JP2018095568A - Hair treatment agent - Google Patents
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- JP2018095568A JP2018095568A JP2016238713A JP2016238713A JP2018095568A JP 2018095568 A JP2018095568 A JP 2018095568A JP 2016238713 A JP2016238713 A JP 2016238713A JP 2016238713 A JP2016238713 A JP 2016238713A JP 2018095568 A JP2018095568 A JP 2018095568A
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- 238000011282 treatment Methods 0.000 title claims abstract description 30
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 29
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 7
- 239000000194 fatty acid Substances 0.000 claims abstract description 7
- 229930195729 fatty acid Natural products 0.000 claims abstract description 7
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 7
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 claims description 8
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 claims description 4
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 claims description 4
- OCIQZTICBOLUJQ-UHFFFAOYSA-N 2,2,3,3-tetraethylhexanoic acid Chemical compound CCCC(CC)(CC)C(CC)(CC)C(O)=O OCIQZTICBOLUJQ-UHFFFAOYSA-N 0.000 claims description 2
- DRRMRHKHTQRWMB-UHFFFAOYSA-N [3-(2-ethylhexanoyloxy)-2,2-bis(2-ethylhexanoyloxymethyl)propyl] 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCC(COC(=O)C(CC)CCCC)(COC(=O)C(CC)CCCC)COC(=O)C(CC)CCCC DRRMRHKHTQRWMB-UHFFFAOYSA-N 0.000 abstract description 2
- VAKUGTCMNBMGQU-UHFFFAOYSA-N [2-(hydroxymethyl)-2-[[2-(hydroxymethyl)-2-(12-hydroxyoctadecanoyloxymethyl)-3-(16-methylheptadecanoyloxy)propoxy]methyl]-3-(16-methylheptadecanoyloxy)propyl] 12-hydroxyoctadecanoate Chemical compound CCCCCCC(O)CCCCCCCCCCC(=O)OCC(CO)(COC(=O)CCCCCCCCCCCCCCC(C)C)COCC(CO)(COC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCC(O)CCCCCC VAKUGTCMNBMGQU-UHFFFAOYSA-N 0.000 abstract 1
- 238000013329 compounding Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 4
- 239000002537 cosmetic Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical compound CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229940008099 dimethicone Drugs 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 2
- 239000002453 shampoo Substances 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ORAWFNKFUWGRJG-UHFFFAOYSA-N Docosanamide Chemical compound CCCCCCCCCCCCCCCCCCCCCC(N)=O ORAWFNKFUWGRJG-UHFFFAOYSA-N 0.000 description 1
- IUMSDRXLFWAGNT-UHFFFAOYSA-N Dodecamethylcyclohexasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 IUMSDRXLFWAGNT-UHFFFAOYSA-N 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- ARCGXLSVLAOJQL-UHFFFAOYSA-N anhydrous trimellitic acid Natural products OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- IWWCATWBROCMCW-UHFFFAOYSA-N batyl alcohol Natural products CCCCCCCCCCCCCCCCCCOC(O)CO IWWCATWBROCMCW-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000006297 carbonyl amino group Chemical group [H]N([*:2])C([*:1])=O 0.000 description 1
- 229940082500 cetostearyl alcohol Drugs 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Chemical compound OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 description 1
- 229940090934 diphenylsiloxy phenyl trimethicone Drugs 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 239000003676 hair preparation Substances 0.000 description 1
- 230000003699 hair surface Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920006007 hydrogenated polyisobutylene Polymers 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- ZUHZZVMEUAUWHY-UHFFFAOYSA-N n,n-dimethylpropan-1-amine Chemical compound CCCN(C)C ZUHZZVMEUAUWHY-UHFFFAOYSA-N 0.000 description 1
- UTBABEVADWVTHM-UHFFFAOYSA-N n,n-dimethylpropan-1-amine;octadecanamide Chemical compound CCCN(C)C.CCCCCCCCCCCCCCCCCC(N)=O UTBABEVADWVTHM-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- -1 trimellitic acid triesters Chemical class 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical group 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
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- Cosmetics (AREA)
Abstract
Description
本発明は、ヘアトリートメント剤に関する。 The present invention relates to a hair treatment agent.
