JP5963848B2 - 非触媒性の復熱式改質装置 - Google Patents
非触媒性の復熱式改質装置 Download PDFInfo
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Description
本発明は、米国エネルギー省によって与えられた許可番号DE−FG36−08GO18130の下で生み出され、米国政府は、その許可に準ずる本発明中の特定の権利を有してもよい。
とりわけ工業用途における多くのプロセスは、大量の余剰な熱−すなわち、プロセスで効率的に使用することができる以上の熱−を発生させる。廃熱回収方法は、さもなければ浪費される余分な熱からある程度のエネルギーの抽出し利用することを試みている。工業用途における熱を回収する典型的な方法は、プロセスそれ自体、復熱装置、熱交換器、および廃熱ボイラーへの直接的な熱回収を含んでいる。
Claims (17)
- (i)燃焼排ガス流路の第1の部分、および、(ii)燃焼排ガス流路の第1の部分内に少なくとも部分的に埋め込まれた改質用混合物流路の第1の部分であって、燃焼排ガス流路内の燃焼排ガスと、改質用混合物流路内の改質用混合物との間の伝熱を可能にする第1の部分、を含む予熱器部分、および、
(i)燃焼排ガス流路の第2の部分、および、(ii)燃焼排ガス流路の第2の部分内に少なくとも部分的に埋め込まれた改質用混合物流路の第2の部分であって、燃焼排ガス流路内の燃焼排ガスと、改質用混合物流路内の改質用混合物との間の伝熱を可能にする第2の部分、を含む反応器部分、
を含む復熱式改質装置であって、
燃焼排ガス流路は熱プロセスから熱い燃焼排ガスを受け取るように構成され、
改質用混合物流路の第1の部分は、体積流量を有するガス状の改質用混合物を受け取るように構成され、および、改質用混合物流路の第2の部分は、改質用混合物流路の第1の部分から改質用混合物を受け取るように構成され、
改質用混合物流路は触媒を含まず、
改質用混合物流路の第2の部分の少なくとも一部は、金属材料の拡大面を包含しており、および、
改質用混合物流路の第2の部分は、体積流量を有する改質用混合物のあらかじめ定義された閾値よりも大きな、または、該閾値と等しい滞留時間を提供するように構成される、ことを特徴とする復熱式改質装置。 - あらかじめ決められた閾値は、1秒乃至2分の範囲である、ことを特徴とする請求項1に記載の復熱式改質装置。
- 改質用混合物流路の第2の部分の体積は、改質用混合物流路の第1の部分の体積よりも大きい、ことを特徴とする請求項2に記載の復熱式改質装置。
- 改質用混合物流路の第2の部分における拡大した金属表面の表面積は、燃焼排ガスと改質用混合物の効率的な伝熱に必要とされる表面積よりも大きい、ことを特徴とする請求項2に記載の復熱式改質装置。
- 改質用混合物流路は、パラジウム、レニウム、または、酸化ニッケルをまったく含まない、ことを特徴とする請求項2に記載の復熱式改質装置。
- 改質用混合物流路の第1の部分は、(i)燃焼排ガス流路の第1の部分の一方の側に第1の部分を、燃焼排ガス流路の第1の部分の反対側に第2の部分を有する予熱器のプレナム、(ii)予熱器のプレナムの第1の部分と予熱器のプレナムの第2の部分とを接続する複数の導管、および、(iii)改質用混合物流路の第1の部分の導管へと改質用混合物をガイドするための、予熱器のプレナムの第1の部分と第2の部分内の1以上のバッフルを含み、
改質用混合物流路の第2の部分は、(i)燃焼排ガス流路の第2の部分の一方の側に第1の部分と、燃焼排ガス流路の第2の部分の反対側に第2の部分を有する反応器のプレナム、(ii)反応器のプレナムの第1の部分と反応器のプレナムの第2の部分とを接続する複数の導管、および、(iii)改質用混合物流路の第2の部分の導管へと改質用混合物をガイドするための、反応器のプレナムの第1の部分と第2の部分内の1以上のバッフルを含む、ことを特徴とする請求項5に記載の復熱式改質装置。 - 反応器のプレナムの第1の部分と第2の部分を接続する導管はパイプである、ことを特徴とする請求項6に記載の復熱式改質装置。
- 反応器のプレナムの第1の部分と第2の部分を接続する導管は、プレート形状の流路である、ことを特徴とする請求項6に記載の復熱式改質装置。
- 燃焼排ガス流路は、熱い燃焼排ガスが燃焼排ガス流路の第2の部分を通り、その後、燃焼排ガス流路の第1の部分を通るように、構成される、ことを特徴とする請求項6に記載の復熱式改質装置。
- 改質用混合物流路の第1の部分の体積は、改質用混合物流路の第2の部分の体積よりも小さい、ことを特徴とする請求項2に記載の復熱式改質装置。
- 改質用混合物流路の第2の部分の少なくとも一部に含まれる金属材料の拡大面は、80重量%よりも大きなニッケル含量を有するステンレススチールまたは合金からできている、ことを特徴とする請求項2に記載の復熱式改質装置。
- 改質用混合物流路の第2の部分の体積は、3600hr−1の最大空間速度を提供する、ことを特徴とする請求項1に記載の復熱式改質装置。
- 炭化水素燃料を高発熱燃料へと改質する方法であって、
前記方法は、
熱プロセスからの熱い燃焼排ガスを改質装置の燃焼排ガス流路に導入する工程、
体積流量を有する改質用混合物を改質装置の改質用混合物流路に導入する工程であって、改質用混合物流路の少なくとも一部は、燃焼排ガス流路の燃焼排ガスから、改質用混合物流路の改質用混合物への伝熱を可能にするために、燃焼排ガス流路内に埋め込まれ、および、改質用混合物流路は実質的に触媒を含まず、改質用混合物流路は、体積流量を有する改質用混合物のあらかじめ定義された閾値よりも大きなまたは該閾値と等しい滞留時間を提供するように構成される、工程、および、
改質用混合物流路の出口から、改質された燃料を出力する工程を含む、ことを特徴とする方法。 - 改質用混合物は、少なくともその一部の中に金属材料の拡大面を含む改質用混合物流路へと導入される、ことを特徴とする請求項13に記載の方法。
- あらかじめ定められた閾値は、1秒乃至2分の範囲である、ことを特徴とする請求項13に記載の方法。
- 改質用混合物は、少なくともその一部の中に金属パイプを含む改質用混合物流路へと導入される、ことを特徴とする請求項13に記載の方法。
- 改質用混合物は、少なくともその一部のためのプレート形状の金属流路を含む改質用混合物流路へと導入される、ことを特徴とする請求項13に記載の方法。
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US13/086,433 | 2011-04-14 | ||
US13/086,433 US9216396B2 (en) | 2011-04-14 | 2011-04-14 | Non-catalytic recuperative reformer |
PCT/US2012/033212 WO2012142216A1 (en) | 2011-04-14 | 2012-04-12 | Non-catalytic recuperative reformer |
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JP2014517799A JP2014517799A (ja) | 2014-07-24 |
JP2014517799A5 JP2014517799A5 (ja) | 2015-05-21 |
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US (1) | US9216396B2 (ja) |
EP (1) | EP2697856A4 (ja) |
JP (1) | JP5963848B2 (ja) |
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WO (1) | WO2012142216A1 (ja) |
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US20100081103A1 (en) * | 2008-09-26 | 2010-04-01 | Hisashi Kobayashi | Furnace with multiple heat recovery systems |
US9803153B2 (en) | 2011-04-14 | 2017-10-31 | Gas Technology Institute | Radiant non-catalytic recuperative reformer |
JP6178979B2 (ja) * | 2013-06-28 | 2017-08-16 | パナソニックIpマネジメント株式会社 | 燃料処理装置 |
JP2017113746A (ja) * | 2015-12-21 | 2017-06-29 | ガス テクノロジー インスティテュート | 放射状の非触媒性の回収改質装置 |
US10337465B2 (en) * | 2016-12-23 | 2019-07-02 | Automotive Research & Testing Center | Device for producing hydrogen by reforming reaction and waste heat |
US10822233B2 (en) | 2018-05-11 | 2020-11-03 | Doosan Fuel Cell America, Inc. | Reformer including catalyst in an inlet plenum |
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NL8602404A (nl) * | 1986-09-23 | 1988-04-18 | Veg Gasinstituut Nv | Werkwijze voor het uitvoeren van een gasverbrandingsproces, onder terugwinning van een gedeelte van in de verbrandingsgassen aanwezige warmte. |
US5595059A (en) | 1995-03-02 | 1997-01-21 | Westingthouse Electric Corporation | Combined cycle power plant with thermochemical recuperation and flue gas recirculation |
JP4451128B2 (ja) * | 2003-12-09 | 2010-04-14 | 新日鐵化学株式会社 | マイクロリアクター |
US7293533B2 (en) | 2005-08-08 | 2007-11-13 | Utilization Technology Development, Nfp | Recuperative reforming reactor |
US7207323B1 (en) | 2006-01-06 | 2007-04-24 | Utilization Technology Development, Nfp | Catalytic core reactor for thermochemical heat recovery |
NZ573217A (en) * | 2006-05-05 | 2011-11-25 | Plascoenergy Ip Holdings S L Bilbao Schaffhausen Branch | A facility for conversion of carbonaceous feedstock into a reformulated syngas containing CO and H2 |
JP4179337B2 (ja) | 2006-05-17 | 2008-11-12 | 日新イオン機器株式会社 | イオン源およびその運転方法 |
US7798220B2 (en) * | 2007-04-20 | 2010-09-21 | Shell Oil Company | In situ heat treatment of a tar sands formation after drive process treatment |
US20090011290A1 (en) * | 2007-07-05 | 2009-01-08 | Gas Technology Institute | Method and apparatus for thermochemical recuperation with partial heat recovery of the sensible heat present in products of combustion |
US8323363B2 (en) * | 2007-08-30 | 2012-12-04 | Innovative Energy Solution | Reformation of hydrogen-containing fluids in a cyclic flow reactor |
US20090071155A1 (en) * | 2007-09-14 | 2009-03-19 | General Electric Company | Method and system for thermochemical heat energy storage and recovery |
JP5453760B2 (ja) * | 2008-10-22 | 2014-03-26 | Jfeスチール株式会社 | 冶金炉発生排ガスの改質・増熱方法およびその装置 |
JP4837064B2 (ja) * | 2009-03-31 | 2011-12-14 | 株式会社東芝 | ガスタービンシステム |
JP2011057869A (ja) * | 2009-09-10 | 2011-03-24 | Babcock Hitachi Kk | 改質炉 |
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EP2697856A1 (en) | 2014-02-19 |
WO2012142216A1 (en) | 2012-10-18 |
US9216396B2 (en) | 2015-12-22 |
EP2697856A4 (en) | 2014-11-05 |
JP2014517799A (ja) | 2014-07-24 |
KR20140043729A (ko) | 2014-04-10 |
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