JP2005232141A - Hair cosmetic - Google Patents
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- JP2005232141A JP2005232141A JP2004047101A JP2004047101A JP2005232141A JP 2005232141 A JP2005232141 A JP 2005232141A JP 2004047101 A JP2004047101 A JP 2004047101A JP 2004047101 A JP2004047101 A JP 2004047101A JP 2005232141 A JP2005232141 A JP 2005232141A
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 23
- 239000000203 mixture Substances 0.000 claims abstract description 23
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 14
- 150000002148 esters Chemical class 0.000 claims abstract description 8
- PUAQLLVFLMYYJJ-UHFFFAOYSA-N 2-aminopropiophenone Chemical compound CC(N)C(=O)C1=CC=CC=C1 PUAQLLVFLMYYJJ-UHFFFAOYSA-N 0.000 claims abstract description 6
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 5
- 239000000839 emulsion Substances 0.000 claims description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 150000002366 halogen compounds Chemical group 0.000 claims description 3
- 238000001035 drying Methods 0.000 abstract description 13
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 7
- 239000000194 fatty acid Substances 0.000 abstract description 7
- 229930195729 fatty acid Natural products 0.000 abstract description 7
- 238000011282 treatment Methods 0.000 abstract description 5
- 230000003648 hair appearance Effects 0.000 abstract description 2
- 235000019482 Palm oil Nutrition 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 239000002540 palm oil Substances 0.000 abstract 1
- -1 fatty acid ester quat halide Chemical class 0.000 description 15
- 239000003676 hair preparation Substances 0.000 description 10
- 238000011156 evaluation Methods 0.000 description 9
- 238000002156 mixing Methods 0.000 description 8
- 239000003093 cationic surfactant Substances 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 7
- 238000005406 washing Methods 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 239000007844 bleaching agent Substances 0.000 description 4
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 238000012733 comparative method Methods 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 3
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 2
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 2
- 229960000735 docosanol Drugs 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N heptadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
- IRHTZOCLLONTOC-UHFFFAOYSA-N hexacosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCO IRHTZOCLLONTOC-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- IACKKVBKKNJZGN-UHFFFAOYSA-N pentacosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCO IACKKVBKKNJZGN-UHFFFAOYSA-N 0.000 description 2
- REIUXOLGHVXAEO-UHFFFAOYSA-N pentadecan-1-ol Chemical compound CCCCCCCCCCCCCCCO REIUXOLGHVXAEO-UHFFFAOYSA-N 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical class CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- TYWMIZZBOVGFOV-UHFFFAOYSA-N tetracosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCO TYWMIZZBOVGFOV-UHFFFAOYSA-N 0.000 description 2
- FPLNRAYTBIFSFW-UHFFFAOYSA-N tricosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCO FPLNRAYTBIFSFW-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 description 1
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- XPFCZYUVICHKDS-UHFFFAOYSA-N 3-methylbutane-1,3-diol Chemical compound CC(C)(O)CCO XPFCZYUVICHKDS-UHFFFAOYSA-N 0.000 description 1
- ODHCTXKNWHHXJC-VKHMYHEASA-N 5-oxo-L-proline Chemical compound OC(=O)[C@@H]1CCC(=O)N1 ODHCTXKNWHHXJC-VKHMYHEASA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 239000004166 Lanolin Chemical class 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- XEKAUTDWPYQNFU-UHFFFAOYSA-N chlorane Chemical compound Cl.Cl.Cl XEKAUTDWPYQNFU-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- VKKVMDHHSINGTJ-UHFFFAOYSA-M di(docosyl)-dimethylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCCCCCC VKKVMDHHSINGTJ-UHFFFAOYSA-M 0.000 description 1
- VBVQYGNPGUXBIS-UHFFFAOYSA-M dimethyl(dioctadecyl)azanium;hydroxide Chemical compound [OH-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC VBVQYGNPGUXBIS-UHFFFAOYSA-M 0.000 description 1
- QMQQXUKIVNEQCM-UHFFFAOYSA-M dimethyl(dioctyl)azanium;hydroxide Chemical compound [OH-].CCCCCCCC[N+](C)(C)CCCCCCCC QMQQXUKIVNEQCM-UHFFFAOYSA-M 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 description 1
- JVQOASIPRRGMOS-UHFFFAOYSA-M dodecyl(trimethyl)azanium;hydroxide Chemical compound [OH-].CCCCCCCCCCCC[N+](C)(C)C JVQOASIPRRGMOS-UHFFFAOYSA-M 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 229920002674 hyaluronan Polymers 0.000 description 1
- 229960003160 hyaluronic acid Drugs 0.000 description 1
- BTFJIXJJCSYFAL-UHFFFAOYSA-N icosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940094506 lauryl betaine Drugs 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 1
- XGFDHKJUZCCPKQ-UHFFFAOYSA-N n-nonadecyl alcohol Natural products CCCCCCCCCCCCCCCCCCCO XGFDHKJUZCCPKQ-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229940079889 pyrrolidonecarboxylic acid Drugs 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- FLXZVVQJJIGXRS-UHFFFAOYSA-M trimethyl(octadecyl)azanium;hydroxide Chemical compound [OH-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C FLXZVVQJJIGXRS-UHFFFAOYSA-M 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
本発明は毛髪化粧料に関する。さらに詳しくは、組成物の安定性、すすぎ時の滑らかさ・しなやかさ、ドライ後の使用感(しっとり感、滑らかさ、しなやかさ)に優れる毛髪化粧料に関する。 The present invention relates to a hair cosmetic. More specifically, the present invention relates to a hair cosmetic that is excellent in the stability of the composition, the smoothness and suppleness at the time of rinsing, and the feeling after use (moistness, smoothness, and suppleness) after drying.
