JP4504306B2 - 顔料インク用インクジェット記録材料 - Google Patents
顔料インク用インクジェット記録材料 Download PDFInfo
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- JP4504306B2 JP4504306B2 JP2005352175A JP2005352175A JP4504306B2 JP 4504306 B2 JP4504306 B2 JP 4504306B2 JP 2005352175 A JP2005352175 A JP 2005352175A JP 2005352175 A JP2005352175 A JP 2005352175A JP 4504306 B2 JP4504306 B2 JP 4504306B2
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- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 description 1
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- JGDITNMASUZKPW-UHFFFAOYSA-K aluminium trichloride hexahydrate Chemical compound O.O.O.O.O.O.Cl[Al](Cl)Cl JGDITNMASUZKPW-UHFFFAOYSA-K 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
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- ZZPAXHDZFDUTLY-UHFFFAOYSA-L ammonium nickel sulfate hexahydrate Chemical compound N.N.O.O.O.O.O.O.[Ni+2].OS([O-])(=O)=O.OS([O-])(=O)=O ZZPAXHDZFDUTLY-UHFFFAOYSA-L 0.000 description 1
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- 229910052788 barium Inorganic materials 0.000 description 1
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- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
- 239000001639 calcium acetate Substances 0.000 description 1
- 229960005147 calcium acetate Drugs 0.000 description 1
- 235000011092 calcium acetate Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229960002713 calcium chloride Drugs 0.000 description 1
- 235000011148 calcium chloride Nutrition 0.000 description 1
- 239000004281 calcium formate Substances 0.000 description 1
- 229940044172 calcium formate Drugs 0.000 description 1
- 235000019255 calcium formate Nutrition 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 229940095672 calcium sulfate Drugs 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- 150000001767 cationic compounds Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229920006319 cationized starch Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- OIDPCXKPHYRNKH-UHFFFAOYSA-J chrome alum Chemical compound [K]OS(=O)(=O)O[Cr]1OS(=O)(=O)O1 OIDPCXKPHYRNKH-UHFFFAOYSA-J 0.000 description 1
- WYYQVWLEPYFFLP-UHFFFAOYSA-K chromium(3+);triacetate Chemical compound [Cr+3].CC([O-])=O.CC([O-])=O.CC([O-])=O WYYQVWLEPYFFLP-UHFFFAOYSA-K 0.000 description 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
- 229910000152 cobalt phosphate Inorganic materials 0.000 description 1
- 229910000361 cobalt sulfate Inorganic materials 0.000 description 1
- 229940044175 cobalt sulfate Drugs 0.000 description 1
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 1
- INDBQWVYFLTCFF-UHFFFAOYSA-L cobalt(2+);dithiocyanate Chemical compound [Co+2].[S-]C#N.[S-]C#N INDBQWVYFLTCFF-UHFFFAOYSA-L 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 229960003280 cupric chloride Drugs 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- SFQOCJXNHZJOJN-UHFFFAOYSA-H dialuminum;dioxido-oxo-sulfanylidene-$l^{6}-sulfane Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=S.[O-]S([O-])(=O)=S.[O-]S([O-])(=O)=S SFQOCJXNHZJOJN-UHFFFAOYSA-H 0.000 description 1
