JP7326312B2 - 安定度を高めた天然生物由来油を含む誘電流体 - Google Patents
安定度を高めた天然生物由来油を含む誘電流体 Download PDFInfo
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- JP7326312B2 JP7326312B2 JP2020549672A JP2020549672A JP7326312B2 JP 7326312 B2 JP7326312 B2 JP 7326312B2 JP 2020549672 A JP2020549672 A JP 2020549672A JP 2020549672 A JP2020549672 A JP 2020549672A JP 7326312 B2 JP7326312 B2 JP 7326312B2
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- phosphite
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- 239000012530 fluid Substances 0.000 title claims description 315
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 326
- 239000003963 antioxidant agent Substances 0.000 claims description 124
- 235000006708 antioxidants Nutrition 0.000 claims description 123
- 230000003078 antioxidant effect Effects 0.000 claims description 99
- 239000000203 mixture Substances 0.000 claims description 97
- 238000000034 method Methods 0.000 claims description 37
- -1 cyclic phosphites Chemical class 0.000 claims description 33
- 239000007789 gas Substances 0.000 claims description 32
- 239000002184 metal Substances 0.000 claims description 28
- 229910052751 metal Inorganic materials 0.000 claims description 28
- 150000001875 compounds Chemical class 0.000 claims description 22
- 239000001257 hydrogen Substances 0.000 claims description 21
- 229910052739 hydrogen Inorganic materials 0.000 claims description 21
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 20
- 238000004868 gas analysis Methods 0.000 claims description 20
- 230000015572 biosynthetic process Effects 0.000 claims description 14
- 230000001590 oxidative effect Effects 0.000 claims description 13
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 238000009826 distribution Methods 0.000 claims description 11
- 150000008301 phosphite esters Chemical group 0.000 claims description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 6
- 239000005977 Ethylene Substances 0.000 claims description 6
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical group CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 6
- 239000012964 benzotriazole Substances 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 239000002530 phenolic antioxidant Substances 0.000 claims description 5
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 4
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 claims description 4
- WGVKWNUPNGFDFJ-DQCZWYHMSA-N β-tocopherol Chemical compound OC1=CC(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C WGVKWNUPNGFDFJ-DQCZWYHMSA-N 0.000 claims description 4
- GZIFEOYASATJEH-VHFRWLAGSA-N δ-tocopherol Chemical compound OC1=CC(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 GZIFEOYASATJEH-VHFRWLAGSA-N 0.000 claims description 4
- QSRJVOOOWGXUDY-UHFFFAOYSA-N 2-[2-[2-[3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoyloxy]ethoxy]ethoxy]ethyl 3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C)=CC(CCC(=O)OCCOCCOCCOC(=O)CCC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 QSRJVOOOWGXUDY-UHFFFAOYSA-N 0.000 claims description 3
- GAODDBNJCKQQDY-UHFFFAOYSA-N 2-methyl-4,6-bis(octylsulfanylmethyl)phenol Chemical compound CCCCCCCCSCC1=CC(C)=C(O)C(CSCCCCCCCC)=C1 GAODDBNJCKQQDY-UHFFFAOYSA-N 0.000 claims description 3
- PZRWFKGUFWPFID-UHFFFAOYSA-N 3,9-dioctadecoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C1OP(OCCCCCCCCCCCCCCCCCC)OCC21COP(OCCCCCCCCCCCCCCCCCC)OC2 PZRWFKGUFWPFID-UHFFFAOYSA-N 0.000 claims description 3
- QRLSTWVLSWCGBT-UHFFFAOYSA-N 4-((4,6-bis(octylthio)-1,3,5-triazin-2-yl)amino)-2,6-di-tert-butylphenol Chemical compound CCCCCCCCSC1=NC(SCCCCCCCC)=NC(NC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=N1 QRLSTWVLSWCGBT-UHFFFAOYSA-N 0.000 claims description 3
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 claims description 3
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 3
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000004250 tert-Butylhydroquinone Substances 0.000 claims description 3
- 235000019281 tert-butylhydroquinone Nutrition 0.000 claims description 3
- XKZGIJICHCVXFV-UHFFFAOYSA-N 2-ethylhexyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OCC(CC)CCCC)OC1=CC=CC=C1 XKZGIJICHCVXFV-UHFFFAOYSA-N 0.000 claims description 2
- SSADPHQCUURWSW-UHFFFAOYSA-N 3,9-bis(2,6-ditert-butyl-4-methylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound CC(C)(C)C1=CC(C)=CC(C(C)(C)C)=C1OP1OCC2(COP(OC=3C(=CC(C)=CC=3C(C)(C)C)C(C)(C)C)OC2)CO1 SSADPHQCUURWSW-UHFFFAOYSA-N 0.000 claims description 2
- SDCYWERHEYVPHL-UHFFFAOYSA-N 3,9-diphenoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound O1CC2(COP(OC=3C=CC=CC=3)OC2)COP1OC1=CC=CC=C1 SDCYWERHEYVPHL-UHFFFAOYSA-N 0.000 claims description 2
- ZVVFVKJZNVSANF-UHFFFAOYSA-N 6-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]hexyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCCCCCCOC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 ZVVFVKJZNVSANF-UHFFFAOYSA-N 0.000 claims description 2
- ADRNSOYXKABLGT-UHFFFAOYSA-N 8-methylnonyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OCCCCCCCC(C)C)OC1=CC=CC=C1 ADRNSOYXKABLGT-UHFFFAOYSA-N 0.000 claims description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 2
- GZIFEOYASATJEH-UHFFFAOYSA-N D-delta tocopherol Natural products OC1=CC(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 GZIFEOYASATJEH-UHFFFAOYSA-N 0.000 claims description 2
- XAQKFOUWWAKVCH-UHFFFAOYSA-N OP(O)OP(O)O.C(C)(C)(C1=CC=CC=C1)C1=C(C=CC(=C1)C(C)(C)C1=CC=CC=C1)C(O)C(CO)(CO)CO Chemical compound OP(O)OP(O)O.C(C)(C)(C1=CC=CC=C1)C1=C(C=CC(=C1)C(C)(C)C1=CC=CC=C1)C(O)C(CO)(CO)CO XAQKFOUWWAKVCH-UHFFFAOYSA-N 0.000 claims description 2
- 125000004104 aryloxy group Chemical group 0.000 claims description 2
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims description 2
- 235000010389 delta-tocopherol Nutrition 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- NYCZNDFWFCCTPA-UHFFFAOYSA-N methyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC)OC1=CC=CC=C1 NYCZNDFWFCCTPA-UHFFFAOYSA-N 0.000 claims description 2
- 235000010388 propyl gallate Nutrition 0.000 claims description 2
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- ICKWICRCANNIBI-UHFFFAOYSA-N 2,4-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C(C(C)(C)C)=C1 ICKWICRCANNIBI-UHFFFAOYSA-N 0.000 claims 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 2
- GXURZKWLMYOCDX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.OCC(CO)(CO)CO GXURZKWLMYOCDX-UHFFFAOYSA-N 0.000 claims 1
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Classifications
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
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- H01G9/07—Dielectric layers
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- C10M2203/1025—Aliphatic fractions used as base material
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- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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- C10M2207/2805—Esters used as base material
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/401—Fatty vegetable or animal oils used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M2207/402—Castor oils
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C10M2215/064—Di- and triaryl amines
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- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/049—Phosphite
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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- C10N2030/02—Pour-point; Viscosity index
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Description
ISO3016で決定して、-20℃未満の流動点を有する。一態様では、誘電流体は、ISO3016で決定して、-25℃未満の流動点を有する。一態様では、誘電流体は、ISO3016で決定して、-30℃未満の流動点を有する。一態様では、誘電流体は、ISO3016で決定して、-45℃未満の流動点を有する。一態様では、誘電流体の油が生物由来油又は合成エステル油である場合、誘電流体は、ISO3016で決定して、-10℃未満の流動点を有する。一態様では、誘電流体の油が大豆系の油を含む場合、誘電流体は、ISO3016で決定して、-15℃未満の流動点を有するか、又はISO3016で決定して、-20℃未満の流動点を有する。一態様では、誘電流体の油がナタネ系の油を含む場合、誘電流体は、ISO3016で決定して、-30℃未満の流動点を有する。一態様では、誘電流体の油が合成エステル油である場合、誘電流体は、ISO3016で決定して、-45℃未満の流動点を有する。一態様では、誘電流体の油が鉱油である場合、誘電流体は、ISO3016で決定して、-40℃未満の流動点を有するか、又はISO3016で決定して、-60℃未満の流動点を有する。
Claims (17)
- 天然生物由来油と、1種以上のホスファイト化合物を含むホスファイト成分と、を含む誘電流体であって、ホスファイト成分は、ホスファイト成分を含有しない同様の誘電流体組成物と比較して、溶解ガス分析(ASTM D3612-02、方法C)で決定して、誘電流体中の漂遊ガスの形成を低減させるのに十分な量で存在し、漂遊ガスが水素、エタン、メタンまたはエチレンであり、
漂遊ガスが水素である場合に、前記ホスファイト成分が、ホスファイト成分を含有しない同様の誘電流体組成物と比較して、少なくとも60%、又はホスファイト成分を含有しない同様の誘電流体組成物と比較して、少なくとも70%、又はホスファイト成分を含有しない同様の電流体組成物と比較して、少なくとも80%、前記誘電流体のH 2 ガス発生を低減させるのに十分な量で存在することを特徴とする、誘電流体。 - 前記ホスファイト成分が、ホスファイト成分を含有しない同様の誘電流体組成物と比較して、少なくとも60%、前記誘電流体のエタンガス発生を低減させるのに十分な量で存在するか、又は、前記ホスファイト成分が、ホスファイト成分を含有しない同様の誘電流体組成物と比較して、少なくとも70%、前記誘電流体のエタンガス発生を低減させるのに十分な量で存在するか、又は、前記ホスファイト成分が、ホスファイト成分を含有しない同様の誘電流体組成物と比較して、少なくとも80%、前記誘電流体のエタンガス発生を低減させるのに十分な量で存在する、請求項1に記載の誘電流体。
- 前記ホスファイト成分が、前記誘電流体中に0.05~溶解限度の量で存在するか、又は前記ホスファイト成分が、前記誘電流体中に0.1~溶解限度の量で存在するか、又は前記ホスファイト成分が、0.05~4重量%の量で存在するか、又は前記ホスファイト成分が、0.05~3重量%の量で存在するか、又は前記ホスファイト成分が、0.05~2重量%の量で存在するか、又は前記ホスファイト成分が、0.05~1.5重量%の量で存在するか、又は前記ホスファイト成分が、0.05~1重量%の量で存在するか、又は前記ホスファイト成分が、0.05~0.5重量%の量で存在するか、又は前記ホスファイト成分が、0.1~4重量%の量で存在するか、又は前記ホスファイト成分が、0.1~3重量%の量で存在するか、又は前記ホスファイト成分が、0.1~2重量%の量で存在するか、又は前記ホスファイト成分が、0.1~1.5重量%の量で存在するか、又は前記ホスファイト成分が、0.1~1重量%の量で存在するか、又は前記ホスファイト成分が、0.1~0.5重量%の量で存在する、請求項1または2に記載の誘電流体。
- 前記ホスファイト成分が、水安定であるホスファイト化合物から選択される、請求項1~3のいずれか一項に記載の誘電流体。
- 前記ホスファイト成分が、ホスファイトエステル、トリアリールホスファイト、トリアルキルホスファイト、環状ホスファイト、ビスアリールホスファイトペンタエリトリトール環状エステルから選択される、請求項1~4のいずれか一項に記載の誘電流体。
- 前記ホスファイト成分が、1~3個のアリールオキシ基を有するホスファイト化合物から選択される、請求項1~4のいずれか一項に記載の誘電流体。
- 前記ホスファイト成分が、トリアリールホスファイト化合物から選択される、請求項1~4のいずれか一項に記載の誘電流体。
- 前記ホスファイト成分が、環状アリールホスファイト、環状アルキルアリールホスファイト、アリール環状フェノキシホスファイト、ビスアリールホスファイト、アルキルアリールホスファイト、及びこれらの混合物からなる群から選択される、請求項1~4のいずれか一項に記載の誘電流体。
- 前記ホスファイト成分が、トリス(2,4-ジ-tert-ブチルフェニル)ホスファイト、ビス(2,4-ジクミルフェニルペンタエリトリトールジホスファイト、トリス-ノニルフェニルホスファイト、1,3,7,9-テトラtert-ブチル-11-(2-エチルヘキソキシ)-5H-ベンゾ[d][1,3,2]ベンゾジオキサホスホシン、3,9-ビス(2,6-ジ-tert-ブチル-4-メチルフェノキシ)-2,4,8,10-テトラオキサ-3,9-ジホスファスピロ[5.5]ウンデカン、ビス(2,4-ジ-tert-ブチルフェノール)ペンタエリトリトールジホスファイト、4,4’-イソプロピリイデンジフェノールC12~15アルコールホスファイト、3,9-ジフェノキシ-2,4,8,10-テトラオキサ-3,9-ジホスファスピロ[5.5]ウンデカン、3,9-ビス(オクタデシルオキシ)-2,4,8,10-テトラオキサ-3,9-ジホスファスピロ[5.5]ウンデカン、トリフェニルホスファイト、イソデシルジフェニルホスファイト、2-エチルヘキシルジフェニルホスファイト、5,5-ジメチ(dimethy)-2-フェノキシ-1,3,2-ジオキサホスホリナン、メチルジフェニルホスファイト、及びこれらの混合物からなる群から選択される、請求項1~4のいずれか一項に記載の誘電流体。
- 前記誘電流体が、1種以上の非ホスファイト抗酸化剤化合物から選択される非ホスファイト抗酸化成分を更に含む、請求項1~9のいずれか一項に記載の誘電流体。
- 前記非ホスファイト抗酸化成分が、フェノール系抗酸化剤からなる群から選択される、請求項10に記載の誘電流体。
- 前記非ホスファイト抗酸化成分が、ブチル化ヒドロアニソール、ブチル化ヒドロトルエン、tert-ブチルヒドロキノン、テトラヒドロブトロフェノン(butrophenone)、アスコルビン酸パルミテート、プロピルガレート、アルファ-、ベータ-、又はデルタ-トコフェロール、及びこれらの混合物からなる群から選択される、請求項10に記載の誘電流体。
- 前記非ホスファイト抗酸化成分が、ペンタエリトリトールテトラキス(3-(3,5-ジ-tert-ブチル-4-ヒドロキシフェニル)プロピオネート)、ヘキサメチレンビス[3-(3,5-ジ-tert-ブチル-4-ヒドロキシフェニル)プロピオネート]、オクタデシル-[3-(3,5-ジ-tert-ブチル-4-ヒドロキシフェニル)プロピオネート]、エチレンビス(オキシエチレン)ビス(3-(5-tert-ブチル-4-ヒドロキシ-m-トリル)プロピオネート)、2,6-ジ-tert-ブチル-4-(4,6-ビス(オクチルチオ)-1,3,5-トリアジン-2-イルアミノ)フェノール、N,N’-ヘキサン-1,6-ジイルビス(3-3,5-ジ-tert-ブチル-4-ヒドロキシフェニルプロピオンアミド)、4,6-ビス(オクチルチオメチル)-o-クレゾール、4,4’-メチレン-ビス-2,6-ジ-tert-ブチルフェノール、及び2,6-ジ-tert-ブチル-4-メチルフェノールからなる群から選択される、請求項10に記載の誘電流体。
- 前記ホスファイト成分が、前記誘電流体組成物中に0.05重量%~前記ホスファイト成分の溶解限度の量で存在し、前記非ホスファイト抗酸化成分は、ホスファイト成分と非ホスファイト抗酸化成分との比が1部のホスファイト成分に対して0~1.2部の非ホスファイト抗酸化成分であるような量で存在し、
又は
前記ホスファイト成分が、前記誘電流体組成物中に0.2重量%~前記ホスファイト成分の溶解限度の量で存在し、前記非ホスファイト抗酸化成分は、ホスファイト成分と非ホスファイト抗酸化成分との比が1部のホスファイト成分に対して0~1.2部の非ホスファイト抗酸化成分であるような量で存在し、又は
前記ホスファイト成分が、0.2重量%~1重量%の量で存在し、前記非ホスファイト抗酸化成分は、ホスファイト成分と非ホスファイト抗酸化成分との比が1部のホスファイト成分に対して0~1.2部の非ホスファイト抗酸化成分であるような量で存在し、又は
前記ホスファイト成分が、前記誘電流体組成物中に0.4重量%~前記ホスファイト成分の溶解限度の量で存在し、前記非ホスファイト抗酸化成分は、ホスファイト成分と非ホスファイト抗酸化成分との比が1部のホスファイト成分に対して0~1.2部の非ホスファイト抗酸化成分であるような量で存在し、又は
前記ホスファイト成分が、0.4重量%~0.6重量%の量で存在し、前記非ホスファイト抗酸化成分は、ホスファイト成分と非ホスファイト抗酸化成分との比が1部のホスファイト成分に対して0~1.2部の非ホスファイト抗酸化成分であるような量で存在し、又は
前記ホスファイト成分が、前記誘電流体組成物中に0.05重量%~前記ホスファイト成分の溶解限度の量で存在し、前記ホスファイト成分が、前記誘電流体組成物中に0.05重量%~前記非ホスファイト抗酸化成分の溶解限度の量で存在するが、ただし、更に、ホスファイト成分と非ホスファイト抗酸化成分との比が、1部のホスファイト成分に対して0~1.2部の非ホスファイト抗酸化成分であり、又は
前記ホスファイト成分が、前記誘電流体組成物中に0.2重量%~前記ホスファイト成分の溶解限度の量で存在し、前記ホスファイト成分が、前記誘電流体組成物中に0.05重量%~前記非ホスファイト抗酸化成分の溶解限度の量で存在するが、ただし、更に、ホスファイト成分と非ホスファイト抗酸化成分との比が、1部のホスファイト成分に対して0~1.2部の非ホスファイト抗酸化成分であり、又は
前記ホスファイト成分が、0.2重量%~1重量%の量で存在し、前記ホスファイト成分が、前記誘電流体組成物中に0.05重量%~前記非ホスファイト抗酸化成分の溶解限度の量で存在するが、ただし、更に、ホスファイト成分と非ホスファイト抗酸化成分との比が、1部のホスファイト成分に対して0~1.2部の非ホスファイト抗酸化成分であり、又は
前記ホスファイト成分が、前記誘電流体組成物中に0.4重量%~前記ホスファイト成分の溶解限度の量で存在し、前記ホスファイト成分が、前記誘電流体組成物中に0.05重量%~前記非ホスファイト抗酸化成分の溶解限度の量で存在するが、ただし、更に、ホスファイト成分と非ホスファイト抗酸化成分との比が、1部のホスファイト成分に対して0~1.2部の非ホスファイト抗酸化成分であり、又は
前記ホスファイト成分が、0.4重量%~0.6重量%の量で存在し、前記ホスファイト成分が、前記誘電流体組成物中に0.05重量%~前記非ホスファイト抗酸化成分の溶解限度の量で存在するが、ただし、更に、ホスファイト成分と非ホスファイト抗酸化成分との比が、1部のホスファイト成分に対して0~1.2部の非ホスファイト抗酸化成分であり、又は
前記ホスファイト成分が、前記誘電流体組成物中に0.4重量%~前記ホスファイト成分の溶解限度の量で存在し、前記ホスファイト成分が、前記誘電流体組成物中に0.2重量%~前記非ホスファイト抗酸化成分の溶解限度の量で存在するが、ただし、更に、ホスファイト成分と非ホスファイト抗酸化成分との比が、1部のホスファイト成分に対して0~1.2部の非ホスファイト抗酸化成分であり、又は
前記ホスファイト成分が、0.4重量%~0.6重量%の量で存在し、前記ホスファイト成分が、前記誘電流体組成物中に0.2重量%~前記非ホスファイト抗酸化成分の溶解限度の量で存在するが、ただし、更に、ホスファイト成分と非ホスファイト抗酸化成分との比が、1部のホスファイト成分に対して0~1.2部の非ホスファイト抗酸化成分であり、又は
前記ホスファイト成分が、前記誘電流体組成物中に0.4重量%~前記ホスファイト成分の溶解限度の量で存在し、前記ホスファイト成分が、前記誘電流体組成物中に0.3重量%~前記非ホスファイト抗酸化成分の溶解限度の量で存在するが、ただし、更に、ホスファイト成分と非ホスファイト抗酸化成分との比が、1部のホスファイト成分に対して0~1.2部の非ホスファイト抗酸化成分であり、又は
前記ホスファイト成分が、0.4重量%~0.6重量%の量で存在し、前記ホスファイト成分が、前記誘電流体組成物中に0.3重量%~前記非ホスファイト抗酸化成分の溶解限度の量で存在するが、ただし、更に、ホスファイト成分と非ホスファイト抗酸化成分との比が、1部のホスファイト成分に対して0~1.2部の非ホスファイト抗酸化成分である、請求項10~13のいずれか一項に記載の誘電流体。 - 前記誘電流体が、金属不動態化剤を更に含む、請求項1~14のいずれか一項に記載の誘電流体。
- 前記金属不動態化剤が、ベンゾトリアゾール又はその誘導体から選択される、請求項15に記載の誘電流体。
- 電気分配又は動力装置で使用するように配合された誘電流体であって、前記誘電流体が、天然生物由来油と、1種以上のホスファイト化合物を含むホスファイト成分と、を含む、誘電流体。
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB498215A (en) | 1936-11-21 | 1939-01-04 | Okonite Callender Cable Co Inc | Improved method and apparatus for treating insulating oils |
GB716029A (en) * | 1950-04-17 | 1954-09-29 | Johnson & Co A | Improvements in and relating to the treatment of electric apparatus |
US3305526A (en) * | 1964-07-07 | 1967-02-21 | Weston Chemical Corp | Phenoxy phosphite polymers |
US3565855A (en) * | 1969-05-14 | 1971-02-23 | Ethyl Corp | Phosphorus-containing antioxidant in polyolefins |
US4082866A (en) | 1975-07-28 | 1978-04-04 | Rte Corporation | Method of use and electrical equipment utilizing insulating oil consisting of a saturated hydrocarbon oil |
NL7602387A (nl) | 1976-03-08 | 1977-09-12 | Nkf Kabel Bv | Installatie voor het drogen en ontgassen van olie, in het bijzonder kabelolie. |
US4142003A (en) | 1977-08-22 | 1979-02-27 | American Home Products Corporation | Non-aerosol vegetable oil compositions containing lecithin and pure ethyl alcohol |
JPS6015089B2 (ja) * | 1977-11-30 | 1985-04-17 | 株式会社日立製作所 | 電気絶縁油 |
US4543207A (en) * | 1982-12-25 | 1985-09-24 | Nippon Petrochemicals Company, Limited | Electrical insulating oil and oil-filled electrical appliances |
US4498992A (en) | 1984-02-09 | 1985-02-12 | Petro-Williams Service Company | Process for treating contaminated transformer oil |
JPS6212185A (ja) | 1985-07-09 | 1987-01-21 | 田中貴金属工業株式会社 | 石英基板に超高周波回路用Cu薄膜を形成する方法 |
US4857150A (en) | 1988-06-22 | 1989-08-15 | Union Carbide Corporation | Silicone oil recovery |
US5366648A (en) * | 1990-02-23 | 1994-11-22 | The Lubrizol Corporation | Functional fluids useful at high temperatures |
US5260077A (en) | 1991-02-12 | 1993-11-09 | The Lubrizol Corporation | Vegetable oil compositions |
JP2883256B2 (ja) * | 1993-01-18 | 1999-04-19 | 旭電化工業株式会社 | エポキシ化植物油組成物 |
DE4339556C1 (de) | 1993-11-19 | 1995-02-02 | Metallgesellschaft Ag | Verfahren zum Entschleimen von Pflanzenöl mittels Enzymen |
US5750476A (en) * | 1995-10-18 | 1998-05-12 | Exxon Chemical Patents Inc. | Power transmitting fluids with improved anti-shudder durability |
US5736915A (en) | 1995-12-21 | 1998-04-07 | Cooper Industries, Inc. | Hermetically sealed, non-venting electrical apparatus with dielectric fluid having defined chemical composition |
US6398986B1 (en) | 1995-12-21 | 2002-06-04 | Cooper Industries, Inc | Food grade vegetable oil based dielectric fluid and methods of using same |
US5766517A (en) | 1995-12-21 | 1998-06-16 | Cooper Industries, Inc. | Dielectric fluid for use in power distribution equipment |
US6352655B1 (en) | 1995-12-21 | 2002-03-05 | Cooper Industries, Inc. | Vegetable oil based dielectric fluid |
US6037537A (en) | 1995-12-21 | 2000-03-14 | Cooper Industries, Inc. | Vegetable oil based dielectric coolant |
US6280659B1 (en) | 1996-03-01 | 2001-08-28 | David W. Sundin | Vegetable seed oil insulating fluid |
JP2000511349A (ja) | 1996-05-29 | 2000-08-29 | アセア ブラウン ボヴェリ エービー | 直流変圧器/リアクトル |
US6340658B1 (en) * | 1998-05-11 | 2002-01-22 | Wavely Light And Power | Vegetable-based transformer oil and transmission line fluid |
US6441209B1 (en) | 1998-11-20 | 2002-08-27 | Ip Holdings, L.L.C. | Method for treating organic acid-treated phosphatides |
US7524440B2 (en) | 2003-10-02 | 2009-04-28 | Cooper Industries, Inc. | Method comprising additive for dielectric fluid |
AU2005263954B2 (en) | 2004-07-16 | 2011-04-07 | Dupont Nutrition Biosciences Aps | Enzymatic oil-degumming method |
DE202005002390U1 (de) | 2005-02-15 | 2005-06-16 | Merlaku, Kastriot | Computer-Kühl-System |
CN101278362B (zh) * | 2005-09-09 | 2012-06-06 | 狮王株式会社 | 电绝缘油用基剂 |
BRPI0618409C1 (pt) | 2005-10-11 | 2011-12-20 | Biolectric Pty Ltd | fluido dielétricos à base de óleo contendo ácido monoinsaturado de baixa viscosidade, processo para suas produções, transformador e modificador de viscosidade |
JP2007173685A (ja) | 2005-12-26 | 2007-07-05 | Japan Ae Power Systems Corp | 静止誘導電器 |
US20080194442A1 (en) * | 2007-02-13 | 2008-08-14 | Watts Raymond F | Methods for lubricating a transmission |
US8801975B2 (en) | 2007-05-17 | 2014-08-12 | Cooper Industries, Llc | Vegetable oil dielectric fluid composition |
US8076123B2 (en) | 2007-10-26 | 2011-12-13 | Oilseeds Biorefinery Corporation | Emulsification-free degumming of oil |
WO2010044648A1 (es) | 2008-10-16 | 2010-04-22 | Ragasa Industrias S.A. De C.V. | Aceite vegetal de alta pureza dieléctrico, método para obtención y su aplicación en un aparato eléctrico |
JP5745542B2 (ja) * | 2009-12-28 | 2015-07-08 | ダウ グローバル テクノロジーズ エルエルシー | 電気部品のための藻類油をベースにした誘電性流体 |
JP5475600B2 (ja) | 2010-09-13 | 2014-04-16 | レンゴー株式会社 | 箱の底組みロック |
SG10201509035WA (en) | 2010-11-03 | 2015-12-30 | Solazyme Inc | Microbial Oils With Lowered Pour Points, Dielectric Fluids Produced Therefrom, And Related Methods |
DE102011079550A1 (de) | 2011-07-21 | 2013-01-24 | Evonik Degussa Gmbh | Alkalimetall-Glycerate zur Entsäuerung und Trocknung von Fettsäureestern |
US9240259B2 (en) | 2011-10-07 | 2016-01-19 | E I Du Pont De Nemours And Company | Liquid compositions used as insulating and heat transfer means, electrical devices containing said compositions and preparation method for such compositions |
WO2014020170A1 (en) * | 2012-08-02 | 2014-02-06 | Addivant Switzerland Gmbh | Phosphite compositions |
WO2014100649A1 (en) | 2012-12-20 | 2014-06-26 | Cargill, Incorporated | Enzymatically-degummed oil and uses thereof |
EP3120368A4 (en) | 2014-03-17 | 2017-11-22 | Novvi LLC | Dielectric fluid and coolant made with biobased base oil |
GB201502874D0 (en) * | 2015-02-20 | 2015-04-08 | M & I Materials Ltd | Low temperature dielectric fluid compositions |
JP6669343B2 (ja) * | 2015-02-27 | 2020-03-18 | 出光興産株式会社 | 生分解性潤滑油組成物 |
CN106118833A (zh) | 2016-06-13 | 2016-11-16 | 句容市江电电器机械有限公司 | 一种兼具润滑冷却功效的变压器绝缘油及其制备方法 |
CN106867638A (zh) * | 2017-04-01 | 2017-06-20 | 江苏奥克化学有限公司 | 一种变压器油组合物、变压器油及其制备方法 |
FR3068038B1 (fr) | 2017-06-21 | 2020-09-18 | Nexans | Composition polymere comprenant un liquide dielectrique polaire |
US11814598B2 (en) | 2018-03-21 | 2023-11-14 | Cargill, Incorporated | Synthetic ester and mineral oil dielectric fluids with increased stability |
US10712105B1 (en) * | 2019-06-19 | 2020-07-14 | Exxonmobil Research And Engineering Company | Heat transfer fluids and methods of use |
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CN117327520A (zh) | 2024-01-02 |
US20240043767A1 (en) | 2024-02-08 |
US20210027910A1 (en) | 2021-01-28 |
JP2021518972A (ja) | 2021-08-05 |
EP3769322A1 (en) | 2021-01-27 |
CN117343770A (zh) | 2024-01-05 |
US11814598B2 (en) | 2023-11-14 |
CN112005319B (zh) | 2023-07-07 |
EP3797430A4 (en) | 2022-05-04 |
WO2019183214A1 (en) | 2019-09-26 |
CN117327521A (zh) | 2024-01-02 |
EP3769322A4 (en) | 2022-01-12 |
CN116884670A (zh) | 2023-10-13 |
US20210027911A1 (en) | 2021-01-28 |
CN117343769A (zh) | 2024-01-05 |
US20240043766A1 (en) | 2024-02-08 |
CN112005319A (zh) | 2020-11-27 |
CN112041942B (zh) | 2023-10-03 |
BR112020019106A2 (pt) | 2020-12-29 |
CN112041942A (zh) | 2020-12-04 |
JP2023126767A (ja) | 2023-09-12 |
WO2019183213A1 (en) | 2019-09-26 |
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