JP6059026B2 - 射出成型用加飾シート、射出成型用シート積層体及び射出成型品 - Google Patents
射出成型用加飾シート、射出成型用シート積層体及び射出成型品 Download PDFInfo
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- JP6059026B2 JP6059026B2 JP2013008497A JP2013008497A JP6059026B2 JP 6059026 B2 JP6059026 B2 JP 6059026B2 JP 2013008497 A JP2013008497 A JP 2013008497A JP 2013008497 A JP2013008497 A JP 2013008497A JP 6059026 B2 JP6059026 B2 JP 6059026B2
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- injection molding
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- SEEYREPSKCQBBF-UHFFFAOYSA-N n-methylmaleimide Chemical compound CN1C(=O)C=CC1=O SEEYREPSKCQBBF-UHFFFAOYSA-N 0.000 description 1
- YPHQUSNPXDGUHL-UHFFFAOYSA-N n-methylprop-2-enamide Chemical compound CNC(=O)C=C YPHQUSNPXDGUHL-UHFFFAOYSA-N 0.000 description 1
- JFOJYGMDZRCSPA-UHFFFAOYSA-J octadecanoate;tin(4+) Chemical compound [Sn+4].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O JFOJYGMDZRCSPA-UHFFFAOYSA-J 0.000 description 1
- KZCOBXFFBQJQHH-UHFFFAOYSA-N octane-1-thiol Chemical compound CCCCCCCCS KZCOBXFFBQJQHH-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- MMSLOZQEMPDGPI-UHFFFAOYSA-N p-Mentha-1,3,5,8-tetraene Chemical compound CC(=C)C1=CC=C(C)C=C1 MMSLOZQEMPDGPI-UHFFFAOYSA-N 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000001007 phthalocyanine dye Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000011116 polymethylpentene Substances 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 239000006234 thermal black Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
- B29C48/18—Articles comprising two or more components, e.g. co-extruded layers the components being layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0053—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor combined with a final operation, e.g. shaping
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C63/00—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
- B29C63/02—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
- B32B37/153—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0053—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor combined with a final operation, e.g. shaping
- B29C2045/0079—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor combined with a final operation, e.g. shaping applying a coating or covering
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
- B29K2033/04—Polymers of esters
- B29K2033/12—Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/722—Decorative or ornamental articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/402—Coloured
