JPH0251555A - Thermoplastic resin composition - Google Patents
Thermoplastic resin compositionInfo
- Publication number
- JPH0251555A JPH0251555A JP19997788A JP19997788A JPH0251555A JP H0251555 A JPH0251555 A JP H0251555A JP 19997788 A JP19997788 A JP 19997788A JP 19997788 A JP19997788 A JP 19997788A JP H0251555 A JPH0251555 A JP H0251555A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- resin
- polymer
- styrene
- polyphenylene ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011342 resin composition Substances 0.000 title claims description 11
- 229920005992 thermoplastic resin Polymers 0.000 title claims description 10
- 229920000642 polymer Polymers 0.000 claims abstract description 48
- 229920005668 polycarbonate resin Polymers 0.000 claims abstract description 17
- 239000004431 polycarbonate resin Substances 0.000 claims abstract description 17
- 239000004793 Polystyrene Substances 0.000 claims description 34
- 229920002223 polystyrene Polymers 0.000 claims description 34
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 43
- 229920005989 resin Polymers 0.000 abstract description 38
- 239000011347 resin Substances 0.000 abstract description 38
- -1 polybutylene terephthalate Polymers 0.000 abstract description 25
- 229920001955 polyphenylene ether Polymers 0.000 abstract description 25
- 239000000203 mixture Substances 0.000 abstract description 21
- 229920001225 polyester resin Polymers 0.000 abstract description 19
- 239000004645 polyester resin Substances 0.000 abstract description 19
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 abstract description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 abstract description 6
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract description 6
- NXXYKOUNUYWIHA-UHFFFAOYSA-N 2,6-Dimethylphenol Chemical compound CC1=CC=CC(C)=C1O NXXYKOUNUYWIHA-UHFFFAOYSA-N 0.000 abstract description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 abstract description 4
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 4
- 229920001707 polybutylene terephthalate Polymers 0.000 abstract description 4
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 abstract description 2
- 229920001577 copolymer Polymers 0.000 description 19
- 230000000704 physical effect Effects 0.000 description 14
- 125000003700 epoxy group Chemical group 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 12
- 239000002253 acid Substances 0.000 description 11
- 239000000835 fiber Substances 0.000 description 11
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 229920001971 elastomer Polymers 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 125000004018 acid anhydride group Chemical group 0.000 description 5
- 150000002989 phenols Chemical class 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 5
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000000806 elastomer Substances 0.000 description 4
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- 239000012763 reinforcing filler Substances 0.000 description 4
- 239000012779 reinforcing material Substances 0.000 description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- 239000005060 rubber Substances 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 238000007664 blowing Methods 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 125000003262 carboxylic acid ester group Chemical group [H]C([H])([*:2])OC(=O)C([H])([H])[*:1] 0.000 description 3
- 125000002843 carboxylic acid group Chemical group 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 238000006068 polycondensation reaction Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical group CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 2
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 2
- OZJPLYNZGCXSJM-UHFFFAOYSA-N 5-valerolactone Chemical compound O=C1CCCCO1 OZJPLYNZGCXSJM-UHFFFAOYSA-N 0.000 description 2
- CIRRFAQIWQFQSS-UHFFFAOYSA-N 6-ethyl-o-cresol Chemical compound CCC1=CC=CC(C)=C1O CIRRFAQIWQFQSS-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 229920002725 thermoplastic elastomer Polymers 0.000 description 2
- 150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 description 2
- XVOUMQNXTGKGMA-OWOJBTEDSA-N (E)-glutaconic acid Chemical compound OC(=O)C\C=C\C(O)=O XVOUMQNXTGKGMA-OWOJBTEDSA-N 0.000 description 1
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- YOUHVVBPILYPKM-IHWYPQMZSA-N (Z)-but-2-ene-1,1-diol Chemical compound C\C=C/C(O)O YOUHVVBPILYPKM-IHWYPQMZSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- WAEOXIOXMKNFLQ-UHFFFAOYSA-N 1-methyl-4-prop-2-enylbenzene Chemical group CC1=CC=C(CC=C)C=C1 WAEOXIOXMKNFLQ-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- CISIJYCKDJSTMX-UHFFFAOYSA-N 2,2-dichloroethenylbenzene Chemical compound ClC(Cl)=CC1=CC=CC=C1 CISIJYCKDJSTMX-UHFFFAOYSA-N 0.000 description 1
- WCUDDVOHXLKLQN-UHFFFAOYSA-N 2,3,6-triethylphenol Chemical compound CCC1=CC=C(CC)C(CC)=C1O WCUDDVOHXLKLQN-UHFFFAOYSA-N 0.000 description 1
- QWBBPBRQALCEIZ-UHFFFAOYSA-N 2,3-dimethylphenol Chemical compound CC1=CC=CC(O)=C1C QWBBPBRQALCEIZ-UHFFFAOYSA-N 0.000 description 1
- HJPICRYOHOZPSA-UHFFFAOYSA-N 2,6-dimethyl-3-propylphenol Chemical compound CCCC1=CC=C(C)C(O)=C1C HJPICRYOHOZPSA-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- JJRUAPNVLBABCN-UHFFFAOYSA-N 2-(ethenoxymethyl)oxirane Chemical group C=COCC1CO1 JJRUAPNVLBABCN-UHFFFAOYSA-N 0.000 description 1
- BMFMTNROJASFBW-UHFFFAOYSA-N 2-(furan-2-ylmethylsulfinyl)acetic acid Chemical compound OC(=O)CS(=O)CC1=CC=CO1 BMFMTNROJASFBW-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- YSUHBROHWRSYSF-UHFFFAOYSA-N 2-[3-[carboxy(hydroxy)methyl]phenyl]-2-hydroxyacetic acid Chemical compound OC(=O)C(O)C1=CC=CC(C(O)C(O)=O)=C1 YSUHBROHWRSYSF-UHFFFAOYSA-N 0.000 description 1
- FKLAJCGHOJXZRK-UHFFFAOYSA-N 2-[4-[carboxy(hydroxy)methyl]phenyl]-2-hydroxyacetic acid Chemical compound OC(=O)C(O)C1=CC=C(C(O)C(O)=O)C=C1 FKLAJCGHOJXZRK-UHFFFAOYSA-N 0.000 description 1
- WREVCRYZAWNLRZ-UHFFFAOYSA-N 2-allyl-6-methyl-phenol Chemical compound CC1=CC=CC(CC=C)=C1O WREVCRYZAWNLRZ-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- HCUZVMHXDRSBKX-UHFFFAOYSA-N 2-decylpropanedioic acid Chemical compound CCCCCCCCCCC(C(O)=O)C(O)=O HCUZVMHXDRSBKX-UHFFFAOYSA-N 0.000 description 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- PGJXFACHLLIKFG-UHFFFAOYSA-N 2-methyl-6-phenylphenol Chemical compound CC1=CC=CC(C=2C=CC=CC=2)=C1O PGJXFACHLLIKFG-UHFFFAOYSA-N 0.000 description 1
- NXSQQKKFGJHACS-UHFFFAOYSA-N 2-methyl-6-propylphenol Chemical compound CCCC1=CC=CC(C)=C1O NXSQQKKFGJHACS-UHFFFAOYSA-N 0.000 description 1
- WMRCTEPOPAZMMN-UHFFFAOYSA-N 2-undecylpropanedioic acid Chemical compound CCCCCCCCCCCC(C(O)=O)C(O)=O WMRCTEPOPAZMMN-UHFFFAOYSA-N 0.000 description 1
- YMTYZTXUZLQUSF-UHFFFAOYSA-N 3,3'-Dimethylbisphenol A Chemical compound C1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=CC=2)=C1 YMTYZTXUZLQUSF-UHFFFAOYSA-N 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- NMSZFQAFWHFSPE-UHFFFAOYSA-N 3-(oxiran-2-ylmethoxycarbonyl)but-3-enoic acid Chemical compound OC(=O)CC(=C)C(=O)OCC1CO1 NMSZFQAFWHFSPE-UHFFFAOYSA-N 0.000 description 1
- BKFXSOCDAQACQM-UHFFFAOYSA-N 3-chlorophthalic acid Chemical compound OC(=O)C1=CC=CC(Cl)=C1C(O)=O BKFXSOCDAQACQM-UHFFFAOYSA-N 0.000 description 1
- DRNBTKBRWOSYSD-UHFFFAOYSA-N 3-ethyl-2,6-dimethylphenol Chemical compound CCC1=CC=C(C)C(O)=C1C DRNBTKBRWOSYSD-UHFFFAOYSA-N 0.000 description 1
- KBFJHOCTSIMQKL-UHFFFAOYSA-N 3-methoxycarbonylbut-3-enoic acid Chemical compound COC(=O)C(=C)CC(O)=O KBFJHOCTSIMQKL-UHFFFAOYSA-N 0.000 description 1
- AYKYXWQEBUNJCN-UHFFFAOYSA-N 3-methylfuran-2,5-dione Chemical compound CC1=CC(=O)OC1=O AYKYXWQEBUNJCN-UHFFFAOYSA-N 0.000 description 1
