JP5669391B2 - 高い透過性を有する吸水性ポリマー粒子の重合による製造方法 - Google Patents
高い透過性を有する吸水性ポリマー粒子の重合による製造方法 Download PDFInfo
- Publication number
- JP5669391B2 JP5669391B2 JP2009519941A JP2009519941A JP5669391B2 JP 5669391 B2 JP5669391 B2 JP 5669391B2 JP 2009519941 A JP2009519941 A JP 2009519941A JP 2009519941 A JP2009519941 A JP 2009519941A JP 5669391 B2 JP5669391 B2 JP 5669391B2
- Authority
- JP
- Japan
- Prior art keywords
- polymer particles
- water
- monomer
- absorbing polymer
- fibers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920000642 polymer Polymers 0.000 title claims description 101
- 239000002245 particle Substances 0.000 title claims description 100
- 238000004519 manufacturing process Methods 0.000 title claims description 14
- 230000035699 permeability Effects 0.000 title claims description 12
- 238000006116 polymerization reaction Methods 0.000 title description 20
- 239000000178 monomer Substances 0.000 claims description 51
- 238000000034 method Methods 0.000 claims description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- 239000007789 gas Substances 0.000 claims description 28
- 238000006243 chemical reaction Methods 0.000 claims description 15
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 12
- 239000003431 cross linking reagent Substances 0.000 claims description 12
- 230000002209 hydrophobic effect Effects 0.000 claims description 12
- 239000003999 initiator Substances 0.000 claims description 12
- 239000012159 carrier gas Substances 0.000 claims description 10
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 239000000835 fiber Substances 0.000 description 52
- 239000002250 absorbent Substances 0.000 description 30
- 230000002745 absorbent Effects 0.000 description 30
- 239000000203 mixture Substances 0.000 description 28
- 239000000243 solution Substances 0.000 description 27
- 239000007788 liquid Substances 0.000 description 26
- -1 alkali metal hydrogencarbonates Chemical class 0.000 description 23
- 229920003043 Cellulose fiber Polymers 0.000 description 17
- 239000002657 fibrous material Substances 0.000 description 17
- 239000000463 material Substances 0.000 description 16
- 239000000047 product Substances 0.000 description 15
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 13
- 238000010438 heat treatment Methods 0.000 description 13
- 229920002994 synthetic fiber Polymers 0.000 description 13
- 239000012209 synthetic fiber Substances 0.000 description 13
- 239000000499 gel Substances 0.000 description 11
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 10
- 239000012071 phase Substances 0.000 description 10
- 229920001169 thermoplastic Polymers 0.000 description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- 239000002131 composite material Substances 0.000 description 9
- 230000014759 maintenance of location Effects 0.000 description 9
- 229920000728 polyester Polymers 0.000 description 9
- 239000004416 thermosoftening plastic Substances 0.000 description 9
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 8
- 238000004132 cross linking Methods 0.000 description 8
- 238000005259 measurement Methods 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 7
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 7
- 206010021639 Incontinence Diseases 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 235000011187 glycerol Nutrition 0.000 description 6
- 150000002314 glycerols Chemical class 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 229920001155 polypropylene Polymers 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 230000002787 reinforcement Effects 0.000 description 6
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 229920000297 Rayon Polymers 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 5
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical class CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 5
- 239000001506 calcium phosphate Substances 0.000 description 5
- 229910000389 calcium phosphate Inorganic materials 0.000 description 5
- 235000011010 calcium phosphates Nutrition 0.000 description 5
- 229920002678 cellulose Polymers 0.000 description 5
- 239000001913 cellulose Substances 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000011261 inert gas Substances 0.000 description 5
- 239000011159 matrix material Substances 0.000 description 5
- 239000002964 rayon Substances 0.000 description 5
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000004971 Cross linker Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000000017 hydrogel Substances 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- 229940048053 acrylate Drugs 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000012876 carrier material Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 125000004386 diacrylate group Chemical group 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- SBGKURINHGJRFN-UHFFFAOYSA-N hydroxymethanesulfinic acid Chemical compound OCS(O)=O SBGKURINHGJRFN-UHFFFAOYSA-N 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 238000010557 suspension polymerization reaction Methods 0.000 description 3
