JP2019536852A - 半結晶性ポリオレフィン系添加剤マスターバッチ組成物 - Google Patents
半結晶性ポリオレフィン系添加剤マスターバッチ組成物 Download PDFInfo
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- JP2019536852A JP2019536852A JP2019522465A JP2019522465A JP2019536852A JP 2019536852 A JP2019536852 A JP 2019536852A JP 2019522465 A JP2019522465 A JP 2019522465A JP 2019522465 A JP2019522465 A JP 2019522465A JP 2019536852 A JP2019536852 A JP 2019536852A
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- 238000000034 method Methods 0.000 claims abstract description 25
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- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 9
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- 229910052736 halogen Inorganic materials 0.000 description 7
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- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 6
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- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
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- 239000002841 Lewis acid Substances 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- 229910052570 clay Inorganic materials 0.000 description 4
- CGPRUXZTHGTMKW-UHFFFAOYSA-N ethene;ethyl prop-2-enoate Chemical compound C=C.CCOC(=O)C=C CGPRUXZTHGTMKW-UHFFFAOYSA-N 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 229910052738 indium Inorganic materials 0.000 description 4
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
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- 239000008188 pellet Substances 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- ZNRLMGFXSPUZNR-UHFFFAOYSA-N 2,2,4-trimethyl-1h-quinoline Chemical compound C1=CC=C2C(C)=CC(C)(C)NC2=C1 ZNRLMGFXSPUZNR-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
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- 239000001257 hydrogen Substances 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 3
- 238000010606 normalization Methods 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
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- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 3
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 3
- BZQKBFHEWDPQHD-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-[2-(2,3,4,5,6-pentabromophenyl)ethyl]benzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1CCC1=C(Br)C(Br)=C(Br)C(Br)=C1Br BZQKBFHEWDPQHD-UHFFFAOYSA-N 0.000 description 2
- XYXJKPCGSGVSBO-UHFFFAOYSA-N 1,3,5-tris[(4-tert-butyl-3-hydroxy-2,6-dimethylphenyl)methyl]-1,3,5-triazinane-2,4,6-trione Chemical group CC1=CC(C(C)(C)C)=C(O)C(C)=C1CN1C(=O)N(CC=2C(=C(O)C(=CC=2C)C(C)(C)C)C)C(=O)N(CC=2C(=C(O)C(=CC=2C)C(C)(C)C)C)C1=O XYXJKPCGSGVSBO-UHFFFAOYSA-N 0.000 description 2
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- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- YMOONIIMQBGTDU-UHFFFAOYSA-N 2-bromoethenylbenzene Chemical compound BrC=CC1=CC=CC=C1 YMOONIIMQBGTDU-UHFFFAOYSA-N 0.000 description 2
- AOUSBQVEVZBMNI-UHFFFAOYSA-N 2-bromoethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCBr AOUSBQVEVZBMNI-UHFFFAOYSA-N 0.000 description 2
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 2
- HCILJBJJZALOAL-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)-n'-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyl]propanehydrazide Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 HCILJBJJZALOAL-UHFFFAOYSA-N 0.000 description 2
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- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 2
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- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical class C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
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- ORECYURYFJYPKY-UHFFFAOYSA-N n,n'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine;2,4,6-trichloro-1,3,5-triazine;2,4,4-trimethylpentan-2-amine Chemical compound CC(C)(C)CC(C)(C)N.ClC1=NC(Cl)=NC(Cl)=N1.C1C(C)(C)NC(C)(C)CC1NCCCCCCNC1CC(C)(C)NC(C)(C)C1 ORECYURYFJYPKY-UHFFFAOYSA-N 0.000 description 2
- GTIBACHAUHDNPH-WHYMJUELSA-N n,n'-bis[(z)-benzylideneamino]oxamide Chemical compound C=1C=CC=CC=1\C=N/NC(=O)C(=O)N\N=C/C1=CC=CC=C1 GTIBACHAUHDNPH-WHYMJUELSA-N 0.000 description 2
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
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- DJKGDNKYTKCJKD-BPOCMEKLSA-N (1s,4r,5s,6r)-1,2,3,4,7,7-hexachlorobicyclo[2.2.1]hept-2-ene-5,6-dicarboxylic acid Chemical compound ClC1=C(Cl)[C@]2(Cl)[C@H](C(=O)O)[C@H](C(O)=O)[C@@]1(Cl)C2(Cl)Cl DJKGDNKYTKCJKD-BPOCMEKLSA-N 0.000 description 1
- GRKDVZMVHOLESV-UHFFFAOYSA-N (2,3,4,5,6-pentabromophenyl)methyl prop-2-enoate Chemical compound BrC1=C(Br)C(Br)=C(COC(=O)C=C)C(Br)=C1Br GRKDVZMVHOLESV-UHFFFAOYSA-N 0.000 description 1
- OWICEWMBIBPFAH-UHFFFAOYSA-N (3-diphenoxyphosphoryloxyphenyl) diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=C(OP(=O)(OC=2C=CC=CC=2)OC=2C=CC=CC=2)C=CC=1)(=O)OC1=CC=CC=C1 OWICEWMBIBPFAH-UHFFFAOYSA-N 0.000 description 1
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- DZICVNVZFSBZHA-UHFFFAOYSA-N 1,1,2,2,2-pentabromoethylbenzene;2,4,6-tribromophenol Chemical compound OC1=C(Br)C=C(Br)C=C1Br.BrC(Br)(Br)C(Br)(Br)C1=CC=CC=C1 DZICVNVZFSBZHA-UHFFFAOYSA-N 0.000 description 1
- XQKQZOLAVMIQHZ-UHFFFAOYSA-N 1,1-dibromo-3-(3,3-dibromopropoxy)propane Chemical compound BrC(Br)CCOCCC(Br)Br XQKQZOLAVMIQHZ-UHFFFAOYSA-N 0.000 description 1
- NDRKXFLZSRHAJE-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-(2,3,4-tribromophenyl)benzene Chemical group BrC1=C(Br)C(Br)=CC=C1C1=C(Br)C(Br)=C(Br)C(Br)=C1Br NDRKXFLZSRHAJE-UHFFFAOYSA-N 0.000 description 1
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- 238000011282 treatment Methods 0.000 description 1
- NMEPHPOFYLLFTK-UHFFFAOYSA-N trimethoxy(octyl)silane Chemical compound CCCCCCCC[Si](OC)(OC)OC NMEPHPOFYLLFTK-UHFFFAOYSA-N 0.000 description 1
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- OOZBTDPWFHJVEK-UHFFFAOYSA-N tris(2-nonylphenyl) phosphate Chemical compound CCCCCCCCCC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC OOZBTDPWFHJVEK-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
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Abstract
Description
Claims (11)
- (A)半結晶性ポリオレフィンキャリア樹脂と、(B)難燃剤を含む添加剤パッケージと、を含む添加剤マスターバッチ組成物であって、(A)が、前記添加剤マスターバッチ組成物の総重量(100.00重量%)の10〜90重量パーセント(重量%)であり、前記添加剤パッケージが、90〜10重量%である、添加剤マスターバッチ組成物。
