JPH0384073A - Thermally anchoring ink and patterned sheet and formation of pattern - Google Patents
Thermally anchoring ink and patterned sheet and formation of patternInfo
- Publication number
- JPH0384073A JPH0384073A JP1220689A JP22068989A JPH0384073A JP H0384073 A JPH0384073 A JP H0384073A JP 1220689 A JP1220689 A JP 1220689A JP 22068989 A JP22068989 A JP 22068989A JP H0384073 A JPH0384073 A JP H0384073A
- Authority
- JP
- Japan
- Prior art keywords
- heat
- ink
- pattern
- sheet
- fixable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000010698 whale oil Substances 0.000 description 1
Landscapes
- Impression-Transfer Materials And Handling Thereof (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、定着性、耐熱性、耐擦過性に優れて熱転写用
途に好適な熱定着性インクとそのインクシート、及び当
該インクを用いたパターンシ一トとその製造方法、並び
にパターン形成方法に関する。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a thermally fixable ink that has excellent fixing properties, heat resistance, and scratch resistance and is suitable for thermal transfer applications, an ink sheet thereof, and a pattern sheet using the ink. The present invention relates to a pattern, a method for manufacturing the same, and a method for forming a pattern.
発明の背景
記録装置の小型化や維持管理の容易性、低騒音性などの
利点に着目されて、熱転写記録方式がワードプロセッサ
等のＯＡ分野や、バーコードプリンタ等のＦＡ分野ない
しＰＯＳシステム等へと普及するのに伴い、それに用い
る熱定着性インクに新たな性能が要求されている。高温
保存のための耐熱性の要求、長期保存のための耐擦過性
の要求などはその例である。耐熱性に優れる熱定着性イ
ンクは、例えばバーコード等を付与した識別ラベルの場
合、ガラスないし坑底セラミックや金属などからなる熱
処理を受ける製品や半製品ないし部品等への適用が可能
となり、多品種少量生産体制下でのそれら製品等の管理
を容易にする。BACKGROUND OF THE INVENTION As the advantages of recording devices such as miniaturization, ease of maintenance and management, and low noise are noticed, thermal transfer recording methods have been used in the OA field such as word processors, the FA field such as barcode printers, and POS systems. As inks become more popular, new performance is required of heat-fixing inks used for them. Examples include the requirement for heat resistance for high-temperature storage and the requirement for scratch resistance for long-term storage. Heat-fixable inks with excellent heat resistance can be applied to products, semi-finished products, and parts made of glass, bottom-bottom ceramics, and metals that undergo heat treatment, for example, in the case of identification labels with barcodes, etc. It facilitates the management of these products under a low-variety, low-volume production system.
従来の技術及び課題
従来、熱定着性インクとしては、カーボン等の顔料と熱
溶融性バインダとの混合物からなるものが知られていた
。しかしながら、かかる熱定着性インクを用いてパター
ンを付与した被着体を高温（約３００℃以上）で処理す
ると、パターンが焼失したり、変質したりして実用に供
しつるパターンが得られない問題点があった。BACKGROUND ART Conventionally, heat-fixable inks made of a mixture of a pigment such as carbon and a heat-fusible binder have been known as heat-fixable inks. However, when an adherend to which a pattern has been applied using such a heat-fixable ink is treated at high temperatures (approximately 300°C or higher), the pattern may be burned off or deteriorated, making it impossible to obtain a pattern that can be used in practical applications. There was a point.
ガラス粉末を併用して焼成によりパターンが定着するよ
うにした熱定着性インクも知られているが、ガラス粉末
含量が少ないと被着体に付与したパターンが外部衝撃等
で簡単に損傷したり、その周辺を汚染するなど耐擦過性
に乏しく、反対にガラス粉末含量が多いと熱転写性の維
持下に付与インク層の厚さを増すことが困難でパターン
濃度に乏しく、明瞭なパターンを形成できない問題点が
あった。Heat-fixable inks are also known in which a pattern is fixed by firing using glass powder, but if the glass powder content is low, the pattern applied to the adherend may be easily damaged by external impact, etc. The problem is that scratch resistance is poor due to contamination of the surrounding area, and on the other hand, if the content of glass powder is high, it is difficult to increase the thickness of the applied ink layer while maintaining thermal transferability, resulting in poor pattern density and the inability to form a clear pattern. There was a point.
課題を解決するための手段
本発明は、熱溶融性の無機粉末と耐熱性顔料の体積に基
づく配合割合を制御することにより上記の課題を克服し
たものである。Means for Solving the Problems The present invention overcomes the above problems by controlling the blending ratio based on the volume of the heat-fusible inorganic powder and the heat-resistant pigment.
すなわち本発明は、熱溶融性の無機粉末と、耐熱性顔料
と、熱溶融性バインダからなり、前記無機粉末を体積部
に基づいて耐熱性顔料１００部あたり１００〜５００部
含有することを特徴とする熱定着性インク、並びに前記
熱定着性インクを支持基材に保持させてなることを特徴
とするインクシート、及びそのインクシートをケースに
収容してなることを特徴とするインクリボンカートリッ
ジの提供を目的とする。That is, the present invention is characterized by comprising a heat-fusible inorganic powder, a heat-resistant pigment, and a heat-fusible binder, and containing 100 to 500 parts by volume of the inorganic powder per 100 parts of the heat-resistant pigment. To provide a heat-fixable ink, an ink sheet comprising the heat-fixable ink held on a support base material, and an ink ribbon cartridge comprising the ink sheet housed in a case. With the goal.
また本発明は、当該熱定着性インクからなるパターンを
、受容シートにおける熱溶融性のインク受容層又は転写
紙の上に設けてなることを特徴とするパターンシート、
及び前記したインクシートを用いて熱転写プリンタを介
しインク受容層の上にパターンを形成定着させることを
特徴とする当該パターンシートの製造方法の提供も目的
とする。The present invention also provides a pattern sheet, characterized in that a pattern made of the heat-fixable ink is provided on a heat-fusible ink receiving layer of a receiving sheet or on a transfer paper;
Another object of the present invention is to provide a method for manufacturing a pattern sheet, which comprises forming and fixing a pattern on an ink-receiving layer using a thermal transfer printer using the above-described ink sheet.
