JP5716356B2 - Hair cosmetics - Google Patents
Hair cosmetics Download PDFInfo
- Publication number
- JP5716356B2 JP5716356B2 JP2010247318A JP2010247318A JP5716356B2 JP 5716356 B2 JP5716356 B2 JP 5716356B2 JP 2010247318 A JP2010247318 A JP 2010247318A JP 2010247318 A JP2010247318 A JP 2010247318A JP 5716356 B2 JP5716356 B2 JP 5716356B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- points
- feeling
- carbon atoms
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003676 hair preparation Substances 0.000 title description 14
- 125000004432 carbon atom Chemical group C* 0.000 claims description 21
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 21
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 21
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 19
- 238000006116 polymerization reaction Methods 0.000 claims description 19
- 125000000217 alkyl group Chemical group 0.000 claims description 17
- 239000002537 cosmetic Substances 0.000 claims description 12
- 229940119170 jojoba wax Drugs 0.000 claims description 11
- 238000002844 melting Methods 0.000 claims description 9
- 230000008018 melting Effects 0.000 claims description 9
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 7
- 125000005843 halogen group Chemical group 0.000 claims description 3
- 239000000203 mixture Substances 0.000 description 19
- 229920001296 polysiloxane Polymers 0.000 description 18
- 238000001035 drying Methods 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 13
- 230000000694 effects Effects 0.000 description 7
- 238000002156 mixing Methods 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- 239000003925 fat Substances 0.000 description 4
- -1 hydroxyethyl group Chemical group 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- YASYEJJMZJALEJ-UHFFFAOYSA-N Citric acid monohydrate Chemical compound O.OC(=O)CC(O)(C(O)=O)CC(O)=O YASYEJJMZJALEJ-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 229960002303 citric acid monohydrate Drugs 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 235000019197 fats Nutrition 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 description 3
- 239000008158 vegetable oil Substances 0.000 description 3
- 206010016322 Feeling abnormal Diseases 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 2
- 235000018936 Vitellaria paradoxa Nutrition 0.000 description 2
- 239000010775 animal oil Substances 0.000 description 2
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical group O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 241000221095 Simmondsia Species 0.000 description 1
- 235000004433 Simmondsia californica Nutrition 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000005764 Theobroma cacao ssp. cacao Nutrition 0.000 description 1
- 235000005767 Theobroma cacao ssp. sphaerocarpum Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 235000001046 cacaotero Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229940082500 cetostearyl alcohol Drugs 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229960004106 citric acid Drugs 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- ZCPCLAPUXMZUCD-UHFFFAOYSA-M dihexadecyl(dimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCC ZCPCLAPUXMZUCD-UHFFFAOYSA-M 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- CDIPRYKTRRRSEM-UHFFFAOYSA-M docosyl(trimethyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C CDIPRYKTRRRSEM-UHFFFAOYSA-M 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000012812 general test Methods 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229940075529 glyceryl stearate Drugs 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 229920006007 hydrogenated polyisobutylene Polymers 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- SZEMGTQCPRNXEG-UHFFFAOYSA-M trimethyl(octadecyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C SZEMGTQCPRNXEG-UHFFFAOYSA-M 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
本発明は、毛髪化粧料に関するものであり、具体的にはヘアコンディショナー、ヘアトリートメント、ヘアリンス、ヘアパック等の毛髪化粧料に関するものである。さらに詳しくは、毛髪に塗布した際に、毛髪と指の間に厚みを与えて優れた塗布感（リッチ感）を有しながらも、乾燥後にべたつかず、毛髪にハリ・コシやうるおい（しっとり感）を与え、かつ、指通り性やまとまり性に優れる毛髪化粧料に関するものである。 The present invention relates to hair cosmetics, and specifically to hair cosmetics such as hair conditioners, hair treatments, hair rinses, and hair packs. More specifically, when it is applied to the hair, it gives a thickness between the hair and fingers and has an excellent coating feeling (rich feeling), but does not become sticky after drying, and the hair is firm, firm and moist (moist feeling) ) And is excellent in finger cosmetics and cohesiveness.
毛髪は、ドライヤーの熱、紫外線等の外的な要因や、パーマやヘアカラー、ブリーチ等の化学処理によって日々損傷を受けており、また加齢に伴って、艶やハリ・コシがなくなったり、まとまり性が悪くなったりする。近年、シャンプーによる洗髪回数の増加により、毛髪の油分が失われがちとなり、損傷毛となりやすくなっている。そのため、洗髪後に使用するインバス用の毛髪化粧料、例えばヘアコンディショナーやヘアトリートメント、ヘアリンス、ヘアパック等の毛髪化粧料、ヘアミルク、ヘアクリーム等のアウトバス用の毛髪化粧料を使用することで、傷んだ毛髪を補修して、まとまり性を良くし、艶やハリ・コシの付与といったコンディショニング効果を発揮し、健やかな髪を保たせようとしている。 Hair is damaged daily by external factors such as the heat of the dryer, UV rays, and chemical treatments such as perms, hair colors, bleach, etc. The cohesiveness becomes worse. In recent years, with the increase in the number of shampooing, the oil content of the hair tends to be lost, and the hair tends to be damaged. Therefore, the use of in-bath hair cosmetics used after washing, such as hair conditioners, hair treatments, hair rinses, hair packs, etc., out-bath hair cosmetics such as hair milk, hair creams, etc. It is trying to maintain healthy hair by repairing the hair, improving the cohesiveness, and exerting conditioning effects such as gloss and firmness.
これらの効果を発揮するために、各種シリコーン化合物、カチオン性界面活性剤、炭化水素やエステル油、動植物油脂などの油性成分を適宜配合した各種毛髪化粧料が提案されている。例えば、特許文献１には、アミノ変性シリコーン、炭化水素油、植物油およびポリオキシアルキレングリセリルエーテルを含有する毛髪化粧料が提案されている。しかしながら、この毛髪化粧料は傷んだ毛髪を修復してまとまり性を付与できるものの、毛髪のハリ・コシが不足したり、うるおいが不足したりするという問題があった。さらに、乾燥後にべたついたり、指通り性が不十分であった。 In order to exert these effects, various hair cosmetics have been proposed in which various silicone compounds, cationic surfactants, oily components such as hydrocarbons, ester oils, animal and vegetable oils and fats are appropriately blended. For example, Patent Document 1 proposes a hair cosmetic containing amino-modified silicone, hydrocarbon oil, vegetable oil, and polyoxyalkylene glyceryl ether. However, although this hair cosmetic can repair damaged hair and impart cohesiveness, it has problems such as lack of elasticity and moisture of hair. Furthermore, it was sticky after drying, and the fingering property was insufficient.
