JP5586225B2 - フィルムと、非晶性ポリアミドベースの支持体とから成る複合部材 - Google Patents
フィルムと、非晶性ポリアミドベースの支持体とから成る複合部材 Download PDFInfo
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- JP5586225B2 JP5586225B2 JP2009526054A JP2009526054A JP5586225B2 JP 5586225 B2 JP5586225 B2 JP 5586225B2 JP 2009526054 A JP2009526054 A JP 2009526054A JP 2009526054 A JP2009526054 A JP 2009526054A JP 5586225 B2 JP5586225 B2 JP 5586225B2
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- polyamide
- film
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
- C08J5/124—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives using adhesives based on a macromolecular component
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/24—Homopolymers or copolymers of amides or imides
- C08L33/26—Homopolymers or copolymers of acrylamide or methacrylamide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/10—Methods of surface bonding and/or assembly therefor
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
Description
I.部分結晶性のポリアミドから成る成形材料から成る層I.)aを含むフィルム、ならびに
II.ほぼ非晶性のポリアミドから成る成形材料から成る支持体
から構成される複合部材によって解決される。
− 1,12−ドデカン二酸と、4,4’−ジアミノジシクロヘキシルメタン(PAPACM12)とから成るポリアミド、とりわけ35〜65%のトランス,トランス−異性体割合を有する4,4’−ジアミノジシクロヘキシルメタンから出発するポリアミド;
− PA612、PA1010、PA1012、PA11、PA12、PA1212、ならびにこれらから成る混合物;
− 以下のモノマーの組み合わせから製造可能なコポリアミド:
a)脂肪族の非分枝状ジアミンと、脂肪族の非分枝状ジカルボン酸とから成るほぼ等モルの混合物65〜99mol%、好ましくは75〜98mol%、特に好ましくは80〜97mol%、およびとりわけ85〜96mol%、この際、混合物は場合によっては塩として存在し、かつそれに加えて、ジアミンとジカルボン酸とを組成の計算の際にその都度それぞれ別々に計算し、ただしジアミンとジカルボン酸とから成る混合物は1のモノマーあたり平均で8〜12のC原子、および好ましくは9〜11のC原子を含む。
− テレフタル酸および/またはイソフタル酸と、2,2,4−トリメチルヘキサメチレンジアミンと2,4,4−トリメチルヘキサメチレンジアミンとから成る異性体混合物とから成るポリアミド、
− イソフタル酸と、1,6−ヘキサメチレンジアミンとから成るポリアミド、
− テレフタル酸/イソフタル酸と、1,6−ヘキサメチレンジアミンとから成る、場合によっては4,4’−ジアミノジシクロヘキシルメタンとの混合物でのコポリアミド、
− テレフタル酸、および/またはイソフタル酸と、3,3’−ジメチル−4,4’−ジアミノジシクロヘキシルメタン、およびラウリンラクタムまたはカプロラクタムとから成るコポリアミド、
− 1,12−ドデカン二酸、またはセバシン酸と、3,3’−ジメチル−4,4’−ジアミノジシクロヘキシルメタン、および場合によってはラウリンラクタムまたはカプロラクタムとから成る(コ)ポリアミド、
− イソフタル酸と、4,4’−ジアミノジシクロヘキシルメタン、およびラウリンラクタムまたはカプロラクタムとから成るコポリアミド、
− 1,12−ドデカン二酸と、4,4’−ジアミノジシクロヘキシルメタン(低い割合のトランス,トランス−異性体)とから成るポリアミド、
− テレフタル酸、および/またはイソフタル酸、ならびにアルキル置換されたビス(4−アミノシクロヘキシル)メタンの同族体から成り、場合によってはヘキサメチレンジアミンとの混合物でのコポリアミド、
− ビス(4−アミノ−3−メチル−5−エチル−シクロヘキシル)メタン(場合によってはさらなるジアミンと共に)と、イソフタル酸(場合によってはさらなるジカルボン酸と共に)とから成るコポリアミド
− m−キシレンジアミンと、さらなるジアミン、例えばヘキサメチレンジアミンとの混合物、ならびに(場合によってはさらなるジカルボン酸、例えばテレフタル酸、および/または2,6−ナフタリンジカルボン酸と共に)イソフタル酸から成るコポリアミド
− ビス(4−アミノ−シクロヘキシル)メタンと、ビス−(4−アミノ−3−メチル−シクロヘキシル)メタンとの混合物と、8〜14のC原子を有する脂肪族ジカルボン酸とから成るコポリアミド、ならびに
− 1,14−テトラデカン二酸、ならびに芳香族、脂肪族、もしくは脂環式のジアミンを含む混合物から成るポリアミドまたはコポリアミドである。
− アクリル酸誘導体、メタクリル酸誘導体、α−オレフィン、および芳香族ビニル化合物から選択されているビニル化合物から誘導されるモノマー単位70〜99.9%、
ならびに
− カルボン酸無水物基、エポキシド基、およびオキサゾリン基から選択されている1の官能基を含むモノマー単位0.1〜30質量%。
1.以下の式:
の単位から選択されているモノマー単位約70〜約99.9質量%、好ましくは80〜99.4質量%、および特に好ましくは85〜99質量%;
2.以下の式:
の単位から選択されているモノマー単位約0.1〜約30質量%、好ましくは0.6〜20質量%、および特に好ましくは1〜15質量%。
A.式(I)[式中、R2はHではない]の単位14〜96質量%、好ましくは20〜85質量%、および特に好ましくは25〜75質量%;
式(V)[式中、m=1]の単位0〜75質量%、好ましくは1〜60質量%、および特に好ましくは5〜40質量%;
式(I)[式中、R2=H]の単位0〜15質量%、好ましくは0〜10質量%、および特に好ましくは0.1〜7質量%;
式(VI)[式中、m=1]の単位0.1〜30質量%、好ましくは1〜20質量%、および特に好ましくは2〜15質量%。
式(III)の単位39.9〜80質量%、好ましくは44.9質量%〜75質量%、および特に好ましくは49.9〜70質量%;
式(VI)[式中、m=0]の単位0.1〜30質量%、好ましくは0.6〜20質量%、および特に好ましくは1〜15質量%。
式(IV)の単位0〜60質量%、好ましくは0.1〜50質量%、および特に好ましくは2〜40質量%;
式(VI)[式中、m=0]の単位0.1〜30質量%、好ましくは0.6〜20質量%、および特に好ましくは1〜15質量%。
式(III)の単位0.1〜45質量%、好ましくは1〜40質量%、および特に好ましくは2〜35質量%;
式(VI)[式中、m=0]の単位0.1〜30質量%、好ましくは0.6〜20質量%、および特に好ましくは1〜15質量%。
式(IV)の単位0〜60質量%、好ましくは0.1〜50質量%、および特に好ましくは2〜40質量%、
式(VII)の単位0.1〜30質量%、好ましくは0.6〜20質量%、および特に好ましくは1〜15質量%、
G.式(I)[式中、R2はHではない]と、式(III)とから選択された単位0〜99.9質量%、好ましくは0.1〜99.4質量%、および特に好ましくは2〜99質量%、
式(IV)の単位0〜60質量%、好ましくは0.1〜50質量%の、および特に好ましくは2〜40質量%、
式(VIII)の単位0.1〜30質量%、好ましくは0.6〜20質量%、および特に好ましくは1〜15質量%。
a)I.a)に記載の層/定着剤層
b)I.a)に記載の層/定着剤層/非晶性ポリアミドから成る層
c)クリアコート/着色層としてのI.a)に記載の層/定着剤層
d)クリアコート/着色層/I.a)に記載の層/定着剤層
e)クリアコート/担体層/I.a)に記載の層/定着剤層
f)クリアコート/着色層/担体層/I.a)に記載の層/定着剤層
である。
g)クリアコート/着色層/担体層/I.a)に記載の層/定着剤層/非晶性ポリアミドから成る層
好ましい実施形態において、フィルムは0.02〜1.2mmの層厚、特に好ましくは0.05〜1mmの、極めて特に好ましくは0.1〜0.8mmの、およびとりわけ好ましくは0.2〜0.6mmの層厚を有する。この際好ましい実施形態において、定着剤は0.01〜0.5mmの層厚、特に好ましくは0.02〜0.4mmの、極めて特に好ましくは0.04〜0.3mmの、およびとりわけ好ましくは0.05〜0.2mmの層厚を有する。このフィルムは公知の方法、例えば押出成形によって製造するか、または多層システムの場合は、共押出、または積層により製造する。場合によっては、これらは引き続き形を変えることができる。
