JPH0381377A - Thermally fixable ink, pattern sheet, and method for forming baking pattern - Google Patents
Thermally fixable ink, pattern sheet, and method for forming baking patternInfo
- Publication number
- JPH0381377A JPH0381377A JP1217885A JP21788589A JPH0381377A JP H0381377 A JPH0381377 A JP H0381377A JP 1217885 A JP1217885 A JP 1217885A JP 21788589 A JP21788589 A JP 21788589A JP H0381377 A JPH0381377 A JP H0381377A
- Authority
- JP
- Japan
- Prior art keywords
- heat
- ink
- pattern
- sheet
- adherend
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- 238000002844 melting Methods 0.000 claims abstract description 25
- 239000000843 powder Substances 0.000 claims abstract description 23
- 230000008018 melting Effects 0.000 claims abstract description 15
- 239000000049 pigment Substances 0.000 claims abstract description 13
- 239000011230 binding agent Substances 0.000 claims abstract description 8
- 229910052751 metal Inorganic materials 0.000 claims description 20
- 239000002184 metal Substances 0.000 claims description 20
- 238000012546 transfer Methods 0.000 claims description 14
- 238000010304 firing Methods 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 6
- -1 2(Co Inorganic materials 0.000 abstract description 10
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 abstract description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052749 magnesium Inorganic materials 0.000 abstract description 3
- 239000012188 paraffin wax Substances 0.000 abstract description 3
- 229910052718 tin Inorganic materials 0.000 abstract description 3
- 229910052725 zinc Inorganic materials 0.000 abstract description 3
- 235000021314 Palmitic acid Nutrition 0.000 abstract description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 abstract description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 abstract description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 abstract 2
- 229910002477 CuCr2O4 Inorganic materials 0.000 abstract 1
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- 238000013329 compounding Methods 0.000 abstract 1
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- FULFYAFFAGNFJM-UHFFFAOYSA-N oxocopper;oxo(oxochromiooxy)chromium Chemical compound [Cu]=O.O=[Cr]O[Cr]=O FULFYAFFAGNFJM-UHFFFAOYSA-N 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 63
- 239000010410 layer Substances 0.000 description 18
- 239000000919 ceramic Substances 0.000 description 15
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- 238000010438 heat treatment Methods 0.000 description 12
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- 239000000047 product Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 235000021355 Stearic acid Nutrition 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 239000012790 adhesive layer Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 4
- 239000008117 stearic acid Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- XIRNKXNNONJFQO-UHFFFAOYSA-N ethyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC XIRNKXNNONJFQO-UHFFFAOYSA-N 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 229920001477 hydrophilic polymer Polymers 0.000 description 2
- 229920001600 hydrophobic polymer Polymers 0.000 description 2
- 150000002484 inorganic compounds Chemical class 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 2
- 235000019809 paraffin wax Nutrition 0.000 description 2
- 235000019271 petrolatum Nutrition 0.000 description 2
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- 238000003860 storage Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- MHXBHWLGRWOABW-UHFFFAOYSA-N tetradecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCC MHXBHWLGRWOABW-UHFFFAOYSA-N 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 102000011632 Caseins Human genes 0.000 description 1
- 108010076119 Caseins Proteins 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
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- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
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- 238000011156 evaluation Methods 0.000 description 1
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- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
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Landscapes
- Impression-Transfer Materials And Handling Thereof (AREA)
- Duplication Or Marking (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、低温ないし短時間定着性、耐熱性、耐擦過性
に優れる熱定着性インクとそのインクシート、及び当該
インクを用いたパターンシートとその製造方法、並びに
焼成パターン形成方法に関する。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a heat-fixable ink that has excellent low-temperature or short-time fixing properties, heat resistance, and scratch resistance, an ink sheet thereof, and a pattern sheet using the ink and a pattern sheet thereof. The present invention relates to a manufacturing method and a firing pattern forming method.
発明の背景
記録装置の小型化や維持管理の容易性、低騒音性などの
利点に着目されて、熱転写記録方式がワ−ドブロセッサ
等のＯＡ分野や、バーコードプリンタ等のＦＡ分野ない
しＰＯＳシステム等へと普及するのに伴い、それに用い
る熱定着性インクに新たな性能が要求されている。高温
保存のための耐熱性の要求、長期保存のための耐擦過性
の要求などはその例である。耐熱性に優れる熱定着性イ
ンクは、例えばバーコード等を付与した識別ラベルの場
合、ガラスないし焼成セラミックや金属などからなる熱
処理を受ける製品や半製品ないし部品等への適用が可能
となり、多品種少量生産体制下でのそれら製品等の管理
を容易にする。BACKGROUND OF THE INVENTION Thermal transfer recording methods have been widely used in the OA field such as word processors, FA fields such as barcode printers, POS systems, etc. due to the advantages of recording devices such as miniaturization, ease of maintenance, and low noise. As the technology becomes more widespread, new performance is required of the heat-fixable inks used therein. Examples include the requirement for heat resistance for high-temperature storage and the requirement for scratch resistance for long-term storage. Heat-fixable ink with excellent heat resistance can be applied to products, semi-finished products, and parts made of glass, fired ceramics, and metals that undergo heat treatment, such as for identification labels with barcodes, etc., and can be applied to a wide variety of products. To facilitate the management of these products under a small-volume production system.