特許文献２には、重合度の異なる２種のジメチルポリシロキサン、アミノ変性シリコーン、第４級アンモニウム塩を配合した毛髪化粧料が提案され、特許文献３には、シリコーン化合物、カチオン性界面活性剤、水溶性高分子、シア脂を配合した毛髪化粧料が提案されている。しかしこれらの毛髪化粧料はべたつきがなく、毛髪にハリ・コシやうるおいを付与することができるものの、使用した際に化粧料の塗布感が十分に得られず物足りなさを感じる場合があった。さらに乾燥後の指通りやまとまり性において、十分に満足のできるものではなく、改善する余地があった。 Patent Document 2 proposes a hair cosmetic containing two types of dimethylpolysiloxane, amino-modified silicone, and quaternary ammonium salt having different polymerization degrees. Patent Document 3 discloses a silicone compound and a cationic surfactant. Hair cosmetics containing water-soluble polymers and shea fats have been proposed. However, these hair cosmetics have no stickiness and can impart firmness, firmness and moisture to the hair, but when used, the cosmetics cannot be sufficiently applied and sometimes feel unsatisfactory. Furthermore, the finger-sticking and cohesiveness after drying is not fully satisfactory, and there is room for improvement.
本発明は、上記の課題に鑑み、毛髪に塗布した際に、毛髪と指の間に厚みを与えて優れた塗布感（リッチ感）を有しながらも、乾燥後にべたつかず、毛髪にハリ・コシやうるおい（しっとり感）を与え、かつ、指通り性やまとまり性に優れる毛髪化粧料を提供することを目的とする。 In view of the above-described problems, the present invention provides an excellent coating feeling (rich feeling) by applying a thickness between hair and fingers when applied to hair, but does not become sticky after drying. An object of the present invention is to provide a hair cosmetic that gives firmness and moisture (moist feeling) and is excellent in fingering and cohesiveness.
本発明者らは、上記課題を解決するために鋭意検討した結果、（Ａ）シリコーン又はシリコーン誘導体、（Ｂ）第４級アンモニウム塩とともに、（Ｃ）炭素数が１４〜２２の直鎖のアルコール、（Ｄ）融点が４０〜６０℃である水添ホホバ油を特定の比率で組み合わせることで、上記課題を解決することができる毛髪化粧料が得られることを見出し、本発明を完成するに至った。 As a result of intensive studies to solve the above problems, the present inventors have found that (A) silicone or a silicone derivative, (B) a quaternary ammonium salt, and (C) a linear alcohol having 14 to 22 carbon atoms. (D) It discovered that the hair cosmetics which can solve the said subject were obtained by combining hydrogenated jojoba oil whose melting | fusing point is 40-60 degreeC with a specific ratio, and came to complete this invention. It was.
すなわち、本発明は、（Ａ）平均重合度が１０００〜５０００であるジメチルポリシロキサン又はジメチルポリシロキサン誘導体を０．１〜３質量％、（Ｂ）式１で示される第４級アンモニウム塩を０．３〜５質量％、（Ｃ）炭素数が１４〜２２の直鎖のアルコールを１〜１０質量％、（Ｄ）融点が４０〜６０℃である水添ホホバ油を０．３〜３質量％で含有し、（Ｂ）、（Ｃ）および（Ｄ）の含有量が（Ｃ）≧（Ｂ）かつ（Ｃ）≧（Ｄ）であることを特徴とする毛髪化粧料である。 That is, the present invention, (A) an average degree of polymerization of 0.1 to 3% by weight of dimethyl polysiloxane or dimethyl polysiloxane derivative is 1000-5000, the quaternary ammonium salt represented by the formula (B) 1 0 3 to 5% by mass, (C) 1 to 10% by mass of linear alcohol having 14 to 22 carbon atoms, and (D) 0.3 to 3% of hydrogenated jojoba oil having a melting point of 40 to 60 ° C. % , And the contents of (B), (C) and (D) are (C) ≧ (B) and (C) ≧ (D).
（式中Ｒ１は炭素数１６〜２４の直鎖のアルキル基を表し、Ｒ2は炭素数１６〜２４の直鎖のアルキル基、炭素数１〜３のアルキル基もしくはヒドロキシアルキル基を表し、Ｒ３，Ｒ４はそれぞれ独立して炭素数１〜３のアルキル基もしくはヒドロキシアルキル基を表し、Ｘはハロゲン原子を表す。） (Wherein R 1 represents a linear alkyl group having 16 to 24 carbon atoms, R 2 represents a linear alkyl group having 16 to 24 carbon atoms, an alkyl group having 1 to 3 carbon atoms, or a hydroxyalkyl group; R 3 and R 4 each independently represents an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group, and X represents a halogen atom.)
本発明の毛髪化粧料によれば、毛髪に塗布した際に、毛髪と指の間に厚みを与えて優れた塗布感（リッチ感）を有しながらも、乾燥後にべたつかず、毛髪にハリ・コシやうるおい（しっとり感）を与え、かつ、指通り性やまとまり性に優れるという効果が得られる。 According to the hair cosmetic composition of the present invention, when applied to the hair, it gives a thickness between the hair and fingers and has an excellent feeling of application (rich feeling), but does not become sticky after drying. The effect of giving firmness and moisture (moist feeling) and excellent in fingering and cohesiveness is obtained.
以下、本発明の実施形態を説明する。本発明の毛髪化粧料は、下記（Ａ）成分〜（Ｄ）成分を含有する。 Embodiments of the present invention will be described below. The hair cosmetic composition of the present invention contains the following components (A) to (D).
〔（Ａ）シリコーン又はシリコーン誘導体〕
本発明に用いられる（Ａ）シリコーンはジメチルポリシロキサンを意味し、シリコーン誘導体はジメチルポリシロキサン誘導体を意味する。ジメチルポリシロキサン誘導体はジメチルポリシロキサン骨格にアミノ基、アルキル基、ポリエーテル基、カチオン基などを導入した各種変性ジメチルポリシロキサンを意味する。シリコーン又はシリコーン誘導体の分子量（重合度）については、低分子量のシリコーン油からシリコーングリース、シリコーンゴム、シリコーン樹脂（ケイ素樹脂）といった高分子量のものが使用できるが、本発明においては乾燥時の毛髪の指通り性を与える効果から、好ましくは平均重合度が１０００〜５０００のジメチルポリシロキサン又はジメチルポリシロキサン誘導体であり、更に好ましくは平均重合度が２０００〜５０００のジメチルポリシロキサン又はジメチルポリシロキサン誘導体である。平均重合度が１０００未満では十分な指通り性が得られない場合がある。一方、平均重合度が５０００を超えると、十分なハリ・コシが得られない場合があり、また油性成分との相溶性が悪くなるため、十分な経時安定性が得られない場合がある。これらのジメチルポリシロキサン又はジメチルポリシロキサン誘導体を２種類以上組み合わせることも可能である。
[(A) Silicone or silicone derivative]
The (A) silicone used in the present invention means dimethylpolysiloxane, and the silicone derivative means a dimethylpolysiloxane derivative. The dimethylpolysiloxane derivative means various modified dimethylpolysiloxanes in which an amino group, an alkyl group, a polyether group, a cationic group, or the like is introduced into a dimethylpolysiloxane skeleton. With respect to the molecular weight (degree of polymerization) of silicone or silicone derivatives, low molecular weight silicone oils to high molecular weights such as silicone grease, silicone rubber, and silicone resin (silicon resin) can be used. from the effects of giving the finger combing properties, is preferably a dimethyl polysiloxane or dimethyl polysiloxane derivatives having an average polymerization degree of 1,000 to 5,000, more preferably an average polymerization degree of 2000 to 5000 dimethylpolysiloxane or dimethylpolysiloxane derivative . If the average degree of polymerization is less than 1000, sufficient fingering properties may not be obtained. On the other hand, if the average degree of polymerization exceeds 5,000, sufficient tension and stiffness may not be obtained, and compatibility with the oil component may be deteriorated, so that sufficient stability over time may not be obtained. Two or more kinds of these dimethylpolysiloxanes or dimethylpolysiloxane derivatives can be combined.
また、これら平均重合度のシリコーン又はシリコーン誘導体を、作業性の点より、重合度が１０〜１００のジメチルポリシロキサンやデカメチルシクロペンタシロキサン等で希釈したものを使用することも可能である。 Moreover, it is also possible to use what diluted these average degree-of-polymerization silicones or silicone derivatives with dimethylpolysiloxane, decamethylcyclopentasiloxane, etc. with a degree of polymerization of 10-100 from the viewpoint of workability.
〔（Ｂ）第４級アンモニウム塩〕
本発明に用いられる（Ｂ）第４級アンモニウム塩は、前記式１で示されるものである。式中Ｒ１ は炭素数１６〜２４の直鎖のアルキル基を表し、Ｒ2は炭素数１６〜２４の直鎖のアルキル基、又は炭素数１〜３のアルキル基もしくはヒドロキシアルキル基を表し、Ｒ３，Ｒ４はそれぞれ独立して炭素数１〜３のアルキル基もしくはヒドロキシアルキル基を表す。Ｒ１，Ｒ2 における炭素数１６〜２４の直鎖のアルキル基は、炭素数が好ましくは１８〜２２である。具体的なアルキル基としては、セチル基、ステアリル基、ベヘニル基等が挙げられる。Ｒ2〜Ｒ４における炭素数１〜３のアルキル基もしくは炭素数１〜３のヒドロキシアルキル基の具体例としては、メチル基、エチル基、プロピル基、ヒドロキシメチル基、ヒドロキシエチル基等が挙げられる。Ｘはハロゲン原子を表し、具体的には塩素、臭素、ヨウ素等が挙げられる。（Ｂ）第４級アンモニウム塩は１種又は２種以上を用いることができる。
[(B) Quaternary ammonium salt]
The (B) quaternary ammonium salt used in the present invention is represented by the above formula 1. In the formula, R 1 represents a linear alkyl group having 16 to 24 carbon atoms, R 2 represents a linear alkyl group having 16 to 24 carbon atoms, or an alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms, R 3 and R 4 each independently represents an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group. The linear alkyl group having 16 to 24 carbon atoms in R 1 and R 2 preferably has 18 to 22 carbon atoms. Specific examples of the alkyl group include a cetyl group, a stearyl group, and a behenyl group. Specific examples of the alkyl group having 1 to 3 carbon atoms or the hydroxyalkyl group having 1 to 3 carbon atoms in R 2 to R 4 include a methyl group, an ethyl group, a propyl group, a hydroxymethyl group, and a hydroxyethyl group. . X represents a halogen atom, and specific examples include chlorine, bromine, iodine and the like. (B) Quaternary ammonium salt can use 1 type (s) or 2 or more types.
式１で示される（Ｂ）第４級アンモニウム塩としては、例えば、塩化ステアリルトリメチルアンモニウム、塩化ベヘニルトリメチルアンモニウム、塩化セチルトリメチルアンモニウム、臭化ステアリルトリメチルアンモニウム、臭化ベヘニルトリメチルアンモニウム、臭化セチルトリメチルアンモニウム、塩化ジステアリルジメチルアンモニウム、塩化ジセチルジメチルアンモニウム、等が挙げられる。中でも、毛髪のまとまり性の点において、塩化ステアリルトリメチルアンモニウム、塩化ベヘニルトリメチルアンモニウムが好ましい。 Examples of (B) quaternary ammonium salts represented by Formula 1 include stearyl trimethyl ammonium chloride, behenyl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium bromide, behenyl trimethyl ammonium bromide, cetyl trimethyl ammonium bromide. , Distearyldimethylammonium chloride, dicetyldimethylammonium chloride, and the like. Of these, stearyltrimethylammonium chloride and behenyltrimethylammonium chloride are preferable from the viewpoint of cohesiveness of hair.
〔（Ｃ）アルコール〕
本発明に用いられる（Ｃ）アルコールは、炭素数１４〜２２で直鎖のアルキル基を有するアルコール類を指し、好ましくは炭素数１６〜１８である。具体的には、ミリスチルアルコール、セチルアルコール、ステアリルアルコール、アラキルアルコール、ベヘニルアルコール等や、これらの混合物であるセトステアリルアルコールや水添ナタネ油アルコール等が挙げられる。またこれらの化合物の中から２種類以上を組み合わせることができ、組成物の保存安定性においてアルコールの平均炭素数が１６〜１８となるように組み合わせることが好ましい。
[(C) alcohol]
The (C) alcohol used in the present invention refers to alcohols having a linear alkyl group having 14 to 22 carbon atoms, and preferably 16 to 18 carbon atoms. Specific examples include myristyl alcohol, cetyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol, and the like, and cetostearyl alcohol and hydrogenated rapeseed oil alcohol, which are mixtures thereof. Two or more of these compounds can be combined, and it is preferable to combine them so that the average carbon number of the alcohol is 16 to 18 in the storage stability of the composition.
〔（Ｄ）水添ホホバ油〕
本発明に用いられる（Ｄ）水添ホホバ油は、ホホバ油を融点が４０〜６０℃となるように水素添加したものを指す。融点は、医薬部外品原料規格２００６記載の一般試験法融点測定法第２法の方法により測定した値とする。融点が６０℃を超えるホホバ油を用いた場合、指通り性やまとまり性が悪く、また保存性も悪くなる。本発明に用いられる水添ホホバ油の具体的な製品としては、香栄興業株式会社製の「ホバクリームM-40」が挙げられる。さらに、水添ホホバ油以外の特定の油性成分を併用することができ、毛髪にハリ・コシやうるおい（しっとり感）を付与することができる。特定の油性成分としては、融点が３０〜４０℃の動植物油が挙げられ、具体的には、シア脂、カカオ脂、ムルムル脂、ラノリン等が挙げられる。
[(D) Hydrogenated jojoba oil]
The (D) hydrogenated jojoba oil used in the present invention refers to a hydrogenated jojoba oil having a melting point of 40 to 60 ° C. The melting point is a value measured by the method of the general test method melting point measurement method 2 described in the quasi-drug raw material standard 2006. When jojoba oil having a melting point of more than 60 ° C. is used, the fingering property and cohesiveness are poor, and the storage stability is also deteriorated. Specific examples of the hydrogenated jojoba oil used in the present invention include “Hoba Cream M-40” manufactured by Koei Kogyo Co., Ltd. Furthermore, specific oily components other than hydrogenated jojoba oil can be used in combination, and the hair can be given firmness, moisture and moisture (moist feeling). Specific oil components include animal and vegetable oils having a melting point of 30 to 40 ° C., and specifically include shea fat, cacao butter, murmuru fat, lanolin and the like.
〔各成分の含有率〕
本発明において、上記の（Ａ）シリコーン又はシリコーン誘導体の含有量は、組成物全量中に０．１〜３質量％であり、好ましくは０．２〜２質量％であり、更に好ましくは０．２〜１質量％である。０．１質量％未満では良好な指通り性が得られず、３質量％を超えるとハリ・コシが得られ難く、ごわつきが生じてまとまり性が悪くなる。
[Content of each component]
In this invention, content of said (A) silicone or silicone derivative is 0.1-3 mass% in the whole composition, Preferably it is 0.2-2 mass%, More preferably, it is 0.00. 2 to 1% by mass. If the amount is less than 0.1% by mass, good fingering properties cannot be obtained, and if it exceeds 3% by mass, it is difficult to obtain firmness and stiffness, resulting in stiffness and poor cohesion.
（Ｂ）第４級アンモニウム塩の含有量は、組成物全量中に０．３〜５質量％であり、好ましくは０．５〜４質量％であり、さらに好ましくは１〜３質量％である。０．３質量％未満では得られる毛髪のまとまり性が不十分であり、また安定した組成物を調製することができず、５質量％を超えると配合量に見合った効果が得られない上、べたつきが生じるおそれがあり、また保存安定性が悪くなる。 (B) Content of quaternary ammonium salt is 0.3-5 mass% in the whole composition, Preferably it is 0.5-4 mass%, More preferably, it is 1-3 mass%. . If the amount is less than 0.3% by mass, the resulting hair is insufficiently cohesive, and a stable composition cannot be prepared. If the amount exceeds 5% by mass, an effect commensurate with the blending amount cannot be obtained. There is a possibility that stickiness may occur, and storage stability deteriorates.
（Ｃ）高級アルコールの含有量は、組成物全量中に１〜１０質量％であり、好ましくは２〜７質量％であり、更に好ましくは３〜７質量％である。１質量％未満では毛髪にうるおい（しっとり感）を付与できず塗布感（リッチ感）が得られず、また安定した組成物を調製することができず、１０質量％を超えるとべたつきや指通り性が悪くなり、組成物が硬くなって使用性が悪くなり、また低温での保存安定性が悪くなる。 (C) Content of a higher alcohol is 1-10 mass% in a composition whole quantity, Preferably it is 2-7 mass%, More preferably, it is 3-7 mass%. If the amount is less than 1% by mass, moisture (moisturation) cannot be imparted to the hair, and a feeling of application (rich feeling) cannot be obtained, and a stable composition cannot be prepared. The composition becomes hard, the composition becomes hard and the usability deteriorates, and the storage stability at low temperatures deteriorates.
（Ｄ）水添ホホバ油の含有量は、組成物全量中に０．３〜３質量％であり、好ましくは０．３〜２質量％であり、さらに好ましくは０．５〜２質量％である。０．３質量％未満では髪にハリ・コシやうるおい（しっとり感）を得ることができず、３質量％を超えると毛髪のまとまり性が悪くなりべたつきが生じ、また保存安定性が悪くなる。 (D) Content of hydrogenated jojoba oil is 0.3-3 mass% in the whole composition, Preferably it is 0.3-2 mass%, More preferably, it is 0.5-2 mass% is there. If the amount is less than 0.3% by mass, the hair cannot be firm, firm or moist (moist feeling), and if it exceeds 3% by mass, the hair becomes less cohesive and sticky, and the storage stability also deteriorates.
本発明において（Ｂ）、（Ｃ）および（Ｄ）の含有量が（Ｃ）≧（Ｂ）かつ（Ｃ）≧（Ｄ）である。（Ｂ）の含有量が（Ｃ）の含有量を超えている、もしくは（Ｄ）の含有量が（Ｃ）の含有量を超えていると、安定した組成物を調製することができず、毛髪への塗布感（リッチ感）を得ることができず、また組成物の保存安定性が悪くなる。 In the present invention, the contents of (B), (C) and (D) are (C) ≧ (B) and (C) ≧ (D). If the content of (B) exceeds the content of (C), or if the content of (D) exceeds the content of (C), a stable composition cannot be prepared, An application feeling (rich feeling) to the hair cannot be obtained, and the storage stability of the composition is deteriorated.
本発明の毛髪化粧料は、ヘアコンディショナー、ヘアトリートメント、ヘアリンス、ヘアパック等に適用することができ、それぞれ通常の方法に従って製造することができる。なお、本発明の毛髪化粧料には、化粧料に常用されている他の成分を本発明の性能を損なわない範囲で配合することも可能である。 The hair cosmetic composition of the present invention can be applied to hair conditioners, hair treatments, hair rinses, hair packs, etc., and can be produced according to ordinary methods. In addition, it is also possible to mix | blend with the hair cosmetics of this invention the other component normally used for cosmetics in the range which does not impair the performance of this invention.
