JP5547415B2 - 防錆塗料組成物 - Google Patents
防錆塗料組成物 Download PDFInfo
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- JP5547415B2 JP5547415B2 JP2009065112A JP2009065112A JP5547415B2 JP 5547415 B2 JP5547415 B2 JP 5547415B2 JP 2009065112 A JP2009065112 A JP 2009065112A JP 2009065112 A JP2009065112 A JP 2009065112A JP 5547415 B2 JP5547415 B2 JP 5547415B2
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- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title claims description 42
- 230000003449 preventive effect Effects 0.000 title claims description 30
- 239000003973 paint Substances 0.000 title description 28
- 239000000203 mixture Substances 0.000 title description 18
- 238000000576 coating method Methods 0.000 claims description 102
- 239000011248 coating agent Substances 0.000 claims description 98
- 229920000647 polyepoxide Polymers 0.000 claims description 94
- 239000003822 epoxy resin Substances 0.000 claims description 92
- 229910052751 metal Inorganic materials 0.000 claims description 67
- 239000002184 metal Substances 0.000 claims description 67
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 60
- 229920005989 resin Polymers 0.000 claims description 55
- 239000011347 resin Substances 0.000 claims description 55
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 54
- 239000000049 pigment Substances 0.000 claims description 54
- 239000008199 coating composition Substances 0.000 claims description 48
- 229920001225 polyester resin Polymers 0.000 claims description 40
- 239000004645 polyester resin Substances 0.000 claims description 40
- 239000004925 Acrylic resin Substances 0.000 claims description 39
- 229920000178 Acrylic resin Polymers 0.000 claims description 39
- 239000003795 chemical substances by application Substances 0.000 claims description 39
- 229930185605 Bisphenol Natural products 0.000 claims description 38
- 238000006243 chemical reaction Methods 0.000 claims description 36
- 239000002253 acid Substances 0.000 claims description 32
- 239000007787 solid Substances 0.000 claims description 31
- 150000003839 salts Chemical class 0.000 claims description 26
- 239000000377 silicon dioxide Substances 0.000 claims description 25
- 150000003682 vanadium compounds Chemical class 0.000 claims description 24
- 150000007519 polyprotic acids Polymers 0.000 claims description 21
- 229910052804 chromium Inorganic materials 0.000 claims description 20
- 239000011651 chromium Substances 0.000 claims description 20
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 19
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 17
- 150000001875 compounds Chemical class 0.000 claims description 17
- 230000009477 glass transition Effects 0.000 claims description 17
- 125000003700 epoxy group Chemical group 0.000 claims description 16
- 239000000126 substance Substances 0.000 claims description 16
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 14
- 125000001931 aliphatic group Chemical group 0.000 claims description 14
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims description 14
- 239000010419 fine particle Substances 0.000 claims description 14
- 239000005011 phenolic resin Substances 0.000 claims description 14
- 229920001228 polyisocyanate Polymers 0.000 claims description 13
- 239000005056 polyisocyanate Substances 0.000 claims description 13
- 125000001302 tertiary amino group Chemical group 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims description 10
- 229920003180 amino resin Polymers 0.000 claims description 8
- 229910052914 metal silicate Inorganic materials 0.000 claims description 8
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 claims description 6
- DNWNZRZGKVWORZ-UHFFFAOYSA-N calcium oxido(dioxo)vanadium Chemical compound [Ca+2].[O-][V](=O)=O.[O-][V](=O)=O DNWNZRZGKVWORZ-UHFFFAOYSA-N 0.000 claims description 6
- 229920003987 resole Polymers 0.000 claims description 6
- 239000000539 dimer Substances 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- -1 etc. Substances 0.000 description 48
- 238000004519 manufacturing process Methods 0.000 description 41
- 238000005260 corrosion Methods 0.000 description 40
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- 239000000243 solution Substances 0.000 description 31
