JP4500564B2 - ベニバナ赤色素とその精製方法 - Google Patents
ベニバナ赤色素とその精製方法 Download PDFInfo
- Publication number
- JP4500564B2 JP4500564B2 JP2004065739A JP2004065739A JP4500564B2 JP 4500564 B2 JP4500564 B2 JP 4500564B2 JP 2004065739 A JP2004065739 A JP 2004065739A JP 2004065739 A JP2004065739 A JP 2004065739A JP 4500564 B2 JP4500564 B2 JP 4500564B2
- Authority
- JP
- Japan
- Prior art keywords
- red pigment
- resin
- safflower red
- safflower
- adsorbed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 235000003255 Carthamus tinctorius Nutrition 0.000 title claims description 42
- 244000020518 Carthamus tinctorius Species 0.000 title claims description 42
- 239000001054 red pigment Substances 0.000 title claims description 34
- 238000000034 method Methods 0.000 title claims description 20
- 238000000746 purification Methods 0.000 title description 9
- 229920005989 resin Polymers 0.000 claims description 27
- 239000011347 resin Substances 0.000 claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 239000007864 aqueous solution Substances 0.000 claims description 17
- 239000000243 solution Substances 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 11
- 239000002952 polymeric resin Substances 0.000 claims description 8
- 229920003002 synthetic resin Polymers 0.000 claims description 8
- 239000003960 organic solvent Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 230000002378 acidificating effect Effects 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 5
- 239000000975 dye Substances 0.000 claims 2
- 239000004793 Polystyrene Substances 0.000 claims 1
- 229920002223 polystyrene Polymers 0.000 claims 1
- 239000001044 red dye Substances 0.000 claims 1
- WLYGSPLCNKYESI-RSUQVHIMSA-N Carthamin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1[C@@]1(O)C(O)=C(C(=O)\C=C\C=2C=CC(O)=CC=2)C(=O)C(\C=C\2C([C@](O)([C@H]3[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O3)O)C(O)=C(C(=O)\C=C\C=3C=CC(O)=CC=3)C/2=O)=O)=C1O WLYGSPLCNKYESI-RSUQVHIMSA-N 0.000 description 25
- DYQVDISPPLTLLR-HJQYTNQXSA-N Carthamin Natural products CC[C@H]1O[C@H]([C@H](O)[C@@H](O)[C@@H]1O)[C@]2(O)C(=C(C=C/3C(=O)C(=C(O)[C@](O)([C@@H]4O[C@H](CO)[C@@H](O)[C@H](O)[C@H]4O)C3=O)C(=O)C=Cc5ccc(O)cc5)C(=O)C(=C2O)C(=O)C=Cc6ccc(O)cc6)O DYQVDISPPLTLLR-HJQYTNQXSA-N 0.000 description 25
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 15
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 15
- 239000001913 cellulose Substances 0.000 description 13
- 235000010980 cellulose Nutrition 0.000 description 12
- 229920002678 cellulose Polymers 0.000 description 12
- 239000007788 liquid Substances 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 6
- 239000004744 fabric Substances 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000012670 alkaline solution Substances 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- 239000011259 mixed solution Substances 0.000 description 3
- 229910000027 potassium carbonate Inorganic materials 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 229920001429 chelating resin Polymers 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 235000013373 food additive Nutrition 0.000 description 2
- 239000002778 food additive Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000001052 yellow pigment Substances 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 238000012812 general test Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 235000019814 powdered cellulose Nutrition 0.000 description 1
- 229920003124 powdered cellulose Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000001062 red colorant Substances 0.000 description 1
- KINGXFAMZNIVNL-SXQDSXCISA-N safflor yellow A Natural products OC[C@@H]1O[C@H]2[C@H](OC3=C2C(=O)C(=C(O)C=Cc4ccc(O)cc4)C(=O)[C@]3(O)[C@@H]5O[C@H](CO)[C@@H](O)[C@H](O)[C@H]5O)[C@@H](O)[C@H]1O KINGXFAMZNIVNL-SXQDSXCISA-N 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
Claims (1)
- ベニバナ赤色素をアルカリ性水溶液に溶解して抽出処理した後、ポリスチレン系の多孔性重合樹脂に色素を吸着してベニバナ赤色素を精製する方法において、
前記樹脂に色素を吸着させる際、前記樹脂の存在下で色素アルカリ性水溶液を撹拌しつつ酸を添加して混合液をpH2〜6にすることによりベニバナ赤色素を前記樹脂に吸着させ、
次いでベニバナ赤色素を吸着した前記樹脂をカラムに充填して水および/または酸性水溶液で洗浄後、含水有機溶媒で処理してベニバナ赤色素を溶出することを特徴とするベニバナ赤色素の精製方法。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004065739A JP4500564B2 (ja) | 2004-03-09 | 2004-03-09 | ベニバナ赤色素とその精製方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004065739A JP4500564B2 (ja) | 2004-03-09 | 2004-03-09 | ベニバナ赤色素とその精製方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2005255719A JP2005255719A (ja) | 2005-09-22 |
JP4500564B2 true JP4500564B2 (ja) | 2010-07-14 |
Family
ID=35081784
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004065739A Expired - Lifetime JP4500564B2 (ja) | 2004-03-09 | 2004-03-09 | ベニバナ赤色素とその精製方法 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP4500564B2 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112521769A (zh) * | 2020-11-25 | 2021-03-19 | 清华大学 | 一种红花红色素及其制备方法和染色方法 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105906596B (zh) * | 2016-05-04 | 2018-06-01 | 浙江大学 | 一种红花黄色素的精制工艺 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6253375A (ja) * | 1985-08-30 | 1987-03-09 | Nisshin Oil Mills Ltd:The | カルサミンの抽出・分離方法 |
JPH02145657A (ja) * | 1988-11-28 | 1990-06-05 | T Hasegawa Co Ltd | カーサミンの抽出方法 |
JPH05302038A (ja) * | 1992-04-28 | 1993-11-16 | Toyo Ink Mfg Co Ltd | カルタミン類色素の精製法 |
JP2000095963A (ja) * | 1998-09-21 | 2000-04-04 | Toyo Ink Mfg Co Ltd | カルタミン塩の製造方法 |
JP2000095962A (ja) * | 1998-09-22 | 2000-04-04 | Seiichi Yahagi | 紅花の赤色色素抽出方法及びその方法により作られた着色料 |
-
2004
- 2004-03-09 JP JP2004065739A patent/JP4500564B2/ja not_active Expired - Lifetime
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6253375A (ja) * | 1985-08-30 | 1987-03-09 | Nisshin Oil Mills Ltd:The | カルサミンの抽出・分離方法 |
JPH02145657A (ja) * | 1988-11-28 | 1990-06-05 | T Hasegawa Co Ltd | カーサミンの抽出方法 |
JPH05302038A (ja) * | 1992-04-28 | 1993-11-16 | Toyo Ink Mfg Co Ltd | カルタミン類色素の精製法 |
JP2000095963A (ja) * | 1998-09-21 | 2000-04-04 | Toyo Ink Mfg Co Ltd | カルタミン塩の製造方法 |
JP2000095962A (ja) * | 1998-09-22 | 2000-04-04 | Seiichi Yahagi | 紅花の赤色色素抽出方法及びその方法により作られた着色料 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112521769A (zh) * | 2020-11-25 | 2021-03-19 | 清华大学 | 一种红花红色素及其制备方法和染色方法 |
Also Published As
Publication number | Publication date |
---|---|
JP2005255719A (ja) | 2005-09-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPS5828246A (ja) | ステビオサイドの製造方法 | |
CN105294467B (zh) | 一种从发酵液中提取饲料级缬氨酸的工艺 | |
CN107383115A (zh) | 提取植物花色苷的方法 | |
CN100571530C (zh) | 一种高纯度α-玉米朊的制备方法 | |
JP4129577B2 (ja) | 精製コチニール色素及びその製造方法 | |
WO2004078695A1 (en) | Method for the purification of crocetin | |
US20040077883A1 (en) | Method for isolating terpene trilactones (ginkgolides, bilobalide) from leaves and pharmaceutical powders of Ginkgo biloba | |
JP4500564B2 (ja) | ベニバナ赤色素とその精製方法 | |
JP5295744B2 (ja) | テアシネンシンの製造方法 | |
CN107802978A (zh) | 一种大豆蛋白甲醛清除剂及其生产工艺 | |
JPH0273079A (ja) | フラボノイドの製法 | |
JP2004131633A (ja) | クチナシ黄色素の精製方法及び精製されたクチナシ黄色素 | |
JP3410610B2 (ja) | ベニバナ抽出液からのベニバナ黄色素と糖類の分離方法 | |
JPH01275512A (ja) | 可溶性卵殻膜の製法 | |
WO2003064538A1 (fr) | Couleur de mais rouge purifiee et procede de preparation de celle-ci | |
JP2019055369A (ja) | 機能性成分の吸着に用いる吸着剤 | |
JP3029270B2 (ja) | イチョウエキス及びその製造法 | |
JP2605207B2 (ja) | ビートサポニンの精製方法 | |
JP4079246B2 (ja) | ナリンゲニンカルコン及び/またはその誘導体の安定化法 | |
JP4184148B2 (ja) | コチニール色素の精製方法 | |
JPH05302038A (ja) | カルタミン類色素の精製法 | |
JPH0314572A (ja) | 植物体のカテキン類の製造方法 | |
JP2009007257A (ja) | ケルセチン含有植物材料を用いたケルセチンスルホン酸の製造方法 | |
SE523623C2 (sv) | Återvinningsmetod för hydrofoba nitroxylradikaler | |
KR0149553B1 (ko) | 키틴의 제조방법 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20070202 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20091201 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100201 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100302 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100318 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20100413 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20100419 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130423 Year of fee payment: 3 |
|
R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 Ref document number: 4500564 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140423 Year of fee payment: 4 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
EXPY | Cancellation because of completion of term |