ヘアトリートメント剤は、ヘアパック、ヘアリンス等とも呼ばれ、毛髪の表面をなめらかにして櫛通りを良くし、また、しっとり感を与えるといった効果を有する毛髪化粧料であり、多くの種類のものが上市されている。ヘアトリートメント剤は、毛髪をなめらかにしたり、しっとり感を与えるため、通常、様々な重合度のシリコーンやアミノ基で変性したシリコーン等のシリコーン類を配合している。しかし、シリコーン類は、毛髪表面へ蓄積する性質を有するため、シリコーン類を配合したヘアトリートメント剤を繰り返し使用していると、毛髪にごわつきやきしみが生じてくるといった問題があった。 Hair treatments, also called hair packs and hair rinses, are hair cosmetics that have the effect of smoothing the surface of the hair to improve the combing and moisturizing properties. Has been. Hair treatment agents usually contain silicones such as silicones with various degrees of polymerization and silicones modified with amino groups in order to make the hair smooth and moist. However, since silicones have a property of accumulating on the hair surface, there has been a problem that when hair treatment agents containing silicones are repeatedly used, the hair becomes stiff and squeaky.
そこで、シリコーン類を含有しない特許文献１や特許文献２のようなヘアトリートメント剤が開発されている。特許文献１は、シリコーン類の代わりに、脂肪酸アミドアミン、高級アルコール及び水添ポリイソブテン及び／又は水添ポリデセンを配合しており、特許文献２は、脂肪酸アミドアミン、高級アルコール及びトリメリト酸トリエステル類を配合している。しかし、いずれのヘアトリートメント剤も、毛髪に塗布したときの使用感が不十分であり、また、安定性については何らか評価されていない。 Therefore, hair treatment agents such as Patent Document 1 and Patent Document 2 that do not contain silicones have been developed. Patent Document 1 contains fatty acid amidoamine, higher alcohol and hydrogenated polyisobutene and / or hydrogenated polydecene instead of silicone, and Patent Document 2 contains fatty acid amidoamine, higher alcohol and trimellitic acid triesters. doing. However, none of the hair treatment agents have an insufficient feeling of use when applied to hair, and the stability has not been evaluated at all.
そこで、本発明は、シリコーン類を含有しなくとも、使用感が良く、また、安定性の高いヘアトリートメント剤を提供することを課題とする。 Therefore, an object of the present invention is to provide a hair treatment agent that has good usability and high stability even if it does not contain silicones.
すなわち、本発明は、下記の（Ａ）〜（Ｄ）を含有し、シリコーン類を含有しないことを特徴とするヘアトリートメント剤を提供する。
（Ａ）脂肪酸アミドアミン
（Ｂ）高級アルコール
（Ｃ）テトラエチルヘキサン酸ペンタエリスリチル
（Ｄ）テトラ（ヒドロキシステアリン酸／イソステアリン酸）ジペンタエリスリチル
That is, this invention provides the hair treatment agent characterized by containing the following (A)-(D) and not containing silicones.
(A) Fatty acid amidoamine (B) Higher alcohol (C) Tetraethylhexanoic acid pentaerythrityl (D) Tetra (hydroxystearic acid / isostearic acid) dipentaerythrityl
本発明によると、シリコーン類を含有しなくとも、使用感が良く、また、安定性に優れたヘアトリートメント剤を得られる。 According to the present invention, it is possible to obtain a hair treatment agent having good usability and excellent stability without containing silicones.
本発明で用いられる成分（Ａ）脂肪酸アミドアミンは、化学式がＲ１ＣＯＮＨ（ＣＨ２）ｎＮＲ２Ｒ３で表される化合物をいい、Ｒ１は、置換されていてもよい直鎖又は分岐した炭素数８〜２４の飽和又は不飽和脂肪酸残基を、Ｒ２及びＲ３は、同一又は異なっていてもよく、置換されていてもよい直鎖又は分岐した炭素数１〜１０のアルキル基を、またｎは１〜１０を示す化合物である。本発明で用いられる脂肪酸アミドアミンは、この化学式で表されるものであれば、いずれも使用できるが、これらの中でも、ステアラミドプロピルジメチルアミン（化粧品表示名称）、ベヘナミドプロピルジメチルアミン（化粧品表示名称）を用いるのが好ましい。 The component (A) fatty acid amidoamine used in the present invention refers to a compound represented by the chemical formula R 1 CONH (CH 2 ) nNR 2 R 3 , wherein R 1 is a linear or branched carbon which may be substituted. A saturated or unsaturated fatty acid residue of formula 8-24, R 2 and R 3 may be the same or different, and may be a linear or branched alkyl group of 1 to 10 carbon atoms, Moreover, n is a compound which shows 1-10. Any fatty acid amide amine used in the present invention can be used as long as it is represented by this chemical formula. Among them, stearamide propyl dimethylamine (cosmetic label), behenamide propyl dimethylamine (cosmetic label) Name) is preferably used.
