して、安定して良好な定着性を示した。Example 3 Instead of the butadiene homopolymer in Example 1,
A capsule toner was prepared in the same manner using 80 g of maleated polybutadiene resin (BN-2010: manufactured by Nippon Soda Co., Ltd.) and 20 g of rosin resin (Ester Gum HP: manufactured by Arakawa Chemical Co., Ltd.) instead of petroleum resin. A test similar to Example 1 was conducted. As a result, average charge amount: -9μc/g
, the amount of reverse polarity toner was 3% by weight, and the image was clear with no fog. When repeated printing was performed, clear printed images were obtained even after printing 20,000 sheets. Furthermore, the fixing properties were stable after 30 minutes, and stable and good fixing properties were shown in the finger rubbing, eraser, and bending tests.
【００２２】実施例４
実施例１、２および３で作製したカプセルトナーを、定
着圧力８０ｋｇ／ｃｍ２ 、温度５０℃として、加熱ア
シスト付圧力定着器を取り付けた富士ゼロックス社製４
１０５プリンター改造機でテストした結果、定着直後に
指こすり、消しゴム、折り曲げの各テストを実施したと
ころ、何等の変化も見られず、極めて良好な結果が得ら
れることが分かった。Example 4 The capsule toners prepared in Examples 1, 2, and 3 were fixed at a fixing pressure of 80 kg/cm 2 and a temperature of 50° C. using a Fuji Xerox 4 manufactured by Fuji Xerox Co., Ltd. equipped with a pressure fixing device with heating assist.
As a result of testing on a modified 105 printer, it was found that when finger rubbing, eraser, and bending tests were performed immediately after fixing, no changes were observed, and very good results were obtained.
【００２３】実施例５
実施例１におけるブタジエンホモポリマーの代わりに、
α，ω−ポリブタジエングリコール（Ｇ−２０００：日
本曹達社製）７５ｇを用いた以外は、同様にカプセルト
ナーを作成し、実施例１と同様のテストを行った。その
結果、鮮明なプリント画像が得られ、また定着性も良好
なものであった。Example 5 Instead of the butadiene homopolymer in Example 1,
A capsule toner was prepared in the same manner as in Example 1, except that 75 g of α,ω-polybutadiene glycol (G-2000, manufactured by Nippon Soda Co., Ltd.) was used, and the same test as in Example 1 was conducted. As a result, a clear printed image was obtained, and the fixability was also good.
【００２４】実施例６
（カプセル粒子の作製）ブタジエンホモポリマー（Ｂ−
１０００：日本曹達社製）５０ｇおよび石油樹脂（ＦＴ
Ｒ６１２５：三井油化学社製）１５ｇを、飽和脂肪族炭
化水素系溶剤（Ｉｓｏｐａｒ Ｈ：エクソン化学社製
）２５ｇと酢酸エチル３０ｇの混合液に溶解させた。得
られた溶液に、磁性粉（ＥＰＴ−１０００：戸田工業社
製）５５ｇを入れ、ボールミルにて２０時間分散処理し
た。次にこの分散液１００ｇに対して、イソシアナート
（スミジュールＬ：住友バイエルウレタン社製）１５ｇ
および酢酸エチル１５ｇを加え充分混合した（この液を
Ａ液とする。）。一方イオン交換水２００ｇに、ヒドロ
キシプロピルメチルセルロース（メトロース６５ＳＨ５
０：信越化学社製）１０ｇを溶解させ、５℃まで冷却し
た（この液をＢ液とする。）。Example 6 (Preparation of capsule particles) Butadiene homopolymer (B-
1000: Nippon Soda Co., Ltd.) 50g and petroleum resin (FT
15 g of R6125 (manufactured by Mitsui Oil Chemicals) was dissolved in a mixed solution of 25 g of a saturated aliphatic hydrocarbon solvent (Isopar H: manufactured by Exxon Chemical) and 30 g of ethyl acetate. 55 g of magnetic powder (EPT-1000, manufactured by Toda Kogyo Co., Ltd.) was added to the obtained solution, and dispersed in a ball mill for 20 hours. Next, for 100 g of this dispersion, 15 g of isocyanate (Sumidur L: manufactured by Sumitomo Bayer Urethane)
and 15 g of ethyl acetate were added and thoroughly mixed (this liquid is referred to as liquid A). On the other hand, add hydroxypropyl methylcellulose (Metrose 65SH5) to 200g of ion-exchanged water.
0: manufactured by Shin-Etsu Chemical Co., Ltd.) was dissolved and cooled to 5°C (this liquid is referred to as liquid B).
【００２５】乳化機（オートホモミクサー：特殊機化工
業製）でＢ液を撹拌し、この中にＡ液をゆっくり投入し
て乳化を行った。このようにして乳化液中の油滴粒子の
平均粒径が約１２μｍのＯ／Ｗエマルジョンを得た。つ
ぎに乳化機に代えて、プロペラ型の撹拌羽根を備えた撹
拌機（スリーワンモータ：新東科学社製）を使用し、４
００回転／分で撹拌した。１０分後、この中に５％のジ
エチレントリアミン水溶液１００ｇを滴下した。滴下終
了後、６０℃に加温し、酢酸エチルを脱気させながら３
時間カプセル化反応を行った。反応終了後、２リットル
のイオン交換水にあけ、充分撹拌し静置した。カプセル
粒子が沈降した後、上澄みを取り除いた。この操作をあ
と７回繰り返して、カプセル粒子を洗浄した。このよう
にして、本発明のカプセル粒子を得た。カプセル粒子に
イオン交換水を加え、固形分濃度４０％の懸濁液に調製
した。Solution B was stirred in an emulsifier (auto homo mixer, manufactured by Tokushu Kika Kogyo Co., Ltd.), and solution A was slowly added thereto for emulsification. In this way, an O/W emulsion in which the average particle size of oil droplets in the emulsion was about 12 μm was obtained. Next, in place of the emulsifier, a stirrer equipped with propeller-type stirring blades (Three-One Motor: manufactured by Shinto Kagakusha) was used.
Stirred at 00 revolutions/min. After 10 minutes, 100 g of a 5% diethylenetriamine aqueous solution was added dropwise thereto. After dropping, heat to 60°C and add 3 ml of ethyl acetate while degassing the ethyl acetate.
A time encapsulation reaction was performed. After the reaction was completed, the mixture was poured into 2 liters of ion-exchanged water, thoroughly stirred, and allowed to stand still. After the capsule particles had settled, the supernatant was removed. This operation was repeated seven more times to wash the capsule particles. In this way, capsule particles of the present invention were obtained. Ion-exchanged water was added to the capsule particles to prepare a suspension with a solid content concentration of 40%.
【００２６】調製したカプセル粒子の懸濁液１２５ｇ（
カプセル粒子５０ｇに相当）に、イオン交換水１２５ｇ
を加え、プロペラ型の撹拌羽根を備えた撹拌機（スリー
ワンモータ：新東科学社製）にて２００回転／分で撹拌
した。これに１Ｎの硝酸５ｇ、１０％の硫酸セリウム水
溶液４ｇを加えた後、ジメタクリル酸エチレングリコー
ルを０．５ｇを加え、１５℃で３時間反応を行った。
反応終了後１リットルのイオン交換水にあけ、充分撹拌
し静置した。カプセル粒子が沈降した後、上澄みを取り
除いた。この操作をあと２回繰り返して、カプセル粒子
を洗浄した。このようにしてジメタクリル酸エチレング
リコールがカプセル外殻の表面にグラフト重合したカプ
セル粒子を得た。これを再びイオン交換水に再懸濁し、
プロペラ型の撹拌羽根を備えた撹拌機（スリーワンモー
タ：新東科学社製）にて２００回転／分で撹拌した。次
にこの中に０．４ｇの過硫酸カリウム、トリフルオロエ
チルメタクリレート１ｇ、０．１６ｇの亜硫酸水素ナト
リウムを順次添加し、２５℃で３時間反応を行った。反
応終了後、２リットルのイオン交換水にあけ、充分撹拌
し静置した。カプセル粒子が沈降した後、上澄みを取り
除いた。この操作をあと４回繰り返して、カプセル粒子
を洗浄した。このようにしてトリフルオロエチルメタク
リレートがカプセル外殻の表面にグラフト重合したカプ
セルトナーを得た。得られたカプセル懸濁液をステンレ
ス鋼のバットにあけ、乾燥機（ヤマト科学社製）にて６
０℃で１０時間乾燥した。125 g of the prepared capsule particle suspension (
(equivalent to 50g of capsule particles), 125g of ion exchange water