- KFIRODWJCYBBHY-UHFFFAOYSA-N 3-nitrophthalic acid Chemical compound OC(=O)C1=CC=CC([N+]([O-])=O)=C1C(O)=O KFIRODWJCYBBHY-UHFFFAOYSA-N 0.000 description 1
- WVDRSXGPQWNUBN-UHFFFAOYSA-N 4-(4-carboxyphenoxy)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1OC1=CC=C(C(O)=O)C=C1 WVDRSXGPQWNUBN-UHFFFAOYSA-N 0.000 description 1
- LABJFIBQJFPXHZ-UHFFFAOYSA-N 4-(carboxymethoxy)benzoic acid Chemical compound OC(=O)COC1=CC=C(C(O)=O)C=C1 LABJFIBQJFPXHZ-UHFFFAOYSA-N 0.000 description 1
- DMEDOWYXHVUPMO-UHFFFAOYSA-N 4-(carboxymethyl)benzoic acid Chemical compound OC(=O)CC1=CC=C(C(O)=O)C=C1 DMEDOWYXHVUPMO-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 239000004358 Butane-1, 3-diol Substances 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000005749 Copper compound Substances 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 229940048053 acrylate Drugs 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- AOJOEFVRHOZDFN-UHFFFAOYSA-N benzyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1=CC=CC=C1 AOJOEFVRHOZDFN-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000006085 branching agent Substances 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical class C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- GBRBMTNGQBKBQE-UHFFFAOYSA-L copper;diiodide Chemical compound I[Cu]I GBRBMTNGQBKBQE-UHFFFAOYSA-L 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 description 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 1
- FOTKYAAJKYLFFN-UHFFFAOYSA-N decane-1,10-diol Chemical compound OCCCCCCCCCCO FOTKYAAJKYLFFN-UHFFFAOYSA-N 0.000 description 1
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 description 1
- ZWWQRMFIZFPUAA-UHFFFAOYSA-N dimethyl 2-methylidenebutanedioate Chemical compound COC(=O)CC(=C)C(=O)OC ZWWQRMFIZFPUAA-UHFFFAOYSA-N 0.000 description 1
- LDCRTTXIJACKKU-ARJAWSKDSA-N dimethyl maleate Chemical compound COC(=O)\C=C/C(=O)OC LDCRTTXIJACKKU-ARJAWSKDSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- DZBOAIYHPIPCBP-UHFFFAOYSA-L magnesium;2-methylprop-2-enoate Chemical compound [Mg+2].CC(=C)C([O-])=O.CC(=C)C([O-])=O DZBOAIYHPIPCBP-UHFFFAOYSA-L 0.000 description 1
- DWLAVVBOGOXHNH-UHFFFAOYSA-L magnesium;prop-2-enoate Chemical compound [Mg+2].[O-]C(=O)C=C.[O-]C(=O)C=C DWLAVVBOGOXHNH-UHFFFAOYSA-L 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- NKHAVTQWNUWKEO-IHWYPQMZSA-N methyl hydrogen fumarate Chemical compound COC(=O)\C=C/C(O)=O NKHAVTQWNUWKEO-IHWYPQMZSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- ABMFBCRYHDZLRD-UHFFFAOYSA-N naphthalene-1,4-dicarboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=C(C(O)=O)C2=C1 ABMFBCRYHDZLRD-UHFFFAOYSA-N 0.000 description 1
- DFFZOPXDTCDZDP-UHFFFAOYSA-N naphthalene-1,5-dicarboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1C(O)=O DFFZOPXDTCDZDP-UHFFFAOYSA-N 0.000 description 1
- JSKSILUXAHIKNP-UHFFFAOYSA-N naphthalene-1,7-dicarboxylic acid Chemical compound C1=CC=C(C(O)=O)C2=CC(C(=O)O)=CC=C21 JSKSILUXAHIKNP-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 description 1
- 229940065472 octyl acrylate Drugs 0.000 description 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- GYDSPAVLTMAXHT-UHFFFAOYSA-N pentyl 2-methylprop-2-enoate Chemical compound CCCCCOC(=O)C(C)=C GYDSPAVLTMAXHT-UHFFFAOYSA-N 0.000 description 1
- ULDDEWDFUNBUCM-UHFFFAOYSA-N pentyl prop-2-enoate Chemical compound CCCCCOC(=O)C=C ULDDEWDFUNBUCM-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- QIWKUEJZZCOPFV-UHFFFAOYSA-N phenyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1=CC=CC=C1 QIWKUEJZZCOPFV-UHFFFAOYSA-N 0.000 description 1
- WRAQQYDMVSCOTE-UHFFFAOYSA-N phenyl prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1 WRAQQYDMVSCOTE-UHFFFAOYSA-N 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000088 plastic resin Substances 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 229920003225 polyurethane elastomer Polymers 0.000 description 1
- LLLCSBYSPJHDJX-UHFFFAOYSA-M potassium;2-methylprop-2-enoate Chemical compound [K+].CC(=C)C([O-])=O LLLCSBYSPJHDJX-UHFFFAOYSA-M 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229940047670 sodium acrylate Drugs 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- SONHXMAHPHADTF-UHFFFAOYSA-M sodium;2-methylprop-2-enoate Chemical compound [Na+].CC(=C)C([O-])=O SONHXMAHPHADTF-UHFFFAOYSA-M 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- SFXOHDOEOSCUCT-UHFFFAOYSA-N styrene;hydrochloride Chemical compound Cl.C=CC1=CC=CC=C1 SFXOHDOEOSCUCT-UHFFFAOYSA-N 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 150000003739 xylenols Chemical class 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- XKMZOFXGLBYJLS-UHFFFAOYSA-L zinc;prop-2-enoate Chemical compound [Zn+2].[O-]C(=O)C=C.[O-]C(=O)C=C XKMZOFXGLBYJLS-UHFFFAOYSA-L 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、ポリフェニレンエーテル樹脂、ポリエステル
樹脂、ポリカーボネート樹脂および、変性ポリスチレン
系重合体からなる、機械的物性。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to mechanical properties of polyphenylene ether resins, polyester resins, polycarbonate resins, and modified polystyrene polymers.
耐熱性、衝撃強度および成形加工性に優れた熱可塑性樹
脂組成物に関する。これらは自動車用部品。This invention relates to a thermoplastic resin composition with excellent heat resistance, impact strength, and moldability. These are automotive parts.
ハウジングなどに使用される。Used for housing, etc.
［従来の技術および問題点］
ボリフヱニレンエーテル樹脂は、耐熱性２機械的強度１
寸法安定性、電気的性質などに優れているが、耐溶剤性
や成形加工性が劣るため、この樹脂単独で用いられるこ
とは少なかった。一方、ポリエステル樹脂は１機械的強
度、電気的性質、酎溶剤性などに優れており、各種分野
で利用されているが、耐熱性や衝撃強度に劣るため、用
途に制限を受けることがあった。[Prior art and problems] Polyphenylene ether resin has a heat resistance of 2 and a mechanical strength of 1.
Although it has excellent dimensional stability and electrical properties, it has poor solvent resistance and moldability, so it has rarely been used alone. On the other hand, polyester resin has excellent mechanical strength, electrical properties, and solvent resistance, and is used in a variety of fields, but its applications have been limited due to its inferior heat resistance and impact strength. .
従来、ポリフェニレンエーテル樹脂とポリエステル樹脂
の長所を生かした樹脂組成物を作る目的で、両樹脂を溶
融混合する試みが数多く行なわれている（特開昭４９−
７５６６２号公報、特開昭５９−１５９８４７号公報な
ど）。In the past, many attempts have been made to melt and mix polyphenylene ether resins and polyester resins in order to make resin compositions that take advantage of their advantages (Japanese Patent Application Laid-Open No. 1983-1972).
75662, JP-A-59-159847, etc.).
しかし１両樹脂を溶融混合した樹脂組成物の成形加工性
はポリフェニレンエーテル樹脂に比べると改良されてい
るが、両樹脂の分散性が悪いため、機械的強度や耐熱性
などはｒ４４Ｊ！ｌ脂の混合割合から予想される値より
も悪いものしか得られていない。However, although the molding processability of a resin composition obtained by melt-mixing both resins is improved compared to polyphenylene ether resin, due to the poor dispersibility of both resins, the mechanical strength and heat resistance are only r44J! The results obtained were worse than expected from the mixing ratio of fat.
また、特開昭６０−２６０６４９号公報、特開昭６２−
２７４５７号公報などでは、両樹脂の分散性が改良され
た組成物を得る目的で、両樹脂を溶融混合する際、エポ
キシ基を有するスチレン系重合体を添加する方法が開示
されている。この方法で得られる樹脂組成物の機械的強
度や耐熱性はそれほど高くない。Also, JP-A-60-260649, JP-A-62-
Publication No. 27457 and the like disclose a method of adding a styrene polymer having an epoxy group when melt-mixing both resins in order to obtain a composition with improved dispersibility of both resins. The mechanical strength and heat resistance of the resin composition obtained by this method are not so high.
本発明の目的は、ポリフェニレンエーテル樹脂とポリエ
ステル樹脂の長所を生かした、機械的強度、＋ｉｔ熱性
、衝撃強度および成形加工性に優れた熱可塑性樹脂組成
物を提供することにある。An object of the present invention is to provide a thermoplastic resin composition that takes advantage of the advantages of polyphenylene ether resin and polyester resin and has excellent mechanical strength, thermal properties, impact strength, and moldability.
［問題点を解決するための手段］
本発明の目的を解決するため、鋭意検ル１した結果、ポ
リフェニレンエーテル樹脂とポリエステル樹脂からなる
混合物に、特定量のポリカーボネート樹脂と変性ポリス
チレン系重合体を溶融混練することにより、本発明の目
的の熱ｎ（塑性樹脂組成物を得ることを見いだした。[Means for Solving the Problems] In order to solve the object of the present invention, as a result of extensive research, we melted a specific amount of polycarbonate resin and modified polystyrene polymer into a mixture consisting of polyphenylene ether resin and polyester resin. It has been found that the objective plastic resin composition of the present invention can be obtained by kneading.
すなわち、本発明の目的は、ポリフェニレンエーテル樹
脂１０〜９０ｉ重量部および、ポリエステル樹脂１０〜
９０重量部からなる混合物１００重量部に対して、ポリ
カーボネート樹脂１０〜ｌＯＯ重量部および変性ポリス
チレン系重合体１〜３０重量部を加えることにより達成
できる。That is, the object of the present invention is to combine 10 to 90 parts by weight of polyphenylene ether resin and 10 to 90 parts by weight of polyester resin.
This can be achieved by adding 10 to 100 parts by weight of a polycarbonate resin and 1 to 30 parts by weight of a modified polystyrene polymer to 100 parts by weight of a mixture consisting of 90 parts by weight.
ポリフェニレンエーテル樹脂とポリエステル樹脂とを溶
融混合した混合物は、ポリカーボネート樹脂あるいは変
性ポリスチレン系重合体をそれぞれ単独で添加した場合
には、機械的強度、衝撃強度や耐熱性はほとんど改善さ
れない、しかし、ポリフェニレンエーテル樹脂とポリエ
ステル樹脂を溶融混合した混合物に、ポリカーボネート
樹脂および変性ポリスチレン系重合体の両者を併用する
と得られる樹脂混合物の分散性が向上し、機械的強度、
衝撃強度および耐熱性などが大幅に改善される。このこ
とは本発明の大きな特徴である。When a polyphenylene ether resin and a polyester resin are melt-mixed, the mechanical strength, impact strength, and heat resistance are hardly improved when a polycarbonate resin or a modified polystyrene polymer is added alone. When both a polycarbonate resin and a modified polystyrene polymer are used in combination with a melt-mixed mixture of a resin and a polyester resin, the dispersibility of the resulting resin mixture improves, and mechanical strength and
Impact strength and heat resistance are greatly improved. This is a major feature of the present invention.
本発明で使用するポリフェニレンエーテル樹脂は、下記
−服代（１）
で示される。これらの樹脂は次のフェノール化合物から
得られる。具体例としては、２．６−ジメチルフェノー
ル、２．６−ジエチルフェノール、２−メチル−６−エ
チルフェノール、２−メチル−６−アリルフェノール、
２−メチル−６−フェニルフェノール、 ２．８−ジ
フェニルフェノール。The polyphenylene ether resin used in the present invention is represented by the following formula (1). These resins are obtained from the following phenolic compounds. Specific examples include 2.6-dimethylphenol, 2.6-diethylphenol, 2-methyl-6-ethylphenol, 2-methyl-6-allylphenol,
2-methyl-6-phenylphenol, 2,8-diphenylphenol.
２．６−ジメチルフェノール、２−メチル−６−プロピ
ルフェノール、 ２，３．６−トリエチルフェノール
、２．３−ジメチル−６−エチルフェノール。2.6-dimethylphenol, 2-methyl-6-propylphenol, 2,3.6-triethylphenol, 2.3-dimethyl-6-ethylphenol.
２．３．１３− トリエチルフェノール、 ２，３．
１３− トリプロピルフェノール、２，６−シメチルー
３−エチルフェノール、２．６−シメチルー３−プロピ
ルフェノールなどが挙げられる。これらのフェノール化
合物は、単独でも、併用しても使用することができる。2.3.13-triethylphenol, 2,3.
Examples include 13-tripropylphenol, 2,6-dimethyl-3-ethylphenol, and 2,6-dimethyl-3-propylphenol. These phenol compounds can be used alone or in combination.
最も好ましいポリフェニレンエーテル樹脂としては、
２，８−ジメチルフェノールから得られるポリフェニレ
ンエーテル、および２．６−ジメチルフェノール、 ２
，３．８− ）ジメチルフェノール。The most preferred polyphenylene ether resin is
Polyphenylene ether obtained from 2,8-dimethylphenol and 2,6-dimethylphenol, 2
, 3.8-) dimethylphenol.
２．８−ジフェニルフェノールの共重合によって得られ
るポリフェニレンエーテルである。使用されるポリフェ
ニレンエーテル系樹脂の極限粘度［η］ （クロロホル
ム０．５％溶液、３０℃）は０．３から３．０が好まし
い、また、ポリフェニレンエーテルにスチレン系単量体
が共重合したものや、スチレン系ポリマーを混合したも
のも使用できる。スチレン系単量体のグラフト共重合や
スチレン系ポリマーの添加により成形加工性は向上する
が、耐熱性や機械的強度が低下するため、本発明で使用
する場合、ポリフェニレンエーテル樹脂１００重量部に
対してスチレン系樹脂は３０重量部以下が好ましい０本
発明でのポリフェニレンエーテル樹脂の使用量は１０〜
９０重量部、より好ましくは３０〜７０重量部である。It is a polyphenylene ether obtained by copolymerization of 2.8-diphenylphenol. The intrinsic viscosity [η] (0.5% chloroform solution, 30°C) of the polyphenylene ether resin used is preferably 0.3 to 3.0, and polyphenylene ether copolymerized with a styrene monomer. or a mixture of styrene polymers can also be used. Graft copolymerization of styrene monomers or addition of styrene polymers improves moldability, but heat resistance and mechanical strength decrease. The amount of styrene resin used is preferably 30 parts by weight or less. The amount of polyphenylene ether resin used in the present invention is 10 to 30 parts by weight.
It is 90 parts by weight, more preferably 30 to 70 parts by weight.
使用量が１０重量部より少なくなると耐熱性が悪くなり
、使用量が９０重量部より多くなると、成形加工性が悪
くなり好ましくない。If the amount used is less than 10 parts by weight, heat resistance will deteriorate, and if the amount used is more than 90 parts by weight, moldability will deteriorate, which is not preferable.
本発明で使用するポリエステル樹脂とは、分子の主鎖に
エステル結合を持っている高分子量の熱可塑性樹脂であ
り、ジカルボン酸またはその誘導体と２価アルコールま
たは２価フェノール化合物とから得られる重縮合化合物
、ジカルボン酸またはその誘導体と環状エーテル化合物
とから得られる重縮合化合物、ジカルボン酸の金属塩と
ジハロゲン化合物とから得られる重縮合化合物、環状エ
ーテル化合物の開環重合物などが挙げられる。The polyester resin used in the present invention is a high molecular weight thermoplastic resin having an ester bond in the main chain of the molecule, and is a polycondensation resin obtained from a dicarboxylic acid or its derivative and a dihydric alcohol or a dihydric phenol compound. Examples include a polycondensation compound obtained from a dicarboxylic acid or a derivative thereof and a cyclic ether compound, a polycondensation compound obtained from a metal salt of a dicarboxylic acid and a dihalogen compound, and a ring-opening polymer of a cyclic ether compound.
ここで、ジカルボン酸の誘導体とは酸無水物、エステル
化物あるいは酸三塩化物である。ジカルボン酸は脂肪族
であっても芳香族であってもよく、芳香族ジカルボン酸
としては、例えば、テレフタル酸、イソフタル酸、フタ
ル醜、クロルフタル醜。Here, the dicarboxylic acid derivative is an acid anhydride, an ester, or an acid trichloride. Dicarboxylic acids may be aliphatic or aromatic, and examples of aromatic dicarboxylic acids include terephthalic acid, isophthalic acid, phthalic acid, and chlorphthalic acid.
ニトロフタル酸、ｐ−カルボキシルフェニル酢酸。Nitrophthalic acid, p-carboxylphenylacetic acid.
ｍ−フェニレンジグリコール酸、ｐ−フェニレンジグリ
コール酸、ジフェニルジ酢酸、ジフェニル−ｐ、ｐ’−
ジカルボン酸、ジフェニル−■、ｍ−ジカルボン酸、ジ
フェニル−４，４°−ジ酢酸、ジフェニルメタン−ｐ、
ｐ’−ジカルボン酸、ジフェニルエタン−ｍ、ｍ’−ジ
カルボン酸、スチルベンジルカルボン酸、ジフェニルブ
タン−ｐ、ｐ’−ジカルボン酸。m-phenylene diglycolic acid, p-phenylene diglycolic acid, diphenyldiacetic acid, diphenyl-p, p'-
dicarboxylic acid, diphenyl-■, m-dicarboxylic acid, diphenyl-4,4°-diacetic acid, diphenylmethane-p,
p'-dicarboxylic acid, diphenylethane-m,m'-dicarboxylic acid, stilbenzylcarboxylic acid, diphenylbutane-p,p'-dicarboxylic acid.
ベンゾフェノン−４，４°−ジカルボン酸、ナフタリン
−１，４−ジカルボン酸、ナフタリン−１，５−ジカル
ボン酸、ナフタリン−２，８−ジカルボン酸。Benzophenone-4,4°-dicarboxylic acid, naphthalene-1,4-dicarboxylic acid, naphthalene-1,5-dicarboxylic acid, naphthalene-2,8-dicarboxylic acid.
ナフタリン−２，７−ジカルポ゛ン酸、Ｐ−カルボキシ
フェノキシ酢酸、Ｐ−カルボキシフェノキシブチル酸、
１．２−ジフェノキシプロパン−ｐ、ｐ’−ジカルボン
酸、 １．４−ジフェノキシプロパン−ｐ、Ｐ−ジカ
ルボン酸、ｌ、５−ジフェノキシペンタン−ｐ、ｐ’−
ジカルボン醜、ｌ、＋３−ジフェノキシヘキサン−ｐ、
ｐ−ジカルボンＭ、ｐ−（ｐ−カルボキシフェノキシ）
安息香酸、ｌ、２−ビス（２−メトキシフェノキシ）−
エタン−ｐ、ｐ’−ジカルボン酸。naphthalene-2,7-dicarponic acid, P-carboxyphenoxyacetic acid, P-carboxyphenoxybutyric acid,
1.2-diphenoxypropane-p,p'-dicarboxylic acid, 1.4-diphenoxypropane-p,p-dicarboxylic acid, l,5-diphenoxypentane-p,p'-
Dicarbonate, l, +3-diphenoxyhexane-p,
p-dicarboxylic M, p-(p-carboxyphenoxy)
Benzoic acid, l, 2-bis(2-methoxyphenoxy)-
Ethane-p,p'-dicarboxylic acid.
１．３−ビス（２−メトキシフェノキシ）プロパン−ｐ
、ｐ’−ジカルボン酸、ｌ、４−ビス（２−メトキシフ
ェノキシ）ブタン−ｐ、ｐ’−ジカルボン酸。1.3-bis(2-methoxyphenoxy)propane-p
, p'-dicarboxylic acid, l,4-bis(2-methoxyphenoxy)butane-p,p'-dicarboxylic acid.
１．５−ビス（２−メトキシフェノキシ）−３−オキシ
ペンタン−ｐ、ｐ’−ジカルボン酸などを挙げることが
でき、また脂肪族ジカルボン酸としては、例えば、シュ
ウ酸、コハク酸、アジピン酸、コルク酸 −２ゼライン
酸、セバシン酸、ドデカンジカルボン酸、ウンデカンジ
カルボン酸、マレイン酸。Examples of aliphatic dicarboxylic acids include 1,5-bis(2-methoxyphenoxy)-3-oxypentane-p,p'-dicarboxylic acid, and examples of aliphatic dicarboxylic acids include oxalic acid, succinic acid, adipic acid, Corkic acid-2gelaic acid, sebacic acid, dodecanedicarboxylic acid, undecanedicarboxylic acid, maleic acid.
フマル酸などが挙げられる。好ましいジカルボン酸の例
は、芳香族ジカルボン酸類であり、さらに好ましくは、
テレフタル酸、イソフタル酸あるいはフタル酸を挙げる
ことができる。Examples include fumaric acid. Examples of preferred dicarboxylic acids are aromatic dicarboxylic acids, and more preferably,
Mention may be made of terephthalic acid, isophthalic acid or phthalic acid.
２価アルコールとしては、例えば、エチレングリコール
、トリメチレングリコール、ブタン−１，３−ジオール
、ブタン−１，４−ジオール、２．２−ジメチルプロパ
ン−１，４−ジオール、ｃｉｓ−２−ブテン−１，４−
ジオール、テトラメチレングリコール、ペンタメチレン
グリコール、ヘキサメチレングリコール、オクタメチレ
ングリコール、デカメチレングリコール、シクロヘキサ
ンジメタツールなどが挙げられる。好ましい２価アルコ
ールの例は、エチレングリコール、ブタン−１，４−ジ
オール、あるいはシクロヘキサンジメタツールである。Examples of dihydric alcohols include ethylene glycol, trimethylene glycol, butane-1,3-diol, butane-1,4-diol, 2,2-dimethylpropane-1,4-diol, and cis-2-butene-diol. 1,4-
Examples include diol, tetramethylene glycol, pentamethylene glycol, hexamethylene glycol, octamethylene glycol, decamethylene glycol, cyclohexane dimetatool, and the like. Examples of preferred dihydric alcohols are ethylene glycol, butane-1,4-diol, or cyclohexane dimetatool.
２価フェノール化合物の例としては、例えば、ヒドロキ
ノン、レゾルシノール、ビスフェノールＡなどを挙げる
ことができる。前記環状エーテル化合物としては、エチ
レンオキサイド。Examples of dihydric phenol compounds include hydroquinone, resorcinol, bisphenol A, and the like. The cyclic ether compound is ethylene oxide.
プロピレンオキサイドを挙げることができ、また前記環
状エステル化合物としては、δ−バレロラクトンやε−
カプロラクトンを挙げることができる。ジカルボン酸金
属塩と反応させるジハロゲン化合物とは、上記２価アル
コールまたは２価フェノール化合物の２つの水酸基を塩
素または臭素といったハロゲン原子で置換することによ
って得られる化合物である。使用されるポリエステル樹
脂の極限粘度（ｍ−クレゾール１％溶液、２５℃）は、
０．８から３．０が好ましい。Examples of the cyclic ester compound include δ-valerolactone and ε-
Mention may be made of caprolactone. The dihalogen compound to be reacted with the dicarboxylic acid metal salt is a compound obtained by replacing two hydroxyl groups of the dihydric alcohol or dihydric phenol compound with halogen atoms such as chlorine or bromine. The intrinsic viscosity of the polyester resin used (1% m-cresol solution, 25°C) is:
0.8 to 3.0 is preferred.
本発明でのポリエステル樹脂の使用量は１０〜９０重量
部である。使用量が１０重量部より少なくなると、成形
加工性が悪くなり、９０重量部より多くなると耐熱性が
悪くなり好ましくない。The amount of polyester resin used in the present invention is 10 to 90 parts by weight. If the amount used is less than 10 parts by weight, moldability will deteriorate, and if it exceeds 90 parts by weight, heat resistance will deteriorate, which is not preferable.
本発明で使用するポリカーボネート樹脂は下記−服代（
２）
であり、２価フェノールとカーボネート前駆体との溶融
法あるいは溶液法で製造される。ここで、２価フェノー
ルとしては、例えば、ビスフェノールＡ （２，２−ビ
ス（４−ヒドロキシフェニル）フロパン）、ビス（４−
ヒドロキシジフェニル）メタン） 、 １．１−ビ
ス（４−ヒドロキシフェニル）。The polycarbonate resin used in the present invention is as follows:
2) It is produced by a melt method or a solution method using dihydric phenol and a carbonate precursor. Here, as the dihydric phenol, for example, bisphenol A (2,2-bis(4-hydroxyphenyl)furopane), bis(4-
hydroxydiphenyl)methane), 1.1-bis(4-hydroxyphenyl).
エタン） 、 ２．２−ビス（４−ヒドロキシ−３
−メチルフェニル）プロパン）などを挙げることができ
、好ましい２価フェノールはビス（４−ヒドロキシフェ
ニル）アルカン系化合物、特にビスフェノールＡである
。２価フェノールは単独で、あるいは２種以上混合して
使用することができる。ethane), 2,2-bis(4-hydroxy-3
-methylphenyl)propane), and the preferred dihydric phenol is a bis(4-hydroxyphenyl)alkane compound, particularly bisphenol A. Dihydric phenols can be used alone or in combination of two or more.
また、カーボネート前駆体としては、例えば、ハロホル
メートなどを挙げることができる０代表的な例としては
、ホスゲン、ジフェニルカーボネート、２価フェノール
のジハロホルメートおよびこれらの混合物を挙げること
ができる。芳香族ポリカーボネートの製造に際しては、
適当な分子量調整剤９分岐剤触媒なども使用できる。極
限粘度（塩化メチレン０．５％溶液、２０°Ｃ）は、０
．１から１．３が好ましい。Examples of carbonate precursors include haloformates. Representative examples include phosgene, diphenyl carbonate, dihaloformates of dihydric phenols, and mixtures thereof. When manufacturing aromatic polycarbonate,
Appropriate molecular weight regulators, 9-branching agent catalysts, etc. can also be used. Intrinsic viscosity (0.5% methylene chloride solution, 20°C) is 0
．． 1 to 1.3 is preferred.
末完ＩＪＪで使用される変性ポリスチレン系重合体とは
、スチレン、メチルスチレン、ビニルキシレン、クロル
スチレン、ジクロルスチレン、ブロムスチレン、ジブロ
ムスチレン、ｐ−ｔ−ブチルスチレン、エチルスチレン
、ビニルナフタレンなどスチレン糸上ツマ−を主たる構
成成分とするポリマーと、カルボン酸基、カルボン酸エ
ステル基。The modified polystyrene polymers used in finished IJJ include styrene, methylstyrene, vinylxylene, chlorstyrene, dichlorostyrene, bromustyrene, dibromstyrene, pt-butylstyrene, ethylstyrene, vinylnaphthalene, etc. A polymer whose main constituents are styrene threads, carboxylic acid groups, and carboxylic acid ester groups.