本発明の毛髪化粧料はｐＨが４〜７であれば、より高い効果が得られるとともに、経時安定性にも優れたものとすることができるため好ましい。ｐＨは、クエン酸、グルタミン酸や乳酸などの有機酸を使用して調整することができる。 When the pH of the hair cosmetic composition of the present invention is 4 to 7, it is preferable because a higher effect can be obtained and the stability over time can be improved. The pH can be adjusted using an organic acid such as citric acid, glutamic acid or lactic acid.
以下、実施例および比較例を挙げて本発明をさらに具体的に説明する。
〔実施例１〜６および比較例１〜１０〕
毛髪化粧料として表１に示すヘアリンスを調製し、下記の方法により評価を行った。その結果を表１に示す。なお、下記表記中の％とあるのは、質量％を意味する。但し、（Ａ）〜（Ｄ）として表２〜表５に示す各成分を使用した。クエン酸一水和物によりｐＨを４．０〜５．０に調整した。
Hereinafter, the present invention will be described more specifically with reference to examples and comparative examples.
[Examples 1 to 6 and Comparative Examples 1 to 10]
Hair rinses shown in Table 1 were prepared as hair cosmetics and evaluated by the following methods. The results are shown in Table 1. In the following notation, “%” means mass%. However, each component shown in Tables 2 to 5 was used as (A) to (D). The pH was adjusted to 4.0-5.0 with citric acid monohydrate.
※１「ＫＦ−９０２９」（信越化学工業株式会社製品）
ジメチルポリシロキサン（平均重合度：３５００) ／（平均重合度：３０）＝１５：８５（Ｖ／Ｖ）
※２「ＫＦ−８０２０」（信越化学工業株式会社製品）
アミノプロピルジメチルポリシロキサン（平均重合度：３５００）／（平均重合度：３０）＝２０：８０（Ｖ／Ｖ）
* 1 "KF-9029" (Shin-Etsu Chemical Co., Ltd. product)
Dimethylpolysiloxane (average polymerization degree: 3500) / (average polymerization degree: 30) = 15: 85 (V / V)
* 2 "KF-8020" (Shin-Etsu Chemical Co., Ltd. product)
Aminopropyldimethylpolysiloxane (average degree of polymerization: 3500) / (average degree of polymerization: 30) = 20: 80 (V / V)
なお、表１中の成分Ａ−１の含有量は平均重合度が３５００であるジメチルポリシロキサンの含有量を表し、成分Ａ−２の含有量は平均重合度が３５００であるアミノプロピルジメチルポリシロキサンの含有量を表す。 In Table 1, the content of component A-1 represents the content of dimethylpolysiloxane having an average degree of polymerization of 3500, and the content of component A-2 is an aminopropyldimethylpolysiloxane having an average degree of polymerization of 3500. Represents the content of.
※３「ホバクリームＭ−４０」（香栄興業株式会社製品）
※４「リペックスシア」（ＡＫＫ社製品）
※５「極度水添ホホバ」（香栄興業株式会社製品）
* 3 “Hoba Cream M-40” (product of Koei Kogyo Co., Ltd.)
* 4 “Repex Shear” (AKK product)
* 5 “Extremely hydrogenated jojoba” (product of Koei Kogyo Co., Ltd.)
（１）毛髪への塗布感（リッチ感）
２０名の男女（２０〜４０才）をパネラーとし、洗髪後の濡れた頭髪に各ヘアリンス５ｇを塗布した際の感触について下記の基準で評価した。２０名の平均値を求めて、１５点以上を毛髪に塗布感（リッチ感）を与えるヘアリンスであると評価して表１中に「○」を表示し、１５点未満１０点以上を毛髪に塗布感（リッチ感）をやや与えるヘアリンスであると評価して表１中に「△」を表示し、１０点未満を毛髪に塗布感（リッチ感）を殆ど与えないヘアリンスであると評価して表１中に「×」を表示した。
２０点：毛髪への塗布感（リッチ感）があると感じた場合。
１０点：毛髪への塗布感（リッチ感）がややあると感じた場合。
０点：毛髪への塗布感（リッチ感）がないと感じた場合。
(1) Feeling of application to hair (rich feeling)
Twenty men and women (20 to 40 years old) were panelists, and the touch when 5 g of each hair rinse was applied to wet hair after washing was evaluated according to the following criteria. An average value of 20 people was obtained, and 15 or more points were evaluated as a hair rinse that gave the hair a feeling of application (rich feeling), and “◯” was displayed in Table 1. Evaluate it as a hair rinse that gives a slightly applied feeling (rich feeling) and display “△” in Table 1, and evaluate that it is a hair rinse that gives almost no feeling of application (rich feeling) to hair less than 10 points. In Table 1, “x” is displayed.
20 points: When it is felt that there is a feeling of application (rich feeling) to the hair.
10 points: When a feeling of application (rich feeling) to hair is somewhat felt.
0 point: When it felt that there was no feeling of application (rich feeling) to hair.
（２）毛髪の指通り性
２０名の男女（２０〜４０才）をパネラーとし、洗髪後の濡れた頭髪に各ヘアリンス５ｇを塗布し洗い流して、タオルドライ後２時間乾燥した時の感触について下記の基準で評価した。２０名の平均値を求めて、１５点以上を毛髪に優れた指通り性を与えるヘアリンスであると評価して表１中に「○」を表示し、１５点未満１０点以上を毛髪に指通り性をやや与えるヘアリンスであると評価して表１中に「△」を表示し、１０点未満を毛髪に指通り性を殆ど与えないヘアリンスであると評価して表１中に「×」を表示した。
２０点：毛髪の指通りがとても良好であると感じた場合。
１０点：毛髪の指通りがまあまあであると感じた場合。
０点：毛髪がきしみ、指通りが悪いと感じた場合。
(2) Penetration of hair Using 20 males and females (20-40 years old) as panelists, 5 g of each hair rinse is applied to the wet hair after washing and washed away, and the feel when dried for 2 hours after towel drying is as follows. Evaluation based on the criteria. An average value of 20 people was obtained, and 15 or more points were evaluated as hair rinses that gave excellent fingering properties to hair, and “◯” was displayed in Table 1, and less than 15 points and 10 points or more were indicated on the hair. It is evaluated that it is a hair rinse that gives a little passability, and "△" is displayed in Table 1, and less than 10 points are evaluated as a hair rinse that hardly gives finger hair to pass, and "X" is shown in Table 1. Is displayed.