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 30
- 238000000034 method Methods 0.000 description 27
- 238000012360 testing method Methods 0.000 description 23
- 229910000831 Steel Inorganic materials 0.000 description 22
- 239000010959 steel Substances 0.000 description 22
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 16
- 239000003054 catalyst Substances 0.000 description 16
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 16
- 239000000047 product Substances 0.000 description 16
- 230000008961 swelling Effects 0.000 description 16
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 15
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 15
- 235000019441 ethanol Nutrition 0.000 description 14
- 239000004593 Epoxy Substances 0.000 description 12
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 12
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 12
- 239000000178 monomer Substances 0.000 description 12
- 238000010438 heat treatment Methods 0.000 description 11
- 239000000463 material Substances 0.000 description 11
- 238000003786 synthesis reaction Methods 0.000 description 11
- 125000003277 amino group Chemical group 0.000 description 10
- 235000014113 dietary fatty acids Nutrition 0.000 description 10
- 239000000194 fatty acid Substances 0.000 description 10
- 229930195729 fatty acid Natural products 0.000 description 10
- 150000004665 fatty acids Chemical class 0.000 description 10
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 9
- 241001163841 Albugo ipomoeae-panduratae Species 0.000 description 9
- 229910019142 PO4 Inorganic materials 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 150000001412 amines Chemical class 0.000 description 9
- 235000012241 calcium silicate Nutrition 0.000 description 9
- 229910052918 calcium silicate Inorganic materials 0.000 description 9
- 239000010452 phosphate Substances 0.000 description 9
- 239000002904 solvent Substances 0.000 description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 8
- 239000002981 blocking agent Substances 0.000 description 8
- 239000002987 primer (paints) Substances 0.000 description 8
- 239000002210 silicon-based material Substances 0.000 description 8
- 229910001424 calcium ion Inorganic materials 0.000 description 7
- 229910000389 calcium phosphate Inorganic materials 0.000 description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical group [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 230000005856 abnormality Effects 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 238000009835 boiling Methods 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 239000012046 mixed solvent Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 230000009257 reactivity Effects 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 5
- 229910001297 Zn alloy Inorganic materials 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 239000001506 calcium phosphate Substances 0.000 description 5
- 229960001714 calcium phosphate Drugs 0.000 description 5
- 235000011010 calcium phosphates Nutrition 0.000 description 5
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 5
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 5
- 239000004843 novolac epoxy resin Substances 0.000 description 5
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 5
- 239000011134 resol-type phenolic resin Substances 0.000 description 5
- 150000005846 sugar alcohols Polymers 0.000 description 5
- 235000010215 titanium dioxide Nutrition 0.000 description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 5
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 5
- 239000011701 zinc Substances 0.000 description 5
- 229910052725 zinc Inorganic materials 0.000 description 5
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 229920000877 Melamine resin Polymers 0.000 description 4
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 4
- IPTNXMGXEGQYSY-UHFFFAOYSA-N acetic acid;1-methoxybutan-1-ol Chemical compound CC(O)=O.CCCC(O)OC IPTNXMGXEGQYSY-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 4
