JP5894508B2 - フッ素化構造化有機フィルム組成物 - Google Patents
フッ素化構造化有機フィルム組成物 Download PDFInfo
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- JP5894508B2 JP5894508B2 JP2012135173A JP2012135173A JP5894508B2 JP 5894508 B2 JP5894508 B2 JP 5894508B2 JP 2012135173 A JP2012135173 A JP 2012135173A JP 2012135173 A JP2012135173 A JP 2012135173A JP 5894508 B2 JP5894508 B2 JP 5894508B2
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/002—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds
- C08G65/005—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens
- C08G65/007—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens containing fluorine
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/18—Monomers containing fluorine
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24777—Edge feature
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
Description
<1>少なくとも第1のセグメントタイプを含む複数のセグメントおよび複数のリンカーを含むフッ素化構造化有機フィルム(SOF)であって、このリンカーが少なくとも、共有結合性有機骨格(COF)として整列された第1のリンカータイプを含み、ここで少なくとも第1のセグメントタイプがフッ素を含有する、フィルム。
<2>前記複数のセグメントがさらに、前記第1のセグメントタイプとは構造が異なる、フッ素を含有する第2のセグメントタイプを含む、<1>に記載のSOF。
<3>前記SOFのセグメントの約30重量%〜約70重量%がフッ素化されている、<1>に記載のSOF。
<4>前記SOFのフッ素含有量が、前記SOFの約5重量%〜約65重量%である、<1>に記載のSOF。
<5>前記SOFが実質的にピンホールのないフィルムである、<1>に記載のSOF。
<6>前記SOFがコンポジットSOFである、<1>に記載のSOF。
<7>前記SOFが電気活性の追加機能を有する、<1>に記載のSOF。
<8>前記第1のセグメントタイプが、2,2,3,3,4,4,5,5−オクタフルオロ−1,6−ヘキサンジオール、2,2,3,3,4,4,5,5,6,6,7,7−ドデカンフルオロ−1,8−オクタンジオール、2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9−ペルフルオロデカン−1,10−ジオール、(2,3,5,6−テトラフルオロ−4−ヒドロキシメチル−フェニル)−メタノール、2,2,3,3−テトラフルオロ−1,4−ブタンジオール、2,2,3,3,4,4−ヘキサフルオロ−1,5−ペンタンジオール、2,2,3,3,4,4,5,5,6,6,7,7,8,8−テトラデカフルオロ−1,9−ノナンジオールからなる群から選択される、<1>に記載のSOF。
<9>前記SOFが欠陥のないSOFである、<1>に記載のSOF。
<10>前記SOFの表面での水接触角が少なくとも80°である、<1>に記載のSOF。
用語「SOF」は、一般的に、巨視的な見方だとフィルムである、共有結合性有機骨格(COF)を指す。語句「巨視的な見方」は、このSOFの肉眼での見え方を指す。
フッ素含有セグメントのパーセントは、約10重量%超過、例えば約30重量%超過、または50重量%超過であってもよい;フッ素含有セグメントの上限は、100重量%または約70重量%未満であってもよい。
高度に撥油性は、炭化水素系液滴が表面に関して高い接触角、例えば約130°、または約135°〜約170°の接触角を形成する場合と記載される。超撥油性は、炭化水素系液滴が表面に関して高い接触角、例えば約150°を超える接触角を形成する場合と記載される。
構造化された有機フィルムを調製するプロセスは、
(a)それぞれがセグメント(少なくとも1つのセグメントがフッ素を含み得る)と多くの官能基とを含む複数の分子ビルディングブロックおよびプレSOFを含む、液体を含有する反応混合物を調製することと;
(b)この反応混合物を濡れたフィルムとして堆積させることと;
(c)分子ビルディングブロックを含む湿潤フィルムの、複数のセグメントと、共有結合性有機骨格として整列した複数のリンカーとを含むSOFを含む乾燥したフィルムへの変化を促進し、この共有結合性有機骨格が、巨視的な見方だとフィルムであることと;
(d)場合により、基材からSOFを取り外し、自立型SOFを得ることと;
(e)場合により、この自立型SOFをロールへと加工することと;
(f)場合により、このSOFを切断し、ベルトになるように縫い合わせることと;
(g)場合により、SOF(上述のSOF形成プロセスによって調製された)を基材として用い、次のSOF形成プロセスで上述のSOF形成プロセスを行うことと;を含む。
(LW)、(+)、(−)は、SFEインデックスの分散性、酸および塩基成分であり;
jは液体1、2、3を指し;
θjは、基材上のj番目の液体の接触角であり;
γjは、液体jの表面張力であり;および
下付き文字sは固体を指す。
Claims (16)
- 複数のセグメントおよび複数のリンカーを含むフッ素化構造化有機フィルム(SOF)であって、
複数のセグメントは、
2,2,3,3,4,4,5,5−オクタフルオロ−1,6−ヘキサンジオール、2,2,3,3,4,4,5,5,6,6,7,7−ドデカンフルオロ−1,8−オクタンジオール、及び2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9−ペルフルオロデカン−1,10−ジオールからなる群より選択される第1のセグメントタイプ、並びに、
下記化合物、
からなる群より選択される第2のセグメントタイプを含み、
複数のリンカーは、共有結合性有機骨格(COF)として整列された第1のリンカータイプを含む、フッ素化構造化有機フィルム(SOF)。 - 前記SOFのセグメントの30重量%〜70重量%はフッ素化されている、請求項
1に記載のSOF。 - 前記SOFのフッ素含有量は、前記SOFの5重量%〜65重量%である、請求項
