JP5639272B2 - 断熱性が改善された接着剤 - Google Patents
断熱性が改善された接着剤 Download PDFInfo
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- JP5639272B2 JP5639272B2 JP2013528321A JP2013528321A JP5639272B2 JP 5639272 B2 JP5639272 B2 JP 5639272B2 JP 2013528321 A JP2013528321 A JP 2013528321A JP 2013528321 A JP2013528321 A JP 2013528321A JP 5639272 B2 JP5639272 B2 JP 5639272B2
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- 239000000853 adhesive Substances 0.000 title claims description 262
- 230000001070 adhesive effect Effects 0.000 title claims description 261
- 238000009413 insulation Methods 0.000 title claims description 56
- 239000000203 mixture Substances 0.000 claims description 303
- 229920002472 Starch Polymers 0.000 claims description 141
- 235000019698 starch Nutrition 0.000 claims description 141
- 239000008107 starch Substances 0.000 claims description 141
- 239000000123 paper Substances 0.000 claims description 105
- 229920000103 Expandable microsphere Polymers 0.000 claims description 77
- 239000004005 microsphere Substances 0.000 claims description 74
- 239000011111 cardboard Substances 0.000 claims description 44
- 229920001685 Amylomaize Polymers 0.000 claims description 33
- 238000004519 manufacturing process Methods 0.000 claims description 31
- 238000000034 method Methods 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 15
- 239000003431 cross linking reagent Substances 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 12
- 229920000856 Amylose Polymers 0.000 claims description 9
- 229910021538 borax Inorganic materials 0.000 claims description 5
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 5
- 239000004328 sodium tetraborate Substances 0.000 claims description 5
- 239000002131 composite material Substances 0.000 claims description 3
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 claims description 3
- 239000006260 foam Substances 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 3
- 230000005855 radiation Effects 0.000 claims description 2
- 238000009955 starching Methods 0.000 claims 1
- 239000000306 component Substances 0.000 description 92
- 239000000047 product Substances 0.000 description 58
- 238000007711 solidification Methods 0.000 description 35
- 230000008023 solidification Effects 0.000 description 35
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- 239000000945 filler Substances 0.000 description 11
- 239000002798 polar solvent Substances 0.000 description 10
- 239000004971 Cross linker Substances 0.000 description 7
- 230000002335 preservative effect Effects 0.000 description 6
- 229920002261 Corn starch Polymers 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 239000012792 core layer Substances 0.000 description 5
- 239000008120 corn starch Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000011087 paperboard Substances 0.000 description 3
- DLRVVLDZNNYCBX-UHFFFAOYSA-N Polydextrose Polymers OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(O)O1 DLRVVLDZNNYCBX-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 229910000267 dualite Inorganic materials 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
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- 238000011065 in-situ storage Methods 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
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- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 229920001100 Polydextrose Polymers 0.000 description 1
- MQUFAARYGOUYEV-UWEXFCAOSA-N Quillaic acid Natural products CC1(C)CC[C@@]2([C@H](O)C[C@]3(C)C(=CC[C@H]4[C@@]5(C)CC[C@H](O)[C@](C)(C=O)[C@H]5CC[C@@]34C)[C@H]2C1)C(=O)O MQUFAARYGOUYEV-UWEXFCAOSA-N 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 235000013773 glyceryl triacetate Nutrition 0.000 description 1
- 239000001087 glyceryl triacetate Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 235000012171 hot beverage Nutrition 0.000 description 1
