JP4986398B2 - いわゆるクアンタム・バッテリに電気エネルギーを蓄積する新しい方法 - Google Patents
いわゆるクアンタム・バッテリに電気エネルギーを蓄積する新しい方法 Download PDFInfo
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- H01G4/002—Details
- H01G4/018—Dielectrics
- H01G4/20—Dielectrics using combinations of dielectrics from more than one of groups H01G4/02 - H01G4/06
- H01G4/206—Dielectrics using combinations of dielectrics from more than one of groups H01G4/02 - H01G4/06 inorganic and synthetic material
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- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/26—Electrodes characterised by their structure, e.g. multi-layered, porosity or surface features
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/46—Metal oxides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
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- H—ELECTRICITY
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L28/00—Passive two-terminal components without a potential-jump or surface barrier for integrated circuits; Details thereof; Multistep manufacturing processes therefor
- H01L28/40—Capacitors
- H01L28/60—Electrodes
- H01L28/82—Electrodes with an enlarged surface, e.g. formed by texturisation
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/43—Electric condenser making
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/43—Electric condenser making
- Y10T29/435—Solid dielectric type
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
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- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Fixed Capacitors And Capacitor Manufacturing Machines (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Ceramic Capacitors (AREA)
- Semiconductor Memories (AREA)
Description
この蓄電デバイスは固定電源から独立しており、したがって、主として化石燃料の代替エネルギーとなることを目指した移動交通(道路、列車、船及び航空機)用の電気駆動装置に電力を供給する目的に利用される。抵抗損のないこの高密度蓄電技術はさらに、一般家庭に対するエネルギー供給への用途、及び太陽エネルギー利用技術によって得たエネルギーの運搬を可能にする。この特殊な材料はさらに、新しいタイプの電子構成部品の製造を可能にする。電気的に蓄積されたこのエネルギーの極めて速い、損失のない放電は、このデバイスを爆発物として使用することすら可能にする。
従来のバッテリ及びコンデンサに電気エネルギーを蓄積するときの高い比重量は、移動交通に利用するときの主要な欠点の1つである。一方、はるかに有利な化石燃料における化学エネルギーの直接的な蓄積及びその利用のし易さは、取り戻すことができない天然資源の容認できない浪費へとつながった。さらに、例えば鉛蓄電池における電気エネルギーの技術的蓄積及び放電は高い抵抗と結び付いており、この高い抵抗は、充電及び放電速度を強力に制限する高い熱損失をもたらす。現時点で使用可能な「スーパー・コンデンサ」は異なる物理原理で動作している。これらのスーパー・コンデンサは低電圧でしか動作せず、機械的な衝撃に敏感であり、ある高い抵抗を示し、数桁低いエネルギー密度及び出力密度を有する。
1.4.1.利点
この新しいデバイスでは、化学エネルギーとして化石燃料に蓄積できるエネルギーと同じ程度の密度で電気エネルギーを直接に蓄積することができる。この新しい蓄電デバイスの特殊な材料はほぼ無限回の充電及び放電サイクルが可能であり、この材料は摩耗しない。動作中、この蓄電デバイスは抵抗による損失を示さない。このデバイスは機械的衝撃、過度の加速及び極端な温度に耐える。さらに、空間内にどのように配置しても動作には影響しない。
本発明は、絶縁マトリックス、例えばSiO2又はポリマー樹脂の中に埋め込まれた、強い電界の応力下にあり、かつ臨界電圧条件(充電条件)にあるTiO2(強い電気陰性)などの強い双極子結晶材料からなる非常に小さな粒子が、仮想光子共振(新しい量子物理効果)によって導電性(半導体)となり、したがってエネルギーを受け取る物理効果に基づく。このエネルギーは通常の平板コンデンサと同様の方法で蓄えられる。この蓄電デバイスは数ボルトから数千ボルトの電圧に対するものを構築することができる。その蓄電容量は、最大限可能な物理的、機械的に大きさによってのみ制限される。
粉砕してnmサイズの粒子とした、又はnm厚さの層としたTiO2、SrTiO3などの蓄電結晶を、絶縁媒質とともに担体表面に塗布する。結晶のタイプに関しては特定の必要条件があり、大部分が「ルチル」型であることが必須条件である。
Claims (6)
- 電気絶縁材料内で、共振励起され、結晶性の、化学的に双極子のナノ粒子中に電気的エネルギーを蓄積するスーパー・コンデンサ又はクアンタム・バッテリを製造するための方法であって、
ポリマー樹脂とナノ粒子を混ぜて、混合物を得て、
予備成形された複合フィルムであって、絶縁された金属箔を含んでなる該複合フィルムを準備し、
前記混合物を前記複合フィルム上に静電噴霧によって塗布して、被覆されたフィルムを得て、それによって、前記金属箔は対電極として作用し、そして前記静電噴霧は電場を生じ、そして、
容量効果とともに前記電場によって生じる表面力によって、幾何学的に正確な層とフィールド整列している前記ナノ粒子を形成し、
熱又は放射硬化させることを含み、
前記ナノ粒子がルチル型であるTiO 2 又はSrTiO 3 から構成される、上記方法。 - 前記被覆フィルムを切断して複数のフィルムを得て、成形して多層コンデンサとすることを更に含む、請求項1に記載の方法。
- 電気絶縁材料によって分離された、共振励起され、結晶性の、化学的に双極子のナノ粒子中に電気的エネルギーを蓄積するスーパー・コンデンサ又はクアンタム・バッテリを製造するための方法であって、
キャリアー表面を準備し、
ナノ粒子の層及び絶縁材料の層を、前記表面上に化学的又は物理的蒸着によって、交互に付着させて、前記層が互いに重なり合っているサンドイッチ構造を得て、
ルチル型の結晶相を得るために、前記サンドイッチ構造を800℃超の温度でアニーリングすることを含み、前記層は異なる熱膨張係数による層間はく離を生じることがなく、 前記絶縁材料がSiO 2 であり、前記ナノ粒子がTiO 2 又はSrTiO 3 から構成される、上記方法。 - コンデンサが平板コンデンサとして形成されているか、或いは平板コンデンサである、請求項1〜2のいずれか一項に記載の方法。
- コンデンサが巻き容量として形成されているか、或いは巻きコンデンサである、請求項1〜2のいずれか一項に記載の方法。
- 前記ナノ粒子がナノ結晶であるように選択されている、請求項1〜3のいずれか一項に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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CH1130/02 | 2002-07-01 | ||
CH11302002 | 2002-07-01 | ||
PCT/CH2003/000423 WO2004004026A2 (de) | 2002-07-01 | 2003-06-26 | Verfahren zur herstellung von superkondensatoren |
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JP2010015505A Division JP2010093306A (ja) | 2002-07-01 | 2010-01-27 | いわゆるクアンタム・バッテリに電気エネルギーを蓄積する新しい方法 |
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JP2005531922A JP2005531922A (ja) | 2005-10-20 |
JP4986398B2 true JP4986398B2 (ja) | 2012-07-25 |
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JP2004516408A Expired - Fee Related JP4986398B2 (ja) | 2002-07-01 | 2003-06-26 | いわゆるクアンタム・バッテリに電気エネルギーを蓄積する新しい方法 |
JP2010015505A Pending JP2010093306A (ja) | 2002-07-01 | 2010-01-27 | いわゆるクアンタム・バッテリに電気エネルギーを蓄積する新しい方法 |
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US (2) | US20060164788A1 (ja) |
EP (1) | EP1522082A2 (ja) |
JP (2) | JP4986398B2 (ja) |
CN (1) | CN1679123B (ja) |
AU (1) | AU2003240363A1 (ja) |
CA (1) | CA2491552A1 (ja) |
RU (1) | RU2357313C2 (ja) |
WO (1) | WO2004004026A2 (ja) |
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CN210041358U (zh) * | 2018-03-02 | 2020-02-07 | 意法半导体有限公司 | 电池充电***和移动设备 |
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BR112021003870A2 (pt) | 2018-08-31 | 2021-05-18 | Innophos, Inc. | modulador botânico de transtornos metabólicos |
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AU2001274857A1 (en) * | 2000-05-18 | 2001-12-03 | Georgia Tech Research Corporation | High dielectric constant nano-structure polymer-ceramic composite |
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CN1679123B (zh) | 2010-04-28 |
RU2005102398A (ru) | 2005-08-20 |
CA2491552A1 (en) | 2004-01-08 |
US20060164788A1 (en) | 2006-07-27 |
AU2003240363A1 (en) | 2004-01-19 |
AU2003240363A8 (en) | 2004-01-19 |
EP1522082A2 (de) | 2005-04-13 |
RU2357313C2 (ru) | 2009-05-27 |
US20080016681A1 (en) | 2008-01-24 |
CN1679123A (zh) | 2005-10-05 |
JP2005531922A (ja) | 2005-10-20 |
US7895721B2 (en) | 2011-03-01 |
JP2010093306A (ja) | 2010-04-22 |
WO2004004026A3 (de) | 2004-03-25 |
WO2004004026A2 (de) | 2004-01-08 |
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