ヘアリンスやヘアトリートメント等の毛髪化粧料には、すすぎ時および乾燥(ドライ)後の毛髪に対するコンディショニング効果(柔軟性や平滑性)が求められており、従来、セチルトリメチルアンモニウムクロライド、ステアリルトリメチルアンモニウムクロライド等のモノアルキルトリメチルアンモニウムクロライドや、ジステアリルジメチルアンモニウムクロライド、ジベヘニルジメチルアンモニウムクロライド等のジアルキルジメチルアンモニウムクロライドに代表されるカチオン性界面活性剤が使用されてきた。また、エステルクワットを用いた毛髪化粧料も提案されている(例えば、特許文献1参照)。 Hair cosmetics such as hair rinses and hair treatments are required to have a conditioning effect (flexibility and smoothness) on hair after rinsing and after drying (dry). Conventionally, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, etc. Cationic surfactants typified by dialkyldimethylammonium chloride such as monoalkyltrimethylammonium chloride, distearyldimethylammonium chloride and dibehenyldimethylammonium chloride have been used. In addition, hair cosmetics using ester quats have also been proposed (see, for example, Patent Document 1).
一方、近年ヘアカラー人口の増加に伴い、毛髪のダメージ度がアップしており、以前にもましてヘアリンスやヘアトリートメントによる毛髪に対するコンディショニング効果が求められている。 On the other hand, with the increase in the hair color population in recent years, the degree of damage to hair has increased, and the conditioning effect on hair by hair rinsing and hair treatment has been demanded more than before.
しかし、従来使用されてきた上記のカチオン性界面活性剤や、エステルクワットの使用だけでは、毛髪に対して十分な柔軟性と平滑性、疎水化効果を付与することはできず、特に乾燥(ドライ)後の櫛通りや髪の滑らかさの付与が十分ではなかった。 However, the use of the above-described cationic surfactants and ester quats alone cannot impart sufficient flexibility, smoothness and hydrophobizing effect to the hair. ) Subsequent combing and hair smoothness were not sufficient.
本発明は、上記従来の問題点を解決し、髪質に関係なく、すすぎ時の滑らかさ・しなやかさ、ドライ後の使用感(しっとり感、滑らかさ、しなやかさ)に優れるとともに、組成物の安定性にも優れる毛髪化粧料(ヘアリンス、ヘアトリートメント等)を提供することを目的とする。 The present invention solves the above-mentioned conventional problems, and is excellent in smoothness and suppleness at the time of rinsing, and feeling after use (moistness, smoothness, suppleness) regardless of the quality of the hair. It aims at providing hair cosmetics (hair rinse, hair treatment, etc.) which are excellent also in stability.
本発明者らは、特定のアミノ変性シリコーンと、特定のエステルクワットを組合せ配合することにより、上記従来の問題点を解決し得ることを見出し、本発明を完成するに至った。 The present inventors have found that the above conventional problems can be solved by combining a specific amino-modified silicone and a specific ester quat, and have completed the present invention.
すなわち本発明は、(a)下記一般式(I)で示されるエステルクワットと、(b)重合度110〜5000のアミノ変性シリコーンを含有する、毛髪化粧料を提供する。 That is, the present invention provides a hair cosmetic comprising (a) an ester quat represented by the following general formula (I) and (b) an amino-modified silicone having a polymerization degree of 110 to 5000.
(式(I)中、R1COは、炭素原子数が12〜22で、二重結合を0、1、2または3個有する脂肪族アミル基を示し、kは2または3の数を示し、Xはハロゲン化合物、メトスルフェートまたはメトホスフェートを示す。)
また本発明は、(b)成分が下記一般式(II)で示されるアミノ変性シリコーンである、上記毛髪化粧料を提供する。
(In the formula (I), R 1 CO represents an aliphatic amyl group having 12 to 22 carbon atoms and having 0, 1, 2, or 3 double bonds, and k represents a number of 2 or 3. , X represents a halogen compound, methosulfate or methophosphate.)