成分（Ａ）は、一種を単独で使用してもよいし、二種以上を併用してもよく、本発明のヘアトリートメント剤全量に対し、０．５〜５質量％の配合量が好ましい。配合量が０．５質量％未満又は５質量％を超えると、安定性が悪くなる場合がある。 A component (A) may be used individually by 1 type, and may use 2 or more types together, and the compounding quantity of 0.5-5 mass% is preferable with respect to the hair treatment agent whole quantity of this invention. If the blending amount is less than 0.5% by mass or exceeds 5% by mass, the stability may be deteriorated.
本発明で用いられる成分（Ｂ）高級アルコールは、直鎖又は分岐鎖のアルキル基又はアルケニル基を有する高級アルコール類であり、特に制限されずに使用することができる。具体的にはミリスチルアルコール、セタノール、ステアリルアルコール、セトステアリルアルコール、ベヘニルアルコール、バチルアルコール、イソステアリルアルコール等が挙げられる。これらの中でもセタノール（化粧品表示名称）を用いるのが好ましい。 The component (B) higher alcohol used in the present invention is a higher alcohol having a linear or branched alkyl group or alkenyl group, and can be used without particular limitation. Specific examples include myristyl alcohol, cetanol, stearyl alcohol, cetostearyl alcohol, behenyl alcohol, batyl alcohol, and isostearyl alcohol. Of these, cetanol (name of cosmetic display) is preferably used.
成分（Ｂ）は、一種を単独で使用してもよいし、二種以上を併用してもよく、本発明のヘアトリートメント剤全量に対し、１〜２０質量％の配合量が好ましい。配合量が１質量％未満又は２０質量％を超えると、安定性が悪くなる場合がある。 A component (B) may be used individually by 1 type, and may use 2 or more types together, and the compounding quantity of 1-20 mass% is preferable with respect to the hair treatment agent whole quantity of this invention. If the blending amount is less than 1% by mass or exceeds 20% by mass, the stability may be deteriorated.
本発明で用いられる成分（Ｃ）テトラエチルヘキサン酸ペンタエリスリチルは、エチルヘキサン酸とペンタエリスリトールとのテトラエステルであり、特に制限されずに使用することができる。 Component (C) pentaerythrityl tetraethylhexanoate used in the present invention is a tetraester of ethylhexanoic acid and pentaerythritol, and can be used without particular limitation.
成分（Ｃ）は、一種を単独で使用してもよいし、二種以上を併用してもよく、本発明のヘアトリートメント剤全量に対し、１〜１５質量％の配合量が好ましい。配合量が１質量％未満であると、使用感及び安定性に影響を及ぼす場合があり、１５質量％を超えると、安定性が悪くなる場合がある。 A component (C) may be used individually by 1 type, and may use 2 or more types together, and the compounding quantity of 1-15 mass% is preferable with respect to the hair treatment agent whole quantity of this invention. When the blending amount is less than 1% by mass, the feeling of use and stability may be affected, and when it exceeds 15% by mass, the stability may be deteriorated.
本発明で用いられる成分（Ｄ）テトラ（ヒドロキシステアリン酸／イソステアリン酸）ジペンタエリスリチルは、ヒドロキシステアリン酸及びイソステアリン酸とジペンタエリスリトールとのテトラエステルであり、特に制限されずに使用することができる。 Component (D) tetra (hydroxystearic acid / isostearic acid) dipentaerythrityl used in the present invention is hydroxystearic acid and a tetraester of isostearic acid and dipentaerythritol, and can be used without particular limitation.