PAPACM12: TROGAMID(登録商標)CX7323(Degussa GmbH)
PA12: ISO307に従い測定して、2.1の溶液相対粘度ηrelを有するタイプ
PA1012: 2.1の溶液相対粘度ηrelを有するタイプ
PA1010: 2.0の溶液相対粘度ηrelを有するタイプ
定着剤(HV):
a)式
b)式
c)式
d)式
という組成のコポリマー。
− DIN53745に記載の、摩擦ローラー(テーバー)法による摩擦;
− 耐薬品性(相応する試料のプレートを、20℃で24時間にわたって完全に接触させて貯蔵;プレートをスタンドでビーカーに入れ、かつ引き続き表面を視覚的に評価した)。
Claims (11)
- ISO11357に従い測定して少なくとも8J/gの溶融エンタルピーを有する部分結晶性のポリアミドから成る成形材料から成る層を含むフィルムと、
ISO11357に従い測定して8J/g未満の溶融エンタルピーを有する、ほぼ非晶性のポリアミドから成る成形材料から成る支持体と
から構成されている複合部材であって、前記フィルムの厚さが、0.02〜1.2mmである、前記複合部材。 - 前記フィルムが支持体側に定着剤層を含むことを特徴とする、請求項1に記載の複合部材。
- 前記定着剤が、フィルム層の部分結晶性のポリアミドと同一の、または当該ポリアミドと相容性のポリアミドと、ならびに前記支持体のほぼ非晶性のポリアミドと同一の、または当該ポリアミドと相容性のポリアミドとから成るブレンドを含むことを特徴とする、請求項2に記載の複合部材。
- 前記定着剤が以下のモノマー単位:
− アクリル酸誘導体、メタクリル酸誘導体、α−オレフィン、および芳香族ビニル化合物から選択されているビニル化合物から誘導されるモノマー単位70〜99.9質量%、
ならびに
− カルボン酸無水物基、エポキシド基、およびオキサゾリン基から選択されている1の官能基を含むモノマー単位0.1〜30質量%
を含むコポリマーを2〜100質量%含むことを特徴とする、請求項2に記載の複合部材。 - 前記コポリマーが以下のモノマー単位:
a)以下の式:
の単位から選択されているモノマー単位70〜99.9質量%、
b)以下の式:
の単位から選択されているモノマー単位0.1〜30質量%
を含むことを特徴とする、請求項4に記載の複合部材。 - 前記定着剤が、
コポリマーを2〜99.9質量%、および
ポリアミドを0.1〜98質量%
含むことを特徴とする、請求項4または5に記載の複合部材。 - 前記フィルムが、
− ポリアミド成形材料から成る支持体側の保護層
− 着色層
− さらなるポリアミド層
− 保護層もしくはクリアコート、ならびに
− 剥離可能な保護フィルム
から選択されているさらなる層を含むことを特徴とする、請求項1から6までのいずれか1項に記載の複合部材。 - 前記複合部材を、接着、プレス成形、積層、背面射出成形、背面発泡成形、または背面プレス成形によって製造することを特徴とする、請求項1から7までのいずれか1項に記載の複合部材。
- 前記支持体が平面状に形成されていることを特徴とする、請求項1から8までのいずれか1項に記載の複合部材。
- 光学的な部材、自動車もしくは輸送用車両の部材、または医療用品、衛生用品、もしくは保健用品であることを特徴とする、請求項1から9までのいずれか1項に記載の複合部材。
- フィルムと支持体とから成る複合部材を、接着、プレス成形、積層、背面射出成形、背面発泡成形、または背面プレス成形によって製造することを特徴とする、請求項1から10までのいずれか1項に記載の複合部材の製造方法。
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DE102006041138.2 | 2006-09-01 | ||
PCT/EP2007/058796 WO2008025729A1 (de) | 2006-09-01 | 2007-08-24 | Verbundteil aus einer folie und einem substrat auf basis eines amorphen polyamids |
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JP4175077B2 (ja) * | 2002-10-15 | 2008-11-05 | 東レ株式会社 | 積層フィルム |
DE10333005A1 (de) | 2003-07-18 | 2005-02-03 | Degussa Ag | Formmasse auf Basis von Polyetheramiden |
DE102004029217A1 (de) * | 2004-06-16 | 2006-01-05 | Degussa Ag | Mehrschichtfolie |