- 前記(A)半結晶性ポリオレフィンキャリア樹脂が、(i)半結晶性中密度ポリエチレン、(ii)半結晶性高密度ポリエチレン、(iii)半結晶性ポリプロピレン、(iv)半結晶性エチレン/プロピレンコポリマー、(v)半結晶性ポリ(エチレン−コ−アルファ−オレフィン)コポリマー、(vi)(i)、(ii)および(v)のうちのいずれか2つ以上の組み合わせ(例えば、混合物またはブレンド)、(vii)前記(A)半結晶性ポリオレフィンキャリア樹脂が、50〜<100重量%の結晶化度を有するもの、または(viii)(i)〜(vi)の限定、および前記(A)半結晶性ポリオレフィンキャリア樹脂のうちのいずれか1つが、50〜<100重量%の結晶化度を有するもの、の(i)〜(viii)のうちのいずれか1つから本質的になる、請求項1に記載の添加剤マスターバッチ組成物。
- 前記(A)半結晶性ポリオレフィンキャリア樹脂が、(i)少なくとも0.925g/cm3の密度のポリエチレンであるか、もしくは0.89〜0.90g/cm3の密度のポリプロピレンであるもの、(ii)50〜<100重量%の結晶化度のポリエチレンであるもの、(iii)190℃/2.16kg荷重で10分当たり0.1〜50グラム(g/10分)のメルトフローインデックス(MFI)のポリエチレンであるか、もしくは230℃/2.16kg荷重で0.5〜50g/10分のメルトフローレート(MFR)のポリプロピレンであるもの、(iv)単峰性である分子量分布(MWD)、(v)二峰性であるMWD、(vi)(i)と(ii)との両方、(vii)(i)と(iii)との両方、(viii)(ii)と(iii)との両方、(ix)(iv)と、(i)〜(iii)のうちの少なくとも1つとの両方、または(x)(v)と、(i)〜(iii)のうちの少なくとも1つとの両方、の(i)〜(x)のうちのいずれか1つを有する、請求項1または2に記載の添加剤マスターバッチ組成物。
- 前記(B)難燃剤が、(B1)鉱物、(B2)有機ハロゲン化合物、(B3)(有機)リン化合物、および(B4)ハロゲン化シリコーン、またはそれらのいずれか2つ以上の組み合わせである、請求項1〜3のいずれか一項に記載の添加剤マスターバッチ組成物。
- (C)酸性縮合触媒、(D)式(I):(R1−Ar)2NH(I)であって、式中、各Arが、ベンゼン−1,4−ジイル、または両方のArが、互いに結合し、前記式(I)のNHと一緒になってカルバゾール−3,6−ジイルを構成し、各R1が、独立して(C1−C20)ヒドロカルビルである、第二級ジアリールアミン、(E)式(I)および互いとは異なる構造を各々有する、1つまたは2つの第2の酸化防止剤、(F)加工助剤、(G)着色剤、(H)金属不活性化剤、(I)(不飽和炭素−炭素結合)を含まない加水分解性シラン、(J)腐食防止剤、(K)(C)と(D)との反応生成物、ならびに(L)ヒンダードアミン光安定剤、ならびに(M)(K)と、添加剤(C)〜(J)のうちのいずれか2つ以上との組み合わせ、から選択された少なくとも1つの添加剤をさらに含む、請求項1〜4のいずれか一項に記載の添加剤マスターバッチ組成物。
- 請求項1〜5のいずれか一項に記載の添加剤マスターバッチ組成物および(加水分解性シリル基)−官能性ポリオレフィンプレポリマーを含む湿気硬化性ポリオレフィン組成物であって、前記(加水分解性シリル基)−官能性ポリオレフィンプレポリマー中で、(i)各加水分解性シリル基が、独立して、式(II):(R2)m(R3)3−mSi−(II)の一価の基であり、式中、添字mが、1、2、もしくは3の整数であり、各R2が、独立して、H、HO−、(C1−C6)アルコキシ、(C2−C6)カルボキシ、((C1−C6)アルキル)2N−、(C1−C6)アルキル(H)C=NO−、もしくは((C1−C6)アルキル)2C=NO−であり、各R3が、独立して(C1−C6)アルキルもしくはフェニルである、(ii)前記ポリオレフィンが、ポリエチレン系、ポリ(エチレン−コ−(C3−C40)アルファ−オレフィン)系、もしくはそれらの組み合わせである、または(iii)(i)と(ii)との両方である、湿気硬化性ポリオレフィン組成物。
- 湿気硬化性ポリオレフィン組成物を作製する方法であって、(加水分解性シリル基)−官能性ポリオレフィンプレポリマーと請求項1〜5のいずれか一項に記載の添加剤マスターバッチ組成物の分割された固体形態とを混合して混合物を得ることと、前記混合物を溶融または押し出しして、前記湿気硬化性ポリオレフィン組成物を作製することと、を含む、方法。
- 請求項6に記載の湿気硬化性ポリオレフィン組成物の湿気硬化の生成物である、湿気硬化されたポリオレフィン組成物、または前記湿気硬化されたポリオレフィン組成物を得るために請求項7に記載の方法によって作製された組成物。
- 請求項8に記載の湿気硬化されたポリオレフィン組成物の成形体を含む製造物品。
- 導電性コアと、前記導電性コアを少なくとも部分的に囲むポリマー層とを含む被覆導体であって、前記ポリマー層の少なくとも一部分が、請求項8に記載の湿気硬化されたポリオレフィン組成物を含む、被覆導体。
- 電気を伝導する方法であって、請求項10に記載の被覆導体の前記導電性コア全体に電圧を印加して、前記導電性コアを通る電気の流れを発生させることを含む、方法。
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PCT/US2017/059217 WO2018085236A1 (en) | 2016-11-02 | 2017-10-31 | Semi-crystalline polyolefin-based additive masterbatch composition |
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KR20220001043A (ko) * | 2020-06-26 | 2022-01-05 | 문성철 | 폐 폴리올레핀 발포체 분말을 이용한 고난연성 및 친환경성 폴리올레핀계 나노복합 마스터뱃치 |
KR102523047B1 (ko) | 2020-06-26 | 2023-04-18 | 문성철 | 폐 폴리올레핀 발포체 분말을 이용한 고난연성 및 친환경성 폴리올레핀계 나노복합 마스터뱃치 |
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BR112019008312A2 (ja) | 2019-04-24 |
WO2018085236A1 (en) | 2018-05-11 |
CN109890877B (zh) | 2022-06-28 |
EP3535312A1 (en) | 2019-09-11 |
KR20190078582A (ko) | 2019-07-04 |
KR102569082B1 (ko) | 2023-08-24 |
EP3535312B1 (en) | 2024-02-21 |
JP7082975B2 (ja) | 2022-06-09 |
CN109890877A (zh) | 2019-06-14 |
BR112019008312B1 (pt) | 2023-09-26 |
US20200055997A1 (en) | 2020-02-20 |
CA3042235A1 (en) | 2018-05-11 |
MX2019004916A (es) | 2019-08-05 |
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