JP7506848B2 - 紫外線透過ガラス - Google Patents
紫外線透過ガラス Download PDFInfo
- Publication number
- JP7506848B2 JP7506848B2 JP2019200882A JP2019200882A JP7506848B2 JP 7506848 B2 JP7506848 B2 JP 7506848B2 JP 2019200882 A JP2019200882 A JP 2019200882A JP 2019200882 A JP2019200882 A JP 2019200882A JP 7506848 B2 JP7506848 B2 JP 7506848B2
- Authority
- JP
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- Prior art keywords
- glass
- less
- ultraviolet ray
- transmitting glass
- ultraviolet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000011521 glass Substances 0.000 title claims description 182
- 238000002834 transmittance Methods 0.000 claims description 45
- 229910018068 Li 2 O Inorganic materials 0.000 claims description 37
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 23
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- 238000007789 sealing Methods 0.000 claims description 6
- 239000004065 semiconductor Substances 0.000 claims description 6
- 239000012790 adhesive layer Substances 0.000 claims description 5
- 229910052796 boron Inorganic materials 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 2
- 230000007423 decrease Effects 0.000 description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 26
- 238000002844 melting Methods 0.000 description 18
- 230000008018 melting Effects 0.000 description 18
- 238000004031 devitrification Methods 0.000 description 16
- 238000005191 phase separation Methods 0.000 description 16
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 16
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 14
- 239000002994 raw material Substances 0.000 description 13
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 12
- 239000000377 silicon dioxide Substances 0.000 description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 10
- 238000000034 method Methods 0.000 description 7
- 229910052697 platinum Inorganic materials 0.000 description 7
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 6
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 6
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 229910052906 cristobalite Inorganic materials 0.000 description 5
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 5
- 239000006066 glass batch Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 description 4
- 229910011255 B2O3 Inorganic materials 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 229910052681 coesite Inorganic materials 0.000 description 4
- 229910052593 corundum Inorganic materials 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000006060 molten glass Substances 0.000 description 4
- NOTVAPJNGZMVSD-UHFFFAOYSA-N potassium monoxide Inorganic materials [K]O[K] NOTVAPJNGZMVSD-UHFFFAOYSA-N 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 229910052682 stishovite Inorganic materials 0.000 description 4
- 229910052905 tridymite Inorganic materials 0.000 description 4
- 229910001845 yogo sapphire Inorganic materials 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 238000000137 annealing Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 230000003746 surface roughness Effects 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000005538 encapsulation Methods 0.000 description 2
- 239000006025 fining agent Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 238000007088 Archimedes method Methods 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000003280 down draw process Methods 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 238000007496 glass forming Methods 0.000 description 1
- JVPLOXQKFGYFMN-UHFFFAOYSA-N gold tin Chemical compound [Sn].[Au] JVPLOXQKFGYFMN-UHFFFAOYSA-N 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000007500 overflow downdraw method Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000005297 pyrex Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000005361 soda-lime glass Substances 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/0085—Compositions for glass with special properties for UV-transmitting glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/11—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/11—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen
- C03C3/112—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine
- C03C3/115—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine containing boron
- C03C3/118—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine containing boron containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Description
Claims (14)
- ガラス組成として、質量%で、SiO2 60~78%、Al2O3 1~25%、B2O3 10.8~30%、Li2O 0~1.5%、Na2O 0~4.36%、K2O 1.6~8%、Li2O+Na2O+K2O 1.6~10%、CaO 0~0.26%、SrO 0~3%、BaO 0~1.9%未満、Li2O+BaO 0~1.9%未満、Cl 0~1%、ZnO 0.1~3%を含有し、厚み0.5mm、波長200nmにおける外部透過率が40%以上である、紫外線透過ガラス。
- 温度121℃、相対湿度85%、試験時間24時間の高速加速寿命試験(HAST)を行った時、ガラス表面に発生する異物の最大の最大長が100μm以下になる、請求項1に記載の紫外線透過ガラス。
- ガラス粘度Logρ=6.0dPa・sに相当する温度が870℃以下である、請求項1又は2に記載の紫外線透過ガラス。
- ガラス粘度Logρ=4.0dPa・sに相当する温度が1200℃以下である、請求項1~3の何れかに記載の紫外線透過ガラス。
- 30~380℃における平均熱膨張係数が40×10-7~65×10-7/℃である、請求項1~4の何れかに記載の紫外線透過ガラス。
- 厚み0.5mm、波長230nmにおける外部透過率が70%以上である、請求項1~5の何れかに記載の紫外線透過ガラス。
- 厚み0.5mm、波長200nmにおける外部透過率(%)をT200、厚み0.5mm、波長260nmにおける外部透過率(%)をT260とした場合、T200/T260≧0.45の関係を満たす、請求項1~6の何れかに記載の紫外線透過ガラス。
- ガラス表面に機能性膜が形成されている、請求項1~7の何れかに記載の紫外線透過ガラス。
- ガラス表面にレンズ構造が形成されている、請求項1~7の何れかに記載の紫外線透過ガラス。
- ガラス表面にプリズム構造が形成されている、請求項1~7の何れかに記載の紫外線透過ガラス。
- ガラス表面に接着層が形成されている、請求項1~7の何れかに記載の紫外線透過ガラス。
- 形状が板状又は管状であり、その厚みが0.1~3.0mmである、請求項1~11の何れかに記載の紫外線透過ガラス。
- 形状が管状であり、且つその内径が1mm以上である、請求項1~12の何れかに記載の紫外線透過ガラス。
- 紫外線発光ダイオード(LED)、半導体パッケージ、受光素子封止パッケージ、紫外光発光ランプ、光電子増倍管の何れかに用いる、請求項1~13の何れかに記載の紫外線透過ガラス。
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2019200882A JP7506848B2 (ja) | 2019-11-05 | 2019-11-05 | 紫外線透過ガラス |
CN202080067292.4A CN114430731A (zh) | 2019-11-05 | 2020-10-08 | 紫外线透射玻璃 |
PCT/JP2020/038098 WO2021090631A1 (ja) | 2019-11-05 | 2020-10-08 | 紫外線透過ガラス |
US17/769,897 US20220388893A1 (en) | 2019-11-05 | 2020-10-08 | Ultraviolet transmission glass |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2019200882A JP7506848B2 (ja) | 2019-11-05 | 2019-11-05 | 紫外線透過ガラス |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2021075407A JP2021075407A (ja) | 2021-05-20 |
JP7506848B2 true JP7506848B2 (ja) | 2024-06-27 |
Family
ID=75849912
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2019200882A Active JP7506848B2 (ja) | 2019-11-05 | 2019-11-05 | 紫外線透過ガラス |
Country Status (4)
Country | Link |
---|---|
US (1) | US20220388893A1 (ja) |
JP (1) | JP7506848B2 (ja) |
CN (1) | CN114430731A (ja) |
WO (1) | WO2021090631A1 (ja) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11951713B2 (en) | 2020-12-10 | 2024-04-09 | Corning Incorporated | Glass with unique fracture behavior for vehicle windshield |
WO2023100893A1 (ja) * | 2021-12-01 | 2023-06-08 | 日本電気硝子株式会社 | 磁気記録媒体用ガラス基板、磁気記録媒体用ガラスディスク、磁気記録媒体及びガラスディスクの製造方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010184816A (ja) | 2009-01-16 | 2010-08-26 | Asahi Glass Co Ltd | 固体撮像素子パッケージ用窓ガラス |
JP2015193521A (ja) | 2014-03-19 | 2015-11-05 | 日本電気硝子株式会社 | 紫外線透過ガラス及びその製造方法 |
JP2018504356A (ja) | 2015-01-20 | 2018-02-15 | ショット グラス テクノロジーズ (スゾウ) カンパニー リミテッドSchott Glass Technologies (Suzhou) Co., Ltd. | 高いuv透過率および耐ソラリゼーション性を示す低cteガラス |
WO2019167399A1 (ja) | 2018-02-28 | 2019-09-06 | 日本電気硝子株式会社 | 紫外線透過ガラス及びその製造方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5402184B2 (ja) * | 2009-04-13 | 2014-01-29 | 日本電気硝子株式会社 | ガラスフィルムおよびその製造方法 |
TWI692459B (zh) * | 2015-05-29 | 2020-05-01 | 日商Agc股份有限公司 | 紫外線透射玻璃 |
WO2018100991A1 (ja) * | 2016-11-30 | 2018-06-07 | 旭硝子株式会社 | 紫外線透過フィルタ |
JP2019167399A (ja) * | 2018-03-22 | 2019-10-03 | 三井化学株式会社 | 反射材用ポリエステル樹脂の製造方法 |
CN110183104B (zh) * | 2019-06-28 | 2021-09-28 | 中国建筑材料科学研究总院有限公司 | 一种透深紫外玻璃及其制备方法、应用 |
-
2019
- 2019-11-05 JP JP2019200882A patent/JP7506848B2/ja active Active
-
2020
- 2020-10-08 CN CN202080067292.4A patent/CN114430731A/zh active Pending
- 2020-10-08 US US17/769,897 patent/US20220388893A1/en active Pending
- 2020-10-08 WO PCT/JP2020/038098 patent/WO2021090631A1/ja active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010184816A (ja) | 2009-01-16 | 2010-08-26 | Asahi Glass Co Ltd | 固体撮像素子パッケージ用窓ガラス |
JP2015193521A (ja) | 2014-03-19 | 2015-11-05 | 日本電気硝子株式会社 | 紫外線透過ガラス及びその製造方法 |
JP2018504356A (ja) | 2015-01-20 | 2018-02-15 | ショット グラス テクノロジーズ (スゾウ) カンパニー リミテッドSchott Glass Technologies (Suzhou) Co., Ltd. | 高いuv透過率および耐ソラリゼーション性を示す低cteガラス |
WO2019167399A1 (ja) | 2018-02-28 | 2019-09-06 | 日本電気硝子株式会社 | 紫外線透過ガラス及びその製造方法 |
Also Published As
Publication number | Publication date |
---|---|
WO2021090631A1 (ja) | 2021-05-14 |
JP2021075407A (ja) | 2021-05-20 |
CN114430731A (zh) | 2022-05-03 |
US20220388893A1 (en) | 2022-12-08 |
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