US20060014035A1 (en) * | 2004-06-22 | 2006-01-19 | Thibaut Montanari | Polyamide-based multilayer structure for covering substrates |
US20060036044A1 (en) * | 2004-08-13 | 2006-02-16 | Cheng Paul P | Transparent polyamide compositions and articles made therefrom |
DE102004048776A1 (de) * | 2004-10-07 | 2006-04-13 | Degussa Ag | Mehrschichtverbund mit EVOH-Schicht und Schutzschicht |
DE102004048777A1 (de) * | 2004-10-07 | 2006-04-13 | Degussa Ag | Mehrschichtverbund mit Polyesterschicht und Schutzschicht |
DE102004063220A1 (de) * | 2004-12-29 | 2006-07-13 | Degussa Ag | Transparente Formmassen |
DE102005004280A1 (de) * | 2005-01-28 | 2006-08-03 | Degussa Ag | Verfahren zur Herstellung eines Verbundes |
DE102005007663A1 (de) * | 2005-02-19 | 2006-08-24 | Degussa Ag | Transparente, dekorierbare mehrschichtige Folie |
DE102005007664A1 (de) * | 2005-02-19 | 2006-08-31 | Degussa Ag | Transparente Formmasse |
DE102005007665A1 (de) * | 2005-02-19 | 2006-08-31 | Degussa Ag | Folie auf Basis eines Polyamidblends |
DE102005026264A1 (de) * | 2005-06-08 | 2006-12-14 | Degussa Ag | Transparente Formmasse |
DE102005051126A1 (de) * | 2005-10-26 | 2007-05-03 | Degussa Gmbh | Folie mit Deckschicht aus einer Polyamidzusammensetzung |
-
2006
- 2006-09-01 DE DE102006041138A patent/DE102006041138A1/de not_active Withdrawn
-
2007
- 2007-08-24 JP JP2009526054A patent/JP5586225B2/ja not_active Expired - Fee Related
- 2007-08-24 US US12/373,547 patent/US20100055425A1/en not_active Abandoned
- 2007-08-24 EP EP07788532.5A patent/EP2057015B1/de active Active
- 2007-08-24 WO PCT/EP2007/058796 patent/WO2008025729A1/de active Application Filing
- 2007-08-24 CN CN200780031775.3A patent/CN101505960A/zh active Pending
Also Published As
Publication number | Publication date |
---|---|
JP2010501381A (ja) | 2010-01-21 |
WO2008025729A1 (de) | 2008-03-06 |
EP2057015A1 (de) | 2009-05-13 |
DE102006041138A1 (de) | 2008-03-06 |
EP2057015B1 (de) | 2014-06-18 |
CN101505960A (zh) | 2009-08-12 |
US20100055425A1 (en) | 2010-03-04 |
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