- KFCWRPFNNIEZRY-UHFFFAOYSA-H dialuminum;trisulfate;nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O KFCWRPFNNIEZRY-UHFFFAOYSA-H 0.000 description 1
- YDIQKOIXOOOXQQ-UHFFFAOYSA-H dialuminum;trisulfite Chemical compound [Al+3].[Al+3].[O-]S([O-])=O.[O-]S([O-])=O.[O-]S([O-])=O YDIQKOIXOOOXQQ-UHFFFAOYSA-H 0.000 description 1
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 1
- JGHYBJVUQGTEEB-UHFFFAOYSA-M dimethylalumanylium;chloride Chemical compound C[Al](C)Cl JGHYBJVUQGTEEB-UHFFFAOYSA-M 0.000 description 1
- 150000002012 dioxanes Chemical class 0.000 description 1
- 208000028659 discharge Diseases 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- AFOSIXZFDONLBT-UHFFFAOYSA-N divinyl sulfone Chemical compound C=CS(=O)(=O)C=C AFOSIXZFDONLBT-UHFFFAOYSA-N 0.000 description 1
- 238000000635 electron micrograph Methods 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 229940032296 ferric chloride Drugs 0.000 description 1
- 229940046149 ferrous bromide Drugs 0.000 description 1
- 229960002089 ferrous chloride Drugs 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical group O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- FMXLGOWFNZLJQK-UHFFFAOYSA-N hypochlorous acid;zirconium Chemical compound [Zr].ClO FMXLGOWFNZLJQK-UHFFFAOYSA-N 0.000 description 1
- OOCSVLHOTKHEFZ-UHFFFAOYSA-N icosanamide Chemical compound CCCCCCCCCCCCCCCCCCCC(N)=O OOCSVLHOTKHEFZ-UHFFFAOYSA-N 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 1
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
- GYCHYNMREWYSKH-UHFFFAOYSA-L iron(ii) bromide Chemical compound [Fe+2].[Br-].[Br-] GYCHYNMREWYSKH-UHFFFAOYSA-L 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 229940050906 magnesium chloride hexahydrate Drugs 0.000 description 1
- DHRRIBDTHFBPNG-UHFFFAOYSA-L magnesium dichloride hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-] DHRRIBDTHFBPNG-UHFFFAOYSA-L 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 229960003390 magnesium sulfate Drugs 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 229940071125 manganese acetate Drugs 0.000 description 1
- 239000011565 manganese chloride Substances 0.000 description 1
- 235000002867 manganese chloride Nutrition 0.000 description 1
- 229940099607 manganese chloride Drugs 0.000 description 1
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 1
- SQWDGUOWCZUSAO-UHFFFAOYSA-L manganese(2+);diformate;dihydrate Chemical compound O.O.[Mn+2].[O-]C=O.[O-]C=O SQWDGUOWCZUSAO-UHFFFAOYSA-L 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000005055 methyl trichlorosilane Substances 0.000 description 1
- YSTQWZZQKCCBAY-UHFFFAOYSA-L methylaluminum(2+);dichloride Chemical compound C[Al](Cl)Cl YSTQWZZQKCCBAY-UHFFFAOYSA-L 0.000 description 1
- JLUFWMXJHAVVNN-UHFFFAOYSA-N methyltrichlorosilane Chemical compound C[Si](Cl)(Cl)Cl JLUFWMXJHAVVNN-UHFFFAOYSA-N 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- ZAKLKBFCSHJIRI-UHFFFAOYSA-N mucochloric acid Natural products OC1OC(=O)C(Cl)=C1Cl ZAKLKBFCSHJIRI-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229940078487 nickel acetate tetrahydrate Drugs 0.000 description 1
- LAIZPRYFQUWUBN-UHFFFAOYSA-L nickel chloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].[Cl-].[Ni+2] LAIZPRYFQUWUBN-UHFFFAOYSA-L 0.000 description 1
- RRIWRJBSCGCBID-UHFFFAOYSA-L nickel sulfate hexahydrate Chemical compound O.O.O.O.O.O.[Ni+2].[O-]S([O-])(=O)=O RRIWRJBSCGCBID-UHFFFAOYSA-L 0.000 description 1
- 229940116202 nickel sulfate hexahydrate Drugs 0.000 description 1
- OINIXPNQKAZCRL-UHFFFAOYSA-L nickel(2+);diacetate;tetrahydrate Chemical compound O.O.O.O.[Ni+2].CC([O-])=O.CC([O-])=O OINIXPNQKAZCRL-UHFFFAOYSA-L 0.000 description 1
- TXRHHNYLWVQULI-UHFFFAOYSA-L nickel(2+);disulfamate;tetrahydrate Chemical compound O.O.O.O.[Ni+2].NS([O-])(=O)=O.NS([O-])(=O)=O TXRHHNYLWVQULI-UHFFFAOYSA-L 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000013054 paper strength agent Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229940044652 phenolsulfonate Drugs 0.000 description 1
- BCTWNMTZAXVEJL-UHFFFAOYSA-N phosphane;tungsten;tetracontahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.P.[W].[W].[W].[W].[W].[W].[W].[W].[W].[W].[W].[W] BCTWNMTZAXVEJL-UHFFFAOYSA-N 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000013055 pulp slurry Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229940032330 sulfuric acid Drugs 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- IYQJAGXFXWIEJE-UHFFFAOYSA-H trimagnesium;2-hydroxypropane-1,2,3-tricarboxylate;nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Mg+2].[Mg+2].[Mg+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O IYQJAGXFXWIEJE-UHFFFAOYSA-H 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 238000010947 wet-dispersion method Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229940102001 zinc bromide Drugs 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229940118827 zinc phenolsulfonate Drugs 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- BOVNWDGXGNVNQD-UHFFFAOYSA-L zinc;2-hydroxybenzenesulfonate Chemical compound [Zn+2].OC1=CC=CC=C1S([O-])(=O)=O.OC1=CC=CC=C1S([O-])(=O)=O BOVNWDGXGNVNQD-UHFFFAOYSA-L 0.000 description 1
- 150000003755 zirconium compounds Chemical class 0.000 description 1
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1
- LJQSESUEJXAKBR-UHFFFAOYSA-J zirconium(4+) tetrachloride octahydrate Chemical compound O.O.O.O.O.O.O.O.[Cl-].[Cl-].[Cl-].[Cl-].[Zr+4] LJQSESUEJXAKBR-UHFFFAOYSA-J 0.000 description 1
- ZXAUZSQITFJWPS-UHFFFAOYSA-J zirconium(4+);disulfate Chemical compound [Zr+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZXAUZSQITFJWPS-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
Landscapes
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Ink Jet (AREA)
Description
1)基紙の両面をポリオレフィン樹脂層で被覆した樹脂被覆支持体上に、下層として平均二次粒子径が500nm以下の無機微粒子と樹脂バインダーを主体に含有するインク受容層、上層として単分散性のコロイダルシリカと水溶性多価金属化合物を主体に含有する光沢付与層を設けたインクジェット記録材料において、光沢付与層に含有されるコロイダルシリカの固形分塗布量が0.02〜0.5g/m2であり、光沢付与層におけるコロイダルシリカ(C)と水溶性多価金属化合物(M)の固形分混合比(C/M)が1/8〜1/1であり、光沢付与層においてコロイダルシリカに対してバインダーを10質量%以上含有しないことを特徴とする顔料インク用インクジェット記録材料。
広葉樹晒クラフトパルプ(LBKP)と広葉樹晒サルファイトパルプ(LBSP)の1:1混合物をカナディアン スタンダード フリーネスで300mlになるまで叩解し、パルプスラリーを調製した。これにサイズ剤とアルキルケテンダイマーを対パルプ0.5質量%、強度剤としてポリアクリルアミドを対パルプ1質量%、カチオン化澱粉を対パルプ2質量%、ポリアミドエピクロロヒドリン樹脂を対パルプ0.5質量%添加し、水で希釈して1%スラリーとした。このスラリーを長網抄紙機で坪量170g/m2になるように抄造し、乾燥調湿して支持体の基紙とした。抄造した基紙の印字面側に密度0.918g/cm3の低密度ポリエチレン100質量%の樹脂に対して、10質量%のアナターゼ型チタンを均一に分散したポリエチレン樹脂組成物を320℃で溶融し、200m/分で厚さ30μmになるように押出し、微粗面加工されたクーリングロールで冷却しながら、インク受容層塗布面側の樹脂被覆層を設けた。反対面側には密度0.962g/cm3の高密度ポリエチレン樹脂70質量部と密度0.918g/cm3の低密度ポリエチレン樹脂30質量部のブレンド樹脂組成物を同様に320℃で溶融し、厚さ25μmになるようにクーリングロールで冷却しながら樹脂被覆層を設けた。
石灰処理ゼラチン 100部
スルフォコハク酸−2−エチルヘキシルエステル塩 2部
クロム明ばん 10部
水にジメチルアルミニウムクロライドポリマー(分子量:9000)3部と気相法シリカ(平均一次粒径7nm、比表面積300m2/g)100部を添加し予備分散液を作製した後、高圧ホモジナイザーで処理して、固形分濃度20質量%の気相法シリカ分散液を作製した。
気相法シリカ分散液 103部
ホウ酸 5部
ポリビニルアルコール 23部
(ケン化度88%、平均重合度3500)
固形分濃度が12質量%になるように水で調整した。
クォートロンPL−3L 100部
(扶桑化学工業株式会社製単分散コロイダルシリカ、平均一次粒子径40nm、変動係数0.11)
ZA−30 400部
(第一希元素化学工業(株)社製酢酸ジルコニル)
固形分濃度が2.5質量%になるように水で調整した。
水にジメチルジアリルアンモニウムクロライドホモポリマー(分子量9,000、4部)と沈降法シリカ(ニップシールVN3、平均二次粒径23μm、100部)を添加し、のこぎり歯状ブレード型分散機(ブレード周速30m/秒)を使用して予備分散液を作成した。次に得られた予備分散物をビーズミルに、直径0.3mmのジルコニアビーズ、充填率80容量%、円盤周速10m/秒の条件で1回通過させて、固形分濃度30質量%、平均二次粒径200nmの湿式法シリカ分散液を得た。
湿式法シリカ分散液 104部
ほう酸 4部
ポリビニルアルコール 17部
(ケン化度88%、平均重合度3500)
固形分濃度が12質量%になるように水で調整した。
アルミナ水和物 100部
(SASOL社製のDisperal.HP−14、平均二次粒径160nm)
硝酸 1.4部
ホウ酸 0.2部
ポリビニルアルコール 9.5部
(ケン化度88%、平均重合度3500)
固形分濃度が15質量%になるように水で調整した。
クォートロンPL−3L 100部
(扶桑化学工業株式会社製単分散コロイダルシリカ、平均一次粒子径35nm、変動係数0.11)
ピュラケムWT 400部
((株)理研グリーン社製メチルアルミニウムクロライドポリマー)
固形分濃度が2.5質量%になるように水で調整した。
クォートロンPL−2L 100部
(扶桑化学工業株式会社製単分散コロイダルシリカ、平均一次粒子径19nm、変動係数0.11)
ZA−30 400部
(第一希元素化学工業(株)社製酢酸ジルコニル)
クォートロンPL−3L 100部
(扶桑化学工業株式会社製単分散コロイダルシリカ、平均一次粒子径35nm、変動係数0.11)
ZA−30 400部
(第一希元素化学工業(株)社製酢酸ジルコニル)
ポリビニルアルコール 4部
(ケン化度88%、平均重合度3500)
固形分濃度が2.5質量%になるように水で調整した。
光沢付与層1を塗布しないこと以外は、実施例1と同様にすることで比較例1の記録材料を作製した。なお、電子顕微鏡観察による気相法シリカの平均二次粒子径は80nmであった。
実施例1の光沢付与層1の固形分量を0.05g/m2(コロイダルシリカ固形分量 0.01g/m2)になるようにする以外は実施例1と同様にすることで比較例2の記録材料を作製した。
実施例1の光沢付与層1の固形分量を3.5g/m2 (コロイダルシリカ固形分量 0.7g/m2)になるようにする以外は実施例1と同様にすることで比較例3の記録材料を作製した。その結果、インク受容層と光沢付与層との接着性が十分でなく、評価するに値する品質を得ることができなかった。
実施例1の光沢付与層1を光沢付与層5に変更すること以外は、実施例1と同様にすることで比較例4の記録材料を作製した(コロイダルシリカの固形分量 0.1g/m2)。なお、電子顕微鏡観察による気相法シリカの平均二次粒子径は80nmであった。
PL−3L 100部
(扶桑化学工業株式会社製単分散コロイダルシリカ、平均一次粒子径35nm、変動係数0.11)
固形分濃度が0.5質量%になるように水で調整した。
実施例1の光沢付与層1を光沢付与層6に変更すること以外は、実施例1と同様にすることで比較例5の記録材料を作製した(コロイダルシリカの固形分量 0.1g/m2)。なお、電子顕微鏡観察による気相法シリカの平均二次粒子径は80nmであった。その結果、インク受容層と光沢付与層との接着性が十分でなく、評価するに値する品質を得ることができなかった。
ST−OL40 100部
(日産化学工業社製多分散コロイダルシリカ、平均一次粒子径43nm、変動係数0.20)
ZA−30 400部
(第一希元素化学工業(株)社製酢酸ジルコニル)
固形分濃度が2.5質量%になるように水で調整した。
実施例1の光沢付与層1を光沢付与層7に変更すること以外は、実施例1と同様にすることで比較例6の記録材料を作製した(コロイダルシリカの固形分量 0.1g/m2)。なお、電子顕微鏡観察による気相法シリカの平均二次粒子径は80nmであった。
クォートロンPL−3L 100部
(扶桑化学工業株式会社製単分散コロイダルシリカ、平均一次粒子径35nm、変動係数0.11)
ZA−30 400部
(第一希元素化学工業(株)社製酢酸ジルコニル)
ポリビニルアルコール 15部
(ケン化度88%、平均重合度3500)
固形分濃度が2.5質量%になるように水で調整した。
実施例1の光沢付与層1を光沢付与層8に変更すること以外は、実施例1と同様にすることで比較例7の記録材料を作製した(コロイダルシリカの固形分量 0.1g/m2)。なお、電子顕微鏡観察による気相法シリカの平均二次粒子径は80nmであった。その結果、インク受容層と光沢付与層との接着性が十分でなく、評価するに値する品質を得ることができなかった。
ST−OZL 100部
(日産化学工業社製多分散コロイダルシリカ、平均一次粒子径80nm、変動係数0.31)
ZA−30 400部
(第一希元素化学工業(株)社製酢酸ジルコニル)
固形分濃度が2.5質量%になるように水で調整した。
実施例1の光沢付与層1を光沢付与層9に変更すること以外は、実施例1と同様にすることで比較例7の記録材料を作製した(コロイダルシリカの固形分量 0.1g/m2)。なお、電子顕微鏡観察による気相法シリカの平均二次粒子径は80nmであった。その結果、インク受容層と光沢付与層との接着性が十分でなく、評価するに値する品質を得ることができなかった。
ST−AKL 100部
(日産化学工業社製多分散コロイダルシリカ、平均一次粒子径45nm、変動係数0.26)
ZA−30 400部
(第一希元素化学工業(株)社製酢酸ジルコニル)
固形分濃度が2.5質量%になるように水で調整した。
顔料インク用インクジェットプリンター(セイコーエプソン(株)社製PX−G900)を用いて、Blueの最大インク吐出量でベタ印字を50枚連続で行い、ギザローラが通過した画像部を目視評価した。
○:顔料インクの剥離なし。
△:顔料インクの剥離がわずかにある。
×:顔料インクの剥離があり。
××:顔料インクの剥離が激しい。
JIS−Z8741に基づいて20度光沢度を変角光沢計VGS−300A(日本電色(株)製)で測定した。
○:40%より高い。
△:30〜40%。
×:30%より低い。
得られたインクジェット記録材料について、塗布面の光沢ムラを目視で観察した。
○:問題なし。
△:若干ムラあり。
×:ムラが目立つ。
Claims (1)
- 基紙の両面をポリオレフィン樹脂層で被覆した樹脂被覆支持体上に、下層として平均二次粒子径が500nm以下の無機微粒子と樹脂バインダーを主体に含有するインク受容層、上層として単分散性のコロイダルシリカと水溶性多価金属化合物を主体に含有する光沢付与層を設けたインクジェット記録材料において、光沢付与層に含有されるコロイダルシリカの固形分塗布量が0.02〜0.5g/m2であり、光沢付与層におけるコロイダルシリカ(C)と水溶性多価金属化合物(M)の固形分混合比(C/M)が1/8〜1/1であり、光沢付与層においてコロイダルシリカに対してバインダーを10質量%以上含有しないことを特徴とする顔料インク用インクジェット記録材料。
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2000141992A (ja) * | 1998-11-13 | 2000-05-23 | Dainippon Printing Co Ltd | 曲面印刷用転写フィルムおよびその製造方法 |
JP2001341412A (ja) * | 2000-03-27 | 2001-12-11 | Oji Paper Co Ltd | インクジェット記録体 |
JP2005161836A (ja) * | 2003-11-10 | 2005-06-23 | Mitsubishi Paper Mills Ltd | インクジェット記録媒体の製造方法 |
JP2005231094A (ja) * | 2004-02-18 | 2005-09-02 | Mitsubishi Paper Mills Ltd | インクジェット記録材料およびその製造方法 |
JP2005254611A (ja) * | 2004-03-11 | 2005-09-22 | Mitsubishi Paper Mills Ltd | 顔料インク用インクジェット記録用紙 |
JP2005280095A (ja) * | 2004-03-30 | 2005-10-13 | Mitsubishi Paper Mills Ltd | インクジェット記録用紙 |
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Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000141992A (ja) * | 1998-11-13 | 2000-05-23 | Dainippon Printing Co Ltd | 曲面印刷用転写フィルムおよびその製造方法 |
JP2001341412A (ja) * | 2000-03-27 | 2001-12-11 | Oji Paper Co Ltd | インクジェット記録体 |
JP2005161836A (ja) * | 2003-11-10 | 2005-06-23 | Mitsubishi Paper Mills Ltd | インクジェット記録媒体の製造方法 |
JP2005231094A (ja) * | 2004-02-18 | 2005-09-02 | Mitsubishi Paper Mills Ltd | インクジェット記録材料およびその製造方法 |
JP2005254611A (ja) * | 2004-03-11 | 2005-09-22 | Mitsubishi Paper Mills Ltd | 顔料インク用インクジェット記録用紙 |
JP2005280095A (ja) * | 2004-03-30 | 2005-10-13 | Mitsubishi Paper Mills Ltd | インクジェット記録用紙 |
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