JPH02289185A - Production of deodorizing textile product - Google Patents
Production of deodorizing textile productInfo
- Publication number
- JPH02289185A JPH02289185A JP1106969A JP10696989A JPH02289185A JP H02289185 A JPH02289185 A JP H02289185A JP 1106969 A JP1106969 A JP 1106969A JP 10696989 A JP10696989 A JP 10696989A JP H02289185 A JPH02289185 A JP H02289185A
- Authority
- JP
- Japan
- Prior art keywords
- deodorizing
- resin
- textile product
- substance
- inorganic substance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000001877 deodorizing effect Effects 0.000 title claims abstract description 74
- 239000004753 textile Substances 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 229920005989 resin Polymers 0.000 claims abstract description 41
- 239000011347 resin Substances 0.000 claims abstract description 41
- 239000000126 substance Substances 0.000 claims abstract description 34
- 239000000835 fiber Substances 0.000 claims abstract description 32
- 238000004332 deodorization Methods 0.000 claims description 5
- 239000007789 gas Substances 0.000 abstract description 16
- 239000000839 emulsion Substances 0.000 abstract description 15
- 239000000203 mixture Substances 0.000 abstract description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052802 copper Inorganic materials 0.000 abstract description 4
- 239000010949 copper Substances 0.000 abstract description 4
- 229920002635 polyurethane Polymers 0.000 abstract description 4
- 239000004814 polyurethane Substances 0.000 abstract description 4
- 229920002994 synthetic fiber Polymers 0.000 abstract description 4
- 239000012209 synthetic fiber Substances 0.000 abstract description 4
- 239000011701 zinc Substances 0.000 abstract description 4
- 239000007788 liquid Substances 0.000 abstract description 3
- 229910052725 zinc Inorganic materials 0.000 abstract description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract description 2
- 229910019142 PO4 Inorganic materials 0.000 abstract description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052782 aluminium Inorganic materials 0.000 abstract description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 229910052749 magnesium Inorganic materials 0.000 abstract description 2
- 239000011777 magnesium Substances 0.000 abstract description 2
- 239000010452 phosphate Substances 0.000 abstract description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 2
- 239000010936 titanium Substances 0.000 abstract description 2
- 229910052719 titanium Inorganic materials 0.000 abstract description 2
- 230000001413 cellular effect Effects 0.000 abstract 2
- 238000000034 method Methods 0.000 description 13
- 239000000243 solution Substances 0.000 description 13
- 239000002245 particle Substances 0.000 description 10
- 239000011148 porous material Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 239000002781 deodorant agent Substances 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- -1 linen Polymers 0.000 description 4
- 239000003094 microcapsule Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 241000779819 Syncarpia glomulifera Species 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 150000004676 glycans Chemical class 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000001739 pinus spp. Substances 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229920001282 polysaccharide Polymers 0.000 description 3
- 239000005017 polysaccharide Substances 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 229940036248 turpentine Drugs 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 229910000464 lead oxide Inorganic materials 0.000 description 2
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 239000000341 volatile oil Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 108010059892 Cellulase Proteins 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 229920001651 Cyanoacrylate Polymers 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- MWCLLHOVUTZFKS-UHFFFAOYSA-N Methyl cyanoacrylate Chemical compound COC(=O)C(=C)C#N MWCLLHOVUTZFKS-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 244000062793 Sorghum vulgare Species 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 229920006318 anionic polymer Polymers 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 229940088598 enzyme Drugs 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000011133 lead Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000019713 millet Nutrition 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000011135 tin Chemical class 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、衣料用、家庭用、各種産業用として用いる消
臭繊維製品の製造方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a method for producing deodorizing textile products for use in clothing, household use, and various industrial uses.
従来の技術
従来から、わな、糸、布帛などの繊維製品に消臭機能を
付与するために、消臭機能を有する物質を繊維に付着さ
せる方法として種々の試みがなされており、たとえば消
臭機能を有する物質を合成繊維に練込んだり、樹脂で繊
維表面に接着させたり、繊維に直接染着させたりする方
法がある。BACKGROUND OF THE INVENTION Various attempts have been made to attach deodorizing substances to fibers in order to impart deodorizing functions to textile products such as traps, threads, and fabrics. There are methods of kneading a substance having this into synthetic fibers, adhering it to the fiber surface with resin, or directly dyeing the fiber.