1又は2に記載のSOF。 - 前記SOFの厚さ内でフッ素は不均質に分布している、請求項1〜3のいずれか一項に記載のSOF。
- 前記SOFは更にキャッピングユニットを含む、請求項1〜4のいずれか一項に記載のSOF。
- 前記SOFはピンホールのないフィルムである、請求項1〜5のいずれか一項に記載のSOF。
- 前記SOFはコンポジットSOFである、請求項1〜6のいずれか一項に記載のSOF。
- 前記SOFは電気活性の追加機能を有する、請求項1〜7のいずれか一項に記載のSOF。
- 前記SOFはビルディングブロック内の複数の連結欠陥を有さない、請求項1〜8にいずれか一項に記載のSOF。
- 前記SOFの表面での水接触角は少なくとも80°である、請求項1〜9のいずれか一項に記載のSOF。
- フッ素セグメントの存在は前記SOFの表面エネルギーを調節する、請求項1〜10のいずれか一項に記載のSOF。
- (a)2,2,3,3,4,4,5,5−オクタフルオロ−1,6−ヘキサンジオール、2,2,3,3,4,4,5,5,6,6,7,7−ドデカンフルオロ−1,8−オクタンジオール、及び2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9−ペルフルオロデカン−1,10−ジオールからなる群より選択される第1のセグメントタイプ、
下記化合物、
からなる群より選択される第2のセグメントタイプ、並びに、
複数の官能基を含み、官能基のそれぞれはヒドロキシ基又はメトキシ基である、液体を含有する反応混合物を調製すること;
(b)前記反応混合物の湿潤フィルムを形成すること;及び
(c)前記湿潤フィルムの乾燥したSOFへの変化を促進すること、を含む、フッ素化構造化有機フィルムの製造プロセス。 - 前記液体を含有する反応混合物は均質な溶液である、請求項12に記載のプロセス。
- 前記乾燥したSOFのフッ素含有量は5%〜65%である、請求項12又は13に記載のプロセス。
- 前記乾燥したSOFのセグメントの30重量%〜70重量%はフッ素化されている、請求項12〜14のいずれか一項に記載のプロセス。
- 複数のセグメントおよび複数のリンカーを含むフッ素化構造化有機フィルム(SOF)であって、
複数のセグメントは、
2,2,3,3,4,4,5,5−オクタフルオロ−1,6−ヘキサンジオール、2,2,3,3,4,4,5,5,6,6,7,7−ドデカンフルオロ−1,8−オクタンジオール、及び2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9−ペルフルオロデカン−1,10−ジオールからなる群より選択される第1のセグメントタイプ、並びに、
下記化合物、
からなる群より選択される第2のセグメントタイプを含み、
複数のリンカーは、共有結合性有機骨格(COF)として整列された第1のリンカータイプを含み、前記第1のリンカータイプはエーテル結合であり、
ここで前記SOFの骨格はリンカーを通して共有結合されたフッ素含有キャッピングユニットを含む、フッ素化構造化有機フィルム(SOF)。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/173,948 US8247142B1 (en) | 2011-06-30 | 2011-06-30 | Fluorinated structured organic film compositions |
US13/173,948 | 2011-06-30 |
Publications (3)
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JP2013014762A JP2013014762A (ja) | 2013-01-24 |
JP2013014762A5 JP2013014762A5 (ja) | 2015-08-06 |
JP5894508B2 true JP5894508B2 (ja) | 2016-03-30 |
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JP2012135173A Expired - Fee Related JP5894508B2 (ja) | 2011-06-30 | 2012-06-14 | フッ素化構造化有機フィルム組成物 |
Country Status (6)
Country | Link |
---|---|
US (1) | US8247142B1 (ja) |
JP (1) | JP5894508B2 (ja) |
KR (1) | KR101817363B1 (ja) |
CN (1) | CN102850934B (ja) |
CA (1) | CA2781330C (ja) |
DE (1) | DE102012210395A1 (ja) |
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US20180171086A1 (en) * | 2016-12-16 | 2018-06-21 | South Dakota Board Of Regents | Large area monolayer of perfluoro polymers |
US11426818B2 (en) | 2018-08-10 | 2022-08-30 | The Research Foundation for the State University | Additive manufacturing processes and additively manufactured products |
KR20240046795A (ko) * | 2021-09-30 | 2024-04-09 | 호야 렌즈 타일랜드 리미티드 | 안경 렌즈, 방오제 조성물, 및 안경 렌즈의 제조 방법 |
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2011
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CN102850934B (zh) | 2017-05-17 |
KR101817363B1 (ko) | 2018-01-11 |
KR20130004159A (ko) | 2013-01-09 |
CN102850934A (zh) | 2013-01-02 |
DE102012210395A1 (de) | 2013-01-03 |
US8247142B1 (en) | 2012-08-21 |
CA2781330C (en) | 2015-10-06 |
JP2013014762A (ja) | 2013-01-24 |
CA2781330A1 (en) | 2012-12-30 |
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