従来の技術及び課題
従来、熱定着性インクとしては、カーボン等の顔料と熱
溶融性バインダとの混合物からなるものが知られていた
。しかしながら、ががる熱定着性インクを用いてパター
ンを付与した被着体を高温（約３００℃以上）で処理す
ると、パターンが焼失したり、変質したりして実用に供
しつる焼成パターンが得られない問題点があった。BACKGROUND ART Conventionally, heat-fixable inks made of a mixture of a pigment such as carbon and a heat-fusible binder have been known as heat-fixable inks. However, if an adherend to which a pattern has been applied using a heat-fixing ink is treated at high temperatures (approximately 300°C or higher), the pattern may be burned out or altered, making it impossible to use it in practical use with a vine-fired pattern. There was a problem that could not be solved.
ガラス粉末を併用して焼成によりパターンが定着するよ
うにした熱定着性インクも知られているが、定着処理に
長時間を要する問題点、あるいは被着体に付与したパタ
ーンが外部衝撃等で簡単に損傷したり、その周辺を汚染
するなど耐擦過性に乏しい問題点があった。Heat-fixable inks that use glass powder in combination to fix patterns by firing are also known, but there are problems in that the fixing process takes a long time, or the pattern applied to the adherend is easily damaged by external impact, etc. There were problems with poor abrasion resistance, such as damage to the surface and contamination of the surrounding area.
課題を解決するための手段
本発明は、低融点金属粉末と耐熱性顔料を用いて上記の
課題を克服したものである。Means for Solving the Problems The present invention overcomes the above problems by using a low melting point metal powder and a heat resistant pigment.
すなわち本発明は、融点６００℃以下の低融点金属粉末
と、耐熱性顔料と、熱溶融性バインダからなることを特
徴とする熱定着性インク、並びにかかる熱定着性インク
を支持基材に保持させてなることを特徴とするインクシ
ート、及びそのインクシートをケースに収容してなるこ
とを特徴とするインクリボンカートリッジの提供を目的
とする。That is, the present invention provides a heat fixable ink characterized by comprising a low melting point metal powder with a melting point of 600°C or less, a heat resistant pigment, and a heat melt binder, as well as a heat fixable ink that is made to be held on a supporting base material. An object of the present invention is to provide an ink sheet characterized by comprising: and an ink ribbon cartridge characterized by containing the ink sheet in a case.
また本発明は、当該熱定着性インクからなるパターンを
、受容シートにおける熱溶融性のインク受容層の上に設
けてなることを特徴とするパターンシート、及び前記し
たインクシートを用いて熱転写プリンタを介しインク受
容層の上にパターンを形成定着させることを特徴とする
当該パターンシートの製造方法の提供も目的とする。The present invention also provides a pattern sheet in which a pattern made of the heat-fixable ink is provided on a heat-melting ink receiving layer of a receiving sheet, and a thermal transfer printer using the above-described ink sheet. Another object of the present invention is to provide a method for manufacturing the pattern sheet, which comprises forming and fixing a pattern on an ink-receiving layer through an intervening ink-receiving layer.
さらに本発明は、受容シートを用いてなるパターンシー
トを被着体に接着し、そのパターンシートを加熱処理し
て被着体に焼成パターンを設けるこを特徴とする焼成パ
ターン形成方法、及び被着体に接着した受容シートのイ
ンク受容層の上に、当該熱定着性インクからなるパター
ンを設けて加熱処理し、被着体に焼成パターンを設ける
こを特徴とする焼成パターン形成方法の提供も目的とす
る。Furthermore, the present invention provides a method for forming a fired pattern, which comprises adhering a pattern sheet using a receptor sheet to an adherend, and heat-treating the pattern sheet to provide a fired pattern on the adherend. Another object of the present invention is to provide a method for forming a baked pattern, which comprises forming a pattern made of the heat-fixable ink on the ink-receiving layer of a receiving sheet adhered to an adherend, and heat-treating the ink to form a baked pattern on the adherend. shall be.
作用
低融点金属粉末を併用することにより、耐熱性顔料に基
づく優れた耐熱性、耐擦過性を損なうことなく、低温定
着性、ないし短時間定着性に優れる熱定着性インクとす
ることができる。また受容シートのインク受容層の上に
熱定着性インクのパターンを設けてこれを加熱処理して
も、そのパターンが良好な状態で温存する焼成パターン
を得ることができる。その場合、受容シートがセラミッ
ク系シートからなる場合には、焼成体からなるパターン
付シートとすることができる。By using a low melting point metal powder in combination, it is possible to obtain a heat-fixable ink that has excellent low-temperature fixability or short-time fixability without impairing the excellent heat resistance and scratch resistance based on the heat-resistant pigment. Furthermore, even if a pattern of heat-fixable ink is provided on the ink-receiving layer of the receiving sheet and then heat-treated, a fired pattern in which the pattern is preserved in good condition can be obtained. In that case, if the receptor sheet is made of a ceramic sheet, it can be a patterned sheet made of a fired body.
発明の構成要素の例示
本発明の熱定着性インクは、低融点金属粉末と耐熱性顔
料と熱溶融性バインダを成分とする。Examples of Constituent Elements of the Invention The heat-fixing ink of the present invention contains a low-melting point metal powder, a heat-resistant pigment, and a heat-melting binder.
低融点金属粉末としては、融点が６００℃以下、就中１
００〜６００℃のものが用いられる。一般には亜鉛、ス
ズ、鉛、カドミウム、ビスマスなどからなる金属の単体
物や、かかる金属を２種以上含む合金などが用いられる
。粉末の形状、粒径について特に限定はないが、インク
シートの形成性等の点からは平均粒径１０ｍ以下、就中
１〜５μｍのものが好ましい。As the low melting point metal powder, the melting point is 600℃ or less, especially 1
00 to 600°C is used. Generally, single metals such as zinc, tin, lead, cadmium, bismuth, etc., and alloys containing two or more of such metals are used. There are no particular limitations on the shape and particle size of the powder, but from the viewpoint of ink sheet formability, it is preferable to have an average particle size of 10 m or less, particularly 1 to 5 μm.
耐熱性顔料としては、コバルト、クロム、鉄、銅、亜鉛
、マグネシウム、スズ、マンガン、アルミニウム、ニッ
ケル、チタンなどの金属の少なくとも１種を含む無機化
合物や、耐熱性カーボンなどがあげられる。無機化合物
の具体例としては、ＣｕＣｒ２Ｏ４，２（Ｃｏ、Ｍｇ）
Ｏ−８ｎ０２ 、Ｃｏｏ ・Ａ１２０３ 、Ｆｅ２０ｗ
１ 、Ｃｏ（ＡｉＣｒ）２０４ 、ＭｎＰＯ９、Ｃｏ０
−ＺｎＯなどがあげられる。Examples of heat-resistant pigments include inorganic compounds containing at least one metal such as cobalt, chromium, iron, copper, zinc, magnesium, tin, manganese, aluminum, nickel, and titanium, and heat-resistant carbon. Specific examples of inorganic compounds include CuCr2O4,2 (Co, Mg)
O-8n02, Coo・A1203, Fe20w
1, Co(AiCr)204, MnPO9, Co0
-ZnO and the like.
熱溶融性バインダとしてはワックスが用いられる。その
種類につき特に限定はない。好ましく用いうるワックス
の例としては、パラフィンワックス、マイクロワックス
、ポリエチレンワックスの如きパラフィン系ワックス類
、蜜ろう、カルナウバワックス、木ろうの如き天然ワッ
クス類、ステアリルアルコール、パルミチルアルコール
の如き高級アルコール系ワックス類、ステアロアミド、
オレオアミド、パルミチロアミドの如き高級アミド系ワ
ックス類、ヘキストワックス、ブチルステアレート、エ
チルパルミテート、ミリスチルステアレートの如きエス
テル系ワックス類、ステアリン酸、パルミチン酸、ベヘ
ニン酸、ミリスチン酸、カプリン酸、ラウリン酸、１．
２０−エイコサンニ酸の如き高級脂肪酸からなる酸ワツ
クス類、ソルビタン誘導体類などがあげられる。Wax is used as the heat-melting binder. There are no particular limitations on the type. Examples of waxes that can be preferably used include paraffin waxes such as paraffin wax, micro wax, and polyethylene wax, natural waxes such as beeswax, carnauba wax, and pyril wax, and higher alcohol waxes such as stearyl alcohol and palmityl alcohol. waxes, stearamide,
Higher amide waxes such as oleamide and palmityroamide, ester waxes such as Hoechst wax, butyl stearate, ethyl palmitate, myristyl stearate, stearic acid, palmitic acid, behenic acid, myristic acid, capric acid, lauric acid, 1.
Examples include acid waxes made of higher fatty acids such as 20-eicosanniic acid, sorbitan derivatives, and the like.
熱溶融性バインダとしてポリマを併用してもよい。親水
性ポリマ、疎水性ポリマのいずれも用いることができ、
環球法に基づく軟化点が４０〜２００℃のポリマが好ま
しく用いられる。親水性ポリマの例としては、ゼラチン
、その誘導体、セルロース誘導体、カゼイン等の蛋白質
やデンプン等の多糖類の如き天然物ないしその誘導体、
ポリビニルアルコール、ポリビニルピロリドン、アクリ
ルアミド重合体の如き水溶性ポリマ、ビニル系ラテック
ス、ウレタン系ラテックスの如きポリマーラテックスな
どがあげられる。好ましく用いつる疎水性ポリマの例と
しては、ポリビニルブチラール、ポリビニルホルマール
、ポリエチレン、ポリプロピレン、ポリアミド、エチル
セルロース、セルロースアセテート、ポリスチレン、ポ
リ酢酸ビニル、ポリ塩化ビニル、ポリ塩化ビニリデン、
塩化ビニル・酢酸ビニルコポリマ、エチレン・酢酸ビニ
ルコポリマ、塩化ビニル・酢酸ビニル・マレイン酸ター
ポリマ、エステルガムの如きロジン誘導体などがあげら
れる。その他種々のポリマも用いうる（米国特許第３０
６２６７４号明細書、同第３１４２５８６号明細書、同
第３１４３３８８号明細書、同第３２２０８４４号明細
書、同第３２８７２８９号明細書、同第３４１１９１１
号明細書など〉。A polymer may also be used as a thermofusible binder. Both hydrophilic and hydrophobic polymers can be used,
A polymer having a softening point of 40 to 200°C based on the ring and ball method is preferably used. Examples of hydrophilic polymers include natural products such as gelatin, derivatives thereof, cellulose derivatives, proteins such as casein, polysaccharides such as starch, and derivatives thereof;
Examples include water-soluble polymers such as polyvinyl alcohol, polyvinylpyrrolidone, and acrylamide polymers, and polymer latexes such as vinyl latex and urethane latex. Examples of preferably used hydrophobic polymers include polyvinyl butyral, polyvinyl formal, polyethylene, polypropylene, polyamide, ethyl cellulose, cellulose acetate, polystyrene, polyvinyl acetate, polyvinyl chloride, polyvinylidene chloride,
Examples include vinyl chloride/vinyl acetate copolymers, ethylene/vinyl acetate copolymers, vinyl chloride/vinyl acetate/maleic acid terpolymers, and rosin derivatives such as ester gum. Various other polymers may also be used (U.S. Pat. No. 30
62674 specification, 3142586 specification, 3143388 specification, 3220844 specification, 3287289 specification, 3411911
number specification, etc.>
熱定着性インクにおける低融点金属粉末、耐熱性顔料、
ワックス、ポリマの組成比は適宜に決定してよい。一般
には耐熱性顔料１００重量部あたり低融点金属粉末５０
〜５００重量部、好ましくは２００〜４００奮量部、ワ
ックス１０〜５００重量部、好ましくは３０〜４００重
量部、ポリマＯ〜５００重量部、好ましくは１〜４００
重量部、就中５〜３００重量部が用いられる。熱定着性
インクはこれらを適宜に混合して調製される。Low melting point metal powder, heat resistant pigment, in heat fixable ink,
The composition ratio of wax and polymer may be determined as appropriate. Generally, 50 parts of low melting point metal powder per 100 parts by weight of heat-resistant pigment.
