JP6345687B2 - 難燃性ポリカーボネート成形組成物vi - Google Patents
難燃性ポリカーボネート成形組成物vi Download PDFInfo
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- JP6345687B2 JP6345687B2 JP2015545789A JP2015545789A JP6345687B2 JP 6345687 B2 JP6345687 B2 JP 6345687B2 JP 2015545789 A JP2015545789 A JP 2015545789A JP 2015545789 A JP2015545789 A JP 2015545789A JP 6345687 B2 JP6345687 B2 JP 6345687B2
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- 239000000203 mixture Substances 0.000 title claims description 88
- 229920000515 polycarbonate Polymers 0.000 title claims description 28
- 239000004417 polycarbonate Substances 0.000 title claims description 28
- 239000003063 flame retardant Substances 0.000 title claims description 15
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims description 13
- 238000000465 moulding Methods 0.000 title description 16
- 229920001971 elastomer Polymers 0.000 claims description 59
- 239000005060 rubber Substances 0.000 claims description 59
- 239000000178 monomer Substances 0.000 claims description 52
- 229920002379 silicone rubber Polymers 0.000 claims description 48
- 239000004945 silicone rubber Substances 0.000 claims description 45
- 125000003118 aryl group Chemical group 0.000 claims description 27
- GKTNLYAAZKKMTQ-UHFFFAOYSA-N n-[bis(dimethylamino)phosphinimyl]-n-methylmethanamine Chemical compound CN(C)P(=N)(N(C)C)N(C)C GKTNLYAAZKKMTQ-UHFFFAOYSA-N 0.000 claims description 25
- 229920002554 vinyl polymer Polymers 0.000 claims description 25
- 238000004519 manufacturing process Methods 0.000 claims description 24
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 21
- 125000000217 alkyl group Chemical group 0.000 claims description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- 229920000578 graft copolymer Polymers 0.000 claims description 19
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 18
- 229920001283 Polyalkylene terephthalate Polymers 0.000 claims description 17
- 229920000728 polyester Polymers 0.000 claims description 16
- 150000002367 halogens Chemical class 0.000 claims description 13
- 239000002131 composite material Substances 0.000 claims description 12
- 125000004122 cyclic group Chemical group 0.000 claims description 12
- 229910052736 halogen Inorganic materials 0.000 claims description 12
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 10
- 239000013638 trimer Substances 0.000 claims description 10
- 229920001169 thermoplastic Polymers 0.000 claims description 9
- 239000004416 thermosoftening plastic Substances 0.000 claims description 9
- 239000000654 additive Substances 0.000 claims description 7
- 229920006163 vinyl copolymer Polymers 0.000 claims description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- 239000003381 stabilizer Substances 0.000 claims description 5
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 3
- 125000003277 amino group Chemical group 0.000 claims description 3
- 239000002216 antistatic agent Substances 0.000 claims description 3
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 3
- 125000004104 aryloxy group Chemical group 0.000 claims description 3
- 239000000314 lubricant Substances 0.000 claims description 3
- 239000006082 mold release agent Substances 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 239000012779 reinforcing material Substances 0.000 claims description 3
- 239000003086 colorant Substances 0.000 claims description 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 239000002667 nucleating agent Substances 0.000 claims description 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 2
- 238000002347 injection Methods 0.000 claims 1
- 239000007924 injection Substances 0.000 claims 1
- 230000035515 penetration Effects 0.000 claims 1
- -1 phosphorus compound Chemical class 0.000 description 58
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 27
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 17
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 16
- 229920000642 polymer Polymers 0.000 description 15
- 239000003431 cross linking reagent Substances 0.000 description 14
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 13
