JPH01104885A - Deodorizing clothing - Google Patents
Deodorizing clothingInfo
- Publication number
- JPH01104885A JPH01104885A JP63152652A JP15265288A JPH01104885A JP H01104885 A JPH01104885 A JP H01104885A JP 63152652 A JP63152652 A JP 63152652A JP 15265288 A JP15265288 A JP 15265288A JP H01104885 A JPH01104885 A JP H01104885A
- Authority
- JP
- Japan
- Prior art keywords
- clothing
- acid
- deodorizing
- parts
- carboxylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000001877 deodorizing effect Effects 0.000 title claims abstract description 44
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 44
- 239000011342 resin composition Substances 0.000 claims abstract description 27
- -1 aluminum compound Chemical class 0.000 claims abstract description 21
- 239000002781 deodorant agent Substances 0.000 claims abstract description 20
- 239000002253 acid Substances 0.000 claims abstract description 15
- 239000000463 material Substances 0.000 claims abstract description 14
- 150000003752 zinc compounds Chemical class 0.000 claims abstract description 13
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 4
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 239000004744 fabric Substances 0.000 claims description 11
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract description 17
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract description 15
- 239000000839 emulsion Substances 0.000 abstract description 12
- 229920002635 polyurethane Polymers 0.000 abstract description 11
- 239000004814 polyurethane Substances 0.000 abstract description 11
- 239000003960 organic solvent Substances 0.000 abstract description 9
- 239000011787 zinc oxide Substances 0.000 abstract description 9
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 abstract description 8
- 150000001735 carboxylic acids Chemical class 0.000 abstract description 7
- 238000000576 coating method Methods 0.000 abstract description 6
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 abstract description 3
- 229920005989 resin Polymers 0.000 abstract description 2
- 239000011347 resin Substances 0.000 abstract description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract 1
- 235000019645 odor Nutrition 0.000 description 34
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 27
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 24
- 239000000047 product Substances 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 238000000034 method Methods 0.000 description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 10
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000000123 paper Substances 0.000 description 9
- 239000002649 leather substitute Substances 0.000 description 8
- 235000014692 zinc oxide Nutrition 0.000 description 8
- 239000003995 emulsifying agent Substances 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 6
- 229910021529 ammonia Inorganic materials 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- 229920005862 polyol Polymers 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 5
- 125000005442 diisocyanate group Chemical group 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 150000003077 polyols Chemical class 0.000 description 5
- 210000003491 skin Anatomy 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- NPUVYHNDWLTMSW-UHFFFAOYSA-N OS(O)(=O)=O.OS(O)(=O)=O.OS(O)(=O)=O.[AsH3].[AsH3] Chemical compound OS(O)(=O)=O.OS(O)(=O)=O.OS(O)(=O)=O.[AsH3].[AsH3] NPUVYHNDWLTMSW-UHFFFAOYSA-N 0.000 description 4
- UJMDYLWCYJJYMO-UHFFFAOYSA-N benzene-1,2,3-tricarboxylic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1C(O)=O UJMDYLWCYJJYMO-UHFFFAOYSA-N 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 239000003085 diluting agent Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 229920001400 block copolymer Polymers 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 229920000578 graft copolymer Polymers 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000005056 polyisocyanate Substances 0.000 description 3
- 229920001228 polyisocyanate Polymers 0.000 description 3
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 description 3
- 229920005604 random copolymer Polymers 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- 239000011667 zinc carbonate Substances 0.000 description 3
- 235000004416 zinc carbonate Nutrition 0.000 description 3
- 229910000010 zinc carbonate Inorganic materials 0.000 description 3
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 239000004970 Chain extender Substances 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 210000003608 fece Anatomy 0.000 description 2
- 239000011790 ferrous sulphate Substances 0.000 description 2
- 235000003891 ferrous sulphate Nutrition 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000002648 laminated material Substances 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 244000144972 livestock Species 0.000 description 2
- 239000010871 livestock manure Substances 0.000 description 2
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 2
- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052979 sodium sulfide Inorganic materials 0.000 description 2
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 2
- 239000012756 surface treatment agent Substances 0.000 description 2
- 210000004243 sweat Anatomy 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- PAALZGOZEUHCET-UHFFFAOYSA-N 1,4-dioxecane-5,10-dione Chemical compound O=C1CCCCC(=O)OCCO1 PAALZGOZEUHCET-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 240000002234 Allium sativum Species 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
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- 240000001548 Camellia japonica Species 0.000 description 1
- 241001070941 Castanea Species 0.000 description 1
- 235000014036 Castanea Nutrition 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- ODBLHEXUDAPZAU-ZAFYKAAXSA-N D-threo-isocitric acid Chemical compound OC(=O)[C@H](O)[C@@H](C(O)=O)CC(O)=O ODBLHEXUDAPZAU-ZAFYKAAXSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
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- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
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- 230000002378 acidificating effect Effects 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
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- 229940103272 aluminum potassium sulfate Drugs 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
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- 125000006267 biphenyl group Chemical group 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
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- 229940018557 citraconic acid Drugs 0.000 description 1
- XFTRTWQBIOMVPK-UHFFFAOYSA-N citramalic acid Chemical compound OC(=O)C(O)(C)CC(O)=O XFTRTWQBIOMVPK-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 235000018597 common camellia Nutrition 0.000 description 1
- YQLZOAVZWJBZSY-UHFFFAOYSA-N decane-1,10-diamine Chemical compound NCCCCCCCCCCN YQLZOAVZWJBZSY-UHFFFAOYSA-N 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 description 1
- 235000004611 garlic Nutrition 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- MZYHMUONCNKCHE-UHFFFAOYSA-N naphthalene-1,2,3,4-tetracarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=C(C(O)=O)C(C(O)=O)=C21 MZYHMUONCNKCHE-UHFFFAOYSA-N 0.000 description 1
- KVQQRFDIKYXJTJ-UHFFFAOYSA-N naphthalene-1,2,3-tricarboxylic acid Chemical compound C1=CC=C2C(C(O)=O)=C(C(O)=O)C(C(=O)O)=CC2=C1 KVQQRFDIKYXJTJ-UHFFFAOYSA-N 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 239000004631 polybutylene succinate Substances 0.000 description 1
- 229920002961 polybutylene succinate Polymers 0.000 description 1
- 229920000921 polyethylene adipate Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- UORVCLMRJXCDCP-UHFFFAOYSA-N propynoic acid Chemical compound OC(=O)C#C UORVCLMRJXCDCP-UHFFFAOYSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000035900 sweating Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- ODBLHEXUDAPZAU-UHFFFAOYSA-N threo-D-isocitric acid Natural products OC(=O)C(O)C(C(O)=O)CC(O)=O ODBLHEXUDAPZAU-UHFFFAOYSA-N 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- WGIWBXUNRXCYRA-UHFFFAOYSA-H trizinc;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O WGIWBXUNRXCYRA-UHFFFAOYSA-H 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011746 zinc citrate Substances 0.000 description 1
- 235000006076 zinc citrate Nutrition 0.000 description 1
- 229940068475 zinc citrate Drugs 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- HJSYJHHRQVHHMQ-TYYBGVCCSA-L zinc;(e)-but-2-enedioate Chemical compound [Zn+2].[O-]C(=O)\C=C\C([O-])=O HJSYJHHRQVHHMQ-TYYBGVCCSA-L 0.000 description 1
- ZPEJZWGMHAKWNL-UHFFFAOYSA-L zinc;oxalate Chemical compound [Zn+2].[O-]C(=O)C([O-])=O ZPEJZWGMHAKWNL-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
【発明の詳細な説明】
(産業上の利用分野)
本発明は、臭気あるいは独特の匂いがある環境で着用す
るための衣料に関するもので、その臭気が皮膚、頭髪に
浸透しないようにしたものである。[Detailed Description of the Invention] (Industrial Application Field) The present invention relates to clothing to be worn in environments where there is an odor or a unique odor, and which prevents the odor from penetrating the skin and hair. be.
さらに詳しくは、不快臭を除去できる脱臭性に優れた合
成皮革、擬革、その他の各種ボタウレタン系樹脂製品を
与えるポリウレタン系樹脂組成物を適用した素材を生地
とした衣料に関する。More specifically, the present invention relates to clothing made of a material applied with a polyurethane resin composition that provides synthetic leather, fake leather, and other various botanical urethane resin products that have excellent deodorizing properties that can remove unpleasant odors.
臭気あるいは独特の匂い(以下、臭気と略記する)があ
る環境には、例えば、家畜の畜舎、糞尿の処理施設、魚
市場、塵芥収集・処理、長期の病人の療養、大量に汗を
かくスポーツなどの場がある。Environments with odors or unique odors (hereinafter abbreviated as odors) include, for example, livestock barns, manure processing facilities, fish markets, garbage collection and processing, medical treatment for long-term patients, and sports that involve sweating profusely. There are places like this.
(従来技術)
従来、臭気がある環境における臭気防護方法としては、
例えば、家畜の畜舎、ふん尿の処理施設などにおいては
、衣類で体の全てを被う、あるいは、ゴム引き合羽を着
用する等の方法が行われていた。(Prior art) Conventionally, odor protection methods in environments with odors include:
For example, in livestock barns, manure processing facilities, etc., people used to cover their entire bodies with clothing or wear rubberized coats.
(従来技術の問題点)
しかし、単に通常の衣類で体の全てを被う場合は、着用
衣類に少しでも通気性があれば、臭気が衣類を通して皮
膚面に臭気層を形成する。(Problems with the Prior Art) However, if the entire body is simply covered with ordinary clothing, and if the clothing is even slightly breathable, the odor will pass through the clothing and form an odor layer on the skin surface.
また、通気性がないゴム、ビニールその他の合成樹脂性
材料の雨合羽のようなものでは、汗で蒸れて、特に夏期
には作業し難いので結局着用できない。In addition, raincoats made of non-breathable rubber, vinyl, or other synthetic resin materials cannot be worn because they become stuffy with sweat and are difficult to work in, especially in the summer.
そして、いずれの場合でも、臭気が体に移った後は、た
とい入浴して何度も洗っても臭気が消えず、会う人に不
快感を抱かせる虞が残るのである。In either case, once the odor has transferred to the body, the odor does not go away even if one takes a bath and washes it many times, and there is a risk that it may cause discomfort to those who meet the body.
ところで、従来、ボタウレタン系樹脂をベースとする有
機溶剤溶液、分散液或いは乳化液等はポリウレタン系樹
脂製の各種合成皮革、擬革、通気性シート材料ならびに
各種材料との積層材、複合材等のポリウレタン系樹脂製
品の製造に広く使用されてきた。By the way, conventionally, organic solvent solutions, dispersions, emulsions, etc. based on botanical urethane resins have been used for various synthetic leathers, fake leathers, breathable sheet materials, laminated materials with various materials, composite materials, etc. made of polyurethane resins. It has been widely used in the production of polyurethane resin products.
このポリウレタン系樹脂組成物から得られる各種製品が
、悪臭が蓄積したり発生したりしている場所で使用され
る場合には、これらの製品に活性炭や硫酸第一鉄等の脱
臭剤を包含させることが考えられていた。・
しかし、活性炭は黒色であるため製品を黒色にし、又、
硫酸第一鉄は空気中の酸素によって容易に褐色に変化す
るという問題があるため、本発明が問題にしている衣料
に通用するには、衣料とは種々の着色が要求されるもの
であるから、やはり適当なものではなかった。When various products obtained from this polyurethane resin composition are used in places where bad odors accumulate or are generated, deodorizing agents such as activated carbon and ferrous sulfate should be included in these products. That was considered.・However, since activated carbon is black, it makes the product black, and
Since ferrous sulfate has the problem of easily turning brown due to oxygen in the air, in order to be used in the clothing that is the subject of the present invention, clothing requires various colors. , it still wasn't appropriate.
(本発明の目的)
本発明は、上述の問題点に漏み、製品を着色せずに、周
囲雰囲気の不快な臭気を長時間吸収して周囲から不快な
臭気を除去できる組成物を利用した、夏期にも着用でき
、かつ、任意の色調に容易に着色可能な消臭衣料を提供
することを目的とする。(Objective of the present invention) The present invention addresses the above-mentioned problems and utilizes a composition that can remove unpleasant odors from the surrounding atmosphere by absorbing unpleasant odors in the surrounding atmosphere for a long time without coloring the product. To provide deodorizing clothing that can be worn even in summer and can be easily colored in any color.
(問題点を解決するための手段)
このため本発明の消臭衣料は、下記aの特徴を有する脱
臭性ポリウレタン系樹脂組成物を適用した素材により形
成された生地から作製されていることを特徴とする。(Means for Solving the Problems) Therefore, the deodorant clothing of the present invention is characterized in that it is made from a fabric made of a material to which a deodorizing polyurethane resin composition having the following characteristics a is applied. shall be.
a ポリウレタン系樹脂、液媒体及び添加剤からなるポ
リウレタン系樹脂組成物において、添加剤の少なくとも
一部が実質的に白色又は無色の脱臭剤である。a In a polyurethane resin composition comprising a polyurethane resin, a liquid medium, and an additive, at least a portion of the additive is a substantially white or colorless deodorizing agent.
(好ましい実施態様)
次に本発明を、本発明の好ましい実施態様を挙げて更に
詳しく説明する。(Preferred Embodiments) Next, the present invention will be described in more detail by citing preferred embodiments of the present invention.
本発明において消臭衣料に適用する脱臭性ポリウレタン
系樹脂組成物に使用する(以下、組成物に関する記載に
おいては、本発明において使用する、という)、ポリウ
レタン系樹脂とは、ポリオール、ポリイソシアネート、
鎖伸長剤等を反応させて得られる樹脂であり、従来公知
のポリウレタン系樹脂はいずれも本発明で使用すること
ができるものであり、特に限定されない。In the present invention, the polyurethane resin used in the deodorizing polyurethane resin composition applied to deodorant clothing (hereinafter referred to as "used in the present invention" in the description of the composition) refers to polyols, polyisocyanates,
The resin is obtained by reacting a chain extender, etc., and any conventionally known polyurethane resin can be used in the present invention, and is not particularly limited.
例えば、ポリオールとしては、従来公知のポリウレタン
系樹脂用ポリオールはいずれも使用でき、例えば、好ま
しいものとして末端基が水酸基であり、分子量が300
乃至4,000のポリエチレンアジペート、
ポリエチレンプロピレンアジペート、
ポリエチレンブチレンアジベート、
ポリジエチレンアジペート、
ポリブチレンアジペート、
ポリエチレンサクシネート、
ポリブチレンサクシネート、
ポリエチレンセバケート、
ポリブチレンセバケート、
ポリテトラメチレンエーテルグリコール、ポリ−ε−カ
プロラクトンジオール、
ポリへキサメチレンアジペート、
カーボネートポリオール、
ポリプロピレングリコール等、及び上記ポリオール中に
適当な量ポリオキシエチレン鎖を含有するものが挙げら
れる。For example, as the polyol, any conventionally known polyol for polyurethane resins can be used. For example, it is preferable that the terminal group is a hydroxyl group and the molecular weight is 300.
to 4,000 polyethylene adipate, polyethylene propylene adipate, polyethylene butylene adipate, polydiethylene adipate, polybutylene adipate, polyethylene succinate, polybutylene succinate, polyethylene sebacate, polybutylene sebacate, polytetramethylene ether glycol, poly Examples include -ε-caprolactone diol, polyhexamethylene adipate, carbonate polyol, polypropylene glycol, and those containing an appropriate amount of polyoxyethylene chains in the above polyols.
有機ポリイソシアネートとしては、従来公知のいずれの
ものも使用できるが、例えば、好ましいものとして、
4.4′−ジフェニルメタンジイソシアネート(MDI
)
水添加MDI、
イソホロンジイソシアネート、
1.3−ジシリレンジイソシアネート、1.4−ジシリ
レンジイソシアネート、2.4−シリレンジイソシアネ
ート、
2.6−シリレンジイソシアネート、
1.5−シフタリンジイソシアネート、m−ジェニレン
ジイソシアネート、
p−ジエニレンジイソシアネート等があり、或いはこれ
らの有機ポリイソシアネートと低分子量のポリオールや
ポリアミンとを末端イソシアネートとなるように反応さ
せて得られるウレタンプレポリマー等も当然使用するこ
とができる。Any conventionally known organic polyisocyanate can be used, but for example, 4,4'-diphenylmethane diisocyanate (MDI) is preferred.
) Water-added MDI, isophorone diisocyanate, 1.3-disylylene diisocyanate, 1.4-disylylene diisocyanate, 2.4-silylene diisocyanate, 2.6-silylene diisocyanate, 1.5-shiftylene diisocyanate, m-genylene diisocyanate There are isocyanates, p-dienylene diisocyanates, etc., or urethane prepolymers obtained by reacting these organic polyisocyanates with low molecular weight polyols or polyamines to form terminal isocyanates can also be used.
鎖伸長剤としては、従来公知のいずれのものも使用でき
るが、例えば、好ましいものとしては、エチレングリコ
ール、
プロピレングリコール、
ジエチレングリコール、
1.4−ジタンジオール、
1.6−ジキサンジオール、
エチレンジアミン、
1.2−プロピレンジアミン、
トリメチレンジアミン、
テトラメチレンジアミン、
ヘキサメチレンジアミン、
デカメチレンジアミン、
イソホロンジアミン、
m−ジシリレンジアミン、
ヒドラジン、
水等がある。As the chain extender, any conventionally known ones can be used, but for example, preferred ones are ethylene glycol, propylene glycol, diethylene glycol, 1,4-ditanediol, 1,6-dixanediol, ethylenediamine, 1 .2-propylene diamine, trimethylene diamine, tetramethylene diamine, hexamethylene diamine, decamethylene diamine, isophorone diamine, m-disilylene diamine, hydrazine, water, etc.
本発明の消臭衣料に適用するポリウレタン系樹脂組成物
は、上記ポリウレタン系樹脂を有機溶剤中に溶解させた
り、分散させたり或いは水を用いてWlo又はOZW型
の乳化液とする場合において、その添加剤の少なくとも
一部として実質的に白色又は無色の脱臭剤を添加したこ
とを特徴とする。The polyurethane resin composition applied to the deodorant clothing of the present invention can be prepared by dissolving or dispersing the polyurethane resin in an organic solvent or by using water to form a Wlo or OZW type emulsion. It is characterized in that a substantially white or colorless deodorizing agent is added as at least a part of the additive.
上記組成物に使用する液媒体は水又は有機溶剤或いはそ
れらの混合物であり、例えば有機溶剤として好ましいも
のは、メチルエチルケトン、メチル−n−プロピルケト
ン、メチルイソブチルケトン、ジエチルケトン、ギ酸メ
チル、ギ酸エチル、ギ酸プロピル、酢酸メチル、酢酸エ
チル、酢酸ブチル等であり、又、アセトン、シクロヘキ
サン、テトラヒドロフラン、ジオキサン、メタノール、
エタノール、イソプロピルアルコール、ブタノール、ト
ルエン、キシレン、ジメチルホルムアミド、ジメチルス
ルホキシド、パークロルエチレン、トリクロルエチレン
、メチルセロソルブ、ブチルセロソルブ、セロソルブア
セテート等及びこれらの任意の比率の混合物が使用でき
る。The liquid medium used in the above composition is water, an organic solvent, or a mixture thereof. For example, preferred organic solvents include methyl ethyl ketone, methyl-n-propyl ketone, methyl isobutyl ketone, diethyl ketone, methyl formate, ethyl formate, Propyl formate, methyl acetate, ethyl acetate, butyl acetate, etc. Also, acetone, cyclohexane, tetrahydrofuran, dioxane, methanol,
Ethanol, isopropyl alcohol, butanol, toluene, xylene, dimethylformamide, dimethyl sulfoxide, perchloroethylene, trichlorethylene, methyl cellosolve, butyl cellosolve, cellosolve acetate, etc., and mixtures thereof in arbitrary ratios can be used.
使用する有機溶剤がポリウレタン系樹脂に対して良溶剤
であればポリウレタン系樹脂の溶液となり、液媒体が貧
溶媒であれば分散液となる。又、これらの有機溶剤溶液
或いは分散液中に界面活性剤を用いて水を乳化させるか
或いは水中に界面活性剤を用いて上記溶液又は分散液を
乳化させることによって乳化液が得られる。又、ポリウ
レタン系樹脂を単に水中に界面活性剤を使用して乳化さ
せてもよい。If the organic solvent used is a good solvent for the polyurethane resin, it will be a solution of the polyurethane resin, and if the liquid medium is a poor solvent, it will be a dispersion. Further, an emulsion can be obtained by emulsifying water using a surfactant in these organic solvent solutions or dispersions, or by emulsifying the above solutions or dispersions in water using a surfactant. Alternatively, the polyurethane resin may be simply emulsified in water using a surfactant.
乳化剤としては、従来公知の油中水型或いは水中油型乳
化剤は、いずれも使用できるが、特に好適なものは、分
子中に適当な量のポリオキシエチレン鎖を有するポリウ
レタン系界面活性剤である。As the emulsifier, any of the conventionally known water-in-oil or oil-in-water emulsifiers can be used, but particularly preferred are polyurethane surfactants having an appropriate amount of polyoxyethylene chains in the molecule. .
これらの乳化剤は、ポリウレタン系樹脂溶液の固形分1
00重量部あたり、約1乃至10重量部の割合で使用す
るのが好ましい。These emulsifiers have a solid content of 1
Preferably, it is used in a proportion of about 1 to 10 parts by weight per 00 parts by weight.
以上のようなポリウレタン系樹脂の溶液、分散液又は乳
化液は固形分が5乃至60重量%程度のものが好ましい
。The polyurethane resin solution, dispersion, or emulsion as described above preferably has a solid content of about 5 to 60% by weight.
上記のようなポリウレタン系樹脂組成物に包含させる脱
臭剤は、活性炭のように黒色のものではなく、白色又は
実質的に無色であり、且つ変色性の無いことが必要であ
り、更にポリウレタン系樹脂組成物の品質、特に着色性
を低下させるものであってはならず、−船室屋内等で生
じるアンモニア臭、アミン臭、硫化水素臭等の不快臭を
良好に吸収するものであることが好ましい。The deodorizing agent included in the polyurethane resin composition as described above must be white or substantially colorless, not black like activated carbon, and should not discolor. It should not reduce the quality of the composition, especially its colorability, and it should preferably absorb unpleasant odors such as ammonia odor, amine odor, hydrogen sulfide odor, etc. that occur inside the cabin of a ship.
以上のような特性を有する脱臭剤としては、有機カルボ
ン酸と亜鉛化合物との混合物又は亜鉛化合物とアルミニ
ウム化合物との混合物が挙げられる。Examples of the deodorizing agent having the above characteristics include a mixture of an organic carboxylic acid and a zinc compound or a mixture of a zinc compound and an aluminum compound.
好ましい有機カルボン酸は、脂肪族ポリカルボン酸、芳
香族ポリカルボン酸及びポリマーカルボン酸である。Preferred organic carboxylic acids are aliphatic polycarboxylic acids, aromatic polycarboxylic acids and polymeric carboxylic acids.
脂肪族ポリカルボン酸の好ましい例としては、例えば、
シヱウ酸、マロン酸、コハク酸、グルタル酸、アジピン
酸、ピメリン酸、フマル酸、マレイン酸、メチルマレイ
ン酸、メチルフマル酸、イタコン酸、シトラコン酸、メ
サコン酸、アセチレン酸、リンゴ酸、メチルリンゴ酸、
クエン酸、イソクエン酸、酒石酸等のジ又はトリカルボ
ン酸又はそれらの塩であり、特に好ましいものはクエン
酸、フマル酸又はその塩である。Preferred examples of aliphatic polycarboxylic acids include, for example,
Oxic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, fumaric acid, maleic acid, methylmaleic acid, methylfumaric acid, itaconic acid, citraconic acid, mesaconic acid, acetylenic acid, malic acid, methylmalic acid,
Di- or tricarboxylic acids such as citric acid, isocitric acid, and tartaric acid, or salts thereof, and particularly preferred are citric acid, fumaric acid, or salts thereof.
芳香族ポリカルボン酸の好ましい例としては、例えば、
フタル酸、テレフタル酸、イソフタル酸、トリメリット
酸、1.2.3−ベンゼントリカルボン酸、1,3.5
−ベンゼントリカルボン酸、ピロメリット酸、ベンゼン
ヘキサカルボン酸、ナフタレンジカルボン酸、ナフタレ
ントリカルボン酸、ナフタレンテトラカルボン酸、ジフ
ェニルテトラカルボン酸、ジフェニルエーテルテトラカ
ルボン酸、アゾベンゼンテトラカルボン酸等の芳香族カ
ルボン酸或いはそれらの無水物であり、特に好ましい芳
香族ポリカルボン酸は、ベンゼントリカルボン酸、特に
トリメリット酸である。Preferred examples of aromatic polycarboxylic acids include, for example,
Phthalic acid, terephthalic acid, isophthalic acid, trimellitic acid, 1.2.3-benzenetricarboxylic acid, 1,3.5
- Aromatic carboxylic acids such as benzenetricarboxylic acid, pyromellitic acid, benzenehexacarboxylic acid, naphthalenedicarboxylic acid, naphthalenetricarboxylic acid, naphthalenetetracarboxylic acid, diphenyltetracarboxylic acid, diphenyl ethertetracarboxylic acid, azobenzenetetracarboxylic acid, etc.; A particularly preferred aromatic polycarboxylic acid which is anhydride is benzenetricarboxylic acid, especially trimellitic acid.
又、ポリマーカルボン酸としては、クエン酸、酒石酸、
フタル酸等の多価カルボン酸と、エチレングリコール、
1,4−ブタンジオール、ジエチレングリコール等の多
価アルコールとを酸過剰で反応させて得られる末端カル
ボキシル基ポリウレタン系;多価カルボン酸で変性した
酸性セルロース誘導体;多価カルボン酸のビニルエーテ
ルエステルモノマー等の単独重合体又は他の一般的なモ
ノマーとのランダム共重合体、ブロック共重合体、グラ
フト共重合体;アクリル酸又はメタクリル酸等のモノマ
ーの単独重合体又は他の一般的なモノマーとのランダム
共重合体、ブロック共重合体、グラフト共重合体;無水
マレイン酸、イタコン酸等角α、β−不飽和ビニルモノ
マー等の単独重合体又は他の一般的なモノマーとのラン
ダム共重合体、ブロック共重合体、グラフト共重合体等
が挙げられる。In addition, examples of polymer carboxylic acids include citric acid, tartaric acid,
Polyhydric carboxylic acids such as phthalic acid, ethylene glycol,
Polyurethane with terminal carboxyl groups obtained by reacting polyhydric alcohols such as 1,4-butanediol and diethylene glycol with excess acid; acidic cellulose derivatives modified with polycarboxylic acids; vinyl ether ester monomers of polycarboxylic acids, etc. Homopolymers or random copolymers with other common monomers, block copolymers, graft copolymers; homopolymers of monomers such as acrylic acid or methacrylic acid or random copolymers with other common monomers. Polymers, block copolymers, graft copolymers; homopolymers such as maleic anhydride, itaconic acid conformal α, β-unsaturated vinyl monomers, or random copolymers, block copolymers with other common monomers. Examples include polymers, graft copolymers, and the like.
上記のような有機カルボン酸に亜鉛化合物を添加するこ
とによって、アミン臭やアンモニア臭とともに他の悪臭
源である硫化水素臭をも同時に吸収することができる。By adding a zinc compound to the above organic carboxylic acid, it is possible to simultaneously absorb hydrogen sulfide odor, which is another source of bad odor, along with amine odor and ammonia odor.
このような亜鉛化合物としては、例えば、酸化亜鉛、硫
酸亜鉛、塩化亜鉛、リン酸亜鉛、硝酸亜鉛、炭酸亜鉛等
の無機亜鉛化合物、酢酸亜鉛、シュウ酸亜鉛、クエン酸
亜鉛、フマル酸亜鉛、ギ酸亜鉛等の有機亜鉛塩が使用で
きるが、特に好ましいものは亜鉛華(酸化亜鉛)及び炭
酸亜鉛である。Examples of such zinc compounds include inorganic zinc compounds such as zinc oxide, zinc sulfate, zinc chloride, zinc phosphate, zinc nitrate, zinc carbonate, zinc acetate, zinc oxalate, zinc citrate, zinc fumarate, and formic acid. Organic zinc salts such as zinc can be used, but particularly preferred are zinc white (zinc oxide) and zinc carbonate.
このような亜鉛化合物は有機カルボン酸100重量部あ
たりl乃至1,000重量部、好ましくは30乃至30
0重量部の割合で配合する。Such a zinc compound is used in an amount of 1 to 1,000 parts by weight, preferably 30 to 30 parts by weight, per 100 parts by weight of organic carboxylic acid.
It is blended in a proportion of 0 parts by weight.
更に好ましい白色又は実質的に無色の脱臭剤としては、
上記亜鉛化合物にアルミニウム化合物を配合したものが
挙げられる。このような脱臭剤も、ポリウレタン系樹脂
組成物の好ましい物性や染色性等を低下させることなく
、各種の悪臭源であるアミン臭、アンモニア臭及び硫化
水素臭等の不快臭を吸収することができる。アルミニウ
ム化合物として好ましいものは硫酸アルミニウムや硫酸
アルミニウムカリウム等であり、これらのアルミニウム
化合物は亜鉛化合物100重量部に対して1乃至1,0
00重量部、好ましくは30乃至300重量部の割合で
使用する。More preferred white or substantially colorless deodorizers include:
Examples include those in which an aluminum compound is blended with the above zinc compound. Such a deodorizing agent can also absorb unpleasant odors such as amine odor, ammonia odor, and hydrogen sulfide odor, which are sources of various odor, without reducing the desirable physical properties or dyeability of the polyurethane resin composition. . Preferred aluminum compounds are aluminum sulfate, aluminum potassium sulfate, etc., and these aluminum compounds are used in an amount of 1 to 1.0 parts by weight per 100 parts by weight of the zinc compound.
00 parts by weight, preferably 30 to 300 parts by weight.
以上のような脱臭剤は、得られるポリウレタン系樹脂組
成物全量中で約0.5乃至50重量%を占める割合で使
用するのが好ましい。使用量が上記の範囲未満であると
、本組成物の目的、すなわち、消臭衣料に適用するため
の脱臭性能が不十分であり、又上記範囲を越える使用割
合では、物性が不十分なので好ましくない。The deodorizing agent as described above is preferably used in an amount of about 0.5 to 50% by weight of the total amount of the polyurethane resin composition obtained. If the amount used is less than the above range, the deodorizing performance for the purpose of the composition, which is applied to deodorant clothing, will be insufficient, and if the usage rate exceeds the above range, the physical properties will be insufficient, so it is preferable. do not have.
このようにして得られたポリウレタン系樹脂の溶液、分
散液又は乳化液は、必要に応じて各種の添加剤、例えば
、着色剤、架橋剤、安定剤、充槙剤等のように公知の添
加剤を任意に添加することができる。The solution, dispersion, or emulsion of the polyurethane resin obtained in this manner may contain various additives, such as colorants, crosslinking agents, stabilizers, fillers, etc., as necessary. Agents can optionally be added.
上記のようなポリウレタン系樹脂組成物から合成皮革、
擬革或いは他のシート材料および積層材、複合材等の素
材を製造するのに使用する基材としては、例えば、各種
の離型紙、織布、編布、不織布、離型紙、プラスチック
フィルム、金属板、ガラス板等いかなる基材でもよい。Synthetic leather from polyurethane resin compositions as above,
Substrates used to produce fake leather or other sheet materials, laminated materials, composite materials, etc. include various release papers, woven fabrics, knitted fabrics, non-woven fabrics, release papers, plastic films, and metals. Any base material such as a plate or glass plate may be used.
その基材に対する上記ポリウレタン系樹脂組成物の適用
方法は、例えば、コーティング法、浸漬法、これらの組
合せ方法等いずれの公知の方法でもよく、その含浸及び
/又は塗布量は、約5乃至2、’OOOg(配合液)/
ホのように、その目的に応じて広い範囲で変化させるこ
とができる。The method for applying the polyurethane resin composition to the substrate may be any known method such as a coating method, a dipping method, or a combination of these methods, and the amount of impregnation and/or application is about 5 to 2. 'OOOg (compounded liquid)/
Like E, it can be varied within a wide range depending on the purpose.
上記のポリウレタン系樹脂組成物を含浸及び/または塗
布した基材のゲル化及び乾燥は、いずれも従来技術と同
様でよいものであり、例えば、約40乃至200°C程
度の温度で数分間乃至数時間の乾燥で、消臭衣料に適用
して優れた特性を有するポリウレタン系樹脂製品が得ら
れる。Gelation and drying of the substrate impregnated and/or coated with the above polyurethane resin composition may be carried out in the same manner as in the prior art, for example, at a temperature of about 40 to 200°C for several minutes to After several hours of drying, a polyurethane resin product with excellent properties for use in deodorizing clothing can be obtained.
(作用)
以上のように、本発明の消臭衣料は、上記ポリウレタン
系樹脂組成物を適用した衣料であって、特にその着色性
と脱臭性に優れたものであり、悪臭や異臭が発生したり
、蓄積する場所で使用される衣服、靴、手袋等として有
用である。(Function) As described above, the deodorizing clothing of the present invention is a clothing to which the above-mentioned polyurethane resin composition is applied, and has particularly excellent coloring properties and deodorizing properties, and does not generate bad or strange odors. It is useful as clothing, shoes, gloves, etc., used in places where it accumulates.
次に実施例を挙げて本発明を更に具体的に説明する。尚
、文中、部又は%とあるのは重量基準である。Next, the present invention will be explained in more detail with reference to Examples. Note that parts and percentages in the text are based on weight.
(実施例)
以下、まず、図面に示した実施例に基づき、本発明の消
臭衣料の形態を説明する。(Example) First, the form of deodorant clothing of the present invention will be described based on the example shown in the drawings.
第1図は実施例による消臭衣料である。FIG. 1 shows deodorant clothing according to an example.
消臭衣料は、服1の部分、帽子2.3の部分及びズボン
4の部分とからなり、帽子及びズボンの部分はいずれも
服の部分と一体でも別体でもよい。The deodorizing clothing consists of a clothing part 1, a hat 2.3 part, and a trousers 4 part, and the hat and trousers parts may both be integrated with the clothing part or separate from the clothing part.
この衣料の生地は、適当な素材の基材に、本発明に使用
する脱臭性ポリウレタン系樹脂組成物を適用することに
より得る。The fabric for this clothing is obtained by applying the deodorizing polyurethane resin composition used in the present invention to a base material of a suitable material.
素材は、シート状、布帛状、繊維状等、衣料製品を形成
するものであれば、どの段階のものでもよい。例えば、
繊維状のものを用いた場合は、最終製品に形成するまで
の適当な時期に織地にする等の加工を施して、生地にす
る。The material may be in any stage as long as it forms a clothing product, such as a sheet, fabric, or fiber. for example,
If a fibrous material is used, it is processed into a cloth at an appropriate time before it is formed into a final product, such as by being woven into a fabric.
適用方法には、コーティング、噴霧、浸漬、これらの組
合せ等いずれの公知の方法でもよい。The application method may be any known method such as coating, spraying, dipping, or a combination thereof.
この生地をそのまま縫製するか、または、さらに積層あ
るいはキルテイング加工等を経た後、縫製し、適宜の形
状の服、帽子、ズボンを得る。This fabric is sewn as it is, or it is further laminated or quilted and then sewn to obtain clothes, hats, and pants of appropriate shapes.
以下に、実施例としてこのように形成される消臭衣料の
脱臭性能を、各種の脱臭性ポリウレタン系樹脂組成物つ
いて述べる。Below, as examples, the deodorizing performance of deodorant clothing formed in this way will be described using various deodorizing polyurethane resin compositions.
実施例ル
ザミンcu77LV (大日精化工業製、ポリウレタン
系樹脂)25部、硫酸アルミニウム40部、酸化亜鉛1
0部及びジメチルホルムアミド40部をボールミルにて
混練し、分散粒子の粒径を5μm以下にして本発明の消
臭衣料に適用するポリウレタン系樹脂組成物を得た。Example Lusamine cu77LV (manufactured by Dainichiseika Chemical Industry Co., Ltd., polyurethane resin) 25 parts, aluminum sulfate 40 parts, zinc oxide 1
0 parts and 40 parts of dimethylformamide were kneaded in a ball mill to reduce the particle size of dispersed particles to 5 μm or less to obtain a polyurethane resin composition to be applied to the deodorant clothing of the present invention.
上記組成物5部をレザミンME (大日精化工業製、ポ
リウレタン系樹脂)100部、セイカセブンALT
(大日精化工業製)15部、希釈溶剤としてのジメチル
ホルムアミド15部及びメチルエチルケトン20部を加
え均一になるまで撹拌した後脱泡処理し、離型紙上に1
20g/rrf・smetの割合で塗布し、120℃で
2分間乾燥し表皮層を形成した。5 parts of the above composition, 100 parts of Rezamin ME (polyurethane resin, manufactured by Dainichiseika Chemical Industry Co., Ltd.), and 100 parts of Seika Seven ALT.
(manufactured by Dainichiseika Chemical Industry Co., Ltd.), 15 parts of dimethylformamide as a diluting solvent, and 20 parts of methyl ethyl ketone were added, stirred until homogeneous, defoamed, and placed on release paper.
It was applied at a rate of 20 g/rrf·smet and dried at 120° C. for 2 minutes to form a skin layer.
次にレザミンIJ D 660 S^ (大日精化工業
製、ポリウレタン系樹脂)100部、レザミンUD架橋
剤(大日精化工業製)10部、希釈剤としてのメチルエ
チルケトン40部を加え均一になるまで撹拌したものを
、予め作成しておいた上記の表皮層を形成した離型紙上
に、ナイフコーターで100乃至150 g/rrr
・wetの量で塗布し、100℃30秒間乾燥し、直ち
に基布を載置圧着して120°Cで2分間乾燥し1、巻
取り後50℃で24時間熟成する。その後離型紙を剥離
し、ポリウレタン系樹脂製合成皮革を得た。Next, 100 parts of Rezamin IJ D 660 S^ (manufactured by Dainichiseika Kagyo, polyurethane resin), 10 parts of Rezamin UD crosslinking agent (manufactured by Dainichiseika Kagyo), and 40 parts of methyl ethyl ketone as a diluent were added and stirred until uniform. The obtained product was coated on a release paper with the above skin layer formed in advance using a knife coater at 100 to 150 g/rrr.
・Apply in a wet amount, dry at 100°C for 30 seconds, immediately place and press base fabric, dry at 120°C for 2 minutes 1, and age at 50°C for 24 hours after winding up. Thereafter, the release paper was peeled off to obtain a polyurethane resin synthetic leather.
この得られた合成皮革について下記の方法で脱臭効果を
測定したところ、下記のような有意差のある結果を得た
。When the deodorizing effect of the obtained synthetic leather was measured using the method described below, results with significant differences as shown below were obtained.
300mj!容の三角フラスコに、28%アンモニア水
を10μ2採取して、完全にガス化させた後、サンプル
(サイズ50X200 mm、1枚)を投入し、25℃
に保存し、所定の時間経過後、凡用式ガス検知器を用い
てフラスコ内のアンモニア残存濃度を測定した。300mj! Collect 10 μ2 of 28% ammonia water into a 3-volume Erlenmeyer flask, and after completely gasifying it, put the sample (size 50 x 200 mm, 1 sheet) and heat at 25°C.
After a predetermined period of time had elapsed, the residual concentration of ammonia in the flask was measured using a general-purpose gas detector.
」旦Y盟止水塞
300mf容の三角フラスコに、800ppmの硫化ナ
トリウム水溶液1ml及び1規定硫酸l。In a 300 mf Erlenmeyer flask with a water stopper, add 1 ml of 800 ppm sodium sulfide aqueous solution and 1 N sulfuric acid.
Omlを入れ硫化水素を生成させ、サンプル(サイズ5
0X50mm、 1枚)を投入し、25°Cに保存し
、所定の時間経過後、凡用式ガス検知器を用いてフラス
コ内の硫化水素残存濃度を測定した。Add Oml to generate hydrogen sulfide, and remove the sample (size 5
0x50 mm, 1 piece) was placed in the flask and stored at 25°C. After a predetermined period of time, the residual concentration of hydrogen sulfide in the flask was measured using a general-purpose gas detector.
試■椛果
5背後30分後120分後 試料のサイズブランク 4
,400 4,400 4,400 50X20Omm
本処理品 4,000 2,300 900 50x
200柵(尚、ブランクは脱臭剤を使用していことを除
き本発明と同様にしたものである。以下同様)B)硫ヒ
素の脱自能(ρpm )
1日後3日後7日後 試料のサイズ
ブランク 160 160 160 50X 50
mm本処理品 50 NOND 50X50
mm(ND=検出されず、以下同様)
実施例2
実施例1で得た樹脂組成物中の脱臭剤として硫酸アルミ
ニウムカリウム30部及び炭酸亜鉛20部を使用し、他
は実施例1と同様にして調製した本発明の消臭衣料に適
用する樹脂組成物5部をレザロイドLU1500 (大
日精化工業製、ポリウレタン系表面処理剤)100部に
加え均一に撹拌して表面処理液とする。Trial■ Camellia 5 Behind 30 minutes After 120 minutes Sample size blank 4
,400 4,400 4,400 50X20Omm
Mainly treated product 4,000 2,300 900 50x
200 fence (The blank was made in the same manner as in the present invention except that a deodorizing agent was used. The same applies hereinafter) B) Ability to remove arsenic sulfate (ρpm) 1 day, 3 days, 7 days later Sample size Blank 160 160 160 50X 50
mm processed product 50 NOND 50X50
mm (ND = not detected, the same applies hereinafter) Example 2 30 parts of potassium aluminum sulfate and 20 parts of zinc carbonate were used as a deodorizing agent in the resin composition obtained in Example 1, and the other conditions were the same as in Example 1. 5 parts of the resin composition to be applied to the deodorizing clothing of the present invention prepared in the above manner are added to 100 parts of Retheroid LU1500 (polyurethane surface treatment agent manufactured by Dainichiseika Chemical Industry Co., Ltd.) and stirred uniformly to obtain a surface treatment liquid.
レザミンME (大日精化工業製、ポリウレタン系樹’
Jll)100部、セイカセブンALT (大日精化
工業製)15部、希釈溶剤としてのジメチルホルムアミ
ド15部及びメチルエチルケトン20部を加え均一にな
るまで撹拌した後脱泡処理し、離型紙上に120 g/
rd−setの割合で塗布し、120°Cで7分間乾
燥し表皮層を形成した。Rezamin ME (manufactured by Dainichiseika Chemical Industry Co., Ltd., polyurethane-based tree)
Jll), 15 parts of Seika Seven ALT (manufactured by Dainichiseika Chemical Industry Co., Ltd.), 15 parts of dimethylformamide as a diluting solvent, and 20 parts of methyl ethyl ketone were added, stirred until uniform, defoamed, and 120 g was placed on release paper. /
It was applied at a ratio of rd-set and dried at 120°C for 7 minutes to form an epidermal layer.
次にレザミンUD6605A (大日精化工業製、ポ
リウレタン系樹脂)100部、レザミンUD架橋剤(大
日精化工業製)10部、レザミンIJD102促進剤(
大日精化工業製)10部、希釈剤としてのメチルエチル
ケトン40部を加え均=になるまで撹拌したものを、予
め作成しておいた上記の表皮層を形成した離型紙上に、
ナイフコーターで100乃至150 g/ni ・we
tの量で塗布し、100°C30秒間乾燥し、直ちに基
布を載置圧着して120℃で2分間乾燥し、巻取り後5
0°Cで24時間熟成する。その後離型紙を剥離し、上
記表面処理1剤をグラビア印刷機で120メツシュ版で
1回塗布し、乾燥してポリウレタン系樹脂製合成皮革を
得た。Next, 100 parts of Rezamin UD6605A (manufactured by Dainichiseika Kagyo, polyurethane resin), 10 parts of Rezamin UD crosslinking agent (manufactured by Dainichiseika Kagyo), and Rezamin IJD102 accelerator (
10 parts (manufactured by Dainichiseika Chemical Industry Co., Ltd.) and 40 parts of methyl ethyl ketone as a diluent were added and stirred until the mixture was evenly mixed.
100 to 150 g/ni ・we with knife coater
It was applied in an amount of
Aging at 0°C for 24 hours. Thereafter, the release paper was peeled off, and the above-mentioned surface treatment agent was applied once using a 120 mesh plate using a gravure printing machine, and dried to obtain a polyurethane resin synthetic leather.
この得られた合成皮革について上記の方法で脱臭効果を
測定したところ、下記のような有意差のある結果を得た
。When the deodorizing effect of the obtained synthetic leather was measured using the method described above, the following significant differences were obtained.
5背後30分後120分後 試料のサイズブランク4,
400 4,400 4,400 50X 200mm
本処理品4,000 2,000 1,300 5QX
200mmB)硫ヒ 素の脱臭能(pm)
1日後3日後7日後 試料のサイズ
ブランク 160 160 160 50X 50
mm本処理品 10 ND ND 50
x50胴実施例3
実施例1で得た樹脂組成物中の脱臭剤として酸化亜鉛2
0部及びクエン酸5部を使用し、他は実施例1と同様に
して調製した本発明の消臭衣料に適用する樹脂組成物5
部、レザミンCU (大日精化工業製、ポリウレタン系
樹脂)100部、セイカセブンBS (大日精化工業製
)5乃至20部、界面活性剤3部、希釈容剤としてジメ
チルホルムアミド50部を加え均一になるまで撹拌し脱
泡後起毛布土に1mmの厚さで塗布し、水中で約10分
間凝固させ、50℃の温水中で30分間ジメチルホルム
アミドを抽出除去し、更に20°Cの水中で洗浄し、1
00°Cで乾燥して多孔質シート材料を得た。5 After 30 minutes After 120 minutes Sample size blank 4,
400 4,400 4,400 50X 200mm
Mainly treated product 4,000 2,000 1,300 5QX
200mmB) Deodorizing ability of arsenic sulfate (pm) 1 day, 3 days, 7 days Sample size blank 160 160 160 50X 50
mm processed product 10 ND ND 50
x50 cylinder Example 3 Zinc oxide 2 as a deodorizer in the resin composition obtained in Example 1
Resin composition 5 applied to deodorant clothing of the present invention, prepared in the same manner as in Example 1 except using 0 parts and 5 parts of citric acid.
100 parts of Rezamin CU (manufactured by Dainichiseika Chemical Industry Co., Ltd., polyurethane resin), 5 to 20 parts of Seika Seven BS (manufactured by Dainichiseika Chemical Industry Co., Ltd.), 3 parts of surfactant, and 50 parts of dimethylformamide as a diluent were added and mixed uniformly. After degassing, it was applied to a thickness of 1 mm on raised clay, coagulated in water for about 10 minutes, dimethylformamide was extracted and removed in warm water at 50°C for 30 minutes, and further soaked in water at 20°C. Wash, 1
A porous sheet material was obtained by drying at 00°C.
この得られた多孔質シート材料について上記の方法で脱
臭効果を測定したところ、下記のような有意差のある結
果を得た。When the deodorizing effect of the obtained porous sheet material was measured using the method described above, results with significant differences as shown below were obtained.
■腋級来
A アンモニアの脱−m
5背後30分後120分後 試料のサイズブランク4.
400 4,400 4.400 50X 200X2
本処理品4.OQ0 3,400 2,700 50X
200X2B 硫ヒ水素の脱 能Cppm )
1日後3日後 7日後 試料のサイズ
ブランク 160 160 160 50x 5
0 x2′2部理晶 ND ND ND
50X 50 X2実施例4
実施例1で得た樹脂組成物中の脱臭剤として酸化亜鉛2
0部及びトリメリット酸10部を使用し、他は実施例1
と同様にして調製した本発明の消臭衣料に適用する樹脂
組成物5部、レザミンCU (大日精化工業製、ポリウ
レタン系樹脂> ioo部、セイカセブンBS (大日
精化工業製)0乃至5部、界面活性剤3部、希釈容剤と
してジメチルホルムアミド200部を加え均一になるま
で撹拌し脱泡後起毛布土に含浸させてピックアップ率3
00%絞りを行った後、水中で約10分間凝固させ、5
0°Cの温水中で30分間ジメチルホルムアミドを抽出
除去し、更に20°Cの水中で洗浄し、100°Cで乾
燥して含浸起毛布を得た。この起毛布を用い実施例2で
作成した方法でポリウレタン系樹脂製合成皮革を得た。■ Armpit level A Ammonia removal m 5 30 minutes later 120 minutes later Sample size blank 4.
400 4,400 4.400 50X 200X2
Mainly treated product 4. OQ0 3,400 2,700 50X
200X2B Arsenic sulfate removal Cppm) 1 day 3 days 7 days later Sample size blank 160 160 160 50x 5
0 x2' 2 part Risho ND ND ND
50X 50X2 Example 4 Zinc oxide 2 as a deodorizing agent in the resin composition obtained in Example 1
0 parts and 10 parts of trimellitic acid, the rest was as in Example 1.
5 parts of the resin composition applied to the deodorant clothing of the present invention prepared in the same manner as above, Rezamin CU (manufactured by Dainichiseika Chemical Industries, Ltd., polyurethane resin> ioo part, Seika Seven BS (manufactured by Dainichiseika Chemical Industries, Ltd.) 0 to 5 1 part, 3 parts of surfactant, and 200 parts of dimethylformamide as a diluting agent, stirred until uniform, defoamed, and impregnated into the raised soil to obtain a pick-up rate of 3.
After squeezing 00%, coagulate in water for about 10 minutes,
Dimethylformamide was extracted and removed in warm water at 0°C for 30 minutes, further washed in water at 20°C, and dried at 100°C to obtain an impregnated napkin. A synthetic leather made of a polyurethane resin was obtained using the raised fabric in the same manner as in Example 2.
この得られた合成皮革について上記の方法で脱臭効果を
測定したところ、下記のような有意差のある結果を得た
。When the deodorizing effect of the obtained synthetic leather was measured using the method described above, the following significant differences were obtained.
試IL展
5背後30分後120分後 試料のサイズブランク4,
400 4.400 4,400 50X 200X
2本処理品4,000 2,700 1,800
50X 200X 2(B 硫化水素の脱臭能(ppm
)
1日後3日後7日後 試料のサイズ
ブランク 160 160 160 50x 20
x 2本処理品 ND NOND 50X
20 X 2実施例5
■、4−ブタンエチレンアジペート(平均分子量約i、
ooo、水酸基価112)!、000部、1.4−ブタ
ンジオール31部、ジフェニルメタンジイソシアネート
333部をメチルエチルケトン3,183部中に加え、
70°Cで8時間反応し、平均分子量が6万5千である
固形分30%のポリウレタン系樹脂溶液(A)を得た。Trial IL exhibition 5 30 minutes later 120 minutes later Sample size blank 4,
400 4.400 4,400 50X 200X
2-piece processed product 4,000 2,700 1,800
50X 200X 2 (B Hydrogen sulfide deodorizing ability (ppm
) 1 day later 3 days later 7 days later Sample size blank 160 160 160 50x 20
x 2 processed product ND NOND 50X
20 X 2 Example 5 ■, 4-butane ethylene adipate (average molecular weight approximately i,
ooo, hydroxyl value 112)! , 000 parts, 31 parts of 1,4-butanediol, and 333 parts of diphenylmethane diisocyanate were added to 3,183 parts of methyl ethyl ketone,
The reaction was carried out at 70°C for 8 hours to obtain a polyurethane resin solution (A) with an average molecular weight of 65,000 and a solid content of 30%.
上記(A)、乳化剤、有機溶剤及び水をホモミキサーで
撹拌し、下記の本発明の消臭衣料に適用するポリウレタ
ン系乳濁液を調製した。The above (A), emulsifier, organic solvent, and water were stirred using a homomixer to prepare a polyurethane emulsion to be applied to deodorant clothing of the present invention as described below.
(1) ポリウレタン系乳濁液(A)ポリウレタン系
溶液(A) 100部ウレタン系乳化剤
2部酸化亜鉛 5
部硫酸アルミニウムカリウム 3部メチルエチ
ルケトン 20部トルエン
20部水
80部上記乳濁液Aを離型紙上に塗布量200
g/ボの割合で塗布し、130°Cで2時間乾燥後、
被膜を剥離して多孔性シートを得た。(1) Polyurethane emulsion (A) Polyurethane solution (A) 100 parts Urethane emulsifier
2 parts zinc oxide 5
Part potassium aluminum sulfate 3 parts methyl ethyl ketone 20 parts toluene
20 parts water
80 parts of the above emulsion A was applied in an amount of 200 parts on release paper.
After applying at a ratio of g/bo and drying at 130°C for 2 hours,
The coating was peeled off to obtain a porous sheet.
この得られた多孔性シートを上記の方法で脱臭効果を測
定したところ、下記のような有意差のある結果を得た。When the deodorizing effect of the obtained porous sheet was measured using the method described above, results with significant differences as shown below were obtained.
5背後30分後120分後 試料のサイズ、ブランク
4.400 4.400 4.400 50X 200
X 2本処理品 4,000 3,100 2,500
50X 200X 2B 硫 、の m
1日後3日後 7日後 試料のサイズ
ブランク 160 160 160 50X 2
0 X 2本処理品 10 ND ND
50X 20 X 2実施例6
ポリテトラメチレングルコール(平均分子量約1.00
0、水酸基価112)1.000部、エチレングリコー
ル24部及びジフェニルメタンジイソシアネート340
部をメチルエチルケトン3゜183部中に加え、70°
Cで9時間反応させ、平均分子量が5万2千である固形
分30%のポリウレタン系樹脂溶液(B)を得た。5 After 30 minutes After 120 minutes Sample size, blank
4.400 4.400 4.400 50X 200
X 2-piece processed product 4,000 3,100 2,500
50X 200X 2B Sulfuric acid, m After 1 day After 3 days After 7 days Sample size blank 160 160 160 50X 2
0 X 2-piece processed product 10 ND ND
50X 20X 2 Example 6 Polytetramethylene glycol (average molecular weight approximately 1.00
0, hydroxyl value 112) 1.000 parts, ethylene glycol 24 parts and diphenylmethane diisocyanate 340
183 parts of methyl ethyl ketone at 70°
C for 9 hours to obtain a polyurethane resin solution (B) with an average molecular weight of 52,000 and a solid content of 30%.
上記(B)、乳化剤、有機溶剤及び水をホモミキサーで
撹拌し、下記の本発明の消臭衣料に適用するポリウレタ
ン系乳濁液を調製した。The above (B), emulsifier, organic solvent, and water were stirred in a homomixer to prepare a polyurethane emulsion to be applied to the deodorant clothing of the present invention as described below.
(2) ポリウレタン系乳濁液(B)ポリウレタン
系溶液(B) loo部酸化亜鉛
5部ポリアクリル酸 5部ウ
レタン系乳化剤 2部メチルエチルケト
ン 20部トルエン
20部水 80
部上記乳濁液Bを離型紙上に塗布量200 g/ボの割
合で塗布し、130°Cで2分間乾燥後、被膜を剥離し
て多孔性シートを得た。(2) Polyurethane emulsion (B) Polyurethane solution (B) Loo part zinc oxide
5 parts polyacrylic acid 5 parts urethane emulsifier 2 parts methyl ethyl ketone 20 parts toluene
20 parts water 80
The above emulsion B was applied onto release paper at a coating amount of 200 g/bottom, and after drying at 130°C for 2 minutes, the coating was peeled off to obtain a porous sheet.
この得られた多孔性シートを上記の方法で脱臭効果を測
定したところ、下記のような有意差のある結果を得た。When the deodorizing effect of the obtained porous sheet was measured using the method described above, results with significant differences as shown below were obtained.
5背後30分後120分後 試料のサイズブランク4.
400 4,400 4,400 50X 200X
2本処理品4.000 3,700 3.000 50
X 200X 2B 硫化水素の脱臭能(ppm
1日後3日後 7日後 試料のサイズ
ブランク 160 160 160 50x 2
0 x 2本処理品 20 ND ND
50X 20 X 2実施例7
実施例1で得た脱臭性ポリウレタン系樹脂組成物を、実
施例1のポリウレタン樹脂に代えナイロン生地に、実施
例1と同様にして塗布してナイロン製加工布を得た。5 After 30 minutes After 120 minutes Sample size blank 4.
400 4,400 4,400 50X 200X
2-piece processed product 4.000 3,700 3.000 50
X 200X 2B Hydrogen sulfide deodorizing ability (ppm 1 day 3 days later 7 days later Sample size blank 160 160 160 50x 2
0 x 2 processed products 20 ND ND
50 x 20 Ta.
この得られた加工布について下記の方法で脱臭効果を測
定したところ、下記のような有意差のある結果を得た。When the deodorizing effect of the obtained processed cloth was measured using the method described below, results with significant differences as shown below were obtained.
300m l容三角フラスコに、28%アンモニア水を
1Ou1.採取して、完全にガス化させた後、サンプル
(サイズ50x200 mm、 1枚)を投入、25℃
に保存し、所定の時間経過後、北 用穴ガス検知器を用
いて、フラスコ内のアンモニア残存濃度を測定した。In a 300 ml Erlenmeyer flask, add 1 ounce of 28% ammonia water. After collecting and completely gasifying, a sample (size 50 x 200 mm, 1 piece) was placed at 25℃.
After a predetermined period of time, the residual concentration of ammonia in the flask was measured using a gas detector.
181m栗
300+112容三角フラスコに、800ppm硫化ナ
トリウム水容液を1ml、およびl規定硫酸1.0++
1を入れ、硫化水素を生成させ、サンプル(サイズ50
X200 M。In a 181 m chestnut 300 + 112 volume Erlenmeyer flask, add 1 ml of 800 ppm sodium sulfide aqueous solution and 1.0++ l normal sulfuric acid.
1 to generate hydrogen sulfide, and sample (size 50
X200M.
1枚)を投入、25℃に保存し、所定の時間経過後、凡
用式ガス検知器を用いて、フラスコ内の硫化水素残存濃
度を測定した。After a predetermined period of time, the residual concentration of hydrogen sulfide in the flask was measured using a general-purpose gas detector.
5背後30分後120分後 試料のサイズブランク6.
200 6.200 6,200 50x200本処理
品4,000 2.600 1,700 50x200
B)硫化水素の脱臭能(ppm )
1日後3日後 7日後 試料のサイズ
ブランク 140 − 50X200
本処理品 ND −50X200(発明の効果
)
上述の本発明の消臭衣料によれば、臭気を完全に防備す
ることができ、夏期でも蒸れることもなく快適に作業が
でき、作業後、他人に不快感を与える虞もない。5 After 30 minutes After 120 minutes Sample size blank 6.
200 6.200 6,200 50x200 processed product 4,000 2.600 1,700 50x200
B) Deodorizing ability of hydrogen sulfide (ppm) After 1 day After 3 days After 7 days Sample size blank 140 - 50X200
Treated product ND-50 There is no risk of causing discomfort.
本発明の消臭衣料は、衣料自体及び人体の皮膚頭髪等の
双方を臭気から守ることができ、かつ、任意の色調のも
のが容易に得られる。The deodorizing clothing of the present invention can protect both the clothing itself and the skin and hair of the human body from odors, and can be easily obtained in any color tone.
また、上記のように、衣料の外側からくる臭気ばかりで
なく、汗や体質によるもの、あるいはアルコール、大蒜
等のある種の香辛料等の大量摂取などによる匂いのよう
に、衣料の内側からくるものをも、必要に応じて防ぐこ
とができる。Also, as mentioned above, not only odors that come from the outside of clothing, but also odors that come from the inside of clothing, such as odors from sweat, physical constitution, or intake of large amounts of alcohol, certain spices such as garlic, etc. can also be prevented if necessary.
第1図 本発明による消臭衣料の外形図1服 2.3 帽子 4 ズポン Figure 1 Outline diagram of deodorant clothing according to the present invention 1 clothing 2.3 Hat 4 Zupon
Claims (6)
組成物を適用した素材により形成された生地から作製さ
れた消臭衣料 a ポリウレタン系樹脂、液媒体及び添加剤からなるポ
リウレタン系樹脂組成物において、添加剤の少なくとも
一部が実質的に白色又は無色の脱臭剤である。(1) Deodorizing clothing made from a fabric made from a material to which a deodorizing polyurethane resin composition having the following characteristics a is applied: In a polyurethane resin composition comprising a polyurethane resin, a liquid medium, and an additive. , at least a portion of the additive is a substantially white or colorless deodorant.
なる請求項(1)記載の消臭衣料。(2) The deodorizing clothing according to claim (1), wherein the deodorizing agent comprises an organic carboxylic acid and a zinc compound.
からなる請求項(1)記載の消臭衣料。(3) The deodorizing clothing according to claim (1), wherein the deodorizing agent comprises a zinc compound and an aluminum compound.
なる請求項(2)記載の消臭衣料。(4) The deodorant clothing according to claim (2), wherein the organic carboxylic acid is an aliphatic polycarboxylic acid.
なる請求項(2)記載の消臭衣料。(5) The deodorant clothing according to claim (2), wherein the organic carboxylic acid is an aromatic polycarboxylic acid.
る請求項(2)記載の消臭衣料。(6) The deodorant clothing according to claim (2), wherein the organic carboxylic acid is a polymer carboxylic acid.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63152652A JPH01104885A (en) | 1987-03-23 | 1988-06-21 | Deodorizing clothing |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62065754A JPH078952B2 (en) | 1987-03-23 | 1987-03-23 | Deodorant polyurethane resin composition |
JP63152652A JPH01104885A (en) | 1987-03-23 | 1988-06-21 | Deodorizing clothing |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP62065754A Division JPH078952B2 (en) | 1987-03-23 | 1987-03-23 | Deodorant polyurethane resin composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH01104885A true JPH01104885A (en) | 1989-04-21 |
JPH0210274B2 JPH0210274B2 (en) | 1990-03-07 |
Family
ID=26406899
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP63152652A Granted JPH01104885A (en) | 1987-03-23 | 1988-06-21 | Deodorizing clothing |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH01104885A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02289185A (en) * | 1989-04-26 | 1990-11-29 | Unitika Ltd | Production of deodorizing textile product |
JPH02289184A (en) * | 1989-04-26 | 1990-11-29 | Unitika Ltd | Deodorizing textile product |
JPH03106395U (en) * | 1990-02-14 | 1991-11-01 | ||
US6652845B2 (en) * | 2001-12-18 | 2003-11-25 | Kimberly-Clark Worldwide, Inc. | Layer materials treated with durable acidic odor control/binder systems |
US6767553B2 (en) | 2001-12-18 | 2004-07-27 | Kimberly-Clark Worldwide, Inc. | Natural fibers treated with acidic odor control/binder systems |
KR100452034B1 (en) * | 1996-06-11 | 2004-12-03 | 도레이 가부시끼가이샤 | Deodorant textile material and its manufacturing method |
JP2011079750A (en) * | 2009-10-05 | 2011-04-21 | Kao Corp | Liquid deodorant composition |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6215388A (en) * | 1985-07-12 | 1987-01-23 | カネボウ株式会社 | Durable deodorizing fiber structure |
-
1988
- 1988-06-21 JP JP63152652A patent/JPH01104885A/en active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6215388A (en) * | 1985-07-12 | 1987-01-23 | カネボウ株式会社 | Durable deodorizing fiber structure |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02289185A (en) * | 1989-04-26 | 1990-11-29 | Unitika Ltd | Production of deodorizing textile product |
JPH02289184A (en) * | 1989-04-26 | 1990-11-29 | Unitika Ltd | Deodorizing textile product |
JPH03106395U (en) * | 1990-02-14 | 1991-11-01 | ||
KR100452034B1 (en) * | 1996-06-11 | 2004-12-03 | 도레이 가부시끼가이샤 | Deodorant textile material and its manufacturing method |
US6652845B2 (en) * | 2001-12-18 | 2003-11-25 | Kimberly-Clark Worldwide, Inc. | Layer materials treated with durable acidic odor control/binder systems |
US6767553B2 (en) | 2001-12-18 | 2004-07-27 | Kimberly-Clark Worldwide, Inc. | Natural fibers treated with acidic odor control/binder systems |
JP2011079750A (en) * | 2009-10-05 | 2011-04-21 | Kao Corp | Liquid deodorant composition |
Also Published As
Publication number | Publication date |
---|---|
JPH0210274B2 (en) | 1990-03-07 |
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