-500 parts by weight, preferably 200-400 parts by weight, wax 10-500 parts by weight, preferably 30-400 parts by weight, polymer O -500 parts by weight, preferably 1-400 parts by weight
Parts by weight, especially 5 to 300 parts by weight, are used. The heat fixable ink is prepared by appropriately mixing these.
なお、熱定着性インクには柔軟剤等の適宜な添加剤を加
えてもよい。柔軟剤としては通常、ひまし油、アマニ油
、オリーブ油の如き植物油、鯨油の如き動物油、その他
鉱油などが用いられる。Note that appropriate additives such as a softener may be added to the heat fixable ink. As softeners, vegetable oils such as castor oil, linseed oil, and olive oil, animal oils such as whale oil, and other mineral oils are usually used.
本発明のインクシートは、熱定着性インクを支持基材に
塗布するなり、含浸させるなどして保持させたものであ
る。支持基材としては例えば、普通紙、コンデンサー紙
、ラミネート紙、コート紙の如き紙類、ポリエチレン、
ポリプロピレン、ポリエステル、ポリスチレン、ポリイ
ミドの如き樹脂からなるフィルムないし紙・フィルム複
合体、アルミニウム箔の如き金属シート、ポリアミド、
ポリイミド、ポリエステル等の繊維からなる布などがあ
げられる。The ink sheet of the present invention is obtained by coating or impregnating a support base material with heat-fixable ink. Examples of supporting substrates include papers such as plain paper, condenser paper, laminated paper, coated paper, polyethylene,
Films or paper/film composites made of resins such as polypropylene, polyester, polystyrene, and polyimide, metal sheets such as aluminum foil, polyamides,
Examples include cloth made of fibers such as polyimide and polyester.
熱転写プリンタに適用するためのインクシートにあって
は、耐熱性、寸法安定性、表面平滑性に優れる支持基材
を用いることが望ましい。サーマルプリンターヘッド等
の熱源の加熱温度で軟質化ないし可塑化せず、支持体と
しての強靭性を保持する耐熱性ないし寸法安定性を有し
、熱定着性インクの転写を阻害しない表面平滑性を有す
る支持基材が好ましく用いうる。表面平滑度としては、
転写率や画像の再現制度の点より、ＪＩＳ Ｐ ８１
１９に基づくベック試験機による平滑度が１００秒以上
、就中３００秒以上のものが好ましい。支持基材の厚さ
は通常、熱伝導性の点より約６０μｍ以下、就中２〜２
Ｏｎが適当である。For ink sheets to be applied to thermal transfer printers, it is desirable to use a support base material that has excellent heat resistance, dimensional stability, and surface smoothness. It does not soften or plasticize at the heating temperature of a heat source such as a thermal printer head, has heat resistance or dimensional stability that maintains its toughness as a support, and has a surface smoothness that does not inhibit the transfer of heat-fixable ink. A supporting base material having the following properties can be preferably used. As for surface smoothness,
In terms of transfer rate and image reproduction system, JIS P 81
It is preferable that the smoothness is 100 seconds or more, especially 300 seconds or more as measured by a Beck tester based on 19. The thickness of the supporting base material is usually about 60 μm or less, especially 2 to 2 μm, from the viewpoint of thermal conductivity.
On is appropriate.