- 125000004432 carbon atom Chemical group C* 0.000 description 13
- 238000000034 method Methods 0.000 description 13
- KKEYFWRCBNTPAC-UHFFFAOYSA-N benzene-dicarboxylic acid Natural products OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 12
- 229920001577 copolymer Polymers 0.000 description 12
- 239000002245 particle Substances 0.000 description 12
- 239000000460 chlorine Substances 0.000 description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 11
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 10
- 239000006085 branching agent Substances 0.000 description 10
- 229910052801 chlorine Inorganic materials 0.000 description 10
- 238000007720 emulsion polymerization reaction Methods 0.000 description 10
- 238000006116 polymerization reaction Methods 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000002253 acid Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 9
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 9
- 229920000098 polyolefin Polymers 0.000 description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 8
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 8
- 239000000839 emulsion Substances 0.000 description 8
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 8
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 7
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- 125000005907 alkyl ester group Chemical group 0.000 description 7
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 7
- 229910052794 bromium Inorganic materials 0.000 description 7
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 7
- 150000001735 carboxylic acids Chemical class 0.000 description 7
- 238000004132 cross linking Methods 0.000 description 7
- 238000010559 graft polymerization reaction Methods 0.000 description 7
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 7
- 239000004810 polytetrafluoroethylene Substances 0.000 description 7
- 150000003254 radicals Chemical class 0.000 description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical group OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 6
- 150000002009 diols Chemical class 0.000 description 6
- 229920000126 latex Polymers 0.000 description 6
- 239000004816 latex Substances 0.000 description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 230000008961 swelling Effects 0.000 description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- OCKWAZCWKSMKNC-UHFFFAOYSA-N [3-octadecanoyloxy-2,2-bis(octadecanoyloxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(COC(=O)CCCCCCCCCCCCCCCCC)(COC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC OCKWAZCWKSMKNC-UHFFFAOYSA-N 0.000 description 5
- 150000004996 alkyl benzenes Chemical class 0.000 description 5
- 229940106691 bisphenol a Drugs 0.000 description 5
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 238000005227 gel permeation chromatography Methods 0.000 description 5
- 230000009477 glass transition Effects 0.000 description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 5
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 5
- 125000000962 organic group Chemical group 0.000 description 5
- 229910052698 phosphorus Inorganic materials 0.000 description 5
- 239000011574 phosphorus Substances 0.000 description 5
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 4
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 238000012662 bulk polymerization Methods 0.000 description 4
- 239000007957 coemulsifier Substances 0.000 description 4
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 239000011737 fluorine Substances 0.000 description 4
- 229910052731 fluorine Inorganic materials 0.000 description 4
- 150000003949 imides Chemical class 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 4
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 4
- KTZVZZJJVJQZHV-UHFFFAOYSA-N 1-chloro-4-ethenylbenzene Chemical compound ClC1=CC=C(C=C)C=C1 KTZVZZJJVJQZHV-UHFFFAOYSA-N 0.000 description 3
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 3
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 3