カルボン酸金属塩基、酸無水物基、エポキシ基から選ば
れた一種以上の官能基を有するモノマーとの反応により
、生成したポリマーである。このポリマーには、ブタジ
ェン、ブテン、イソプレン。It is a polymer produced by reaction with a monomer having one or more functional groups selected from carboxylic acid metal bases, acid anhydride groups, and epoxy groups. This polymer includes butadiene, butene, and isoprene.
ビニルシアン化合物、アクリル酸アルキルエステル、メ
タクリル酸アルキルエステル、マレイミド系化合物など
が共重合していてもよい。A vinyl cyanide compound, an acrylic acid alkyl ester, a methacrylic acid alkyl ester, a maleimide compound, etc. may be copolymerized.
カルボン酸基を有するモノマーの具体例としては、アク
リル酸、メタクリル酸、マレイン酸、フマル酸、イタコ
ン酸、クロトン酸、メチルマレイン酸、メチルフマル酸
、メタコン酸、シトラコン醜、グルタコン酸などのα、
β−不飽和酸がある。Specific examples of monomers having a carboxylic acid group include acrylic acid, methacrylic acid, maleic acid, fumaric acid, itaconic acid, crotonic acid, methylmaleic acid, methylfumaric acid, methaconic acid, citraconic acid, glutaconic acid, etc.
There are β-unsaturated acids.
特に好ましいものには、アクリル酸、メタクリル酸、マ
レイン酸である。Particularly preferred are acrylic acid, methacrylic acid, and maleic acid.
カルボン酸エステル基を有するモノマーの例としては、
メチルアクリレート、エチルアクリレート、プロピルア
クリレート、ブチルアクリレート。Examples of monomers having carboxylic acid ester groups include:
Methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate.
アミルアクリレート、オクチルアクリレート、２−エチ
ルへキシルアクリレート、シクロヘキシルアクリレート
、ドデシルアクリレート、オクタドデシルアクリレート
、フェニルアクリレート、ヒドロキシエチルアクリ１／
−ト、メチルメタクリレート、エチルメタクリレート、
ブチルメタクリレート、アミルメタクリレート、ヘキシ
ルメタクリレート、オクチルメタクリレート、２−エチ
ルヘキシルメタクリレート、シクロヘキシルメタクリレ
ート、ドデシルメタクリレート、フェニルメタクリレー
ト、ベンジルメタクリレート、ヒドロキシエチルメタク
リレート、マレイン酸水素メチル、マレイン酸ジメチル
、イタコン酸水素メチル。Amyl acrylate, octyl acrylate, 2-ethylhexyl acrylate, cyclohexyl acrylate, dodecyl acrylate, octadodecyl acrylate, phenyl acrylate, hydroxyethyl acrylate 1/
-t, methyl methacrylate, ethyl methacrylate,
Butyl methacrylate, amyl methacrylate, hexyl methacrylate, octyl methacrylate, 2-ethylhexyl methacrylate, cyclohexyl methacrylate, dodecyl methacrylate, phenyl methacrylate, benzyl methacrylate, hydroxyethyl methacrylate, methyl hydrogen maleate, dimethyl maleate, methyl hydrogen itaconate.
イタコン酸ジメチルなどのα、β−不飽和カルポン酸の
誘導体がある。これらの内で好ましいものには、メチル
アクリレート、メチルメタクリレート、エチルアクリレ
ート、エチルメタクリレートなどである。There are derivatives of α,β-unsaturated carboxylic acids such as dimethyl itaconate. Among these, preferred are methyl acrylate, methyl methacrylate, ethyl acrylate, and ethyl methacrylate.
カルボン酸金属塩基を有する七ツマ−の例としては、ナ
トリウムメタクリレート、カリウムメタクリレート、マ
グネシウムメタクリレート、メタクリル酸亜鉛、ナトリ
ウムアクリレート、マグネシウムアクリレート、アクリ
ル酸亜鉛などのα。Examples of heptads having carboxylic acid metal bases include sodium methacrylate, potassium methacrylate, magnesium methacrylate, zinc methacrylate, sodium acrylate, magnesium acrylate, zinc acrylate, and the like.
β−不飽和カルポン酸の金属塩がある。酸無水物基を有
する七ツマ−としては、無水マレイン酸。There are metal salts of β-unsaturated carboxylic acids. Maleic anhydride is an example of a hexamer having an acid anhydride group.
無水イタコン酸、無水シトラコン酸、エンドビシクロ−
［２，２，１１−５−へブテン−２，３−ジカルボン酸
、エンドビシクロ−［２，２，１１−５−ヘブテン−２
，３−無水ジカルボ７酸などのα、β−不飽和カルポン
酸の無水物がある。これらの内で好ましいものには、無
水マレイン酸、無水イタコン酸などがある。エポキシ基
を有する七ツマ−としては。Itaconic anhydride, citraconic anhydride, endobicyclo-
[2,2,11-5-hebutene-2,3-dicarboxylic acid, endobicyclo-[2,2,11-5-hebutene-2
, 3-dicarboxylic anhydride and other α,β-unsaturated carboxylic acid anhydrides. Among these, preferable ones include maleic anhydride and itaconic anhydride. As a hexamer having an epoxy group.
アクリル酸グリシジル、メタクリル酸グリシジル。Glycidyl acrylate, glycidyl methacrylate.
エタクリル酸グリシジル、イタコン酸グリシジル。Glycidyl ethacrylate, glycidyl itaconate.
アリルグリシジルエーテル、ビニールグリシジルエーテ
ルなどのエポキシ基含有不飽和化合物がある。これらの
内で好ましいものには、アクリル酸グリシジル、メタク
リル酸グリシジル、アリルグリシジルエーテルなどがあ
る。There are unsaturated compounds containing epoxy groups such as allyl glycidyl ether and vinyl glycidyl ether. Preferred among these include glycidyl acrylate, glycidyl methacrylate, and allyl glycidyl ether.
これらの変性ポリスチレン系重合体は単独でも。These modified polystyrene polymers can be used alone.
２種類以上を併用することもできる。これらの変性ポリ
スチレン系重合体は、公知のラジカル重合法を利用して
、塊状重合、溶液重合、懸濁重合または乳化重合によっ
て製造できる。また、溶融状態でグラフトさせる場合は
、押出し機、ニーダ−バンバリーミキサ−などの溶融混
合機を用いることにより、比較的短時間に容易に目的の
ものを得ることができる。この共重合体の数平均分子量
は５千〜１５万、より好ましくは２万〜１０万の範囲で
ある。Two or more types can also be used in combination. These modified polystyrene polymers can be produced by bulk polymerization, solution polymerization, suspension polymerization, or emulsion polymerization using known radical polymerization methods. Further, when grafting is performed in a molten state, the desired product can be easily obtained in a relatively short time by using a melt mixer such as an extruder or a kneader/Banbury mixer. The number average molecular weight of this copolymer is in the range of 5,000 to 150,000, more preferably 20,000 to 100,000.
カルボン酸基、カルボン酸エステル基、カルボン酸金属
塩、酸無水物基およびエポキシ基を有する七ツマ−の反
応量は変性ポリスチレン系重合体の全構成成分に対して
、ｏ、ｏｏｉ〜４０モル％、好ましくは０．０１〜２０
モル％である。これらの七ツマ−の量が０．００１モル
％未満では、本発明で使用するポリフェニレンエーテル
樹脂とポリエステル樹脂との分散性を改善する効果が少
なく、４０モル％より多くなると副反応が起こりやすく
なり、生成する変性ポリスチレン系重合体がゲル化する
ため、ポリフェニレンエーテル樹脂とポリエステル樹脂
との分散が悪くなり、混合物の機械的強度も低下する。The reaction amount of the hexamer having a carboxylic acid group, a carboxylic acid ester group, a carboxylic acid metal salt, an acid anhydride group, and an epoxy group is from o, ooi to 40 mol% based on the total components of the modified polystyrene polymer. , preferably 0.01 to 20
It is mole%. If the amount of these 7-mers is less than 0.001 mol%, the effect of improving the dispersibility of the polyphenylene ether resin and polyester resin used in the present invention is small, and if it exceeds 40 mol%, side reactions are likely to occur. Since the resulting modified polystyrene polymer gels, the dispersion of the polyphenylene ether resin and polyester resin deteriorates, and the mechanical strength of the mixture also decreases.
変性ポリスチレン系重合体の具体例としては、スチレン
・アクリル酸共重合体、スチレン・メタクリル酸・メタ
グリル酸ナトリウム共重合体、スチレン・メタクリル醸
共重合体、スチレン・メチルメタクリレート共重合体、
スチレン・無水マレイン酸共重合体、スチレン・アクリ
ル酸グリシジル共重合体、スチレン拳メタクリル酸グリ
シジル共重合体、スチレン・ブタジェン・無水マレイン
酸共重合体、スチレン・ブタジェン拳メタクリル酸グリ
シジル共重合体、水素化スチレン・ブタジェン・無ホマ
レイン酸へ重合体、水素化スチレン・ブタジェン・メタ
クリル酸グリシジル共重合体。Specific examples of modified polystyrene polymers include styrene/acrylic acid copolymer, styrene/methacrylic acid/sodium methacrylate copolymer, styrene/methacrylate copolymer, styrene/methyl methacrylate copolymer,
Styrene-maleic anhydride copolymer, styrene-glycidyl acrylate copolymer, styrene-glycidyl methacrylate copolymer, styrene-butadiene-maleic anhydride copolymer, styrene-butadiene-glycidyl methacrylate copolymer, hydrogen Polymer of styrene chloride, butadiene, and non-fomaleic acid, hydrogenated styrene, butadiene, and glycidyl methacrylate copolymer.
スチレンφアクリロニトリル・無水マレイン酸共重合物
、スチレン・７クリロニトリル・メタクリル醜グリシジ
ル共重合体、スチレン・アクリロニトリル・ブタジェン
・無水マレイン酸共重合体。Styrene φ acrylonitrile/maleic anhydride copolymer, styrene/7-acrylonitrile/methacrylic ugly glycidyl copolymer, styrene/acrylonitrile/butadiene/maleic anhydride copolymer.
スチレン・アクリロニトリル・ブタジェンｅメタクリル
酸グリシジル共重合体などを挙げることができる。これ
らの重合体は、ブロック共重合体。Examples include styrene/acrylonitrile/butadiene/glycidyl methacrylate copolymer. These polymers are block copolymers.
グラフト共重合体、ランダム共重合体のいずれであって
もよい、なお、本発明の変性ポリスチレン系重合体には
官能基を含まない通常のポリスチレン共重合体を少量含
んでいてもよい。The modified polystyrene polymer of the present invention may be either a graft copolymer or a random copolymer, and the modified polystyrene polymer of the present invention may contain a small amount of a normal polystyrene copolymer containing no functional groups.
本発明で使用するポリカーボネート樹脂および変性ポリ
スチレン系重合体の使用量は、（ａ）ポリフェニレンエ
ーテル系樹脂および（ｂ）ポリエステル樹脂からなる混
合物１００重量部に対して、ポリカーボネート樹脂は５
〜１００重量部、より好ましくは１０〜７０重量部であ
り、変性ポリスチレン系重合体は１〜３０重量部、より
好ましくは３〜２０重量部である。ポリカーボネート樹
脂および変性ポリスチレン系重合体の使用酸が上記下限
より少ないと樹脂同士の分散性が悪くなり、機械的強度
や衝撃強度が低くなり、上記上限より多くなると成形加
工性が悪くなり、好ましくない。The amount of polycarbonate resin and modified polystyrene polymer used in the present invention is 5 parts by weight of the polycarbonate resin per 100 parts by weight of the mixture consisting of (a) polyphenylene ether resin and (b) polyester resin.
The amount of the modified polystyrene polymer is 1 to 100 parts by weight, more preferably 10 to 70 parts by weight, and the amount of the modified polystyrene polymer is 1 to 30 parts by weight, more preferably 3 to 20 parts by weight. If the amount of acid used in polycarbonate resins and modified polystyrene polymers is less than the above lower limit, the dispersibility of the resins will be poor, resulting in lower mechanical strength and impact strength, and if it is more than the above upper limit, moldability will deteriorate, which is not preferable. .
本発明の熱可塑性樹脂組成物には、各種強化材や充填材
、公知のエラストマーの添加が可能である０強化材、充
填材の例としては、ガラスａｍ。Various reinforcing materials, fillers, and known elastomers can be added to the thermoplastic resin composition of the present invention. Examples of reinforcing materials and fillers include glass am.
アスベスト繊維、カーボン繊維、シリカ繊維、シリカ・
アルミナｍｍ、アルミナ繊維、ジルコニア繊維、窒化ホ
ウ素繊維、窒化ケイ素繊維、ホウ素繊維、ステンレス、
アルミニウム、チタン、銅。Asbestos fiber, carbon fiber, silica fiber, silica
Alumina mm, alumina fiber, zirconia fiber, boron nitride fiber, silicon nitride fiber, boron fiber, stainless steel,
Aluminum, titanium, copper.
しんちゅう、マグネシウムなどの金属繊維、およびポリ
アミド、フッ素樹脂、ポリエステル、アクリル樹脂など
の有機質繊維、銅、鉄、ニッケル。Metal fibers such as brass and magnesium, organic fibers such as polyamide, fluororesin, polyester, and acrylic resin, copper, iron, and nickel.
亜鉛、スす、鉛、ステンレス、アルミニウム、金。Zinc, soot, lead, stainless steel, aluminum, gold.
銀などの金属粉末、ヒユームドシリカ、ケイ酸アルミニ
ウム、ガラスピーズ、カーボンブラック、石英粉末、タ
ルク、酸化チタン、酸化鉄、炭酸カルシウム、ケイソウ
土などがある。繊維状物質は特に制限はないが平均繊維
径が５１Ｌｍから５０終ｍ、繊維長が５０終ｍから３０
ｍｍのものが好ましい、これらの強化材、充填材は公知
のシランカップリング剤やチタネート系カップリング剤
で表面処理したものも使用できる。これらの強化材、充
填材は単独でも、２種類以上を併用することもできる。Examples include metal powders such as silver, fumed silica, aluminum silicate, glass beads, carbon black, quartz powder, talc, titanium oxide, iron oxide, calcium carbonate, and diatomaceous earth. There are no particular restrictions on the fibrous material, but the average fiber diameter is from 51 Lm to 50 Lm, and the fiber length is from 50 Lm to 30 Lm.
These reinforcing materials and fillers, which preferably have a diameter of mm, may be surface-treated with a known silane coupling agent or titanate coupling agent. These reinforcing materials and fillers can be used alone or in combination of two or more.
公知のエラストマーの例としては、スチレン−ブタジェ
ンブロック共重合体、水素化スチレン−ブタジェンブロ
ック共重合体、スチレングラフトエチレン−プロピレン
共重合体、ポリブタジェン、ポリイソプレン、ジエン化
合物とビニル芳香族化合物との共重合体、ニトリルゴム
、エチレン−プロピレン共重合体、エチレン−プロピレ
ン−ジエン共重合体（ＥＰＤＭ）、チオコールゴム、ポ
リスルフィドゴム、アクリル酸ゴム。Examples of known elastomers include styrene-butadiene block copolymers, hydrogenated styrene-butadiene block copolymers, styrene-grafted ethylene-propylene copolymers, polybutadiene, polyisoprene, diene compounds and vinyl aromatic compounds. copolymers, nitrile rubber, ethylene-propylene copolymers, ethylene-propylene-diene copolymers (EPDM), thiol rubber, polysulfide rubber, acrylic acid rubber.
ポリウレタンゴム、ブチルゴムとポリエチレンゴムとの
グラフト物、ポリエステルエラストマーボリアミドエラ
ストマーなどが挙げられる。Examples include polyurethane rubber, a graft product of butyl rubber and polyethylene rubber, polyester elastomer, and polyamide elastomer.
本発明の熱可塑性樹脂組成物には、ヒンダードフェノー
ル、ハイドロキノン、ホスファイト類およびこれらの置
換体、ヨウ化銅などの銅化合物などの酸化防止剤や熱安
定剤、レゾルシノール、サリシレート、ベンゾトリアゾ
ール、ベンゾフェノンなどの紫外線吸収剤、ステアリン
酸およびその塩、ステアリルアルコールなどの離型剤、
ハロゲン系、メラミンあるいはシアヌル酸系の難燃剤。The thermoplastic resin composition of the present invention includes hindered phenol, hydroquinone, phosphites and substituted products thereof, antioxidants and heat stabilizers such as copper compounds such as copper iodide, resorcinol, salicylate, benzotriazole, Ultraviolet absorbers such as benzophenone, stearic acid and its salts, mold release agents such as stearyl alcohol,
Halogen-based, melamine or cyanuric acid-based flame retardants.
難燃助剤、ドデシルベンゼンスルホン酸ナトリウム、ポ
リアルキレングリコールなどの帯電防止剤。Antistatic agents such as flame retardant aids, sodium dodecylbenzenesulfonate, and polyalkylene glycols.
結晶化促進剤、染料、顔料などの添加剤を１種類以上添
加することも可能である。It is also possible to add one or more types of additives such as crystallization promoters, dyes, pigments, etc.
また、少量のポリエグーレン、ポリプロピレン。Also small amounts of polyegulene and polypropylene.
エチレン、酢酸ビニル共重合体、ポリアセタール。Ethylene, vinyl acetate copolymer, polyacetal.
ポリスルホンなどの熱Ｏｆ塑性樹脂およびその変性物、
例えば酸およびその誘導体、グリシジルメタアクリレー
トなどのグラフト物や、フェノール樹脂、メラミン樹脂
、シリコーン樹脂、エポキシ樹脂などの熱硬化性樹脂を
添加することもできる。Thermoplastic resins such as polysulfone and modified products thereof,
For example, acids and their derivatives, grafts such as glycidyl methacrylate, and thermosetting resins such as phenol resins, melamine resins, silicone resins, and epoxy resins can also be added.
本発明熱可塑性樹脂組成物の製造方法は、押出機。The method for producing the thermoplastic resin composition of the present invention uses an extruder.
バンバリーミキサ−、ニーダ−などの通常の溶融混練加
工装置によって行うことができ、さらに、用出成形、押
出成形などによって各種用途の成形品に加工することが
できる。This can be carried out using ordinary melt-kneading processing equipment such as a Banbury mixer or a kneader, and furthermore, it can be processed into molded products for various uses by molding, extrusion molding, or the like.
