JP4879499B2 - 漂白剤組成物 - Google Patents
漂白剤組成物 Download PDFInfo
- Publication number
- JP4879499B2 JP4879499B2 JP2005079423A JP2005079423A JP4879499B2 JP 4879499 B2 JP4879499 B2 JP 4879499B2 JP 2005079423 A JP2005079423 A JP 2005079423A JP 2005079423 A JP2005079423 A JP 2005079423A JP 4879499 B2 JP4879499 B2 JP 4879499B2
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- JP
- Japan
- Prior art keywords
- acid
- bleaching
- mass
- foam
- bleach
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 50
- 239000007844 bleaching agent Substances 0.000 title claims description 32
- 239000006260 foam Substances 0.000 claims description 44
- 238000004061 bleaching Methods 0.000 claims description 42
- 125000004432 carbon atom Chemical group C* 0.000 claims description 33
- -1 olefin sulfonate Chemical class 0.000 claims description 23
- 125000000217 alkyl group Chemical group 0.000 claims description 16
- 239000002736 nonionic surfactant Substances 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 12
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- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 10
- 150000001408 amides Chemical class 0.000 claims description 9
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 150000001412 amines Chemical class 0.000 claims description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 4
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 4
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- 238000011049 filling Methods 0.000 claims description 3
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- 150000004996 alkyl benzenes Chemical class 0.000 claims 1
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- 125000002947 alkylene group Chemical group 0.000 description 6
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- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
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- 239000005642 Oleic acid Substances 0.000 description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
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- ZMJBYMUCKBYSCP-UHFFFAOYSA-N (+)-Erythro-hydroxycitric acid Natural products OC(=O)C(O)C(O)(C(O)=O)CC(O)=O ZMJBYMUCKBYSCP-UHFFFAOYSA-N 0.000 description 2
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- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 2
- CAERUOHSFJZTJD-UHFFFAOYSA-N 4-dodecanoyloxybenzenesulfonic acid Chemical compound CCCCCCCCCCCC(=O)OC1=CC=C(S(O)(=O)=O)C=C1 CAERUOHSFJZTJD-UHFFFAOYSA-N 0.000 description 2
- VNEUMNOZRFLRPI-UHFFFAOYSA-N 4-nonanoyloxybenzenesulfonic acid Chemical compound CCCCCCCCC(=O)OC1=CC=C(S(O)(=O)=O)C=C1 VNEUMNOZRFLRPI-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
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- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
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- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
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- 229910052737 gold Inorganic materials 0.000 description 1
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- 229960002154 guar gum Drugs 0.000 description 1
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- 238000011086 high cleaning Methods 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- GTTBQSNGUYHPNK-UHFFFAOYSA-N hydroxymethylphosphonic acid Chemical compound OCP(O)(O)=O GTTBQSNGUYHPNK-UHFFFAOYSA-N 0.000 description 1
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- 238000005342 ion exchange Methods 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
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- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
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Description
本発明の漂白剤組成物は、(a)成分として、使い勝手の良い漂白基剤である、過酸化水素を含有する。(a)成分の含有量は、優れた漂白性能を得るために、0.1〜6質量%、好ましくは、0.3〜6質量%、更に好ましくは、0.5〜5質量%である。
〔式中、R1aは炭素数10〜16、好ましくは10〜14の炭化水素基、より好ましくは10〜14のアルキル基であり、R1bはエチレン基又はプロピレン基、好ましくはエチレン基であり、Tは−O−、−COO−、−CON<、−N<から選ばれる基であり、w、vは本発明のHLBの範囲に入るように選ばれる。vはTが−O−、又は−COO−の場合には1の数であり、Tが−CON<、又は−N<の場合には2の数であり、Tが−O−、又は−COO−の場合にはwは4〜16、好ましくは5〜14、より好ましくは6〜10が好ましく、Tが−CON<、又は−N<の場合にはwは2〜8、好ましくは2〜7、より好ましくは3〜6が好適である。〕
〔式中、R2aは炭素数10〜14のアルキル基を示す。uは4〜12、好ましくは5〜10、特に好ましくは6〜8.5の数である。〕
R2b−O−[(C2H4O)t/(C3H6O)s]−H (2−2)
〔式中、R2bは炭素数10〜14のアルキル基を示す。t及びsはそれぞれ独立に2〜12の数であり、t+sは4〜12、好ましくは5〜10の数である。また、エチレンオキシド(C2H4O)とプロピレンオキシド(C3H6O)はランダムあるいはブロック付加体であってもよい。〕
R3a−CON−R3b(R3COH) (3)
〔式中、R3a−CO−は、炭素数8〜18の炭化水素基を有するアシル基、R3bは、メチル基又はエチル基、R3cは、炭素数1〜3のアルキレン基又はアルケニレン基である。〕
漂白剤組成物(2.50g)のイオン交換水20倍希釈液50gを200mlトールビーカー(55mm)に入れ、特殊機化工業(株)製ホモミキサー(TOKUSHUKIKA ROBO MICS No.011002)(攪拌部は、直径3cmの4枚羽根であって、筒状金属(高さ3×直径3.5cm)で覆われている)を用いて6000rpmで5分間攪拌する。その後、直ちに、400倍で顕微鏡観察した。得られた画像を画像解析し、平均粒子径を得た。
本発明の漂白剤組成物は、泡形成機構を有するトリガー式スプレーヤーを用いて泡を汚れに直接作用させることで、優れた洗浄漂白効果が得られる。このため、漂白対象に泡状で作用させることが好ましく、泡形成機構を有するトリガー式スプレーヤーを具備する容器に充填してなる容器入りの漂白剤製品として用いることがより好ましい。
以下の実施例、比較例で用いた成分は以下の通りである。これらを用いて表1の液体漂白剤組成物を調製し、以下の評価を行った。結果を表1に示す。また、液体漂白剤組成物のpH、気泡の平均粒径、粘度も表1に示した。
・b−1;直鎖アルキル(炭素数11〜15)ベンゼンスルホン酸ナトリウム
・b−2;α−オレフィン(炭素数14〜18)スルホン酸ナトリウム
・b−3;α−スルホ脂肪酸エステルナトリウム(炭素数14〜16のα−スルホ脂肪酸と炭素数1のアルコールのエステルのナトリウム塩)
・c−1;ポリオキシエチレンラウリルエーテル(オキシエチレン平均付加モル数7、HLB12.1)
・d−1;N−エタノール−N−メチルオクタン酸アミド
・d−2;ラルリルジメチルアミンオキサイド
・d−3;ラウリン酸アミドプロピルヒドロキシスルホベタイン
・金属イオン封鎖剤;1−ヒドロキシエチリデン−1,1−ジホスホン酸(デイクエスト2010(ソルーシア社製デイクエスト))
・e−1;イオン交換水
200mlのプラスティック製メスシリンダー(内径40mm)に、市販トリガー容器(花王(株)社製アタック シュッと泡スプレー/製造ロット番号:W1410474、1回のストロークで0.8g噴射する。中身を抜いて水で数回洗浄し、乾燥させたものに組成物を充填し使用。)を用いて表1の液体漂白剤組成物を10回スプレーし、その時の組成物の質量と泡の容積から、以下の計算式(1−1)から起泡性(ml/g)を算出した。スプレー直後及び5分後の起泡性の値から、以下の計算式(1−2)により泡安定性(%)を算出した。
起泡性(ml/g)=泡体積(ml)/組成物質量(g) (1−1)
泡安定性(%)=〔5分後の起泡性(ml/g)/直後の起泡性(ml/g)〕×100 (1−2)
表1の漂白剤組成物(2.50g)のイオン交換水20倍希釈液50gを200mlトールビーカー(55mm)に入れ、特殊機化工業(株)製ホモミキサー(TOKUSHUKIKA ROBO MICS No.011002)(攪拌部は、直径3cmの4枚羽根であって、筒状金属(高さ3×直径3.5cm)で覆われている)を用いて6000rpmで5分間攪拌する。その後、直ちに、400倍で顕微鏡観察した。得られた画像を画像解析し、平均粒子径を得た。この平均粒径を表1に示す。
上記(1)で用いたトリガー容器に各組成物を充填したものを用いて、下記で調製したミートソース汚染布4枚にそれぞれ1回ずつ噴霧し組成物を泡状で塗布した。その際、塗布した泡のクリーミーさを10名のパネラーにより以下の基準の評価点で判定し、その結果を表1に示した。結果は平均点で表示した。
5:泡が非常にきめ細かく、白い
4:泡がきめ細かく、やや白い
3:普通
2:泡が粗く、あまり白くない
1:泡が非常に粗く、ほとんど白くない
カゴメ(製)ミートソース(完熟トマトのミートソース/内容量259gの缶詰/製造ロット番号:D3611JI)の固形分をメッシュ(目開き;500μm)で除去した後、得られた液を煮沸するまで加熱した。この液に木綿金布#2003を浸し、約15分間煮沸した。そのまま火からおろし約2時間程度放置し室温まで放置した後、布を取りだし、余分に付着しているミートソース液をへらで除去し、自然乾燥させた。その後プレスし、10cm×10cmの試験布として実験に供した。
Claims (9)
- (a)過酸化水素0.1〜6質量%、(b)スルホン酸基含有界面活性剤0.1〜2質量%、(c)HLBが10〜15の非イオン界面活性剤、(d)アルカノールアマイド、アミンオキサイド、及びベタインから選ばれる1種以上の界面活性剤0.1〜3質量%、並びに(e)水を含有し、質量比で(b)/(d)=0.5〜5、かつ(c)/(d)=0.5〜5であり、20℃における粘度が1〜10mPa・sである漂白剤組成物。
- 前記(b)スルホン酸基含有界面活性剤が、アルキルベンゼンスルホン酸塩、オレフィンスルホン酸塩、及びα−スルホ脂肪酸エステル塩から選ばれる1種類以上の界面活性剤である請求項1記載の漂白剤組成物。
- 前記(c)HLBが10〜15の非イオン界面活性剤が、下記一般式(2−1)の化合物及び下記一般式(2−2)の化合物から選ばれる1種以上である請求項1又は2記載の漂白剤組成物。
R 2a −O−(C 2 H 4 O) u −H (2−1)
〔式中、R 2a は炭素数10〜14のアルキル基を示す。uは4〜12の数である。〕
R 2b −O−[(C 2 H 4 O) t /(C 3 H 6 O) s ]−H (2−2)
〔式中、R 2b は炭素数10〜14のアルキル基を示す。t及びsはそれぞれ独立に2〜12の数であり、t+sは4〜12の数である。また、エチレンオキシド(C 2 H 4 O)とプロピレンオキシド(C 3 H 6 O)はランダムあるいはブロック付加体であってもよい。〕 - 前記(c)HLBが10〜15の非イオン界面活性剤を、0.1〜20質量%含有する請求項1〜3の何れか1項記載の漂白剤組成物。
- 泡形成機構を有するトリガー式スプレーヤーを具備する容器に充填して使用される請求項1〜4の何れか1項記載の漂白剤組成物。
- 請求項1〜5の何れか1項記載の漂白剤組成物を、泡形成機構を有するトリガー式スプレーヤーを具備する容器に充填してなる、漂白剤製品。
- 請求項1〜5の何れか1項記載の漂白剤組成物を、泡形成機構を有するトリガー式スプレーヤーを用いて漂白対象に泡状に付着させる漂白方法。
- 泡の付着量が0.1〜1g/cm 2 である請求項7記載の漂白方法。
- 泡を付着させた後、5〜60分間放置する請求項7又は8記載の漂白方法。
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