was added and stirred at 200 rpm using a stirrer equipped with a propeller-type stirring blade (Three-One Motor: manufactured by Shinto Kagakusha). After adding 5 g of 1N nitric acid and 4 g of 10% cerium sulfate aqueous solution to this, 0.5 g of ethylene glycol dimethacrylate was added, and the reaction was carried out at 15° C. for 3 hours. After the reaction was completed, the mixture was poured into 1 liter of ion-exchanged water, thoroughly stirred, and allowed to stand still. After the capsule particles had settled, the supernatant was removed. This operation was repeated two more times to wash the capsule particles. In this way, capsule particles in which ethylene glycol dimethacrylate was graft-polymerized on the surface of the capsule shell were obtained. Resuspend this in ion-exchanged water again,
Stirring was carried out at 200 revolutions/min using a stirrer equipped with a propeller-type stirring blade (Three-One Motor: manufactured by Shinto Kagakusha Co., Ltd.). Next, 0.4 g of potassium persulfate, 1 g of trifluoroethyl methacrylate, and 0.16 g of sodium bisulfite were sequentially added to the mixture, and the reaction was carried out at 25° C. for 3 hours. After the reaction was completed, the mixture was poured into 2 liters of ion-exchanged water, thoroughly stirred, and allowed to stand still. After the capsule particles had settled, the supernatant was removed. This operation was repeated four more times to wash the capsule particles. In this way, a capsule toner in which trifluoroethyl methacrylate was graft-polymerized on the surface of the capsule shell was obtained. The obtained capsule suspension was poured into a stainless steel vat and dried in a dryer (manufactured by Yamato Kagaku Co., Ltd.) for 6 hours.
It was dried at 0°C for 10 hours.
【００２７】次に、このカプセルトナー１００部に対し
て、疎水性シリカ（Ｒ９７２：日本アエロジル社製）を
０．７部添加し、充分混合した後、温度２０℃、湿度５
０％の環境下で評価を行った。使用した装置は、富士ゼ
ロックス社製の４１０５プリンターをカプセルトナー用
に改造したもので、定着圧力１２０ｋｇ／ｃｍ２ の圧
力定着器を装着したものであった。帯電性を測定した結
果、平均帯電量：−８μｃ／ｇ、逆極性トナー量：７重
量％であり、画像もかぶりのない鮮明な物であった。ま
た、定着性については、２４時間後測定したところ、指
でこすっても、消ゴムで消しても、画像流れや消えるこ
とは全くなかった。また、折り曲げテストを行って、画
像は剥がれ落ちることはなかった。Next, 0.7 parts of hydrophobic silica (R972: manufactured by Nippon Aerosil Co., Ltd.) was added to 100 parts of this capsule toner, and after thorough mixing, the temperature was 20°C and the humidity was 5%.
The evaluation was performed under a 0% environment. The apparatus used was a Fuji Xerox 4105 printer modified for use with capsule toner, and was equipped with a pressure fixing device with a fixing pressure of 120 kg/cm2. As a result of measuring the charging property, the average charge amount was -8 μc/g, the amount of reverse polarity toner was 7% by weight, and the image was clear without fogging. Regarding the fixability, measurements were taken after 24 hours, and there was no image fading or fading even when rubbed with a finger or erased with an eraser. In addition, the image did not peel off during the bending test.