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2333/00—Polymers of unsaturated acids or derivatives thereof
- B32B2333/04—Polymers of esters
- B32B2333/12—Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
射出成型により成型される樹脂成型品の外面に付設される樹脂製の射出成型用加飾シートであって、
樹脂成型品に接着される内層と、この内層の外面側に積層された外層とが、押出し成型法により一体的に積層された多層構造を有し、
上記内層又は外層が、黒色系色料を含有することを特徴とする。
α1*(Tg1−室温)・・・(1)
α2*(Tg2−室温)・・・(2)
これにより、内層及び外層を共押出し成形した場合の内部応力を低減して上記室温でのカールの発生を好適に防止することができる。
<射出成型用加飾シート>
図1の射出成型用加飾シート1は、内層2と外層3とを有している。射出成型用加飾シート1は、射出成型により成型される樹脂成型品の外面に付設される。射出成型用加飾シート1において、内層2と外層3とは直接積層されている。射出成型用加飾シート1は、内層2と外層3との二層構造体として形成されている。
内層2は、樹脂成型品に接着される。内層2は、合成樹脂を主成分として形成されている。内層2の主成分としては、特に限定されないが、ABS系樹脂、ポリオレフィン系樹脂、スチレン系樹脂、アクリル系樹脂、塩化ビニル系樹脂、ポリカーボネート系樹脂等の熱可塑性樹脂が挙げられる。なかでも、内層2の主成分としては、樹脂成型品の主成分と同種の樹脂であることが好ましい。当該射出成型用加飾シート1は、内層2の主成分が樹脂成型品の主成分と同種の樹脂であることによって、樹脂成型品と内層2との接着性を向上することができる。従って、当該射出成型用加飾シート1は、かかる構成によれば、樹脂成型品の外面に好適に付着することができる。
外層3は、内層2の外面に積層される。外層3は、合成樹脂を主成分として形成されている。外層3の主成分としては、特に限定されないが、アクリル系樹脂が好ましい。当該射出成型用加飾シート1は、外層3の主成分としてアクリル系樹脂を用いることによって、耐候性及び耐汚染性を向上することができる。
D1238;I条件)としては、得られる射出成型用加飾シート1の強度の観点から15g/10分以下が好ましく、12g/10分以下がより好ましく、10g/10分以下がさらに好ましい。
α1*(Tg1−室温)・・・(1)
α2*(Tg2−室温)・・・(2)
射出成型用加飾シート1は押出し成形法によって内層2及び外層3が一体的に積層される。射出成型用加飾シート1は、例えば一対の押出機を有する共押出機(図示せず)を用いて製造される。具体的には、まず、内層2の形成材料が一方の押出機に投入され、外層3の形成材料が他方の押出機に投入される。次に、内層2の形成材料及び外層3の形成材料は、分配ブロックに供給され、所望の厚みになるように分配される。そして、内層2の形成材料及び外層3の形成材料は、所望の厚みに分配された後、マルチマニホールドダイ内で積層され、マルチマニホールドダイの先端からフィルム状に押出しされる。なお、一対の押出機及びマルチマニホールドダイの温度設定は、使用される樹脂の融点等を考慮して適宜選択される。
当該射出成型用加飾シート1は、内層2と外層3とが押出し成型法により一体的に積層されるので、従来のようにシート同士を接着剤で貼着するものに比べて、内層2と外層3との間に異物が混入するおそれが少ない。また、当該射出成型用加飾シート1は、内層2又は外層3に黒色系色料を含有させるため、従来のように印刷面により意匠性を持たせるものに比べて、内層2又は外層3が含有する黒色系色料によって十分な黒色を呈することができる。
<射出成型用加飾シート>
図2の射出成型用加飾シート11は、内層12と、外層3と、ハードコート層13とを有している。射出成型用加飾シート11は、射出成型により成型される樹脂成型品の外面に付設される。射出成型用加飾シート1において、内層12と外層3とは直接積層されている。また、外層3については、図1の射出成型用加飾シート1と同様のため、同一番号を付して説明を省略する。
内層12は、樹脂成型品に接着される。内層12は、合成樹脂を主成分として形成されている。内層12の主成分及び平均厚みとしては図1の内層2と同様である。内層12は、黒色系色料を含有しない透明層として形成されている。
ハードコート層13の形成材料としては、特に限定されるものではないが、トリアジン環含有(メタ)アクリレートプレポリマーと有機微粒子とを含む組成物が好適に用いられる。このトリアジン環含有(メタ)アクリレートプレポリマーとしては、アミノトリアジン化合物、パラホルムアルデヒド及び水酸基含有(メタ)アクリレートから1工程で合成されるものが挙げられる。また、上記有機微粒子としては、乳化重合法によって合成される微粒子が挙げられる。上記トリアジン環含有(メタ)アクリレートプレポリマーの平均分子量としては、特に限定されないが、200以上20000以下が好ましい。上記平均分子量が上記上限を超える場合、粘度が高くなり塗工が困難になるおそれが高くなる。逆に、上記平均分子量が上記下限未満である場合、十分な硬度が得られないおそれが高くなる。
射出成型用加飾シート11の製造方法としては、一般的には(a)内層12及び外層3からなる積層体を形成する工程と、(b)この積層体の外層3の外面にハードコート層13を形成する工程とを有している。上記(a)としては、図1の射出成型用加飾シート1と同様の製造方法が挙げられる。また、上記(b)としては、ハードコート層13の形成材料を外層3の外面に塗布し、乾燥、硬化させる方法が挙げられる。
当該射出成型用加飾シート11は、外層3の外面に積層されるハードコート層13をさらに備えているので、例えば当該射出成型用加飾シート11が樹脂成型品の外面に付設された後等において、上記外層3の外面が傷付くことをハードコート層13によって的確に防止することができる。
<射出成型用シート積層体>
図3の射出成型用シート積層体21は、射出成型用加飾シート1と離型シート22とを有している。射出成型用加飾シート1は、内層2と、外層3とを有している。内層2及び外層3については、図1の射出成型用加飾シート1と同様のため同一番号を付して説明を省略する。
離型シート22は、射出成型用加飾シート1の外層3の外面に剥離可能に積層されている。離型シート22は、基材フィルムを有している。この基材フィルムは、耐熱性、製造に耐える機械的強度、耐溶剤性等を有する種々の材料によって形成される。上記基材フィルムを形成する主成分としては、例えばポリエチレンテレフタレート、ポリエチレンナフタレート等のポリエステル系樹脂、ポリエチレン、ポリプロピレン、ポリメチルペンテン等のポリオレフィン系樹脂、ナイロン6等のポリアミド系樹脂、ポリ塩化ビニル等のビニル系樹脂、ポリメチルメタクリレート等のアクリル系樹脂、ポリカーボネート、セロファン、セルロースアセテート等のセルロース系樹脂等の合成樹脂が挙げられる。なかでも、耐熱性、機械的強度の点でポリエステル系樹脂が好ましく、ポリエチレンテレフタレートが特に好ましい。
当該射出成型用シート積層体21は、当該射出成型用加飾シート1と、この射出成型用加飾シート1の外層3の外面に剥離可能に積層される離型シート22とを備えているので、離型シート22が成形型の型面と対面するよう配設し、この成形型に溶融樹脂を射出し、樹脂の硬化後に離型シート22を剥離することで、外面に当該射出成型用加飾シート1が付設された射出成型品を得ることができ、この射出成型品は、当該射出成型用加飾シート1の内部に異物混入のおそれが少なく、十分な黒色を呈することができる。
<射出成型品>
図4の射出成型品31は、射出成型用加飾シート1と、樹脂成型品32とを有している。射出成型品31は、射出成型用加飾シート1が樹脂成型品32の外面に付設されている。
樹脂成型品32の形成材料としては、特に限定されるものではなく、ポリオレフィン系樹脂、ポリカーボネート系樹脂、ABS樹脂、ウレタン系樹脂、ポリエステル系樹脂、ポリスチレン系樹脂、塩化ビニル系樹脂、ポリアミド系樹脂等が挙げられる。
射出成型用加飾シート1を樹脂成型品32に付設する方法としては、インサート成形やインモールド成形等が好ましい。上記射出成型用加飾シート1を樹脂成型品32に付設する方法としては、例えば(a)射出成型用加飾シート1を射出成形金型内に配設する工程と、(b)真空成型を施して金型内面に射出成型用加飾シート1を密着させる工程と、(c)この金型内に樹脂成型品32の形成材料を射出成型する工程とを有している。
当該射出成型品31は、当該射出成型用加飾シート1が外面に付設されているので、当該射出成型用加飾シート1の内部に異物混入のおそれが少なく、十分な黒色を呈することができる。
なお、本発明の射出成型用加飾シート、射出成型用シート積層体及び射出成型品は、上記態様の他、種々の変更、改良を施した態様で実施することができる。また、本発明に係る上記各実施形態の構成は、適宜組み合わせて実施することが可能である。
2 内層
3 外層
11 射出成型用加飾シート
12 内層
13 ハードコート層
21 射出成型用シート積層体
22 離型シート
31 射出成型品
32 樹脂成型品
Claims (11)
- 射出成型により成型される樹脂成型品の外面に付設される樹脂製の射出成型用加飾シートであって、
樹脂成型品に接着される内層と、この内層の外面側に積層された外層とが、押出し成型法により一体的に積層された多層構造を有し、
上記内層がカーボンブラックを含有し、かつ上記外層がカーボンブラック及び黒色系染料を含有することを特徴とする射出成型用加飾シート。 - 上記内層及び外層が直接積層された二層構造を有する請求項1に記載の射出成型用加飾シート。
- 上記外層の外面に積層されるハードコート層をさらに備える請求項1又は請求項2に記載の射出成型用加飾シート。
- 外面の算術平均粗さ(Ra)が、0.01μm以上0.3μm以下である請求項1、請求項2又は請求項3に記載の射出成型用加飾シート。
- 外面の60°光沢度が、70以上90以下である請求項1から請求項4のいずれか1項に記載の射出成型用加飾シート。
- 上記外層の主成分がアクリル系樹脂である請求項1から請求項5のいずれか1項に記載の射出成型用加飾シート。
- 引張強さが20MPa以上である請求項6に記載の射出成型用加飾シート。
- 上記内層の主成分が上記樹脂成型品の主成分と同種の樹脂である請求項1から請求項7のいずれか1項に記載の射出成型用加飾シート。
- 上記内層の線膨張係数(α1)及びガラス転移温度(Tg1)と、上記外層の線膨張係数(α2)及びガラス転移温度(Tg2)と、室温との関係として、下記式(1)及び(2)の値の差が4×10−3以下である請求項1から請求項8のいずれか1項に記載の射出成型用加飾シート。
α1*(Tg1−室温)・・・(1)
α2*(Tg2−室温)・・・(2) - 請求項1から請求項9のいずれか1項に記載の射出成型用加飾シートと、
この射出成型用加飾シートの外層の外面側に剥離可能に積層される離型シートと
を備える射出成型用シート積層体。 - 請求項1から請求項10のいずれか1項に記載の射出成型用加飾シートが外面に付設された射出成型品。
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