JPH03171152A - Liquid developer for electrostatic charge image - Google Patents
Liquid developer for electrostatic charge imageInfo
- Publication number
- JPH03171152A JPH03171152A JP1311765A JP31176589A JPH03171152A JP H03171152 A JPH03171152 A JP H03171152A JP 1311765 A JP1311765 A JP 1311765A JP 31176589 A JP31176589 A JP 31176589A JP H03171152 A JPH03171152 A JP H03171152A
- Authority
- JP
- Japan
- Prior art keywords
- carboxyl group
- polymer
- fixing
- copying machine
- manufactured
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 18
- 239000002904 solvent Substances 0.000 claims abstract description 14
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 13
- 239000011347 resin Substances 0.000 claims abstract description 12
- 229920005989 resin Polymers 0.000 claims abstract description 12
- 229920000642 polymer Polymers 0.000 claims abstract description 10
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 9
- 150000001412 amines Chemical class 0.000 claims abstract description 7
- 238000004132 cross linking Methods 0.000 claims abstract description 5
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 3
- 239000011737 fluorine Substances 0.000 claims abstract description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000003086 colorant Substances 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 239000000178 monomer Substances 0.000 abstract description 12
- 229930195733 hydrocarbon Natural products 0.000 abstract description 6
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 6
- 239000004215 Carbon black (E152) Substances 0.000 abstract description 5
- 229920002545 silicone oil Polymers 0.000 abstract description 4
- 230000015572 biosynthetic process Effects 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract 2
- 238000000576 coating method Methods 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- -1 ethylene olefins Chemical class 0.000 description 8
- 239000001993 wax Substances 0.000 description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- RVZRBWKZFJCCIB-UHFFFAOYSA-N perfluorotributylamine Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)N(C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F RVZRBWKZFJCCIB-UHFFFAOYSA-N 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- CNPVJWYWYZMPDS-UHFFFAOYSA-N 2-methyldecane Chemical compound CCCCCCCCC(C)C CNPVJWYWYZMPDS-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- 241000557626 Corvus corax Species 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 2
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000012046 mixed solvent Substances 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- UIYCHXAGWOYNNA-UHFFFAOYSA-N vinyl sulfide Chemical compound C=CSC=C UIYCHXAGWOYNNA-UHFFFAOYSA-N 0.000 description 2
- QBZIEGUIYWGBMY-FUZXWUMZSA-N (5Z)-5-hydroxyimino-6-oxonaphthalene-2-sulfonic acid iron Chemical compound [Fe].O\N=C1/C(=O)C=Cc2cc(ccc12)S(O)(=O)=O.O\N=C1/C(=O)C=Cc2cc(ccc12)S(O)(=O)=O.O\N=C1/C(=O)C=Cc2cc(ccc12)S(O)(=O)=O QBZIEGUIYWGBMY-FUZXWUMZSA-N 0.000 description 1
- QLLUAUADIMPKIH-UHFFFAOYSA-N 1,2-bis(ethenyl)naphthalene Chemical compound C1=CC=CC2=C(C=C)C(C=C)=CC=C21 QLLUAUADIMPKIH-UHFFFAOYSA-N 0.000 description 1
- OSNILPMOSNGHLC-UHFFFAOYSA-N 1-[4-methoxy-3-(piperidin-1-ylmethyl)phenyl]ethanone Chemical compound COC1=CC=C(C(C)=O)C=C1CN1CCCCC1 OSNILPMOSNGHLC-UHFFFAOYSA-N 0.000 description 1
- KTZVZZJJVJQZHV-UHFFFAOYSA-N 1-chloro-4-ethenylbenzene Chemical compound ClC1=CC=C(C=C)C=C1 KTZVZZJJVJQZHV-UHFFFAOYSA-N 0.000 description 1
- OZCMOJQQLBXBKI-UHFFFAOYSA-N 1-ethenoxy-2-methylpropane Chemical compound CC(C)COC=C OZCMOJQQLBXBKI-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- WROUWQQRXUBECT-UHFFFAOYSA-N 2-ethylacrylic acid Chemical compound CCC(=C)C(O)=O WROUWQQRXUBECT-UHFFFAOYSA-N 0.000 description 1
- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 1
- DWDURZSYQTXVIN-UHFFFAOYSA-N 4-[(4-aminophenyl)-(4-methyliminocyclohexa-2,5-dien-1-ylidene)methyl]aniline Chemical compound C1=CC(=NC)C=CC1=C(C=1C=CC(N)=CC=1)C1=CC=C(N)C=C1 DWDURZSYQTXVIN-UHFFFAOYSA-N 0.000 description 1
- IYHIFXGFKVJNBB-UHFFFAOYSA-N 5-chloro-2-[(2-hydroxynaphthalen-1-yl)diazenyl]-4-methylbenzenesulfonic acid Chemical compound C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S(O)(=O)=O IYHIFXGFKVJNBB-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 102100040440 Adenylate kinase isoenzyme 5 Human genes 0.000 description 1
- 101710168711 Adenylate kinase isoenzyme 5 Proteins 0.000 description 1
- VVAVKBBTPWYADW-UHFFFAOYSA-L Biebrich scarlet Chemical compound [Na+].[Na+].OC1=CC=C2C=CC=CC2=C1N=NC(C(=C1)S([O-])(=O)=O)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 VVAVKBBTPWYADW-UHFFFAOYSA-L 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
- LTGPFZWZZNUIIK-LURJTMIESA-N Lysol Chemical compound NCCCC[C@H](N)CO LTGPFZWZZNUIIK-LURJTMIESA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- FNYLWPVRPXGIIP-UHFFFAOYSA-N Triamterene Chemical compound NC1=NC2=NC(N)=NC(N)=C2N=C1C1=CC=CC=C1 FNYLWPVRPXGIIP-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000004234 Yellow 2G Substances 0.000 description 1
- YFCGDEUVHLPRCZ-UHFFFAOYSA-N [dimethyl(trimethylsilyloxy)silyl]oxy-dimethyl-trimethylsilyloxysilane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C YFCGDEUVHLPRCZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- PZTQVMXMKVTIRC-UHFFFAOYSA-L chembl2028348 Chemical compound [Ca+2].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 PZTQVMXMKVTIRC-UHFFFAOYSA-L 0.000 description 1
- ZLFVRXUOSPRRKQ-UHFFFAOYSA-N chembl2138372 Chemical compound [O-][N+](=O)C1=CC(C)=CC=C1N=NC1=C(O)C=CC2=CC=CC=C12 ZLFVRXUOSPRRKQ-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- LDCRTTXIJACKKU-ARJAWSKDSA-N dimethyl maleate Chemical compound COC(=O)\C=C/C(=O)OC LDCRTTXIJACKKU-ARJAWSKDSA-N 0.000 description 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
- FTZLWXQKVFFWLY-UHFFFAOYSA-L disodium;2,5-dichloro-4-[3-methyl-5-oxo-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazol-1-yl]benzenesulfonate Chemical compound [Na+].[Na+].CC1=NN(C=2C(=CC(=C(Cl)C=2)S([O-])(=O)=O)Cl)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 FTZLWXQKVFFWLY-UHFFFAOYSA-L 0.000 description 1
- AFOSIXZFDONLBT-UHFFFAOYSA-N divinyl sulfone Chemical compound C=CS(=O)(=O)C=C AFOSIXZFDONLBT-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 235000010985 glycerol esters of wood rosin Nutrition 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- PBZROIMXDZTJDF-UHFFFAOYSA-N hepta-1,6-dien-4-one Chemical compound C=CCC(=O)CC=C PBZROIMXDZTJDF-UHFFFAOYSA-N 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 235000010187 litholrubine BK Nutrition 0.000 description 1
- 229940107698 malachite green Drugs 0.000 description 1
- FDZZZRQASAIRJF-UHFFFAOYSA-M malachite green Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 FDZZZRQASAIRJF-UHFFFAOYSA-M 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- ZARXZEARBRXKMO-UHFFFAOYSA-N n,n-bis(ethenyl)aniline Chemical compound C=CN(C=C)C1=CC=CC=C1 ZARXZEARBRXKMO-UHFFFAOYSA-N 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- JMXROTHPANUTOJ-UHFFFAOYSA-H naphthol green b Chemical compound [Na+].[Na+].[Na+].[Fe+3].C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21 JMXROTHPANUTOJ-UHFFFAOYSA-H 0.000 description 1
- PYUYQYBDJFMFTH-WMMMYUQOSA-N naphthol red Chemical compound CCOC1=CC=CC=C1NC(=O)C(C1=O)=CC2=CC=CC=C2\C1=N\NC1=CC=C(C(N)=O)C=C1 PYUYQYBDJFMFTH-WMMMYUQOSA-N 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- HILCQVNWWOARMT-UHFFFAOYSA-N non-1-en-3-one Chemical compound CCCCCCC(=O)C=C HILCQVNWWOARMT-UHFFFAOYSA-N 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 description 1
- 229940065472 octyl acrylate Drugs 0.000 description 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 235000012736 patent blue V Nutrition 0.000 description 1
- UCUUFSAXZMGPGH-UHFFFAOYSA-N penta-1,4-dien-3-one Chemical class C=CC(=O)C=C UCUUFSAXZMGPGH-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- ZJIJAJXFLBMLCK-UHFFFAOYSA-N perfluorohexane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F ZJIJAJXFLBMLCK-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- WRAQQYDMVSCOTE-UHFFFAOYSA-N phenyl prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1 WRAQQYDMVSCOTE-UHFFFAOYSA-N 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- 229960000834 vinyl ether Drugs 0.000 description 1
- FUSUHKVFWTUUBE-UHFFFAOYSA-N vinyl methyl ketone Natural products CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 235000019235 yellow 2G Nutrition 0.000 description 1
Abstract
Description
本発明は、電子写真、静電記録、静電印刷等に用いられ
る熱ロール定着用の液体現像剤に関する．The present invention relates to a liquid developer for hot roll fixing used in electrophotography, electrostatic recording, electrostatic printing, etc.
熱ロール定着ロール用の液体現像剤として、特開昭６３
−３０１９６６〜３０１９６９号公報、同６４−５００
６２〜５００６７号，同６４−５２１６７号，同６４−
１４２５６０〜１４２５６１号公報などがある。これら
は脂肪族炭化水素が主成分の担体液のため、その脂肪族
炭化水素のガスが複写機外に排出される、定着ロールに
塗布するためのシリコンオイルを供給しなければならず
、そのために複写機が複雑になったり、消耗品点数が増
すなどの問題があった。
（本発明の目的１
複写機から発生する炭化水素系の溶剤ガスの低減を目的
とする。
液体現像剤を使用した熱ロール定着装置において、定着
ロールへのオイル塗布装置の除去を可能とし、またオイ
ル供給の手間を省く。
不燃性の液剤をある割合で混入させることにより引火な
どの危険を少なくする。
【発明の構成１
近年、熱効率が高く高速定着が可能な液体現像剤の定着
方法として、熱ロール定着が提案されている。担体液に
炭化水素系の溶剤を使用し、この定着方法採用すると、
従来より使用されている雰囲気定着に比べ、若干単位枚
数あたりの溶剤ガス排出量が減少するが、高速で多数枚
複写をしたときには大量の溶剤ガスが発生する。また、
トナー層と定着ロールとの離型性を上げるためシリコン
オイルの塗布が必要であった。本発明は、担体液として
フッ素系溶剤を含有させることにより、上記欠点を改良
するとともに、トナーの凝集力を−Ｌげ、いわゆる′゛
ホットオフセット”を防止する点にある。
本発明に使川されるフッ素系の溶剤としては、フロリナ
ートＦＣ−７７、ＦＣ−４０、ＦＣ−４３、ＦＣ−７０
（以Ｌ住友３Ｍ社製）、アフルード、Ｅ−１０．Ｅ−
１６、Ｅ−１８（以Ｌ旭硝ｆ社製）等が挙げられる。ま
た、同特に使用されてもよいシリコーン系の溶剤として
は、ＫＦ９６（信越シリコン）．Ｓ＋＋２００，ＳＨ３
４４ （東レシリコン）．ＴＳＦ４５１（東芝シリコ
ン）などが挙げられ、その他デカメチルテトラシロキサ
ン、オクタメチルトリシロキサン等を使用してもよい。
また、脂肪族炭化水素溶液としてシクロヘキサン、ｎ−
ヘキサン、ｎ−ヘプタン、ｎ−オクタン、ｎ−ノナン、
イソオクタン、イソドデカン、リグロイン及びそれらの
混合物などの石油系炭化水素（市販品としてエクソンケ
ミカル社製アイソバーＥ，Ｇ，！−｛，Ｌ，Ｋ，Ｖやシ
ェル石油社製シェルゾール７１、ソルッペッソ１５０，
等がある）が挙げられこれらを適宜混合して使用する。
転写用剤を低減するために、担体液はｌＯｃｓｔ以下、
好ましくは３ｃｓｔ以下がよい。
本発明においてはトナーの凝集力を上げる手段としてカ
ルボキシル基を有するビニル系重合体をアミンで架橋し
て得られる重合体を用いるものである。
Ａｉｉ記ビニル系重合体合成用のカルボキシル基含イｆ
モノマーとしては、例えば，アクリル酸、メタクリル酸
、α一エチルアクリル酸、クロトン酸などのアクリル酸
及びそのα一或いはβ−アルキル誘導体、フマル酸、マ
レイン酸、シトラコン酸などの不飽和ジカルボン酸及び
そのモノエステル誘導体などがあり、このようなモノマ
ーを単独或いは混合して、他のモノマーと共重合させる
ことにより所望のカルボキシル基を含有する重合体を作
ることができる。
上記のようなカルボキシル基含有モノマーと共重合可能
なモノマーとしては、例えば、スチレン、α−メチルス
チレン，ｐ−クロルスチレン、ビニルナフタリン、アク
リル酸メチル、アクリル酸エチル、アクリル酸ブチル、
アクリル酸ドデシル、アクリル酸オクチル、アクリル酸
フェニル、メタクリル酸メチル、メタクリル酸エチル、
メタクリル酸ブチル，メタクリル酸オクチル、アクリロ
ニトリル、メタクリロニトリル、アクリルアミドなどの
ような二重結合を有するモノカルボン酸の置換体；例え
ば、マレイン酸ジブチル、マレイン酸ジメチルなどのよ
うな二重結合を有するジカルボン酸のジエステル誘導体
；例えば塩化ビニル、酢酸ビニル、安息香酸ビニルなど
のようなビニル類；例えばエチレン、ブロビレン、ブチ
レンなどのようなエチレン系オレフイン類；例えばビニ
ルメチルケトン、ビニルヘキシルケトンなどのようなビ
ニルケトン類；例えばビニルメチルエーテル、ビニルエ
チルエーテル、ビニルイソブチルエーテルなどのような
ビニルエーテル類；例えば、ビニルベンゼン、ジビニル
ナフタレンなどのような芳香族ジビニル化合物；例えば
エチレングリコールジアクリレート、エチレングリコー
ルジメタクリレート、１．３−ブタンジオールジメタク
リレートなどのような二重結合を２個有するカルボン酸
エステル；例えばジビニルアニリン、ジビニルエーテル
、ジビニルスルフイド、ジビニルスルホンなどのジビニ
ル化合物及び３個以上のビニル基を有する化合物を単独
若しくは混合物として用いることができる。
カルボキシル基を有する重合体中に含まれるカルボキシ
ル基含有モノマーの割合としては、０．１〜３０重量％
が良好な結果を与え、０．５〜２０重量％の範囲にある
と、特に好ましい結果が得られる。
次に、本発明中でカルボキシル基を有する重合体を架橋
するアミンは、次の一般式を有するものが好摘である。
式中、ａとｂとは２〜４の整数を表わし、同一又は異な
っていてもよく、Ｘとｙは１〜５０の整数を表わし、同
一又は異なっていてもよく、さらにＲは８〜３０の炭素
原子から成るアルキル基（但し、枝分れ及びシクロアル
キル基を含む）を示す。
アミンの使用量は、重合体１００重量部に対し、約０．
１〜０．５重量部が好ましい。
本発明に使用できる着色材としては、プリンテックスＶ
、プリンテックスＵ，プリンテックスＧ，スペシャルブ
ラックｌ５、スペシャルブラック４、スペシャルブラッ
ク４−Ｂ（以上デグサ社製）、三菱＃４４、＃３０，Ｍ
Ｒ−１１、ＭＡ− １ ０ ０（以上三菱化成社ｆｊ３
）．ラーベン＋０３５、ラーベンｌ２５２、ニュースペ
クト■（以上コロンビアカーボン社製）、リーガル４０
０、６６０、ブラックパール９００％ １１００，１３
００、モ−ガルＬ（以上キャボット社製）などの無機顔
料およびフタロシアニンブルー、フタロシアニングリー
ン、スカイブルー、ローダミンレーキ、マラカイトグリ
ーンレーキ、メチルバイオレットレーキ、ビーコックブ
ルーレーキ、ナフトールグリーンＢ，ナフトールグリー
ンＹ、ナフトールイエロー８１ナフトールレッド、リソ
ールファーストイエロー２Ｇ、パーマネントレッド４Ｒ
，ブリリアントファーストスカーレット，ハンザイエロ
ー、ベンジジンイエロー、リソールレッド、レーキレッ
ドＣ、レーキレッドＤ１ブリリアントカーミン６Ｂ、パ
ーマネントレッドＦ５Ｒ、ビグメントスカーレット３Ｂ
インジゴ，チオインジゴオイルピンクおよびボルドー１
０Ｂなどの有機顔料があげられる。
以上の顔料を前記樹脂と、二本ロール、二一ダーフラッ
シャーなどで混線、粉砕し、顔料を処理することができ
る。また、前記樹脂とともに下記の樹脂を使用しても良
い。
イーストマンケミカル（Ｅａｓｔｍａｎ Ｃｈｅｍｉｃ
ａｌ）社製（Ｎ−１０，Ｎ−１１，Ｎ−１２，Ｎ−１４
，Ｎ−３４，Ｎ−４５，Ｃ−１０，Ｃ−１３，Ｃ−１５
，Ｃ−１６，Ｅ−１０，Ｅ−１１，Ｅ−１２，Ｅ−１４
，Ｅ−１５）三井石油化学社製
（ Ｉ ＩＯＰ， ２２０Ｐ， ２２０ＭＰ， ８２０
ＭＰ， ４ １０ＭＰ， ２１０ＭＰ， ３ １０ＭＰ
，４０５ＭＰ， ２００Ｐ， ４２０２Ｅ， ４０５３
Ｅ）三洋化成社製
（＋３ＩＰ， ＋５ＩＰ， ＋６ＩＰ， ＋７ＩＰ，Ｅ
３００，Ｅ２５０Ｐ）サゾール社製
（＋１１，１１２，ＡＩ，Ａ２，Ａ３，Ａ４）バスフ（
ＢＡＳＦ）社製
（ＯＡ ＷＡＸ，Ａ ＷＡＸ）
ペトロライト（Ｐｅｔｒｏｌ ｉｔｅ）社製（バレコ（
ＢＡＲＥＣＯ）５００，同２０００， Ｅ−７３０，Ｅ
−２０１８，Ｅ−２０２０，Ｅ−１０４０，ペトロナバ
（Ｐｅｔｒｏｎａｂａ）Ｃ，同Ｃ−３６，同Ｃ−４００
，同Ｃ−７５００ ’）
ヘキスト（Ｈｏｅｃｈｓｔ）社製
（ＰＥ５８０， ＰＥｌ３０， ＰＥＤＩ ２ １，
ＰＥＤＩ３６， ＰＥＤｌ５３， ＰＥＤ５２ １ ，
ＰＥＤ５２２， ＰＥＤ５３４ ）
ユニオンカーバイド社製
（ＤＹＮ ｌ ， ＤＹＮＦ， ＤＹＮＨ， ＤＹＮＪ
， ＤＹＮＫ ）モンサント社
（オルゾン（ＯＲＵＺＯＮ）８０５，７０５．５０）デ
ュポン社
（アラトン（ＡＬＡ．ＴｌｌＯＮ）３， １０， ＋２
． １４． １６，２０，２２．２３）アライドケミカ
ル社
（ＡＣポリエチレン６．６Ａ，６１５）三井ポリケミカ
ル社
（エバフレックス１５０，２１０，２２０，２５０，２
６０，３１０，３６０，４１０，４２０，４５０，４６
０，５５０，５６０）などの合成ポリエステル、ボリブ
ロビレン及びその変成したもの、カルナバワックス、モ
ンタンワックス、キャンデリラワックス、シュガーケー
ンワックス、オーキュリーワックス、密蝋、木蝋、ヌカ
蝋などの天然ワックス、エステルガム、硬化ロジンなど
の天然樹脂、天然樹脂変成マレイン酸樹脂、天然樹脂変
成フェノール樹脂、天然樹脂変成ポリエステル樹脂、天
然樹脂変成ペンタエリストール樹脂、エボキシ樹脂など
の天然樹脂変成硬化樹脂等が併用できる。
また本発明に併用することが好ましい分散用樹脂として
は
一般式
ＣＨ，＝ＣＲ
ＣＯＯＣ，Ｈ．，．
（ＲはＨまたはＣＨ，を、ｎは６〜２０の整数を表わす
。）
であらわされるビニルモノマーＡと
一般式
ＣＨ，＝ＣＲ
ＧＯＯＲ，
（Ｒ，は１１またはＣ１１．を、
Ｒ．は｝ｌ， Ｃ，，Ｈ，，，＋１［ｎ＝１−５］Ｉ
Ｃ，１１，ＯＨＩ（ｍｌ〜４〕を表わす。）
で表わされるビニルモノマー及びビニルビリジン、ビニ
ルビロリドン、エチレングリコールジメタクリレート、
スチレン、ジビニルベンゼン、ビニルトルエンより選ば
れるモノマーＢの各一種づつもしくは、数種の共重合体
、グラフト共重合体があげられる。
またシリコン溶剤を担持液として用いる場合には、分散
性を上げるためにアクロイル基を有するシリコン材料、
信越シリコン社製のＬＳ４０８０などを共重合させても
良いし、同様に東亜合成化学社製のＡＫ−５、チッソ社
製のＴＭＯ７０１、ＦＭＯ７１１，ＦＭＯ７２１，ＦＭ
Ｏ７２５を使用しても良い。
これらの着色材、樹脂、担体液をボールミル、キテイー
ミル、ディスクミル、ビンミルなどの分散機に投入、分
散、混練を行い濃縮トナーを調製し、これを本発明の担
持液中に分散させることにより現像液を得ることができ
る。
（実施例）
以下の実施例中「部」は全て「重量部」を表わす。
実施例１
カーボンブラック
（デグサ社製ＰｒｉｎＬｅｘ）
３０部
を１２０℃で３０分間二本ロールで混線後粉砕した。
前記粉砕物
５０部
アイソパー８ ２０％溶液 １００部ア
イソバーＨ （ＥＸＸＳＯＮ社商品名）２００部をボー
ルミルに入れて２４時間分散後、さらにアイソバーＨを
３００部加え、１時間分散し、これを濃縮トナーとした
。これを２００ｇ取り、フロリナートＦＣ−７２（住友
３Ｍ社製）５０％とＫＦ９６ （信越シリコーン社製、
粘度３ ｃ ｓ ｔ ） ５０％の混合溶剤ＩＱ．中に
希釈し、現像剤とした。
実施例２
ナイミーンＳ ２０２
０．１５部
２５０Ｐ （三洋化成社製ポリエチレン）８部
ＭＡ６０
（三菱化成社製カーボンブラック）
３５部
をフラッシャーで混練後粉砕した。
前記粉砕物
６０部
アイソバー｝｛ １００
部をボールミルに入れて２４時間分散後、さらにアイソ
パーＨを３００部加え、１時間分散し、これを濃縮トナ
ーとした。これを２００ｇ取り、フロリナートＦＣ−７
２（住友３Ｍ社製）５０％とアイソパーＨ５０％の混合
溶剤ＩＱ中に希釈し、現像剤とした。
これを実施例ｌと同様にして現像剤を得た。
実施例３
ナイミーンＳ ２０２
０．２部
ＡＣ４００Ａ （アライドケミカル社製〉１０部リーガ
ル４００（キャボット社製）３０部を１４０℃、６０分
間フラツシャーで混練粉砕した。
以下実施例ｌと同様にして現像剤を調製した。
比較例
実施例１〜３において希釈剤をアイソバーＨとした以外
は同様にして、それぞれ比較現像剤１〜３を得た。
リコー製ＣＴ５０８５の定着部を熱ロール定着に改良し
た試験機でオイルレスで定着試験を行った。その結果は
次表の通りであった。
以上の結果より明らかなとおり、本発明現像剤によりオ
フセット現象を示さない熱ローラ定着可能な範囲の温度
巾が得られ、熱ローラ定着が可能であることがわかる。
また密閉された室内で、試験複写機を用い連続コピーを
行い、溶剤ガス濃度を測定したところ、比較現像剤を用
いた場合はいずれも３００〜３６０ｐｐｇ＋に対し、本
発明現像剤ではいずれも８０〜１５０ｐｐｍと半減して
いた。
［効果１
本発明現像剤を用いることにより、定着ロールにオイル
塗布を行わなくても、オフセット現象を起こすことなく
、熱ロール定着が可能となり、コンパクトな複写機で高
速、かつ低エネルギ一定着が可能となった。また、複写
機より発生する炭化水素系ガス量も低減した。
Ｕ清大株式会社リコーAs a liquid developer for heat roll fixing rolls, JP-A-63
-301966 to 301969, 64-500
No. 62-50067, No. 64-52167, No. 64-
142560-142561, etc. Since these are carrier liquids mainly composed of aliphatic hydrocarbons, the aliphatic hydrocarbon gas is discharged outside the copying machine, and silicone oil must be supplied to apply to the fixing roll. There were problems such as the copying machine becoming more complex and the number of consumables increasing. (Objective 1 of the present invention is to reduce hydrocarbon solvent gas generated from copying machines. In a hot roll fixing device using a liquid developer, it is possible to remove an oil application device to the fixing roll, and Eliminates the trouble of oil supply. Reduces the risk of ignition by mixing a certain proportion of non-flammable liquid. [Configuration 1 of the Invention] In recent years, as a fixing method for liquid developers that has high thermal efficiency and enables high-speed fixing, Heat roll fixing has been proposed.If a hydrocarbon solvent is used as the carrier liquid and this fixing method is adopted,
Compared to conventional atmospheric fixing, the amount of solvent gas emitted per unit number of sheets is slightly reduced, but a large amount of solvent gas is generated when a large number of sheets are copied at high speed. Also,
It was necessary to apply silicone oil to improve the releasability between the toner layer and the fixing roll. The present invention improves the above-mentioned drawbacks by containing a fluorine-based solvent as a carrier liquid, and also reduces the cohesive force of the toner to prevent so-called ``hot offset.'' Examples of fluorinated solvents include Fluorinert FC-77, FC-40, FC-43, and FC-70.
(manufactured by Sumitomo 3M), Afrud, E-10. E-
16, E-18 (manufactured by Asahi Glass Co., Ltd.), and the like. In addition, examples of silicone-based solvents that may be used include KF96 (Shin-Etsu Silicon). S++200, SH3
44 (Toray Silicon). Examples include TSF451 (Toshiba Silicon), and other materials such as decamethyltetrasiloxane and octamethyltrisiloxane may also be used. In addition, cyclohexane, n-
hexane, n-heptane, n-octane, n-nonane,
Petroleum hydrocarbons such as isooctane, isododecane, ligroin, and mixtures thereof (commercially available products include Isovar E, G, !-{, L, K, V, manufactured by Exxon Chemical Co., Ltd.; Shellsol 71, Solupesso 150, manufactured by Shell Oil Company;
etc.), and these may be mixed and used as appropriate. In order to reduce the transfer agent, the carrier liquid should be less than lOcst,
Preferably it is 3 cst or less. In the present invention, a polymer obtained by crosslinking a vinyl polymer having a carboxyl group with an amine is used as a means for increasing the cohesive force of the toner. Aii carboxyl group-containing f for vinyl polymer synthesis
Examples of monomers include acrylic acid and its α- or β-alkyl derivatives such as acrylic acid, methacrylic acid, α-ethyl acrylic acid, and crotonic acid; unsaturated dicarboxylic acids such as fumaric acid, maleic acid, and citraconic acid; There are monoester derivatives, etc., and by copolymerizing such monomers alone or in combination with other monomers, a polymer containing a desired carboxyl group can be produced. Examples of monomers copolymerizable with the above carboxyl group-containing monomers include styrene, α-methylstyrene, p-chlorostyrene, vinylnaphthalene, methyl acrylate, ethyl acrylate, butyl acrylate,
Dodecyl acrylate, octyl acrylate, phenyl acrylate, methyl methacrylate, ethyl methacrylate,
Substituted monocarboxylic acids with double bonds, such as butyl methacrylate, octyl methacrylate, acrylonitrile, methacrylonitrile, acrylamide, etc.; dicarboxylic acids with double bonds, such as dibutyl maleate, dimethyl maleate, etc. Diester derivatives of acids; vinyls such as vinyl chloride, vinyl acetate, vinyl benzoate, etc.; ethylene olefins such as ethylene, brobylene, butylene, etc.; vinyl ketones such as vinyl methyl ketone, vinyl hexyl ketone, etc. Vinyl ethers such as vinyl methyl ether, vinyl ethyl ether, vinyl isobutyl ether, etc.; Aromatic divinyl compounds such as vinylbenzene, divinylnaphthalene, etc.; For example, ethylene glycol diacrylate, ethylene glycol dimethacrylate, 1. Carboxylic acid esters having two double bonds such as 3-butanediol dimethacrylate; divinyl compounds such as divinylaniline, divinyl ether, divinyl sulfide, divinyl sulfone, and compounds having three or more vinyl groups; It can be used alone or as a mixture. The proportion of the carboxyl group-containing monomer contained in the carboxyl group-containing polymer is 0.1 to 30% by weight.
gives good results, and a range of 0.5 to 20% by weight gives particularly favorable results. Next, in the present invention, the amine for crosslinking the carboxyl group-containing polymer preferably has the following general formula. In the formula, a and b represent integers of 2 to 4 and may be the same or different, X and y represent integers of 1 to 50 and may be the same or different, and R is 8 to 30. represents an alkyl group consisting of carbon atoms (including branched and cycloalkyl groups). The amount of amine used is approximately 0.00 parts by weight per 100 parts by weight of the polymer.
1 to 0.5 parts by weight is preferred. As a coloring material that can be used in the present invention, Printex V
, Printex U, Printex G, Special Black l5, Special Black 4, Special Black 4-B (manufactured by Degussa), Mitsubishi #44, #30, M
R-11, MA-100 (Mitsubishi Kasei fj3
). Raven+035, Raven l252, New Spect■ (manufactured by Columbia Carbon), Regal 40
0,660, black pearl 900% 1100,13
00, inorganic pigments such as Mogul L (manufactured by Cabot) and phthalocyanine blue, phthalocyanine green, sky blue, rhodamine lake, malachite green lake, methyl violet lake, beacock blue lake, naphthol green B, naphthol green Y, Naphthol Yellow 81 Naphthol Red, Resol Fast Yellow 2G, Permanent Red 4R
, Brilliant First Scarlet, Hansa Yellow, Benzidine Yellow, Lysol Red, Lake Red C, Lake Red D1 Brilliant Carmine 6B, Permanent Red F5R, Pigment Scarlet 3B
Indigo, Thioindigo Oil Pink and Bordeaux 1
Examples include organic pigments such as 0B. The pigment can be treated by mixing and crushing the above pigment with the resin using a two-roll, twenty-one-dar flasher, or the like. Further, the following resins may be used together with the above resins. Eastman Chemical
al) manufactured by (N-10, N-11, N-12, N-14
, N-34, N-45, C-10, C-13, C-15
, C-16, E-10, E-11, E-12, E-14
, E-15) Manufactured by Mitsui Petrochemical Co., Ltd. (IIOP, 220P, 220MP, 820
MP, 4 10MP, 210MP, 3 10MP
,405MP, 200P, 4202E, 4053
E) Manufactured by Sanyo Chemical Co., Ltd. (+3IP, +5IP, +6IP, +7IP, E
300, E250P) manufactured by Sasol (+11, 112, AI, A2, A3, A4) bathf (
Manufactured by BASF (OA WAX, A WAX) Manufactured by Petrolite (Bareco (
BARECO) 500, 2000, E-730, E
-2018, E-2020, E-1040, Petronaba C, Petronaba C-36, Petronaba C-400
, C-7500') manufactured by Hoechst (PE580, PE130, PEDI 2 1,
PEDI36, PEDl53, PED52 1,
PED522, PED534) Manufactured by Union Carbide (DYNl, DYNF, DYNH, DYNJ)
, DYNK) Monsanto Company (ORUZON 805,705.50) DuPont Company (ALA.TllON) 3, 10, +2
．． 14. 16, 20, 22. 23) Allied Chemical Company (AC polyethylene 6.6A, 615) Mitsui Polychemical Company (Evaflex 150, 210, 220, 250, 2
60,310,360,410,420,450,46
0,550,560), natural waxes such as carnauba wax, montan wax, candelilla wax, sugar cane wax, oculie wax, beeswax, wood wax, bran wax, and ester gum. Natural resins such as hardened rosin, natural resin-modified maleic acid resins, natural resin-modified phenol resins, natural resin-modified polyester resins, natural resin-modified pentaerythtol resins, and natural resin-modified hardened resins such as epoxy resins can be used in combination. In addition, the dispersing resins preferably used in combination in the present invention have the general formulas CH, =CR COOC, H. 、． (R represents H or CH, and n represents an integer of 6 to 20.) Vinyl monomer A represented by the general formula CH, = CR GOOR, (R represents 11 or C11., R. represents }l) , C,,H,,,+1[n=1-5]I
Vinyl monomers represented by C, 11, OHI (representing ml to 4) and vinyl biridine, vinyl pyrrolidone, ethylene glycol dimethacrylate,
Examples include copolymers and graft copolymers of each type of monomer B selected from styrene, divinylbenzene, and vinyltoluene, or several types of monomers. In addition, when using a silicone solvent as a supporting liquid, a silicone material having an acroyl group,
LS4080 manufactured by Shin-Etsu Silicon Co., Ltd. may be copolymerized, and similarly AK-5 manufactured by Toagosei Chemical Co., Ltd., TMO701, FMO711, FMO721, FM manufactured by Chisso Co., Ltd.
O725 may also be used. These coloring materials, resins, and carrier liquids are put into a dispersing machine such as a ball mill, kitty mill, disk mill, and bottle mill, and then dispersed and kneaded to prepare a concentrated toner, which is then dispersed in the carrier liquid of the present invention for development. liquid can be obtained. (Example) In the following examples, all "parts" represent "parts by weight." Example 1 30 parts of carbon black (PrinLex manufactured by Degussa) was mixed with two rolls at 120° C. for 30 minutes and then ground. 50 parts of the pulverized product Isopar 8 20% solution 100 parts 200 parts of Isovar H (trade name of EXXSON) were placed in a ball mill and dispersed for 24 hours, then 300 parts of Isovar H was added and dispersed for 1 hour, and this was mixed into a concentrated toner. did. Take 200g of this, add 50% Fluorinert FC-72 (manufactured by Sumitomo 3M) and KF96 (manufactured by Shin-Etsu Silicone,
Viscosity 3 c s t ) 50% mixed solvent IQ. It was diluted into a developer and used as a developer. Example 2 0.15 parts of Naimeen S 202 250P (polyethylene manufactured by Sanyo Chemical Co., Ltd.) 8 parts MA60 (carbon black manufactured by Mitsubishi Chemical Corporation) 35 parts were kneaded with a flasher and then pulverized. 60 parts of the pulverized material {100
After dispersing for 24 hours in a ball mill, 300 parts of Isopar H was further added and dispersed for 1 hour to obtain a concentrated toner. Take 200g of this and use Fluorinert FC-7
2 (manufactured by Sumitomo 3M) and Isopar H 50% in a mixed solvent IQ to prepare a developer. A developer was obtained in the same manner as in Example 1. Example 3 0.2 parts of Naimeen S 202, 10 parts of AC400A (manufactured by Allied Chemical Co.), and 30 parts of Regal 400 (manufactured by Cabot Corporation) were kneaded and ground at 140° C. for 60 minutes using a flasher.The following developer was prepared in the same manner as in Example 1. Comparative Examples Comparative developers 1 to 3 were obtained in the same manner as in Examples 1 to 3 except that Isobar H was used as the diluent.Test in which the fixing unit of Ricoh CT5085 was improved to hot roll fixing. A fixing test was carried out using an oil-less machine.The results are shown in the table below.As is clear from the above results, the developer of the present invention has a temperature range that allows hot roller fixing without causing offset phenomenon. It can be seen that hot roller fixing is possible.In addition, continuous copying was performed using a test copying machine in a sealed room, and the solvent gas concentration was measured. ~360ppg+, the developer of the present invention was halved to 80-150ppm. [Effect 1] By using the developer of the present invention, the offset phenomenon could be avoided even without applying oil to the fixing roll. , heated roll fixing became possible, allowing a compact copying machine to achieve high speed and constant fixation with low energy. Also, the amount of hydrocarbon gas generated by the copying machine was reduced. U Seidai Ricoh Co., Ltd.
Claims (1)
コン系溶剤との混合液体からなる高抵抗低誘電率の担体
液中に、着色剤と樹脂とからなるトナー粒子を分散して
なる静電写真用液体現像剤において、前記樹脂成分とし
てカルボキシル基を有するビニル系重合体をアミンで架
橋して得られる重合体を含有することを特徴とする静電
荷像用液体現像剤。An electrostatic photograph in which toner particles made of a colorant and resin are dispersed in a carrier liquid of high resistance and low dielectric constant made of a liquid mixture of a fluorine-based solvent, an aliphatic hydrocarbon solvent, and/or a silicone-based solvent. A liquid developer for electrostatic images, characterized in that the resin component contains a polymer obtained by crosslinking a vinyl polymer having a carboxyl group with an amine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1311765A JP2826854B2 (en) | 1989-11-30 | 1989-11-30 | Liquid developer for electrostatic image |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1311765A JP2826854B2 (en) | 1989-11-30 | 1989-11-30 | Liquid developer for electrostatic image |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03171152A true JPH03171152A (en) | 1991-07-24 |
| JP2826854B2 JP2826854B2 (en) | 1998-11-18 |
Family
ID=18021216
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1311765A Expired - Fee Related JP2826854B2 (en) | 1989-11-30 | 1989-11-30 | Liquid developer for electrostatic image |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2826854B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0965891A2 (en) * | 1998-06-18 | 1999-12-22 | Canon Kabushiki Kaisha | Image forming method |
-
1989
- 1989-11-30 JP JP1311765A patent/JP2826854B2/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0965891A2 (en) * | 1998-06-18 | 1999-12-22 | Canon Kabushiki Kaisha | Image forming method |
| EP0965891A3 (en) * | 1998-06-18 | 2000-12-06 | Canon Kabushiki Kaisha | Image forming method |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2826854B2 (en) | 1998-11-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH03171152A (en) | Liquid developer for electrostatic charge image | |
| JP2675015B2 (en) | Liquid developer for electrostatic photography | |
| JP2826853B2 (en) | Liquid developer for electrostatic image | |
| JP2826851B2 (en) | Liquid developer for electrostatic image | |
| JP2942845B2 (en) | Liquid developer for electrostatic image | |
| JP2829758B2 (en) | Liquid developer for electrostatic image | |
| JP2829757B2 (en) | Liquid developer for electrostatic image | |
| JP2935271B2 (en) | Liquid developer for electrostatic image | |
| JP2829756B2 (en) | Liquid developer for electrostatic image | |
| JP2572066B2 (en) | Liquid developer for electrostatic image development | |
| JP2675012B2 (en) | Liquid developer for electrostatic photography | |
| JP3068837B2 (en) | Liquid developer for electrostatic photography | |
| JP3034563B2 (en) | Liquid developer for electrostatic photography | |
| JP2936516B2 (en) | Liquid developer for electrostatic image | |
| JP2572065B2 (en) | Liquid developer for electrostatic image development | |
| JP2826871B2 (en) | Liquid developer for electrostatic image | |
| JPH05257332A (en) | Electrophotographic developer | |
| JPS63301967A (en) | Electrostatic charge image developing liquid developer | |
| JP2931012B2 (en) | Liquid developer for electrostatic image | |
| JP2942842B2 (en) | Liquid developer for electrostatic image | |
| JP2826873B2 (en) | Liquid developer for electrostatic image | |
| JP2675013B2 (en) | Liquid developer for electrostatic photography | |
| JP2942843B2 (en) | Liquid developer for electrostatic image | |
| JP2935270B2 (en) | Liquid developer for electrostatic image | |
| JP2675016B2 (en) | Liquid developer for electrostatic photography |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |