JPH0218860A - Battery - Google Patents
BatteryInfo
- Publication number
- JPH0218860A JPH0218860A JP63168144A JP16814488A JPH0218860A JP H0218860 A JPH0218860 A JP H0218860A JP 63168144 A JP63168144 A JP 63168144A JP 16814488 A JP16814488 A JP 16814488A JP H0218860 A JPH0218860 A JP H0218860A
- Authority
- JP
- Japan
- Prior art keywords
- electrode
- battery
- fixing member
- positive electrode
- positive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052751 metal Inorganic materials 0.000 claims abstract description 18
- 239000002184 metal Substances 0.000 claims abstract description 18
- 239000003792 electrolyte Substances 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 238000010276 construction Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 description 14
- 238000003466 welding Methods 0.000 description 11
- 238000006116 polymerization reaction Methods 0.000 description 8
- 229920000767 polyaniline Polymers 0.000 description 7
- 229910052744 lithium Inorganic materials 0.000 description 6
- 229920001940 conductive polymer Polymers 0.000 description 5
- 238000007599 discharging Methods 0.000 description 5
- 239000007774 positive electrode material Substances 0.000 description 5
- 229910001220 stainless steel Inorganic materials 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
- -1 triethylphosphny-1- Chemical compound 0.000 description 5
- 229910000733 Li alloy Inorganic materials 0.000 description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000007772 electrode material Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000002861 polymer material Substances 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- JFDZBHWFFUWGJE-UHFFFAOYSA-N benzonitrile Chemical compound N#CC1=CC=CC=C1 JFDZBHWFFUWGJE-UHFFFAOYSA-N 0.000 description 3
- 239000001989 lithium alloy Substances 0.000 description 3
- 239000007773 negative electrode material Substances 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 238000002788 crimping Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 2
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 1
- JWUJQDFVADABEY-UHFFFAOYSA-N 2-methyltetrahydrofuran Chemical compound CC1CCCO1 JWUJQDFVADABEY-UHFFFAOYSA-N 0.000 description 1
- 229910000619 316 stainless steel Inorganic materials 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Cell Electrode Carriers And Collectors (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
【発明の詳細な説明】
倉栗上辺田圃−分互
本発明は、正極、負極、 ｆｌｔＭ質等の電池構成部材
が外装缶内に収容されてなる電池に関し、更に詳述する
と、電極と外装缶との良好なる電気的接続が保持され、
使用中に内部抵抗が急激に増加するなどの電極と外装缶
との間の接続不良に起因する不都合を生じることのない
簡易で信頼性の高い電池に関する。Detailed Description of the Invention The present invention relates to a battery in which battery components such as a positive electrode, a negative electrode, and fltM are housed in an outer can. A good electrical connection is maintained with the
The present invention relates to a simple and highly reliable battery that does not suffer from problems caused by poor connection between an electrode and an outer can, such as a sudden increase in internal resistance during use.
死米夙抜先
電池の構成は、通常正極、負極、電解質、セパレーター
等の電池構成部材が外装缶に収容された構成とされてい
る。このような電池において正極。The structure of a dead rice battery is usually such that battery components such as a positive electrode, a negative electrode, an electrolyte, and a separator are housed in an outer can. In such a battery the positive electrode.
負極は外装缶の正極部、負極部にそれぞれ電気的に接続
されるが、この接続に不良が生じると、電池作動時に電
気ノイズが入り、安定した出力が得られなくなる。外装
缶と電極との接続方法としては、従来から種々の方法が
採用、提案されており、例えば第９図に示したボタン電
池のように正極ａ及び負極すと正極缶Ｃとの間に弾性板
（スプリング）ｄを介装し、弾性板ｄの押圧力によって
正・負極ａ、ｂと正・負極部Ｑ、ｅとの接触状態を保っ
ているもの、第１０図に示したコイン形電池のように金
属ネットｆ、ｆを予め正・負極部ｃ、ｅに溶接し、その
金属ネットｆ、ｆの凹凸内に正・負極ａ、ｂを埋め込む
ことによって正・負極ａ。The negative electrode is electrically connected to the positive and negative electrodes of the outer can, respectively, but if a fault occurs in these connections, electrical noise will occur during battery operation, making it impossible to obtain stable output. Various methods have been adopted and proposed for connecting the outer can and the electrodes. For example, as in the button battery shown in Fig. A coin-shaped battery shown in Fig. 10, in which a plate (spring) d is interposed and the positive/negative electrodes a, b and the positive/negative electrode parts Q, e are kept in contact by the pressing force of the elastic plate d. Positive and negative electrodes a are formed by welding metal nets f and f to the positive and negative electrode parts c and e in advance, and embedding the positive and negative electrodes a and b in the unevenness of the metal nets f and f, as shown in FIG.
ｂと正・負極部ａ、ｅとが接続されているもの、また第
１１図に示したコイン形電池のように集電体として正極
ａに埋設した金属ネット（正極集電体）ｇの金属露出箇
所と正極缶Ｃとを溶接り、ｈしたものなどがある。なお
第１〜３図中ｉは負極四重体、Ｊはセパレーター、ｋは
パツキン、■はガスケットである。b and the positive and negative electrode parts a and e are connected, and the metal of the metal net (positive electrode current collector) g embedded in the positive electrode a as a current collector like the coin-shaped battery shown in FIG. There is one in which the exposed part and the positive electrode can C are welded together. In FIGS. 1 to 3, i is a negative electrode quadruple, J is a separator, k is a packing, and ■ is a gasket.
発明が解決しようとする課題
ここで電池を構成するにあたり、要求されることは、規
格化された電池容器内にできるだけ多量の電極活物質を
つめ込み、高容量を達成すると共に、安定した出力を維
持し、かつ安価にて１１造することであるが、上記の電
池はこれらの点で問題点を有する。即ち、第９図に示し
たボタン形電池にあっては、弾性板ｄが１！池容器内で
余分な容積を占有し、電極活物質の収容スペースが少な
くなってしまう。また、第１０図に示したコイン形電池
にあっては、金属ネットｆへの電極活物質の埋め込みで
は、強固なＷ１極と外装缶との固着状態が得られず、長
期信頼性に乏しい。更に、第１１図のコイン形電池は正
極ａと外装缶Ｃとの電気的接続は強固で信頼性は高いが
、その製造工程が煩雑になり、コスト高になってしまう
。Problems to be Solved by the Invention When constructing a battery, what is required is to pack as much electrode active material as possible into a standardized battery container, to achieve high capacity, and to maintain stable output. However, the above-mentioned batteries have problems in these respects. That is, in the button type battery shown in FIG. 9, the elastic plate d is 1! This occupies extra volume within the pond container, reducing the space available for accommodating the electrode active material. Furthermore, in the coin-shaped battery shown in FIG. 10, embedding the electrode active material in the metal net f does not provide a strong adhesion between the W1 electrode and the outer can, resulting in poor long-term reliability. Furthermore, although the coin-shaped battery shown in FIG. 11 has a strong electrical connection between the positive electrode a and the outer can C and is highly reliable, the manufacturing process is complicated and the cost is high.
本発明は、上記事情に鑑みなされたもので、使用中に内
部抵抗が急激に増加するようなことのない安定した電極
と外装缶との電気的接続が保持され、更に電池容器（外
装缶）の容積をむだなく有効に使用し得、かつ安価にて
製造することができる電池を提供することを目的とする
。The present invention was made in view of the above circumstances, and it maintains a stable electrical connection between the electrode and the outer can without causing a sudden increase in internal resistance during use. An object of the present invention is to provide a battery that can use the volume of the battery effectively without wasting it, and can be manufactured at low cost.
を するための び
本発明は、上記目的を達成するため、正極、負極及び電
解質を具備し、これら電池構成部材を外装缶内に収容し
てなる電池において、」１記正極及び／又は負極に金属
製電極固定部材をこれに突設された突起を打ち込むこと
により一体化し、この固定部材を外装缶に導電状態に固
定して、該正極及び／又は負極を上記固定部材を介して
上記外装缶に電気的に接続したことを特徴とする電池を
提供するものである。In order to achieve the above object, the present invention provides a battery comprising a positive electrode, a negative electrode, and an electrolyte, and in which these battery components are housed in an outer case. A metal electrode fixing member is integrated by driving a protrusion into it, and this fixing member is fixed to the outer can in a conductive state, and the positive electrode and/or negative electrode is attached to the outer can via the fixing member. The present invention provides a battery characterized in that the battery is electrically connected to the battery.
即ち、本発明電池は、金属製電極固定部材をこれに突設
された突起を正極及び／又は負極に打ち込むことにより
正極及び／又は負極と一体化し。That is, in the battery of the present invention, a metal electrode fixing member is integrated with a positive electrode and/or a negative electrode by driving a projection provided thereon into the positive electrode and/or negative electrode.
この固定部材を外装缶に導電状態に固定させたことによ
って、外装缶と正極や外装缶と負極との安定した電気的
接続が上記固定部材を介して保持されると共に、電池容
器（外装缶）内のスペースを有効に利用し得、更に電池
の製造工程において電極内の集電体を露出させる作業、
リード線のとり出し等の余分な］−程を省略して製造工
程を簡略化し得る簡易で信頼性の高い高性能電池である
。By fixing this fixing member to the outer can in a conductive state, a stable electrical connection between the outer can and the positive electrode and between the outer can and the negative electrode is maintained via the fixing member, and the battery container (outer can) work that allows effective use of internal space and exposes the current collector within the electrode during the battery manufacturing process;
This is a simple, highly reliable, and high-performance battery that can simplify the manufacturing process by omitting unnecessary steps such as taking out lead wires.
以下、本発明につき更に詳しく説明する。The present invention will be explained in more detail below.
本発明に係る電池は、上記したように正極、負極及び電
解質を具備し、これら電池構成部材を外装缶内に１戊容
してなるものである。As described above, the battery according to the present invention includes a positive electrode, a negative electrode, and an electrolyte, and these battery components are housed in an outer case.
ここで、上記正極及び負極を構成する活物質としては、
特に制限されるものではないが、後述する電極固定部材
の突起を打ち込み易い金属或いは金属酸化物、金属硫化
物、フッ化炭素、有機導電性高分子材料等の粉体をバイ
ンダーで固めたもの又は電解重合法により製造した膜状
の有機導電性高分子材料等が好適に使用される。これら
の中で特に正極活物質としては、電解重合法により製造
した膜状の有機導電性高分子材料、特にポリアニリン又
はその誘導体が好適に用いられる。ここで、本発明電池
に用いられるｆｆ１極には、後述する固定部材を固定し
易く、かつ集電効率が高いために固定部材を小形化でき
るという点から内部に全屈製集電極を有するものが好ま
しいが、電極活物質として上記の電解重合法により製造
した有機導電性高分子膜を使用する場合、その電解重合
時に重合極として用いた金ｙＣ１！極をそのまま電池電
極の集電極とすることができる。なお、この場合集電極
（電解重合時には重合極）としては、網状金属が好まし
い。また、正極活物質として有機導電性高分子材料、特
にポリアニリン又はその誘導体を用いる場合、負極活物
質としてはリチウム金属又はクチ９１１合金を使用する
ことが好ましい。この場合、リチウム合金の種類に特に
制限はなく、例えばリチウムとアルミニウム、マグネシ
ウム、インジウム、水銀、亜鉛、カドミウム、鉛、ビス
マス、錫、アンチモン等の１種又は２種以上との合金な
どを好適に使用し得る。これらの中では、特にアルミニ
ウムとリチウムとの合金を用いることが負極特性、成形
性の点で好ましい。なお、リチウム合金を使用する場合
、リチウムと合金化すべき金属のリチウム合金化は電池
容器内で行なうことができる。Here, the active materials constituting the positive electrode and negative electrode are as follows:
Although not particularly limited, metals or powders of metal oxides, metal sulfides, carbon fluoride, organic conductive polymer materials, etc. hardened with a binder into which the protrusions of the electrode fixing member described later can be easily driven, or A membrane-shaped organic conductive polymer material produced by electrolytic polymerization is preferably used. Among these, particularly as the positive electrode active material, a membrane-shaped organic conductive polymer material produced by electrolytic polymerization, particularly polyaniline or a derivative thereof, is preferably used. Here, the ff1 pole used in the battery of the present invention has a fully bent collector electrode inside because it is easy to fix the fixing member described later and the fixing member can be made smaller due to its high current collection efficiency. However, when using the organic conductive polymer film produced by the above electrolytic polymerization method as the electrode active material, the gold yC1! used as the polymerization electrode during the electrolytic polymerization is preferable. The electrode can be used as it is as a collecting electrode of a battery electrode. In this case, the collector electrode (or polymerization electrode in electrolytic polymerization) is preferably a mesh metal. Furthermore, when an organic conductive polymer material, particularly polyaniline or a derivative thereof, is used as the positive electrode active material, it is preferable to use lithium metal or Kuchi 911 alloy as the negative electrode active material. In this case, there is no particular restriction on the type of lithium alloy; for example, alloys of lithium and one or more of aluminum, magnesium, indium, mercury, zinc, cadmium, lead, bismuth, tin, antimony, etc. are preferable. Can be used. Among these, it is particularly preferable to use an alloy of aluminum and lithium in terms of negative electrode characteristics and formability. Note that when a lithium alloy is used, lithium alloying of the metal to be alloyed with lithium can be performed within the battery container.
次に、電解質としては、特に限定されるものではなく、
正極活物質及び負極活物質の種類、つまり電池系によっ
て適宜選択され、液体電解質（電解液）でも固体電解質
でも良い。例えば、正極活物質としてポリアニリン又は
その誘導体、負極活物質としてリチウム金属又はリチウ
ム合金を使用する場合、電解液としては、特に限定され
るものではないが、ＬｉＣＱＯ４，Ｌｉ、ＢＦ４．Ｌｉ
ＰＦ、。Next, the electrolyte is not particularly limited,
The type of positive electrode active material and negative electrode active material, that is, the battery system, is appropriately selected, and the electrolyte may be a liquid electrolyte (electrolytic solution) or a solid electrolyte. For example, when polyaniline or a derivative thereof is used as the positive electrode active material, and lithium metal or lithium alloy is used as the negative electrode active material, the electrolyte is not particularly limited, but LiCQO4, Li, BF4. Li
P.F.
Ｌｉ５Ｏ，ＣＦ、などの電解質をプロピレンカーボネー
ト、エチレンカーボネート、ベンゾニトリル。Propylene carbonate, ethylene carbonate, benzonitrile as an electrolyte such as Li5O, CF, etc.
テトラヒドロフラン、２−メチルテトラヒドロフラン、
γ−ブチロラクトン、ジオキソラン、塩化メチレン、ト
リエチルフォスフニー１−、トリエチルフォスアアイト
、硫酸ジメチル、ジメチルホルムアミド、ジメチルアセ
トアミド、ジメチルスルフオキシドデジオキサン、ジメ
トキシエタン、ポリエチレングリコール、スルフオラン
、ジクロロエタン、クロルベンゼン、ニトロベンゼンな
どの有機溶媒の１種又は２種以上の混合物に溶解したも
のなどが好適に用いられる。Tetrahydrofuran, 2-methyltetrahydrofuran,
γ-Butyrolactone, dioxolane, methylene chloride, triethylphosphny-1-, triethylphosphite, dimethyl sulfate, dimethylformamide, dimethylacetamide, dimethylsulfoxide dedioxane, dimethoxyethane, polyethylene glycol, sulfolane, dichloroethane, chlorobenzene, nitrobenzene Those dissolved in one kind or a mixture of two or more kinds of organic solvents are preferably used.
本発明の電池は１通常上記の正・負極間に電解液を介在
させることにより構成することができるが、この場合正
・負両極間に両極の接触による電流の短絡を防ぐためセ
パレーターを介装することができる。セパレーターとし
ては多孔質でガミ留液を通したり含んだりすることので
きる材料、例えばポリテトラフルオロエチレン、ポリプ
ロピレンやポリエチレンなどの合成樹脂製の不織布、織
布及び網等を使用することができる。The battery of the present invention can usually be constructed by interposing an electrolyte between the above positive and negative electrodes, but in this case, a separator is interposed between the positive and negative electrodes to prevent short circuit of current due to contact between the two electrodes. can do. As the separator, it is possible to use a material that is porous and can allow the gummy distillate to pass through or contain it, such as nonwoven fabric, woven fabric, or net made of synthetic resin such as polytetrafluoroethylene, polypropylene, or polyethylene.
面して、本発明に係る電池は、上記正・負極及び電解質
、更に必要によりセパレーターを電池構成要素とし、そ
の他電池の種類に応じて用いる電池構成要素を外装缶（
電池容器）に収容したものであるが、この外装缶に電池
構成要素を収容するに際し、金属製電極固定部材をこれ
に突設された突起を正極及び／又は負極に打ち込むこと
により正極及び／又は負極と一体化し、この固定部材を
外装缶に導電状態に固定させることによって、外装缶と
正極及び／又は外装缶と負極とを電気的に接続したもの
である。On the other hand, the battery according to the present invention includes the above-mentioned positive and negative electrodes, electrolyte, and if necessary, a separator as battery components, and other battery components used depending on the type of battery in an outer can (
When housing the battery components in this exterior can, the positive electrode and/or By integrating with the negative electrode and fixing this fixing member to the outer can in a conductive state, the outer can and the positive electrode and/or the outer can and the negative electrode are electrically connected.
ここで、上記金属ｇ！電極固定部材は、打ち込み用突起
を有し、該突起を電極に打ち込んで電極と一体化するこ
とができ、更にこの場合電極の少なくとも一面側に固定
部材の一部が露出するような構成であればどのような形
状であってもよく、例えば第３図に示すような線状主体
１ｏの長さ方向両端部をそれぞれ直角に折曲すると共に
、これら折曲突起７．７の先端をそれぞれ尖らせた鏡影
状のものが挙げられる。なお、この固定部材の材質とし
ては、導電性に優れる金属であればよく、特に制限され
るものではないが、特にＴｉ、Ｎｉ等の純金属、ＳＵＳ
３１６．ＳＵＳ ３０４．ＳＵＳ ４３０゜ＳＵ
Ｓ ４４７等のステンレス鋼などが好適に用いられ、
電解質、電極、使用電圧、使用方法等を考慮し、腐蝕が
生じないような材質が選ばれる。Here, the above metal g! The electrode fixing member has a driving protrusion, and can be integrated with the electrode by driving the protrusion into the electrode, and in this case, a part of the fixing member may be exposed on at least one side of the electrode. For example, as shown in FIG. 3, both lengthwise ends of the linear main body 1o are bent at right angles, and the tips of these bent protrusions 7. Examples include mirror-like objects. Note that the material of this fixing member is not particularly limited as long as it is a metal with excellent conductivity, but in particular, pure metals such as Ti and Ni, SUS
316. SUS304. SUS 430゜SU
Stainless steel such as S447 is preferably used,
Materials that will not corrode are selected by considering the electrolyte, electrodes, voltage used, method of use, etc.
上記固定部材を外装缶に固定する方法としては、固定部
材と外装缶とを導電状態に接続し得る方法であればいか
なる方法を採用してもよく、特に制限されるものではな
いが、良好な導電状態を維持することができ、かつ強固
に固着することができることからレーザー溶接法、抵抗
溶接法等の溶接法が好適に採用される。Any method may be used to fix the fixing member to the outer can as long as it connects the fixing member and the outer can in a conductive state, and is not particularly limited. Welding methods such as laser welding and resistance welding are preferably employed because they can maintain a conductive state and are firmly fixed.
なお、外装缶（電池容器）は通常正極缶と負極缶とから
構成されるが、その形状は特に制限されず、コイン形９
円筒形２箱形、シート形等、各種形状に形成することが
できる。Note that the outer can (battery container) is usually composed of a positive electrode can and a negative electrode can, but its shape is not particularly limited and may be coin-shaped.
It can be formed into various shapes such as a cylindrical two-box shape and a sheet shape.
次に、本発明電池の好適な実施態様につき第１〜７図を
参照して説明する。Next, a preferred embodiment of the battery of the present invention will be described with reference to FIGS. 1 to 7.
第１図は、本発明にかかるコイン形電池の一例を示すも
ので、図中１は上端が開口する皿状の外装缶本体（正極
缶）、２はこの外装缶本体１の上端開口部を閉塞する蓋
体（負極缶）であり、外装缶本体１内に正極３と負極４
とがセパレーター５を介して積層された積層形構成の電
極が収容されている・ここで、上記正極３には、その下
面から第３図に示す鏡状の金属製電極固定部材６の突起
７．７が貫通しており、この突起７，７の先端部９．９
が更に折曲して固定部材６と正極３とが一体化している
。更にこの固定部材６は外装缶本体１の底壁内面に導電
状態に固着されている。なお図中８は絶縁パツキンであ
る。FIG. 1 shows an example of a coin-shaped battery according to the present invention. In the figure, 1 indicates a dish-shaped outer can body (positive electrode can) with an open top end, and 2 indicates the top opening of the outer can body 1. It is a lid body (negative electrode can) that closes, and a positive electrode 3 and a negative electrode 4 are placed inside the outer can body 1.
A stacked electrode is housed in which the positive electrode 3 is stacked with a separator 5 in between. Here, the positive electrode 3 has a protrusion 7 of a mirror-shaped metal electrode fixing member 6 shown in FIG. .7 passes through, and the tips 9.9 of these protrusions 7, 7
is further bent to integrate the fixing member 6 and the positive electrode 3. Furthermore, this fixing member 6 is fixed to the inner surface of the bottom wall of the outer can body 1 in a conductive state. Note that 8 in the figure is an insulating packing.
かかる電池を製造する場合は、まず第２図に示すように
正極３の一面側から固定部材６の突起７．７を打ち込み
貫通させ、正極３の他面から突出した突起７，７の先端
部９．９を折曲し、正極３と固定部材６とを一体化させ
る。なお、上記固定部材６は第３図に示すように線状主
体１０の長さ方向両端部をそれぞれ直角に折曲した鋸状
のもので、この折曲突起７，７の先端部は共に尖らせて
あり、容易に電極に打ち込めるようになっている。また
、固定部材６の寸法は、正極３の厚み、面積、集電効率
等に応じて適宜設定される。When manufacturing such a battery, first, as shown in FIG. 2, the protrusions 7, 7 of the fixing member 6 are driven through from one side of the positive electrode 3, and the tips of the protrusions 7, 7 protruding from the other side of the positive electrode 3 are inserted. 9.9 is bent to integrate the positive electrode 3 and the fixing member 6. As shown in FIG. 3, the fixing member 6 has a serrated shape in which both longitudinal ends of the linear main body 10 are bent at right angles, and the tips of the bent protrusions 7 are both sharp. It is placed so that it can be easily driven into the electrode. Further, the dimensions of the fixing member 6 are appropriately set according to the thickness, area, current collection efficiency, etc. of the positive electrode 3.
次に、上記の正極３と固定部材料６との一体物を第４図
に示すように外装缶本体１内に固定部材６の主体１０が
露出している側の面を下にして収容し、固定部材６を外
装缶本体１の底壁内面に導電状態に固着する。この場合
、固定部材６を外装缶本体１に固着する方法としては、
抵抗溶接法が好適に採用される。Next, as shown in FIG. 4, the integral body of the positive electrode 3 and the fixing part material 6 is housed in the outer can body 1 with the side where the main body 10 of the fixing member 6 is exposed facing down. , the fixing member 6 is fixed to the inner surface of the bottom wall of the outer can body 1 in a conductive state. In this case, the method for fixing the fixing member 6 to the outer can body 1 is as follows:
Resistance welding is preferably employed.
なお、正極３と固定部材６との一体化及びこの正極３と
固定部材６との一体化物を外装缶本体１に固定する方法
は、上記方法に限定されず、例えば第５図に示すように
予め外装缶本体１の底壁内面にレーザー溶接、抵抗溶接
等によって固定部材６を固着しておき、この上から正極
３を押し込んで固定部材６の突起７，７を正極３に貫通
させ、その先端突出部分を折曲するようにしてもよい。Note that the method for integrating the positive electrode 3 and the fixing member 6 and for fixing the integrated product of the positive electrode 3 and the fixing member 6 to the outer can body 1 is not limited to the above method, and for example, as shown in FIG. The fixing member 6 is fixed in advance to the inner surface of the bottom wall of the outer can body 1 by laser welding, resistance welding, etc., and the positive electrode 3 is pushed in from above so that the protrusions 7, 7 of the fixing member 6 penetrate the positive electrode 3. The tip protruding portion may be bent.
次いで、上記の外装缶本体１内に固着された正極３と固
定部材６との一体物の−Ｌにセパレーター５及び負極４
を順次積層し、更に外装缶本体】内に電解液を注液した
後、負極４の上から蓋体２を被せると共に蓋体２と外装
缶本体１との間に絶縁性材料よりなるパツキン８を介装
し、加締加工を施すことにより、蓋体２で外装缶本体１
を閉塞し、第１図の電池が構成される。Next, the separator 5 and the negative electrode 4 are attached to the integrated body -L of the positive electrode 3 and the fixing member 6 fixed in the outer can body 1.
After successively stacking the above and pouring electrolyte into the outer can body, the lid 2 is placed over the negative electrode 4, and a packing 8 made of an insulating material is placed between the lid 2 and the outer can body 1. By interposing the outer can body 1 with the lid body 2 and performing crimping process,
The battery shown in FIG. 1 is constructed.
この電池によれば、正極３と一体化した電極固定部材６
が溶接により強固に外装缶本体１にｆｉ’ｊ着され、こ
のため正極３と外装缶本体１との安定した電気的接続が
上記固定部材６を介して長期に亘り保持される。また、
バネなどを使用しないので外装缶のスペースを有効に利
用し得ると共に、ｆ１！極の部分的剥離及びリード線の
とり出し等の余分な工程を省略することができ、製造工
程が簡略化される。According to this battery, the electrode fixing member 6 integrated with the positive electrode 3
is firmly attached to the outer can body 1 by welding, and therefore a stable electrical connection between the positive electrode 3 and the outer can body 1 is maintained for a long period of time via the fixing member 6. Also,
Since no springs are used, the space in the outer can can be used effectively, and f1! Extra steps such as partial peeling off of the poles and taking out the lead wires can be omitted, and the manufacturing process is simplified.
なお、」−起倒においては、正極のみを電極固定部材を
用いて外装缶に固定したが、正・負両極又は負極のみを
固定部材を用いて固定するようにしてもよく、また外装
缶の形状、封口方法等も上記例に限定されるものではな
い。更に、上記の第３図に示された鋸状の電極固定部材
６を用いた電極の固定方法も上記例に限定されるもので
はなく、例えば、第６図に示すように外装缶本体１内に
第２図に示した正極３と電極固定部材６との一体物を固
定部材６の突起先端部９，９が露出している側の面を下
にして収容し、固定部材６の突起先端部９，９を外装缶
本体１の底壁内面に導電状態に固着することもできる。In addition, in the case of raising and lowering, only the positive electrode was fixed to the outer can using an electrode fixing member, but it is also possible to fix both the positive and negative electrodes or only the negative electrode using a fixing member. The shape, sealing method, etc. are not limited to the above examples. Furthermore, the method of fixing an electrode using the saw-shaped electrode fixing member 6 shown in FIG. 3 above is not limited to the above example. For example, as shown in FIG. In this case, the integrated positive electrode 3 and electrode fixing member 6 shown in FIG. The parts 9, 9 can also be fixed to the inner surface of the bottom wall of the outer can body 1 in a conductive manner.
なおこの場合、第７図に示すように、外装缶本体１に正
極コ３を収容し、その上から固定部材６をプレス１１に
より押し込み。In this case, as shown in FIG. 7, the positive electrode 3 is housed in the outer can body 1, and the fixing member 6 is pushed in from above using a press 11.
正極３と固定部材６との一体化及びこの一体物の外装缶
本体１への収容を同時に行なうことができる。更にブレ
ス１１と同時に抵抗溶接を行なうようにしてもよい。The positive electrode 3 and the fixing member 6 can be integrated and the integrated body can be housed in the outer can body 1 at the same time. Furthermore, resistance welding may be performed simultaneously with the brace 11.
２泄Ｒ蔓劃釆
以上説明したように１本発明電池は、その使用中に内部
抵抗が急激に増加するようなことのない安定した電極と
外装缶との電気的接続が保持され。As explained above, the battery of the present invention maintains a stable electrical connection between the electrode and the outer can without causing a sudden increase in internal resistance during use.
更に電池容器（外装缶）の容積をむだなく有効に使用し
得、かつその製造に際しては、簡易な方法により安価に
て製造することができるものである。Furthermore, the volume of the battery container (exterior can) can be used effectively without wasting it, and it can be manufactured by a simple method at low cost.
以下、実施例及び比較例を示し、本発明を具体的に説明
するが１本発明は下記の実施例に制限されるものではな
い。EXAMPLES Hereinafter, the present invention will be specifically explained with reference to Examples and Comparative Examples, but the present invention is not limited to the following Examples.
１モル／Ｑのアニリンと２モル／ＱのＨＢＦ。 1 mol/Q aniline and 2 mol/Q HBF.
を含有する水溶液中でＳＵＳ ３１６ステンレス鋼メ
ツシユ上に電解重合法でポリアニリンを重合析出させ、
ステンレス鋼メツシュとポリアニリンとの一体物を得た
。この一体物を蒸留水で充分に洗浄し、室温で１日乾燥
後、−減圧下で２日間乾燥した。次に、この一体物を直
径１５閣のポンチで打ち抜き、電池正極とした。なお、
この正極中のポリアニリン膜の重量は約５２■であった
。この正極の一面側から５ＵＳ３１ＧＶＤ金属片を第３
図に示したように鋸状に折り曲げた電極固定部材６の突
起７．７を第２図に示したように貫通させ、先端部９，
９を折り曲げて正極と固定部材との一体物を作成した０
次いで第４図に示したように直径２０ＩＩＩ１１の外装
缶１内に上記一体物を静置し、正極３から露出している
固定部材６の突起先端部９，９から抵抗溶接Ｅ、Ｅを施
し、正極３を固定部材６を介して外装缶１内に固定した
。Polyaniline is polymerized and deposited on SUS 316 stainless steel mesh by electrolytic polymerization in an aqueous solution containing
An integrated product of stainless steel mesh and polyaniline was obtained. This integrated product was thoroughly washed with distilled water, dried for one day at room temperature, and then dried for two days under reduced pressure. Next, this one piece was punched out using a punch with a diameter of 15 mm to form a battery positive electrode. In addition,
The weight of the polyaniline film in this positive electrode was about 52 cm. Place the third 5US31GVD metal piece from one side of this positive electrode.
As shown in the figure, the projections 7 and 7 of the electrode fixing member 6 bent into a saw shape are penetrated as shown in FIG.
9 was bent to create an integrated body of the positive electrode and the fixing member.
Next, as shown in FIG. 4, the above-mentioned integrated body was placed in an outer can 1 having a diameter of 20III11, and resistance welding E, E was applied from the protrusion tips 9, 9 of the fixing member 6 exposed from the positive electrode 3. , the positive electrode 3 was fixed inside the outer can 1 via the fixing member 6.
一方、負極としては、直径１５ａｉ、厚さ０．２１のア
ルミ２９１１円板の一面に円板状のリチウムを圧着して
形成したリチウム・アルミニウム合金を使用し、この負
極をセパレーターを介して上記正極上に積層し、電解液
としてＬ ｉ Ｂ Ｆ、を含むプロピレンカーボネート
とジメトキシエタンとの混合溶媒を使用して第１図に示
した厚さ１．６閣、直径２０ｍのコイン型電池を作製し
た。On the other hand, as the negative electrode, we used a lithium-aluminum alloy formed by pressing a disk-shaped lithium onto one surface of an aluminum 2911 disk with a diameter of 15 ai and a thickness of 0.21. A coin type battery with a thickness of 1.6 mm and a diameter of 20 m as shown in Fig. 1 was fabricated using a mixed solvent of propylene carbonate and dimethoxyethane containing L i B F as an electrolyte. .
次に、上記電池に対して、１ｍＡの定電流にて３．０■
まで充電し、１ｍＡの定電流にて２．ＯＶまで放電した
ところ、放電容量は３．０３ｍＡｈであった。更に同様
の充放電を繰り返したところ、１００回目の放電容量は
２．９５ｍＡｈであった。Next, apply 3.0μ to the above battery at a constant current of 1mA.
2. Charge to 1 mA constant current. When discharged to OV, the discharge capacity was 3.03 mAh. When the same charging and discharging was repeated, the 100th discharge capacity was 2.95 mAh.
（比較例１〕
上記実施例と同様にして作製した正極を固定部材を使用
せずに第８図に示したように、正極３の径方向両端部に
形成したステンレスメツシュ露出部分１２．１２を外装
缶本体１に抵抗溶接Ｅ、Ｅした。なお、正極中のポリア
ニリン膜の重量は実施例のものより内部のステンレスメ
ツシュを露出させた分だけ少なく、約４６．であった。(Comparative Example 1) A positive electrode produced in the same manner as in the above example was used without using a fixing member, and as shown in FIG. were resistance welded E and E to the outer can body 1.The weight of the polyaniline film in the positive electrode was about 46 mm, which was less than that of the example due to the exposure of the internal stainless steel mesh.
次に、負極、セパレーター、電解液等上記実施例と同様
のものを使用し、同様の方法により同形状の電池を作製
した。Next, a battery of the same shape was produced by the same method using the same negative electrode, separator, electrolyte, etc. as in the above example.
上記電池について、実施例と同様の充放電試験を行なっ
たところ、１回目の放電容量は２．７６ｍＡｈ、１００
回目の放電容量は２．６１ｍＡｈであり、正極活物質の
量が少ない分んだけ放電容量が小さかった。また、この
電池はその製造課程において、正極のポリアニリン−ス
テンレスメツシュ一体物の露出部分を形成する工程は、
ステンレスメツシュが十分に露出していないと外装缶へ
の溶接が不可となるため、細心の注意を要し、非常に手
間のかかるものであった。When the above battery was subjected to the same charging and discharging test as in the example, the first discharge capacity was 2.76mAh, 100mAh.
The discharge capacity for the second time was 2.61 mAh, and the discharge capacity was small as the amount of positive electrode active material was small. In addition, in the manufacturing process of this battery, the step of forming the exposed portion of the polyaniline-stainless mesh integral part of the positive electrode is as follows:
If the stainless steel mesh is not sufficiently exposed, welding to the outer can is impossible, which requires careful attention and is extremely time-consuming.
〔比較例２〕
上記実施例と同様にして作製した正極を電極固定部材を
使用せずに外装缶内にスポット溶接された直径１５ｍの
ＳＵＳ ３１６１ｆ１１のステンレス鋼円板に圧着す
ることにより外装缶に固定した以外は実施例と同様にし
てコイン形電池を作製した。[Comparative Example 2] A positive electrode produced in the same manner as in the above example was attached to an outer can by crimping it to a 15 m diameter SUS 3161F11 stainless steel disc spot-welded inside the outer can without using an electrode fixing member. A coin-shaped battery was produced in the same manner as in the example except that it was fixed.
上記電池について、実施例と同様の充放電試験を行なっ
たところ、１回目の放電容量は３．０１ｍＡであった。When the above battery was subjected to the same charging and discharging test as in the example, the first discharge capacity was 3.01 mA.
ところがサイクル数８回目から放電時に電気的ノイズが
入り、以後内部抵抗が増大し、サイクル数２０回目で充
放電ができなくなった。However, after the 8th cycle, electrical noise occurred during discharging, and the internal resistance increased thereafter, making charging and discharging impossible at the 20th cycle.
以上の結果より、本発明の電池は、簡易な方法により製
造することができ、かつ（ｉ頼性の高い高性能なもので
あることが確認された。From the above results, it was confirmed that the battery of the present invention can be manufactured by a simple method, and is highly reliable and high performance.
第１図は、本発明の一実施例に係る電池を示す断面図、
第２図Ａ及びＢは、同電池を構成する正極部分を示し、
Ａ図は平面図、Ｂ図は断面図、第３図Ａ及びＢは同電池
を構成する電極固定部材を示し、Ａ図は平面図、Ｂ図は
正面図、第４図Ａ及びＢは第２図に示した正極部を外装
缶に収容したところを示し、Ａ図は平面図、Ｂ図は断面
図、第５図Ａ及びＢは外装缶に電極固定部材を固定した
状態を示し、Ａ図は平面図、Ｂ図は断面図、第６図は正
極部を外装缶に収容した他の状態を示す断面図、第７図
は同状態に正極部を外装缶に収容する方法を説明する断
面図、第８図Ａ及びＢは・比較例１の電池の正極部分を
示し、Ａ図は平面図、Ｂ図は断面図、第９〜１１図はそ
れぞれ、異なる従来例を示し、第９，１１図は断面図、
第１０図は部分断面正面図である。
１・・・外装缶本体 ２・・・蓋体３・・・正極
４・・・負極５・・・セパレーター ６・
・・電極固定部材７・・・突起 ８・・・パ
ツキン出願人 株式会社 ブリデス１−ン
代理人 弁理士 小 島 隆 司
第５図
第９図
第１０図
第１１図FIG. 1 is a sectional view showing a battery according to an embodiment of the present invention;
Figures 2A and B show the positive electrode part constituting the battery,
Figure A is a plan view, Figure B is a sectional view, Figures 3A and B show the electrode fixing member that constitutes the battery, Figure A is a plan view, Figure B is a front view, and Figures 4A and B are sectional views. Figure 2 shows the positive electrode part shown in the outer can housed, Figure A is a plan view, Figure B is a sectional view, Figures A and B show the state in which the electrode fixing member is fixed to the outer can, and Figure A is a plan view. The figure is a plan view, Figure B is a cross-sectional view, Figure 6 is a cross-sectional view showing another state in which the positive electrode part is housed in the outer can, and Figure 7 explains how to house the positive electrode part in the outer can in the same state. 8A and 8B show the positive electrode part of the battery of Comparative Example 1, A is a plan view, B is a sectional view, and FIGS. 9 to 11 respectively show different conventional examples. , 11 is a cross-sectional view,
FIG. 10 is a partially sectional front view. 1... Exterior can body 2... Lid body 3... Positive electrode
4... Negative electrode 5... Separator 6.
...Electrode fixing member 7...Protrusion 8...Patsukin Applicant Brides 1 Co., Ltd. Agent Patent attorney Takashi Kojima Figure 5 Figure 9 Figure 10 Figure 11
Claims (1)
材を外装缶内に収容してなる電池において、上記正極及
び／又は負極に金属製電極固定部材をこれに突設された
突起を打ち込むことにより一体化し、この固定部材を外
装缶に導電状態に固定して、該正極及び／又は負極を上
記固定部材を介して上記外装缶に電気的に接続したこと
を特徴とする電池。1. In a battery comprising a positive electrode, a negative electrode, and an electrolyte, and in which these battery components are housed in an exterior can, driving a metal electrode fixing member into the positive electrode and/or negative electrode with a protrusion protruding from the metal electrode fixing member. A battery characterized in that the fixing member is fixed to the outer can in a conductive state, and the positive electrode and/or the negative electrode are electrically connected to the outer can via the fixing member.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63168144A JPH0218860A (en) | 1988-07-06 | 1988-07-06 | Battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63168144A JPH0218860A (en) | 1988-07-06 | 1988-07-06 | Battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0218860A true JPH0218860A (en) | 1990-01-23 |
Family
ID=15862646
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63168144A Pending JPH0218860A (en) | 1988-07-06 | 1988-07-06 | Battery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0218860A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000306587A (en) * | 1999-04-21 | 2000-11-02 | Fujikoo:Kk | Felt-like conductive material |
| JP2001085016A (en) * | 1999-09-09 | 2001-03-30 | Sony Corp | Non-aqueous electrolyte battery |
| JP2004022418A (en) * | 2002-06-18 | 2004-01-22 | Ishikawajima Harima Heavy Ind Co Ltd | Battery, and its electrode core member, positive electrode and negative electrode |
-
1988
- 1988-07-06 JP JP63168144A patent/JPH0218860A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000306587A (en) * | 1999-04-21 | 2000-11-02 | Fujikoo:Kk | Felt-like conductive material |
| JP2001085016A (en) * | 1999-09-09 | 2001-03-30 | Sony Corp | Non-aqueous electrolyte battery |
| JP2004022418A (en) * | 2002-06-18 | 2004-01-22 | Ishikawajima Harima Heavy Ind Co Ltd | Battery, and its electrode core member, positive electrode and negative electrode |
| JP4576785B2 (en) * | 2002-06-18 | 2010-11-10 | 株式会社Ｉｈｉ | Battery and its electrode core material, positive electrode and negative electrode |
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