成分（Ｄ）は、一種を単独で使用してもよいし、二種以上を併用してもよく、本発明のヘアトリートメント剤全量に対し、１〜１０質量％の配合量が好ましい。配合量が１質量％未満であると、使用感及び安定性に影響を及ぼす場合があり、１０質量％を超えると、安定性が悪くなる場合がある。 A component (D) may be used individually by 1 type, may use 2 or more types together, and the compounding quantity of 1-10 mass% is preferable with respect to the hair treatment agent whole quantity of this invention. When the blending amount is less than 1% by mass, the feeling in use and the stability may be affected, and when it exceeds 10% by mass, the stability may be deteriorated.
本発明のヘアトリートメント剤は、成分（Ａ）〜（Ｄ）に加え、さらに成分（Ｅ）プロパンジオールを含有させることが好ましい。 The hair treatment agent of the present invention preferably further contains component (E) propanediol in addition to components (A) to (D).
本発明で用いられる成分（Ｅ）プロパンジオールは、化学名を１，３−プロパンジオールといい、特に制限されずに使用することがでる。 Component (E) propanediol used in the present invention has a chemical name of 1,3-propanediol, and can be used without particular limitation.
成分（Ｅ）は、一種を単独で使用してもよいし、二種以上を併用してもよく、本発明のヘアトリートメント剤全量に対し、５〜２０質量％の配合量が好ましい。配合量が５質量％未満又は２０質量％を超えると、使用感が悪くなる場合がある。 A component (E) may be used individually by 1 type, and may use 2 or more types together, and the compounding quantity of 5-20 mass% is preferable with respect to the hair treatment agent whole quantity of this invention. If the blending amount is less than 5% by mass or exceeds 20% by mass, the feeling of use may be deteriorated.
本発明のヘアトリートメント剤は、シリコーン類を含有しないことを特徴とする。ここでいうシリコーン類とは、シロキサン結合（Ｓｉ−Ｏ−Ｓｉ）を有する有機化合物をいい、具体的には、ジメチコン、シクロヘキサシロキサン、ジフェニルシロキシフェニルトリメチコン、ＰＥＧ−１０ジメチコン等のシリコーン系油剤やシリコーン系界面活性剤等が挙げられる。 The hair treatment agent of the present invention is characterized by not containing silicones. Silicones here refer to organic compounds having a siloxane bond (Si—O—Si), and specifically, silicone oils such as dimethicone, cyclohexasiloxane, diphenylsiloxyphenyl trimethicone, PEG-10 dimethicone and the like. And silicone surfactants.
本発明のヘアトリートメント剤は、上述の成分の他に、通常の化粧料に用いられる任意成分を、本発明の効果を阻害しない程度に配合することができる。具体的には、油剤、増粘剤、防腐剤、香料、保湿剤、抗酸化剤、抗炎症剤、抗菌剤等を挙げることができる。 The hair treatment agent of this invention can mix | blend the arbitrary component used for normal cosmetics other than the above-mentioned component to such an extent that the effect of this invention is not inhibited. Specific examples include oil agents, thickeners, preservatives, fragrances, moisturizers, antioxidants, anti-inflammatory agents, antibacterial agents, and the like.
本発明のヘアトリートメント剤は、常法により製造することができる。剤型としては、液状、クリーム状、ワックス状等の剤型とすることができ、シャンプー等で毛髪を洗浄した後に用いることが好ましい。また、塗布した後、毛髪に残存する余分なヘアトリートメント剤をすすいで用いることが好ましい。 The hair treatment agent of this invention can be manufactured by a conventional method. The dosage form may be liquid, cream, wax or the like, and is preferably used after washing the hair with a shampoo or the like. Moreover, it is preferable to rinse and use the excess hair treatment agent remaining on the hair after application.
以下、実施例により、本発明を具体的に説明するが、これにより、本発明の範囲が限定されるものではない。なお、配合量は、特に断りのない限り質量％である。 Hereinafter, the present invention will be specifically described by way of examples. However, the scope of the present invention is not limited thereby. In addition, a compounding quantity is the mass% unless there is particular notice.
表の実施例及び比較例のヘアトリートメント剤を、下記の製造方法で製造した。
＜製造方法＞
（１）成分（Ａ）、（Ｂ）、（Ｃ）、（Ｄ）、（Ｅ）及びパルミチン酸イソプロピルを８０℃〜８５℃で、均一に混合した。
（２）上記（１）以外の成分を８０℃〜８５℃で、均一に混合した。
（３）上記（１）に上記（２）を加え、８０℃〜８５℃に加温後、ホモミキサーで均一に混合し、室温まで冷却して、表の各実施例及び比較例のヘアトリートメント剤を製造した。
The hair treatment agents of the examples and comparative examples in the table were produced by the following production method.
<Manufacturing method>
(1) Components (A), (B), (C), (D), (E) and isopropyl palmitate were uniformly mixed at 80 ° C to 85 ° C.
(2) Components other than the above (1) were uniformly mixed at 80 to 85 ° C.
(3) After adding (2) to (1) above, heating to 80 ° C. to 85 ° C., uniformly mixing with a homomixer, cooling to room temperature, hair treatment of each example and comparative example in the table An agent was produced.
そして、各実施例及び比較例のヘアトリートメント剤について、下記の方法で、使用感及び安定性の評価を行った。その結果を表に示す。 And about the hair treatment agent of each Example and the comparative example, the usability | use_condition and stability were evaluated with the following method. The results are shown in the table.
ａ）使用感（髪とのなじみ、すすぎ時の指通り、乾燥後の髪のしっとり感）
専門パネラー５名による使用テストを行った。まず、各パネラーが日常使用しているシャンプーで十分洗髪を行ってから、表のヘアトリートメント剤の使用テストを行い、下記の評価基準に従って、髪とのなじみ、すすぎ時の指通り、乾燥後の髪のしっとり感について、絶対評価をし、更にその５人の評点の平均点を下記判定基準により判定した。評価基準及び判定基準は、髪とのなじみ、すすぎ時の指通り、乾燥後の髪のしっとり感で共通のものとした。
＜評価基準＞
３点：非常に良い
２点：良い
１点：やや悪い
０点：悪い
＜判定基準＞
◎：２．５点以上
○：１．８点以上２．５点未満
△：１．０点以上１．８点未満
×：１．０点未満
a) Feeling of use (familiarity with hair, fingering during rinsing, moist feeling of hair after drying)
A use test was conducted by five expert panelists. First, thoroughly wash your hair with the shampoos used daily by each paneler, and then test the use of the hair treatment agents listed in the table. In accordance with the following evaluation criteria, familiarity with hair, fingering during rinsing, and after drying The moist feeling of the hair was absolutely evaluated, and the average score of the five people was determined according to the following criteria. The evaluation standard and the judgment standard were the same for familiarity with the hair, following the finger during rinsing, and moist feeling of the hair after drying.
<Evaluation criteria>
3 points: very good 2 points: good 1 point: somewhat bad 0 point: bad
<Criteria>
A: 2.5 or more ○: 1.8 or more and less than 2.5 Δ: 1.0 or more and less than 1.8 × ×: less than 1.0
ｂ）安定性
専門評価員３名に、表のヘアトリートメント剤を５℃、２５℃、４０℃で３カ月保管した際の外観の状態を下記の判定基準により判定した。
＜判定基準＞
◎：変化がない
○：変化がほとんどない
△：やや硬度に変化が見られる
×：硬度に変化が見られる
b) The appearance condition when the hair treatment agents in the table were stored at 5 ° C., 25 ° C., and 40 ° C. for 3 months was judged according to the following criteria.
<Criteria>
◎: No change ○: Little change △: Some change in hardness x: Change in hardness
表に示された結果から明らかなように、各実施例のヘアトリートメント剤は、使用感及び安定性すべての面で優れていた。一方、各比較例のヘアトリートメント剤は、使用感及び安定性の面で劣っていた。 As is clear from the results shown in the table, the hair treatment agent of each example was excellent in terms of use feeling and stability. On the other hand, the hair treatment agent of each comparative example was inferior in terms of usability and stability.
Claims (1)
（Ａ）脂肪酸アミドアミン
（Ｂ）高級アルコール
（Ｃ）テトラエチルヘキサン酸ペンタエリスリチル
（Ｄ）テトラ（ヒドロキシステアリン酸／イソステアリン酸）ジペンタエリスリチル A hair treatment agent comprising the following (A) to (D) and not containing silicones.
(A) Fatty acid amidoamine (B) Higher alcohol (C) Tetraethylhexanoic acid pentaerythrityl (D) Tetra (hydroxystearic acid / isostearic acid) dipentaerythrityl
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