JP5452856B2 - ブロックポリマー及びそのブロックポリマーを含む化粧品組成物 - Google Patents
ブロックポリマー及びそのブロックポリマーを含む化粧品組成物 Download PDFInfo
- Publication number
- JP5452856B2 JP5452856B2 JP2007264844A JP2007264844A JP5452856B2 JP 5452856 B2 JP5452856 B2 JP 5452856B2 JP 2007264844 A JP2007264844 A JP 2007264844A JP 2007264844 A JP2007264844 A JP 2007264844A JP 5452856 B2 JP5452856 B2 JP 5452856B2
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- JP
- Japan
- Prior art keywords
- block
- polymer
- acrylate
- isobutyl
- methacrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000000203 mixture Substances 0.000 title claims abstract description 173
- 239000002537 cosmetic Substances 0.000 title claims abstract description 21
- 229920000642 polymer Polymers 0.000 title claims description 193
- 239000000178 monomer Substances 0.000 claims description 88
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical group C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 claims description 53
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical group COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 53
- 229920001519 homopolymer Polymers 0.000 claims description 45
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims description 39
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 32
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 32
- 229920001577 copolymer Polymers 0.000 claims description 28
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 claims description 27
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 claims description 24
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- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 7
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 5
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical group C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
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- 238000000034 method Methods 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 2
- XUDBVJCTLZTSDC-UHFFFAOYSA-N 2-ethenylbenzoic acid Chemical compound OC(=O)C1=CC=CC=C1C=C XUDBVJCTLZTSDC-UHFFFAOYSA-N 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims description 2
- BNKAXGCRDYRABM-UHFFFAOYSA-N ethenyl dihydrogen phosphate Chemical compound OP(O)(=O)OC=C BNKAXGCRDYRABM-UHFFFAOYSA-N 0.000 claims description 2
- 239000001530 fumaric acid Substances 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
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- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 2
- AAYRWMCIKCRHIN-UHFFFAOYSA-N propane-1-sulfonic acid;prop-2-enamide Chemical compound NC(=O)C=C.CCCS(O)(=O)=O AAYRWMCIKCRHIN-UHFFFAOYSA-N 0.000 claims description 2
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- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical group C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 claims 3
- 238000002156 mixing Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 abstract description 14
- 229920001400 block copolymer Polymers 0.000 abstract 1
- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 52
- SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 52
- VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 description 52
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- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 38
- JUIBLDFFVYKUAC-UHFFFAOYSA-N [5-(2-ethylhexanoylperoxy)-2,5-dimethylhexan-2-yl] 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(C)CCC(C)(C)OOC(=O)C(CC)CCCC JUIBLDFFVYKUAC-UHFFFAOYSA-N 0.000 description 32
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 28
- -1 isooctyl Chemical group 0.000 description 27
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- 239000000049 pigment Substances 0.000 description 24
- 239000002904 solvent Substances 0.000 description 22
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- 239000001993 wax Substances 0.000 description 20
- 238000002360 preparation method Methods 0.000 description 18
- IAXXETNIOYFMLW-GYSYKLTISA-N [(1r,3r,4r)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@@]2(C)[C@H](OC(=O)C(=C)C)C[C@@H]1C2(C)C IAXXETNIOYFMLW-GYSYKLTISA-N 0.000 description 17
- 239000013543 active substance Substances 0.000 description 17
- 239000000243 solution Substances 0.000 description 17
- 239000000126 substance Substances 0.000 description 17
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- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 14
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- 125000004432 carbon atom Chemical group C* 0.000 description 13
- 229920000058 polyacrylate Polymers 0.000 description 13
- 238000006116 polymerization reaction Methods 0.000 description 13
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 12
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- 239000004480 active ingredient Substances 0.000 description 11
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- 235000011837 pasties Nutrition 0.000 description 11
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- 150000002430 hydrocarbons Chemical class 0.000 description 9
- 238000002844 melting Methods 0.000 description 9
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- 239000003960 organic solvent Substances 0.000 description 9
- RUEOYQNDBAHZBS-UHFFFAOYSA-N 4-[2-hydroxy-3-(2-hydroxy-3-octadecanoyloxypropoxy)propoxy]-4-oxobutanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)COCC(O)COC(=O)CCC(O)=O RUEOYQNDBAHZBS-UHFFFAOYSA-N 0.000 description 8
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 8
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- 229920002319 Poly(methyl acrylate) Polymers 0.000 description 8
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 5
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Landscapes
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Description
− 標本を30%(εmax)、すなわちその初期長(l0)の約0.3倍伸長させる
− 引張り速度に等しい回帰速度(すなわち50mm/分)を適用することによってストレスを解放し、0ストレス(εi)に戻った後に、標本の残留伸び率を測定する
によるものである。
− a)40℃以上のTgを有するブロック、
− b)20℃以下のTgを有するブロック、
− c)20℃から40℃の間のTgを有するブロック
から選択され、前記第2のブロックは前記第1のブロックとは異なるカテゴリーa)、b)又はc)から選択されることができる。
40℃以上のTgを有するブロックは、例えば、40から150℃の範囲、好ましくは50℃以上、例えば、50から120℃の範囲、より好ましくは50から100℃の範囲、更に好ましくは60℃以上、例えば、60から120℃の範囲のTgを有する。
− そのモノマーから調製されたホモポリマーが40℃以上の、例えば40℃から150℃の範囲の、好ましくは50℃以上の、例えば50℃から120℃の範囲の、より好ましくは60℃以上の、好ましくは60℃から120℃の範囲のTgを有する、モノマー;並びに
− そのモノマーから調製されたホモポリマーが40℃未満のTgを有するモノマーであって、20℃から40℃の間のTgを有するモノマー、及び/又は、20℃未満の、例えば−100から20℃、好ましくは15℃未満、特に−80℃から15℃の範囲、より好ましくは10℃未満、例えば−50℃から0℃の範囲のTgを有する後述するモノマーから選択されるモノマー;
− 式CH2=C(CH3)−COOR1(式中、R1は、メチル、エチル、プロピル又はイソブチル基等の直鎖又は分岐の1から4の炭素原子を含む非置換アルキル基を表し、或いは、R1はC4からC12シクロアルキル基を表す)のメタクリレート;
− 式CH2=CH−COOR2(式中、R2は、イソボルニル基等のC4からC12シクロアルキル基又はtert-ブチル基を表す)のアクリレート;
− 式
− これらの混合物。
20℃以下のTgを有するブロックは、例えば、−100から20℃の範囲、好ましくは15℃以下、特に、−80から15℃の範囲、より好ましくは10℃以下、例えば−100℃から0℃、更に好ましくは−50から0℃の範囲のTgを有する。
− 対応するホモポリマーが20℃以下の、例えば−100℃から20℃の範囲の、好ましくは15℃未満の、特に−80℃から15℃の範囲の、より好ましくは10℃未満の、例えば−50℃から0℃の範囲のTgを有する1以上のモノマー;並びに
− 対応するホモポリマーが20℃より高いTgを有するモノマーであって、例えば、40℃以上、例えば30から150℃の範囲の、好ましくは50℃以上の、例えば50℃から120℃の、より好ましくは60℃以上の、例えば60℃から120℃のTgを有するモノマー、及び/又は、20℃から40℃の間のTgを有する既述のモノマー;
− 式CH2=CH−COOR3(式中、R3は、tert-ブチル基以外の、直鎖又は分岐のC1−C12非置換アルキル基を表し、任意に、O、N及びSから選択される1以上のヘテロ原子が介在する)のアクリレート、
− 式CH2=C(CH3)−COOR4(式中、R4は、直鎖又は分岐のC6−C12非置換アルキル基を表し、任意に、O、N及びSから選択される1以上のヘテロ原子が介在する)のメタクリレート、
− 式R5−CO−O−CH=CH2(式中、R5は、直鎖又は分岐C4−C12アルキル基を表す)のビニルエステル、
− C4−C12アルコール及びビニルアルコールエーテル、
− N−オクチルアクリルアミド等のN−(C4―C12)アルキルアクリルアミド
− 並びに、これらの混合物。
20℃から40℃の間のTgを有するブロックはホモポリマー又はコポリマーであってよい。
− 対応するホモポリマーが40℃以上の、例えば40℃から150℃の範囲の、好ましくは50℃以上の、例えば50℃から120℃の範囲の、より好ましくは60℃以上の、好ましくは60℃から120℃の範囲のTgを有する、既述した主モノマー;及び/又は
− 対応するホモポリマーが20℃以下の、例えば−100℃から20℃の範囲の、好ましくは15℃以下の、特に−80℃から15℃の範囲の、より好ましくは10℃以下の、例えば−50℃から0℃の範囲のTgを有する、既述した主モノマー。前記モノマーは第1のブロックを形成するコポリマーのTgが20から40℃の間となるように選択される。
a)親水性モノマー、例えば、
− 少なくとも1つのカルボン酸又はスルホン酸官能性を含むエチレン性不飽和モノマー、例えば、アクリル酸、メタクリル酸、クロトン酸、無水マレイン酸、イタコン酸、フマル酸、マレイン酸、アクリルアミドプロパンスルホン酸、ビニル安息香酸、ビニルリン酸、及び、これらの塩、
− 少なくとも1つの第3級アミン官能性を有するエチレン性不飽和モノマー、例えば、2−ビニルピリジン、4−ビニルピリジン、ジメチルアミノエチルメタクリレート、ジエチルアミノエチルメタクリレート、及び、ジメチルアミノプロピルメタクリルアミド、並びに、これらの塩、
− 式CH2=C(CH3)−COOR6(式中、R6は、メチル、エチル、プロピル又はイソブチル基等の1から4の炭素原子を含む直鎖又は分岐アルキル基を表し、前記アルキル基は、ヒドロキシル基(例えば、2−ヒドロキシプロピルメタクリレート又は2−ヒドロキシエチルメタクリレート)及びハロゲン原子(Cl、Br、I又はF)(例えば、トリフルオロエチルメタクリレート)から選択される1以上の置換基で置換されている)のメタクリレート、
− 式CH2=C(CH3)−COOR9(式中、R9は、O、N及びSから選択される1以上のヘテロ原子が任意に介在する直鎖又は分岐C6−C12アルキル基を表し、前記アルキル基は、ヒドロキシル基及びハロゲン原子(Cl、Br、I又はF)から選択される1以上の置換基で置換されている)のメタクリレート、
− 式CH2=CHCOOR10(式中、R10はヒドロキシル基(例えば、2−ヒドロキシプロピルアクリレート及び2−ヒドロキシエチルアクリレート)及びハロゲン原子(Cl、Br、I又はF)から選択される1以上の置換基で置換されている直鎖又は分岐C1−C12アルキル基を表し、或いは、R10は、例えばメトキシ−POE等の5から30回のオキシエチレン単位の繰り返しを有する(C1−C12)アルキル−O−POE(ポリオキシエチレン)を表し、或いは、R10は、5から30のエチレンオキシド単位を含むポリオキシエチレン化基を表す)のアクリレート、
b)1以上のケイ素原子を含むエチレン性不飽和モノマー、例えば、
メタクリルオキシプロピルトリメトキシシラン及びメタクリルオキシプロピルトリス(トリメチルシロキシ)シラン、
及び、
− これらの混合物。
− 重合溶媒の一部を適切な反応器に導入して重合に適当な温度(典型的には60から120℃)に達するまで加熱する、
− 前記温度に到達すると、重合開始剤の存在下で、前記第1のブロックの構成モノマーを導入する、
− 90%の最大転換度に相当する時間Tの後に、前記第2のブロックの構成モノマー及び重合開始剤の残りを導入する、
− この混合物をT'時間(3から6時間)の間反応させ、その後、混合物を室温へ冷却する、
− 前記重合溶媒に溶解しているポリマーを得る。
第1の態様では、本発明のポリマーは、a)において既述したような、40℃以上のTgを有する第1のブロックを含み、且つ、b)において既述したような、20℃以下のTgを有する第2のブロックを含む。
−例えば70から110℃の範囲のTgを有する、メチルメタクリレート/アクリル酸コポリマーである、40℃以上のTgを有する第1のブロック;
−例えば0から20℃の範囲のTgを有する、メチルアクリレートホモポリマーである、20℃以下のTgを有する第2のブロック;及び
−メチルメタクリレート/アクリル酸/メチルアクリレートコポリマーである中間ブロック
を含みうる。
−例えば70から100℃の範囲のTgを有する、メチルメタクリレート/アクリル酸/トリフルオロエチルメタクリレートコポリマーである、40℃以上のTgを有する第1のブロック;
−例えば0から20℃の範囲のTgを有する、メチルアクリレートホモポリマーである、20℃以下のTgを有する第2のブロック;及び
−メチルメタクリレート/アクリル酸/メチルアクリレート/トリフルオロエチルメタクリレートランダムコポリマーである中間ブロック
を含みうる。
−例えば0から20℃の範囲のTgを有する、イソボルニルアクリレート/イソブチルメタクリレートコポリマーである、40℃以上のTgを有する第1のブロック;
−例えば−85から−55℃の範囲のTgを有する、2−エチルヘキシルアクリレートホモポリマーである、20℃以下のTgを有する第2のブロック;及び
−イソボルニルアクリレート/イソブチルメタクリレート/2−エチルヘキシルアクリレートランダムコポリマーである中間ブロック
を含みうる。
−例えば85から115℃の範囲のTgを有する、イソボルニルアクリレート/メチルメタクリレートコポリマーである、40℃以上のTgを有する第1のブロック;
−例えば−85から−55℃の範囲のTgを有する、2−エチルヘキシルアクリレートホモポリマーである、20℃以下のTgを有する第2のブロック;及び
−イソボルニルアクリレート/メチルメタクリレート/2−エチルヘキシルアクリレートランダムコポリマーである中間ブロック
を含みうる。
−例えば95から125℃の範囲のTgを有する、イソボルニルアクリレート/イソボルニルメタクリレートコポリマーである、40℃以上のTgを有する第1のブロック;
−例えば−85から−55℃の範囲のTgを有する、2−エチルヘキシルアクリレートホモポリマーである、20℃以下のTgを有する第2のブロック;及び
−イソボルニルアクリレート/イソボルニルメタクリレート/2−エチルヘキシルアクリレートランダムコポリマーである中間ブロック
を含みうる。
−例えば85から115℃の範囲のTgを有する、イソボルニルメタクリレート/イソブチルメタクリレートコポリマーである、40℃以上のTgを有する第1のブロック;
−例えば−35から−5℃の範囲のTgを有する、イソブチルアクリレートホモポリマーである、20℃以下のTgを有する第2のブロック;及び
−イソボルニルメタクリレート/イソブチルメタクリレート/イソブチルアクリレートランダムコポリマーである中間ブロック
を含みうる。
−例えば95から125℃の範囲のTgを有する、イソボルニルアクリレート/イソボルニルメタクリレートコポリマーである、40℃以上のTgを有する第1のブロック;
−例えば−35から−5℃の範囲のTgを有する、イソブチルアクリレートホモポリマーである、20℃以下のTgを有する第2のブロック;及び
−イソボルニルアクリレート/イソボルニルメタクリレート/イソブチルアクリレートランダムコポリマーである中間ブロック
を含みうる。
−例えば60から90℃の範囲のTgを有する、イソボルニルアクリレート/イソブチルメタクリレートコポリマーである、40℃以上のTgを有する第1のブロック;
−例えば−35から−5℃の範囲のTgを有する、イソブチルアクリレートホモポリマーである、20℃以下のTgを有する第2のブロック;及び
−イソボルニルアクリレート/イソブチルメタクリレート/イソブチルアクリレートランダムコポリマーである中間ブロック
を含みうる。
第2の態様では、本発明のポリマーは、c)において既述したブロックに従う、20℃から40℃の間のTgを有する第1のブロックを含み、且つ、b)において既述したような、20℃以下のTgを有する、又は、a)において既述したような、40℃以上のTgを有する、第2のブロックを含む。
−例えば25から39℃の範囲のTgを有する、少なくとも1つのメチルアクリレートモノマー、少なくとも1つのメチルメタクリレートモノマー及び少なくとも1つのアクリル酸モノマーを含むコポリマーである、20℃から40℃の間のTgを有する第1のブロック;
−例えば85から125℃の範囲の、40℃以上のTgを有する、メチルメタクリレートモノマーからなるホモポリマーである第2のブロック;
−少なくとも1つのメチルアクリレート、メチルメタクリレートモノマーを含む中間ブロック、及び、
−メチルメタクリレート、少なくとも1つのアクリル酸モノマー及び少なくとも1つのメチルアクリレートモノマーを含む中間ブロック
を含みうる。
−例えば21から39℃の範囲のTgを有する、イソボルニルアクリレート/イソブチルメタクリレート/2−エチルヘキシルアクリレートを含むコポリマーである、20から40℃の間のTgを有する第1のブロック;
−例えば−65℃から−35℃の範囲の、20℃以下のTgを有する、メチルメタクリレートホモポリマーである、第2のブロック;及び
−イソボルニルアクリレート/イソブチルメタクリレート/2−エチルヘキシルアクリレートランダムコポリマーである中間ブロック
を含みうる。
−例えば21から39℃の範囲のTgを有する、イソボルニルアクリレート/メチルアクリレート/アクリル酸コポリマーである、20から40℃の間のTgを有する第1のブロック;
−例えば85から115℃の範囲のTgを有する、イソボルニルアクリレートホモポリマーである、40℃以上のTgを有する第2のブロック;及び
−イソボルニルアクリレート/メチルアクリレート/アクリル酸ランダムコポリマーである中間ブロック
を含みうる。
ペルヒドロスクアレン等の動物起源の炭化水素油;
例えばヘプタン酸又はオクタン酸といった4から10の炭素原子の脂肪酸の液体トリグリセリド、或いは、向日葵油、トウモロコシ油、大豆油、葡萄種油、胡麻種油、アプリコット油、マカダミア油、ひまし油、アボガド油、カプリル/カプリン酸トリグリセリド、ホホバ油、カリテバター等の植物起源の炭化水素油;
液体パラフィン及びその誘導体、石油ゼリー、ポリデセン、パーリーム等の水素化ポリイソブテン等の鉱物又は合成起源の直鎖又は分岐炭化水素;
特に脂肪酸の、合成エステル又はエーテル、例えば、パーセリン油、イソプロピルミリステート、2−エチルヘキシルパルミテート、2−オクチルドデシルステアレート、2−オクチルドデシルエルケート、イソステアリルイソステアレート;
ヒドロキシル化エステル、例えば、イソステアリルラクテート、オクチルヒドロキシステアレート、オクチルドデシルヒドロキシステアレート、ジイソステアリルマレート、トリイソセチルシトレート及び脂肪アルコールのヘプタノエート、オクタノエート及びデカノエート;
ポリオールエステル、例えば、プロピレングリコールジオクタノエート、ネオペンチルグリコールジヘプタノエート、及び、ジエチレングリコールジイソノナノエート、並びに、ペンタエリトリトールエステル;
12から26の炭素原子を含む脂肪アルコール、例えば、オクチルドデカノール、2−ブチルオクタノール、2−ヘキシルデカノール、2−ウンデシルペンタデカノール及びオレイルアルコール;
部分的に炭化水素ベースのフルオロ油及び/又はフルオロシリコーン油;
シリコーン油、例えば、揮発性又は不揮発性の、室温で液体又はペースト状の、線状又は環状ポリジメチルシロキサン(PDMSs)、例えば、任意にフェニル基を含む、シクロメチコーン、ジメチコーン、例えば、フェニルトリメチコーン、フェニルトリメチルシロキシジフェニルシロキサン、ジフェニルメチルジメチルトリシロキサン、ジフェニルジメチコーン、フェニルジメチコーン、及び、ポリメチルフェニルシロキサン;及び
これらの混合物。
下記の組成を有するマニキュアが調製された。
下記の組成を有するマニキュアが調製された。
下記の組成を有するマスカラが調製された。
パラフィンワックス 3g
カルナウバワックス 6g
ジステアリルジメチルベンジルアンモニウムクロライドで変性されたヘクトライト(Elementis社からのBentone(登録商標)38V) 5.3g
プロピレンカーボネート 1.7g
フィラー 1g
顔料 5g
実施例4のポリマー 活性成分で12g
イソドデカン 全量が100gとなる量
下記の組成を有するマスカラが調製された。
パラフィンワックス 3g
カルナウバワックス 6g
ジステアリルジメチルベンジルアンモニウムクロライドで変性されたヘクトライト(Elementis社からのBentone(登録商標)38V) 5.3g
プロピレンカーボネート 1.7g
フィラー 1g
顔料 5g
実施例7のポリマー 活性成分で12g
イソドデカン 全量が100gとなる量
下記の組成を有する口紅が調製された。
実施例5のポリマー 活性成分で15%
水素化ポリイソブテン(日本油脂(株)からのパーリーム) 26%
顔料 8.6%
イソドデカン 全量が100gとなる量
下記の化合物を含むファンデーションが調製された。
イソステアリルジグリセリルスクシネート(Condea社のImwitor 780K)0.6g
イソドデカン 18.5g
顔料混合物(疎水性酸化チタン及び酸化鉄) 10g
実施例5のポリマー 活性成分で8.7g
ポリアミド粉末(Dupont de Nemours社のNylon-12) 8g
香料 0.5g
相B 水 全量が100gとなる量
硫酸マグネシウム 0.7g
保存剤(メチルパラベン) 0.2g
相C 水 2g
保存剤(ジアゾリルウレア) 0.25g
酢酸ブチル 24.99g
イソプロパノール 10.71g
へキシレングリコール 2.5g
DCレッド7レーキ 1g
ステアリルジメチルベンジルアンモニウムクロライドで変性されたヘクトライト(Elementis社からのBentone(登録商標)27V) 1.3g
酢酸エチル 全量が100gとなる量
パラフィンワックス 3g
カルナウバワックス 6g
ジステアリルジメチルベンジルアンモニウムクロライドで変性されたヘクトライト(Elementis社からのBentone(登録商標)38V) 5.3g
プロピレンカーボネート 1.7g
フィラー 1g
顔料 5g
実施例14のポリマー 活性成分で12g
イソドデカン 全量が100gとなる量
実施例13のポリマー 活性成分で10%
水素化ポリイソブテン(日本油脂(株)からのパーリーム) 26%
顔料 8.6%
イソドデカン 全量が100gとなる量
イソステアリルジグリセリルスクシネート(Condea社のImwitor 780K)0.6g
イソドデカン 18.5g
顔料混合物(疎水性酸化チタン及び酸化鉄) 10g
実施例15のポリマー 活性成分で8.7g
ポリアミド粉末(Dupont de Nemours社のNylon-12) 8g
香料 0.5g
相B 水 全量が100gとなる量
硫酸マグネシウム 0.7g
保存剤(メチルパラベン) 0.2g
相C 水 2g
保存剤(ジアゾリルウレア) 0.25g
イソステアリルジグリセリルスクシネート(Condea社のImwitor 780K)0.6g
シクロペンタジメチルシロキサン 6g
イソドデカン 全量が100gとなる量
顔料混合物(疎水性酸化チタン及び酸化鉄) 10g
実施例4のポリマー 活性成分で2.1g
ポリアミド粉末(Dupont de Nemours社のNylon-12) 8g
相B 水 41.4g
硫酸マグネシウム 0.7g
保存剤 0.3g
イソステアリルジグリセリルスクシネート(Condea社のImwitor 780K)0.6g
シクロペンタジメチルシロキサン 6g
イソドデカン 全量が100gとなる量
顔料混合物(疎水性酸化チタン及び酸化鉄) 10g
実施例10のポリマー 活性成分で2.1g
ポリアミド粉末(Dupont de Nemours社のNylon-12) 8g
相B 水 41.4g
硫酸マグネシウム 0.7g
保存剤 0.3g
Claims (16)
- 40℃以上のガラス転移温度(Tg)を有し、
イソボルニル(メタ)アクリレートから全て又は部分的に誘導される、少なくとも第1のブロックと、
20℃以下(但し、20℃を除く)のTgを有し、
C1−C10アルキル(tert−ブチル基を除く)アクリレートから選択されるモノマーから全て又は部分的に誘導される、少なくとも第2のブロックとを含み、
前記第1及び第2のブロックは、互いに非混和性で、前記第1のブロックの少なくとも1つの構成モノマーと前記第2のブロックの少なくとも1つの構成モノマーとを含むランダムポリマーである中間セグメントを介して一緒に連結されており、
2より大きい多分散性指標Iを有するポリマー。 - 前記第2のブロックのモノマーが、メチルアクリレート、イソブチルアクリレート及び2−エチルヘキシルアクリレート、及び、これらの混合物から選択される、請求項1記載のポリマー。
- 前記第2のブロックのモノマーが、イソブチルアクリレートである、請求項1又は2記載のポリマー。
- 前記第1のブロックが60〜120℃の範囲のTgを有する、請求項1乃至3のいずれかに記載のポリマー。
- 前記第2のブロックが−50〜0℃の範囲のTgを有する、請求項1乃至4のいずれかに記載のポリマー。
- 前記第1のブロックが85〜115℃の範囲のTgを有する、請求項1乃至3のいずれかに記載のポリマー。
- 前記第1のブロックが95〜125℃の範囲のTgを有する、請求項1乃至3のいずれかに記載のポリマー。
- 前記第1のブロックが60〜90℃の範囲のTgを有する、請求項1乃至3のいずれかに記載のポリマー。
- 前記第2のブロックが−35〜−5℃の範囲のTgを有する、請求項6乃至8のいずれかに記載のポリマー。
- 前記ポリマーが、
(i)40℃以上のTgを有する、イソボルニルメタクリレート/イソブチルメタクリレートコポリマーである第1のブロック、
20℃以下(但し、20℃を除く)のTgを有する、イソブチルアクリレートホモポリマーである第2のブロック、及び
イソボルニルメタクリレート/イソブチルメタクリレート/イソブチルアクリレートランダムコポリマーである、中間セグメント
を含むブロックポリマー
(ii)40℃以上のTgを有する、イソボルニルアクリレート/イソボルニルメタクリレートコポリマーである第1のブロック、
20℃以下(但し、20℃を除く)のTgを有する、イソブチルアクリレートホモポリマーである第2のブロック、及び
イソボルニルアクリレート/イソボルニルメタクリレート/イソブチルアクリレートランダムコポリマーである、中間セグメント
を含むブロックポリマー、及び
(iii)40℃以上のTgを有する、イソボルニルアクリレート/イソブチルメタクリレートコポリマーである第1のブロック、
20℃以下(但し、20℃を除く)のTgを有する、イソブチルアクリレートホモポリマーである第2のブロック、及び
イソボルニルアクリレート/イソブチルメタクリレート/イソブチルアクリレートランダムコポリマーである、中間セグメント
を含むブロックポリマー
から選択される、請求項1乃至9のいずれかに記載のポリマー。 - 前記第1のブロック及び/又は前記第2のブロックが、アクリル酸、メタクリル酸、クロトン酸、無水マレイン酸、イタコン酸、フマル酸、マレイン酸、アクリルアミドプロパンスルホン酸、ビニル安息香酸、ビニルリン酸及びこれらの塩から選択される他のモノマーを含む、請求項1乃至10のいずれかに記載のポリマー。
- 前記第1のブロックがイソブチル(メタ)アクリレートを含む、請求項1乃至11のいずれかに記載のポリマー。
- 請求項1乃至12のいずれかに記載のポリマーを含む化粧品組成物。
- 前記ポリマーの含有量が0.1から60重量%である、請求項13記載の化粧品組成物。
- 請求項1乃至12のいずれかに記載のポリマーを化粧品組成物に配合することを特徴とする、化粧品組成物の保持力改善方法。
- 請求項1乃至12のいずれかに記載のポリマーからなる、化粧品用保持力改善剤。
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JP4069778B2 (ja) | 2003-03-25 | 2008-04-02 | セイコーエプソン株式会社 | 端子電極の製造方法および半導体装置の製造方法 |
FR2860156B1 (fr) | 2003-09-26 | 2007-11-02 | Oreal | Composition cosmetique comprenant un agent tenseur et un polymere ethylenique sequence particulier |
FR2860143B1 (fr) | 2003-09-26 | 2008-06-27 | Oreal | Composition cosmetique comprenant un polymere sequence et une huile siliconee non volatile |
FR2860142B1 (fr) | 2003-09-26 | 2007-08-17 | Oreal | Produit cosmetique bicouche, ses utilisations et kit de maquillage contenant ce produit |
FR2864894A1 (fr) | 2004-01-13 | 2005-07-15 | Oreal | Composition de revetement des fibres keratiniques ayant un extrait sec eleve comprenant un polymere sequence et des fibres |
FR2864896B1 (fr) | 2004-01-13 | 2006-03-31 | Oreal | Composition de revetement des fibres keratiniques comprenant un polymere sequence et un polymere semi-cristallin |
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US8728451B2 (en) | 2004-03-25 | 2014-05-20 | L'oreal | Styling composition comprising, in a predominantly aqueous medium, a pseudo-block polymer, processes employing same and uses thereof |
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FR2871057B1 (fr) | 2004-06-08 | 2006-07-28 | Oreal | Composition cosmetique contenant un ester et un agent filmogene |
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FR2904218B1 (fr) | 2006-07-27 | 2012-10-05 | Oreal | Composition cosmetique associant un copolymere, une huile non volatile et une huile brillante. |
FR2904320B1 (fr) | 2006-07-27 | 2008-09-05 | Oreal | Polymeres sequences, et leur procede de preparation |
GB0922457D0 (en) | 2009-12-23 | 2010-02-03 | Parry Mark | GPS enabled software that appraises surfing performance on a mobile device |
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2003
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- 2003-09-26 PT PT03292382T patent/PT1411069E/pt unknown
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- 2003-09-26 DE DE60334765T patent/DE60334765D1/de not_active Expired - Lifetime
- 2003-09-26 KR KR1020030066795A patent/KR100587242B1/ko active IP Right Grant
- 2003-09-26 CN CN031649661A patent/CN1504488B/zh not_active Expired - Lifetime
- 2003-09-26 JP JP2003336449A patent/JP4790976B2/ja not_active Expired - Lifetime
- 2003-09-26 US US10/670,478 patent/US7803877B2/en not_active Expired - Lifetime
- 2003-09-26 BR BRPI0303891-2A patent/BR0303891B1/pt active IP Right Grant
- 2003-09-26 AT AT03292382T patent/ATE486581T1/de active
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- 2007-09-21 US US11/859,004 patent/US20080014158A1/en not_active Abandoned
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Publication number | Publication date |
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KR20040027429A (ko) | 2004-04-01 |
US20080014158A1 (en) | 2008-01-17 |
ATE486581T1 (de) | 2010-11-15 |
KR100587242B1 (ko) | 2006-06-07 |
CN1504488B (zh) | 2010-06-09 |
JP2004149772A (ja) | 2004-05-27 |
EP1411069A2 (fr) | 2004-04-21 |
BR0303891B1 (pt) | 2014-06-17 |
JP4790976B2 (ja) | 2011-10-12 |
JP2008069362A (ja) | 2008-03-27 |
BR0303891A (pt) | 2004-09-08 |
US7932324B2 (en) | 2011-04-26 |
MXPA03008714A (es) | 2004-09-10 |
US20040120920A1 (en) | 2004-06-24 |
EP1411069B1 (fr) | 2010-11-03 |
DE60334765D1 (de) | 2010-12-16 |
PT1411069E (pt) | 2011-01-11 |
US20080014235A1 (en) | 2008-01-17 |
EP1411069A3 (fr) | 2004-07-14 |
CN1504488A (zh) | 2004-06-16 |
US20080014234A1 (en) | 2008-01-17 |
US7915347B2 (en) | 2011-03-29 |
US7803877B2 (en) | 2010-09-28 |
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