20 points: When the fingering of the hair feels very good.
10 points: When the finger of the hair feels so good.
0 point: When the hair is squeezed and the finger feels bad.
（３）毛髪のまとまり性
２０名の男女（２０〜４０才）をパネラーとし、洗髪後の濡れた頭髪に各ヘアリンス５ｇを塗布し洗い流して、タオルドライ後２時間乾燥した時の感触について下記の基準で評価した。２０名の平均値を求めて、１５点以上を毛髪のまとまり性に優れたヘアリンスであると評価して表１中に「○」を表示し、１５点未満１０点以上を毛髪のまとまり性がまあまあであるヘアリンスであると評価して表１中に「△」を表示し、１０点未満を毛髪のまとまり性が殆どないヘアリンスであると評価して表１中に「×」を表示した。
２０点：毛髪のまとまり性が良好であると感じた場合。
１０点：毛髪のまとまり性がまあまあであると感じた場合。
０点：毛髪のまとまり性が悪いと感じた場合。
(3) Hair cohesion 20 males and females (20 to 40 years old) are panelists, 5 g of each hair rinse is applied to the wet hair after shampooing, washed and dried for 2 hours after towel drying. Evaluated by criteria. An average value of 20 people was obtained, and 15 or more points were evaluated as hair rinses excellent in hair cohesiveness, and “○” was displayed in Table 1. Evaluated as a fair hair rinse and indicated “△” in Table 1. Expressed less than 10 hair rinses with little hair coherence and indicated “X” in Table 1. .
20 points: When it is felt that the cohesiveness of the hair is good.
10 points: When hair feels coherent.
0 points: When the hair feels poorly organized.
（４）毛髪のうるおい（しっとり感）
２０名の男女（２０〜４０才）をパネラーとし、洗髪後の濡れた頭髪に各ヘアリンス５ｇを塗布し洗い流して、タオルドライ後２時間乾燥した時の感触について下記の基準で評価した。２０名の平均値を求めて、１５点以上を毛髪にうるおい（しっとり感）を与えるヘアリンスであると評価して表１中に「○」を表示し、１５点未満１０点以上を毛髪にうるおい（しっとり感）をやや与えるヘアリンスであると評価して表１中に「△」を表示し、１０点未満を毛髪にうるおい（しっとり感）を殆ど与えないヘアリンスであると評価して表１中に「×」を表示した。
２０点：毛髪がとてもうるおっていると感じた場合。
１０点：毛髪がややうるおっていると感じた場合。
０点：毛髪がぱさつき、全くうるおっていないと感じた場合。
(4) Moisture of hair (moist feeling)
Twenty men and women (20 to 40 years old) were panelists, and 5 g of each hair rinse was applied to the wet hair after shampooing and washed, and the touch when dried for 2 hours after towel drying was evaluated according to the following criteria. Obtain an average value of 20 people and evaluate that it is a hair rinse that gives hair 15 a moisturizing (moist feeling) and displays “◯” in Table 1. Table 1 shows that it is a hair rinse that gives a little (moisturation) and shows “△” in Table 1. It evaluates that it is a hair rinse that gives hair less moist (moisture) less than 10 points. “×” is displayed on the screen.
20 points: When the hair feels very moist.
10 points: When the hair feels slightly moist.
0 points: When the hair feels crispy and feels no moisture at all.
（５）毛髪のハリ・コシ
２０名の男女（２０〜４０才）をパネラーとし、洗髪後の濡れた頭髪に各ヘアリンス５ｇを塗布し洗い流して、タオルドライ後２時間乾燥した時の毛髪のハリ・コシについて下記の基準で評価した。２０名の平均値を求めて、１５点以上を毛髪にハリ・コシを与えるヘアリンスであると評価して表１中に「○」を表示し、１５点未満１０点以上を毛髪にハリ・コシをやや与えるヘアリンスであると評価して表１中に「△」を表示し、１０点未満を毛髪にハリ・コシを殆ど与えないヘアリンスであると評価して表１中に「×」を表示した。
２０点：毛髪にハリ・コシがあると感じる。
１０点：毛髪にややハリ・コシがあると感じる。
０点：毛髪にハリ・コシがなく、ボリューム感がないと感じる。
(5) Hair tension and stiffness 20 males and females (20 to 40 years old) are panelists, 5 g of each hair rinse applied to the wet hair after shampooing, washing, hair drying when towel drying and drying for 2 hours・ The following criteria were used to evaluate the stiffness. The average value of 20 people is obtained, and it is evaluated that it is a hair rinse that gives the hair a firmness and firmness with 15 points or more, and “◯” is displayed in Table 1, and less than 15 points with 10 points or more on the hair. Evaluate that it is a hair rinse that gives a little hair, and display “△” in Table 1, and evaluate that it is a hair rinse that gives hair almost no firmness and stiffness and display “×” in Table 1. did.
20 points: The hair feels firm and firm.
10 points: I feel that my hair has some elasticity and stiffness.
0 point: There is no firmness or firmness in the hair, and there is no sense of volume.
（６）毛髪のべたつき
２０名の男女（２０〜４０才）をパネラーとし、洗髪後の濡れた頭髪に各ヘアリンス５ｇを塗布し洗い流して、タオルドライ後２時間乾燥した時の感触について下記の基準で評価した。２０名の平均値を求めて、１５点以上を毛髪がべたつかないヘアリンスであると評価して表１中に「○」を表示し、１５点未満１０点以上を毛髪がややべたつくヘアリンスであると評価して表１中に「△」を表示し、１０点未満を毛髪がべたつくヘアリンスであると評価して表１中に「×」を表示した。
２０点：毛髪がべたつかないと感じた場合。
１０点：毛髪がややべたつくと感じた場合。
０点：毛髪がべたつくと感じた場合。
(6) Hair stickiness 20 males and females (20-40 years old) are panelists, apply 5 g of each hair rinse on wet hair after shampooing, wash it off, and dry it for 2 hours after towel drying. It was evaluated with. The average value of 20 people is obtained, and it is evaluated that it is a hair rinse in which hair is not sticky at 15 points or more, “◯” is displayed in Table 1, and a hair rinse in which hair is slightly sticky at less than 15 points and 10 points or more. Evaluation was made with “Δ” in Table 1, and less than 10 points were evaluated as hair rinses with sticky hair, and “X” was shown in Table 1.
20 points: When the hair feels non-sticky.
10 points: When the hair feels slightly sticky.
0 points: When the hair feels sticky.
実施例１〜６より、本発明の毛髪化粧料はいずれも塗布感（リッチ感）を与え、また乾燥後にべたつかず、毛髪にハリ・コシやうるおい（しっとり感）を与え、かつ、指通り性やまとまり性に優れる効果が得られていた。一方、比較例１〜１０では十分な性能が得られていない。 From Examples 1 to 6, all of the hair cosmetics of the present invention give a feeling of application (rich feeling), do not become sticky after drying, give the hair firmness, moisture and moisturization (moist feeling), and are easy to touch The effect which was excellent in unity property was acquired. On the other hand, in Comparative Examples 1-10, sufficient performance is not obtained.
比較例１では、（Ａ）成分の配合量が本発明規定範囲の上限値を超えていることから、毛髪への塗布感や毛髪のまとまり性、ハリ・コシが不十分であり、比較例２では、（Ｂ）成分の配合量が本発明規定範囲の下限値より少ないことから、毛髪のうるおい（しっとり感）やハリ・コシが不十分であり、塗布感に乏しく、まとまり性に欠けている。比較例３では、（Ｄ）成分が配合されていないことから、毛髪への塗布感や、毛髪のまとまり性やうるおいが不十分であり、ハリ・コシが出ておらず、比較例４では、（Ａ）成分が配合されておらず、かつ、（Ｄ）成分の配合量が本発明規定範囲の上限値を超えていることから、べたつきが生じており、指通り性が悪くなっている。 In Comparative Example 1, since the blending amount of the component (A) exceeds the upper limit of the range specified in the present invention, the feeling of application to hair, the cohesiveness of hair, and the firmness and stiffness are insufficient. Comparative Example 2 Then, since the blending amount of the component (B) is less than the lower limit of the range specified in the present invention, the moisture (moist feeling) and firmness of the hair are insufficient, the coating feeling is poor, and the cohesiveness is lacking. . In Comparative Example 3, since the component (D) is not blended, the feeling of application to the hair, the cohesiveness and moisture of the hair are insufficient, and there is no firmness or firmness. In Comparative Example 4, Since the component (A) is not blended and the blending amount of the component (D) exceeds the upper limit of the range specified in the present invention, stickiness occurs and the fingering property is poor.
比較例５では、（Ｃ）成分の配合量が本発明規定範囲の上限値を超えていることから、毛髪への塗布感や毛髪のまとまり性が不十分な上、指通り性が悪く、べたつきが酷く、比較例６では、（Ｂ）成分の含有量が（Ｃ）成分の含有量を超えていることから、毛髪のまとまり性やハリ・コシが不十分な上、塗布感が得られていない。比較例７では、（Ｃ）成分の配合量が本発明規定範囲の下限値より少ないことから、毛髪のまとまり性やハリ・コシが不十分な上、塗布感に劣り、十分なうるおいが得られておらず、比較例８では、（Ｄ）成分の水添ホホバ油を融点が高いものに置き換えていることから、毛髪のまとまり性やうるおい、ハリ・コシが不十分で、若干べたつきが生じ、指通り性が悪くなっている。比較例９では、（Ｄ）成分が配合されず特定の油性成分しか配合されていないために、毛髪の指通り性やハリ・コシが不十分であり、十分なうるおいが得られておらず、比較例１０では、（Ｄ）成分が他の油性成分に置き換えていることから、毛髪の指通り性やまとまり性、うるおい、ハリ・コシが不十分であり、べたつきが生じている。 In Comparative Example 5, since the blending amount of the component (C) exceeds the upper limit of the range specified in the present invention, the feeling of application to the hair and the cohesiveness of the hair are inadequate, the fingering property is poor, and stickiness In Comparative Example 6, since the content of the component (B) exceeds the content of the component (C), the cohesiveness and firmness of the hair are insufficient, and the coating feeling is obtained. Absent. In Comparative Example 7, since the blending amount of the component (C) is less than the lower limit of the range specified in the present invention, the hair cohesiveness and firmness are insufficient, the coating feeling is inferior, and sufficient moisture is obtained. In Comparative Example 8, since the hydrogenated jojoba oil of component (D) is replaced with one having a high melting point, the hair cohesiveness, moisture, firmness and firmness are insufficient, and a slight stickiness occurs. The fingering is getting worse. In Comparative Example 9, since the component (D) is not blended and only a specific oil component is blended, the fingering property and elasticity of hair are insufficient, and sufficient moisture is not obtained. In Comparative Example 10, since the component (D) is replaced with other oily components, the finger's fingering property, cohesion, moisture, firmness and firmness are insufficient, and stickiness occurs.
下記実施例７，８の毛髪化粧料を調製し、上記と同様に評価を行った。結果を下記に示す。 The hair cosmetics of Examples 7 and 8 below were prepared and evaluated in the same manner as described above. The results are shown below.
〔実施例７〕
常法により下記組成のヘアコンディショナーを調製し、評価を行った。
（％）
（１）成分Ａ−１ ０．２
（２）成分Ｂ−１ ０．５
（３）成分Ｃ−１ ２．５
（４）成分Ｄ−１ ０．３
（５）グリセリン ５．０
（６）パラオキシ安息香酸メチル ０．２
（７）パラオキシ安息香酸プロピル ０．１
（８）クエン酸一水和物 ０．１
（９）香料 ０．５
（１０）精製水 残余
なお、成分Ａ−１の含有量は平均重合度が３５００であるジメチルポリシロキサンの含有量を表す。
Example 7
A hair conditioner having the following composition was prepared and evaluated by a conventional method.
(%)
(1) Component A-1 0.2
(2) Component B-1 0.5
(3) Component C-1 2.5
(4) Component D-1 0.3
(5) Glycerin 5.0
(6) Methyl paraoxybenzoate 0.2
(7) Propyl paraoxybenzoate 0.1
(8) Citric acid monohydrate 0.1
(9) Fragrance 0.5
(10) Purified water residue The content of Component A-1 represents the content of dimethylpolysiloxane having an average degree of polymerization of 3500.
毛髪への塗布感（リッチ感）は１８点（○）、毛髪への指通り性は１９点（○）、毛髪のまとまり性は１８点（○）、毛髪のうるおい（しっとり感）は１８点（○）、毛髪のハリ・コシは１９点（○）、毛髪のべたつきは１９点（○）だった。 18 points (o) for hair application (rich feeling), 19 points (o) for finger penetration, 18 points for hair cohesion (o), 18 points for moisture (moisture) (○), 19 points (◯) for hair elasticity and 19 points (○) for hair stickiness.
〔実施例８〕
常法により下記組成のヘアトリートメントを調製し、評価を行った。
（％）
（１）成分Ａ−１ ０．５
（２）成分Ａ−２ ０．５
（３）成分Ｂ−１ ３．０
（４）成分Ｃ−３ ８．０
（５）成分Ｄ−１ ０．５
（６）成分Ｄ−２ ０．５
（７）ステアリン酸グリセリル ３．５
（８）ステアリン酸ＰＥＧ−５ ０．５
（９）ステアリン酸ＰＥＧ−３０ ０．５
（１０）ジグリセリン ３．０
（１１）水添ポリイソブテン ２．０
（動粘度（３７．８℃）：４．１ｍｍ２・Ｓ−１）
（１２）パラオキシ安息香酸メチル ０．２
（１３）パラオキシ安息香酸プロピル ０．１
（１４）クエン酸一水和物 ０．１
（１５）香料 ０．５
（１６）精製水 残余
なお、成分Ａ−１の含有量は平均重合度が３５００であるジメチルポリシロキサンの含有量を表し、成分Ａ−２の含有量は平均重合度が３５００であるアミノプロピルジメチルポリシロキサンの含有量を表す。
Example 8
A hair treatment having the following composition was prepared and evaluated by a conventional method.
(%)
(1) Component A-1 0.5
(2) Component A-2 0.5
(3) Component B-1 3.0
(4) Component C-3 8.0
(5) Component D-1 0.5
(6) Component D-2 0.5
(7) Glyceryl stearate 3.5
(8) PEG-5 stearate 0.5
(9) PEG-30 stearate 0.5
(10) Diglycerin 3.0
(11) Hydrogenated polyisobutene 2.0
(Kinematic viscosity (37.8 ° C.): 4.1 mm 2 · S −1 )
(12) Methyl paraoxybenzoate 0.2
(13) Propyl paraoxybenzoate 0.1
(14) Citric acid monohydrate 0.1
(15) Fragrance 0.5
(16) Purified water residue The content of component A-1 represents the content of dimethylpolysiloxane having an average degree of polymerization of 3500, and the content of component A-2 is aminopropyldimethyl having an average degree of polymerization of 3500. Represents the content of polysiloxane.
毛髪への塗布感（リッチ感）は２０点（○）、毛髪への指通り性は１９点（○）、毛髪のまとまり性は１９点（○）、毛髪のうるおい（しっとり感）は２０点（○）、毛髪のハリ・コシは２０点（○）、毛髪のべたつきは１９点（○）だった。 20 points (○) for hair feel (rich), 19 points (○) for finger penetration, 19 points for hair cohesion (20), 20 points for moisture (moisture) (○), hair firmness and stiffness were 20 points (◯), and hair was 19 points (◯).
実施例７，８より、本発明の毛髪化粧料はいずれも塗布感（リッチ感）を与え、また乾燥後にべたつかず、毛髪にハリ・コシやうるおい（しっとり感）を与え、かつ、指通り性やまとまり性に優れる効果が得られていた。 From Examples 7 and 8, each of the hair cosmetics of the present invention gives a feeling of application (rich feeling), does not become sticky after drying, gives the hair firmness, moisture and moistness (moist feeling), and is easy to touch. The effect which was excellent in unity property was acquired.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010247318A JP5716356B2 (en) | 2010-11-04 | 2010-11-04 | Hair cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010247318A JP5716356B2 (en) | 2010-11-04 | 2010-11-04 | Hair cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2012097047A JP2012097047A (en) | 2012-05-24 |
| JP5716356B2 true JP5716356B2 (en) | 2015-05-13 |
Family
ID=46389390
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010247318A Active JP5716356B2 (en) | 2010-11-04 | 2010-11-04 | Hair cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5716356B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6107066B2 (en) * | 2012-11-12 | 2017-04-05 | 日油株式会社 | Hair cosmetics |
| JP6484029B2 (en) * | 2014-12-25 | 2019-03-13 | 花王株式会社 | Hair cosmetics |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001139437A (en) * | 1999-11-11 | 2001-05-22 | Kanebo Ltd | Hair rinse composition |
| JP2001139429A (en) * | 1999-11-15 | 2001-05-22 | Kanebo Ltd | Hair cosmetic |
| JP2006111606A (en) * | 2004-10-18 | 2006-04-27 | Minoru Kobayashi | Photocatalyst-containing composition for hair |
| JP2006282632A (en) * | 2005-04-04 | 2006-10-19 | Iwase Cosfa Kk | Solid state water-in-oil type emulsion cosmetic |
| JP5758062B2 (en) * | 2008-12-11 | 2015-08-05 | 株式会社ミルボン | Hair treatment agent |
-
2010
- 2010-11-04 JP JP2010247318A patent/JP5716356B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2012097047A (en) | 2012-05-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2387987B1 (en) | Hair cosmetic | |
| JP5725653B2 (en) | Hair rinse composition | |
| JP5808607B2 (en) | Hair cosmetics | |
| JP5138478B2 (en) | Hair cosmetics | |
| JP5575453B2 (en) | Hair treatment agent | |
| JP5716356B2 (en) | Hair cosmetics | |
| JP4937537B2 (en) | Hair cosmetics | |
| JP2001181156A (en) | Hair rinse composition | |
| JP2014043426A (en) | Hair cosmetics | |
| JP5359058B2 (en) | Hair cosmetics | |
| JP6128879B2 (en) | Hair cosmetics | |
| JP6107066B2 (en) | Hair cosmetics | |
| JP6087653B2 (en) | Hair cosmetics | |
| JP7349769B2 (en) | Multi-component hair treatment agent | |
| JP2010013406A (en) | Hair cosmetic | |
| JP4987356B2 (en) | Hair care composition | |
| JP2010059118A (en) | Hair dressing agent | |
| JP2014214150A (en) | Hair cosmetic preparation | |
| JP5774263B2 (en) | Emulsifying hair cosmetics | |
| JP7164298B2 (en) | hair cosmetics | |
| JP7276810B2 (en) | hair cosmetics | |
| JP5202860B2 (en) | Low viscosity transparent composition with water thickening | |
| JP5760436B2 (en) | Hair cosmetics | |
| JP2001139437A (en) | Hair rinse composition | |
| JP7138911B2 (en) | hair cosmetics |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20131023 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20140619 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140701 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140801 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20150217 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20150302 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5716356 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |