JP7509750B2 - 熱可塑性樹脂組成物及び成形体 - Google Patents
熱可塑性樹脂組成物及び成形体 Download PDFInfo
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- JP7509750B2 JP7509750B2 JP2021508987A JP2021508987A JP7509750B2 JP 7509750 B2 JP7509750 B2 JP 7509750B2 JP 2021508987 A JP2021508987 A JP 2021508987A JP 2021508987 A JP2021508987 A JP 2021508987A JP 7509750 B2 JP7509750 B2 JP 7509750B2
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- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 229940114055 beta-resorcylic acid Drugs 0.000 description 1
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 1
- WXNRYSGJLQFHBR-UHFFFAOYSA-N bis(2,4-dihydroxyphenyl)methanone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=C(O)C=C1O WXNRYSGJLQFHBR-UHFFFAOYSA-N 0.000 description 1
- JWAPUVVSOVJCJB-UHFFFAOYSA-N bis(4-hydroxy-3,5-dimethylphenyl)methanone Chemical compound CC1=C(O)C(C)=CC(C(=O)C=2C=C(C)C(O)=C(C)C=2)=C1 JWAPUVVSOVJCJB-UHFFFAOYSA-N 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- ZFVMWEVVKGLCIJ-UHFFFAOYSA-N bisphenol AF Chemical compound C1=CC(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C=C1 ZFVMWEVVKGLCIJ-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 239000006085 branching agent Substances 0.000 description 1
- INLLPKCGLOXCIV-UHFFFAOYSA-N bromoethene Chemical compound BrC=C INLLPKCGLOXCIV-UHFFFAOYSA-N 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- WWNGFHNQODFIEX-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate;styrene Chemical compound C=CC=C.COC(=O)C(C)=C.C=CC1=CC=CC=C1 WWNGFHNQODFIEX-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- MIHINWMALJZIBX-UHFFFAOYSA-N cyclohexa-2,4-dien-1-ol Chemical class OC1CC=CC=C1 MIHINWMALJZIBX-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000006392 deoxygenation reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 150000005205 dihydroxybenzenes Chemical class 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- JZKFHQMONDVVNF-UHFFFAOYSA-N dodecyl sulfate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCOS(O)(=O)=O JZKFHQMONDVVNF-UHFFFAOYSA-N 0.000 description 1
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical class O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N hydroquinone methyl ether Natural products COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229940094506 lauryl betaine Drugs 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- NXPPAOGUKPJVDI-UHFFFAOYSA-N naphthalene-1,2-diol Chemical class C1=CC=CC2=C(O)C(O)=CC=C21 NXPPAOGUKPJVDI-UHFFFAOYSA-N 0.000 description 1
- MNZMMCVIXORAQL-UHFFFAOYSA-N naphthalene-2,6-diol Chemical compound C1=C(O)C=CC2=CC(O)=CC=C21 MNZMMCVIXORAQL-UHFFFAOYSA-N 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- QBDSZLJBMIMQRS-UHFFFAOYSA-N p-Cumylphenol Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=CC=C1 QBDSZLJBMIMQRS-UHFFFAOYSA-N 0.000 description 1
- NKTOLZVEWDHZMU-UHFFFAOYSA-N p-cumyl phenol Natural products CC1=CC=C(C)C(O)=C1 NKTOLZVEWDHZMU-UHFFFAOYSA-N 0.000 description 1
- QUPCNWFFTANZPX-UHFFFAOYSA-M paramenthane hydroperoxide Chemical compound [O-]O.CC(C)C1CCC(C)CC1 QUPCNWFFTANZPX-UHFFFAOYSA-M 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 229960001553 phloroglucinol Drugs 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920001690 polydopamine Polymers 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 description 1
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229940114930 potassium stearate Drugs 0.000 description 1
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 description 1
- MQOCIYICOGDBSG-UHFFFAOYSA-M potassium;hexadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCC([O-])=O MQOCIYICOGDBSG-UHFFFAOYSA-M 0.000 description 1
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 1
- PYJBVGYZXWPIKK-UHFFFAOYSA-M potassium;tetradecanoate Chemical compound [K+].CCCCCCCCCCCCCC([O-])=O PYJBVGYZXWPIKK-UHFFFAOYSA-M 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- QMRNDFMLWNAFQR-UHFFFAOYSA-N prop-2-enenitrile;prop-2-enoic acid;styrene Chemical compound C=CC#N.OC(=O)C=C.C=CC1=CC=CC=C1 QMRNDFMLWNAFQR-UHFFFAOYSA-N 0.000 description 1
- 235000010388 propyl gallate Nutrition 0.000 description 1
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229940079776 sodium cocoyl isethionate Drugs 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- DGSDBJMBHCQYGN-UHFFFAOYSA-M sodium;2-ethylhexyl sulfate Chemical compound [Na+].CCCCC(CC)COS([O-])(=O)=O DGSDBJMBHCQYGN-UHFFFAOYSA-M 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920000638 styrene acrylonitrile Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- VDWRUZRMNKZIAJ-UHFFFAOYSA-N tetradecylazanium;acetate Chemical compound CC(O)=O.CCCCCCCCCCCCCCN VDWRUZRMNKZIAJ-UHFFFAOYSA-N 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- NJMOHBDCGXJLNJ-UHFFFAOYSA-N trimellitic anhydride chloride Chemical compound ClC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 NJMOHBDCGXJLNJ-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/18—Homopolymers or copolymers of nitriles
- C08L33/20—Homopolymers or copolymers of acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
Description
300≦2xr2≦700 (1)
40≦r2-r1≦210 (2)
(式中、r1は前記シードの半径(nm)を表し、r2は前記シードと前記コア層から構成される粒子の半径(nm)を表す。)
本発明の熱可塑性樹脂組成物は、マトリクス樹脂と、耐衝撃性改良剤としてグラフト共重合体を含有するものである。マトリクス樹脂とグラフト共重合体の使用比率は特に限定されず、マトリクス樹脂の組成に応じて適宜設定することができる。優れた耐衝撃性を発揮しながら、良好な発色性も確保する観点から、マトリクス樹脂とグラフト共重合体の合計に対して占めるグラフト共重合体の重量割合は、通常、1~60重量%の範囲であって良い。より具体的に述べると、マトリクス樹脂がアクリロニトリル-スチレン樹脂のみからなる場合には、前記重量割合は、5~55重量%が好ましく、10~50重量%がより好ましく、15~45重量%が更に好ましい。また、マトリクス樹脂がアクリロニトリル-スチレン樹脂とポリカーボネート樹脂の混合物からなる場合には、前記重量割合は、2~20重量%が好ましく、3~19重量%がより好ましく、4~18重量%が更に好ましく、5~17重量%が特に好ましい。
本発明におけるマトリクス樹脂は、少なくとも、アクリロニトリル-スチレン樹脂を含む。該アクリロニトリル-スチレン樹脂(略称AS樹脂、別名SANプラスチック)は、アクリロニトリルとスチレンの共重合体であり、透明性や耐熱性に優れた熱可塑性樹脂として知られている樹脂である。
本発明におけるグラフト共重合体は、シード、前記シード表面に形成されたコア層、及び、前記コア層表面に形成されたシェル層から構成される粒子状のものである。
シードは、グラフト共重合体を構成する粒子の最も内側に存在する小粒子であり、(メタ)アクリル酸エステル、芳香族ビニル化合物、及びシアン化ビニル化合物からなる群より選択される少なくとも1種を含むモノマー成分の重合体から構成される。
前記コア層は、シード粒子の表面に形成された重合体層であり、少なくとも1種のアクリル酸エステルを含むモノマー成分の重合体であって、かつ、架橋構造を有する重合体から構成される層である。このコア層が、主に、マトリクス樹脂に対して耐衝撃性を付与する機能を有する。コア層を構成する重合体は、シードを構成する重合体に対しグラフトしていることが好ましい。コア層は、シード粒子の表面の全体を被覆するものではなく、シード粒子の表面の少なくとも一部を被覆していればよい。
300≦2xr2≦700 (1)
40≦r2-r1≦210 (2)
シェル層は、前記コア層の表面に形成された重合体層であって、グラフト共重合体粒子の最も外側に位置する層である。該シェル層によって、グラフト共重合体とマトリクス樹脂との相溶性が向上し、樹脂組成物又はそれよりなる成形体中において、グラフト共重合体が一次粒子の状態で分散することが可能になる。シェル層を構成する重合体は、コア層を構成する重合体にグラフトしていることが好ましい。また、シェル層を構成する重合体の一部は、シードを構成する重合体にグラフトしていてもよい。シェル層は、コア層の表面の全体を被覆するものではなく、コア層の表面の少なくとも一部を被覆していればよい。
本発明のグラフト共重合体の製造方法は常法によることができるが、具体例を以下に記載する。グラフト共重合体を製造するにあたっては、まず、シードを形成する。シードは、例えば、乳化重合、懸濁重合、マイクロサスペンジョン重合などによって製造することができ、例えば国際公開第2005/028546号に記載の方法を用いることができる。
[試験片作製条件]:
(a)粘度平均分子量19,000の芳香族ポリカーボネート樹脂(帝人(株)製パンライトL-1225WX)74.4重量部
(b)アクリロニトリル-スチレン樹脂(旭化成(株)製STYLAC T8701)16重量部
(c)前記グラフト共重合体9重量部
(d)カーボンブラック30重量%含有ポリカーボネート樹脂マスターバッチ(濤和化学(株)製)0.65重量部
前記(a)~(d)の混合物を、バレル温度200~250℃に加熱した二軸押出機(株式会社日本製鋼所社製TEX44SS)にてスクリュー回転数100rpmの条件で混錬し、押出ペレットを得る。このペレットを熱風乾燥機にて80℃で5時間乾燥し、射出成形機(ファナック(株)社製FAS100B)にて成形温度250℃、金型温度70℃の条件で試験片を作製する。
[測定条件]:
ASTM D256規格に準拠する方法によって、10℃でのIzod衝撃強度を測定する。
[測定条件]:
JIS K8722規格に準じ、日本電色工業社製の色差計(型式:SE-2000)にて反射L値を測定する。
[測定条件]:
JIS K7210 A法に準じ、前記押出ペレットを熱風乾燥機にて80℃で5時間乾燥させた後、測定温度260℃、荷重5kgの条件にてMFR値を測定する。
シードの屈折率は、シードの形成時に用いた各モノマーの屈折率とその使用割合に基づいて算出した。具体的には以下のとおりである。メチルメタクリレート(以下MMAとする)の屈折率1.494、ブチルアクリレート(以下BAとする)の屈折率1.463、スチレン(以下STとする)の屈折率1.595、アクリロニトリル(以下ANとする)の屈折率1.516とし、以下の式1に基づき計算した。各モノマーの重量割合は、シード全体量に対する各モノマーの重量割合とする。
(式1)
シードの屈折率=(MMAの屈折率XMMAの重量割合/100)+(BAの屈折率XBAの重量割合/100)+(STの屈折率XSTの重量割合/100)+(ANの屈折率XANの重量割合/100)
AS樹脂又はポリカーボネート樹脂(以下PC樹脂とする)の2mmのプレートを用い、JIS K7142規格に準じて、アタゴ社製アッベ屈折計2Tを用いて、各樹脂の屈折率を測定した。マトリクス樹脂が混合物である場合に関しては、以下の式2に基づき計算した。
(式2)
マトリクス樹脂の屈折率=(AS樹脂の屈折率Xマトリクス樹脂全体に占めるAS樹脂の重量割合/100)+(PC樹脂の屈折率Xマトリクス樹脂全体に占めるPC樹脂の重量割合/100)
体積平均粒子径は、シードのラテックスの状態、又は、シードとコア層が形成されてシェル層が形成される前の粒子のラテックスの状態で測定した。測定装置として、日機装株式会社製のMICROTRAC UPA150を使用した。
得られたラテックスの一部を採取・精秤し、それを熱風乾燥器中で120℃、1時間乾燥し、その乾燥後の重量を固形分量として精秤した。次に、乾燥前後の精秤結果の比率をラテックス中の固形成分比率として求めた。最後に、この固形成分比率を用いて、以下の式3により重合転化率を算出した。
(式3)
重合転化率=(仕込み原料総重量×固形成分比率-モノマー以外の原料総重量)/仕込みモノマー重量×100(%)
各実施例及び比較例の混合物を、バレル温度200~250℃に加熱した二軸押出機(株式会社日本製鋼所社製TEX44SS)にてスクリュー回転数100rpmの条件で混錬し、押出ペレットを得た。このペレットを熱風乾燥機にて80℃で5時間乾燥し、射出成形機(ファナック(株)社製FAS100B)にて成形温度250℃、金型温度70℃の条件で、長さ63.5mm、幅12.7mm、厚さ3.2mm、vノッチ付きの試験片1を作製した。得られた試験片1について、ASTM D256規格に準拠する方法によって、-30℃、0℃、10℃、及び23℃でのIzod衝撃強度を測定した。
Izod衝撃強度の試験片1と同じ条件で、ASTM D638規格のダンベル型、厚さ3.2mmの試験片2を作製した。得られた試験片2について、JIS K8722規格に準じ、日本電色工業社製の色差計(型式:SE-2000)にて反射L値を測定した。なお、L値は低いほど、濃い黒色であることを示し、発色性が良いことを意味する。
Izod衝撃強度に関して前述した条件で作製した押出ペレットを、JIS K7210 A法に準じ、熱風乾燥機にて80℃で5時間乾燥させた後、測定温度260℃、荷重5kgの条件にてMFR値を測定した。
各表に記載の重量割合に基づいてシード、コア層、及びシェル層から構成されるグラフト共重合体を作製した。作製の過程で、シードの体積平均粒子径(2×r1)、及び、又は、シードとコア層が形成されてシェル層が形成される前の粒子の体積平均粒子径(2×r2)を測定し、得られた2×r2の数値と、算出したr2-r1の数値を各表に示した。
温度計、攪拌機、還流冷却器、窒素流入口、及び、モノマーと乳化剤の添加装置を有するガラス反応器に、脱イオン水180重量部、及び、0.5重量%濃度のジオクチルスルホコハク酸ナトリウム水溶液0.023重量部を仕込み、窒素気流中で攪拌しながら60℃に昇温した。
温度計、攪拌機、還流冷却器、窒素流入口、及び、モノマーと乳化剤の添加装置を有するガラス反応器に、脱イオン水155重量部、ホウ酸0.48重量部、炭酸ナトリウム0.05質量部、及び1.0重量%濃度のポリオキシエチレンラウリルエーテルリン酸水溶液0.016重量部を仕込み、窒素気流中で攪拌しながら50℃に昇温した。
脱イオン水500重量部、25重量%濃度の塩化カルシウム水溶液5重量部を70℃に昇温し、そこにグラフト共重合体のラテックスを投入し、凝固ラテックス粒子を含むスラリーを得た。その後、その凝固ラテックス粒子スラリーを95℃まで昇温し、脱水、乾燥させることにより、白色樹脂粉末としてグラフト共重合体を得た。
得られたグラフト共重合体の白色樹脂粉末と、粘度平均分子量19,000の芳香族ポリカーボネート樹脂(帝人(株)製パンライトL-1225WX)、アクリロニトリル-スチレン樹脂(旭化成(株)製STYLAC T8701)、及び、カーボンブラック30重量%含有ポリカーボネート樹脂マスターバッチ(濤和化学(株)製)を、各表に記載の配合部数で混合して得られた混合物について、上述した条件に従って、Izod衝撃強度、MFR、及びL値を測定し、それらの結果を各表に示した。
Claims (13)
- シード、前記シード表面に形成されたコア層、及び、前記コア層表面に形成されたシェル層から構成される粒子状のグラフト共重合体、及び、マトリクス樹脂を含有する熱可塑性樹脂組成物であって、
前記マトリクス樹脂は、アクリロニトリル-スチレン樹脂を含み、
前記シードは、メタクリル酸アルキルエステルを含むモノマー成分の重合体からなり、
前記シードを構成する前記重合体における芳香族ビニル化合物の含有量が0~20重量%であり、
前記シードの屈折率と、前記マトリクス樹脂の屈折率の差が0.07以上であり、
前記コア層は、少なくとも1種のアクリル酸エステルを含むモノマー成分の重合体であって架橋構造を有する重合体からなり、
前記シェル層は、少なくとも芳香族ビニル化合物及びシアン化ビニル化合物を含むモノマー成分の重合体からなり、
前記グラフト共重合体は、下記式(1)及び式(2)を満足し、
前記グラフト共重合体が、前記マトリクス樹脂と前記グラフト共重合体の合計に対して占める重量割合が1~60重量%である、熱可塑性樹脂組成物。
300≦2×r2≦700 (1)
40≦r2-r1≦210 (2)
(式中、r1は前記シードの半径(nm)を表し、r2は前記シードと前記コア層から構成される粒子の半径(nm)を表す。) - 前記コア層が、前記グラフト共重合体中に占める重量割合が83重量%以下である、請求項1に記載の熱可塑性樹脂組成物。
- 前記シードが、(メタ)アクリル酸エステル80~100重量%及び芳香族ビニル化合物0~20重量%を重合してなる重合体からなる、請求項1又は2に記載の熱可塑性樹脂組成物。
- 前記シードが、メタクリル酸アルキルエステル40~100重量%、アクリル酸アルキルエステル0~35重量%、芳香族ビニル化合物0~10重量%、及び、共重合可能な二重結合を有する他のモノマー0~15重合%を重合してなる重合体からなる、請求項1又は2に記載の熱可塑性樹脂組成物。
- 前記シードを構成する重合体が、架橋構造を有する、請求項1~4のいずれか1項に記載の熱可塑性樹脂組成物。
- 前記コア層が、互いに異なる2種以上の層から構成される、請求項1~5のいずれか1項に記載の熱可塑性樹脂組成物。
- 前記マトリクス樹脂が、ポリカーボネート樹脂をさらに含む、請求項1~6のいずれか1項に記載の熱可塑性樹脂組成物。
- 前記アクリロニトリル-スチレン樹脂と前記ポリカーボネート樹脂の重量比が、25:75~5:95である、請求項7に記載の熱可塑性樹脂組成物。
- 前記グラフト共重合体が、前記マトリクス樹脂と前記グラフト共重合体の合計に対して占める重量割合が2~20重量%である、請求項7又は8に記載の熱可塑性樹脂組成物。
- 下記試験片作製条件に従って作製された、長さ63.5mm、幅12.7mm、厚さ3.2mm、vノッチ付きの試験片1について、下記測定条件に従って測定されるIzod衝撃強度が、30kJ/m2以上である、請求項1~9のいずれか1項に記載の熱可塑性樹脂組成物。
[試験片作製条件]:
(a)粘度平均分子量19,000の芳香族ポリカーボネート樹脂(帝人(株)製パンライトL-1225WX)74.4重量部
(b)アクリロニトリル-スチレン樹脂(旭化成(株)製STYLAC T8701)16重量部
(c)前記グラフト共重合体9重量部
(d)カーボンブラック30重量%含有ポリカーボネート樹脂マスターバッチ(濤和化学(株)製)0.65重量部
前記(a)~(d)の混合物を、バレル温度200~250℃に加熱した二軸押出機(株式会社日本製鋼所社製TEX44SS)にてスクリュー回転数100rpmの条件で混錬し、押出ペレットを得る。このペレットを熱風乾燥機にて80℃で5時間乾燥し、射出成形機(ファナック(株)社製FAS100B)にて成形温度250℃、金型温度70℃の条件で試験片を作製する。
[測定条件]:
ASTM D256規格に準拠する方法によって、10℃でのIzod衝撃強度を測定する。 - 請求項10に記載の試験片作製条件に従って作製された、ASTM D638規格のダンベル型、厚さ3.2mmの試験片2について、下記測定条件に従って測定されるL値が、20以下である、請求項1~10のいずれか1項に記載の熱可塑性樹脂組成物。
[測定条件]:
JIS K8722規格に準じ、日本電色工業社製の色差計(型式:SE-2000)にて反射L値を測定する。 - 請求項10に記載の試験片作製条件中の手順に従って作製された押出ペレットについて、下記測定条件に従って測定されるMFR値が、21以上である、請求項1~11のいずれか1項に記載の熱可塑性樹脂組成物。
[測定条件]:
JIS K7210 A法に準じ、前記押出ペレットを熱風乾燥機にて80℃で5時間乾燥させた後、測定温度260℃、荷重5kgの条件にてMFR値を測定する。 - 請求項1~12のいずれか1項に記載の熱可塑性樹脂組成物が成形されてなる成形体。
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