- 239000002076 α-tocopherol Substances 0.000 description 3
- 235000004835 α-tocopherol Nutrition 0.000 description 3
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 2
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
- IZXIZTKNFFYFOF-UHFFFAOYSA-N 2-Oxazolidone Chemical compound O=C1NCCO1 IZXIZTKNFFYFOF-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- BXAAQNFGSQKPDZ-UHFFFAOYSA-N 3-[1,2,2-tris(prop-2-enoxy)ethoxy]prop-1-ene Chemical compound C=CCOC(OCC=C)C(OCC=C)OCC=C BXAAQNFGSQKPDZ-UHFFFAOYSA-N 0.000 description 2
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 2
- ZMGMDXCADSRNCX-UHFFFAOYSA-N 5,6-dihydroxy-1,3-diazepan-2-one Chemical compound OC1CNC(=O)NCC1O ZMGMDXCADSRNCX-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229920001634 Copolyester Polymers 0.000 description 2
- 229920004934 Dacron® Polymers 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 229920001131 Pulp (paper) Polymers 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 2
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 2
- 229940087168 alpha tocopherol Drugs 0.000 description 2
- 235000010323 ascorbic acid Nutrition 0.000 description 2
- 229960005070 ascorbic acid Drugs 0.000 description 2
- 239000011668 ascorbic acid Substances 0.000 description 2
- LBSPZZSGTIBOFG-UHFFFAOYSA-N bis[2-(4,5-dihydro-1h-imidazol-2-yl)propan-2-yl]diazene;dihydrochloride Chemical compound Cl.Cl.N=1CCNC=1C(C)(C)N=NC(C)(C)C1=NCCN1 LBSPZZSGTIBOFG-UHFFFAOYSA-N 0.000 description 2
- 210000001124 body fluid Anatomy 0.000 description 2
- 239000010839 body fluid Substances 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- HHLFWLYXYJOTON-UHFFFAOYSA-N glyoxylic acid Chemical compound OC(=O)C=O HHLFWLYXYJOTON-UHFFFAOYSA-N 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 239000012442 inert solvent Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 230000002175 menstrual effect Effects 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000005033 polyvinylidene chloride Substances 0.000 description 2
- 239000011164 primary particle Substances 0.000 description 2
- 239000012966 redox initiator Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229920000247 superabsorbent polymer Polymers 0.000 description 2
- 229960000984 tocofersolan Drugs 0.000 description 2
- 239000011732 tocopherol Substances 0.000 description 2
- 229930003799 tocopherol Natural products 0.000 description 2
- 235000010384 tocopherol Nutrition 0.000 description 2
- 229960001295 tocopherol Drugs 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- VPYJNCGUESNPMV-UHFFFAOYSA-N triallylamine Chemical compound C=CCN(CC=C)CC=C VPYJNCGUESNPMV-UHFFFAOYSA-N 0.000 description 2
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical class OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 2
- LGPAKRMZNPYPMG-UHFFFAOYSA-N (3-hydroxy-2-prop-2-enoyloxypropyl) prop-2-enoate Chemical class C=CC(=O)OC(CO)COC(=O)C=C LGPAKRMZNPYPMG-UHFFFAOYSA-N 0.000 description 1
- OYELEBBISJGNHJ-UHFFFAOYSA-N 1,3-oxazinan-2-one Chemical compound O=C1NCCCO1 OYELEBBISJGNHJ-UHFFFAOYSA-N 0.000 description 1
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 1
- HSOOIVBINKDISP-UHFFFAOYSA-N 1-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(CCC)OC(=O)C(C)=C HSOOIVBINKDISP-UHFFFAOYSA-N 0.000 description 1
- GDGUCRQNTDPGSD-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)CO.OCC(CO)(CO)CO GDGUCRQNTDPGSD-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- GJKGAPPUXSSCFI-UHFFFAOYSA-N 2-Hydroxy-4'-(2-hydroxyethoxy)-2-methylpropiophenone Chemical compound CC(C)(O)C(=O)C1=CC=C(OCCO)C=C1 GJKGAPPUXSSCFI-UHFFFAOYSA-N 0.000 description 1
- WMYINDVYGQKYMI-UHFFFAOYSA-N 2-[2,2-bis(hydroxymethyl)butoxymethyl]-2-ethylpropane-1,3-diol Chemical compound CCC(CO)(CO)COCC(CC)(CO)CO WMYINDVYGQKYMI-UHFFFAOYSA-N 0.000 description 1
- GTELLNMUWNJXMQ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical class OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO GTELLNMUWNJXMQ-UHFFFAOYSA-N 0.000 description 1
- XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 description 1
- TURITJIWSQEMDB-UHFFFAOYSA-N 2-methyl-n-[(2-methylprop-2-enoylamino)methyl]prop-2-enamide Chemical compound CC(=C)C(=O)NCNC(=O)C(C)=C TURITJIWSQEMDB-UHFFFAOYSA-N 0.000 description 1
- CARNFEUGBMWTON-UHFFFAOYSA-N 3-(2-prop-2-enoxyethoxy)prop-1-ene Chemical compound C=CCOCCOCC=C CARNFEUGBMWTON-UHFFFAOYSA-N 0.000 description 1
- 125000004080 3-carboxypropanoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C(O[H])=O 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 description 1
- JAYRGGYYLFXBOK-UHFFFAOYSA-N 5-(2-hydroxyethyl)-2H-1,3-oxazol-2-id-4-one Chemical compound OCCC1C(N=[C-]O1)=O JAYRGGYYLFXBOK-UHFFFAOYSA-N 0.000 description 1
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000005370 alkoxysilyl group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000012935 ammoniumperoxodisulfate Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000006286 aqueous extract Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 125000003289 ascorbyl group Chemical group [H]O[C@@]([H])(C([H])([H])O*)[C@@]1([H])OC(=O)C(O*)=C1O* 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- ZPOLOEWJWXZUSP-WAYWQWQTSA-N bis(prop-2-enyl) (z)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C/C(=O)OCC=C ZPOLOEWJWXZUSP-WAYWQWQTSA-N 0.000 description 1
- PZXSLFQJOZPCJG-UHFFFAOYSA-N bis[2-(5-methyl-4,5-dihydro-1h-imidazol-2-yl)propan-2-yl]diazene;dihydrochloride Chemical compound Cl.Cl.N1C(C)CN=C1C(C)(C)N=NC(C)(C)C1=NCC(C)N1 PZXSLFQJOZPCJG-UHFFFAOYSA-N 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000013590 bulk material Substances 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 238000010382 chemical cross-linking Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 150000005676 cyclic carbonates Chemical class 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000013213 extrapolation Methods 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 238000003898 horticulture Methods 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 229920001477 hydrophilic polymer Polymers 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000010191 image analysis Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 238000012417 linear regression Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- AHHWIHXENZJRFG-UHFFFAOYSA-N oxetane Chemical compound C1COC1 AHHWIHXENZJRFG-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000962 poly(amidoamine) Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920006306 polyurethane fiber Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229940047670 sodium acrylate Drugs 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 229920002397 thermoplastic olefin Polymers 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical class OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/22—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing macromolecular materials
- A61L15/24—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
- B01J10/002—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor carried out in foam, aerosol or bubbles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/10—Aqueous solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/103—Esters of polyhydric alcohols or polyhydric phenols of trialcohols, e.g. trimethylolpropane tri(meth)acrylate
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2989—Microcapsule with solid core [includes liposome]
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Hematology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dispersion Chemistry (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
a)少なくとも1つの水溶性のエチレン性不飽和モノマー、
b)少なくとも1つの架橋剤、
c)少なくとも1つの開始剤、
d)水
を含有するモノマー溶液の液滴を該液滴を取り囲む気相中で重合させることによって製造する方法において、前記モノマー溶液中に水不溶性の無機塩が懸濁されており、かつ前記ポリマー粒子が少なくとも150μmの平均直径を有することを特徴とする方法によって解決された。
(A)上部液体透過性カバー
(B)下部液体不透過性層
(C)以下のものを含有する(A)と(B)の間にあるコア
10〜100質量%の本発明による吸水性ポリマー粒子
0〜90質量%の親水性繊維材料
好ましくは
30〜100質量%の本発明による吸水性ポリマー粒子
0〜70質量%の親水性繊維材料
特に好ましくは
50〜100質量%の本発明による吸水性ポリマー粒子
0〜50質量%の親水性繊維材料
特に好ましくは
70〜100質量%の本発明による吸水性ポリマー粒子
0〜30質量%の親水性繊維材料
最も好ましくは
90〜100質量%の本発明による吸水性ポリマー粒子
0〜10質量%の親水性繊維材料
(D)場合により、コア(C)の直上及び直下にある組織層、
(E)場合により、(A)と(C)の間にある吸収層。
測定は、別に記載がない限り、23±2℃の環境温度及び50±10%の相対空気湿度で実施される。吸水性ポリマーは、測定前に良く混和する。
0.3psi(2070Pa)の圧力負荷下での膨潤されたゲル層の液体通過性は、EP−A0640330号中の記載と同様に、高吸収性のポリマーからなる膨潤したゲル層のゲル層透過性として測定され、この場合上記の特許出願明細書第19頁及び図8に記載の装置は、ガラスフリット(40)がもはや使用されず、プランジャー(39)が円筒体(37)と同様のプラスチック材料からなり、今や全載置面にわたって均一に分布するように21個の同じ大きさの孔を含むように十分に変更した。測定の方法及び評価は、EP−A0640330号に対して不変のままである。通過流量は、自動的に捕捉される。
SFC [cm3s/g]=(Fg(t=0)×L0)/(d×A×WP)
上記式中、Fg(t=0)は、g/秒でのNaCl溶液の流量であり、これは、流量測定のデータFg(t)の線形の回帰分析に基づいてt=0に対する外挿法によって得られ、L0は、cmでのゲル層の厚さであり、dは、g/cm3でのNaCl溶液の比重であり、Aは、cm2でのゲル層の面積であり、かつWPは、dyn/cm2でのゲル層上の静水圧力である。
吸水性ポリマー粒子の遠心保持能力は、EDANA(European Disposables and Nonwovens Association)によって推奨された試験方法No.441.2−02"遠心保持能力(Centrifuge retention capacity)"によって測定される。
14.6kgのアクリル酸ナトリウム(水中37.5質量%の溶液)及び1.4kgのアクリル酸を、22.4gの15エトキシ化されたトリメチロールプロパントリアクリレートと混合した。該溶液を、加熱され窒素雰囲気で充填された液滴化塔(Vertropfungsturm)(180℃、12mの高さ、2mの幅、並流で0.1m/sのガス速度)中に液滴化した。計量供給速度は、16kg/hであった。液滴化プレートは、170μmの穿孔を37個有していた。液滴化プレートの直径は、65mmであった。開始剤とリン酸カルシウムを、液滴化装置の直前で、ベンチュリミキサを介してモノマー溶液へと計量供給した。開始剤としては、2,2′−アゾビス[2−(2−イミダゾリン−2−イル)プロパン]ジヒドロクロリドを水中に溶かした15質量%の溶液を使用した。リン酸カルシウムは、30質量%の水溶液(Rhodia社のTCP130型のリン酸カルシウム分散液)として使用した。開始剤溶液の計量供給速度は、0.224kg/hであった。液滴化塔からのガス出口温度は130℃であった。得られたポリマー粒子の平均粒径は、270μmであった。引き続き、得られた吸水性ポリマー粒子を分析した。これらの結果を第1表にまとめる。
Claims (21)
- a) 少なくとも1種のエチレン性不飽和モノマーと、
b) 少なくとも1種の架橋剤と、
c) 少なくとも1種の開始剤と、
d) 水と
を含有するモノマー溶液の液滴を、該液滴を取り囲む気相中で重合させることによって、吸水性ポリマー粒子を製造する方法であって、
前記モノマー溶液中に少なくとも1種の水不溶性の無機塩が懸濁されており、かつ、
前記ポリマー粒子が少なくとも150μmの平均直径を有する、
方法。 - 請求項1に記載の方法であって、前記モノマーa)が少なくとも1つの酸基を有する、方法。
- 請求項2に記載の方法であって、前記モノマーa)の酸基が、少なくとも部分的に中和されている、方法。
- 請求項1から3までのいずれか1項に記載の方法であって、前記モノマーa)が少なくとも50モル%の範囲でアクリル酸である、方法。
- 請求項1から4までのいずれか1項に記載の方法であって、前記ポリマー粒子が、少なくとも200μmの平均直径を有する、方法。
- 請求項1から5までのいずれか1項に記載の方法であって、前記ポリマー粒子のうちの少なくとも90質量%分が、100〜800μmの直径を有する、方法。
- 請求項1から6までのいずれか1項に記載の方法であって、キャリヤーガスを反応室中に流す、方法。
- 請求項7に記載の方法であって、前記反応室を出て行く前記キャリヤーガスを、1回の通過後に、少なくとも部分的に返送する、方法。
- 請求項7又は8に記載の方法であって、前記キャリヤーガスの酸素含有率が0.001〜0.15体積%である、方法。
- 請求項1から9までのいずれか1項に記載の方法であって、得られるポリマー粒子を、少なくとも1つの更なる方法工程において乾燥及び/又は後架橋させる、方法。
- 請求項1から10までのいずれか1項に記載の方法により製造できる吸水性ポリマー粒子。
- a) 少なくとも1種のエチレン性不飽和モノマーと、
b) 少なくとも1種の架橋剤と、
c) 少なくとも1種の開始剤と、
d) 水と
を含有するモノマー溶液の液滴を、該液滴を取り囲む気相中で重合させることによって製造される吸水性ポリマー粒子であって、
前記モノマー溶液中には、少なくとも1種の水不溶性の無機塩が懸濁されており、
前記吸水性ポリマー粒子は、
少なくとも150μmの平均直径を有し、
少なくとも0.84の平均球形度を有し、
0.005質量%未満の疎水性溶剤の含有率を有し、ここで、該疎水性溶剤は、水中での溶解度が5g/100g未満であり、かつ、
少なくとも5×10-7cm3s/gの透過性を有する、
前記吸水性ポリマー粒子。 - 請求項12に記載のポリマー粒子であって、該ポリマー粒子が少なくとも10g/gの遠心保持能力を有する、ポリマー粒子。
- 請求項12又は13に記載のポリマー粒子であって、該ポリマー粒子が少なくとも200μmの平均直径を有する、ポリマー粒子。
- 請求項12から14までのいずれか1項に記載のポリマー粒子であって、該ポリマー粒子のうちの少なくとも90質量%分が、100〜800μmの直径を有する、ポリマー粒子。
- 請求項12から15までのいずれか1項に記載のポリマー粒子であって、該ポリマー粒子が、少なくとも部分的に、重合された酸基を有するモノマーa)からなる、ポリマー粒子。
- 請求項16に記載のポリマー粒子であって、前記の重合されたモノマーa)の酸基が、少なくとも部分的に中和されている、ポリマー粒子。
- 請求項16又は17に記載のポリマー粒子であって、モノマーa)が少なくとも50モル%の範囲でアクリル酸である、ポリマー粒子。
- 請求項12から18までのいずれか1項に記載のポリマー粒子であって、該ポリマー粒子が、水不溶性の無機塩であって前記ポリマー粒子を製造するためのモノマー溶液中に懸濁可能な無機塩を少なくとも1種含有する、ポリマー粒子。
- 請求項11から19までのいずれか1項に記載のポリマー粒子の使用であって、衛生製品の製造のための使用。
- 請求項11から19までのいずれか1項に記載のポリマー粒子を含有する衛生製品。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06117487.6 | 2006-07-19 | ||
EP06117487 | 2006-07-19 | ||
PCT/EP2007/057141 WO2008009612A1 (de) | 2006-07-19 | 2007-07-12 | Verfahren zur herstellung wasserabsorbierender polymerpartikel mit hoher permeabilität durch polymerisation von tropfen einer monomerlösung |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2009543922A JP2009543922A (ja) | 2009-12-10 |
JP5669391B2 true JP5669391B2 (ja) | 2015-02-12 |
Family
ID=38577537
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2009519941A Active JP5669391B2 (ja) | 2006-07-19 | 2007-07-12 | 高い透過性を有する吸水性ポリマー粒子の重合による製造方法 |
Country Status (10)
Country | Link |
---|---|
US (2) | US8748000B2 (ja) |
EP (1) | EP2046403B1 (ja) |
JP (1) | JP5669391B2 (ja) |
CN (1) | CN101489598B (ja) |
BR (1) | BRPI0714444B8 (ja) |
MY (1) | MY157687A (ja) |
RU (1) | RU2463309C2 (ja) |
TW (1) | TWI447149B (ja) |
WO (1) | WO2008009612A1 (ja) |
ZA (1) | ZA200901113B (ja) |
Families Citing this family (95)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2314137T3 (es) | 2003-02-12 | 2009-03-16 | THE PROCTER & GAMBLE COMPANY | Pañal comodo. |
EP1913914B2 (en) | 2003-02-12 | 2014-08-06 | The Procter and Gamble Company | Absorbent core for an absorbent article |
US20060264861A1 (en) | 2005-05-20 | 2006-11-23 | Lavon Gary D | Disposable absorbent article having breathable side flaps |
JP5637685B2 (ja) * | 2006-07-19 | 2014-12-10 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | モノマー溶液の液滴の重合による、高い透過性を有する吸水性ポリマー粒子の製造方法、当該方法により製造できる吸水性ポリマー粒子、及び、当該吸水性ポリマー粒子を含有する衛生製品 |
US8013087B2 (en) | 2006-10-05 | 2011-09-06 | Basf Se | Method for the production of water absorbent polymer particles by polymerizing drops of a monomer solution |
US8419971B2 (en) * | 2006-12-22 | 2013-04-16 | Basf Se | Method for producing mechanically stable water-absorbent polymer particles |
ATE535548T1 (de) | 2007-01-16 | 2011-12-15 | Basf Se | Verfahren zur herstellung von polymerpartikeln durch polymerisation von flüssigkeitstropfen in einer gasphase |
CN101605821A (zh) * | 2007-02-06 | 2009-12-16 | 巴斯夫欧洲公司 | 通过在气相中聚合液滴生产聚合物颗粒的方法 |
EP2478883B1 (en) | 2007-06-18 | 2016-04-06 | The Procter & Gamble Company | Disposable absorbent article with substantially continuously distributed absorbent particulate polymer material and method |
DE112008000011B4 (de) | 2007-06-18 | 2013-11-28 | The Procter & Gamble Company | Einwegabsorptionsartikel und dessen Verwendung |
JP2011517703A (ja) * | 2007-12-19 | 2011-06-16 | ビーエーエスエフ ソシエタス・ヨーロピア | 表面架橋超吸収性物質の製造方法 |
CN101959538A (zh) * | 2008-03-05 | 2011-01-26 | 巴斯夫欧洲公司 | 制备超吸收剂的方法 |
CA2722538C (en) | 2008-04-29 | 2014-08-12 | The Procter & Gamble Company | Process for making an absorbent core with strain resistant core cover |
EP2313041B1 (en) | 2008-08-06 | 2013-07-17 | Basf Se | Fluid-absorbent articles |
EP2313040B1 (en) * | 2008-08-06 | 2013-06-19 | Basf Se | Fluid-absorbent articles |
JP5933262B2 (ja) | 2008-08-06 | 2016-06-08 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 流体吸収性物品 |
JP5755142B2 (ja) | 2008-11-21 | 2015-07-29 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | モノマー溶液の液滴を重合させることによって浸透性の吸水性ポリマー粒子を製造する方法 |
JP5322816B2 (ja) * | 2009-07-15 | 2013-10-23 | キヤノン株式会社 | 撮像装置およびその制御方法 |
US9688781B2 (en) * | 2009-07-20 | 2017-06-27 | The Procter & Gamble Company | Superabsorbent polymer composite particles and processes therefore |
EP2277558B1 (en) * | 2009-07-20 | 2014-07-02 | The Procter and Gamble Company | Superabsorbent polymer composite particles and processes therefore |
JP5661769B2 (ja) * | 2009-08-25 | 2015-01-28 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | モノマー溶液の液滴の重合によって改善された血液吸収を有する、吸水性ポリマー粒子の製造方法 |
US8481159B2 (en) | 2009-09-04 | 2013-07-09 | Basf Se | Water-absorbent porous polymer particles having specific sphericity and high bulk density |
CN102612379A (zh) * | 2009-09-17 | 2012-07-25 | 巴斯夫欧洲公司 | 颜色稳定的超吸收剂 |
JP2013511610A (ja) | 2009-11-23 | 2013-04-04 | ビーエーエスエフ ソシエタス・ヨーロピア | 吸水性ポリマー発泡体の製造方法 |
EP2329803B1 (en) | 2009-12-02 | 2019-06-19 | The Procter & Gamble Company | Apparatus and method for transferring particulate material |
US8852742B2 (en) | 2010-03-15 | 2014-10-07 | Basf Se | Water absorbent polymer particles formed by polymerizing droplets of a monomer solution and coated with sulfinic acid, sulfonic acid, and/or salts thereof |
BR112012023050A2 (pt) | 2010-03-15 | 2016-05-17 | Basf Se | processo para produzir partículas de polímero que absorvem água, partículas de polímero que absorvem água, e, artigo que absorve fluido |
JP5933520B2 (ja) * | 2010-03-24 | 2016-06-08 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | モノマー溶液の液滴を重合することによる吸水ポリマー粒子の製造方法 |
KR101782188B1 (ko) | 2010-03-24 | 2017-09-26 | 바스프 에스이 | 초박형 유체-흡수성 코어 |
US20120088058A1 (en) * | 2010-04-09 | 2012-04-12 | Charles Rick | Aqueous solution-absorbing mat |
PL2532332T5 (pl) | 2011-06-10 | 2018-07-31 | The Procter And Gamble Company | Pieluszka jednorazowego użytku o zredukowanym połączeniu pomiędzy wkładem chłonnym a warstwą spodnią |
EP2532329B1 (en) | 2011-06-10 | 2018-09-19 | The Procter and Gamble Company | Method and apparatus for making absorbent structures with absorbent material |
RU2568565C2 (ru) | 2011-06-10 | 2015-11-20 | Дзе Проктер Энд Гэмбл Компани | Одноразовые подгузники |
CN103596535B (zh) | 2011-06-10 | 2015-11-25 | 宝洁公司 | 用于一次性吸收制品的吸收芯 |
PL2717820T3 (pl) | 2011-06-10 | 2020-01-31 | The Procter And Gamble Company | Struktura chłonna do wyrobów chłonnych |
EP2717823B2 (en) | 2011-06-10 | 2019-04-17 | The Procter and Gamble Company | Absorbent structure for absorbent articles |
PL2532328T3 (pl) | 2011-06-10 | 2014-07-31 | Procter & Gamble | Sposób i urządzenie do wytworzenia struktur chłonnych z materiałem chłonnym |
EP2535698B1 (en) | 2011-06-17 | 2023-12-06 | The Procter & Gamble Company | Absorbent article having improved absorption properties |
EP2535697A1 (en) | 2011-06-17 | 2012-12-19 | The Procter & Gamble Company | Method for determining properties of superabsorbent polymer particles and of absorbent structures containing such particles |
EP2535027B1 (en) | 2011-06-17 | 2022-08-17 | The Procter & Gamble Company | Absorbent article having improved absorption properties |
EP4285882A3 (en) | 2011-06-17 | 2024-03-06 | The Procter & Gamble Company | Absorbent article having improved absorption properties |
WO2013045163A1 (en) | 2011-08-12 | 2013-04-04 | Basf Se | A process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution |
MX2014005627A (es) | 2011-11-21 | 2014-07-11 | Procter & Gamble | Articulos absorbentes con propiedades de absorcion mejoradas. |
EP2644174A1 (en) | 2012-03-29 | 2013-10-02 | The Procter and Gamble Company | Method and apparatus for making personal hygiene absorbent articles |
EP2671554B1 (en) | 2012-06-08 | 2016-04-27 | The Procter & Gamble Company | Absorbent core for use in absorbent articles |
EP2679208B1 (en) | 2012-06-28 | 2015-01-28 | The Procter & Gamble Company | Absorbent core for use in absorbent articles |
EP2679210B1 (en) | 2012-06-28 | 2015-01-28 | The Procter & Gamble Company | Absorbent articles with improved core |
EP2679209B1 (en) | 2012-06-28 | 2015-03-04 | The Procter & Gamble Company | Absorbent articles with improved core |
JP6193391B2 (ja) | 2012-11-13 | 2017-09-06 | ザ プロクター アンド ギャンブル カンパニー | チャネル及びシグナルを備えた吸収性物品 |
US9216118B2 (en) | 2012-12-10 | 2015-12-22 | The Procter & Gamble Company | Absorbent articles with channels and/or pockets |
PL2740452T3 (pl) | 2012-12-10 | 2022-01-31 | The Procter & Gamble Company | Wyrób chłonny o wysokiej zawartości materiału chłonnego |
US8979815B2 (en) | 2012-12-10 | 2015-03-17 | The Procter & Gamble Company | Absorbent articles with channels |
US10639215B2 (en) | 2012-12-10 | 2020-05-05 | The Procter & Gamble Company | Absorbent articles with channels and/or pockets |
EP2740450A1 (en) | 2012-12-10 | 2014-06-11 | The Procter & Gamble Company | Absorbent core with high superabsorbent material content |
ES2743718T3 (es) | 2012-12-10 | 2020-02-20 | Procter & Gamble | Artículo absorbente con sistema de sistema de captación-distribución perfilado |
US9216116B2 (en) | 2012-12-10 | 2015-12-22 | The Procter & Gamble Company | Absorbent articles with channels |
EP2740449B1 (en) | 2012-12-10 | 2019-01-23 | The Procter & Gamble Company | Absorbent article with high absorbent material content |
KR20150095688A (ko) * | 2012-12-17 | 2015-08-21 | 롬 앤드 하스 캄파니 | 단량체 소적의 생성방법 |
US9820894B2 (en) | 2013-03-22 | 2017-11-21 | The Procter & Gamble Company | Disposable absorbent articles |
EP3254656B1 (en) | 2013-06-14 | 2021-11-10 | The Procter & Gamble Company | Absorbent article and absorbent core forming channels when wet |
US10335324B2 (en) | 2013-08-27 | 2019-07-02 | The Procter & Gamble Company | Absorbent articles with channels |
US9987176B2 (en) | 2013-08-27 | 2018-06-05 | The Procter & Gamble Company | Absorbent articles with channels |
US11207220B2 (en) | 2013-09-16 | 2021-12-28 | The Procter & Gamble Company | Absorbent articles with channels and signals |
CN105555243A (zh) | 2013-09-16 | 2016-05-04 | 宝洁公司 | 带有通道和信号的吸收制品 |
EP3351225B1 (en) | 2013-09-19 | 2021-12-29 | The Procter & Gamble Company | Absorbent cores having material free areas |
US9789009B2 (en) | 2013-12-19 | 2017-10-17 | The Procter & Gamble Company | Absorbent articles having channel-forming areas and wetness indicator |
EP2905001B1 (en) | 2014-02-11 | 2017-01-04 | The Procter and Gamble Company | Method and apparatus for making an absorbent structure comprising channels |
EP2944376B1 (en) | 2014-05-13 | 2019-11-13 | The Procter and Gamble Company | Agglomerated superabsorbent polymer particles |
EP2949300B1 (en) | 2014-05-27 | 2017-08-02 | The Procter and Gamble Company | Absorbent core with absorbent material pattern |
EP2949299B1 (en) | 2014-05-27 | 2017-08-02 | The Procter and Gamble Company | Absorbent core with absorbent material pattern |
CN107405242A (zh) | 2015-03-16 | 2017-11-28 | 宝洁公司 | 带有改善的芯的吸收制品 |
US10507144B2 (en) | 2015-03-16 | 2019-12-17 | The Procter & Gamble Company | Absorbent articles with improved strength |
CA2985807A1 (en) | 2015-05-12 | 2016-11-17 | The Procter & Gamble Company | Absorbent article with improved core-to-backsheet adhesive |
CN107683126A (zh) | 2015-05-29 | 2018-02-09 | 宝洁公司 | 具有槽和润湿指示标记的吸收制品 |
EP3167859B1 (en) | 2015-11-16 | 2020-05-06 | The Procter and Gamble Company | Absorbent cores having material free areas |
ES2838027T3 (es) | 2015-12-02 | 2021-07-01 | Hartmann Paul Ag | Artículo absorbente con núcleo mejorado |
EP3205318A1 (en) | 2016-02-11 | 2017-08-16 | The Procter and Gamble Company | Absorbent article with high absorbent capacity |
EP3238678B1 (en) | 2016-04-29 | 2019-02-27 | The Procter and Gamble Company | Absorbent core with transversal folding lines |
EP3238676B1 (en) | 2016-04-29 | 2019-01-02 | The Procter and Gamble Company | Absorbent core with profiled distribution of absorbent material |
EP3251648A1 (en) | 2016-05-31 | 2017-12-06 | The Procter and Gamble Company | Absorbent article with improved fluid distribution |
EP3278782A1 (en) | 2016-08-02 | 2018-02-07 | The Procter and Gamble Company | Absorbent article with improved fluid storage |
US10828208B2 (en) | 2016-11-21 | 2020-11-10 | The Procte & Gamble Company | Low-bulk, close-fitting, high-capacity disposable absorbent pant |
WO2018118614A1 (en) | 2016-12-19 | 2018-06-28 | The Procter & Gamble Company | Absorbent article with absorbent core |
KR102075735B1 (ko) * | 2017-02-16 | 2020-02-10 | 주식회사 엘지화학 | 고흡수성 수지의 제조 방법 |
WO2018151453A1 (ko) * | 2017-02-16 | 2018-08-23 | 주식회사 엘지화학 | 고흡수정 수지의 제조 방법 |
EP3391963B1 (en) | 2017-04-19 | 2021-04-14 | The Procter & Gamble Company | Process to prepare agglomerated superabsorbent polymer particles comprising clay platelets with edge modification and/or surface modification |
US10875985B2 (en) | 2017-04-19 | 2020-12-29 | The Procter & Gamble Company | Superabsorbent polymer particles comprising one or more than one area(s) with clay platelets and at least two distinct areas substantially free of clay platelets |
EP3391961A1 (en) | 2017-04-19 | 2018-10-24 | The Procter & Gamble Company | Agglomerated superabsorbent polymer particles having a specific size ratio |
US10767029B2 (en) | 2017-04-19 | 2020-09-08 | The Procter & Gamble Company | Agglomerated superabsorbent polymer particles comprising clay platelets with edge modification and/or surface modification |
US11053370B2 (en) | 2017-04-19 | 2021-07-06 | The Procter & Gamble Company | Agglomerated superabsorbent polymer particles having a specific size ratio |
EP3391960B1 (en) | 2017-04-19 | 2023-11-22 | The Procter & Gamble Company | Superabsorbent polymer particles comprising one, or more than one area(s) with clay platelets and at least two distinct, non-adjacent areas with no clay platelets |
US20180333310A1 (en) | 2017-05-18 | 2018-11-22 | The Procter & Gamble Company | Incontinence pant with low-profile unelasticized zones |
EP3881814A1 (en) | 2020-03-17 | 2021-09-22 | The Procter & Gamble Company | Absorbent core comprising a high loft central layer and superabsorbent particles |
WO2023168616A1 (en) | 2022-03-09 | 2023-09-14 | The Procter & Gamble Company | Absorbent article with high permeability sap |
US20240091073A1 (en) | 2022-09-08 | 2024-03-21 | The Procter & Gamble Company | Disposable absorbent pants with elasticized waist panel structure and obscuring print patterns |
Family Cites Families (60)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5829846A (ja) * | 1981-08-17 | 1983-02-22 | Kuraray Co Ltd | 吸水性複合体 |
JPS6018690B2 (ja) | 1981-12-30 | 1985-05-11 | 住友精化株式会社 | 吸水性樹脂の吸水性改良方法 |
JPS58180233A (ja) | 1982-04-19 | 1983-10-21 | Nippon Shokubai Kagaku Kogyo Co Ltd | 吸収剤 |
US4734478A (en) | 1984-07-02 | 1988-03-29 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Water absorbing agent |
SE457770B (sv) * | 1985-05-23 | 1989-01-30 | Pharmacia Ab | Foerfarande foer att stabilisera en vattenhaltig dispersion av vattenabasorberade partiklar |
US4820773A (en) * | 1986-04-21 | 1989-04-11 | American Colloid Company | Water absorbent resins prepared by polymerization in the presence of styrene-maleic anhydride copolymers |
EP0348180A3 (en) | 1988-06-22 | 1991-01-30 | Mitsubishi Petrochemical Company Limited | Process for the preparation of water absorptive resin |
KR930007272B1 (ko) * | 1988-06-28 | 1993-08-04 | 닙본 쇼쿠바이 가브시기 가이샤 | 흡수성 수지 및 그 제법 |
TW201758B (ja) * | 1988-06-28 | 1993-03-11 | Catalyst co ltd | |
DE3842184A1 (de) * | 1988-12-15 | 1990-06-21 | Basf Ag | Verfahren zur steuerung der teilchengroesse bei der herstellung von pulverfoermigen polymerisaten |
CA2038779A1 (en) | 1990-04-02 | 1991-10-03 | Takumi Hatsuda | Method for production of fluid stable aggregate |
DE4020780C1 (ja) | 1990-06-29 | 1991-08-29 | Chemische Fabrik Stockhausen Gmbh, 4150 Krefeld, De | |
JP3155294B2 (ja) * | 1991-06-20 | 2001-04-09 | 三菱化学株式会社 | 高吸水性ポリマーの製造法 |
US5269980A (en) | 1991-08-05 | 1993-12-14 | Northeastern University | Production of polymer particles in powder form using an atomization technique |
DE4138408A1 (de) | 1991-11-22 | 1993-05-27 | Cassella Ag | Hydrophile, hochquellfaehige hydrogele |
DE69431321T2 (de) * | 1993-04-23 | 2003-05-22 | Mitsubishi Chem Corp | Stark wasserabsorbierende Polymere mit verbesserter Gelfestigkeit |
EP0738159A1 (en) * | 1993-12-10 | 1996-10-23 | The Procter & Gamble Company | pH-MODIFIED POLYMER COMPOSITIONS WITH ENHANCED BIODEGRADABILITY |
US6174952B1 (en) * | 1995-04-19 | 2001-01-16 | Capitol Specialty Plastics, Inc. | Monolithic polymer composition having a water absorption material |
IN1996KO01040A (ja) | 1995-06-07 | 2005-03-04 | Clarence S Freeman | |
US20010002386A1 (en) * | 1996-12-24 | 2001-05-31 | Absorbent And Process For Making Same | Absorbent and process for making same |
GB9700528D0 (en) * | 1997-01-13 | 1997-03-05 | Allied Colloids Ltd | Polymerisation processes and products |
JP3810899B2 (ja) * | 1997-08-29 | 2006-08-16 | 株式会社日本触媒 | 吸水剤の製造方法 |
US6265488B1 (en) | 1998-02-24 | 2001-07-24 | Nippon Shokubai Co., Ltd. | Production process for water-absorbing agent |
US6503979B1 (en) | 1998-02-26 | 2003-01-07 | Basf Aktiengesellschaft | Method for cross-linking hydrogels with bis- and poly-2-oxazolidinones |
DE19854574A1 (de) | 1998-11-26 | 2000-05-31 | Basf Ag | Verfahren zur Nachvernetzung von Hydrogelen mit N-Acyl-2-Oxazolidinonen |
US6562879B1 (en) | 1999-02-15 | 2003-05-13 | Nippon Shokubai Co., Ltd. | Water-absorbent resin powder and its production process and use |
JP4380873B2 (ja) * | 1999-02-15 | 2009-12-09 | 株式会社日本触媒 | 吸水性樹脂粉末およびその用途 |
DE19909838A1 (de) * | 1999-03-05 | 2000-09-07 | Stockhausen Chem Fab Gmbh | Pulverförmige, vernetzte, wässrige Flüssigkeiten sowie Blut absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung |
US6239230B1 (en) | 1999-09-07 | 2001-05-29 | Bask Aktiengesellschaft | Surface-treated superabsorbent polymer particles |
DE50008535D1 (de) * | 1999-09-08 | 2004-12-09 | Basf Ag | Verfahren zur herstellung einer wässrigen dispersion von aus polymerisat und feinteiligem anorganischen feststoff aufgebauten partikeln |
US6809158B2 (en) | 2000-10-20 | 2004-10-26 | Nippon Shokubai Co., Ltd. | Water-absorbing agent and process for producing the same |
DE60132256T2 (de) * | 2000-11-20 | 2008-12-24 | Sorbent Therapeutics, Inc., Vernon Hills | Wasserabsorbierende polymere und deren verwendung |
US6831122B2 (en) * | 2001-01-19 | 2004-12-14 | Basf Aktiengesellschaft | Water-absorbing agent, method for the production and the utilization thereof |
WO2003011913A1 (fr) * | 2001-07-31 | 2003-02-13 | Mitsubishi Chemical Corporation | Procede de polymerisation et injecteur destine a etre utilise dans le cadre du procede de polymerisation |
US7183360B2 (en) | 2001-10-05 | 2007-02-27 | Basf Aktiengesellschaft | Method for crosslinking hydrogels with morpholine-2,3-diones |
DE10204938A1 (de) | 2002-02-07 | 2003-08-21 | Stockhausen Chem Fab Gmbh | Verfahren zur Nachvernetzung im Bereich der Oberfläche von wasserabsorbierenden Polymeren mit beta-Hydroxyalkylamiden |
DE10204937A1 (de) | 2002-02-07 | 2003-08-21 | Stockhausen Chem Fab Gmbh | Verfahren zur Nachvernetzung im Bereich der Oberfläche von wasserabsorbierenden Polymeren mit Harnstoffderivaten |
DE10239074A1 (de) | 2002-08-26 | 2004-03-11 | Basf Ag | Wasserabsorbierendes Mittel und Verfahren zu seiner Herstellung |
JP4615853B2 (ja) * | 2002-12-26 | 2011-01-19 | 株式会社日本触媒 | 吸水性樹脂組成物 |
WO2004069936A1 (en) * | 2003-02-10 | 2004-08-19 | Nippon Shokubai Co., Ltd. | Particulate water absorbent containing water absorbent resin as a main component |
DE10314466A1 (de) | 2003-03-28 | 2004-10-14 | Basf Ag | Verfahren zur Herstellung von kondensierten Harzen in Pulverform |
DE10334584A1 (de) | 2003-07-28 | 2005-02-24 | Basf Ag | Verfahren zur Nachvernetzung von Hydrogelen mit bicyclischen Amidacetalen |
DE10340253A1 (de) * | 2003-08-29 | 2005-03-24 | Basf Ag | Sprühpolymerisationsverfahren |
WO2005037875A1 (ja) * | 2003-10-16 | 2005-04-28 | Mitsubishi Chemical Corporation | レドックス重合法、吸水性樹脂複合体および吸収性物品 |
EP1701786B2 (en) * | 2003-12-12 | 2022-06-15 | Nippon Shokubai Co.,Ltd. | Water-absorbing agent, manufacture method thereof, and absorbent and absorbent article made therefrom |
DE102004024437A1 (de) * | 2004-05-14 | 2005-12-08 | Basf Ag | Verfahren zur Herstellung wasserquellbarer, polymerer Partikel |
IN2007CN00955A (ja) * | 2004-08-06 | 2007-08-24 | Nippon Catalytic Chem Ind | |
DE102004042948A1 (de) | 2004-09-02 | 2006-03-09 | Basf Ag | Verfahren zur Herstellung von Polymeren durch Sprühpolymerisation |
DE102004042955A1 (de) | 2004-09-02 | 2006-03-09 | Basf Ag | Verfahren zur Herstellung von Polymeren durch Sprühpolymerisation |
DE102004042946A1 (de) | 2004-09-02 | 2006-03-09 | Basf Ag | Verfahren zur Herstellung von Polymeren durch Sprühpolymerisation |
DE102004051242A1 (de) * | 2004-10-20 | 2006-05-04 | Basf Ag | Feinteilige wasserabsorbierende Polymerpartikel mit hoher Flüssigkeitstransport- und Absorptionsleistung |
DE102004057868A1 (de) | 2004-11-30 | 2006-06-01 | Basf Ag | Unlösliche Metallsulfate in wasserabsorbierenden Polymerpartikeln |
DE102005002412A1 (de) | 2005-01-18 | 2006-07-27 | Basf Ag | Verfahren zur Herstellung von Polymeren durch Sprühpolymerisation |
JP5101300B2 (ja) * | 2005-01-28 | 2012-12-19 | ビーエーエスエフ ソシエタス・ヨーロピア | 気相中での液滴重合によって、吸水性ポリマー粒子を製造する方法 |
US7678954B2 (en) | 2005-01-31 | 2010-03-16 | Exxonmobil Chemical Patents, Inc. | Olefin oligomerization to produce hydrocarbon compositions useful as fuels |
CN101115509A (zh) * | 2005-02-04 | 2008-01-30 | 宝洁公司 | 具有改进的吸水材料的吸收结构 |
DE102005019398A1 (de) | 2005-04-25 | 2006-10-26 | Basf Ag | Verfahren zur Herstellung von Fällungspolymeren durch Sprühpolymerisation |
WO2007093531A1 (de) | 2006-02-17 | 2007-08-23 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel durch polymerisation von tropfen einer monomerlösung |
EP2046401B1 (de) * | 2006-07-19 | 2011-01-26 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel mit hoher permeabilität durch polymerisation von tropfen einer monomerlösung |
JP5637685B2 (ja) * | 2006-07-19 | 2014-12-10 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | モノマー溶液の液滴の重合による、高い透過性を有する吸水性ポリマー粒子の製造方法、当該方法により製造できる吸水性ポリマー粒子、及び、当該吸水性ポリマー粒子を含有する衛生製品 |
-
2007
- 2007-07-12 JP JP2009519941A patent/JP5669391B2/ja active Active
- 2007-07-12 BR BRPI0714444A patent/BRPI0714444B8/pt not_active IP Right Cessation
- 2007-07-12 US US12/306,800 patent/US8748000B2/en active Active
- 2007-07-12 RU RU2009105477/04A patent/RU2463309C2/ru not_active IP Right Cessation
- 2007-07-12 CN CN200780027411.8A patent/CN101489598B/zh active Active
- 2007-07-12 EP EP07787412.1A patent/EP2046403B1/de active Active
- 2007-07-12 WO PCT/EP2007/057141 patent/WO2008009612A1/de active Application Filing
- 2007-07-12 MY MYPI20090213A patent/MY157687A/en unknown
- 2007-07-19 TW TW096126361A patent/TWI447149B/zh not_active IP Right Cessation
-
2009
- 2009-02-17 ZA ZA200901113A patent/ZA200901113B/xx unknown
-
2014
- 2014-04-30 US US14/266,367 patent/US20140302321A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
US20140302321A1 (en) | 2014-10-09 |
CN101489598A (zh) | 2009-07-22 |
BRPI0714444B1 (pt) | 2018-05-29 |
EP2046403B1 (de) | 2015-09-16 |
US20090192035A1 (en) | 2009-07-30 |
CN101489598B (zh) | 2015-07-08 |
JP2009543922A (ja) | 2009-12-10 |
MY157687A (en) | 2016-07-15 |
BRPI0714444A2 (pt) | 2013-03-19 |
TWI447149B (zh) | 2014-08-01 |
US8748000B2 (en) | 2014-06-10 |
RU2463309C2 (ru) | 2012-10-10 |
RU2009105477A (ru) | 2010-08-27 |
TW200815504A (en) | 2008-04-01 |
WO2008009612A1 (de) | 2008-01-24 |
BRPI0714444B8 (pt) | 2021-06-22 |
EP2046403A1 (de) | 2009-04-15 |
ZA200901113B (en) | 2010-04-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5955367B2 (ja) | モノマー溶液の液滴の重合による、高い透過性を有する吸水性ポリマー粒子の製造方法 | |
JP5669391B2 (ja) | 高い透過性を有する吸水性ポリマー粒子の重合による製造方法 | |
JP5855179B2 (ja) | 高い透過性を有する吸水性ポリマー粒子 | |
KR101742837B1 (ko) | 수-흡수성 중합체 입자 | |
US8778490B2 (en) | Absorbent composite material comprising water-absorbent resin particles having specific surface strength, and method for manufacturing the same | |
JP6275045B2 (ja) | 新規な吸収剤物品とその製造方法 | |
JP5602428B2 (ja) | モノマー溶液の液滴の重合による、高い吸収性を有する後架橋された吸水性ポリマー粒子の製造方法 | |
JP2016506266A (ja) | 流体吸収剤物品 | |
JP5254225B2 (ja) | 吸水性複合材料の製造法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20100709 |
|
RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20101228 Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20101227 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20130208 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130327 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20130624 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20130701 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20130726 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20130802 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20130827 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20130903 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130927 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20140630 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20141006 |
|
A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20141016 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20141117 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20141216 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5669391 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |