JP5508085B2 - 感光性組成物、感光性平版印刷版材料および感光性平版印刷版材料の製造方法 - Google Patents
感光性組成物、感光性平版印刷版材料および感光性平版印刷版材料の製造方法 Download PDFInfo
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- JP5508085B2 JP5508085B2 JP2010074346A JP2010074346A JP5508085B2 JP 5508085 B2 JP5508085 B2 JP 5508085B2 JP 2010074346 A JP2010074346 A JP 2010074346A JP 2010074346 A JP2010074346 A JP 2010074346A JP 5508085 B2 JP5508085 B2 JP 5508085B2
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- water
- photosensitive
- printing plate
- lithographic printing
- plate material
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- -1 alkyl ether sulfate Chemical class 0.000 claims description 59
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- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
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- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
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- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
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- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
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- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical group C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 125000005409 triarylsulfonium group Chemical group 0.000 description 1
- IELLVVGAXDLVSW-UHFFFAOYSA-N tricyclohexyl phosphate Chemical compound C1CCCCC1OP(OC1CCCCC1)(=O)OC1CCCCC1 IELLVVGAXDLVSW-UHFFFAOYSA-N 0.000 description 1
- WEAPVABOECTMGR-UHFFFAOYSA-N triethyl 2-acetyloxypropane-1,2,3-tricarboxylate Chemical compound CCOC(=O)CC(C(=O)OCC)(OC(C)=O)CC(=O)OCC WEAPVABOECTMGR-UHFFFAOYSA-N 0.000 description 1
- FZGFBJMPSHGTRQ-UHFFFAOYSA-M trimethyl(2-prop-2-enoyloxyethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCOC(=O)C=C FZGFBJMPSHGTRQ-UHFFFAOYSA-M 0.000 description 1
- RRHXZLALVWBDKH-UHFFFAOYSA-M trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCC[N+](C)(C)C RRHXZLALVWBDKH-UHFFFAOYSA-M 0.000 description 1
- JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 description 1
- NDGYGLUZNRIHLX-UHFFFAOYSA-K trisodium;nonoxybenzene;phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O.CCCCCCCCCOC1=CC=CC=C1 NDGYGLUZNRIHLX-UHFFFAOYSA-K 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical class OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000003232 water-soluble binding agent Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
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- Photosensitive Polymer And Photoresist Processing (AREA)
- Materials For Photolithography (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Description
光重合開始剤としてBC−6で示される有機ホウ素塩2部およびT−4で示されるトリハロアルキル置換化合物1.5部を秤取り、さらに重合性二重結合基を有する化合物としてトリメチロールプロパントリアクリレート6部を加え、酢酸エチル200部を加えて溶解した。この溶液にさらに増感剤としてS−38で示すシアニン色素を0.6部加えて溶解した。
上記実施例1〜3で得られた酢酸エチル溜去後の水中乳化物を使用して、さらに着色剤を添加することで感光性平版印刷版材料を製造するための塗布液を作製した。着色剤として水中に青色顔料が分散した市販の水系顔料分散液(御国色素(株)製ハイミクロンKブルー7361)を使用した。使用した水系顔料分散液はフタロシアニン系顔料を水溶性ポリマーである分散剤を使用して分散を行ったものであり、分散剤はフタロシアニン顔料に対して約20%添加されており、またフタロシアニン顔料の固形分濃度は約20%であった。各々の実施例1〜3で得られた水中乳化物全量に対して、それぞれに上記のハイミクロンKブルーを20部加えて攪拌を行い、均一に分散した青色の感光性組成物である塗布液を作製した。
バインダーポリマー(SP−13) 20部
トリメチロールプロパントリアクリレート 6部
光重合開始剤(BC−6) 2部
光重合開始剤(T−4) 1.5部
増感色素(S−38) 0.6部
酢酸エチル 300部
上記のようにして露光した試料を用いて、以下のようにして現像性試験を行った。現像は三菱製紙(株)製自動現像装置P−1310Tを使用して処理を行った。現像温度を25℃および30℃の2条件に設定し、各々の温度で処理時間を10秒、15秒および20秒の3条件で処理を行い、非画像部の溶出性(完全に残膜がなくなる場合を○とし、僅かに残膜が認められる場合を△、明確に残膜が発生し、溶出不良である場合を×とした)を評価した。結果を表3に纏めた。
上記の現像液を用いて処理を行った場合の解像性評価として、10μm細線および1%網点が明瞭に再現されている場合を○とし、これらが部分的に欠落しているが、20μm以上の細線および2%以上の網点が明瞭に再現されている場合を△、これ以下の再現性である場合を×とした。結果を表4に纏めた。比較例5では光硬化性感光層の塗布面が均一でなく20μm程度のピッチでゆず肌状のムラが存在し画質に悪影響を与えており、さらに露光量に対する感度が十分でなく細線の再現性が悪い結果であった。実施例4〜6では光硬化性感光層の塗布面は均一で、感度も高解像度の画像を与えるのに十分であった。
先の現像処理後の試料の内、各々30℃15秒の条件で現像された試料を用い、通常のオフセット印刷を行うため、印刷機はリョービ560を使用し、印刷インキはオフセット印刷用墨インキを使用し、吸湿液は東洋インキ製造(株)製オフセット印刷用吸湿液アクワユニティWKKの1%水溶液を使用した。印刷性評価として、耐刷性について印刷開始から5万枚まで1万枚ごとの印刷物についてマイクロスコープ(オムロン(株)製CCDスコープVC4500−PC)を用いて測定を行った。20μm細線および網点面積率が2%の微小網点部分が印刷物上で再現されている場合を○とし、部分的にかけている場合を△とし、ほぼ完全に欠落した場合を×とした。インキ乗り性については、印刷物濃度の測定を1万枚ごとの印刷物について反射濃度計を用いて測定を行った。結果を表5に纏めた。なお、印刷時の地汚れについては、試験した全ての試料について認めなかった。比較例5では画線が均一でなく、さらに露光量に対する感度が十分でないことが耐刷不良の一因であった。
上記で描画を行った各感光性平版印刷版を用い、自動現像処理装置としてアルミニウム印刷版(PS版)用自動現像装置PD−912−M(大日本スクリーン製造(株)製)を使用して現像処理を行った。現像槽中には30℃に調節したイオン交換水を投入し、現像時間は15秒に設定した。現像槽中において該感光性平版印刷版材料はモルトンロールにより表面が弱く擦られることで大部分の非画像部における光硬化性感光層が除去されるように調節した。モルトンロールによる擦り現像を経て、現像槽出口にある2本の絞りロールにより感光性平版印刷版材料表面の過剰な水分が絞り取られた。引き続く水洗槽において表面がシャワー洗浄され、最後に温風により乾燥を行った。この現像処理プロセスにおいて、水現像性評価として、(A)現像槽出口絞りロールへのスラッジ付着の有無、(B)水現像槽中のスラッジの沈降の有無、(C)処理済みの感光性平版印刷版表面へのスラッジの付着の有無、(D)処理済みの感光性平版印刷版の現像残膜の有無、の4つの評価項目について評価を行った。評価は各々の実施例6および比較例5の感光性平版印刷版材料をA3サイズで100版自動現像装置に連続して通して評価を行った。評価項目(A)については、現像槽出口絞りロールへのスラッジ付着が発生した場合を×とし、発生しなかった場合を○とした。評価項目(B)については、スラッジの沈降が著しい場合を×とし、スラッジの発生がなく、均一に分散した状態を○とした。評価項目(C)については、100版目の版にスラッジ付着が認められた場合を×とし、付着が認められなかった場合を○とした。評価項目(D)については、100版目の版に現像残膜が認められた場合を×とし、認められなかった場合を○とした。結果を表6に纏めた。
実施例4〜6で作製した感光性平版印刷版材料を、35℃で相対湿度85%に調整した加湿機内に2週間放置した。その際、各々の感光性平版印刷版材料の光硬化性感光層表面に100μm厚みのポリエステルフィルムを重ねて放置を行い、ブロッキングの発生が生じるか否かを観察した。取り出した感光性平版印刷版材料の実施例4〜6は全てブロッキングの発生は認められなかった。さらに、上述した条件で露光を行い、さらに現像性試験を行ったが先の結果と同様な結果が得られ、解像性評価の結果も同一であったことから保存安定性試験において変化が認められない良好な結果が得られた。
Claims (3)
- (A)光重合開始剤と(B)重合性二重結合基を有する化合物を(C)スルホン酸塩基を有する水溶性ポリマーと(D)ジオクチルスルホコハク酸ナトリウム、アルキルナフタレンスルホン酸塩類およびアルキルエーテル硫酸塩のポリエチレンオキサイド付加物類から選ばれる少なくとも1種のアニオン性界面活性剤の存在下に乳化分散した水中乳化物である感光性組成物。
- 支持体上に、請求項1に記載の感光性組成物を含有する塗布液を塗布して設けた光硬化性感光層を有する感光性平版印刷版材料。
- 酢酸エチルを使用して、これに光重合開始剤および重合性二重結合基を有する化合物を溶解し、ジオクチルスルホコハク酸ナトリウム、アルキルナフタレンスルホン酸塩類およびアルキルエーテル硫酸塩のポリエチレンオキサイド付加物類から選ばれる少なくとも1種のアニオン性界面活性剤およびスルホン酸塩基を有する水溶性ポリマーを加えて高速剪断下に水中に分散させて感光性組成物の水中乳化物を作製し、該水中乳化物を含有する塗布液を支持体上に塗布、乾燥する感光性平版印刷版材料の製造方法。
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