さらに本発明は、受容シートを用いてなるパターンシー
トを被着体に接着し、そのパターンシートを加熱処理し
てパターンとインク受容層を融和させることを特徴とす
るパターン形成方法、及び被着体に接着した受容シート
のインク受容層の上に、当該熱定着性インクからなるパ
ターンを形成したのち加熱処理し、パターンとインク受
容層を融和させることを特徴とするパターン形成方法の
提供も目的とする。Furthermore, the present invention provides a pattern forming method, which comprises adhering a pattern sheet using a receptor sheet to an adherend, and heat-treating the pattern sheet to blend the pattern and the ink-receiving layer, and an adherend. Another object of the present invention is to provide a pattern forming method, which comprises forming a pattern made of the heat-fixable ink on the ink-receiving layer of a receptor sheet adhered to the substrate, and then heat-treating the ink-receiving layer to blend the pattern with the ink-receiving layer. do.
作用
熱溶融性の無機粉末と耐熱性顔料の配合割合を上記した
体積部に基づく範囲とすることにより、熱転写パターン
の解像度に優れ、焼成後におけるパターンの耐擦過性に
優れる熱定着性インクとすることができる。By adjusting the blending ratio of the heat-fusible inorganic powder and the heat-resistant pigment to the range based on the volume parts described above, a heat-fixing ink with excellent resolution of the heat-transfer pattern and excellent scratch resistance of the pattern after firing can be obtained. be able to.
発明の構成要素の例示
本発明の熱定着性インクは、熱溶融性の無機粉末と、耐
熱性顔料と、熱溶融性バインダを成分とする。Examples of Constituent Elements of the Invention The heat-fixing ink of the present invention includes a heat-fusible inorganic powder, a heat-resistant pigment, and a heat-fusible binder.
熱溶融性の無機粉末としては、２００〜１７００℃で軟
化、ないし溶融するものが用いられる。一般には亜鉛、
スズ、鉛、アルミニウム、クロム、コバルト、鉄、銅、
ニッケル、カドミウム、ビスマスなどからなる金属の単
体物や、かかる金属を含む合金、Ｓｉｏ２、Ｐ２０ｓ
、Ｚｎ０Ｘ’ＰｂＯ，Ｂ２０３ 、Ａ Ｉ ２０３等を
主成分とするガラスの粉末などが用いられる。As the heat-melting inorganic powder, one that softens or melts at 200 to 1700°C is used. Generally zinc,
tin, lead, aluminum, chromium, cobalt, iron, copper,
Single metals such as nickel, cadmium, bismuth, alloys containing such metals, Sio2, P20s
, Zn0X'PbO, B203, A I203, etc., as a main component.
耐熱性顔料としては、焼成の前後における質量変化の少
ないものが用いられる。一般にはコバルト、クロム、鉄
、鋼、亜鉛、マグネシウム、マンガン、スズ、アルミニ
ウム、ニッケル、チタンなどの金属の少なくとも１種を
含む無機化合物や、耐熱性カーボンなどがあげられる。As the heat-resistant pigment, one whose mass changes little before and after firing is used. Common examples include inorganic compounds containing at least one metal such as cobalt, chromium, iron, steel, zinc, magnesium, manganese, tin, aluminum, nickel, and titanium, and heat-resistant carbon.
無機化合物の具体例としては、ＣｕＣｒ２０１．２（Ｃ
ｏ、Ｍｇ）０・ＳｎＯ２、Ｃ０Ｏ−Ａ１２０３、Ｆｅ２
Ｏ３、Ｃ０（ＡＩ−Ｃｒ）２０４ 、（ＺｎＦｅ）（Ｆ
ｅＣｒ）２０４、（ＣｕＭｎ）（ＣｒＭｎ）２０４ 、
ＭｎＰＯ４、（Ｃ。A specific example of an inorganic compound is CuCr201.2 (C
o, Mg)0.SnO2, C0O-A1203, Fe2
O3, C0(AI-Cr)204, (ZnFe)(F
eCr)204, (CuMn)(CrMn)204,
MnPO4, (C.
Ｆｅ）（ＦｅＣｒ）２０４ 、ＣＯ２ＴｉＯ４・Ｎｉ０
ＺｎＯ１ＣｏＯ−ＺｎＯなどがあげられる。Fe) (FeCr)204, CO2TiO4・Ni0
Examples include ZnO1CoO-ZnO.
前記無機粉末や耐熱性顔料の形状や粒径について特に限
定はないが、インクシートの形成性等の点からは平均粒
径２ｈｍ以下、就中１ｈｍ以下のものが好ましい。There are no particular limitations on the shape or particle size of the inorganic powder or heat-resistant pigment, but from the viewpoint of ink sheet formability, it is preferable to have an average particle size of 2 hm or less, particularly 1 hm or less.