The present invention also provides the above-described hair cosmetic, wherein the component (b) is an amino-modified silicone represented by the following general formula (II).
(式(II)中、Qは−Hまたは−(CH2)2NH2を示し、m=100〜5000の数を示し、n=1〜100の数を示し、m+n=110〜5000の数を示す。) (In Formula (II), Q represents —H or — (CH 2 ) 2 NH 2 , represents a number of m = 100 to 5000, represents a number of n = 1 to 100, and represents a number of m + n = 110 to 5000. Is shown.)
また本発明は、(b)成分がエマルションの形態で配合されている、上記毛髪化粧料を提供する。 Moreover, this invention provides the said hair cosmetics with which (b) component is mix | blended with the form of the emulsion.
また本発明は、(a)成分を0.01〜10質量%、(b)成分を0.001〜5質量%(固形分)含有する、上記毛髪化粧料を提供する。 Moreover, this invention provides the said hair cosmetics which contain 0.01-10 mass% of (a) component, and 0.001-5 mass% (solid content) of (b) component.
また本発明は、さらに(c)高級アルコールを含有する、上記毛髪化粧料を提供する。 The present invention further provides the hair cosmetic described above, further comprising (c) a higher alcohol.
また本発明は、(c)成分を1〜20質量%含有する、上記毛髪化粧料を提供する。 Moreover, this invention provides the said hair cosmetics containing 1-20 mass% of (c) component.
本発明により、組成物の安定性、すすぎ時の滑らかさ・しなやかさ、ドライ後の使用感(しっとり感、滑らかさ、しなやかさ)に優れる毛髪化粧料に関する。本発明毛髪化粧料は特に、ダメージヘア(ブリーチヘアなど)に対して優れた機能を有する。 The present invention relates to a hair cosmetic that is excellent in the stability of the composition, the smoothness and suppleness during rinsing, and the feeling after use (moistness, smoothness, and suppleness) after drying. The hair cosmetic composition of the present invention has an excellent function especially for damaged hair (such as bleach hair).
本発明毛髪化粧料において、(a)成分として下記一般式(I)で示されるエステルクワットが用いられる。 In the hair cosmetic composition of the present invention, an ester quat represented by the following general formula (I) is used as the component (a).
式(I)中、R1COは、炭素原子数が12〜22で、二重結合を0、1、2または3個有する脂肪族アミル基を示す。 In the formula (I), R 1 CO represents an aliphatic amyl group having 12 to 22 carbon atoms and having 0, 1, 2, or 3 double bonds.
kは2または3の数を示す。 k represents a number of 2 or 3.
Xはハロゲン化合物、メトスルフェートまたはメトホスフェートを示す。 X represents a halogen compound, methosulfate or methophosphate.
(a)成分としては、ヤシ油脂肪酸系エステルクワットのハロゲン化物またはメトスルフェートが特に好ましい。 As the component (a), a coconut oil fatty acid ester quat halide or methosulfate is particularly preferable.
(a)成分の配合量は、毛髪化粧料全量に対し、0.01〜10質量%が好ましく、より好ましくは0.1〜6質量%である。0.001質量%未満では、組成物の安定性の点で好ましくなく、一方、10質量%を超えて配合すると、すすぎ時にぬるつく、ドライ後にごわつく等、感触の点で好ましくない。 (A) As for the compounding quantity of a component, 0.01-10 mass% is preferable with respect to hair cosmetics whole quantity, More preferably, it is 0.1-6 mass%. If it is less than 0.001% by mass, it is not preferable from the viewpoint of the stability of the composition. On the other hand, if it exceeds 10% by mass, it is not preferable from the viewpoint of feeling such as being greasy at the time of rinsing and stiff after drying.
本発明毛髪化粧料において、(b)成分として重合度110〜5000のアミノ変性シリコーンが用いられる。当該アミノ変性シリコーンとしては、下記一般式(II)で示されるシリコーンが好ましく用いられる。 In the hair cosmetic composition of the present invention, amino-modified silicone having a polymerization degree of 110 to 5000 is used as the component (b). As the amino-modified silicone, a silicone represented by the following general formula (II) is preferably used.