【００２８】実施例７
実施例６におけるブタジエンホモポリマーの変わりに、
α，ω−ポリブタジエンジカルボン酸（Ｃ−１０００：
日本曹達社製）を用いて、同様にカプセルトナーを作成
し、実施例６と同様のテストを行った。その結果、平均
帯電量：−１２μｃ／ｇ、逆極性トナー量：５重量％で
あり、画像もかぶりのない鮮明な物であった。また、定
着性については、１０分、３０分、１時間、５時間、１
２時間、２４時間、１週間、１か月後に、指こすり、消
ゴム、折り曲げの各テストを実施した。その結果、１０
分および３０分後で、消ゴムでこすった場合、僅かに画
像が剥がれる他は、何ら変化もなく、一定した定着性を
示した。Example 7 Instead of the butadiene homopolymer in Example 6,
α,ω-Polybutadiene dicarboxylic acid (C-1000:
Capsule toner was prepared in the same manner using Nippon Soda Co., Ltd.), and the same test as in Example 6 was conducted. As a result, the average charge amount was -12 .mu.c/g, the amount of reverse polarity toner was 5% by weight, and the image was clear with no fog. Regarding fixing properties, 10 minutes, 30 minutes, 1 hour, 5 hours, 1
After 2 hours, 24 hours, 1 week, and 1 month, finger rubbing, eraser, and bending tests were performed. As a result, 10
When the image was rubbed with an eraser after 30 minutes and 30 minutes, there was no change other than slight peeling of the image, indicating constant fixing performance.
【００２９】実施例８
実施例６におけるブタジエンホモポリマーの代わりに、
マレイン化ポリブタジエン樹脂（ＢＮ−２０１０：日本
曹達社製）３０ｇを用い、石油樹脂の変わりにロジン系
樹脂（エステルガムＨＰ：荒川化学社製）２０ｇを用い
て、同様にカプセルトナーを作成し、実施例６と同様の
テストを行った。その結果、平均帯電量：−９μｃ／ｇ
、逆極性トナー量：３重量％であり、画像もかぶりのな
い鮮明な物であった。繰り返しプリントを行ったところ
、２０，０００枚のプリント後でも、鮮明なプリント画
像が得られた。また、定着性については、３０分間以降
は、安定しており、指こすり、消ゴム、折り曲げの各テ
ストに対して、安定して良好な定着性を示した。Example 8 Instead of the butadiene homopolymer in Example 6,
A capsule toner was prepared in the same manner using 30 g of maleated polybutadiene resin (BN-2010: manufactured by Nippon Soda Co., Ltd.) and 20 g of rosin resin (Ester Gum HP: manufactured by Arakawa Chemical Co., Ltd.) instead of petroleum resin. A test similar to Example 6 was conducted. As a result, average charge amount: -9μc/g
, the amount of reverse polarity toner was 3% by weight, and the image was clear with no fog. When repeated printing was performed, clear printed images were obtained even after printing 20,000 sheets. Furthermore, the fixing properties were stable after 30 minutes, and stable and good fixing properties were shown in the finger rubbing, eraser, and bending tests.
【００３０】実施例９
実施例６、７および８で作製したカプセルトナ−を、定
着圧力８０ｋｇ／ｃｍ２ 、温度５０℃として、加熱ア
シスト付圧力定着器を取り付けた富士ゼロックス社製４
１０５プリンター改造機でテストした結果、定着直後に
指こすり、消しゴム、折り曲げの各テストを実施したと
ころ、何等の変化も見られず、極めて良好な結果が得ら
れることが分かった。Example 9 The capsule toners prepared in Examples 6, 7, and 8 were fixed at a fixing pressure of 80 kg/cm 2 and a temperature of 50° C. using a Fuji Xerox 4 manufactured by Fuji Xerox Co., Ltd. equipped with a pressure fixing device with heating assist.
As a result of testing on a modified 105 printer, it was found that when finger rubbing, eraser, and bending tests were performed immediately after fixing, no changes were observed, and very good results were obtained.
【００３１】実施例１０
実施例６におけるブタジエンホモポリマーの代わりに、
α，ω−ポリブタジエングリコール（Ｇ−２０００：日
本曹達社製）５０ｇを用いて、飽和脂肪族炭化水素溶剤
としてＩｓｏｐａｒ Ｌ ３０ｇを用いた以外は、
同様にカプセルトナーを作成し、実施例６と同様のテス
トを行った。その結果、鮮明なプリント画像が得られ、
また定着性も良好なものであった。Example 10 Instead of the butadiene homopolymer in Example 6,
Except that 50 g of α,ω-polybutadiene glycol (G-2000: manufactured by Nippon Soda Co., Ltd.) was used and 30 g of Isopar L was used as the saturated aliphatic hydrocarbon solvent.
A capsule toner was prepared in the same manner, and the same test as in Example 6 was conducted. As a result, clear printed images are obtained,
Furthermore, the fixing properties were also good.
【００３２】[0032]
【発明の効果】本発明においては、芯物質の重合体成分
として、上記一般式（Ｉ）で示されるポリブタジエン化
合物を使用するため、有機感光体を変質する作用を有す
る高沸点溶剤を使用する必要がない。したがって、本発
明のカプセルトナーを用いると、有機感光体を変質する
ことがなくなると共に、定着によって上記ポリブタジエ
ン化合物が、転写紙に浸透して硬化し、強度の高い定着
像を形成する。その結果、形成された定着像は、指こす
り、消しゴムなどでこすっても、画像が流れることがな
くなり、優れた定着性を有するものとなる。Effects of the Invention In the present invention, since the polybutadiene compound represented by the above general formula (I) is used as the polymer component of the core material, it is necessary to use a high boiling point solvent that has the effect of altering the organic photoreceptor. There is no. Therefore, when the capsule toner of the present invention is used, the organic photoreceptor is not altered in quality, and upon fixing, the polybutadiene compound penetrates into the transfer paper and hardens, forming a fixed image with high strength. As a result, the formed fixed image does not run even when rubbed with a finger or an eraser, and has excellent fixing properties.
Claims (2)
らなるカプセルトナーにおいて、該芯物質が、少なくと
も着色材と、下記一般式（Ｉ）で示される分岐ビニル基
を有するポリブタジエン化合物を含有することを特徴と
する電子写真用カプセルトナー。 【化１】1. A capsule toner comprising a core material and a shell material covering the core material, wherein the core material contains at least a colorant and a polybutadiene compound having a branched vinyl group represented by the following general formula (I). A capsule toner for electrophotography, which is characterized by: [Chemical formula 1]
らなるカプセルトナーにおいて、該芯物質が、少なくと
も着色材と、下記一般式（Ｉ）で示される分岐ビニル基
を有するポリブタジエン化合物と、該ポリブタジエン化
合物を溶解または膨潤する飽和脂肪族炭化水素系の高沸
点溶剤とを含有することを特徴とする電子写真用カプセ
ルトナー。 【化２】2. A capsule toner comprising a core material and a shell material covering the core material, wherein the core material contains at least a colorant and a polybutadiene compound having a branched vinyl group represented by the following general formula (I), A capsule toner for electrophotography, comprising a saturated aliphatic hydrocarbon-based high boiling point solvent that dissolves or swells the polybutadiene compound. [Chemical 2]
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3213177A JPH04330457A (en) | 1991-03-05 | 1991-07-31 | Capsule toner |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6234891 | 1991-03-05 | ||
| JP3-62348 | 1991-03-05 | ||
| JP3213177A JPH04330457A (en) | 1991-03-05 | 1991-07-31 | Capsule toner |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04330457A true JPH04330457A (en) | 1992-11-18 |
Family
ID=26403410
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3213177A Pending JPH04330457A (en) | 1991-03-05 | 1991-07-31 | Capsule toner |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04330457A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06175389A (en) * | 1992-12-04 | 1994-06-24 | Fuji Xerox Co Ltd | Encapsulated toner and image forming method using the same |
| JP2007133308A (en) * | 2005-11-14 | 2007-05-31 | Konica Minolta Business Technologies Inc | Electrophotographic toner, method for manufacturing the electrophotographic toner, and image forming method |
-
1991
- 1991-07-31 JP JP3213177A patent/JPH04330457A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06175389A (en) * | 1992-12-04 | 1994-06-24 | Fuji Xerox Co Ltd | Encapsulated toner and image forming method using the same |
| JP2007133308A (en) * | 2005-11-14 | 2007-05-31 | Konica Minolta Business Technologies Inc | Electrophotographic toner, method for manufacturing the electrophotographic toner, and image forming method |
| JP4661541B2 (en) * | 2005-11-14 | 2011-03-30 | コニカミノルタビジネステクノロジーズ株式会社 | Electrophotographic toner, method for producing electrophotographic toner, and image forming method |
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