熱定着性インクを支持基材に保持させる方式について特
に限定はなく、いずれの公知方式も適用することができ
る。その例としては、熱定着性インクを適宜な溶媒に溶
解ないし分散させた液を支持基材に塗布する方式などが
あげられる。その際、溶媒としては例えばトルエン、メ
チルエチルケトン、メチルイソブチルケトン、酢酸エチ
ル、酢酸ブチル、メタノール、エタノール、イソプロパ
ツール、ソルベントナフサ、ヘキサン、ヘプタンなど適
宜なものを用いてよい。塗布は、リバースロールコータ
、押出コータ、グラビアコータ、ワイヤバーなと適宜な
塗布機を用いて行ってよい。熱定着性インクを塗布層と
して支持基材に設ける場合、その厚さは１５ｎ以下、就
中２〜ＩＯｐｍが適当である。なお、熱定着性インクの
塗布層を設けない支持基材面は任意に構成してよく、適
宜に利用してよい。There is no particular limitation on the method of holding the heat fixable ink on the support substrate, and any known method can be applied. An example of this method is a method in which a liquid in which heat-fixable ink is dissolved or dispersed in an appropriate solvent is applied to a supporting substrate. In this case, appropriate solvents such as toluene, methyl ethyl ketone, methyl isobutyl ketone, ethyl acetate, butyl acetate, methanol, ethanol, isopropanol, solvent naphtha, hexane, and heptane may be used. Coating may be performed using a suitable coating machine such as a reverse roll coater, extrusion coater, gravure coater, or wire bar. When the heat-fixable ink is provided as a coating layer on the support substrate, the thickness thereof is suitably 15 nm or less, particularly 2 to IOpm. Note that the supporting base material surface on which the heat-fixable ink coating layer is not provided may be configured as desired and may be used as appropriate.
インクシートはそのまま実用に供してもよい。The ink sheet may be put to practical use as it is.
また、適当な幅に裁断して熱転写リボン、押印転写リボ
ン、押印印字リボン等のリボン形態とし、これをケース
に収容してインクリボンカートリッジにするなどして、
各種のプリンタなどに適用できる形態として実用に供し
てもよい。In addition, we cut the appropriate width into ribbons such as thermal transfer ribbons, stamp transfer ribbons, stamp printing ribbons, etc., and store them in cases to make ink ribbon cartridges.
It may be put to practical use in a form that can be applied to various printers.
本発明の熱定着性インクないしそのインクシートは紙、
プラスチック、金属、セラミック等の種々の材質からな
る被着体に適用することができる。The heat fixable ink or ink sheet of the present invention can be applied to paper,
It can be applied to adherends made of various materials such as plastic, metal, and ceramic.
熱転写プリンタ等の加熱媒体を介し被着体に印字ないし
パターンを付与した場合にはそのままインクを定着させ
ることができる。転写紙に形成したパターンを被着体に
転写したときなど、加熱媒体を介すことなくパターンを
付与した場合には、熱ロールで押圧するなど適宜な加熱
処理を施すことにより、インクを定着させることができ
る。インクを定着させるための加熱処理は被着体に対し
て行ってもよい。なおインクを定着させるための加熱処
理は、熱定着性インクにおける低融点金属粉末の種類等
に応じて適宜な温度で行ってよい。好ましくは低融点金
属粉末の融点よりも１０〜１００℃高い加熱温度である
。When printing or patterns are applied to an adherend using a heating medium such as a thermal transfer printer, the ink can be fixed as is. When a pattern is applied without using a heating medium, such as when a pattern formed on transfer paper is transferred to an adherend, the ink is fixed by applying an appropriate heat treatment such as pressing with a heated roll. be able to. Heat treatment for fixing the ink may be performed on the adherend. Note that the heat treatment for fixing the ink may be performed at an appropriate temperature depending on the type of low melting point metal powder in the heat fixable ink. Preferably, the heating temperature is 10 to 100°C higher than the melting point of the low melting point metal powder.
本発明のパターンシートは、受容シートのインク受容層
の上に熱定着性インクからなるパターンを設けたもので
ある。The pattern sheet of the present invention has a pattern made of heat-fixable ink provided on the ink-receiving layer of the receiving sheet.
受容シートとしては、無機粉末と樹脂の混合物からなり
インクの定着ベースとなる熱溶融性のインク受容層を耐
熱性フィルムからなる基材に設けたものや、ガラス粉末
ないしセラミック粉末を含有する熱溶融性のセラミック
系シートなどがあげられる。なお識別ラベルとして利用
する場合などのように、熱定着性インクとインク受容層
の加熱処理体との間に良好なコントラストや色調の変化
が望まれるときには、インク受容層に顔料や充填剤を添
加して適当な色調に着色化することが好ましい。The receiving sheet may be one in which a heat-melting ink-receiving layer made of a mixture of inorganic powder and resin and serving as an ink fixing base is provided on a base material made of a heat-resistant film, or a heat-melting ink-receiving layer containing a glass powder or ceramic powder. Examples include ceramic sheets. In addition, when a good contrast or change in color tone is desired between the heat-fixable ink and the heat-treated ink-receiving layer, such as when used as an identification label, pigments or fillers may be added to the ink-receiving layer. It is preferable to color it to an appropriate color tone.
受容シートのインク受容層に設けるパターンは、バーコ
ードパターンや文字、陶磁器用等の絵柄パターンなど任
意である。また、パターンの形成方法も任意である。熱
定着性インクそのもの、ないしそのインク液の場合、手
書き方式、パターン形成マスクを介しての塗布方式など
適宜な方式でパターンを形成することができる。インク
シートの場合には、上記したようにＸＹプロッタ、ワイ
ヤートッド型や熱転写型ないしインパクト型などの適宜
なプリンタを用いてパターンを形成することができる。The pattern provided on the ink receiving layer of the receiving sheet may be arbitrary, such as a bar code pattern, characters, or a picture pattern for ceramics. Furthermore, the method of forming the pattern is also arbitrary. In the case of the heat-fixable ink itself or its ink liquid, a pattern can be formed by an appropriate method such as a handwriting method or a coating method using a pattern-forming mask. In the case of an ink sheet, a pattern can be formed using an appropriate printer such as an XY plotter, wire tod type, thermal transfer type or impact type as described above.
プリンタによる場合には、印字パターン、バーコードパ
ターン、転写パターン、絵付はパターンなどの適宜なパ
ターンを能率的に、かつ精度よく形成することができる
。When using a printer, appropriate patterns such as printed patterns, barcode patterns, transfer patterns, and decorative patterns can be efficiently and accurately formed.
受容シートを用いたパターンシートの好ましい製造方法
は、熱転写式のインクシートとプリンタを介してパター
ンを形成しつつ定着させる方法である。この方法は、パ
ターンシートの製造効率に優れるほか、形成されたパタ
ーンシートを被着体に接着する場合等における取り扱い
性に優れるなどの利点を有する。また、パターンシート
を加熱処理してなるパターン付シートにおける焼成パタ
ーンが耐擦過性に優れる利点もある。A preferred method for manufacturing a pattern sheet using a receiving sheet is a method in which a pattern is formed and fixed using a thermal transfer ink sheet and a printer. This method has advantages such as excellent production efficiency of the pattern sheet and excellent handling properties when adhering the formed pattern sheet to an adherend. Another advantage is that the fired pattern in a patterned sheet obtained by heat treating a patterned sheet has excellent scratch resistance.
被着体にパターンを形成する方法としては、受容シート
を用いてなるパターンシートを被着体に接着して加熱処
理する方法、あるいは被着体に受容シートを接着したの
ち、そのインク受容層に熱定着性インクのパターンを付
与して加熱処理する方法などがあげられる。前者の方法
は、予めパターンシートを形成してこれを被着体に接着
するもので、適宜なプリンタ等を用いて形成したパター
ンシートを介し、精微なパターンを被着体に容易に付与
できる利点がある。後者の方法は、先ず受容シートを被
着体に接着したのち、そのインク受容層にパターンを形
成してパターンシートとするもので、被着体が基板やシ
ート状のものなどからなる場合に好ましく適用される。As a method of forming a pattern on an adherend, there is a method of adhering a pattern sheet made of a receptor sheet to an adherend and heat treatment, or a method of adhering a receptor sheet to an adherend and then applying a pattern to the ink-receiving layer. Examples include a method in which a pattern of heat-fixable ink is applied and then heat-treated. The former method involves forming a pattern sheet in advance and adhering it to the adherend, and has the advantage that a fine pattern can be easily applied to the adherend through the pattern sheet formed using an appropriate printer, etc. There is. In the latter method, a receiving sheet is first adhered to an adherend, and then a pattern is formed on the ink-receiving layer to form a pattern sheet, and is preferred when the adherend consists of a substrate or sheet-like object. Applicable.
なお、離型処理紙ないしフィルム、金属箔などの適宜な
転写紙に設けたパターンを受容シートに転写してパター
ンシートとする方式は、いずれの形成方法の場合にも適
用することができる。Note that any method of forming a pattern sheet by transferring a pattern on a suitable transfer paper such as release-treated paper, film, or metal foil to a receiving sheet can be applied.
被着体に接着するパターンシートの加熱処理は、インク
受容層の種類などに応して適宜な加熱温度で行ってよい
。加熱処理により、熱定着性インクとインク受容層が融
和し、焼成パターンからなるパターン付シートが形成さ
れる。その際セラミック系シートの場合のように、加熱
処理で溶融したセラミック粉末等の接着剤的機能により
、パターンとの一体化物として被着体に固着させること
も可能である。The pattern sheet to be adhered to the adherend may be heated at an appropriate heating temperature depending on the type of ink-receiving layer. The heat treatment causes the heat-fixable ink and the ink-receiving layer to fuse together, forming a patterned sheet consisting of a fired pattern. In this case, as in the case of ceramic sheets, it is also possible to use the adhesive function of ceramic powder or the like melted by heat treatment to fix it to the adherend as an integral part with the pattern.
被着体に接着される受容シートには、必要に応じ粘着剤
層や接着層を付設するなどして被着体に対する接着力が
高められる。受容シートを焼成処理する場合には焼成時
に消失する粘着剤の使用が適当である。なお、粘着剤層
等の露出面にはセパレータを貼着するなどして取り扱い
性を良くしておくことが望ましい。If necessary, a pressure-sensitive adhesive layer or an adhesive layer may be added to the receiving sheet to be adhered to the adherend to increase its adhesion to the adherend. When the receiving sheet is subjected to baking treatment, it is appropriate to use an adhesive that disappears during baking. Note that it is desirable to attach a separator to the exposed surface of the adhesive layer or the like to improve handling properties.
被着体としては、ガラスないし焼成セラミック、金属な
どからなる完成品、未焼成のセラミック成形体などの未
完成品であってもよい。未完成品の場合、その被着体の
焼成をセラミック系シートからなるパターンシートのそ
れと兼ねてもよい。The adherend may be a finished product made of glass, fired ceramic, metal, or the like, or an unfinished product such as an unfired ceramic molded body. In the case of an unfinished product, the firing of the adherend may also be performed for the pattern sheet made of a ceramic sheet.
本発明の焼成パターン形成方法は、陶磁器、ガラス製品
、はうろう体などへの絵付けに好ましく適用できる。ま
た、ガラスないしセラミック、金属などからなる製品、
半製品ないし部品、搬送用パレットなどの種々の物品、
特にセラミック箋の耐熱性基板、試作品などへの社名、
ロフト番号、品名、納入先、輸出国や、その他任意な識
別記号、着色パターン、色分はパターン、バーコードな
どからなる識別ラベルの付与などにも好ましく適用でき
る。もちろん上記に限定するものでなく、その他種々の
目的を有するパターンの付与に適用することができる。The firing pattern forming method of the present invention can be preferably applied to painting on ceramics, glass products, floating bodies, and the like. In addition, products made of glass, ceramic, metal, etc.
Various items such as semi-finished products or parts, transportation pallets,
In particular, the company name for heat-resistant substrates for ceramic paper, prototypes, etc.
Loft number, product name, destination of delivery, country of export, and other arbitrary identification symbols, coloring patterns, and colors can also be preferably applied to the provision of identification labels consisting of patterns, bar codes, and the like. Of course, the present invention is not limited to the above, and can be applied to provide patterns having various other purposes.
発明の効果
本発明の熱定着性インクは、低融点金属粉末を含有する
ので低温定着性、ないし短時間定着性に優れている。従
って、かかる熱定着性インクからなるインクシート、パ
ターンシートは定着性に優れており、定着処理されたパ
ターンは耐擦過性に優れて被着体に長時間存続し、精微
なパターンも容易に形成することができる利点も有して
いる。Effects of the Invention The heat-fixable ink of the present invention contains low-melting point metal powder, and therefore has excellent low-temperature fixability or short-time fixability. Therefore, ink sheets and pattern sheets made of such heat-fixable inks have excellent fixing properties, and the fixed patterns have excellent scratch resistance and remain on the adherend for a long time, making it easy to form minute patterns. It also has the advantage of being able to
また、本発明の焼成パターン形成方法は、曲面に対して
も容易に適用でき、任意なパターンを容易、かつ臨機に
形成することができて、大量生産品用ばかりでなく、多
品種少量生産品用の識別ラベルや絵柄などのパターンを
容易に得ることができる。加えて、焼成により被着体に
固着した焼成パターンは、上記特長のほか耐久性、耐熱
性、耐薬品性等にも優れる。In addition, the firing pattern forming method of the present invention can be easily applied to curved surfaces, and any pattern can be easily and flexibly formed. You can easily obtain identification labels, patterns, etc. In addition, the fired pattern fixed to the adherend by firing has excellent durability, heat resistance, chemical resistance, etc. in addition to the above-mentioned features.
実施例
参考例
ＢａＯ−ＣａＯ−８ｉＯ２系ガラス１００部（重量部、
以下間し〉、ポリメタクリル酸イソブチル１２部、ジブ
チルフタレート４部及びオレイン酸１部の混合物からな
るガラス粉末含有層を、セパ−レータ上に設けた粘着剤
層の上に形成してガラス粉末含有シート（セラミック系
シート）を調製した。Examples Reference Examples 100 parts of BaO-CaO-8iO2 glass (parts by weight,
In the following, a glass powder-containing layer consisting of a mixture of 12 parts of isobutyl polymethacrylate, 4 parts of dibutyl phthalate, and 1 part of oleic acid was formed on the adhesive layer provided on the separator. A sheet (ceramic sheet) was prepared.
実施例
平均粒径３ ｕｍの亜鉛粉末４５部、ＣｕＣｒ２０ｑ１
５部、ステアリン酸３２部及びエチレン・酢酸ビニル共
重合体８部をボールミルでトルエン中に均一に分散させ
て熱定着性インクの塗布液を調製した。Example 45 parts of zinc powder with an average particle size of 3 um, CuCr20q1
A heat-fixable ink coating solution was prepared by uniformly dispersing 5 parts of stearic acid, 32 parts of stearic acid, and 8 parts of ethylene/vinyl acetate copolymer in toluene using a ball mill.
ついで、前記の塗布液を厚さ６μｍのポリエステルフィ
ルム上に乾燥後の厚さが約１０μｍとなるよう塗布機に
て塗布し、乾燥させてインクシートを作製した。Next, the above coating liquid was applied onto a polyester film having a thickness of 6 μm using a coating machine so that the thickness after drying would be approximately 10 μm, and was dried to prepare an ink sheet.
次に、前記のインクシートを所定幅に裁断してリボンと
し、これをケースに収容してインクリボンカートリッジ
を作製し、これを用いて通常の熱転写プリンタを介し、
参考例で得たガラス粉末含有シートにおけるガラス粉末
含有層の上に所定のバーコードパターンを印刷し、パタ
ーンシートを得た。Next, the ink sheet is cut into a predetermined width to form a ribbon, which is housed in a case to create an ink ribbon cartridge.
A predetermined barcode pattern was printed on the glass powder-containing layer of the glass powder-containing sheet obtained in Reference Example to obtain a pattern sheet.
前記のパターンシートをその粘着剤層を介し、表面を加
熱酸化したステンレス板に接着し、これを４５０℃で３
０分間焼焼成て、ステンレス板に固着した焼成パターン
を得た。なお焼成時にステアリン酸等の有機成分は焼失
した。The above pattern sheet was adhered via its adhesive layer to a stainless steel plate whose surface had been heated and oxidized, and this was heated at 450°C for 3
Firing was performed for 0 minutes to obtain a fired pattern that was fixed to the stainless steel plate. Note that organic components such as stearic acid were burned out during firing.
得られた焼成パターンについてメンディングテープ剥離
法により定着性試験を行ったが、パターンは剥ぎ取られ
ることなく、優れた定着性を示した。なおメンディング
テープ剥離法による定着性の評価は、印字部の上にメン
ディングテープ（スコッチメンディングテープ＃８１０
：商品名〉を軽く貼り付けてその上を１−の円筒状重
りをゆっくりと二往復させて押圧し、その後メンディン
グテープを印字面に対して１８０度の角度で剥離し、テ
ープ側に付着したインク量に基づいて行った。A fixability test was conducted on the obtained fired pattern by a mending tape peeling method, but the pattern was not peeled off and showed excellent fixability. In addition, evaluation of fixation by the mending tape peeling method was performed using mending tape (Scotch mending tape #810) on the printed area.
: Lightly paste the product name〉 and press the cylindrical weight 1- slowly back and forth twice on top of it, then peel off the mending tape at a 180 degree angle to the printed surface and adhere to the tape side. This was done based on the amount of ink used.
比較例
亜鉛粉末を用いないほかは実施例に準じ熱定着性インク
、インクシート、パターンシート、焼成パターンを形威
し、その焼成パターンにつきメンディングテープ剥離法
による定着性試験を行ったところ、パターンは定着が不
十分で部分的に剥ぎ取られ、識別不能となった。Comparative Example A heat-fixable ink, an ink sheet, a pattern sheet, and a fired pattern were formed in the same manner as in the example except that zinc powder was not used, and the fired pattern was subjected to a fixability test using the mending tape peeling method. was not fully fixed and was partially peeled off, making it unrecognizable.
Claims (1)
と、熱溶融性バインダからなることを特徴とする熱定着
性インク。 ２、請求項１に記載の熱定着性インクを支持基材に保持
させてなることを特徴とするインクシート。 ３、請求項２に記載のインクシートをケースに収容して
なることを特徴とするインクリボンカートリッジ。 ４、受容シートにおける熱溶融性のインク受容層の上に
、請求項１に記載の熱定着性インクからなるパターンを
有することを特徴とするパターンシート。 ５、請求項２に記載のインクシートを用いて熱転写プリ
ンタを介し、インク受容層の上にパターンを形成定着さ
せることを特徴とする請求項４に記載のパターンシート
の製造方法。 ６、請求項４に記載のパターンシートを被着体に接着し
、そのパターンシートを加熱処理して被着体に焼成パタ
ーンを設けることを特徴とする焼成パターン形成方法。 ７、被着体に接着した受容シートのインク受容層の上に
、請求項１に記載の熱定着性インクからなるパターンを
設けて加熱処理し、被着体に焼成パターンを設けること
を特徴とする焼成パターン形成方法。[Claims] 1. A heat fixable ink comprising a low melting point metal powder having a melting point of 600° C. or less, a heat resistant pigment, and a heat melting binder. 2. An ink sheet comprising the heat fixable ink according to claim 1 held on a supporting base material. 3. An ink ribbon cartridge comprising the ink sheet according to claim 2 housed in a case. 4. A patterned sheet having a pattern made of the heat-fixable ink according to claim 1 on a heat-fusible ink-receiving layer of the receiving sheet. 5. The method for manufacturing a patterned sheet according to claim 4, wherein a pattern is formed and fixed on the ink receiving layer using the ink sheet according to claim 2 using a thermal transfer printer. 6. A fired pattern forming method, which comprises adhering the pattern sheet according to claim 4 to an adherend, and heat-treating the pattern sheet to provide a fired pattern on the adherend. 7. A pattern made of the heat-fixable ink according to claim 1 is provided on the ink-receiving layer of a receptor sheet adhered to an adherend, and heat-treated to provide a fired pattern on the adherend. A firing pattern forming method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1217885A JPH0381377A (en) | 1989-08-24 | 1989-08-24 | Thermally fixable ink, pattern sheet, and method for forming baking pattern |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1217885A JPH0381377A (en) | 1989-08-24 | 1989-08-24 | Thermally fixable ink, pattern sheet, and method for forming baking pattern |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0381377A true JPH0381377A (en) | 1991-04-05 |
Family
ID=16711292
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1217885A Pending JPH0381377A (en) | 1989-08-24 | 1989-08-24 | Thermally fixable ink, pattern sheet, and method for forming baking pattern |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0381377A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20010004350A (en) * | 1999-06-28 | 2001-01-15 | 장용균 | the method of producing dye diffusion thermal transfer ribbon |
| US8973287B2 (en) | 2008-08-27 | 2015-03-10 | Himiko Co., Ltd. | Shoe midsole and footwear |
| CN109177540A (en) * | 2018-10-29 | 2019-01-11 | 河南卓立膜材料股份有限公司 | Transfer printing print ultra-high temperature resistant carbon ribbon and preparation method thereof |
-
1989
- 1989-08-24 JP JP1217885A patent/JPH0381377A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20010004350A (en) * | 1999-06-28 | 2001-01-15 | 장용균 | the method of producing dye diffusion thermal transfer ribbon |
| US8973287B2 (en) | 2008-08-27 | 2015-03-10 | Himiko Co., Ltd. | Shoe midsole and footwear |
| CN109177540A (en) * | 2018-10-29 | 2019-01-11 | 河南卓立膜材料股份有限公司 | Transfer printing print ultra-high temperature resistant carbon ribbon and preparation method thereof |
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