上記式(II)中、Qは−Hまたは−(CH2)2NH2を示す。 In the above formula (II), Q represents —H or — (CH 2 ) 2 NH 2 .
mは100〜5000の数を示し、好ましくは1000〜3000の数を示す。 m shows the number of 100-5000, Preferably it shows the number of 1000-3000.
nは1〜100の数を示し、好ましくは1〜10の数を示す。 n shows the number of 1-100, Preferably the number of 1-10 is shown.
m+nは110〜5000の数を示し、好ましくは1000〜3000の数を示す。m+nが110未満ではドライ後の使用感(しっとり感、しなやかさ)が不十分となり、一方、5000超では組成物の安定性、特に高温安定性の点で、好ましくない。 m + n shows the number of 110-5000, Preferably it shows the number of 1000-3000. If m + n is less than 110, the feeling after use (moist feeling, suppleness) after drying becomes insufficient. On the other hand, if it exceeds 5000, it is not preferable from the viewpoint of stability of the composition, particularly stability at high temperature.
本発明において、(b)成分の毛髪化粧料中への配合方法は、特に制限されるものではないが、(b)成分をあらかじめ乳化しエマルションとして添加する方法が好ましい。このような方法を用いることにより、組成物中に分散される(b)成分の粒子径の制御が容易となり、付与する触感が調整しやすくなる。 In the present invention, the blending method of the component (b) in the hair cosmetic is not particularly limited, but a method of emulsifying the component (b) in advance and adding it as an emulsion is preferable. By using such a method, the particle diameter of the component (b) dispersed in the composition can be easily controlled, and the tactile sensation to be imparted can be easily adjusted.
エマルションの製造には、公知の方法を用いることができ、例えば、コロイドミル、ラインミル、ホモミキサー、ホモジナイザーなどの乳化機や、アンカーミキサーと、ホモミキサーまたはディスパーミキサーが一体となった乳化機などを用いて行うことができる。 A known method can be used for producing the emulsion. For example, an emulsifier such as a colloid mill, a line mill, a homomixer, or a homogenizer, or an emulsifier in which an anchor mixer and a homomixer or a dispermixer are integrated. Can be used.
エマルションの製造には界面活性剤および水が使用される。界面活性剤には、特に限定されるものではないが、本発明毛髪化粧料では、カチオン性界面活性剤、ノニオン性界面活性剤、および両性界面活性剤の中から選ばれる1種または2種以上が好適に用いられる。 Surfactant and water are used in the production of the emulsion. Although it does not specifically limit to surfactant, In this invention hair cosmetics, 1 type, or 2 or more types chosen from cationic surfactant, nonionic surfactant, and amphoteric surfactant Are preferably used.
カチオン性界面活性剤としては、ラウリルトリメチルアンモニウムヒドロキシド、ステアリルトリメチルアンモニウムヒドロキシド、ジオクチルジメチルアンモニウムヒドロキシド、ジステアリルジメチルアンモニウムヒドロキシド、塩化ラウリルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウム、塩化セチルトリメチルアンモニウム、塩化ジココイルジメチルアンモニウム、塩化ジステアリルジメチルアンモニウム、塩化ベンザルコニウム、塩化ステアリルジメチルベンジルアンモニウムなどが例示的に挙げられる。ノニオン性界面活性剤としては、POEラウリルエーテル、POE脂肪酸エステル、POEソルビタン脂肪酸エステル、ソルビタン脂肪酸エステル、グリセリン脂肪酸エステル、POE硬化ヒマシ油、POEソルビトール脂肪酸エステルなどが例示的に挙げられる。両性界面活性剤としては、ラウリルアミンオキシド、ラウリルベタイン、ココアミドプロピルベタインなどが例示的に挙げられる。 Cationic surfactants include lauryl trimethyl ammonium hydroxide, stearyl trimethyl ammonium hydroxide, dioctyl dimethyl ammonium hydroxide, distearyl dimethyl ammonium hydroxide, lauryl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, dichloride chloride. Examples thereof include cocoyl dimethyl ammonium, distearyl dimethyl ammonium chloride, benzalkonium chloride, and stearyl dimethyl benzyl ammonium chloride. Examples of nonionic surfactants include POE lauryl ether, POE fatty acid ester, POE sorbitan fatty acid ester, sorbitan fatty acid ester, glycerin fatty acid ester, POE hydrogenated castor oil, POE sorbitol fatty acid ester, and the like. Examples of amphoteric surfactants include laurylamine oxide, lauryl betaine, cocoamidopropyl betaine, and the like.
これら界面活性剤の配合量は、エマルション全体の1〜40質量%の範囲が好ましく、より好ましくは5〜20質量%である。1質量%未満では、各成分を良好に分散させることが困難になり、また40質量%を超えるとエマルションの安定性が低下する。 The blending amount of these surfactants is preferably in the range of 1 to 40% by mass, more preferably 5 to 20% by mass of the whole emulsion. If it is less than 1% by mass, it is difficult to disperse each component well, and if it exceeds 40% by mass, the stability of the emulsion is lowered.