発明が解決しようとする課題
しかしながら、上記のような方法では消臭機能を有する
物質（以下消臭性物質という）を繊維に固着させた状態
で、消臭性物質の表面を繊維形成物質や樹脂などで被覆
してしまって、繊維表面上に存在させた消臭性物質の量
に見合う消臭性能が発揮できず、消臭速度が遅く、消臭
効率も低いという問題があった。Problems to be Solved by the Invention However, in the above method, a substance having a deodorizing function (hereinafter referred to as a deodorizing substance) is fixed to fibers, and then the surface of the deodorant substance is coated with a fiber-forming substance or resin. There was a problem in that the deodorizing performance was not achieved in proportion to the amount of the deodorizing substance present on the fiber surface, the deodorizing speed was slow, and the deodorizing efficiency was low.
本発明は上記の問題を解決するもので、消臭速度、消臭
効率のすぐれた消臭繊維製品を得ることができる消臭繊
維製品の製造方法を堤供することを目的とするものであ
る。The present invention solves the above-mentioned problems, and aims to provide a method for producing a deodorizing textile product that can obtain a deodorizing textile product with excellent deodorizing speed and efficiency.
課題を解決するための手段
上記の課題を解決するために本発明の消臭繊維製品の製
造方法は、繊維製品を消臭性態Ｉｌ物質を含有する樹脂
溶液で処理して、前記繊維製品の繊維表面に前記消臭性
無機物質を含む樹脂の多孔質皮膜を形成することを特徴
とするものである。Means for Solving the Problems In order to solve the above-mentioned problems, the method for producing a deodorant textile product of the present invention involves treating a textile product with a resin solution containing a deodorizing Il substance to improve the quality of the textile product. It is characterized in that a porous film of resin containing the deodorizing inorganic substance is formed on the fiber surface.
本発明でいう繊維製品とは、木綿、麻、レーヨンなどの
セルロース系繊維、羊毛、絹などの蛋白質系繊維、ポリ
アミド、ポリエステル、ポリアクリロニトリル、ポリプ
ロピレン、ポリ塩化ビニルなどの合成繊維もしくはこれ
らの繊維の混用品であって、わな、糸、ｍ織物、不織布
などの通常の繊維により形成される全ての形態のものを
含む。The textile products referred to in the present invention include cellulose fibers such as cotton, linen, and rayon, protein fibers such as wool and silk, synthetic fibers such as polyamide, polyester, polyacrylonitrile, polypropylene, and polyvinyl chloride, or synthetic fibers made of these fibers. Mixed products include all forms formed from conventional fibers such as traps, threads, woven fabrics, non-woven fabrics, etc.
本発明で用いる消臭性無機物質としては、マグネシウム
、アルミニウム、チタン、銅、亜鉛、ジルコニウム、銀
ｔａｒ鉛の酸化物、リン酸塩、珪酸塩もしくはこれらの
混合物であって、混合物はアモルファス状態に均一混合
されていることが望ましい、また銅、亜鉛、銀、錫、鉛
の塩を吸着させたゼオライトを用いてもよく、ゼオライ
トは天然、人工のどちらでもよい、これらの消臭性無機
物質は、粒子が絹かい程表面積が大きくなって消臭効率
が良く、消臭速度も速くなり、また繊維への接着性、風
合の観点からも細かい程良く、平均粒子径が５μｍ以下
、特に３μｍ以下が望ましい。The deodorizing inorganic substance used in the present invention is magnesium, aluminum, titanium, copper, zinc, zirconium, silver tar lead oxide, phosphate, silicate, or a mixture thereof, and the mixture is in an amorphous state. It is desirable that the mixture is homogeneous, and zeolite adsorbed with salts of copper, zinc, silver, tin, and lead may also be used. Zeolite may be either natural or artificial; these deodorizing inorganic substances are The silkier the particles, the larger the surface area, the better the deodorizing efficiency, and the faster the deodorizing speed.Also, from the viewpoint of adhesion to fibers and texture, the finer the better, the average particle size is 5 μm or less, especially 3 μm. The following are desirable.
本発明で用いる樹脂としては、ポリアクリル系樹脂、ポ
リウレタン系樹脂、ポリ塩化ビニル系樹脂、ポリビニル
アルコール系樹脂、ポリ酢酸ビニル系樹脂などのいずれ
でもよく、皮膜強度、造膜性、消臭性無機物質および繊
維との接着性が良好であることが好ましい、これらの樹
脂は、水溶性のものは水溶液とし、水不溶性のものは水
性分散液（エマルジョン）か有機溶剤溶液として（これ
らを総称して樹脂溶液という）用い、この樹脂溶液中に
前記消臭性無機物質の微粉末を分散させ、繊維製品を処
理する。この樹脂溶液による繊維製品の処理は、浸漬法
、パッド法、スプレー法、プリント法、コーティング法
、ラミネート法などにより行なうことができ、繊維の種
類、繊維製品の形態、樹脂や溶液の種類などによって適
宜選択することができる。The resin used in the present invention may be any of polyacrylic resin, polyurethane resin, polyvinyl chloride resin, polyvinyl alcohol resin, polyvinyl acetate resin, etc. It is preferable that these resins have good adhesion to substances and fibers.Water-soluble resins can be used as aqueous solutions, and water-insoluble resins can be used as aqueous dispersions (emulsions) or organic solvent solutions (these are collectively called A fine powder of the deodorizing inorganic substance is dispersed in the resin solution to treat the textile product. Textile products can be treated with this resin solution by a dipping method, a pad method, a spray method, a printing method, a coating method, a laminating method, etc., depending on the type of fiber, the form of the textile product, the type of resin and solution, etc. It can be selected as appropriate.
また前記ＭＭ詣は、皮膜形成後の状態で多孔質となるこ
とが必要であり、皮膜の多数の細孔が消臭性無機物質の
表面と悪臭ガスとが直接接触しうる部分を形成して、極
めて迅速な消臭を可能にする。In addition, the MM pilgrim needs to be porous in the state after the film is formed, and the many pores of the film form a part where the surface of the deodorizing inorganic substance and the malodorous gas can come into direct contact. , which enables extremely quick deodorization.
均一な皮膜では、消臭性無機物質の使用量に対する消臭
効果が小さく、また速度も遅く、効率的ではない、ａｔ
脂の多孔質皮膜の細孔の径は０．１μｍ〜１．０μｍが
望ましい。樹脂の多孔質皮膜の形成は、次の３種類の方
法が一般的で、工程上も簡単である。With a uniform film, the deodorizing effect is small depending on the amount of deodorizing inorganic substance used, and the speed is slow and inefficient.
The diameter of the pores in the porous fat film is preferably 0.1 μm to 1.0 μm. The following three methods are generally used to form a porous resin film, and the process is simple.
（１）樹脂の水溶液もしくはエマルジョン液に、水と揮
発油の０／Ｗ型エマルジヨンを混入する。エマルジョン
の揮発油の粒径は界面活性剤により１０μｍ以下に調節
し、樹脂溶液に消臭性無機物質と共に混合し、上記のよ
うな方法で繊維製品を処理して繊維表面に付着させた後
、乾燥してエマルジョンの粒子に対応する細孔を形成す
ることができる。４１孔の数および大きさはエマルジョ
ンの混入量と界面活性剤のＨＬＢにより粒径を制御して
調整できる。(1) A 0/W type emulsion of water and volatile oil is mixed into an aqueous resin solution or emulsion liquid. The particle size of the volatile oil in the emulsion is adjusted to 10 μm or less using a surfactant, mixed with a deodorizing inorganic substance in a resin solution, and treated with the above method to adhere to the fiber surface. It can be dried to form pores corresponding to the particles of the emulsion. The number and size of the 41 pores can be adjusted by controlling the particle size by adjusting the amount of emulsion mixed and the HLB of the surfactant.
（２）樹脂の水溶液もしくはエマルジョン液に、アルギ
ン酸ナトリウムやカルボキシメチルセルロースのような
多糖類アニオン系高分子電解質、可溶化澱粉、グアーガ
ムやプリティシュガムのような水溶性多糖類と消臭性無
機物質とを混合し、繊維表面に塗布し、皮膜形成後に水
洗もしくは酵素により前記多糖類などを分解除去して細
孔を形成する。(2) Add a polysaccharide anionic polymer electrolyte such as sodium alginate or carboxymethylcellulose, a water-soluble polysaccharide such as guar gum or pritish gum, and a deodorizing inorganic substance to the aqueous solution or emulsion of the resin. are mixed and applied to the fiber surface, and after forming a film, the polysaccharides and the like are decomposed and removed by washing with water or using enzymes to form pores.
（３）樹脂の水溶液もしくはエマルジョン液に、気体を
封入したマイクロカプセルを混入しておき、繊維表面に
塗布し、乾燥造膜後熱によりマイクロカプセルをその中
の気体を膨張させて破壊することにより細孔を形成する
０ｍ孔の量および径は、混入するマイクロカプセルの量
および粒径により調整することができる。(3) Microcapsules filled with gas are mixed into an aqueous solution or emulsion of the resin, applied to the fiber surface, dried, and then heated to expand the gas inside and destroy the microcapsules. The amount and diameter of the 0m pores forming the pores can be adjusted by the amount and particle size of the microcapsules to be mixed.
上記のようにして形成する消臭性無機物質を含む樹脂の
多孔質皮膜には、耐摩耗性や耐水性を向上させる目的で
架橋性樹脂を混入してもよい。架橋性樹脂は、エポキシ
系樹脂、ホルマリン系樹脂、インシアネート系樹脂、シ
アノアクリレート系樹脂、エチレンイミノ系樹脂などの
反応性基を２以上含む樹脂であればよく、これらの架橋
性樹脂の混入により、耐摩耗性、耐水性を向上させ、し
かも悪臭除去機能を長期にわたって持続させることがで
きる。A crosslinkable resin may be mixed into the porous resin film containing the deodorizing inorganic substance formed as described above for the purpose of improving wear resistance and water resistance. The crosslinkable resin may be any resin containing two or more reactive groups such as epoxy resin, formalin resin, incyanate resin, cyanoacrylate resin, or ethyleneimino resin, and by mixing these crosslinkable resins, , improves abrasion resistance and water resistance, and maintains its odor removal function over a long period of time.
作用
上記の構成により、繊維製品の繊維表面に消臭性無機物
質を樹脂の多孔質皮膜を介して保持させて、消臭性無機
物質と悪臭ガスとの接触面積が大きく、消臭速度と消臭
効率の極めてすぐれた消臭繊維製品を容易に得ることが
できる。Effect With the above structure, the deodorizing inorganic substance is held on the fiber surface of the textile product through the porous resin film, and the contact area between the deodorant inorganic substance and the malodorous gas is large, which improves the deodorizing speed and deodorization. A deodorizing fiber product with extremely high odor efficiency can be easily obtained.
実施例
実施例１
２０番手綿糸使いの密度経７０本／黍′、緯５５本／ン
の絹布に、ポリアクリル酸エステル４０％エマルジョン
３０部、ミネラルターペン６５％エマルジョン５０部、
酸化亜鉛、酸化珪素の１：１アモルファス混合物の微粉
砕物１０部、水１０部で調製したコーテイング液をコー
ティングし、乾燥して消臭性能の良好な消臭繊維織物を
得た。消臭性能の試験結果を第１表に示した。Examples Example 1 30 parts of a 40% polyacrylic acid ester emulsion, 50 parts of a 65% mineral turpentine emulsion,
A coating solution prepared with 10 parts of a finely ground mixture of a 1:1 amorphous mixture of zinc oxide and silicon oxide and 10 parts of water was coated and dried to obtain a deodorizing fiber fabric with good deodorizing performance. The test results for deodorizing performance are shown in Table 1.
実施例２
４０番手綿／ポリエステル： ４０／６０混紡糸使いの
密度径９０本／メン、緯８０本／黍ンのキャンプリック
を、ポリウレタン４５％エマルジョン２０％、ミネラル
ターペン６５％エマルジョン２０％、酸化亜鉛、酸化チ
タンの混合比１：１平均粒子径３μｍの微粉砕混合物１
５％の混合液にパッドした後乾燥して、消臭性能および
風合共にすぐれた消臭繊維織物を得た。Example 2 40 count cotton/polyester: camprick using 40/60 blended yarn with a density of 90 yarns/men and 80 yarns/millet, 45% polyurethane, 20% emulsion, 65% mineral turpentine, 20% emulsion, and oxidation. Finely ground mixture 1 of zinc and titanium oxide at a mixing ratio of 1:1 and an average particle size of 3 μm
It was padded with a 5% mixed solution and dried to obtain a deodorizing fiber fabric with excellent deodorizing performance and texture.
消臭性能の試験結果を第１表に示した。The test results of deodorizing performance are shown in Table 1.
実施例３
３０番手綿糸をかぜ状にして、ポリウレタン４５％エマ
ルジョン１０％、ミネラルターペン６５％エマルジョン
２０％、酸化アルミニウム、酸化鉛、酸化銀の混合比５
：３：１．平均粒子径２μｍの混合微粉末１０％の混合
液中で、浴比１：１５にて６０℃で６０分間処理し、乾
燥して消臭繊維糸を形成し、この糸を用いてソックスを
編成し、性能良好な消臭・抗菌ソックスを製作した。こ
の消臭・抗菌ソックスの消臭性能の試験結果を第１表に
示した。Example 3 A 30 count cotton thread was made into a crimp shape, and a mixture ratio of 45% polyurethane, 10% emulsion, 65% mineral turpentine, 20% emulsion, aluminum oxide, lead oxide, and silver oxide was 5.
:3:1. Treated in a mixture of 10% mixed fine powder with an average particle size of 2 μm at a bath ratio of 1:15 at 60°C for 60 minutes, dried to form deodorizing fiber yarn, and this yarn is used to knit socks. We have created deodorizing and antibacterial socks with good performance. Table 1 shows the test results of the deodorizing performance of these deodorizing and antibacterial socks.
実施例４
４０番手綿糸使いの密度経９４本／工′、緯８０本／手
′のキャンプリックを、ポリウレタン４５％水溶液５０
部、カルボキシメチルセルロース３０％水溶液３０部、
酸化チタン、酸化亜鉛の混合比２：１、平均粒子径３μ
ｍの混合微粉末１０部、水１０部で調製したコーテイン
グ液でコーティングし、乾燥後セルラーゼ酵素５ｇ／Ω
の処理液中でカルボキシメチルセルロースを分解除去し
て、透湿性、消臭性共に良好な消臭繊維織物を得た。消
臭性能の試験結果を第１表に示した。Example 4 A camprick using 40 count cotton yarn with a density of 94 threads/hand' and 80 threads/hand' was mixed with 50% polyurethane 45% aqueous solution.
parts, 30 parts of carboxymethyl cellulose 30% aqueous solution,
Mixing ratio of titanium oxide and zinc oxide 2:1, average particle size 3μ
Coated with a coating solution prepared with 10 parts of mixed fine powder of M and 10 parts of water, and after drying, 5 g/Ω of cellulase enzyme was applied.
Carboxymethylcellulose was decomposed and removed in the treatment solution to obtain a deodorizing fiber fabric with good moisture permeability and deodorizing properties. The test results for deodorizing performance are shown in Table 1.
実施例５
５０番手綿／ポリエステル：６０／４０混紡糸使いの密
度経１２０本／纂′、緯８０本／≠ンのボブリンに、ポ
リアクリル酸エステル４０％溶液にマイクロカプセル起
泡剤５％と、ゼオライトに銅と銀を飽和吸着させた平均
粒子径３μｍの微粉末１０％とを混入し、増粘剤で粘度
を７０００ｃ 、 ｐ 、 ｓに調整した処理液をプリ
ントし、乾燥後発泡させて消臭繊維織物を得た。消臭性
能の試験結果を第１表に示した。Example 5 Boblin made of 50 count cotton/polyester: 60/40 blended yarn with a density of 120 yarns/stem and 80 yarns/≠ was added with 5% microcapsule foaming agent in a 40% solution of polyacrylic acid ester. , zeolite was mixed with 10% fine powder with an average particle size of 3 μm in which copper and silver were saturated and adsorbed, and the viscosity was adjusted to 7000c, p, s using a thickener.The treatment solution was printed, dried, and then foamed. A deodorizing fiber fabric was obtained. The test results for deodorizing performance are shown in Table 1.
上記実施例１〜５で得た各消臭繊維製品について、次の
方法により、硫化水素とアンモニアに対する消臭性能を
試験した。Each of the deodorant fiber products obtained in Examples 1 to 5 above was tested for deodorizing performance against hydrogen sulfide and ammonia by the following method.
容量３Ωのポリ弗化エチレン製袋内に、各消臭繊維製品
試料１ｇと所定の初期濃度のガス６００ｎ ｉとを封入
し、室温で３時間放置後のガス濃度を測定した。また別
に上記と同様の初期濃度のガス６００１ρだけを封入し
て、同様に３時間放置後のガス濃度を測定し、ブランク
ガス濃度とした。脱臭率（％）は次式により求めた。1 g of each deodorizing fiber product sample and 600 n i of gas at a predetermined initial concentration were sealed in a polyfluorinated ethylene bag with a capacity of 3 Ω, and the gas concentration was measured after being left at room temperature for 3 hours. Separately, only gas 6001ρ having the same initial concentration as above was sealed, and the gas concentration was similarly measured after being left for 3 hours, which was used as a blank gas concentration. The deodorization rate (%) was determined by the following formula.
第１表
第１表に示すように、上記各実施例で得られた消臭＃ａ
維製品は、硫化水素、アンモニアに対して極めてすぐれ
た消臭性能を有している。Table 1 As shown in Table 1, deodorizing #a obtained in each of the above examples
Textile products have extremely good deodorizing performance against hydrogen sulfide and ammonia.
上記のように各実施例で得られた消臭繊維製品において
、消臭性！Ｉ！機物質物質体となる繊維は表面積が大き
く、したがって悪臭ガスとの接触面積が大きく、特に繊
維が収束している部分で悪臭ガスの通過抵抗が起って消
臭性無機物質と悪臭ガスとの接触時間が長くなって消臭
効率が良好である。As mentioned above, the deodorizing fiber products obtained in each example have excellent deodorizing properties! I! Fibers, which are organic substances, have a large surface area, and therefore have a large contact area with malodorous gases. Particularly in the areas where the fibers converge, there is resistance to the passage of malodorous gases, and the interaction between the deodorizing inorganic material and the malodorous gases is increased. The contact time is longer and the deodorizing efficiency is better.
しかも消臭性無機物質が樹脂の多孔質皮膜を介して保持
されているので、消臭性無機物質と悪臭ガスとの接触面
積がさらに著しく増大し、かつ皮膜厚さが多孔質とした
ことにより薄くなり、悪臭ガスが樹脂皮膜内部を拡散す
る時間が短くなって消臭速度が速くなり、また消臭性無
機物質の大部分が消臭に寄与して消臭効率が著しく良好
である。Moreover, since the deodorizing inorganic substance is retained through the porous resin film, the contact area between the deodorizing inorganic substance and the foul-smelling gas increases significantly, and the thickness of the film is made porous. As the resin film becomes thinner, the time for the malodorous gas to diffuse inside the resin film becomes shorter, resulting in faster deodorizing speed, and most of the deodorizing inorganic substance contributes to deodorizing, resulting in extremely good deodorizing efficiency.
発明の効果
以上のように本発明の消臭ｍ、Ｉ！！製品の製造方法に
おいては、繊維製品を消臭性無機物質を含有する樹脂溶
液で処理して、前記繊維製品の繊維表面に前記消臭性無
機物質を含む樹脂の多孔質皮膜を形成するものであり、
任意の方法による後加工で消臭繊維製品を容易に生産で
き、しかも得られる消臭ｍ維製品では、消臭性無機物質
と悪臭ガスとの接触面積が大きく、かつ接触時間も十分
で、消臭性無機物質の大部分が消臭に寄与して、消臭速
度、消臭効率が極めて良好で、耐久性らすぐれており、
一般衣料用のほか、カーテン、内装材として室内の消臭
に使用でき、布団側地、中綿などに用いた消臭布団は養
護老人、身障者用などとして有用であり、一方フイルタ
ーなどの表面積の大きさが必要な用途にも好適であるな
ど、多種多様な用途に用いることができる。As described above, the deodorizing method of the present invention m, I! ! The method for manufacturing the product includes treating a textile product with a resin solution containing a deodorizing inorganic substance to form a porous film of the resin containing the deodorizing inorganic substance on the fiber surface of the textile product. can be,
Deodorizing fiber products can be easily produced by post-processing using any method, and the resulting deodorizing fiber products have a large contact area between the deodorant inorganic substance and the malodorous gas, and a sufficient contact time. Most of the odorous inorganic substances contribute to deodorization, resulting in extremely good deodorizing speed and efficiency, and excellent durability.
In addition to general clothing, it can be used to deodorize rooms as curtains and interior decoration materials.Deodorizing futons used for futon sides and filling are useful for nursing the elderly and people with disabilities; It can be used in a wide variety of applications, including applications that require high performance.
代理人 森 本 義 弘Agent Hiroshi Mori Moto
Claims (1)
理して、前記繊維製品の繊維表面に前記消臭性無機物質
を含む樹脂の多孔質皮膜を形成することを特徴とする消
臭繊維製品の製造方法。1. Deodorization characterized by treating a textile product with a resin solution containing a deodorizing inorganic substance to form a porous film of the resin containing the deodorizing inorganic substance on the fiber surface of the textile product. Method of manufacturing textile products.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1106969A JPH02289185A (en) | 1989-04-26 | 1989-04-26 | Production of deodorizing textile product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1106969A JPH02289185A (en) | 1989-04-26 | 1989-04-26 | Production of deodorizing textile product |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02289185A true JPH02289185A (en) | 1990-11-29 |
Family
ID=14447141
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1106969A Pending JPH02289185A (en) | 1989-04-26 | 1989-04-26 | Production of deodorizing textile product |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02289185A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100452034B1 (en) * | 1996-06-11 | 2004-12-03 | 도레이 가부시끼가이샤 | Deodorant textile material and its manufacturing method |
| WO2005026431A1 (en) * | 2003-09-10 | 2005-03-24 | Toray Industries, Inc. | Fibrous structure |
| JP2017086799A (en) * | 2015-11-17 | 2017-05-25 | 平岡織染株式会社 | Deodorant sheet and method for regenerating deodorant performance of the same |
| JP2017086798A (en) * | 2015-11-17 | 2017-05-25 | 平岡織染株式会社 | Deodorant sheet and method for regenerating deodorant performance of the same |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54104885A (en) * | 1978-02-06 | 1979-08-17 | Hitachi Ltd | Pressure monitor and operation device for vacuum apparatus |
| JPS62299571A (en) * | 1986-06-13 | 1987-12-26 | ダイセル化学工業株式会社 | Staple fiber having deodorizing action |
| JPH01104885A (en) * | 1987-03-23 | 1989-04-21 | Dainichiseika Color & Chem Mfg Co Ltd | Deodorizing clothing |
-
1989
- 1989-04-26 JP JP1106969A patent/JPH02289185A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54104885A (en) * | 1978-02-06 | 1979-08-17 | Hitachi Ltd | Pressure monitor and operation device for vacuum apparatus |
| JPS62299571A (en) * | 1986-06-13 | 1987-12-26 | ダイセル化学工業株式会社 | Staple fiber having deodorizing action |
| JPH01104885A (en) * | 1987-03-23 | 1989-04-21 | Dainichiseika Color & Chem Mfg Co Ltd | Deodorizing clothing |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100452034B1 (en) * | 1996-06-11 | 2004-12-03 | 도레이 가부시끼가이샤 | Deodorant textile material and its manufacturing method |
| WO2005026431A1 (en) * | 2003-09-10 | 2005-03-24 | Toray Industries, Inc. | Fibrous structure |
| JP2017086799A (en) * | 2015-11-17 | 2017-05-25 | 平岡織染株式会社 | Deodorant sheet and method for regenerating deodorant performance of the same |
| JP2017086798A (en) * | 2015-11-17 | 2017-05-25 | 平岡織染株式会社 | Deodorant sheet and method for regenerating deodorant performance of the same |
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