- 235000021268 hot food Nutrition 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 239000001259 polydextrose Substances 0.000 description 1
- -1 polydextrose Chemical class 0.000 description 1
- 235000013856 polydextrose Nutrition 0.000 description 1
- 229940035035 polydextrose Drugs 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 229960004063 propylene glycol Drugs 0.000 description 1
- MQUFAARYGOUYEV-UAWZMHPWSA-N quillaic acid Chemical compound C1C[C@H](O)[C@@](C)(C=O)[C@@H]2CC[C@@]3(C)[C@]4(C)C[C@@H](O)[C@@]5(C(O)=O)CCC(C)(C)C[C@H]5C4=CC[C@@H]3[C@]21C MQUFAARYGOUYEV-UAWZMHPWSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
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- 235000010356 sorbitol Nutrition 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- 229940045136 urea Drugs 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Images
Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/54—Starch
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B31—MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
- B31F—MECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
- B31F1/00—Mechanical deformation without removing material, e.g. in combination with laminating
- B31F1/20—Corrugating; Corrugating combined with laminating to other layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B31—MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
- B31F—MECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
- B31F1/00—Mechanical deformation without removing material, e.g. in combination with laminating
- B31F1/20—Corrugating; Corrugating combined with laminating to other layers
- B31F1/24—Making webs in which the channel of each corrugation is transverse to the web feed
- B31F1/26—Making webs in which the channel of each corrugation is transverse to the web feed by interengaging toothed cylinders cylinder constructions
- B31F1/28—Making webs in which the channel of each corrugation is transverse to the web feed by interengaging toothed cylinders cylinder constructions combined with uniting the corrugated webs to flat webs ; Making double-faced corrugated cardboard
- B31F1/2804—Methods
- B31F1/2809—Methods characterised by the chemical composition of the glue
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/35—Heat-activated
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/40—Adhesives in the form of films or foils characterised by release liners
- C09J7/405—Adhesives in the form of films or foils characterised by release liners characterised by the substrate of the release liner
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
- D21H21/52—Additives of definite length or shape
- D21H21/54—Additives of definite length or shape being spherical, e.g. microcapsules, beads
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/412—Additional features of adhesives in the form of films or foils characterized by the presence of essential components presence of microspheres
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/10—Methods of surface bonding and/or assembly therefor
- Y10T156/1002—Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina
- Y10T156/1025—Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina to form undulated to corrugated sheet and securing to base with parts of shaped areas out of contact
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
本願は、2010年9月10日出願の米国仮特許出願No.61/381,642の利益を主張するものであり、同出願の内容を参考文献として本明細書に組み込むものとする。
本発明は、断熱性が改善された接着剤組成物に関する。特に本発明は、段ボール製品などの紙製品に断熱性を付与するために用いられる接着剤組成物とその接着剤組成物の製造方法を含む。
実施例
実施例1−断熱性が改善された接着剤の形成
実施例2−断熱性が改善された接着剤の形成
実施例3−いろいろな接着剤の比較
Claims (18)
- 以下の成分:
a.でんぷん成分;
b.アルカリ性成分;
c.四ホウ酸ナトリウム;
d.水;および
e.複数の膨張性マイクロスフェア;
を含有する断熱性が改善された接着剤組成物であって、
該でんぷん成分が、上記膨張性マイクロスフェアが膨張する温度以上の温度で、該でん
ぷん成分の完全糊化が可能なように選ばれている接着剤組成物であって、
接着剤組成物の糊化開始温度が、マイクロスフェアのTexp(Texpはマイクロス
フェアが膨張開始する温度)より11.1℃〜22.2℃低く(20°F〜40°F低く)、
接着剤組成物が完全に凝固する温度が、膨張性マイクロスフェアのTmax以上(Tma
xは、マイクロスフェアが最大膨張率に到達する温度である)である、該接着剤組成物。 - 上記でんぷん成分が高アミロース濃度のでんぷん組成物を含む請求項1の接着剤組成物
。 - 上記でんぷん成分が以下の成分を含む請求項1の接着剤組成物:
a.未変性でんぷん組成物;および
b.高アミロース濃度のでんぷん組成物。 - 上記接着剤組成物が、上記未変性でんぷん組成物を上記接着剤組成物の20重量%の量
で含み、上記高アミロース濃度のでんぷん組成物を上記接着剤組成物の4重量%の量で含
む請求項3の接着剤組成物。 - 上記アルカリ性成分が水酸化ナトリウムを含む請求項1の接着剤組成物。
- 上記膨張性マイクロスフェアが、加熱及び/又は放射線の存在下で膨張して断熱発泡体
を形成する高分子マイクロスフェアを含む請求項1の接着剤組成物。 - 上記膨張性マイクロスフェアが82.2℃(180°F)〜98.9℃(210°F)
の温度で膨張し始める請求項6の接着剤組成物。 - 上記膨張性マイクロスフェアが、121.1℃(250°F)〜137.8℃(280
°F)の温度で最大の膨張レベルをもつ請求項6の接着剤組成物。 - 上記複数の膨張性マイクロスフェアが、上記接着剤組成物の0.5%〜5重量%の量で
存在する請求項1の接着剤組成物。 - 以下の工程を含む断熱性が改善された段ボール製品の製造方法:
a.平面状で第一の面と第二の面をもつ第一の紙ライナーを与える工程;
b.複数のフルートをもち、各フルートが1つの頂部と1つの谷部を有する第二の紙ライ
ナーを与える工程;
c.以下の工程を含む断熱性が改善された接着剤組成物の製造工程:
i.高アミロースでんぷん成分、アルカリ性成分、架橋剤および水を混合してでんぷ
ん混合物を形成する工程;
ii.上記高アミロースでんぷん混合物を加熱して加熱でんぷん混合物を形成する工
程;、
iii.上記加熱でんぷん混合物に未変性でんぷん成分を加える工程;および
iv.上記加熱でんぷん混合物に複数の膨張性マイクロスフェアを加える工程:
d.上記フルートのそれぞれの頂部に上記接着剤組成物を塗布する工程;
e.上記フルートの頂部を上記平面状の紙ライナーの第一の面の表面に合わせて、第一の
紙ライナーと第二の紙ライナーが上記フルートの上記頂部で互いに接触した複合構造物を
形成する工程;および
f.上記複合構造物の上記接着剤組成物を第一の温度と第二の温度に加熱して硬化させる
工程であって、上記第一の温度と上記第二の温度が11.1℃〜22.2℃異なる(20°F〜40°F異なる)工程、であり、接着剤組成物の糊化開始温度が、マイクロスフェアのTexp(Texpはマイクロスフェアが膨張開始する温度)より11.1℃〜22.2℃低く(20°F〜40°F低く)、接着剤組成物が完全に凝固する温度が、膨張性マイクロスフェアのTmax以上(Tmaxは、マイクロスフェアが最大膨張率に到達する温度である)であり、上記第一の温度が接着剤組成物の糊化開始温度であり、上記第二の温度が膨張性マイクロスフェアのTmaxより高い温度である、上記製造方法。 - 上記フルートの先端を上記平坦な紙ライナーの第一の面におく上記工程が、圧力を用い
て上記先端を上記第一の面に固定することを含む請求項10の方法。 - 上記第一の温度が58.9℃(138°F)〜68.9℃(156°F)である請求項
10の方法。 - 以下の工程を含む断熱シートの製造方法:
a.第一の面と第二の面をもつ平面状の紙シートを与える工程であって、上記第一の面が
断熱成分を収容するのに十分な構造をもつ表面を持つ工程;
b.以下の工程を含む接着剤組成物の製造工程:
i.高アミロースでんぷん成分、アルカリ性成分、架橋剤および水を混合してでんぷ
ん混合物を形成する工程;
ii.上記高アミロースでんぷん混合物を加熱して加熱でんぷん混合物を形成する工
程;
iii.上記加熱でんぷん混合物に未変性でんぷん成分を加える工程;および
iv.上記加熱でんぷん混合物に複数の膨張性マイクロスフェアを加える工程:
c.上記平面状の紙シートの第一の面の表面に上記接着剤組成物を塗布して、塗布された
接着剤組成物を持つシートを形成する工程;
d.上記塗布された接着剤組成物をもつシートを、上記膨張性マイクロスフェアを膨張さ
せるのに十分な第一の温度に加熱する工程;
e.上記塗布された接着剤組成物を持つシートを、上記接着剤組成物を完全に硬化させる
のに十分な第二の温度に加熱する工程、
であり、接着剤組成物の糊化開始温度が、マイクロスフェアのTexp(Texpはマイ
クロスフェアが膨張開始する温度)より11.1℃〜22.2℃低く(20°F〜40°F低く)、接着剤組成物が完全に凝固する温度が、膨張性マイクロスフェアのTmax以上(Tmaxは、マイクロスフェアが最大膨張率に到達する温度である)である、上記製造方法。 - 上記でんぷん成分が、上記膨張性マイクロスフェアが膨張する温度以上の温度で上記で
んぷん成分の完全糊化が可能なように選ばれる請求項13の方法。 - 上記でんぷん成分が、未変性でんぷんと高アミロースでんぷんの混合物を含む請求項1
3の方法。 - 上記平坦な紙シートの第一の面に上記接着剤組成物を塗布する工程が、上記複数の膨張
性マイクロスフェアが、点状、縞状、波状、格子状、平坦な底面を持ついずれかの一般的
な多面体形状、円柱状、これらの組み合わせからなる群から選ばれる構造で塗布されるよ
うに上記接着剤組成物を塗布することを含む請求項13の方法。 - 上記第一の温度が上記接着剤組成物を完全硬化させるのに不十分である請求項13の方
法。 - 上記第一の温度が82.2℃(180°F)〜98.9℃(210°F)である請求項
13の方法。
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US38164210P | 2010-09-10 | 2010-09-10 | |
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US (6) | US8747603B2 (ja) |
EP (1) | EP2614124B1 (ja) |
JP (1) | JP5639272B2 (ja) |
KR (1) | KR101420581B1 (ja) |
CN (2) | CN104669757B (ja) |
BR (1) | BR112013004955B1 (ja) |
ES (1) | ES2677972T3 (ja) |
MX (3) | MX369481B (ja) |
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US9580629B2 (en) | 2017-02-28 |
US20140238586A1 (en) | 2014-08-28 |
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US10208429B2 (en) | 2019-02-19 |
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MX369481B (es) | 2019-11-11 |
KR20130106397A (ko) | 2013-09-27 |
JP2013537249A (ja) | 2013-09-30 |
MX350366B (es) | 2017-09-05 |
CN103189460B (zh) | 2014-10-29 |
US20190218720A1 (en) | 2019-07-18 |
US20130160945A1 (en) | 2013-06-27 |
EP2614124A2 (en) | 2013-07-17 |
ES2677972T3 (es) | 2018-08-07 |
MX2019010073A (es) | 2019-11-21 |
US20190136456A1 (en) | 2019-05-09 |
CN104669757A (zh) | 2015-06-03 |
WO2012033998A3 (en) | 2012-07-05 |
MX2013002701A (es) | 2013-06-05 |
KR101420581B1 (ko) | 2014-07-16 |
US11427963B2 (en) | 2022-08-30 |
BR112013004955A8 (pt) | 2018-02-06 |
US20170130399A1 (en) | 2017-05-11 |
BR112013004955A2 (pt) | 2016-08-16 |
CN103189460A (zh) | 2013-07-03 |
US11649589B2 (en) | 2023-05-16 |
BR112013004955B1 (pt) | 2021-05-25 |
WO2012033998A2 (en) | 2012-03-15 |
EP2614124A4 (en) | 2015-02-11 |
CN104669757B (zh) | 2018-01-09 |
EP2614124B1 (en) | 2018-04-25 |
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