熱溶融性バインダとしてはワックスが用いられる。その
種類につき特に限定はない。好ましく用いうるワックス
の例としては、パラフィンワ・ソクス、マイクロワック
ス、ポリエチレンワックスの如きパラフィン系ワックス
類、蜜ろう、カルナウバワックス、木ろうの如き天然ワ
ックス類、ステアリルアルコール、パルミチルアルコー
ルの如き高級アルコール系ワックス類、ステアロアミド
、オレオアミド、パルミチロアミドの如き高級アミド系
ワックス類、ヘキストワックス、ブチルステアレート、
エチルパルミテート、ミリスチルステアレートの如きエ
ステル系ワックス類、ステアリン酸、パルミチン酸、ベ
ヘニン酸、ミリスチン酸、カプリン酸、ラウリン酸、１
．２０−エイコサンニ酸の如き高級脂肪酸からなる酸ワ
ツクス類、ソルビタン誘導体類などがあげられる。Wax is used as the heat-melting binder. There are no particular limitations on the type. Examples of waxes that can be preferably used include paraffin waxes such as paraffin wax, micro wax, and polyethylene wax, natural waxes such as beeswax, carnauba wax, and pyril wax, and high-grade waxes such as stearyl alcohol and palmityl alcohol. Alcohol waxes, higher amide waxes such as stearamide, oleamide, palmityroamide, Hoechst wax, butyl stearate,
Ester waxes such as ethyl palmitate and myristyl stearate, stearic acid, palmitic acid, behenic acid, myristic acid, capric acid, lauric acid, 1
．． Examples include acid waxes made of higher fatty acids such as 20-eicosanniic acid, sorbitan derivatives, and the like.
熱溶融性バインダとしてポリマを併用してもよく、環球
法に基づく軟化点が４０〜２００℃のポリマが好ましく
用いられる。その例としては、ゼラチン、その誘導体、
セルロース誘導体、カゼイン等の蛋白質やデンプン等の
多糖類の如き天然物ないしその誘導体、ポリビニルアル
コール、ポリビニルピロリドン、アクリルアミド重合体
の如き水溶性ポリマ、ビニル系ラテックス、ウレタン系
ラテックスの如きポリマーラテックス、ポリビニルブチ
ラール、ポリビニルホルマール、ポリエチレン、ポリプ
ロピレン、ポリアミド、エチルセルロース、セルロース
アセテート、ポリスチレン、ポリ酢酸ビニル、ポリ塩化
ビニル、ポリ塩化ビニリデン、塩化ビニル・酢酸ビニル
コポリマ、エチレン・酢酸ビニルコポリマ、塩化ビニル
・酢酸ビニル・マレイン酸ターポリマ、エステルガムの
如きロジン誘導体、アクリル酸やメタクリル酸の如き酸
系ポリマ、メチル基、エチル基、ｎ−ブチル基、イソブ
チル基の如きアルキル基を有する前記酸のエステル系モ
ノマなどを成分とする単成分系ポリマや共重合系ポリマ
、あるいは前記エステル系モノマにエチレン、スチレン
、酢酸ビニル、塩化ビニル、ブチレン、イソブチレン、
ブタジェンの如きビニル系モノマを２０重量％以下、就
中１０重量％以下併用した共重合系ポリマなどがあげら
れる。A polymer may also be used as the heat-melting binder, and a polymer having a softening point of 40 to 200°C based on the ring and ball method is preferably used. Examples include gelatin, its derivatives,
Cellulose derivatives, proteins such as casein, natural products or derivatives thereof such as polysaccharides such as starch, water-soluble polymers such as polyvinyl alcohol, polyvinylpyrrolidone, acrylamide polymers, polymer latex such as vinyl latex, urethane latex, polyvinyl butyral. , polyvinyl formal, polyethylene, polypropylene, polyamide, ethyl cellulose, cellulose acetate, polystyrene, polyvinyl acetate, polyvinyl chloride, polyvinylidene chloride, vinyl chloride/vinyl acetate copolymer, ethylene/vinyl acetate copolymer, vinyl chloride/vinyl acetate/maleic acid terpolymers, rosin derivatives such as ester gums, acid polymers such as acrylic acid and methacrylic acid, and ester monomers of the above acids having alkyl groups such as methyl, ethyl, n-butyl, and isobutyl groups. Monocomponent polymers, copolymer polymers, or the ester monomers include ethylene, styrene, vinyl acetate, vinyl chloride, butylene, isobutylene,
Examples include copolymer polymers containing a vinyl monomer such as butadiene in an amount of 20% by weight or less, especially 10% by weight or less.
熱定着性インクの調製は、熱溶融性の無機粉末と耐熱性
顔料と熱溶融性バインダの１種又は２種以上を適宜に混
合することにより行うことができる。熱定着性インクに
おける熱溶融性の無機粉末、耐熱性顔料、ワックス、ポ
リマの組成比は、熱溶融性の無機粉末と耐熱性顔料の合
計１００重量部あたりワックス１０〜５００重量部、就
中３０〜４００重量部、ポリマＯ〜５００重量部、就中
１〜４００重量部、特に５〜３００重量部が用いられる
。熱溶融性の無機粉末の配合量は、体積部に基づいて耐
熱性顔料１００部あたり１００〜５００部、就中１５０
〜４００部とされる。The heat-fixable ink can be prepared by appropriately mixing one or more of heat-fusible inorganic powder, heat-resistant pigment, and heat-fusible binder. The composition ratio of the heat-fusible inorganic powder, heat-resistant pigment, wax, and polymer in the heat-fixable ink is 10 to 500 parts by weight, especially 30 parts by weight, of wax per 100 parts by weight of the heat-fusible inorganic powder and heat-resistant pigment. ~400 parts by weight, ~500 parts by weight of polymer O, particularly 1 to 400 parts by weight, especially 5 to 300 parts by weight are used. The blending amount of the heat-fusible inorganic powder is 100 to 500 parts, particularly 150 parts, per 100 parts of the heat-resistant pigment based on volume parts.
~400 copies.
かかる配合割合とすることにより、明瞭なパターンを形
成できて、焼成後における形成パターンを耐擦過性、明
瞭性に優れるものとすることができる。なお前記の体積
部における体積は、質量を比重で除した値に基づき、そ
の比重は比重びん法やビクノメーター法の如き液浸法で
測定した真密度に基づく。With such a blending ratio, a clear pattern can be formed, and the formed pattern after firing can have excellent scratch resistance and clarity. The volume in the above-mentioned volume part is based on the value obtained by dividing the mass by the specific gravity, and the specific gravity is based on the true density measured by an immersion method such as the pycnometer method or the vicinometer method.
熱定着性インクには柔軟剤等の適宜な添加剤を加えても
よい。柔軟剤としては通常、ひまし油、アマニ油、オリ
ーブ油の如き植物油、鯨油の如き動物油、その他鉱油な
どが用いられる。Appropriate additives such as softeners may be added to the heat fixable ink. As softeners, vegetable oils such as castor oil, linseed oil, and olive oil, animal oils such as whale oil, and other mineral oils are usually used.
本発明のインクシートは、熱定着性インクを支持基材に
塗布するなり、含浸させるなどして保持させたものであ
る。支持基材としては例えば、普通紙、コンデンサー紙
、ラミネート紙、コート紙の如き紙類、ポリエチレン、
ポリプロピレン、ボッエステル、ポリスチレン、ポリイ
ミドの如き樹脂からなるフィルムないし紙・フィルム複
合体、アルミニウム箔の如き金属シート、ポリアミド、
ポリイミド、ポリエステル等の繊維からなる布などがあ
げられる。The ink sheet of the present invention is obtained by coating or impregnating a support base material with heat-fixable ink. Examples of supporting substrates include papers such as plain paper, condenser paper, laminated paper, coated paper, polyethylene,
Films or paper/film composites made of resins such as polypropylene, Bossester, polystyrene, polyimide, metal sheets such as aluminum foil, polyamide,
Examples include cloth made of fibers such as polyimide and polyester.
熱転写プリンタに適用するためのインクシートにあって
は、耐熱性、寸法安定性、表面平滑性に優れる支持基材
を用いることが望ましい。サーマルプリンターヘッド等
の熱源の加熱温度で軟質化ないし可塑化せず、支持体と
しての強靭性を保持する耐熱性ないし寸法安定性を有し
、熱定着性インクの転写を阻害しない表面平滑性を有す
る支持基材が好ましく用いつる。表面平滑度としては、
転写率や画像の再現制度の点より、ＪＩＳ Ｐ ８１
１９に基づくベック試験機による平滑度が１００秒以上
、就中３００秒以上のものが好ましい。支持基材の厚さ
は通常、熱伝導性の点より約６０μｍ以下、就中２〜２
０μｍが適当である。For ink sheets to be applied to thermal transfer printers, it is desirable to use a support base material that has excellent heat resistance, dimensional stability, and surface smoothness. It does not soften or plasticize at the heating temperature of a heat source such as a thermal printer head, has heat resistance or dimensional stability that maintains its toughness as a support, and has a surface smoothness that does not inhibit the transfer of heat-fixable ink. A supporting substrate having a vine is preferably used. As for surface smoothness,
In terms of transfer rate and image reproduction system, JIS P 81
It is preferable that the smoothness is 100 seconds or more, especially 300 seconds or more as measured by a Beck tester based on 19. The thickness of the supporting base material is usually about 60 μm or less, especially 2 to 2 μm, from the viewpoint of thermal conductivity.
0 μm is appropriate.
熱定着性インクを支持基材に保持させる方式について特
に限定はなく、いずれの公知方式も適用することができ
る。その例としては、熱定着性インクを適宜な溶媒に溶
解ないし分散させた液を支持基材に塗布する方式などが
あげられる。その際、溶媒としては例えばトルエン、メ
チルエチルケトン、メチルイソブチルケトン、酢酸エチ
ル、酢酸ブチル、メタノール、エタノール、イソプロパ
ツール、ソルベントナフサ、ヘキサン、ヘプタンなど適
宜なものを用いてよい。塗布は、リバースロールコータ
、押出コータ、グラビアコータ、ワイヤバーなと適宜な
塗布機を用いて行ってよい。熱定着性インクを塗布層と
して支持基材に設ける場合、その厚さは耐熱性顔料の含
有濃度にもよるが、一般には３０μｍ以下、就中２〜２
０μｍとされる。なお熱定着性インクの塗布層を設けな
い支持基材面は任意に構成してよく、適宜に利用してよ
い。There is no particular limitation on the method of holding the heat fixable ink on the support substrate, and any known method can be applied. An example of this method is a method in which a liquid in which heat-fixable ink is dissolved or dispersed in an appropriate solvent is applied to a supporting substrate. In this case, appropriate solvents such as toluene, methyl ethyl ketone, methyl isobutyl ketone, ethyl acetate, butyl acetate, methanol, ethanol, isopropanol, solvent naphtha, hexane, and heptane may be used. Coating may be performed using a suitable coating machine such as a reverse roll coater, extrusion coater, gravure coater, or wire bar. When a heat-fixable ink is provided as a coating layer on a supporting substrate, its thickness depends on the concentration of the heat-resistant pigment, but is generally 30 μm or less, particularly 2 to 2 μm.
It is assumed to be 0 μm. Note that the supporting base material surface on which the heat-fixable ink coating layer is not provided may be configured as desired and may be used as appropriate.
インクシートはそのまま実用に供してもよい。The ink sheet may be put to practical use as it is.
また、適当な幅に裁断して熱転写リボン等のリボン形態
とし、これをケースに収容してインクリボンカートリッ
ジにするなどして、各種のプリンタなどに適用できる形
態として実用に供してもよい。Further, the ribbon may be cut to an appropriate width to form a ribbon such as a thermal transfer ribbon, and this may be housed in a case to form an ink ribbon cartridge, so that it can be put to practical use in a form that can be applied to various printers.
本発明の熱定着性インクないしそのインクシートは紙、
プラスチック、金属、セラミック等の種々の材質からな
る被着体に適用することができる。The heat fixable ink or ink sheet of the present invention can be applied to paper,
It can be applied to adherends made of various materials such as plastic, metal, and ceramic.
熱転写プリンタ等の加熱媒体を介し被着体に印字ないし
パターンを付与した場合にはそのままインクを定着させ
ることができる。転写紙に形成したパターンを被着体に
転写したときなど、加熱媒体を介すことなくパターンを
付与した場合には、熱ロールで押圧するなど適宜な加熱
処理を施すことにより、インクを定着させることができ
る。インクを定着させるための加熱処理は被着体に対し
て行ってもよい。When printing or patterns are applied to an adherend using a heating medium such as a thermal transfer printer, the ink can be fixed as is. When a pattern is applied without using a heating medium, such as when a pattern formed on transfer paper is transferred to an adherend, the ink is fixed by applying an appropriate heat treatment such as pressing with a heated roll. be able to. Heat treatment for fixing the ink may be performed on the adherend.
本発明のパターンシートは、受容シートのインク受容層
や、転写紙の上に熱定着性インクからなるパターンを設
けたものである。受容シートのインク受容層の上に設け
る場合、そのパターンは加熱定着させるときもあるが、
転写紙の上に設ける場合には、そのパターンを他の被着
体に転写する必要のあることから、転写紙に対しパター
ンを加熱定着させない。The pattern sheet of the present invention is one in which a pattern made of heat-fixable ink is provided on the ink receiving layer of a receiving sheet or on a transfer paper. When provided on the ink receiving layer of a receiving sheet, the pattern is sometimes fixed by heating.
When provided on transfer paper, the pattern is not heat-fixed to the transfer paper because it is necessary to transfer the pattern to another adherend.
受容シートとしては、無機粉末と樹脂の混合物からなり
インクの定着ベースとなる熱溶融性のインク受容層を耐
熱性フィルムからなる基材に設けたものや、ガラス粉末
ないしセラミック粉末を含有する熱溶融性のセラミック
系シートなどがあげられる。The receiving sheet may be one in which a heat-melting ink-receiving layer made of a mixture of inorganic powder and resin and serving as an ink fixing base is provided on a base material made of a heat-resistant film, or a heat-melting ink-receiving layer containing a glass powder or ceramic powder. Examples include ceramic sheets.
前者は２００〜３００℃程度の比較的低温での使用を目
的とする低温用受容シートであり、ポリエステルやポリ
イミドの如き耐熱性樹脂からなるフィルムやその積層体
に、エポキシ樹脂、アクリル樹脂、ポリエステル樹脂等
の樹脂と無機粉末の混合物からなるインク受容層を設け
て形成される。The former is a low-temperature receiving sheet intended for use at relatively low temperatures of about 200 to 300 degrees Celsius, and is a film or laminate made of heat-resistant resin such as polyester or polyimide, and is coated with epoxy resin, acrylic resin, or polyester resin. It is formed by providing an ink-receiving layer made of a mixture of resin and inorganic powder.
後者のセラミック系シートは、高温、就中３００〜１７
００℃での使用を目的とする高温用受容シートである。The latter ceramic sheet can be heated at high temperatures, especially 300 to 17
This is a high temperature receiving sheet intended for use at 00°C.
その例としては鉛ガラス系、ホウ珪酸鉛ガラス系、ソー
ダガラス系、珪酸ガラス系、石英ガラス系等の適宜なガ
ラス粉末を、必要に応じセラミック、金属ないしその酸
化物等からなる無機物や、有機バインダなどを用いて熱
溶融性のシートとしたものがあげられる（例えば特開昭
６２−２２３０５７号公報等〉。なお、識別ラベルとし
て利用する場合などのように、熱定着性インクとインク
受容層の加熱処理体との間に良好なコントラストや色調
の変化が望まれるときには、インク受容層に顔料や充填
剤を添加して適当な色調に着色化することが好ましい。Examples include suitable glass powders such as lead glass, lead borosilicate glass, soda glass, silicate glass, and quartz glass, as well as ceramics, inorganic materials such as metals or their oxides, and organic Examples include sheets made into heat-fusible sheets using a binder etc. (for example, Japanese Patent Laid-Open No. 62-223057, etc.).In addition, when used as an identification label, heat-fixable ink and an ink-receiving layer are used. When a good contrast or change in color tone is desired with respect to the heat-treated body, it is preferable to add pigments or fillers to the ink-receiving layer to color the ink-receiving layer into an appropriate color tone.
受容シートのインク受容層に設けるパターンは、バーコ
ードパターンや文字、陶磁器用等の絵柄パターンなど任
意である。The pattern provided on the ink receiving layer of the receiving sheet may be arbitrary, such as a bar code pattern, characters, or a picture pattern for ceramics.
受容シートを用いたパターンシートの好ましい製造方法
は、熱転写式のインクシートとプリンタを介してパター
ンを形成しつつ定着させる方法である。この方法は、パ
ターンシートの製造効率に優れるほか、形成されたパタ
ーンシートを被着体に接着する場合等における取り扱い
性に優れるなどの利点を有する。また、パターンシート
を加熱処理してなるパターン付シートにおけるパターン
が耐擦過性に優れる利点もある。A preferred method for manufacturing a pattern sheet using a receiving sheet is a method in which a pattern is formed and fixed using a thermal transfer ink sheet and a printer. This method has advantages such as excellent production efficiency of the pattern sheet and excellent handling properties when adhering the formed pattern sheet to an adherend. Another advantage is that the pattern on a patterned sheet obtained by heat-treating a patterned sheet has excellent scratch resistance.
被着体にパターンを形成する方法としては、受容シート
を用いてなるパターンシートを被着体に接着して加熱処
理する方法、あるいは被着体に受容シートを接着したの
ち、そのインク受容層に熱定着性インクのパターンを付
与して加熱処理する方法などがあげられる。前者の方法
は、予めパターンシートを形成してこれを被着体に接着
するもので、熱転写プリンタを用いて形成したパターン
シートを介し、精微なパターンを被着体に容易に付与で
きる利点がある。後者の方法は、先ず受容シートを被着
体に接着したのち、そのインク受容層にパターンを形成
してパターンシートとするもので、被着体が基板やシー
ト状のものなどからなる場合に好ましく適用される。な
お、離型処理紙ないしフィルム、金属箔などの適宜な転
写紙に設けたパターンを受容シートに転写してパターン
シートとする方式は、いずれの形成方法の場合にも適用
することができる。As a method of forming a pattern on an adherend, there is a method of adhering a pattern sheet made of a receptor sheet to an adherend and heat treatment, or a method of adhering a receptor sheet to an adherend and then applying a pattern to the ink-receiving layer. Examples include a method in which a pattern of heat-fixable ink is applied and then heat-treated. The former method involves forming a pattern sheet in advance and adhering it to the adherend, and has the advantage that a fine pattern can be easily applied to the adherend through the pattern sheet formed using a thermal transfer printer. . In the latter method, a receiving sheet is first adhered to an adherend, and then a pattern is formed on the ink-receiving layer to form a pattern sheet, and is preferred when the adherend consists of a substrate or sheet-like object. Applicable. Note that any method of forming a pattern sheet by transferring a pattern on a suitable transfer paper such as release-treated paper, film, or metal foil to a receiving sheet can be applied.
被着体に接着するパターンシートの加熱処理は、熱定着
性インクやインク受容層の種類などに応じて適宜な加熱
温度で行ってよい。一般には、２００〜１７００℃の温
度範囲とされる。加熱処理により、熱定着性インク中の
熱溶融性無機粉末が耐熱性顔料を保持しつつインク受容
層と融和し、耐擦過性に優れるパターンを形成する。The pattern sheet to be adhered to the adherend may be heated at an appropriate heating temperature depending on the type of heat-fixable ink and ink-receiving layer. Generally, the temperature range is 200 to 1700°C. Through the heat treatment, the heat-fusible inorganic powder in the heat-fixable ink blends with the ink-receiving layer while retaining the heat-resistant pigment, forming a pattern with excellent scratch resistance.
被着体に接着される受容シートには、必要に応じ粘着剤
層や接着層を付設するなどして被着体に対する接着力が
高められる。セラミック系シートを用いて焼成処理する
場合には、焼成時に消失する粘着剤の使用が適当である
。低温用受容シートの場合には、耐熱性の粘着剤、ない
し加熱処理で硬化する接着剤が適当である。なお、粘着
剤層等の露出面にはセパレータを貼着するなどして取り
扱い性を良くしておくことが望ましい。接着処理にはロ
ボットによる自動接着方式なども採用してよい。If necessary, a pressure-sensitive adhesive layer or an adhesive layer may be added to the receiving sheet to be adhered to the adherend to increase its adhesion to the adherend. When firing a ceramic sheet, it is appropriate to use an adhesive that disappears during firing. In the case of a low-temperature receiving sheet, a heat-resistant adhesive or an adhesive that hardens by heat treatment is suitable. Note that it is desirable to attach a separator to the exposed surface of the adhesive layer or the like to improve handling properties. An automatic adhesion method using a robot may also be used for the adhesion process.
被着体としては、ガラスないし焼成セラミック、金属な
どからなる完成品、未焼成のセラミック成形体などの未
完成品であってもよい。未完成品の場合、その被着体の
焼成をセラミック系シートからなるパターンシートのそ
れと兼ねてもよい。The adherend may be a finished product made of glass, fired ceramic, metal, or the like, or an unfinished product such as an unfired ceramic molded body. In the case of an unfinished product, the firing of the adherend may also be performed for the pattern sheet made of a ceramic sheet.
本発明のパターン形成方法は、陶磁器、ガラス製品、は
うろう体などへの絵付けに好ましく適用できる。また、
ガラスないしセラミック、金属などからなる製品、半製
品ないし部品、搬送用パレットなどの種々の物品、特に
セラミック等の耐熱性基板、試作品などへの社名、ロッ
ト番号、品名、納入先、輸出国や、その他任意な識別記
号、着色パターン、色分はパターン、バーコードなどか
らなる識別ラベルの付与などにも好ましく適用できる。The pattern forming method of the present invention can be preferably applied to painting on ceramics, glass products, floating objects, etc. Also,
The company name, lot number, product name, delivery destination, export country, etc. for products made of glass, ceramic, metal, etc., semi-finished products or parts, transportation pallets, etc., especially heat-resistant substrates such as ceramic, prototype products, etc. , and other arbitrary identification symbols, colored patterns, color separations, patterns, bar codes, etc. can also be preferably applied to the provision of identification labels.
もちろん上記に限定するものでなく、その他種々の目的
を有するパターンの付与に適用することができる。Of course, the present invention is not limited to the above, and can be applied to provide patterns having various other purposes.
発明の効果
本発明の熱定着性インクは、熱溶融性無機粉末と耐熱性
顔料を特定の割合で配合したので、明瞭なパターンを形
成することができ、焼成後のパターンは耐擦過性、明瞭
性に優れている。Effects of the Invention The heat-fixable ink of the present invention contains a heat-fusible inorganic powder and a heat-resistant pigment in a specific ratio, so it can form a clear pattern, and the pattern after baking is scratch-resistant and clear. Excellent in sex.
また本発明のパターン形成方法は、曲面に対しても容易
に適用でき、任意なパターンを容易、かつ臨機に形成す
ることができて、大量生産品用ばかりでなく、多品種少
量生産品用の識別ラベルや絵柄などのパターンを容易に
得ることができる。Furthermore, the pattern forming method of the present invention can be easily applied to curved surfaces, and any pattern can be easily and flexibly formed. Patterns such as identification labels and designs can be easily obtained.
参考例ｌ
ＰｂＯ−８２０３・ＺｎＯ系ガラス粉末８５部（重量部
、以下同じ〉、白色顔料１５部、アクリル系ポリマ３０
部、トルエン５０部の混合物を、セパレータ上に設けた
粘着剤層の上に塗布し、乾燥させてガラス粉末含有シー
ト（セラミック系シート）を調製した。Reference Example 1 85 parts of PbO-8203/ZnO glass powder (parts by weight, same hereinafter), 15 parts of white pigment, 30 parts of acrylic polymer
A glass powder-containing sheet (ceramic sheet) was prepared by applying a mixture of 50 parts of toluene and 50 parts of toluene onto the adhesive layer provided on the separator and drying it.
参考例２
Ｓｉ○２系ガラス粉末１００部、白色顔料１０部、アク
リル系ポリマ３０部、トルエン５０部の混合物を、セパ
レータ上に設けた粘着剤層の上に塗布し、乾燥させてガ
ラス粉末含有シート（セラミック系シート）を調製した
。Reference Example 2 A mixture of 100 parts of Si○2-based glass powder, 10 parts of white pigment, 30 parts of acrylic polymer, and 50 parts of toluene was applied onto the adhesive layer provided on the separator and dried to form a mixture containing glass powder. A sheet (ceramic sheet) was prepared.
実施例１
ＣｕＣｒ２０４ （比重５．３ ｇ ／ ｃｄ ）
１００体積部と、ＰｂＯ−８２０３・ＺｎＯ系ガラス粉
末（比重６．２ｇ ／ ｃｄ ） ３００体積部の割合
で合計ｌ００部、ステアリン酸４０部及びエチレン・酢
酸ビニル共重合体ＩＯ部の混合物をロールミルでトルエ
ン中に均一に分散させて熱定着性インクの塗布液を調製
した。Example 1 CuCr204 (specific gravity 5.3 g/cd)
A mixture of 100 parts by volume, 300 parts by volume of PbO-8203/ZnO-based glass powder (specific gravity 6.2 g/cd), a total of 100 parts, 40 parts of stearic acid, and IO parts of ethylene/vinyl acetate copolymer was milled using a roll mill. A heat-fixable ink coating solution was prepared by uniformly dispersing it in toluene.
ついで、前記の塗布液を厚さ５μｍのポリエステルフィ
ルム上に乾燥後の厚さが約１０μｍとなるよう塗布し、
乾燥させてインクシートを作製した。Then, the coating solution was applied onto a polyester film having a thickness of 5 μm so that the thickness after drying was approximately 10 μm,
It was dried to produce an ink sheet.
次に、前記のインクシートを所定幅に裁断してリボンと
し、これをケースに収容してインクリボンカートリッジ
を作製し、これを用いて通常の熱転写プリンタを介し、
参考例１で得たガラス粉末含有シートにおけるガラス粉
末含有層の上に所定のバーコードパターンを印刷し、明
瞭なパターンを有するパターンシートを得た。Next, the ink sheet is cut into a predetermined width to form a ribbon, which is housed in a case to create an ink ribbon cartridge.
A predetermined barcode pattern was printed on the glass powder-containing layer of the glass powder-containing sheet obtained in Reference Example 1 to obtain a pattern sheet having a clear pattern.
前記のパターンシートをその粘着剤層を介し、表面を加
熱酸化したステンレス板に接着し、これを４５０℃で３
０分間焼成して、ステンレス板に固着した焼成パターン
を得た。なお焼成時にステアリン酸等の有機成分は焼失
した。The above pattern sheet was adhered via its adhesive layer to a stainless steel plate whose surface had been heated and oxidized, and this was heated at 450°C for 3
After firing for 0 minutes, a fired pattern fixed to the stainless steel plate was obtained. Note that organic components such as stearic acid were burned out during firing.
得られた焼成パターンについてＪＩＳ Ｈ８５０３に準
拠して耐磨耗試験を行ったが、パターンは削られること
なく、優れた定着性を示した。The obtained fired pattern was subjected to an abrasion resistance test according to JIS H8503, and the pattern showed excellent fixing properties without being scratched.
比較例１
ＣｕＣｒ２０４ ／ＰｂＯ−Ｂ２０３ ” ＺｎＯ系ガ
ラス粉末の配合体積比を１００１５０としたほかは実施
例１に準じ熱定着性インク、インクシート、パターンシ
ート、焼成パターンを形成し、その焼成パターンにつき
ＪＩＳ Ｈ８５０３に準拠して耐磨耗試験を行ったとこ
ろ、パターンは定着が不十分で部分的に削り取られ、識
別不能となった。Comparative Example 1 A heat-fixable ink, an ink sheet, a pattern sheet, and a firing pattern were formed in the same manner as in Example 1, except that the volume ratio of CuCr204 /PbO-B203'' ZnO-based glass powder was 100150, and the firing pattern was JIS-compliant. When an abrasion resistance test was conducted in accordance with H8503, the pattern was insufficiently fixed and was partially scraped off, making it unidentifiable.
比較例２
ＣｕＣｒ２０４／ＰｂＯ−Ｂ２Ｏ３・ＺｎＯ系ガラス粉
末の配合体積比をｔｏｏ／８００としたほかは実施例１
に準じ熱定着性インク、インクシート、パターンシート
を形成したが、濃度不足でパターンの明瞭性に劣ったも
のであった。Comparative Example 2 Example 1 except that the volume ratio of the CuCr204/PbO-B2O3/ZnO-based glass powder was too/800.
A heat-fixable ink, an ink sheet, and a pattern sheet were formed according to the method, but the density was insufficient and the clarity of the pattern was poor.
実施例２
ＰｂＯ−Ｂ２０３・ＺｎＯ系ガラス粉末に代えて亜鉛粉
末（比重７．１４ｇ／ｃｄ）を用いたほかは実施例１に
準じ熱定着性インク、インクシート、パターンシート、
焼成パターンを形成し、その焼成パターンについてＪＩ
Ｓ Ｈ８５０３に準拠して耐磨耗試験を行ったが、パタ
ーンは削られることなく、優れた定着性を示した。Example 2 Heat fixable ink, ink sheet, pattern sheet,
Form a firing pattern and perform JI on the firing pattern.
An abrasion resistance test was conducted in accordance with SH8503, and the pattern was not scratched and showed excellent fixing properties.