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 150000008064 anhydrides Chemical class 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 125000001309 chloro group Chemical group Cl* 0.000 description 3
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 3
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 230000003301 hydrolyzing effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000002609 medium Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 150000002825 nitriles Chemical class 0.000 description 3
- 125000005375 organosiloxane group Chemical group 0.000 description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 3
- 229920001707 polybutylene terephthalate Polymers 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- 150000004756 silanes Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 2
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 2
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 2
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical class O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 description 2
- BSWWXRFVMJHFBN-UHFFFAOYSA-N 2,4,6-tribromophenol Chemical compound OC1=C(Br)C=C(Br)C=C1Br BSWWXRFVMJHFBN-UHFFFAOYSA-N 0.000 description 2
- WHBAYNMEIXUTJV-UHFFFAOYSA-N 2-chloroethyl prop-2-enoate Chemical compound ClCCOC(=O)C=C WHBAYNMEIXUTJV-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 2
- VLZDYNDUVLBNLD-UHFFFAOYSA-N 3-(dimethoxymethylsilyl)propyl 2-methylprop-2-enoate Chemical compound COC(OC)[SiH2]CCCOC(=O)C(C)=C VLZDYNDUVLBNLD-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 229920001634 Copolyester Polymers 0.000 description 2
- 239000004971 Cross linker Substances 0.000 description 2
- 239000004641 Diallyl-phthalate Substances 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- 150000008065 acid anhydrides Chemical class 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 2
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 125000005587 carbonate group Chemical group 0.000 description 2
- 238000010538 cationic polymerization reaction Methods 0.000 description 2
- PFURGBBHAOXLIO-UHFFFAOYSA-N cyclohexane-1,2-diol Chemical compound OC1CCCCC1O PFURGBBHAOXLIO-UHFFFAOYSA-N 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- 125000001188 haloalkyl group Chemical group 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002391 heterocyclic compounds Chemical class 0.000 description 2
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 2
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 2
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- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- KYPYTERUKNKOLP-UHFFFAOYSA-N Tetrachlorobisphenol A Chemical compound C=1C(Cl)=C(O)C(Cl)=CC=1C(C)(C)C1=CC(Cl)=C(O)C(Cl)=C1 KYPYTERUKNKOLP-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- LAUIXFSZFKWUCT-UHFFFAOYSA-N [4-[2-(4-phosphonooxyphenyl)propan-2-yl]phenyl] dihydrogen phosphate Chemical compound C=1C=C(OP(O)(O)=O)C=CC=1C(C)(C)C1=CC=C(OP(O)(O)=O)C=C1 LAUIXFSZFKWUCT-UHFFFAOYSA-N 0.000 description 1
- 150000008360 acrylonitriles Chemical class 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 229910000413 arsenic oxide Inorganic materials 0.000 description 1
- 125000000732 arylene group Chemical group 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- UWCPYKQBIPYOLX-UHFFFAOYSA-N benzene-1,3,5-tricarbonyl chloride Chemical compound ClC(=O)C1=CC(C(Cl)=O)=CC(C(Cl)=O)=C1 UWCPYKQBIPYOLX-UHFFFAOYSA-N 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 230000031709 bromination Effects 0.000 description 1
- 238000005893 bromination reaction Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 150000001804 chlorine Chemical class 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- AOGYCOYQMAVAFD-UHFFFAOYSA-N chlorocarbonic acid Chemical class OC(Cl)=O AOGYCOYQMAVAFD-UHFFFAOYSA-N 0.000 description 1
- HAURRGANAANPSQ-UHFFFAOYSA-N cis-2,4,6-Trimethyl-2,4,6-triphenylcyclotrisiloxane Chemical compound O1[Si](C)(C=2C=CC=CC=2)O[Si](C)(C=2C=CC=CC=2)O[Si]1(C)C1=CC=CC=C1 HAURRGANAANPSQ-UHFFFAOYSA-N 0.000 description 1
- PMMYEEVYMWASQN-IMJSIDKUSA-N cis-4-Hydroxy-L-proline Chemical compound O[C@@H]1CN[C@H](C(O)=O)C1 PMMYEEVYMWASQN-IMJSIDKUSA-N 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical compound OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 description 1
- RLMGYIOTPQVQJR-UHFFFAOYSA-N cyclohexane-1,3-diol Chemical compound OC1CCCC(O)C1 RLMGYIOTPQVQJR-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000001142 dicarboxylic acid group Chemical group 0.000 description 1
- YLJJAVFOBDSYAN-UHFFFAOYSA-N dichloro-ethenyl-methylsilane Chemical compound C[Si](Cl)(Cl)C=C YLJJAVFOBDSYAN-UHFFFAOYSA-N 0.000 description 1
- MROCJMGDEKINLD-UHFFFAOYSA-N dichlorosilane Chemical compound Cl[SiH2]Cl MROCJMGDEKINLD-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- HRKQOINLCJTGBK-UHFFFAOYSA-N dihydroxidosulfur Chemical compound OSO HRKQOINLCJTGBK-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 1
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
- 239000001177 diphosphate Substances 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004870 electrical engineering Methods 0.000 description 1
- 238000010616 electrical installation Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000194 fatty acid Chemical class 0.000 description 1
- 229930195729 fatty acid Chemical class 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 1
- HTDJPCNNEPUOOQ-UHFFFAOYSA-N hexamethylcyclotrisiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O1 HTDJPCNNEPUOOQ-UHFFFAOYSA-N 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- OHMBHFSEKCCCBW-UHFFFAOYSA-N hexane-2,5-diol Chemical compound CC(O)CCC(C)O OHMBHFSEKCCCBW-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000010365 information processing Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000012796 inorganic flame retardant Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910000358 iron sulfate Inorganic materials 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- AKIDPNOWIHDLBQ-UHFFFAOYSA-N naphthalene-1,4,5,8-tetracarbonyl chloride Chemical compound C1=CC(C(Cl)=O)=C2C(C(=O)Cl)=CC=C(C(Cl)=O)C2=C1C(Cl)=O AKIDPNOWIHDLBQ-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- 229920002842 oligophosphate Polymers 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000004028 organic sulfates Chemical class 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 125000005342 perphosphate group Chemical group 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 229960001553 phloroglucinol Drugs 0.000 description 1
- 150000003017 phosphorus Chemical class 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002215 polytrimethylene terephthalate Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- WIJVUKXVPNVPAQ-UHFFFAOYSA-N silyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)O[SiH3] WIJVUKXVPNVPAQ-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 238000010558 suspension polymerization method Methods 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- UQMOLLPKNHFRAC-UHFFFAOYSA-N tetrabutyl silicate Chemical compound CCCCO[Si](OCCCC)(OCCCC)OCCCC UQMOLLPKNHFRAC-UHFFFAOYSA-N 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- ZQZCOBSUOFHDEE-UHFFFAOYSA-N tetrapropyl silicate Chemical compound CCCO[Si](OCCC)(OCCC)OCCC ZQZCOBSUOFHDEE-UHFFFAOYSA-N 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Polymers OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
- XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical compound C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 description 1
- 238000005199 ultracentrifugation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
- C08L69/005—Polyester-carbonates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6581—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and nitrogen atoms with or without oxygen or sulfur atoms, as ring hetero atoms
- C07F9/659—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and nitrogen atoms with or without oxygen or sulfur atoms, as ring hetero atoms having three phosphorus atoms as ring hetero atoms in the same ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
- C08L51/085—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds on to polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/5399—Phosphorus bound to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
A)60〜95重量部、好ましくは65〜90重量部、より好ましくは70〜85重量部、特に好ましくは76〜88重量部、の芳香族ポリカーボネート及び/又は芳香族ポリエステルカーボネート、
B)1.0〜15.0重量部、好ましくは3.0〜12.5重量部、特に好ましくは4.0〜10.0重量部の、シリコーンゴム、シリコーン−アクリレートゴムおよびアクリレートゴム、好ましくはシリコーン−アクリレートゴムからなる群から選択されるブラフトベースとしての、ゴム変性したグラフト重合体、
C)1.0〜20.0重量部、好ましくは1.0〜15.0重量部、より好ましくは1.0〜12.5重量部、特に好ましくは1.5〜10.0重量部、の少なくとも一種の式(X)の環状ホスファゼン
kは、1又は1〜10の整数、好ましくは1〜8、特に好ましくは1〜5の数を表し、
三量体含有量(k=1)が、成分Cに対して、60〜98mol%、より好ましくは65〜95mol%、特に好ましくは65〜90mol%、最も好ましくは65〜85mol%、特に70〜85mol%であり、
Rは、それぞれの場合に、同一であるか、又は異なるものであって、アミン基;それぞれ所望によりハロゲン化、好ましくはフッ素でハロゲン化されている、C1〜C8アルキル、好ましくはメチル、エチル、プロピル又はブチル;C1〜C8アルコキシ、好ましくはメトキシ、エトキシ、プロポキシ又はブトキシ;それぞれ所望によりアルキル、好ましくはC1〜C4アルキル、及び/又はハロゲン、好ましくは塩素及び/又は臭素により置換されている、C5〜C6シクロアルキル;それぞれ所望によりアルキル、好ましくはC1〜C4アルキル、及び/又はハロゲン、好ましくは塩素、臭素及び/又はヒドロキシにより置換されている、C6〜C20アリールオキシ、好ましくはフェノキシ、ナフチルオキシ;それぞれ所望によりアルキル、好ましくはC1〜C4アルキル、及び/又はハロゲン、好ましくは塩素及び/又は臭素により置換されている、C7〜C12アラルキル、好ましくはフェニル−C1〜C4アルキル;又はハロゲン基、好ましくは塩素、又はOH基を表す。)、
D)0〜15.0重量部、好ましくは2.0〜12.5重量部、より好ましくは3.0〜9.0重量部、特に好ましくは3.0〜6.0重量部、のゴムを含まない、ビニル(共)重合体又はポリアルキレンテレフタレート、
E)0〜15.0重量部、好ましくは0.05〜15.00重量部、より好ましくは0.2〜10.0重量部、特に好ましくは0.4〜5.0重量部、の添加剤、
F)0.05〜5.0重量部、好ましくは0.1〜2.0重量部、特に好ましくは0.1〜1.0重量部、の滴防止剤
を含んでなり、全ての重量部が好ましくは、本願では、組成物中の全ての成分A+B+C+D+E+Fの重量部の合計が100になるように、正規化されている組成物により、達成されることが分かった。
本発明に好適な成分Aによる芳香族ポリカーボネート及び/又は芳香族ポリエステルカーボネートは、文献中で公知であるか、又は、文献中で公知の方法により製造することができる(芳香族ポリカーボネートの製造に関しては、例えばSchnell、"Chemistry and Physics of Polycarbonates"、Interscience Publishers、1964及びDE-AS 1495626、独国特許出願公開第2232877号、第2703376号、第2714544号、第3000610号、第3832396号参照、芳香族ポリエステルカーボネートの製造に関しては、例えば独国特許出願公開第3007934号参照)。
Aは、単結合、C1〜C5アルキレン、C2〜C5アルキリデン、C5〜C6シクロアルキリデン、−O−、−SO−、−CO−、−S−、−SO2−、C6〜C12アリーレンであり、そこには所望により異原子を含むさらなる芳香族環が縮合することができる、
又は式(II)又は(III)の基であり、
xは、それぞれ相互に独立して、0、1または2であり、
pは、1または0であり、
R5及びR6は、各X1に対して個別に選択することができ、それぞれ相互に独立して、水素又はC1〜C6アルキル、好ましくは水素、メチル又はエチルであり、
X1は、炭素であり、
mは、4〜7の整数、好ましくは4または5であるが、ただし、少なくとも一個のX1上で、R5及びR6は、同時にアルキルである。)
成分Bは、グラフトベースとして、シリコーンゴム、シリコーン−アクリレートゴムおよびアクリレートゴムからなる群から選択される1種以上のゴム弾性グラフトポリマーを含む。
B.1 5〜95重量%、好ましくは20〜80重量%、特に30〜80重量%の、少なくとも1種のビニルモノマーと、
B.2 95〜5重量%、好ましくは80〜20重量%、特に70〜20重量%の、シリコーン、シリコーン−アクリレートおよびアクリレートゴムからなる群から選択される少なくとも1種のグラフトベースであって、ガラス転移温度が好ましくは<10℃、より好ましくは<0℃、特に好ましくは<−20℃である、少なくとも1種のグラフトベースと
のグラフト反応によって生成した1種以上のポリマーを含む。
B.1.1 50〜99重量部、好ましくは60〜80重量部、のビニル芳香族化合物および/または環上で置換されているビニル芳香族化合物(例えば、スチレン、α−メチルスチレン、p−メチルスチレン、p−クロロスチレン)および/または(メタ)アクリル酸(C1−C8)アルキルエステル(例えば、メチルメタクリレート、エチルメタクリレート)と、
B.1.2 1〜50重量部、好ましくは40〜20重量部、のシアン化ビニル(アクリロニトリルおよびメタクリロニトリルのような不飽和ニトリル)および/または(メタ)アクリル酸(C1−C8)アルキルエステル(例えば、メチルメタクリレート、n−ブチルアクリレート、tert−ブチルアクリレート)および/または不飽和カルボン酸(例えば、マレイン酸無水物およびN−フェニマレイミド)の誘導体(無水物やイミド等)と
の混合物である。
1) ジハロオルガノシランと、
2) 1)を基準として0〜10mol%のトリハロシランと、
3) 1)を基準として0〜3mol%のテトラハロシランと、
4) 1)を基準として0〜0.5mol%のハロトリオルガノシランと、
から得られ、化合物1)、2)、4)における有機基は、
α) C1−C6アルキルまたはシクロヘキシル、好ましくはメチルもしくはエチル、
β) C6−C12アリール、好ましくはフェニル、
γ) C1−C6アルケニル、好ましくはビニルもしくはアリル、
δ) メルカプトC1−C6アルキル、好ましくはメルカプトプロピル
であるが、ただし、合計(γ+δ)は、化合物1)、2)、4)における全ての有機基を基準として、2〜10mol%であり、モル比γ:δは3:1〜1:3、好ましくは2:1〜1:2である。
y-SiX3
(式中、
Xは加水分解可能性基、特にアルコキシまたはハロゲン基、であり、
yは有機基である。)
(a)グラフトベースとして、グラフトポリマー基準で、20〜90重量%の好ましくは−20℃以下のガラス転移点を有する、アクリレートゴムと、
(b)グラフトモノマーとして、グラフトポリマー基準で、10〜80重量%の少なくとも1種の重合性、エチレン性不飽和モノマー(B.1参照)
のグラフト反応によって得られる。
B.1 5〜95重量%、好ましくは7〜50重量%、特に好ましくは9〜30重量%の1種以上のビニルモノマーと
B.2 95〜5重量%、好ましくは93〜50重量%、特に好ましくは91〜70重量%の1種以上の、グラフトベースとしての、シリコーン−アクリレート複合ゴムと
のグラフト反応によって生成される1種以上のグラフトポリマーを含み、このシリコーン−アクリレートゴムは、
B.2.1 5〜75重量%、好ましくは7〜50重量%、特に好ましくは9〜40重量%のシリコーンゴムと、
B.2.2 95〜25重量%、好ましくは93〜50重量%、特に好ましくは91〜60重量%のポリアルキル(メタ)アクリレートゴムと
を含み、上記の2つのゴム成分B.2.1およびB.2.2が複合ゴムに浸透することで、これらは実質的に互いに分離不可能である。
R1は、C1〜C4アルキル、好ましくはメチル、エチルもしくはプロピル、またはフェニルを示し、
R2は、水素またはメチルを示し、
nは0、1または2を表し、
pは1〜6の整数を表す。)
本発明で使用する成分Cによるホスファゼンは、式(X)による環状ホスファゼンである。
Rは、それぞれの場合に、同一であるか、又は異なるものであって、
−アミン基、
−それぞれ所望によりハロゲン化、好ましくはフッ素でハロゲン化されている、より好ましくはモノハロゲン化されている、C1〜C8アルキル、好ましくはメチル、エチル、プロピル又はブチル、
−C1〜C8アルコキシ、好ましくはメトキシ、エトキシ、プロポキシ又はブトキシ、
−それぞれ所望によりアルキル、好ましくはC1〜C4アルキル、及び/又はハロゲン、好ましくは塩素及び/又は臭素により置換されている、C5〜C6シクロアルキル、
−それぞれ所望によりアルキル、好ましくはC1〜C4アルキル、及び/又はハロゲン、好ましくは塩素、臭素及び/又はヒドロキシにより置換されている、C6〜C20アリールオキシ、好ましくはフェノキシ、ナフチルオキシ、
−それぞれ所望によりアルキル、好ましくはC1〜C4アルキル、及び/又はハロゲン、好ましくは塩素及び/又は臭素により置換されている、C7〜C12アラルキル、好ましくはフェニル-C1〜C4アルキル、又は
−ハロゲン基、好ましくは塩素又はフッ素、又は
−OH基を表し、
kは、上記の意味を有する。)