- FJMNNXLGOUYVHO-UHFFFAOYSA-N aluminum zinc Chemical compound [Al].[Zn] FJMNNXLGOUYVHO-UHFFFAOYSA-N 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 238000005452 bending Methods 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 239000000378 calcium silicate Substances 0.000 description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 125000005442 diisocyanate group Chemical group 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 4
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 4
- 239000004137 magnesium phosphate Substances 0.000 description 4
- 229910000157 magnesium phosphate Inorganic materials 0.000 description 4
- 229960002261 magnesium phosphate Drugs 0.000 description 4
- 235000010994 magnesium phosphates Nutrition 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 239000012299 nitrogen atmosphere Substances 0.000 description 4
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 4
- 150000002989 phenols Chemical class 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 4
- 229910001935 vanadium oxide Inorganic materials 0.000 description 4
- 230000002087 whitening effect Effects 0.000 description 4
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 4
- 229910000165 zinc phosphate Inorganic materials 0.000 description 4
- RTTZISZSHSCFRH-UHFFFAOYSA-N 1,3-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC(CN=C=O)=C1 RTTZISZSHSCFRH-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000004606 Fillers/Extenders Substances 0.000 description 3
- 239000004640 Melamine resin Substances 0.000 description 3
- OPKOKAMJFNKNAS-UHFFFAOYSA-N N-methylethanolamine Chemical compound CNCCO OPKOKAMJFNKNAS-UHFFFAOYSA-N 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 239000012963 UV stabilizer Substances 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 3
- 239000001361 adipic acid Substances 0.000 description 3
- 235000011037 adipic acid Nutrition 0.000 description 3
- 125000004849 alkoxymethyl group Chemical group 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 150000001555 benzenes Chemical class 0.000 description 3
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 description 3
- FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 description 3
- 239000007809 chemical reaction catalyst Substances 0.000 description 3
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 3
- 239000001031 chromium pigment Substances 0.000 description 3
- 239000008119 colloidal silica Substances 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 238000010494 dissociation reaction Methods 0.000 description 3
- 230000005593 dissociations Effects 0.000 description 3
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- 230000007613 environmental effect Effects 0.000 description 3
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 3
- 239000001530 fumaric acid Substances 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 3
- 239000011259 mixed solution Substances 0.000 description 3
- WHIVNJATOVLWBW-UHFFFAOYSA-N n-butan-2-ylidenehydroxylamine Chemical compound CCC(C)=NO WHIVNJATOVLWBW-UHFFFAOYSA-N 0.000 description 3
- 229920003986 novolac Polymers 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 235000019832 sodium triphosphate Nutrition 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 3
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 3
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 3
- MUTGBJKUEZFXGO-OLQVQODUSA-N (3as,7ar)-3a,4,5,6,7,7a-hexahydro-2-benzofuran-1,3-dione Chemical compound C1CCC[C@@H]2C(=O)OC(=O)[C@@H]21 MUTGBJKUEZFXGO-OLQVQODUSA-N 0.000 description 2
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 2
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical class O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 2
- KCZQSKKNAGZQSZ-UHFFFAOYSA-N 1,3,5-tris(6-isocyanatohexyl)-1,3,5-triazin-2,4,6-trione Chemical compound O=C=NCCCCCCN1C(=O)N(CCCCCCN=C=O)C(=O)N(CCCCCCN=C=O)C1=O KCZQSKKNAGZQSZ-UHFFFAOYSA-N 0.000 description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 2
- QWBBPBRQALCEIZ-UHFFFAOYSA-N 2,3-dimethylphenol Chemical compound CC1=CC=CC(O)=C1C QWBBPBRQALCEIZ-UHFFFAOYSA-N 0.000 description 2
- NKTOLZVEWDHZMU-UHFFFAOYSA-N 2,5-xylenol Chemical compound CC1=CC=C(C)C(O)=C1 NKTOLZVEWDHZMU-UHFFFAOYSA-N 0.000 description 2
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- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 1
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Landscapes
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- Application Of Or Painting With Fluid Materials (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
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| JP5547376B2 (ja) * | 2008-03-19 | 2014-07-09 | 関西ペイント株式会社 | 防錆塗料組成物 |
| JP5547375B2 (ja) * | 2008-03-19 | 2014-07-09 | 関西ペイント株式会社 | 防錆塗料組成物 |
| JP5922588B2 (ja) * | 2011-01-12 | 2016-05-24 | 日本ペイント・オートモーティブコーティングス株式会社 | アルミホイールの塗装方法及びアルミホイール |
| CN102241940B (zh) * | 2011-05-21 | 2013-01-16 | 江西景新漆业有限公司 | 耐候隔热复合涂料及其应用 |
| CN103013269B (zh) * | 2012-12-12 | 2015-12-09 | 铜陵三佳变压器有限责任公司 | 一种抗湿性变压器用环氧树脂漆 |
| CN103289552A (zh) * | 2013-05-22 | 2013-09-11 | 无锡市华明化工有限公司 | 一种涂料 |
| CN103509430B (zh) * | 2013-09-27 | 2015-09-16 | 无锡阳工机械制造有限公司 | 一种金属防腐蚀涂料及其制备方法 |
| CN104562006B (zh) * | 2013-10-25 | 2018-08-14 | 通用电气公司 | 以耐腐蚀层保护的元件及制造该元件的方法 |
| CN103694856A (zh) * | 2013-12-20 | 2014-04-02 | 海安县吉程机械有限公司 | 一种耐寒防腐涂料 |
| CN103881443A (zh) * | 2014-02-25 | 2014-06-25 | 蚌埠凯盛工程技术有限公司 | 一种环保防腐耐黄变氨基树脂漆 |
| CN103881448A (zh) * | 2014-02-25 | 2014-06-25 | 安徽普源分离机械制造有限公司 | 一种耐候防腐环氧树脂汽车漆 |
| KR101499624B1 (ko) * | 2014-08-21 | 2015-03-09 | 김민수 | 용접관 이음쇠용 친환경 수용성 방청도료 조성물 |
| CN104497285A (zh) * | 2014-12-15 | 2015-04-08 | 广东巴德士化工有限公司 | 一种高润湿性调色专用树脂 |
| CN104946069A (zh) * | 2015-05-08 | 2015-09-30 | 江苏士林电气设备有限公司 | 一种母线槽专用防腐涂料的生产工艺 |
| CN104946070A (zh) * | 2015-05-08 | 2015-09-30 | 江苏士林电气设备有限公司 | 一种母线槽专用防腐涂料 |
| JP6619920B2 (ja) * | 2015-12-16 | 2019-12-11 | 株式会社Uacj | プレコートアルミニウム材 |
| CN107227051A (zh) * | 2017-06-20 | 2017-10-03 | 合肥太通制冷科技有限公司 | 一种冰箱蒸发器用铝板防腐漆及其制备方法 |
| CN109777184A (zh) * | 2017-11-15 | 2019-05-21 | 马锐 | 天然有机功能油漆涂料瓷砖的生产工艺技术 |
| CN108997902A (zh) * | 2018-09-03 | 2018-12-14 | 王劲 | 一种耐深冲耐高温不粘附卷材涂料及其制备方法 |
| EP3666842B1 (en) * | 2018-12-12 | 2021-09-15 | 3M Innovative Properties Company | High chemical resistant coating as protection against aggressive environment |
| WO2021002139A1 (ja) * | 2019-07-03 | 2021-01-07 | 中国塗料株式会社 | 耐熱塗料組成物、耐熱塗膜、耐熱塗膜付き基材およびその製造方法 |
| CN113891918B (zh) * | 2019-09-17 | 2022-07-15 | 关西涂料株式会社 | 二液型涂料组合物 |
| CN112341796A (zh) * | 2020-11-27 | 2021-02-09 | 浙江长鸿纺织科技有限公司 | 一种具有耐腐蚀性的tpu膜 |
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| JPS61276861A (ja) * | 1985-05-31 | 1986-12-06 | Nippon Paint Co Ltd | 金属素材用プライマ−組成物 |
| JP2697883B2 (ja) * | 1989-01-23 | 1998-01-14 | ダウ・ケミカル日本株式会社 | 高分子量エポキシダイマー酸エステル樹脂の製造方法 |
| JPH0692559B2 (ja) * | 1989-02-10 | 1994-11-16 | 東洋インキ製造株式会社 | 塗料組成物 |
| JP2864546B2 (ja) * | 1989-08-09 | 1999-03-03 | 日本鋼管株式会社 | プレコート鋼板 |
| JPH05255636A (ja) * | 1992-03-11 | 1993-10-05 | Origin Electric Co Ltd | 密着性の優れた塗膜を備えた素材 |
| JPH06228497A (ja) * | 1993-02-01 | 1994-08-16 | Kansai Paint Co Ltd | 水性塗料組成物 |
| JPH0751620A (ja) * | 1993-08-18 | 1995-02-28 | Kawasaki Steel Corp | 耐食性に優れかつ無害性のプレコート鋼板 |
| JP3076496B2 (ja) * | 1994-03-29 | 2000-08-14 | 関西ペイント株式会社 | 塗料組成物 |
| JP2002012820A (ja) * | 2000-06-29 | 2002-01-15 | Nippon Yushi Basf Coatings Kk | プライマー塗料組成物 |
| JP2002188041A (ja) * | 2000-12-20 | 2002-07-05 | Toray Ind Inc | 塗料組成物 |
| JP4890688B2 (ja) * | 2001-07-23 | 2012-03-07 | 関西ペイント株式会社 | 水性エポキシ樹脂分散液 |
| JP4061050B2 (ja) * | 2001-11-01 | 2008-03-12 | 関西ペイント株式会社 | プライマー用塗料組成物 |
| JP2003166071A (ja) * | 2001-11-29 | 2003-06-13 | Kansai Paint Co Ltd | 潤滑鋼板用表面処理組成物及び潤滑鋼板 |
| KR100583265B1 (ko) * | 2002-05-30 | 2006-05-25 | 간사이 페인트 가부시키가이샤 | 도료 조성물 |
| CN1215137C (zh) * | 2002-07-30 | 2005-08-17 | 关西涂料株式会社 | 涂料组合物及涂装方法 |
| JP2004190111A (ja) * | 2002-12-12 | 2004-07-08 | Kansai Paint Co Ltd | エッジ部の防食方法 |
| JP5250859B2 (ja) * | 2006-05-22 | 2013-07-31 | 関西ペイント株式会社 | 水性塗料組成物 |
| JP5547376B2 (ja) * | 2008-03-19 | 2014-07-09 | 関西ペイント株式会社 | 防錆塗料組成物 |
| JP5547375B2 (ja) * | 2008-03-19 | 2014-07-09 | 関西ペイント株式会社 | 防錆塗料組成物 |
| JP5086288B2 (ja) * | 2009-02-05 | 2012-11-28 | 関西ペイント株式会社 | クロムフリー塗装金属板の塗膜形成方法及び塗装金属板 |
| JP5366628B2 (ja) * | 2009-04-16 | 2013-12-11 | 関西ペイント株式会社 | 複層塗膜形成方法及び塗装金属板 |
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| TW200948908A (en) | 2009-12-01 |
| CN101560358B (zh) | 2012-05-30 |
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