JP6785870B2 - 高分子組成物 - Google Patents
高分子組成物 Download PDFInfo
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- JP6785870B2 JP6785870B2 JP2018544232A JP2018544232A JP6785870B2 JP 6785870 B2 JP6785870 B2 JP 6785870B2 JP 2018544232 A JP2018544232 A JP 2018544232A JP 2018544232 A JP2018544232 A JP 2018544232A JP 6785870 B2 JP6785870 B2 JP 6785870B2
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- URRFGQHFJDWCFM-UHFFFAOYSA-N tris(2-butoxyethyl) phosphite Chemical compound CCCCOCCOP(OCCOCCCC)OCCOCCCC URRFGQHFJDWCFM-UHFFFAOYSA-N 0.000 description 1
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
- LUUMBHMWFNNZPH-UHFFFAOYSA-N tris(3,5-ditert-butyl-4-hydroxyphenyl) phosphite Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(OP(OC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)OC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 LUUMBHMWFNNZPH-UHFFFAOYSA-N 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
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- C09J133/04—Homopolymers or copolymers of esters
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Description
本出願は、2016年9月8日付けの韓国特許出願第10−2016−0115609号に基づく優先権の利益を主張し、当該韓国特許出願の文献に開示されたすべての内容は、本明細書の一部として含まれる。
例示的な光学積層体は、光学フィルムと;前記光学フィルムの一面に形成されている粘着剤層とを含むことができる。前記粘着剤層は、例えば、前記光学フィルムをディスプレイ装置の液晶パネルなどや他の光学フィルムに付着するための粘着剤層であってもよい。前記粘着剤層は、前述した本発明の高分子組成物の架橋物を主成分として含むことができる。前記で光学フィルムとしては、偏光フィルム、位相差フィルムまたは輝度向上フィルムなどや前記のうち2種以上が積層された積層体が例示され得る。
A’セグメントは、好ましくは、ブチルアクリレート、エチレングリコールまたは2−エチルヘキシルアクリレートに由来する重合単位を主成分として含むことができる。A’セグメントが前述した重合単位を主成分として含むことによって、粘着型光学フィルムに適した粘着剤層を形成し得るベースポリマーを提供することができる。
数平均分子量(Mn)および分子量分布(PDI)は、GPC(Gel permeation chromatography)を使用して以下の条件で測定し、検量線の製作には、Agilent systemの標準ポリスチレンを使用して測定結果を換算した。
測定機:Agilent GPC(Agilent 1200 series、U.S.)
コラム:PL Mixed B 2個連結
コラム温度:40℃
溶離液:THF(tetrahydrofuran)
流速:1.0mL/min
濃度:〜1mg/mL(100μL injection)
実施例または比較例で製造された粘着型偏光板を、横の長さが320cmであり、且つ縦の長さが180cmになるようにカットして、試験片を製造した。製造した試験片を粘着剤層を媒介で厚さが約0.7mm程度である市販のLCDパネルに付着し、試験片が付着したパネルを50℃および5気圧で約20分間保管して、サンプルを製造する。製造されたサンプルを80℃で300時間維持した後、粘着剤層の粘着界面においての気泡または剥離現象の発生の有無を観察し、下記の基準に基づいて耐久性を評価する。
A:気泡および剥離現象の発生が観察されない場合
B:気泡および/または剥離現象が若干観察される場合
C:気泡および/または剥離現象が多量観察される場合
実施例または比較例で製造された粘着型偏光板を、横の長さが3cmであり、且つ縦の長さが40.5cmになるようにカットして、試験片を製造する。製造した試験片を粘着剤層を媒介で厚さが約0.7mm程度である横4cmおよび縦42cmのLCD用パネルに付着する。試験片の一方の端部を磁石を利用して鉄板支持台付きオーブン壁に取り付け、他方の端部が壁から浮かび上がった距離(d1)を測定する。試験片を60℃で72時間保管した後、オーブン壁から浮かび上がった距離(d2)を測定し、曲げを測定する。曲げの相対分率は、比較例3のランダム共重合体を使用した試験片の曲げ値を基準として計算する。
曲げの相対分率(%)=(試験片の曲げ/基準試験片の曲げ)×100
エチレンビス(2−ブロモイソブチレート)0.5g、ブチルアクリレート(Butyl acrylate、BA)15.5gおよびエチルアセテート(Ethyl acetate)16gを500mLの丸い底フラスコに入れ、シールした後、約40分間窒素でバブリングして酸素を除去した。酸素を除去した後、フラスコを65℃に加熱したオイルバスに入れ、0.002gのCuBr2と0.006gのTPMA(tris(2−pyridylmethyl)amine)を酸素を除去した0.1mLのDMF(N、N−dimethylformamide)に溶かした溶液を前記フラスコに投入した。次いで、触媒還元剤として、Sn(EH)2(tin(II)2−ethylhexanoate)0.04gを投入して、反応を開始した。単量体の転換率が約90%である時点であらかじめ酸素を除去しておいたメチルメタクリレート(Methyl methacrylate、MMA)140gおよびエチルアセテート(Ethyl acetate)140gを投入し、さらに40分間窒素でバブリングして酸素を除去した。反応物の温度が65℃に到達すると、0.025gのCuBr2と0.064gのTPMA(tris(2−pyridylmethyl)amine)を酸素を除去した1.0mLのDMF(N、N−dimethylformamide)に溶かした溶液を投入し、0.49gのSn(EH)2(tin(II)2−ethylhexanoate)を入れ、鎖延長反応を行った。転換率が80%以上に到達したときに反応を終了し、数平均分子量(Mn)が85,000であり、分子量分布(Mw/Mn)が1.32であるマクロ開始剤を製造した。メタノールに反応混合物を滴加して沈殿を得、真空乾燥して収得した前記マクロ開始剤100g、ブチルアクリレート(Butyl acrylate、BA)840g、4−ヒドロキシブチルアクリレート(4−Hydroxybutyl acrylate、4−HBA)8.5gおよびエチルアセテート1000gを3Lの重合反応器に投入し、約60分間窒素でバブリングして酸素を除去した。窒素の雰囲気の下で反応温度を約65℃に維持した状態で0.047gのCuBr2と、0.12gのTPMA(tris(2−pyridylmethyl)amine)および5mLのDMF(N、N−dimethylformamide)を混合した触媒溶液を投入し、Sn(EH)2(tin(II)2−ethylhexanoate)1.23g を投入して、反応を開始した。反応転換率が約70%に到達した時点で反応を終了し、分子量(Mn)が350,000であり、分子量分布(Mw/Mn)が1.84であるブロック共重合体溶液を製造した。前記で第1ブロックと第2ブロックの重量比は14:86程度である。
エチレンビス(2−ブロモイソブチレート)0.26g、ブチルアクリレート(Butyl acrylate、BA)28.2gおよびエチルアセテート(Ethyl acetate)30gを500mLの丸い底フラスコに入れ、シールした後、約40分間窒素でバブリングして酸素を除去した。酸素を除去した後、フラスコを65℃に加熱したオイルバスに入れ、0.005gのCuBr2と0.013gのTPMA(tris(2−pyridylmethyl)amine)を酸素を除去した0.2mLのDMF(N、N−dimethylformamide)に溶かした溶液を前記フラスコに投入した。次いで、触媒還元剤としてアゾビスイソブチロニトリル(Azobisisobutyronitrile、AIBN)を5重量%で含有し、溶媒がエチルアセテート(Ethyl acetate)である溶液0.72gを投入して、反応を開始した。単量体の転換率が約90%である時点であらかじめ酸素を除去しておいたメチルメタクリレート(Methyl methacrylate、MMA)145g、スチレン14.5gおよびエチルアセテート(Ethyl acetate)160gを投入し、さらに40分間窒素でバブリングして酸素を除去した。反応物の温度が65℃に到達すると、0.036gのCuBr2と0.092gのTPMA(tris(2−pyridylmethyl)amine)を酸素を除去した1.5mLのDMF(N、N−dimethylformamide)に溶かした溶液を投入し、アゾビスイソブチロニトリル(Azobisisobutyronitrile、AIBN)を5重量%で含有し、溶媒がエチルアセテート(Ethyl acetate)である溶液6gを投入して、鎖延長反応を行った。転換率が80%に到達したとき、反応混合物をポンプを用いて3Lの重合反応器に全量移送した。3Lの反応器にブチルアクリレート(Butyl acrylate)1300g、4−ヒドロキシブチルアクリレート(4−Hydroxybutyl acrylate、4−HBA)13.1gおよびエチルアセテート(Ethyl acetate)1000gを投入し、約60分間窒素でバブリングして酸素を除去した。窒素の雰囲気の下で反応温度を約65℃に維持した状態で0.035gのCuBr2と、0.090gのTPMA(tris(2−pyridylmethyl)amine)および5mLのDMF(N、N−dimethylformamide)を混合した触媒溶液を投入し、アゾビスイソブチロニトリル(Azobisisobutyronitrile、AIBN)を5重量%で含有し、溶媒がエチルアセテート(Ethyl acetate)である溶液3.3gを投入して、反応を鎖延長反応を開始した。反応転換率が約80%に到達した時点で反応を終了し、分子量(Mn)が250,000であり、分子量分布(Mw/Mn)が2.88であるブロック共重合体溶液を製造した。前記で第1ブロックと第2ブロックの重量比は15:85程度である。
ポリエチレングリコール、ビス(2−ブロモイソブチレート)(数平均分子量(Mn)が10,000)19.5g、メチルメタクリレート(Methyl methacrylate、MMA)150g、およびエチルアセテート170gを500mLの丸い底フラスコに入れ、40分間窒素でバブリングして酸素を除去した。フラスコを65℃に加熱したオイルバスに入れ、反応物の温度が65℃に到達すると、0.033gのCuBr2と0.085gのTPMA(tris(2−pyridylmethyl)amine)を酸素を除去した1.5mLのDMF(N、N−dimethylformamide)に溶かした溶液を投入し、アゾビスイソブチロニトリル(Azobisisobutyronitrile、AIBN)を5重量%で含有し、溶媒がエチルアセテート(Ethyl acetate)である溶液5.3gを投入して、鎖延長反応を行った。転換率が80%に到達したとき、反応混合物をポンプを用いて3Lの重合反応器に全量移送した。3Lの反応器にブチルアクリレート(Butyl acrylate、BA)1320g、4−ヒドロキシブチルアクリレート(4−Hydroxybutyl acrylate、4−HBA)13.3gおよびエチルアセテート(Ethyl acetate)1000gを投入し、約60分間窒素でバブリングして酸素を除去した。窒素の雰囲気の下で反応温度を約65℃に維持した状態で0.039gのCuBr2と、0.10gのTPMA(tris(2−pyridylmethyl)amine)および5mLのDMF(N、N−dimethylformamide)を混合した触媒溶液を投入し、アゾビスイソブチロニトリル(Azobisisobutyronitrile、AIBN)を5重量%で含有し、溶媒がエチルアセテート(Ethyl acetate)である溶液3.3gを投入して、鎖延長反応を開始した。反応転換率が約85%に到達した時点で反応を終了し、分子量(Mn)が240,000であり、分子量分布(Mw/Mn)が3.15であるブロック共重合体溶液を製造した。前記で第1ブロックと第2ブロックの重量比は13:87程度である。
エチレングリコールジ−アルファブロモイソブチレート0.33g、2−エチルヘキシルアクリレート(2−Ethylhexyl acrylate、2−EHA)22.9gおよびエチルアセテート(Ethyl acetate)25gを500mLの丸い底フラスコに入れ、シールした後、約40分間窒素でバブリングして酸素を除去した。酸素を除去した後、フラスコを65℃に加熱したオイルバスに入れ、0.003gのCuBr2と0.007gのTPMA(tris(2−pyridylmethyl)amine)を酸素を除去した0.2mLのDMF(N、N−dimethylformamide)に溶かした溶液を前記フラスコに投入した。次いで、触媒還元剤としてアゾビスイソブチロニトリル(Azobisisobutyronitrile、AIBN)5%EA溶液0.40gを投入して、反応を開始した。単量体の転換率が約90%である時点であらかじめ酸素を除去しておいたメチルメタクリレート(Methyl methacrylate、MMA)130gおよびエチルアセテート(Ethyl acetate)160gを投入し、さらに40分間窒素でバブリングして酸素を除去した。反応物の温度が65℃に到達すると、0.029gのCuBr2と0.075gのTPMA(tris(2−pyridylmethyl)amine)を酸素を除去した1.0mLのDMF(N、N−dimethylformamide)に溶かした溶液を投入して、アゾビスイソブチロニトリル(Azobisisobutyronitrile、AIBN)を5重量%で含有し、溶媒がエチルアセテート(Ethyl acetate)である溶液4.6gを投入して鎖延長反応を行った。転換率が80%に到達したとき、反応混合物をポンプを用いて3Lの重合反応器に全量移送した。3Lの反応器にブチルアクリレート(Butyl acrylate、BA)1185g、4−ヒドロキシブチルアクリレート(4−Hydroxybutyl acrylate、4−HBA)12.0gおよびエチルアセテート(Ethyl acetate)1000gを投入し、約60分間窒素でバブリングして酸素を除去した。窒素の雰囲気の下で反応温度を約65℃に維持した状態で0.036gのCuBr2と、0.093gのTPMA(tris(2−pyridylmethyl)amine)および5mLのDMF(N、N−dimethylformamide)を混合した触媒溶液を投入し、アゾビスイソブチロニトリル(Azobisisobutyronitrile、AIBN)を5重量%で含有し、溶媒がエチルアセテート(Ethyl acetate)である溶液3.0gを投入して、鎖延長反応を開始した。反応転換率が約70%に到達した時点で反応を終了し、分子量(Mn)が220,000であり、分子量分布(Mw/Mn)が2.85であるブロック共重合体溶液を製造した。前記で第1ブロックと第2ブロックの重量比は15:85程度である。
エチレングリコールジ−アルファブロモイソブチレート0.26g、メチルメタクリレート(Methyl methacrylate、MMA)190gおよびエチルアセテート(Ethyl acetate)190gを投入し、40分間窒素でバブリングして酸素を除去した。反応物の温度が65℃に到達すると、0.036gのCuBr2と0.092gのTPMA(tris(2−pyridylmethyl)amine)を酸素を除去した1.5mLのDMF(N、N−dimethylformamide)に溶かした溶液を投入し、アゾビスイソブチロニトリル(Azobisisobutyronitrile、AIBN)を5重量%で含有し、溶媒がエチルアセテート(Ethyl acetate)である溶液6gを投入して、鎖延長反応を行った。転換率が80%に到達したとき、反応混合物をポンプを用いて3Lの重合反応器に全量移送した。3Lの反応器にブチルアクリレート(Butyl acrylate、BA)1300g、4−ヒドロキシブチルアクリレート(4−Hydroxybutyl acrylate、4−HBA)13.1gおよびエチルアセテート(Ethyl acetate)1000gを投入し、約60分間窒素でバブリングして、酸素を除去した。窒素の雰囲気の下で反応温度を約65℃に維持した状態で、0.035gのCuBr2と、0.090gのTPMA(tris(2−pyridylmethyl)amine)および5mLのDMF(N、N−dimethylformamide)を混合した触媒溶液を投入し、アゾビスイソブチロニトリル(Azobisisobutyronitrile、AIBN)を5重量%で含有し、溶媒がエチルアセテート(Ethyl acetate)である溶液3.3gを投入して、鎖延長反応を開始した。反応転換率が約80%に到達した時点で反応を終了し、分子量(Mn)が240,000であり、分子量分布(Mw/Mn)が2.84であるブロック共重合体溶液を製造した。前記で第1ブロックと第2ブロックの重量比は15:85程度である。
エチルアルファブロモイソブチレート0.28g、メチルメタクリレート(Methyl methacrylate、MMA)190gおよびエチルアセテート(Ethyl acetate)190gを投入し、40分間窒素でバブリングして酸素を除去した。反応物の温度が65℃に到達すると、0.036gのCuBr2と0.092gのTPMA(tris(2−pyridylmethyl)amine)を酸素を除去した1.5mLのDMF(N、N−dimethylformamide)に溶かした溶液を投入し、アゾビスイソブチロニトリル(Azobisisobutyronitrile、AIBN)を5重量%で含有し、溶媒がエチルアセテート(Ethyl acetate)である溶液6gを投入して、鎖延長反応を行った。転換率が80%に到達したとき、反応混合物をポンプを用いて3Lの重合反応器に全量移送した。3Lの反応器にブチルアクリレート(Butyl acrylate、BA)1300g、4−ヒドロキシブチルアクリレート(4−Hydroxybutyl acrylate、4−HBA)13.1gおよびエチルアセテート(Ethyl acetate)1000gを投入し、約60分間窒素でバブリングして、酸素を除去した。窒素の雰囲気の下で反応温度を約65℃に維持した状態で0.035gのCuBr2と、0.090gのTPMA(tris(2−pyridylmethyl)amine)および5mLのDMF(N、N−dimethylformamide)を混合した触媒溶液を投入し、アゾビスイソブチロニトリル(Azobisisobutyronitrile、AIBN)を5重量%で含有し、溶媒がエチルアセテート(Ethyl acetate)である溶液3.3gを投入して、鎖延長反応を開始した。反応転換率が約80%に到達した時点で反応を終了し、分子量(Mn)が260,000であり、分子量分布(Mw/Mn)が2.87であるブロック共重合体溶液を製造した。前記で第1ブロックと第2ブロックの重量比は、15:85程度である。
化学的架橋だけが導入されたランダム共重合体(B3)は、次のように製造した。ブチルアクリレート(Butyl acrylate、BA)200g、4−ヒドロキシブチルアクリレート(4−Hydroxybutyl acrylate、4−HBA)2.0gおよびエチルアセテート600gをフラスコに投入した後、60分間窒素でバブリングして、溶存酸素を除去する。反応温度が65℃に到達すると、アゾビスイソブチロニトリル(Azobisisobutyronitrille、AIBN)0.10gが含まれた2重量%エチルアセテート溶液を投入して、反応を開始する。反応転換率が約70%になると、反応を終了し、分子量(Mn)が220,000であり、分子量分が布4.52であるランダム共重合体を得た。
製造例1で製造したペンタブロック共重合体(A1)100重量部に架橋剤(TDI−TMPTA adduct、toluene diisocyanate−trimethylolpropane adduct)約0.2重量部と公知の架橋触媒約0.02重量部を配合して、高分子組成物を製造した。次いで、前記組成物を離型処理されたPET(poly(ethylene terephthalate))フィルムに約25μm程度の厚さでコーティングし、120℃で約3分間乾燥させた。次いで、形成された乾燥層を公知の偏光板の一面に転写して、粘着型偏光板を製造した。
製造例2〜4で製造したペンタブロック共重合体(A2、A3、A4)を使用したことを除いて、実施例1と同じ方式で粘着型偏光板を製造した。
比較製造例1〜3で製造したブロック共重合体(B1、B2)およびランダム共重合体を使用したことを除いて、実施例1と同じ方式で粘着型偏光板を製造した。
100 光学フィルム
110 下塗り層
120 粘着剤層
Claims (14)
- ガラス転移温度が20℃以上であり、トリブロック共重合体の形態である第1ブロックおよびガラス転移温度が10℃以下である第2ブロックを含み、
前記第1または第2ブロックは、架橋性官能基を含み、
前記第2ブロックは、前記第1ブロックの両末端にそれぞれ結合されているブロック共重合体を含み、
前記第1ブロックは、AブロックとBブロックを含み、前記Aブロックが前記Bブロックの両末端にそれぞれ結合されており、第2ブロックが前記Aブロックの末端に結合されており、
前記Aブロックは、アルキルメタクリレート、アクリルアミド、N−アルキルアクリルアミド、スチレン、スチレン誘導体、マレイミドおよびアクリロニトリルよりなる群から選ばれた一つ以上に由来する重合単位を主成分として含み、
前記Bブロックは、アルキルアクリレート、オレフィン化合物、ジエン化合物およびアルキレンオキシドよりなる群から選ばれた一つ以上に由来する重合単位を主成分として含み、
前記第2ブロックは、アルキルアクリレートに由来する重合単位を主成分として含み、
架橋性官能基と反応する官能基を有する多官能性架橋剤をさらに含む、高分子組成物。 - 第1ブロックは、ガラス転移温度が30℃以上のAブロックとガラス転移温度が0℃以下のBブロックを含む、請求項1に記載の高分子組成物。
- AおよびBブロックの合計重量を基準としてAブロックの重量比が50〜95重量%の範囲内である、請求項1に記載の高分子組成物。
- 第1ブロックの数平均分子量は、15,000〜150,000の範囲内にある、請求項1に記載の高分子組成物。
- 第1ブロックの多分散度(Mw/Mn)が1.01〜3の範囲内にある、請求項1に記載の高分子組成物。
- 第2ブロックは、アルキルアクリレート100重量部に対して0.1〜5重量部の架橋性単量体に由来する重合単位をさらに含む、請求項1に記載の高分子組成物。
- 第1および第2ブロックの合計重量を基準とする第2ブロックの重量比は、65〜95重量%の範囲内である、請求項1に記載の高分子組成物。
- ブロック共重合体は、数平均分子量(Mn)が10万〜80万の範囲内である、請求項1に記載の高分子組成物。
- ブロック共重合体は、多分散度(Mw/Mn)が5以下である、請求項1に記載の高分子組成物。
- ブロック共重合体は、相分離構造を形成する、請求項1に記載の高分子組成物。
- 相分離構造は、スフィア構造である、請求項10に記載の高分子組成物。
- 光学フィルムと;前記光学フィルムの一面に形成されている粘着剤層と;を含み、前記粘着剤層は、請求項1に記載の高分子組成物の架橋物を含む光学積層体。
- 光学フィルムに下塗り層を介して粘着剤層が設けられている粘着型光学フィルムにおいて、粘着剤層が請求項1に規定の高分子組成物を含有する粘着剤により形成されており、また、前記下塗り層は、ポリマー類を含有することを特徴とする、粘着型光学フィルム。
- 請求項12に記載の光学積層体を含むディスプレイ装置。
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JP7400572B2 (ja) | 2020-03-19 | 2023-12-19 | 三菱ケミカル株式会社 | 活性エネルギー線硬化性剥離型粘着剤組成物および剥離型粘着シート |
Family Cites Families (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19855062A1 (de) * | 1998-11-28 | 2000-05-31 | Bayer Ag | Blockcopolymere auf Vinylcyclohexanbasis |
JP4572006B2 (ja) | 1998-12-08 | 2010-10-27 | 日東電工株式会社 | 粘着剤組成物およびその製造方法と粘着シ―ト類 |
US6288173B1 (en) | 1999-06-03 | 2001-09-11 | Ppg Industries Ohio, Inc. | Block copolymers |
DE10129608A1 (de) * | 2001-06-20 | 2003-05-28 | Tesa Ag | Stripfähige Systeme auf Basis von Acrylatblockcopolymeren |
DE10248380A1 (de) * | 2002-10-17 | 2004-08-05 | Tesa Ag | Haftklebrige Formteile |
DE10256782A1 (de) * | 2002-12-05 | 2004-08-05 | Tesa Ag | Haftklebeartikel |
CN101107282B (zh) * | 2005-01-21 | 2011-03-30 | 日本曹达株式会社 | 高分子、交联高分子、高分子固体电解质用组合物、高分子固体电解质和粘接性组合物 |
EP1865003A1 (en) * | 2005-03-28 | 2007-12-12 | Kaneka Corporation | Acrylic block copolymer and reactive hot-melt adhesive compositions |
DE102006035786A1 (de) * | 2006-07-28 | 2008-03-13 | Tesa Ag | Haftklebefolie mit hoher optischer Transparenz zur Verklebung als Splitterschutz auf Glasscheiben in Konsumgüterelektronikbauteilen |
DE102007039535A1 (de) * | 2007-08-21 | 2009-02-26 | Evonik Röhm Gmbh | Verfahren zur Herstellung von Pentablockcopolymeren mit OH-funktionalisierten Blöcken auf (Meth)acrylatbasis |
KR101171976B1 (ko) | 2007-12-29 | 2012-08-08 | 주식회사 엘지화학 | 아크릴계 점착제 조성물, 이를 포함하는 편광판 및액정표시장치 |
JP5379168B2 (ja) | 2008-03-07 | 2013-12-25 | スリーエム イノベイティブ プロパティズ カンパニー | 帯電防止性ロックコポリマー感圧性接着剤及び物品 |
KR101171977B1 (ko) | 2008-06-05 | 2012-08-08 | 주식회사 엘지화학 | 아크릴계 점착제 조성물, 이를 포함하는 편광판 및액정표시장치 |
KR101023839B1 (ko) | 2008-07-24 | 2011-03-22 | 주식회사 엘지화학 | 점착제 조성물, 상기를 포함하는 편광판 및 액정표시장치 |
JP5563778B2 (ja) * | 2008-09-30 | 2014-07-30 | 積水化学工業株式会社 | 粘着剤組成物 |
US20120029139A1 (en) * | 2009-01-30 | 2012-02-02 | Centre National De La Recherche Scientifique (Cnrs | Block copolymers having associative groups, and adhesive containing same |
EP2578655B1 (en) * | 2010-06-04 | 2016-07-13 | Kuraray Co., Ltd. | Pressure-sensitive adhesive composition for optical film and pressure-sensitive adhesion type optical film |
KR20140119167A (ko) * | 2012-01-31 | 2014-10-08 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 공중합체를 포함하는 필름, 물품 및 방법 |
US9334423B2 (en) * | 2012-08-31 | 2016-05-10 | Basf Se | Compositions comprising an acrylic block copolymer and a UV-curable copolymer and methods of making and using the same |
WO2014178674A1 (ko) * | 2013-05-02 | 2014-11-06 | 주식회사 엘지화학 | 멀티 블록 공중합체 |
WO2015030550A1 (ko) * | 2013-08-30 | 2015-03-05 | 주식회사 엘지화학 | 블록 공중합체 |
US10308751B2 (en) * | 2013-08-30 | 2019-06-04 | Lg Chem, Ltd. | Block copolymer |
JP6378559B2 (ja) * | 2014-07-08 | 2018-08-22 | 日東電工株式会社 | アンカー層形成用組成物、アンカー層、粘着剤層付光学フィルム、及び、画像表示装置 |
KR101713406B1 (ko) | 2015-03-27 | 2017-03-07 | 아이디에이씨 홀딩스, 인크. | 실수 m진 신호 부호화 방법, 및 이를 이용한 부호화 장치 |
KR102672525B1 (ko) * | 2015-08-21 | 2024-06-07 | 가부시키가이샤 닛폰 쇼쿠바이 | 블록 공중합체 |
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KR102097817B1 (ko) | 2020-04-07 |
KR20180028215A (ko) | 2018-03-16 |
WO2018048216A1 (ko) | 2018-03-15 |
TWI642745B (zh) | 2018-12-01 |
CN108779319B (zh) | 2021-01-15 |
EP3434745A4 (en) | 2019-06-12 |
TW201816054A (zh) | 2018-05-01 |
US11180597B2 (en) | 2021-11-23 |
CN108779319A (zh) | 2018-11-09 |
US20200010600A1 (en) | 2020-01-09 |
EP3434745A1 (en) | 2019-01-30 |
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