JP5701486B2 - 毛髪化粧料 - Google Patents
毛髪化粧料 Download PDFInfo
- Publication number
- JP5701486B2 JP5701486B2 JP2009034830A JP2009034830A JP5701486B2 JP 5701486 B2 JP5701486 B2 JP 5701486B2 JP 2009034830 A JP2009034830 A JP 2009034830A JP 2009034830 A JP2009034830 A JP 2009034830A JP 5701486 B2 JP5701486 B2 JP 5701486B2
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- JP
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- Prior art keywords
- hair
- iron
- dimethicone
- peg
- examples
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 210000004209 hair Anatomy 0.000 claims description 128
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- 229910052742 iron Inorganic materials 0.000 claims description 46
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- 230000000694 effects Effects 0.000 description 23
- -1 and the like Chemical compound 0.000 description 12
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- 235000000396 iron Nutrition 0.000 description 11
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 10
- XVOYSCVBGLVSOL-UHFFFAOYSA-N cysteic acid Chemical compound OC(=O)C(N)CS(O)(=O)=O XVOYSCVBGLVSOL-UHFFFAOYSA-N 0.000 description 10
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- 230000005068 transpiration Effects 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- UZNHKBFIBYXPDV-UHFFFAOYSA-N trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)NCCC[N+](C)(C)C UZNHKBFIBYXPDV-UHFFFAOYSA-N 0.000 description 1
- 235000012773 waffles Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229940043810 zinc pyrithione Drugs 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
フル用アイロン」または他の呼称の毛髪に接触させて熱処理を行うアイロン、コテ類の器具全てを含む。また、一般家庭で使用される120〜180℃程度の設定温度の器具だけでなく、美理容専門店で使用されるような200〜220℃あるいはそれ以上の温度に設定可能な器具も含む。
(A)ガラス転移点が180℃以上の水溶性高分子化合物
(B)引火点が180℃以上のジメチコンコポリオール
(C)炭素数2〜4の低級アルコール20質量%以上
−8メチルエーテルジメチコン、PEG−9メチルエーテルジメチコン、PEG−10メチルエーテルジメチコン、PEG−11メチルエーテルジメチコン、PEG−32メチルエーテルジメチコンが好ましい。
ない。実施例に先立ち、各実施例で採用した試験法、評価法を説明する。
アジア人バージン毛の毛束(5g,10cm)に実施例および比較例で示した毛髪化粧料2.0gを塗布し、2分後に180℃に加熱したストレート用アイロン(ES2400デジタルセラミックアイロン,レッカ社製)を用いて30秒間処理を行う。次いで市販のシャンプー・コンディショナーで洗浄後、25℃,RH60%の条件下で一昼夜風乾した。この試料塗布〜風乾の操作を60回繰り返した後、以下の試験を行った。
毛束から毛髪50mgをハサミで細切れに切り取り、6mol/L塩酸水溶液10mLを加えて窒素雰囲気下、110℃で24時間加水分解させた。上澄み液1mLを濃縮乾固させた後、0.001mol/L塩酸水溶液40mLを加えて希釈した後、高速液体クロマトグラフにてシステイン酸量を定量した。尚、システイン酸含有率が低い程、毛髪ダメージを保護していることを示す。
毛束から80±5μmの太さの毛髪を50本選別し、毛髪の直径をマイクロメーターにて計測した。次いで、テクスチャーアナライザー(Stevens/Mechtric社)を用いて引張強度を測定し、毛髪が破断した時の荷重を測定した。毛髪直径と破断荷重の値から毛髪引張強度を算出して平均値を求めた。尚、毛髪引張強度が高い程、切れにくく枝毛や切れ毛の発生が少なく毛髪ダメージを保護していることを示す。
アジア人バージン毛の毛束(1g,15cm)に実施例および比較例で示した毛髪化粧料0.5gを均一に塗布し、2分後に180℃に加熱した市販の巻髪用アイロン(デジタルカールアイロン 25mm、アドスト社製)を用いて30秒間毛束を巻き、ウェーブを形成させた。巻髪用アイロンから毛束をはずして、毛束の見かけの長さ(L1)を測定した。下記の式に従って、セット力を次式にて求め、下記基準で評価した。
セット力(%)=(100×(15−L1))÷15
◎:セット力(%)≧45
○:45>セット力(%)≧30
△:30>セット力(%)≧15
×:15>セット力(%)
上記セット力を評価した毛束の見かけの長さ(L1)を測定後、次に温度25℃湿度90%の恒温恒湿環境下に毛束を吊し、60分放置した後に取り出し、再び毛束の見かけの長さ(L2)を測定した。下記の式に従って、セット保持効果を次式にて求めた。尚、この値が100に近いほどセット保持効果が高いことを示す。
セット保持効果(%)=(15−L2)÷(15−L1)×100
◎:セット保持効果(%)≧90
○:90>セット保持効果(%)≧60
△:60>セット保持効果(%)≧30
×:30>セット保持効果(%)
アジア人バージン毛の毛束(10g,15cm)に実施例および比較例で示した毛髪化粧料2.0gを塗布し、2分後に180℃に加熱した市販の巻髪用アイロン(デジタルカールアイロン 25mm、アドスト社製)を用いて30秒間毛束を巻き、ウェーブを形成させた。毛髪温度が常温に戻してから市販のシャンプー・コンディショナーで洗浄後、25℃,RH60%の条件下で一昼夜風乾した。この試料塗布〜風乾の操作を60回繰り返した後、20名の専門パネルを対毛髪のごわつきの無さ、なめらかさについて官能試験を行い、下記に示す判定基準により評価を行った。
ごわつきの無さ(ごわつく/ごわつかないの二者択一)
◎:パネルの15名以上がごわつかないと判断
○:パネルの10名以上15名未満がごわつかないと判断
△:パネルの5名以上10名未満がごわつかないと判断
×:ごわつかないと判断したパネルが5名未満
なめらかさ(引っかかりがあった/なめらかになったの二者択一)
◎:パネルの15名以上が毛髪がなめらかになったと判断
○:パネルの10名以上15名未満が毛髪がなめらかになったと判断
△:パネルの5名以上10名未満が毛髪がなめらかになったと判断
×:なめらかになったと判断したパネルが5名未満
表1に示すヘアミストを常法により調整し、熱ダメージ保護効果(システイン酸定量、毛髪引張強度)、セット力、セット保持力、官能試験(ごわつきのなさ、なめらかさ)について評価を行いその結果を併せて表1に示した。
(1)(VP/メタクリルアミド/ビニルイミダゾール)コポリマー 2.0
(商品名:ルビセットClear、Tg=218℃,BASF社製)
(2)ジメチコンコポリオール 1.5
(商品名:KF−6011,引火点:262℃,信越化学工業社製)
(3)エタノール 60.0
(4)(アクリレーツ/アクリル酸ステアリル/メタクリル酸アミンオキシド)
コポリマー 1.8
(4)ポリオキシエチレン(60)硬化ヒマシ油 0.1
(5)パラメトキシケイ皮酸2−エチルヘキシル 0.1
(6)L−アルギニン 0.05(7)L−グルタミン酸ナトリウム 0.05(8)ジエチレントリアミン五酢酸ナトリウム 0.01(9)香料 0.1
(10)精製水 残 余
(1)(VP/メタクリルアミド/ビニルイミダゾール)コポリマー 0.3
(商品名:ルビセットClear、Tg=218℃,BASF社製)
(2)塩化メチルビニルイミダゾリウム・ビニルピロリドン共重合体 0.2
(商品名:ルビカットFC550,Tg=207℃,BASF社製)
(3)ジメチコンコポリオール 2.0
(商品名:SS−2805,引火点:250℃,東レ・ダウコーニング社製)
(4)ジメチコンコポリオール 2.0
(商品名:FZ−2405,引火点:185℃,東レ・ダウコーニング社製)
(5)エタノール 50.0
(6)ポリオキシエチレン(60)硬化ヒマシ油 0.1
(7)パラメトキシケイ皮酸2−エチルヘキシル 0.1
(8)1,3−BG 1.0
(9)塩化ステアリルトリメチルアンモニイウム 0.5
(10)クエン酸ナトリウム 0.05(11)香料 0.1
(12)精製水 残 余
してヘアローションを調整した。
(1)(VP/アクリレート/ラウリルメタアクリレート)コポリマー 5.0
(商品名:STYLIZE 2000,Tg=180℃,
アイエスピー・ジャパン社製)
(2)ジメチコンコポリオール 1.0
(商品名:SS−2802,引火点:244℃,東レ・ダウコーニング社製)
(3)エタノール 42.0
(4)パラメトキシケイ皮酸2−エチルヘキシル 0.1
(5)香料 0.1
(6)精製水 残 余
(7)液化石油ガス(0.3MPa,25℃) 50.0
Claims (1)
- 下記(A)〜(C)成分を含有し、ヘアアイロンを使用する前に毛髪に塗布することを特徴とする毛髪化粧料。
(A)ガラス転移点が180℃以上の水溶性高分子化合物
(B)引火点が180℃以上のジメチコンコポリオール
(C)炭素数2〜4の低級アルコール20質量%以上
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JPS6251612A (ja) * | 1985-08-30 | 1987-03-06 | Sanyo Chem Ind Ltd | 毛髪処理用組成物 |
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EP0323715B1 (en) * | 1987-12-11 | 1993-09-08 | The Procter & Gamble Company | Hair styling agents and compositions containing the same |
US5968286A (en) * | 1997-10-03 | 1999-10-19 | Helene Curtis, Inc. | Heat-mediated conditioning from shampoo and conditioner hair care compositions containing silicone |
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JP2002187824A (ja) * | 2000-12-19 | 2002-07-05 | Shiseido Co Ltd | 整髪用化粧料及びそれを用いた整髪方法 |
JP2003012465A (ja) * | 2001-06-26 | 2003-01-15 | Kao Corp | 毛髪化粧料 |
JP3815785B2 (ja) * | 2002-07-08 | 2006-08-30 | 花王株式会社 | 毛髪化粧料 |
JP2005162699A (ja) * | 2003-12-04 | 2005-06-23 | Kao Corp | 毛髪用還元性水性組成物 |
DE202004002471U1 (de) * | 2004-02-18 | 2004-04-22 | Wella Ag | Haarbehandlungsmittel mit Terpolymer aus Vinylpyrrolidon, Methacrylamid und Vinylimidazol und Wirk- und Zusatzstoffen |
WO2006018065A1 (en) * | 2004-08-17 | 2006-02-23 | Unilever Plc | Hair care composition |
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