［実施例］ 以下、実施例により本発明をさらに詳細に説明する。[Example] Hereinafter, the present invention will be explained in more detail with reference to Examples.
製造例１
ボリア ニレンエーール
窒素で置換した、酸素吹き込み装置、冷却用コイル、攪
拌機を備えた反応器に、臭化ｍ２′Ｍ３２．２ｇ、ジ−
ｎ−ブチルアミン６６６ｇと、トルエン２４見に２．６
−キシレノール５．２５ｋｇ溶解させたものを混合添加
し、均一溶解させた後、酸素を急激に吹き込みながら反
応容器内部を３０°Ｃに保ったまま９０分間重合を行っ
た０重合読了後、トルエン１８４１を添加し、さらに、
エチレンジアミン四酢酸２０％水溶液を添加し反応を停
止させた。得られた生成混合物を遠心分離し重合体溶解
相を取り山し、攪拌しながらメタノールを徐々に添加し
た０分別した後、乾燥し極限粘度０．５０のポリフェニ
レンエーテル樹脂を得た。Production Example 1 Boria Nylene Ale 32.2 g of bromide m2'M, di-
666g of n-butylamine and 2.6g of toluene
- 5.25 kg of xylenol was mixed and added, and after homogeneous dissolution, polymerization was carried out for 90 minutes while keeping the inside of the reaction vessel at 30°C while rapidly blowing oxygen. After completing the polymerization, toluene 1841 and further,
A 20% aqueous solution of ethylenediaminetetraacetic acid was added to stop the reaction. The resulting product mixture was centrifuged, the polymer dissolved phase was collected, and methanol was gradually added while stirring to separate the mixture into zero fractions, followed by drying to obtain a polyphenylene ether resin having an intrinsic viscosity of 0.50.
製造例２
ポリスチレン １
１￥ｉ！拌機を備えたセパラブルフラスコにスチレン２
１６ｇ、グリシジルメタクリレート２４ｇ、トルエン１
６０ｇ、アゾビスイソブチロニトリル２ｇを仕込み、２
０分間窒素を吹き込みながら攪拌した後、８５℃に保っ
たオイルバス中にセパラブルフラスコを移し、窒素雰囲
気中で６０分間攪拌し、さらにオイルバスを１０５℃に
昇温し、４５分間攪拌し重合を行った。この後セパラブ
ルフラスコをオイルバスより取り山し冷却し、重合液を
強攪拌下でメタノール中に滴下し分別した。Production example 2 Polystyrene 1 1 yen i! Styrene 2 in a separable flask equipped with a stirrer
16g, glycidyl methacrylate 24g, toluene 1
60g, prepare 2g of azobisisobutyronitrile,
After stirring for 0 minutes while blowing nitrogen, the separable flask was transferred to an oil bath kept at 85°C, stirred for 60 minutes in a nitrogen atmosphere, and then the oil bath was heated to 105°C and stirred for 45 minutes to polymerize. I did it. Thereafter, the separable flask was taken out of the oil bath and cooled, and the polymerization liquid was dropped into methanol under strong stirring and separated.
分別後乾燥しエポキシ基を含むスチレン系重合体を得た
。After separation and drying, a styrene polymer containing epoxy groups was obtained.
得たポリスチレン系重合体の分子量はＧＰ（ａｌｌ定で
、数平均分子量的２１３００であった。また、エポキシ
基濃度は滴定法より６．８１ｍｏｌ／ｇであった。The molecular weight of the obtained polystyrene polymer was 21,300 in terms of number average molecular weight based on GP (all constant).The epoxy group concentration was 6.81 mol/g by titration method.
製造例３
ポリスチレン ２
攪拌機を備えたセパラブルフラスコにスチレン２１６ｇ
、無水マレイン酸８．６ｇ、ジオキサン１６０ｇ、アゾ
ビスイソブチロニトリルＩｇを仕込み、２０分間窒素を
吹き込みながら攪拌した後、８５℃に保ったオイルバス
中にセパラブルフラスコを移し、窒素雰囲気中で６０分
間攪拌し、さらにオイルバスを１０５°ＣにＲ温し、４
５分間ＩＮ拌し重合を行った。この後セパラブルフラス
コをオイルバスより取り出し冷却し、重合液を強ＩＷ拌
下でメタノール中に滴下し分別した９分別後乾燥し無水
マレイン酸基を含むスチレン系重合体を得た。Production Example 3 Polystyrene 2 216g of styrene in a separable flask equipped with a stirrer
, 8.6 g of maleic anhydride, 160 g of dioxane, and Ig of azobisisobutyronitrile were charged, and after stirring for 20 minutes while blowing nitrogen, the separable flask was transferred to an oil bath maintained at 85°C, and the mixture was heated in a nitrogen atmosphere. Stir for 60 minutes, then heat the oil bath to 105°C,
Polymerization was carried out by stirring for 5 minutes. Thereafter, the separable flask was taken out of the oil bath and cooled, and the polymerization solution was dropped into methanol under strong IW stirring and fractionated into 9 fractions, which were then dried to obtain a styrenic polymer containing maleic anhydride groups.
得たポリスチレン系重合体の分子量はＧ Ｐ ＣＩ！１
１定で、数平均分子量が約３００００であり、酸無水物
基濃度は８ 、２ ｍｏｌ／ ｇであった。The molecular weight of the obtained polystyrene polymer is G P CI! 1
At a constant constant, the number average molecular weight was about 30,000, and the acid anhydride group concentration was 8.2 mol/g.
実施例１
表１に示す割合のポリフェニレンエーテル樹脂とポリブ
チレンテレフタレート樹脂とポリカーボネート樹脂と製
造例２で合成したエポキシ基を含むスチレン系重合体を
加え、３００″Ｃに設定したスクリュー径３０ｍｍの異
方向回転２軸押出機にて溶融混練し、ペレットを得た。Example 1 Polyphenylene ether resin, polybutylene terephthalate resin, polycarbonate resin, and the styrene polymer containing epoxy groups synthesized in Production Example 2 were added in the proportions shown in Table 1, and the screw diameter was set at 300″C in a different direction with a screw diameter of 30 mm. The mixture was melt-kneaded using a rotating twin-screw extruder to obtain pellets.
このペレットを成形温度３００°Ｃ９金型温度８０℃の
条件で射出成形を行い、物性測定用試験片を作成しＡＳ
ＴＭに記載の方法に準じ、引張強度、引張伸び９曲げ弾
性率、アイゾツト衝撃強度、熱変形温度を測定した。ま
た、分散性の尺度として走査型電子顕微鏡を用い、成形
品中の分散粒子径を１ｌｌｌｌ定した。その結果を第１
表に示す。The pellets were injection molded at a molding temperature of 300°C and a mold temperature of 80°C to prepare test pieces for measuring physical properties.
Tensile strength, tensile elongation 9 flexural modulus, Izot impact strength, and heat distortion temperature were measured according to the method described in TM. Further, as a measure of dispersibility, a scanning electron microscope was used to determine the diameter of dispersed particles in the molded article. The result is the first
Shown in the table.
比較例１
ポリカーボネート樹脂および製造例２で合成した変性ポ
リスチレン系重合体を使用しない他は。Comparative Example 1 Except that the polycarbonate resin and the modified polystyrene polymer synthesized in Production Example 2 were not used.
実施例１と同様の方法で物性測定用試験片を作製し、実
施例１と同様の項目の特性を測定した。その結果を第１
表に示す。A test piece for measuring physical properties was prepared in the same manner as in Example 1, and the characteristics of the same items as in Example 1 were measured. The result is the first
Shown in the table.
比較例２
ポリカーボネート樹脂を使用しない他は、実施例１と同
様の方法で物性Δ１６定川試験片を作製し、実施例１と
同様の項目の特性を測定した。その結果を第１表に示す
。Comparative Example 2 A physical property Δ16 Sadakawa test piece was prepared in the same manner as in Example 1, except that no polycarbonate resin was used, and the properties in the same items as in Example 1 were measured. The results are shown in Table 1.
比較例３
製造例２で合成した変性ポリスチレン系重合体を使用し
ない他は、実施例１と同様の方法で物性Ａ１ｆＩ定用試
験片を作製し、実施例１と同様の引目の特性を測定した
。その結果を第１表に示す。Comparative Example 3 A physical property A1fI standard test piece was prepared in the same manner as in Example 1, except that the modified polystyrene polymer synthesized in Production Example 2 was not used, and the same draw characteristics as in Example 1 were measured. did. The results are shown in Table 1.
比較例４．５
製造例２で合成したポリスチレン系重合体の使用量を代
えた他は実施例１と同様の方法で物性測定用試験片を作
製し、実施例１と同様の項目の特性を測定した。その結
果を第１表に示す。Comparative Example 4.5 A test piece for measuring physical properties was prepared in the same manner as in Example 1, except that the amount of polystyrene polymer synthesized in Production Example 2 was changed, and the same characteristics as in Example 1 were obtained. It was measured. The results are shown in Table 1.
実施例２．３
ポリフェニレンエーテル樹脂およびポリブチレンテレフ
タレート樹脂の使用量を代えた他は実施例１と同様の方
法で物性測定用試験片を作製し、実施例１と同様の項目
の特性を測定した。その結果を第１表に示す。Example 2.3 A test piece for measuring physical properties was prepared in the same manner as in Example 1, except that the amounts of polyphenylene ether resin and polybutylene terephthalate resin used were changed, and the characteristics of the same items as in Example 1 were measured. . The results are shown in Table 1.
実施例４
ポリカーボネート樹脂の使用量を代えた他は実施例１と
同様の方法で物性測定用試験片を作製し、実施例１と同
様の項目の特性を測定した。その結果を第１表に示す。Example 4 A test piece for measuring physical properties was prepared in the same manner as in Example 1, except that the amount of polycarbonate resin used was changed, and the properties of the same items as in Example 1 were measured. The results are shown in Table 1.
（以下、余白）
実施例５．６
実施例１で使用したエポキシ基を有するポリスチレン系
重合体の代わりに、製造例２と同様の方法で合成した分
子量の異なる変性ポリスチレン系重合体を使用した他は
、実施例１と同様の方法で物性測定用試験片を作製し、
実施例１と同様の項１］の特性をδＩＩＩ定した。その
結果を第２表に示す。(Hereinafter, blank space) Example 5.6 Instead of the polystyrene polymer having an epoxy group used in Example 1, a modified polystyrene polymer with a different molecular weight synthesized in the same manner as Production Example 2 was used. A test piece for measuring physical properties was prepared in the same manner as in Example 1,
Term 1], which is the same as in Example 1, was determined as δIII. The results are shown in Table 2.
実施例７
実施例１で使用したエポキシ基を有するポリスチレン系
重合体の代わりに、製造例２と同様の方法で合成したエ
ポキシ基濃度の異なるポリスチレン系重合体を使用した
他は、実施例１と同様の方法で物性測定用試験片を作製
し、実施例１と同様の項目の特性を測定した。その結果
を第２表に示した。Example 7 The same procedure as Example 1 was used, except that instead of the polystyrene polymer having epoxy groups used in Example 1, a polystyrene polymer having a different concentration of epoxy groups synthesized in the same manner as in Production Example 2 was used. A test piece for measuring physical properties was prepared in the same manner, and the properties of the same items as in Example 1 were measured. The results are shown in Table 2.
実施例８
実施例１で使用したエポキシ基を有するポリスチレン系
重合体の代わりに、製造例３で合成した無水マレイン酸
基を有するポリスチレン系重合体を使用した他は、実施
例１と同様の方法で物性測定用試験片を作製し、実施例
１と同様の項目の特性を測定した。その結果を第２表に
示した。Example 8 The same method as in Example 1 except that the polystyrene polymer having maleic anhydride groups synthesized in Production Example 3 was used instead of the polystyrene polymer having epoxy groups used in Example 1. A test piece for measuring physical properties was prepared, and the characteristics of the same items as in Example 1 were measured. The results are shown in Table 2.
実施例９
実施例１で使用したエポキシ基を有するポリスチレン系
重合体の代わりに、タフチックＭ１９１３（旭化成社製
、酸無水物基含有スチレン・ブチレン系熱可塑性エラス
トマー）を使用した他は、実施例１と同様の方法で物性
測定用試験片を作製し、実施例１と同様の項［１の特性
を°測定した。その結果を第２表に示した。Example 9 Example 1 except that Toughtic M1913 (manufactured by Asahi Kasei Corporation, a styrene/butylene thermoplastic elastomer containing an acid anhydride group) was used instead of the polystyrene polymer having an epoxy group used in Example 1. A test piece for measuring physical properties was prepared in the same manner as in Example 1, and the properties of item [1] were measured in the same manner as in Example 1. The results are shown in Table 2.
（以下、余白）
実施例１０．１１
実施例１で使用したポリブチレンテレフタレート樹脂の
代わりに、ポリエチレンテレフタレート樹脂あるいは１
．４−シクロヘキシレンジメチレン。(Hereinafter, blank space) Example 10.11 Instead of the polybutylene terephthalate resin used in Example 1, polyethylene terephthalate resin or 1
．． 4-Cyclohexylene dimethylene.
エチレンテレフタレート共重合体（ＫｏｄｅｒＰＣＴＧ
１０１７９、イーストマンΦコダック社製）を使用した
他は、実施例１と同様の方法で物性Ａｌ１１定用試験片
を作製し、実施例１と同様の項目の特性を測定した。そ
の結果を第３表に示した。Ethylene terephthalate copolymer (KoderPCTG
A physical property Al11 test piece was prepared in the same manner as in Example 1, except that the same method as in Example 1 was used, except that the same method as in Example 1 was used, and the properties in the same items as in Example 1 were measured. The results are shown in Table 3.
実施例１２
実施例１の組成にさらにタフチック）１１０４１（旭化
成社製、スチレン・ブチレン系熱可塑性エラストマー）
を加えた以外は、実施例１と同様の方法で物性測定用試
験片を作製し、実施例１と同様の項目の特性を測定した
。その結果を第３表に示した。Example 12 Even tougher than the composition of Example 1) 11041 (manufactured by Asahi Kasei Corporation, styrene-butylene thermoplastic elastomer)
A test piece for measuring physical properties was prepared in the same manner as in Example 1, except that the following was added, and the characteristics of the same items as in Example 1 were measured. The results are shown in Table 3.
（以下、余白）
［発明の効果］
ポリフェニレンエーテル樹脂およびポリエステル樹脂か
らなる混合物に特定量のポリカーボネート樹脂および変
性ポリスチレン系重合体とを添加することで、ポリフェ
ニレンエーテル樹脂およびポリエステル樹脂からなる混
合物の機械的強度。(Hereinafter, blank space) [Effect of the invention] By adding a specific amount of polycarbonate resin and modified polystyrene polymer to a mixture of polyphenylene ether resin and polyester resin, the mechanical properties of the mixture of polyphenylene ether resin and polyester resin can be improved. Strength.
耐熱性、＃衝撃性および成形加工性などが改良された物
性のバランスのとれた熱可塑性樹脂組成物を得ることが
できる。A thermoplastic resin composition with well-balanced physical properties and improved heat resistance, impact resistance, moldability, etc. can be obtained.
Claims (1)
よび （ｂ）ポリエステル樹脂１０〜９０重量部 からなる混合物１００重量部に対して （ｃ）ポリカーボネート樹脂５〜１００重量部および （ｄ）変性ポリスチレン系重合体１〜３０重量部配合し
てなる熱可塑性樹能組成物。Scope of Claims: (c) 5 to 100 parts by weight of a polycarbonate resin and (d ) A thermoplastic resin composition containing 1 to 30 parts by weight of a modified polystyrene polymer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19997788A JPH0749510B2 (en) | 1988-08-12 | 1988-08-12 | Thermoplastic resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19997788A JPH0749510B2 (en) | 1988-08-12 | 1988-08-12 | Thermoplastic resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0251555A true JPH0251555A (en) | 1990-02-21 |
| JPH0749510B2 JPH0749510B2 (en) | 1995-05-31 |
Family
ID=16416731
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19997788A Expired - Lifetime JPH0749510B2 (en) | 1988-08-12 | 1988-08-12 | Thermoplastic resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0749510B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60246388A (en) * | 1984-05-18 | 1985-12-06 | Shionogi & Co Ltd | Carboxyalkenamidocephalosporin |
| EP0513812A2 (en) * | 1991-05-16 | 1992-11-19 | Mitsubishi Chemical Corporation | Thermoplastic resin composition |
| US5262476A (en) * | 1992-03-10 | 1993-11-16 | The Dow Chemical Company | Polycarbonate/polyester blends modified with poly(phenylene ether) |
| US5266673A (en) * | 1991-09-03 | 1993-11-30 | Mitsubishi Petrochemical Co., Ltd. | Process for producing a hydroxy-substituted poly(phenylene ether) resin |
| US5539030A (en) * | 1992-03-10 | 1996-07-23 | The Dow Chemical Company | Polycarbonate compositions modified with poly(phenylene ether) |
-
1988
- 1988-08-12 JP JP19997788A patent/JPH0749510B2/en not_active Expired - Lifetime
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60246388A (en) * | 1984-05-18 | 1985-12-06 | Shionogi & Co Ltd | Carboxyalkenamidocephalosporin |
| JPH0780892B2 (en) * | 1984-05-18 | 1995-08-30 | 塩野義製薬株式会社 | Carboxy alkenamide cefalosporin |
| EP0513812A2 (en) * | 1991-05-16 | 1992-11-19 | Mitsubishi Chemical Corporation | Thermoplastic resin composition |
| US5266673A (en) * | 1991-09-03 | 1993-11-30 | Mitsubishi Petrochemical Co., Ltd. | Process for producing a hydroxy-substituted poly(phenylene ether) resin |
| US5262476A (en) * | 1992-03-10 | 1993-11-16 | The Dow Chemical Company | Polycarbonate/polyester blends modified with poly(phenylene ether) |
| US5539030A (en) * | 1992-03-10 | 1996-07-23 | The Dow Chemical Company | Polycarbonate compositions modified with poly(phenylene ether) |
| US5543448A (en) * | 1992-03-10 | 1996-08-06 | The Dow Chemical Company | Polycarbonate polyester blends modified with poly(phenylene ether) |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0749510B2 (en) | 1995-05-31 |
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