成分Dは、一種以上の熱可塑性ビニル(共)重合体又はポリアルキレンテレフタレートを含んでなる。
D.1 50〜99重量部、好ましくは60〜80重量部のビニル芳香族化合物及び/又は環上で置換されたビニル芳香族化合物(例えばスチレン、α−メチルスチレン、p−メチルスチレン、p−クロロスチレン)及び/又は(メタ)アクリル酸(C1〜C8)−アルキルエステル(例えばメチルメタクリレート、エチルメタクリレート)、及び
D.2 1〜50重量部、好ましくは20〜40重量部のビニルシアン化物(不飽和ニトリル)、例えばアクリロニトリル及びメタクリロニトリル、及び/又は(メタ)アクリル酸(C1〜C8)−アルキルエステル、例えばメチルメタクリレート、n−ブチルアクリレート、tert−ブチルアクリレート、及び/又は不飽和カルボン酸、例えばマレイン酸、及び/又は不飽和カルボン酸の誘導体、例えば酸無水物及びイミド(例えば無水マレイン酸及びN−フェニルマレイミド)
の(共)重合体である。
組成物は、さらなる従来の重合体添加剤、例えば滴防止剤以外の難燃性相乗剤、潤滑剤及び離型剤(例えばペンタエリトリトールテトラステアレート)、核形成剤、安定剤(例えばUV/光安定剤、熱安定剤、酸化防止剤、エステル交換反応防止剤、加水分解安定剤)、帯電防止剤(例えば導電性ブラック、カーボン繊維、カーボンナノチューブ並びに有機帯電防止剤、例えばポリアルキレンエーテル、アルキルスルホナート又はポリアミド含有重合体)並びに着色剤、顔料、充填剤及び補強材料、特にガラス繊維、鉱物補強材料及び炭素繊維を含むことができる。
滴防止剤として、特にポリテトラフルオロエチレン(PTFE)又はPTFE含有組成物、例えばPTFEと、スチレン-又はメチルメタクリレート含有重合体もしくは共重合体の、粉体形態の、又は例えば成分Bと凝固した混合物の形態のマスターバッチ、を使用する。
ビスフェノールAを基剤とする直鎖状ポリカーボネート、重量平均分子量Mw27,500g/mol(標準としてポリカーボネートで、ジクロロメタン中でGPCにより測定)
ビスフェノールAを基剤とする直鎖状ポリカーボネート、重量平均分子量Mw25,000g/mol(標準としてポリカーボネートで、ジクロロメタン中でGPCにより測定)
B1
14重量%のメチルメタクリレートと86重量%のグラフトベースとしてのシリコーン−アクリレート複合ゴムとの反応によって調製したグラフトポリマーであり、このシリコーン−アクリレート複合ゴムは36重量%のシリコーンゴムと64重量%のポリアルキル(メタ)アクリレートを含み、この2つのゴム成分が複合ゴムに浸透し、お互いに実質的に分離不可能となっている
17重量%のメチルメタクリレートと83重量%のグラフトベースとしてのシリコーン−アクリレート複合ゴムとの反応によって調製したグラフトポリマーであり、このシリコーン−アクリレート複合ゴムは11重量%のシリコーンゴムと89重量%のポリアルキル(メタ)アクリレートを含み、この2つのゴム成分が複合ゴムに浸透し、お互いに実質的に分離不可能となっている
30重量%のメチルメタクリレートと70重量%のグラフトベースとしての乳化重合によって調製したブチルアクリレートゴムとの反応によって調製したグラフトポリマー
塊状重合によって調製した、重量平均分子量Mwが130kg/モル(GPCにより測定)の77重量%のスチレンと23重量%のアクリロニトリルのコポリマー
潤滑剤/離型剤としてのペンタエリトリトールテトラステアレート
熱安定剤Irganox(登録商標)B900(80%Irgafos(登録商標)168及び20%Irganox(登録商標)1076の混合物、BASF AG、Ludwigshafen/Irgafos(登録商標)168(トリス(2,4−ジ−tert−ブチル−フェニル)ホスファイト)/Irganox(登録商標)1076(2,6−ジ−tert−ブチル−4−(オクタデカノキシカルボニルエチル)フェノール)
ポリテトラフルオロエチレン粉体、CFP 6000 N、DuPont
フッ素化ポリオレフィンのエマルションとスチレン/アクリロニトリル(それぞれ50重量%)ベースのコポリマーのエマルションとの凝固した混合物(SabicからのCycolac INP449)
表1に挙げた物質を、速度225rpm及び処理量20kg/h、機械温度260℃、双軸スクリュー押出機(ZSK-25)(Werner und Pfleiderer)で配合し、造粒した。
Claims (13)
- 組成物であって、
A)60〜95重量部の、芳香族ポリカーボネート及び/又は芳香族ポリエステルカーボネート、
B)1.0〜15.0重量部のゴム変性したグラフト重合体と、シリコーンゴム、シリコーン−アクリレートゴムおよびアクリレートゴムからなる群から選択されるグラフトベース、
C)1.0〜20.0重量部の、少なくとも一種の式(X)の環状ホスファゼン
kが、1又は1〜10の整数、好ましくは1〜8、特に好ましくは1〜5の数を表し、
三量体含有量(k=1)が、成分Cに対して、60〜98mol%であり、
Rが、それぞれの場合に、同一であるか、又は異なるものであって、
アミン基;
所望によりハロゲン化されている、C 1 〜C 8 アルキル;
C 1 〜C 8 アルコキシ;
所望によりアルキル及び/又はハロゲンにより置換されている、C 5 〜C 6 シクロアルキル;
所望によりアルキル、ハロゲン及び/又はヒドロキシにより置換されている、C 6 〜C 20 アリールオキシ;
所望によりアルキル及び/又はハロゲンにより置換されている、C 7 〜C 12 アラルキル;又は
ハロゲン基又は
OH基を表す。)、
D)0〜15.0重量部の、ゴムを含まない、ビニル(共)重合体又はポリアルキレンテレフタレート、
E)0〜15.0重量部の添加剤、
F)0.05〜5.0重量部、好ましくは0.1〜2.0重量部、より好ましくは0.1〜1.0重量部の滴防止剤
を含んでなり、
成分Bが、
B.1 9〜30重量%の1種以上のビニルモノマーと
B.2 91〜70重量%の1種以上の、グラフトベースとしての、シリコーン−アクリレート複合ゴムと
の1種以上のグラフトポリマーを含み、グラフトベースの前記2種類のゴム成分が、複合ゴムに浸透することで、これらは実質的に互いに分離不可能であり、
全ての重量部が好ましくは、組成物中の全ての成分A+B+C+D+E+Fの重量部の合計が100になるように、正規化されている、組成物。 - 三量体(k=1)の含有量が、成分Cに対して、60〜98mol%、より好ましくは65〜95mol%、特に好ましくは65〜90mol%である、請求項1に記載の組成物。
- 成分Cの量が1.5〜10.0重量部である、請求項1又は2に記載の組成物。
- 成分Cが、プロポキシホスファゼン、フェノキシホスファゼン、メチルフェノキシホスファゼン、アミノホスファゼン及びフルオロアルキルホスファゼンを含んでなる群から選択される、請求項1〜3のいずれか一項に記載の組成物。
- Rがフェノキシである、請求項1〜4のいずれか一項に記載の組成物。
- 前記三量体(k=1)の含有量が、成分Cに対して、65〜85mol%である、請求項1に記載の組成物。
- それぞれの場合に成分Cに対して、前記三量体含有量(k=1)が、65〜85mol%、前記四量体含有量(k=2)が10〜20mol%であり、より高級のオリゴマー状ホスファゼン(k=3、4、5、6及び7)の含有量が5〜15mol%であり、k>=8のホスファゼンオリゴマーの含有量が0〜1mol%である、請求項1〜6のいずれか一項に記載の組成物。
- 成分Dが、3.0〜6.0重量部の量で存在する、請求項1〜7のいずれか一項に記載の組成物。
- 前記熱可塑性芳香族ポリカーボネートの平均分子量(重量平均)が、22,000〜30,000g/モルである、請求項1〜8のいずれか一項に記載の組成物。
- 成分Bにおける前記グラフトベースが、9〜40重量%のシリコーンゴムと91〜60重量%のポリアルキル(メタ)アクリレートゴムから形成されるシリコーン−アクリレートゴムを含み、前記2種類のゴム成分が、複合ゴムに浸透することで、これらは実質的に互いに分離不可能である、請求項1〜9のいずれか一項に記載の組成物。
- 成分Eとして、難燃性相乗剤、潤滑剤及び離型剤、核形成剤、安定剤、帯電防止剤、着色剤、顔料及び充填剤並びに補強材料を含んでなる群から選択された少なくとも一種の添加剤を含んでなる、請求項1〜10のいずれか一項に記載の組成物。
- 請求項1〜11のいずれか一項に記載の組成物の、射出成形又は熱成形された成形製品の製造における使用。
- 請求項1〜11のいずれか一項に記載の組成物から得られる成形製品。
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EP12196048 | 2012-12-07 | ||
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PCT/EP2013/075432 WO2014086800A1 (de) | 2012-12-07 | 2013-12-03 | Flammgeschützte polycarbonatformmassen vi |
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Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9637634B2 (en) | 2012-12-07 | 2017-05-02 | Covestro Deutschland Ag | Flame-retardant polycarbonate molding materials V |
CN107531988B (zh) * | 2015-04-30 | 2020-01-10 | 沙特基础工业全球技术有限公司 | 阻燃组合物、其制备方法及包含其的制品 |
WO2017065762A1 (en) | 2015-10-14 | 2017-04-20 | Covestro Llc | Phosphazene modified polycarbonate molded battery cooling device |
CN106025355A (zh) * | 2016-05-17 | 2016-10-12 | 山东海容电源材料有限公司 | 一种阻燃型高安全非水电解液及其加工方法 |
KR102029355B1 (ko) | 2016-12-14 | 2019-10-07 | 롯데첨단소재(주) | 전기적 특성이 우수한 열가소성 수지 조성물 및 이를 이용하여 제조된 성형품 |
KR102041596B1 (ko) * | 2016-12-21 | 2019-11-06 | 롯데첨단소재(주) | 전기적 특성이 우수한 열가소성 수지 조성물 및 이를 이용하여 제조된 성형품 |
EP3428210A1 (de) | 2017-07-11 | 2019-01-16 | Covestro Deutschland AG | Flammgeschützte pur/pir - hartschaumstoffe |
US10544285B2 (en) | 2017-10-12 | 2020-01-28 | International Business Machines Corporation | Impact resistant cyclic phosphazenes |
US11059960B2 (en) | 2017-10-16 | 2021-07-13 | International Business Machines Corporation | Cross-linked impact modified polyphosphazenes |
JP7252727B2 (ja) * | 2018-09-14 | 2023-04-05 | 出光興産株式会社 | ポリカーボネート系樹脂組成物 |
WO2020066535A1 (ja) | 2018-09-26 | 2020-04-02 | 帝人株式会社 | 難燃性ポリカーボネート樹脂組成物 |
JP2022510884A (ja) | 2018-11-29 | 2022-01-28 | コベストロ・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング・アンド・コー・カーゲー | ホスファゼン及びシリコーン/アクリレート耐衝撃性改質剤を含有するSiCoPCブレンド |
KR102206636B1 (ko) * | 2018-12-17 | 2021-01-22 | 한국과학기술연구원 | 수포작용제 제거를 위한 황(s)이 도핑된 금속 산화물 촉매 및 이의 제조 방법 |
CN109796739B (zh) * | 2018-12-28 | 2021-04-09 | 方万漂 | 一种弹性体聚酯材料及其制备方法 |
EP3828236B1 (de) * | 2019-11-27 | 2022-06-01 | Covestro Intellectual Property GmbH & Co. KG | Flammgeschützter polycarbonat-polyester blend |
EP4342948A1 (en) * | 2022-09-23 | 2024-03-27 | Trinseo Europe GmbH | Flame retardant polycarbonate formulations |
Family Cites Families (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2393967A (en) | 1942-12-24 | 1946-02-05 | Du Pont | Process for polymerizing tetrafluoroethylene |
US2891920A (en) | 1955-01-26 | 1959-06-23 | Dow Corning | Polymerization of organopolysiloxanes in aqueous emulsion |
DE1495626B1 (de) | 1960-03-30 | 1971-06-09 | Bayer Ag | Verfahren zum herstellen von polyestern |
US3355414A (en) | 1961-09-14 | 1967-11-28 | Eastman Kodak Co | Thermosetting polyesters |
GB1024024A (en) | 1963-04-08 | 1966-03-30 | Dow Corning | Improvements in or relating to polymerising or co-polymerising organosilicon compounds |
US3419634A (en) | 1966-01-03 | 1968-12-31 | Gen Electric | Organopolysiloxane polycarbonate block copolymers |
FR1580834A (ja) | 1968-01-04 | 1969-09-12 | ||
US3838092A (en) | 1971-04-21 | 1974-09-24 | Kewanee Oil Co | Dustless compositions containing fiberous polytetrafluoroethylene |
US3671487A (en) | 1971-05-05 | 1972-06-20 | Gen Electric | Glass reinforced polyester resins containing polytetrafluoroethylene and flame retardant additives |
US3723373A (en) | 1971-10-04 | 1973-03-27 | American Cyanamid Co | 0.1% to about 2.0% by weight polytetrafluoroethylene emulsion modified polyethylene terephthalate with improved processing characteristics |
DE2232877B2 (de) | 1972-07-05 | 1980-04-10 | Werner & Pfleiderer, 7000 Stuttgart | Verfahren zur Herstellung von Polyestern |
JPS5039599B2 (ja) | 1973-03-30 | 1975-12-18 | ||
US3898300A (en) | 1974-01-31 | 1975-08-05 | Dow Corning | Emulsion polymerization method to produce a polymeric styrene-acrylonitrile-polyorganosiloxane composition and product |
DE2407776A1 (de) | 1974-02-19 | 1975-09-04 | Licentia Gmbh | Schaltung zur regelung der betriebsspannung fuer die transistor-zeilenendstufe eines fernsehempfaengers |
GB1511230A (en) | 1974-05-13 | 1978-05-17 | British Broadcasting Corp | Colour television |
JPS5292295A (en) | 1976-01-29 | 1977-08-03 | Sumitomo Chem Co Ltd | Preparation of aromatic polyester |
IT1116721B (it) | 1976-04-02 | 1986-02-10 | Allied Chem | Copolimero bisfenolo a tereftalato carbonato lavorabili in massa fusa |
DE2715932A1 (de) | 1977-04-09 | 1978-10-19 | Bayer Ag | Schnellkristallisierende poly(aethylen/alkylen)-terephthalate |
DE2842005A1 (de) | 1978-09-27 | 1980-04-10 | Bayer Ag | Polycarbonate mit alkylphenyl-endgruppen, ihre herstellung und ihre verwendung |
JPS5594930A (en) | 1979-01-10 | 1980-07-18 | Sumitomo Chem Co Ltd | Preparation of aromatic polyester by improved bulk polymerization process |
DE2940024A1 (de) | 1979-10-03 | 1981-04-16 | Bayer Ag, 5090 Leverkusen | Aromatische polyester, verfahren zu ihrer herstellung und ihre verwendung zur herstellung von spritzgussartikeln, folien und ueberzuegen |
DE3007934A1 (de) | 1980-03-01 | 1981-09-17 | Bayer Ag, 5090 Leverkusen | Aromatische polyestercarbonate, verfahren zu ihrer herstellung und ihre verwendung zur herstellung von spritzgussartikeln, folien und ueberzuegen |
DE3334782A1 (de) | 1983-04-19 | 1984-10-25 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von polydiorganosiloxanen mit hydroxyaryloxy-endgruppen |
DE3615608A1 (de) | 1986-05-09 | 1987-11-12 | Basf Ag | Thermoplastische formmasse auf basis von polycarbonat, 2 pfropfmischpolymerisaten unterschiedlicher pfropfgrundlage (asa + aes) und vinylaromat/an enthaltenden copolymerisaten |
CA1302602C (en) | 1986-06-17 | 1992-06-02 | Masafumi Hongo | Polycarbonate resin composition |
DE3631540A1 (de) | 1986-09-17 | 1988-03-24 | Bayer Ag | Thermoplastische formmassen mit hoher alterungsbestaendigkeit und guter tieftemperaturzaehigkeit |
EP0307963B1 (en) | 1987-09-21 | 1995-02-15 | Mitsubishi Rayon Co., Ltd. | Polycarbonate resin composition |
DE3832396A1 (de) | 1988-08-12 | 1990-02-15 | Bayer Ag | Dihydroxydiphenylcycloalkane, ihre herstellung und ihre verwendung zur herstellung von hochmolekularen polycarbonaten |
DE69027976T2 (de) | 1989-11-27 | 1997-03-06 | Mitsubishi Rayon Co | Hochschlagfeste Pfropfkopolymere und Harzzusammensetzungen |
JPH04345657A (ja) * | 1991-05-23 | 1992-12-01 | Mitsubishi Kasei Corp | 難燃性ポリカーボネート樹脂組成物 |
EP0728811B1 (en) | 1995-02-27 | 2003-09-17 | Mitsubishi Chemical Corporation | Flame retardant thermoplastic resin composition |
US5807914A (en) | 1995-07-05 | 1998-09-15 | Mitsubishi Engineering-Plastics Corporation | Glass fiber-reinforced polycarbonate resin composition |
DE19615230A1 (de) | 1996-04-18 | 1997-10-23 | Basf Ag | Flammgeschützte thermoplastische Formmassen |
JPH11349796A (ja) * | 1998-06-12 | 1999-12-21 | Idemitsu Petrochem Co Ltd | ポリカーボネート樹脂組成物 |
DE19828539A1 (de) * | 1998-06-26 | 1999-12-30 | Bayer Ag | Flammwidrige Formmassen enthaltend Polycarbonat und Pfropfpolymerisate |
DE19828535A1 (de) | 1998-06-26 | 1999-12-30 | Bayer Ag | Flammwidrige Polycarbonat-ABS-Formmassen |
DE19828536A1 (de) | 1998-06-26 | 1999-12-30 | Bayer Ag | Flammwidrige Polycarbonat/ABS-Formmassen |
DE19828541A1 (de) | 1998-06-26 | 1999-12-30 | Bayer Ag | Flammwidrige Polycarbonat-ABS-Formmassen |
JP2000351893A (ja) * | 1999-06-14 | 2000-12-19 | Otsuka Chem Co Ltd | 難燃性ポリカーボネート樹脂組成物 |
JP2001226575A (ja) * | 2000-02-17 | 2001-08-21 | Otsuka Chem Co Ltd | 難燃性ポリカーボネート樹脂組成物 |
JP3389553B2 (ja) * | 2000-05-01 | 2003-03-24 | 大塚化学株式会社 | フェノキシホスファゼン系化合物の改質方法、難燃性樹脂組成物及び難燃性樹脂成形体 |
JP4570205B2 (ja) * | 2000-06-05 | 2010-10-27 | 三菱エンジニアリングプラスチックス株式会社 | 難燃性ポリカーボネート樹脂組成物 |
JP2002302597A (ja) * | 2001-04-04 | 2002-10-18 | Teijin Chem Ltd | 難燃性ポリカーボネート樹脂組成物およびそれからなる成形品 |
KR100634927B1 (ko) * | 2002-09-13 | 2006-10-18 | 아사히 가세이 케미칼즈 가부시키가이샤 | 포스파젠 조성물 |
DE102005058836A1 (de) * | 2005-12-09 | 2007-06-14 | Bayer Materialscience Ag | Polycarbonat-Formmassen |
DE102008028571A1 (de) * | 2008-06-16 | 2009-12-17 | Bayer Materialscience Ag | Schlagzähmodifizierte Polycarbonat-Zusammensetzungen |
DE102008062945A1 (de) | 2008-12-23 | 2010-06-24 | Bayer Materialscience Ag | Flammgeschützte schlagzähmodifizierte Polycarbonat-Zusammensetzungen |
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BR112015012955A2 (pt) | 2017-07-11 |
TW201439197A (zh) | 2014-10-16 |
KR20150093753A (ko) | 2015-08-18 |
ES2667328T3 (es) | 2018-05-10 |
CN104812825A (zh) | 2015-07-29 |
JP2015537096A (ja) | 2015-12-24 |
CA2893891A1 (en) | 2014-06-12 |
WO2014086800A1 (de) | 2014-06-12 |
EP2928953A1 (de) | 2015-10-14 |
EP2928953B1 (de) | 2018-01-31 |
MX2015006982A (es) | 2016-01-08 |
TWI638852B (zh) | 2018-10-21 |
CN104812825B (zh) | 2020-01-17 |
US20150307707A1 (en) | 2015-10-29 |
KR102136909B1 (ko) | 2020-07-22 |
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