また、エマルションの分散媒としての水の配合量は、エマルション全体の20〜90質量%の範囲が好ましく、より好ましくは40〜80質量%である。 Moreover, the blending amount of water as a dispersion medium of the emulsion is preferably in the range of 20 to 90% by mass, more preferably 40 to 80% by mass of the whole emulsion.
またエマルションの安定性を改善するため、エマルション中に酸を配合してもよい。酸としては、酢酸、乳酸などの有機酸;塩酸、硫酸、リン酸などの無機酸が使用される。このような酸は、アミノ基を含有するポリオルガノシロキサンのアミノ基部分を酸で中和し、エマルションの安定性を改善する。 Moreover, in order to improve the stability of an emulsion, you may mix | blend an acid in an emulsion. As the acid, organic acids such as acetic acid and lactic acid; inorganic acids such as hydrochloric acid, sulfuric acid and phosphoric acid are used. Such an acid neutralizes the amino group portion of the polyorganosiloxane containing amino groups with an acid, thereby improving the stability of the emulsion.
(b)成分の配合量(固形分)は、毛髪化粧料全量に対し、0.001〜5質量%が好ましく、より好ましくは0.01〜3質量%である。0.001質量%未満では、感触(ドライ後のしなやかさ、滑らかさ)の点で好ましくなく、一方、5質量%を超えて配合すると、組成物の安定性、特に高温安定性の点で好ましくない。 (B) As for the compounding quantity (solid content) of a component, 0.001-5 mass% is preferable with respect to hair cosmetics whole quantity, More preferably, it is 0.01-3 mass%. If it is less than 0.001% by mass, it is not preferable in terms of touch (flexibility after drying, smoothness), whereas if it exceeds 5% by mass, it is preferable in terms of stability of the composition, particularly high temperature stability. Absent.
本発明毛髪化粧料では、さらに所望により(c)成分として高級アルコールを配合してもよい。高級アルコールとしては、一般に化粧料に配合され得るものであれば特に限定されるものでなく、例えば、飽和直鎖一価アルコール、不飽和一価アルコールなどが挙げられる。飽和直鎖一価アルコールとしては、ドデカノール(=ラウリルアルコール)、トリデカノール、テトラデカノール(=ミリスチルアルコール)、ペンタデカノール、ヘキサデカノール(=セチルアルコール)、ヘプタデカノール、オクタデカノール(=ステアリルアルコール)、ノナデカノール、イコサノール(=アラキルアルコール)、ヘンイコサノール、ドコサノール(=ベヘニルアルコール)、トリコサノール、テトラコサノール(=カルナービルアルコール)、ペンタコサノール、ヘキサコサノール(=セリルアルコール)等が挙げられる。(c)成分は1種または2種以上を用いることができる。 In the hair cosmetic composition of the present invention, a higher alcohol may be further blended as component (c) if desired. The higher alcohol is not particularly limited as long as it can be generally blended into cosmetics, and examples thereof include saturated linear monohydric alcohols and unsaturated monohydric alcohols. As saturated linear monohydric alcohols, dodecanol (= lauryl alcohol), tridecanol, tetradecanol (= myristyl alcohol), pentadecanol, hexadecanol (= cetyl alcohol), heptadecanol, octadecanol (= stearyl) Alcohol), nonadecanol, icosanol (= aralkyl alcohol), heicosanol, docosanol (= behenyl alcohol), tricosanol, tetracosanol (= carnervir alcohol), pentacosanol, hexacosanol (= seryl alcohol) and the like. (C) A component can use 1 type (s) or 2 or more types.
(c)成分を配合する場合、毛髪化粧料全量に対し、1〜20質量%が好ましく、より好ましくは3〜15質量%である。(c)成分を上記範囲で配合することによりすすぎ時の滑らかさをより一層高めることができる。 (C) When mix | blending a component, 1-20 mass% is preferable with respect to hair cosmetics whole quantity, More preferably, it is 3-15 mass%. By blending the component (c) in the above range, the smoothness during rinsing can be further enhanced.
本発明の毛髪化粧料には、本願発明の効果を損なわない範囲において、他の添加成分を任意に配合し得る。このような成分としては、例えば、流動パラフィン、スクワラン、ラノリン誘導体、各種エステル油などの油分;ヒアルロン酸、コンドロイチン酸、ピロリドンカルボン酸、イソプレングリコールなどの保湿剤;pH調整剤;紫外線吸収剤などが配合される。 In the hair cosmetic composition of the present invention, other additive components can be arbitrarily blended within a range not impairing the effects of the present invention. Examples of such components include oils such as liquid paraffin, squalane, lanolin derivatives, and various ester oils; moisturizers such as hyaluronic acid, chondroitinic acid, pyrrolidone carboxylic acid, and isoprene glycol; pH adjusters; ultraviolet absorbers, and the like. Blended.
本発明の毛髪化粧料は、例えばヘアリンス、ヘアトリートメント等として好適に用いられる。 The hair cosmetic composition of the present invention is suitably used, for example, as hair rinse, hair treatment and the like.
本発明について以下に実施例を挙げてさらに詳述するが、本発明はこれによりなんら限定されるものではない。配合量は特記しない限り、その成分が配合される系に対する質量%で示す。 The present invention will be described in more detail with reference to the following examples, but the present invention is not limited thereto. Unless otherwise specified, the blending amount is expressed in mass% with respect to the system in which the component is blended.
まず本実施例で用いた試験法、評価基準を以下に示す。 First, the test methods and evaluation criteria used in this example are shown below.
[組成物の安定性]
被験試料100gを市販スクリュー管100mL容器に充填し、50℃の高温槽に2ヶ月間放置した後の外観を観察し、以下の通り評価した。
(評価)
○:下部に透明部分がみられなかった
△:下部に厚さ2mm未満の透明層がみられた
×:下部に厚さ2mm未満の透明層がみられた
[Composition stability]
100 g of the test sample was filled in a 100 mL commercial screw tube, and the appearance after being left in a high-temperature bath at 50 ° C. for 2 months was observed and evaluated as follows.
(Evaluation)
○: No transparent portion was seen in the lower part Δ: A transparent layer having a thickness of less than 2 mm was seen in the lower part ×: A transparent layer having a thickness of less than 2 mm was seen in the lower part
[すすぎ時の滑らかさ]
被験試料の洗髪実使用テストを専門パネル(女性20名)によりしてもらい、すすぎ時の髪の滑らかさについて、評価した。
(評価)
◎:20名中、17名以上が、滑らかであると回答
○:20名中、13〜16名が、滑らかであると回答
△:20名中、7〜12名が、滑らかであると回答
×:20名中、6名以下が、滑らかであると回答
[Smoothness when rinsing]
A test panel was used by a specialized panel (20 women) to evaluate the hair smoothness during rinsing.
(Evaluation)
◎: Among 20 people, 17 or more responded that it was smooth. ○: Among 20 people, 13-16 answered that it was smooth. △: Among 20 people, 7-12 answered that it was smooth. ×: Out of 20, 6 or less responded that it was smooth
[すすぎ時のしなやかさ]
被験試料の洗髪実使用テストを専門パネル(女性20名)によりしてもらい、すすぎ時の髪のしなやかさについて、評価した。
(評価)
◎:20名中、17名以上が、しなやかであると回答
○:20名中、13〜16名が、しなやかであると回答
△:20名中、7〜12名が、しなやかであると回答
×:20名中、6名以下が、しなやかであると回答
[Flexibility when rinsing]
A test panel was used for a hair washing actual use test by a specialized panel (20 women), and the suppleness of the hair at the time of rinsing was evaluated.
(Evaluation)
◎: Of 20 people, 17 or more responded that they were pliable ○: 13 out of 20 people answered that they were pliable △: 7-20 of 20 people answered that they were supple ×: Out of 20, 6 or less responded that they were supple
[ドライ後のしっとり感]
被験試料で洗髪、乾燥後の髪のしっとり感の有無を専門パネル(女性20名。ダメージヘア(ブリーチヘア))により実使用テストしてもらい、洗髪後自然乾燥させた後の髪のしっとり感と洗髪前の状態を比較法により官能評価した。
(評価)
◎:20名中、17名以上が、洗髪前よりもしっとり感があると回答
○:20名中、13〜16名が、洗髪前よりもしっとり感があると回答
△:20名中、7〜12名が、洗髪前よりもしっとり感があると回答
×:20名中、6名以下が、洗髪前よりもしっとり感があると回答
[Moist feeling after drying]
The test sample was used to test whether the hair was moist after drying and drying with a professional panel (20 women. Damaged hair (bleach hair)), and after the hair was washed and naturally dried, The state before washing was subjected to sensory evaluation by a comparative method.
(Evaluation)
◎: Among 20 people, 17 or more responded that they were moist than before washing. ○: Among 20 people, 13 to 16 answered that they were moist than before washing. △: Among 20 people, 7 ~ 12 respondents said that they had a moist feeling before shampooing ×: Out of 20, 6 or less responded that they had a moist feeling before shampooing
[ドライ後の滑らかさ]
被験試料で洗髪、乾燥後の髪の滑らかさの有無を専門パネル(女性20名。ダメージヘア(ブリーチヘア))により実使用テストしてもらい、洗髪後自然乾燥させた後の髪の滑らかさと洗髪前の状態を比較法により官能評価した。
(評価)
◎:20名中、17名以上が、洗髪前よりも滑らかであると回答
○:20名中、13〜16名が、洗髪前よりも滑らかであると回答
△:20名中、7〜12名が、洗髪前よりも滑らかであると回答
×:20名中、6名以下が、洗髪前よりも滑らかであると回答
[Smoothness after drying]
The test sample was shampooed and the hair was smooth after dying and was subjected to an actual use test by a professional panel (20 women. Damaged hair (bleach hair)). The previous state was sensory-evaluated by the comparative method.
(Evaluation)
◎: Among 20 people, 17 or more responded that it was smoother than before shampooing ○: Among 20 people, 13-16 answered that it was smoother before shampooing △: Among 20 people, 7-12 Name is answered that it is smoother than before shampooing ×: Six out of 20 people answered that it is smoother than before shampooing
[ドライ後のしなやかさ]
被験試料で洗髪、乾燥後の髪のしなやかさの有無を専門パネル(女性20名。ダメージヘア(ブリーチヘア))により実使用テストしてもらい、洗髪後自然乾燥させた後の髪のしなやかさと洗髪前の状態を比較法により官能評価した。
(評価)
◎:20名中、17名以上が、洗髪前よりもしなやかさがあると回答
○:20名中、13〜16名が、洗髪前よりもしなやかさがあると回答
△:20名中、7〜12名が、洗髪前よりもしなやかさがあると回答
×:20名中、6名以下が、洗髪前よりもしなやかさがあると回答
[Flexibility after drying]
The test sample was shampooed and dried, and the hair was supple and soft, and a professional panel (20 women. Damaged hair (bleach hair)) was tested for actual use. The previous state was sensory-evaluated by the comparative method.
(Evaluation)
◎: Among 20 people, 17 or more responded that they were more supple than before washing. ○: Among 20 people, 13 to 16 answered that they were more supple than before washing. △: Among 20 people, 7 ~ 12 respondents say that there is more flexibility than before shampooing ×: 6 out of 20 respondents said that there is more flexibility than before shampooing
(実施例1〜2、比較例1〜6) (Examples 1-2, Comparative Examples 1-6)
下記表1に示す組成の洗浄料組成物を調製した。これらを被検試料として、上記試験法、評価基準に基づき、各項目を評価した。結果を表1に示す。 A cleaning composition having the composition shown in Table 1 below was prepared. Using these as test samples, each item was evaluated based on the above test method and evaluation criteria. The results are shown in Table 1.
なお表1中、エマルションの形態で配合されているシリコーン類(高重合メチルポリシロキサンエマルション、高重合アミノエチルアミノプロピルメチルシロキサン・ジメチルシロキサン共重合体エマルション(*)、高重合アミノエチルアミノプロピルシロキサン・ジメチルシロキサン共重合体エマルション(**)、高重合ジメチルシロキサン・メチル(アミノプロピル)シロキサン共重合体エマルション(***))の各配合量は、エマルションとしての配合量で示した。したがって、例えば実施例1において、「高重合アミノエチルアミノプロピルシロキサン・ジメチルシロキサン共重合体エマルション(重合度:約1500、純分:70.0質量%)」の配合量「1.0(質量%)」は、固形分配合量(=実分、純分)0.7質量%である。 In Table 1, silicones blended in the form of emulsion (highly polymerized methylpolysiloxane emulsion, highly polymerized aminoethylaminopropylmethylsiloxane / dimethylsiloxane copolymer emulsion (*) , highly polymerized aminoethylaminopropylsiloxane, The blending amounts of dimethylsiloxane copolymer emulsion (**) and highly polymerized dimethylsiloxane / methyl (aminopropyl) siloxane copolymer emulsion (***) ) are shown as blending amounts as emulsions. Therefore, for example, in Example 1, the compounding amount of “highly polymerized aminoethylaminopropylsiloxane / dimethylsiloxane copolymer emulsion (polymerization degree: about 1500, pure content: 70.0% by mass)” “1.0 (% by mass) ) ”Is 0.7% by mass of solid content (= actual component, pure component).
また表1中、高重合アミノ変性シリコーンエマルションは、それぞれ以下のものを用いた。 In Table 1, the following highly polymerized amino-modified silicone emulsions were used.
《高重合アミノエチルアミノプロピルメチルシロキサン・ジメチルシロキサン共重合体エマルション(*)》
上記一般式(II)(式(II)式中、m=1000〜1500、n=2〜5、Qは−(CH2)2NH2を示す)で表されるアミノ変性シリコーン(70.0質量%)をカチオン界面活性剤(4級化アンモニウム塩)にて乳化したエマルションを用いた。
<Highly polymerized aminoethylaminopropylmethylsiloxane / dimethylsiloxane copolymer emulsion (*) >
Amino-modified silicone (70.0) represented by the above general formula (II) (wherein m = 1000 to 1500, n = 2 to 5, Q represents — (CH 2 ) 2 NH 2 ) (Mass%) was emulsified with a cationic surfactant (quaternized ammonium salt).