比較例３
ＣｕＣｒ２０＜／亜鉛粉末の配合体積比を１００１５０
としたほかは実施例２に準じ熱定着性インク、インクシ
ート、パターンシート、焼成パターンを形成し、その焼
成パターンにっきＪＩＳ Ｈ８５０３ニ準拠して耐磨耗
試験を行ったところ、パターンは定着が不十分で部分的
に削り取られ、識別不能となった。Comparative Example 3 The blending volume ratio of CuCr20</zinc powder is 100150
A heat-fixable ink, an ink sheet, a pattern sheet, and a fired pattern were formed in the same manner as in Example 2, except that the fired pattern was subjected to an abrasion resistance test in accordance with JIS H8503. Enough was partially scraped off and became unrecognizable.
実施例３
ＰｂＯ・Ｂ２Ｏ３・ＺｎＯ系ガラス粉末に代えて５ｉｎ
２系ガラス粉末（比重２．２ｇ／ｃｉ）を、参考例１の
シートに代えて参考例２のシートを用い、焼成条件を８
００℃、３０分間としたほかは実施例１に準じ熱定着性
インク、インクシート、パターンシート、焼成パターン
を形成し、その焼成パターンについてＪＩＳ Ｈ８５０
３に準拠して耐磨耗試験を行ったが、パターンは削られ
ることなく、優れた定着性を示した。Example 3 5 inch instead of PbO・B2O3・ZnO glass powder
2 series glass powder (specific gravity 2.2 g/ci) was replaced with the sheet of Reference Example 1, and the sheet of Reference Example 2 was used, and the firing conditions were set to 8.
A heat fixable ink, an ink sheet, a pattern sheet, and a firing pattern were formed according to Example 1 except that the temperature was 00°C for 30 minutes, and the firing pattern was prepared according to JIS H850.
An abrasion resistance test was conducted in accordance with No. 3, and the pattern was not scratched and showed excellent fixing properties.
比較例４
Ｃｕ Ｃｒ ２０４ ／ Ｓ ｉ Ｏ２系ガラス粉末の
配合体積比を１００１５０としたほかは実施例３に準じ
、熱定着性インク、インクシート、パターンシート、焼
成パターンを形成し、その焼成パターンにつきＪＩＳ
Ｈ８５０３に準拠して耐磨耗試験を行ったところ、パタ
ーンは定着が不十分で部分的に削り取られ、識別不能と
なった。Comparative Example 4 A heat-fixable ink, an ink sheet, a pattern sheet, and a firing pattern were formed according to Example 3, except that the volume ratio of the Cu Cr 204 / S i O 2 -based glass powder was 100150, and the firing pattern was JIS
When an abrasion resistance test was conducted in accordance with H8503, the pattern was insufficiently fixed and was partially scraped off, making it unidentifiable.
Claims (1)
インダからなり、前記無機粉末を体積部に基づいて耐熱
性顔料１００部あたり１００〜５００部含有することを
特徴とする熱定着性インク。 ２、請求項１に記載の熱定着性インクを支持基材に保持
させてなることを特徴とするインクシート。 ３、請求項２に記載のインクシートをケースに収容して
なることを特徴とするインクリボンカートリッジ。 ４、受容シートにおける熱溶融性のインク受容層の上に
、請求項１に記載の熱定着性インクからなるパターンを
有することを特徴とするパターンシート。 ５、請求項２に記載のインクシートを用いて熱転写プリ
ンタを介し、インク受容層の上にパターンを形成定着さ
せることを特徴とする請求項４に記載のパターンシート
の製造方法。 ６、転写紙の上に請求項１に記載の熱定着性インクから
なるパターンを有することを特徴とするパターンシート
。 ７、請求項４に記載のパターンシートを被着体に接着し
、そのパターンシートを加熱処理してパターンとインク
受容層を融和させることを特徴とするパターン形成方法
。 ８、被着体に接着した受容シートのインク受容層の上に
、請求項１に記載の熱定着性インクからなるパターンを
形成して加熱処理し、パターンとインク受容層を融和さ
せることを特徴とするパターン形成方法。[Claims] 1. Consists of a heat-fusible inorganic powder, a heat-resistant pigment, and a heat-fusible binder, and contains 100 to 500 parts by volume of the inorganic powder per 100 parts of the heat-resistant pigment. A heat-fixable ink featuring: 2. An ink sheet comprising the heat fixable ink according to claim 1 held on a supporting base material. 3. An ink ribbon cartridge comprising the ink sheet according to claim 2 housed in a case. 4. A patterned sheet having a pattern made of the heat-fixable ink according to claim 1 on a heat-fusible ink-receiving layer of the receiving sheet. 5. The method for manufacturing a patterned sheet according to claim 4, wherein a pattern is formed and fixed on the ink receiving layer using the ink sheet according to claim 2 using a thermal transfer printer. 6. A pattern sheet comprising a pattern made of the heat fixable ink according to claim 1 on a transfer paper. 7. A pattern forming method, which comprises adhering the pattern sheet according to claim 4 to an adherend, and heat-treating the pattern sheet to blend the pattern and the ink-receiving layer. 8. A pattern made of the heat-fixable ink according to claim 1 is formed on the ink-receiving layer of the receptor sheet adhered to the adherend and heat-treated to blend the pattern and the ink-receiving layer. A pattern forming method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1220689A JPH0384073A (en) | 1989-08-28 | 1989-08-28 | Thermally anchoring ink and patterned sheet and formation of pattern |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1220689A JPH0384073A (en) | 1989-08-28 | 1989-08-28 | Thermally anchoring ink and patterned sheet and formation of pattern |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0384073A true JPH0384073A (en) | 1991-04-09 |
Family
ID=16754943
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1220689A Pending JPH0384073A (en) | 1989-08-28 | 1989-08-28 | Thermally anchoring ink and patterned sheet and formation of pattern |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0384073A (en) |
-
1989
- 1989-08-28 JP JP1220689A patent/JPH0384073A/en active Pending
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