JP4942935B2 - ゼロに近い排出で酸性気体および汚染物質を除去する構成および方法 - Google Patents
ゼロに近い排出で酸性気体および汚染物質を除去する構成および方法 Download PDFInfo
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- JP4942935B2 JP4942935B2 JP2004563175A JP2004563175A JP4942935B2 JP 4942935 B2 JP4942935 B2 JP 4942935B2 JP 2004563175 A JP2004563175 A JP 2004563175A JP 2004563175 A JP2004563175 A JP 2004563175A JP 4942935 B2 JP4942935 B2 JP 4942935B2
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1487—Removing organic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1406—Multiple stage absorption
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1462—Removing mixtures of hydrogen sulfide and carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
- B01D53/8612—Hydrogen sulfide
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
- C01B17/0408—Pretreatment of the hydrogen sulfide containing gases
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
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- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Gas Separation By Absorption (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Description
Claims (7)
- 二酸化炭素、硫化水素及びメルカプタンを含む供給気体を処理する方法であって、
生成物気体(12)、少なくとも硫化水素の一部及び二酸化炭素の一部を含む第1の底部生成物(13)、及びメルカプタンを含む第2の底部生成物(10)を生成するために、供給気体(5)及び二酸化炭素飽和リーンソルベントの第1の部分(11)を、第1の吸収装置(103)に供給するステップと、
リーンソルベントの第2の部分(6)を供給気体(5)に接触させると共に、リーンソルベントの第1の部分(14)を第1の吸収装置(103)の生成物気体(12)に接触させ、生成物気体(12)とリーンソルベントの第1の部分(14)とが混合した流れを気液分離して得られた液体(17)である二酸化炭素飽和リーンソルベントを分割して、二酸化炭素飽和リーンソルベントの第1の部分(11)及び二酸化炭素飽和リーンソルベントの第2の部分(25)を形成するステップと、
硫化水素リッチ底部生成物(23)及び二酸化炭素含有気体(44)を生成するために、第1の底部生成物(13)から得られる蒸気の部分(24)及び二酸化炭素飽和リーンソルベントの第2の部分(25)を第2の吸収装置(110)に供給するステップと、
硫化水素含有気体(29)及びリーンソルベント(28)を生成するために、第1の吸収装置(103)からの第2の底部生成物(10)及び第2の吸収装置(110)からの硫化水素リッチ底部生成物(23)を、再生装置(113)に供給するステップとを備えている、前記方法。 - 第1の底部生成物(13)が、リーンソルベント(28)からの熱含有量を使用する熱交換器で減圧及び加熱される、請求項1に記載の方法。
- 減圧された第1の底部生成物(19)が、摂氏116度から摂氏135度(華氏240度から華氏275度)の間の温度に加熱される、請求項2に記載の方法。
- 再生装置(113)からの硫化水素含有気体(29)が、硫黄生成物(37)及び排ガスを生成する硫黄設備(122)に供給される、請求項1に記載の方法。
- 排ガスが再循環気体(39)を生成するように水素化され、又、再循環気体(39)が供給気体(5)と混合される、請求項4に記載の方法。
- 再生装置(113)からの硫化水素含有気体(29)が冷却され、冷却された硫化水素含有気体(30)から蒸気流(32)及び炭化水素流(35)が分離される、請求項1に記載の方法。
- 蒸気流(32)が、吸収装置(118)においてストリッピング気体として使用される、請求項6に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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US43435802P | 2002-12-17 | 2002-12-17 | |
US60/434,358 | 2002-12-17 | ||
PCT/US2003/004376 WO2004058384A1 (en) | 2002-12-17 | 2003-02-12 | Configurations and methods for acid gas and contaminant removal with near zero emission |
Publications (2)
Publication Number | Publication Date |
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JP2006509628A JP2006509628A (ja) | 2006-03-23 |
JP4942935B2 true JP4942935B2 (ja) | 2012-05-30 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2004563175A Expired - Fee Related JP4942935B2 (ja) | 2002-12-17 | 2003-02-12 | ゼロに近い排出で酸性気体および汚染物質を除去する構成および方法 |
Country Status (10)
Country | Link |
---|---|
US (1) | US7597746B2 (ja) |
EP (1) | EP1572324B1 (ja) |
JP (1) | JP4942935B2 (ja) |
CN (1) | CN100563789C (ja) |
AU (1) | AU2003211033B2 (ja) |
CA (1) | CA2503656C (ja) |
EA (1) | EA010169B1 (ja) |
ES (1) | ES2392712T3 (ja) |
MX (1) | MXPA05006242A (ja) |
WO (1) | WO2004058384A1 (ja) |
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JPS5263171A (en) * | 1975-11-18 | 1977-05-25 | Basf Ag | Method of removing co2 and*or h2s and*or cos from gas containing thereof |
JPH02120394A (ja) * | 1988-09-26 | 1990-05-08 | Inst Fr Petrole | 天然ガスの凝縮物の脱水、脱酸および分離方法 |
JPH0848984A (ja) * | 1994-07-08 | 1996-02-20 | Inst Fr Petrole | 高濃度の酸性ガスの製造のためにガスを脱酸する方法 |
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US3989811A (en) * | 1975-01-30 | 1976-11-02 | Shell Oil Company | Process for recovering sulfur from fuel gases containing hydrogen sulfide, carbon dioxide, and carbonyl sulfide |
US4080424A (en) * | 1976-02-11 | 1978-03-21 | Institute Of Gas Technology | Process for acid gas removal from gaseous mixtures |
US4138230A (en) * | 1977-07-05 | 1979-02-06 | Uop Inc. | Dual pressure absorption process |
DE2909335A1 (de) * | 1979-03-09 | 1980-09-18 | Linde Ag | Verfahren und vorrichtung zur zerlegung von erdgas |
US4242108A (en) * | 1979-11-07 | 1980-12-30 | Air Products And Chemicals, Inc. | Hydrogen sulfide concentrator for acid gas removal systems |
NL8001886A (nl) * | 1980-03-31 | 1981-11-02 | Shell Int Research | Werkwijze voor het verwijderen van zure gassen uit een in hoofdzaak uit methaan bestaand gasmengsel. |
DE3047830A1 (de) * | 1980-12-18 | 1982-07-15 | Linde Ag, 6200 Wiesbaden | Verfahren zum reinigen eines gasstromes |
US5240476A (en) * | 1988-11-03 | 1993-08-31 | Air Products And Chemicals, Inc. | Process for sulfur removal and recovery from a power generation plant using physical solvent |
GB8830199D0 (en) * | 1988-12-23 | 1989-02-22 | Shell Int Research | Removing hydrogen sulphide from a gas mixture |
WO1993010883A1 (en) * | 1991-11-27 | 1993-06-10 | Exxon Research And Engineering Company | Lean acid gas enrichment with selective hindered amines |
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2003
- 2003-02-12 WO PCT/US2003/004376 patent/WO2004058384A1/en active Application Filing
- 2003-02-12 ES ES03814002T patent/ES2392712T3/es not_active Expired - Lifetime
- 2003-02-12 JP JP2004563175A patent/JP4942935B2/ja not_active Expired - Fee Related
- 2003-02-12 EP EP03814002A patent/EP1572324B1/en not_active Expired - Lifetime
- 2003-02-12 MX MXPA05006242A patent/MXPA05006242A/es active IP Right Grant
- 2003-02-12 AU AU2003211033A patent/AU2003211033B2/en not_active Ceased
- 2003-02-12 US US10/532,262 patent/US7597746B2/en not_active Expired - Fee Related
- 2003-02-12 CA CA2503656A patent/CA2503656C/en not_active Expired - Fee Related
- 2003-02-12 EA EA200500983A patent/EA010169B1/ru not_active IP Right Cessation
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS5015785A (ja) * | 1973-05-10 | 1975-02-19 | ||
JPS5263171A (en) * | 1975-11-18 | 1977-05-25 | Basf Ag | Method of removing co2 and*or h2s and*or cos from gas containing thereof |
JPH02120394A (ja) * | 1988-09-26 | 1990-05-08 | Inst Fr Petrole | 天然ガスの凝縮物の脱水、脱酸および分離方法 |
JPH0848984A (ja) * | 1994-07-08 | 1996-02-20 | Inst Fr Petrole | 高濃度の酸性ガスの製造のためにガスを脱酸する方法 |
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US7597746B2 (en) | 2009-10-06 |
WO2004058384A1 (en) | 2004-07-15 |
EA010169B1 (ru) | 2008-06-30 |
CN1713948A (zh) | 2005-12-28 |
ES2392712T3 (es) | 2012-12-13 |
AU2003211033A1 (en) | 2004-07-22 |
EA200500983A1 (ru) | 2005-12-29 |
CA2503656C (en) | 2010-10-05 |
JP2006509628A (ja) | 2006-03-23 |
EP1572324A4 (en) | 2006-11-02 |
MXPA05006242A (es) | 2005-08-19 |
CA2503656A1 (en) | 2004-07-15 |
EP1572324A1 (en) | 2005-09-14 |
AU2003211033B2 (en) | 2008-10-09 |
EP1572324B1 (en) | 2012-08-15 |
CN100563789C (zh) | 2009-12-02 |
US20060150812A1 (en) | 2006-07-13 |
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