《高重合アミノエチルアミノプロピルシロキサン・ジメチルシロキサン共重合体エマルション(**)》
下記一般式(III)(式(III)中、r=100、s=3)で表されるアミノ変性シリコーン(40.0質量%)をカチオン界面活性剤(4級化アンモニウム塩)にて乳化したエマルションを用いた。
<Highly polymerized aminoethylaminopropylsiloxane / dimethylsiloxane copolymer emulsion (**) >
An amino-modified silicone (40.0 mass%) represented by the following general formula (III) (r = 100, s = 3 in formula (III)) is emulsified with a cationic surfactant (quaternized ammonium salt). The emulsion used was used.
《高重合ジメチルシロキサン・メチル(アミノプロピル)シロキサン共重合体エマルション(***)》
下記一般式(IV)(式(IV)中、t=10000、u=10)で表されるアミノ変性シリコーン(14.6質量%)をカチオン界面活性剤(4級化アンモニウム塩)にて乳化したエマルションを用いた。
《Highly polymerized dimethylsiloxane ・ methyl (aminopropyl) siloxane copolymer emulsion (***) 》
An amino-modified silicone (14.6% by mass) represented by the following general formula (IV) (in formula (IV), t = 10000, u = 10) is emulsified with a cationic surfactant (quaternized ammonium salt). The emulsion used was used.
表1に示す結果から明らかなように、本願発明構成要件を満足する実施例1、2の系では、組成物の安定性、すすぎ時の滑らかさ・しなやかさ、ドライ後のしっとり感・滑らかさ・しなやかさのいずれの点においても、優れた効果を得ることができた。これに対し、本願発明の構成要件を満足しない比較例1〜6では、これら効果をすべて併せもつことができなかった。 As is apparent from the results shown in Table 1, in the systems of Examples 1 and 2 that satisfy the constituent requirements of the present invention, the stability of the composition, the smoothness and suppleness during rinsing, and the moist feeling and smoothness after drying. -An excellent effect could be obtained in any point of suppleness. On the other hand, Comparative Examples 1 to 6 that do not satisfy the constituent requirements of the present invention could not have all these effects.
Claims (6)
(式(I)中、R1COは、炭素原子数が12〜22で、二重結合を0、1、2または3個有する脂肪族アミル基を示し、kは2または3の数を示し、Xはハロゲン化合物、メトスルフェートまたはメトホスフェートを示す。) A hair cosmetic comprising (a) an ester quat represented by the following general formula (I) and (b) an amino-modified silicone having a polymerization degree of 110 to 5000.
(In the formula (I), R 1 CO represents an aliphatic amyl group having 12 to 22 carbon atoms and having 0, 1, 2, or 3 double bonds, and k represents a number of 2 or 3. , X represents a halogen compound, methosulfate or methophosphate.)
(式(II)中、Qは−Hまたは−(CH2)2NH2を示し、m=100〜5000の数を示し、n=1〜100の数を示し、m+n=110〜5000の数を示す。) The hair cosmetic composition according to claim 1, wherein the component (b) is an amino-modified silicone represented by the following general formula (II).
(In Formula (II), Q represents —H or — (CH 2 ) 2 NH 2 , represents a number of m = 100 to 5000, represents a number of n = 1 to 100, and represents a number of m + n = 110 to 5000. Is shown.)
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007112787A (en) * | 2005-09-20 | 2007-05-10 | Shiseido Co Ltd | Hair cosmetic |
JP2007161595A (en) * | 2005-12-09 | 2007-06-28 | Shiseido Co Ltd | Hair cosmetic |
US9849309B2 (en) | 2011-11-29 | 2017-12-26 | Dow Corning Corporation | Aminofunctional organosiloxanes |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007112787A (en) * | 2005-09-20 | 2007-05-10 | Shiseido Co Ltd | Hair cosmetic |
JP4627055B2 (en) * | 2005-09-20 | 2011-02-09 | 株式会社資生堂 | Hair cosmetics |
JP2007161595A (en) * | 2005-12-09 | 2007-06-28 | Shiseido Co Ltd | Hair cosmetic |
US9849309B2 (en) | 2011-11-29 | 2017-12-26 | Dow Corning Corporation | Aminofunctional organosiloxanes |
US10143862B2 (en) | 2011-11-29 | 2018-12-04 | Dow Silicones Corporation | Aminofunctional Silicone Emulsions |
US10245451B2 (en) | 2011-11-29 | 2019-04-02 | Dow Silicones Corporation | Aminofunctional organosiloxanes |
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