JP2017197467A - Composition for washing and conditioning hair - Google Patents
Composition for washing and conditioning hair Download PDFInfo
- Publication number
- JP2017197467A JP2017197467A JP2016089238A JP2016089238A JP2017197467A JP 2017197467 A JP2017197467 A JP 2017197467A JP 2016089238 A JP2016089238 A JP 2016089238A JP 2016089238 A JP2016089238 A JP 2016089238A JP 2017197467 A JP2017197467 A JP 2017197467A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- acid
- washing
- scalp
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 239000000203 mixture Substances 0.000 title claims abstract description 23
- 238000005406 washing Methods 0.000 title claims abstract description 22
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- 239000000194 fatty acid Substances 0.000 claims abstract description 29
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- 150000001875 compounds Chemical class 0.000 claims abstract description 11
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- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 6
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- 238000000034 method Methods 0.000 claims description 5
- 239000002826 coolant Substances 0.000 claims description 2
- 210000004761 scalp Anatomy 0.000 abstract description 34
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- 230000000694 effects Effects 0.000 abstract description 2
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Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、毛髪の洗浄及びコンディショニング用の組成物に関し、毛髪・頭皮の洗浄剤として使用でき、かつ同時に毛髪のコンディショニングが可能で、毛髪・頭皮の保湿効果に優れる毛髪の洗浄及びコンディショニング用の組成物に関する。 The present invention relates to a composition for washing and conditioning hair, and is a composition for washing and conditioning hair that can be used as a hair and scalp cleaning agent, and that is capable of conditioning hair at the same time and has an excellent moisturizing effect on hair and scalp. Related to things.
一般的なシャンプーには、主成分として水の他に、アニオン性界面活性剤及び両性界面活性剤を含有するものが多く、その大部分が洗髪時に、頭皮及び頭髪で泡立てることで汚れを除去させるものである。アニオン性界面活性剤や両性界面活性剤は、その高い洗浄性と起泡性を理由に配合されることが多く、現代の多くのシャンプーの基材となっている。 Many common shampoos contain an anionic surfactant and an amphoteric surfactant in addition to water as a main component, and most of them remove dirt by lathering in the scalp and hair during hair washing. Is. Anionic surfactants and amphoteric surfactants are often formulated because of their high detergency and foaming properties, and have become the base material for many modern shampoos.
しかし、近年、洗浄性の高い界面活性剤主成分のシャンプー製剤の使用による頭皮の皮脂の取り過ぎが懸念されるようになり、シャンプーを使わずに洗髪する、あるいはシャンプーによる洗髪そのものの頻度を少なくするといった傾向がみられてきた。また、硬い髪のシャンプーユーザーでは、皮脂を取り過ぎることはすなわち毛髪のパサつきにつながるため、界面活性剤による過剰な脱脂により毛髪のつややまとまりが失われ、硬く乾燥した髪質の低下がさらに助長されると懸念する声も上がっている。 However, in recent years, there has been a concern over the removal of sebum from the scalp due to the use of a surfactant-based shampoo formulation with high detergency, and the frequency of shampooing or washing with shampoo is less frequent. The tendency to do has been seen. In addition, for shampoo users with hard hair, too much sebum leads to dryness of the hair, that is, excessive degreasing with a surfactant loses the glossiness of the hair and further deteriorates the quality of the hard and dry hair. Some people are worried about being encouraged.
また、ここ１０年の間に、頭皮へ残留するというイメージからシリコーン化合物の配合を敬遠する消費者が増え、シリコーン化合物を含有しないシャンプーの需要が増加している。シリコーン化合物の配合は、毛髪のコーティング感、指通りには正に寄与するが、一方で人によっては皮膜感をべたつきと捉え、さっぱり感の低減につながる場合がある。そこで、シリコーン化合物を配合しないことで、べたつきや髪の皮膜感は改善されるものの、それにより犠牲となるすすぎ時や仕上がりの指通りとまとまりを補うために、これまで様々な試みがなされ、従来、アニオン性界面活性剤と両性界面活性剤とカチオン化セルロースの３成分の組み合わせについては深く研究されている（例えば、特許文献１参照）。しかしながら、すすぎ時のきしみ感の改善は大きく進歩はしているものの、シリコーン化合物を含有しないシャンプーのみの使用では、コンディショナーやトリートメントを併用せずに髪に優れた指通りやまとまりを与えることは困難であった。 In addition, in the last 10 years, an increasing number of consumers have shunned the formulation of silicone compounds from the image of remaining on the scalp, and the demand for shampoos that do not contain silicone compounds has increased. The compounding of the silicone compound contributes positively to the coating feeling of the hair and the finger, but on the other hand, depending on the person, the film feeling is considered sticky and may lead to a reduction in the refreshing feeling. Therefore, by not adding a silicone compound, the stickiness and the feeling of the film on the hair are improved, but various attempts have been made so far to compensate for the sacrificial rinsing and finishing of the finger. Further, a combination of three components of an anionic surfactant, an amphoteric surfactant and a cationized cellulose has been studied deeply (see, for example, Patent Document 1). However, although the improvement of squeakiness during rinsing has made great progress, using only shampoos that do not contain silicone compounds makes it difficult to provide excellent fingering and cohesion without using conditioners and treatments. Met.
また一方で、それ一つで洗浄と毛髪コンディショニングが可能で簡便であるという面から、シャンプーにコンディショナー成分を配合したリンスインシャンプー製品も多く見られてきたが、コンディショニング効果でコンディショナーの併用に勝る効果を得ることは難しく、適度に頭皮の皮脂汚れを除去でき、かつ地肌を乾燥させずに髪に保湿効果を得たいという消費者の願いを十分に満足させることは困難であった。 On the other hand, there are many rinse-in shampoo products that contain a conditioner component in the shampoo from the standpoint that it is easy and easy to clean and condition the hair, but the conditioning effect is superior to the combined use of the conditioner. It was difficult to obtain, and it was difficult to sufficiently satisfy the consumer's desire to remove sebum stains on the scalp appropriately and to obtain a moisturizing effect on the hair without drying the skin.
本発明の目的は、毛髪・頭皮の洗浄剤として使用でき、かつ同時に毛髪のコンディショニングが可能で、使用感、仕上がり感、及び毛髪・頭皮の保湿効果に優れる毛髪の洗浄及びコンディショニング用の組成物を提供することにある。 It is an object of the present invention to provide a composition for washing and conditioning hair that can be used as a hair and scalp cleaning agent, and at the same time can condition the hair, and has excellent usability, finish, and moisturizing effect on the hair and scalp. It is to provide.
本発明者は、本発明の目的を達成するために鋭意研究した結果、シリコーン化合物、アニオン性界面活性剤及び両性界面活性剤を実質的に含有せず、特定のエステル油と特定のカチオン界面活性剤、及び清涼化剤とを含有する毛髪化粧料が上記目的を達成できることを見出し、本発明を完成した。 As a result of intensive studies to achieve the object of the present invention, the present inventor has substantially no silicone compound, an anionic surfactant and an amphoteric surfactant, and has a specific ester oil and a specific cationic surfactant. The present invention was completed by finding that a hair cosmetic containing an agent and a refreshing agent can achieve the above-mentioned object.
本発明の第１の態様である毛髪の洗浄及びコンディショニング用の組成物は、下記（Ａ）〜（Ｃ）成分を含有し、アニオン性界面活性剤、両性界面活性剤及びシリコーン化合物を実質的に含有しないことを特徴とするものである。
（Ａ）２０℃において液状のエステル油
（Ｂ）下記一般式（Ｉ）で表される脂肪酸アミドアミン及び／又は第４級アンモニウム塩
Ｒ１−ＣＯ−ＮＨ−（ＣＨ２）ｎ−Ｎ（Ｒ２）２ ・・・（Ｉ）
（式中、Ｒ１は、直鎖又は分岐した炭素数１３〜２３の飽和又は不飽和脂肪酸残基、Ｒ２は炭素数１〜３のアルキル基、ｎは１〜５の整数を示す。）
（Ｃ）清涼化剤
The composition for washing and conditioning hair according to the first aspect of the present invention contains the following components (A) to (C), and substantially contains an anionic surfactant, an amphoteric surfactant and a silicone compound. It does not contain.
(A) Ester oil that is liquid at 20 ° C. (B) Fatty acid amidoamine and / or quaternary ammonium salt represented by the following general formula (I) R 1 —CO—NH— (CH 2 ) n —N (R 2 2 ... (I)
(In the formula, R 1 represents a linear or branched saturated or unsaturated fatty acid residue having 13 to 23 carbon atoms, R 2 represents an alkyl group having 1 to 3 carbon atoms, and n represents an integer of 1 to 5).
(C) Coolant
本発明の第２の態様である毛髪の洗浄及びコンディショニング方法は、前記毛髪の洗浄及びコンディショニング用の組成物を濡らした毛髪に適用した後、洗い流すことを特徴とする。 The hair washing and conditioning method according to the second aspect of the present invention is characterized in that the hair washing and conditioning composition is applied to wet hair and then washed away.
本発明によれば、毛髪・頭皮の洗浄剤として使用でき、かつ同時に毛髪のコンディショニングが可能で、使用感、仕上がり感、及び毛髪・頭皮の保湿効果に優れる毛髪の洗浄及びコンディショニング用の組成物を提供することができる。 According to the present invention, there is provided a composition for washing and conditioning hair that can be used as a hair and scalp cleaning agent, and that is capable of conditioning hair at the same time and that is excellent in feeling of use, finish, and moisturizing effect on hair and scalp. Can be provided.
以下、本発明について詳細に説明する。
本発明で用いられる（Ａ）成分の２０℃において液状のエステル油は、脂肪酸とアルコールとのエステル体を主成分とするものである。その具体例としては、ミリスチン酸イソプロピル、ミリスチン酸ブチル、パルミチン酸イソプロピル、オレイン酸エチル、リノール酸エチル等の直鎖高級脂肪酸と低級アルコールとのエステル、カプリル酸セチル、ラウリン酸ヘキシル、ミリスチン酸デシル、オレイン酸デシル、リシノレイン酸セチル等の直鎖高級脂肪酸と直鎖高級アルコールとのエステル、ラウリン酸イソステアリル、ミリスチン酸イソトリデシル、ミリスチン酸イソセチル、ミリスチン酸イソステアリル、ミリスチン酸オクチルドデシル、パルミチン酸２−エチルヘキシル、パルミチン酸イソセチル、パルミチン酸イソステアリル、ステアリン酸イソセチル、オレイン酸イソデシル、オレイン酸オクチルドデシル等の直鎖脂肪酸と分枝アルコールとのエステル、イソステアリン酸エチル、イソステアリン酸イソプロピル等の分枝脂肪酸と低級アルコールとのエステル、オクタン酸セチル、オクタン酸セトステアリル、オクタン酸ステアリル、イソステアリン酸ヘキシル等の分枝脂肪酸と直鎖高級アルコールとのエステル、ジオクタン酸エチレングリコール、ジオレイン酸エチレングリコール、ジカプリル酸プロピレングリコール、ジカプリン酸プロピレングリコール、ジオレイン酸プロピレングリコール、ジカプリン酸ネオペンチルグリコール等の脂肪酸と多価アルコールとのエステル、ネオペンタン酸オクチルドデシル、オクタン酸イソセチル、オクタン酸イソステアリル、イソペラルゴン酸オクチル、ネオデカン酸オクチルドデシル、イソステアリン酸イソステアリル等の分枝脂肪酸と分枝アルコールとのエステル、乳酸ラウリル、乳酸ミリスチル、乳酸セチル等の乳酸エステル、クエン酸トリエチル、クエン酸トリオクチル、クエン酸トリイソセチル、リンゴ酸ジイソステアリル、コハク酸ジ２−エチルヘキシル、セバシン酸ジ２−エチルヘキシル等の二塩基酸のエステルなどが挙げられる。これらの中でも、コハク酸ジ２−エチルヘキシル、ジカプリン酸ネオペンチルグリコールが好ましい。これらの液状のエステル油は、１種又は２種以上を組み合わせて用いることができ、その配合量は、好ましくは１〜１０質量
％、更に好ましくは、１〜５質量％の範囲である。この配合量の範囲であれば、頭皮・毛髪に対して、べたつきや重さを感じることなく、毛髪に対ししなやかでしっとりとした仕上がり感を与えることができるため好ましい。
Hereinafter, the present invention will be described in detail.
The ester oil that is liquid at 20 ° C. of the component (A) used in the present invention is mainly composed of an ester of fatty acid and alcohol. Specific examples thereof include esters of linear higher fatty acids such as isopropyl myristate, butyl myristate, isopropyl palmitate, ethyl oleate, ethyl linoleate and the like, cetyl caprylate, hexyl laurate, decyl myristate, Esters of linear higher fatty acids such as decyl oleate and cetyl ricinoleate and linear higher alcohols, isostearyl laurate, isotridecyl myristate, isocetyl myristate, isostearyl myristate, octyldodecyl myristate, 2-ethylhexyl palmitate , Esters of linear fatty acids such as isocetyl palmitate, isostearyl palmitate, isocetyl stearate, isodecyl oleate, octyldodecyl oleate, etc. Esters of branched fatty acids such as ethyl phosphate and isopropyl isostearate and lower alcohols, esters of branched fatty acids such as cetyl octoate, cetostearyl octoate, stearyl octoate and hexyl isostearate, and linear higher alcohols, dioctane Esters of fatty acids and polyhydric alcohols such as ethylene glycol diolate, ethylene glycol dioleate, propylene glycol dicaprylate, propylene glycol dicaprate, propylene glycol dicaprate, neopentyl glycol dicaprate, isopentyl neopentanoate, isocetyl octanoate, octane Of branched fatty acids such as isostearyl acid, octyl isopelargonate, octyldodecyl neodecanoate, isostearyl isostearate, etc. Lactate esters such as stealth, lauryl lactate, myristyl lactate, cetyl lactate, dibasic bases such as triethyl citrate, trioctyl citrate, triisocetyl citrate, diisostearyl malate, di-2-ethylhexyl succinate, di-2-ethylhexyl sebacate Examples include esters of acids. Among these, di-2-ethylhexyl succinate and neopentyl glycol dicaprate are preferable. These liquid ester oils can be used singly or in combination of two or more, and the blending amount thereof is preferably 1 to 10% by mass, more preferably 1 to 5% by mass. This blending amount is preferable because it gives a soft and moist finish to the scalp and hair without feeling sticky or heavy.
本発明で用いられる（Ｂ）成分のうち、脂肪酸アミドアミンとしては、例えば、下記一般式（Ｉ）
Ｒ１−ＣＯ−ＮＨ−（ＣＨ２）ｎ−Ｎ（Ｒ２）２ ・・・（Ｉ）
（式中、Ｒ１は、直鎖又は分岐した炭素数１３〜２３の飽和又は不飽和脂肪酸残基、Ｒ２は炭素数１〜３のアルキル基、ｎは１〜５の整数を示す。）で表されるものが挙げられる。具体例を示すと、ラウリン酸ジメチルアミノプロピルアミド、ミリスチン酸ジメチルアミノプロピルアミド、パルミチン酸ジメチルアミノプロピルアミド、ステアリン酸ジメチルアミノプロピルアミド、ベヘニン酸ジメチルアミノプロピルアミド、オレイン酸ジメチルアミノプロピルアミド、ヤシ脂肪酸ジメチルアミノプロピルアミド、パーム脂肪酸ジメチルアミノプロピルアミド、牛脂脂肪酸ジメチルアミノプロピルアミド、イソステアリン酸ジメチルアミノプロピルアミド、ラウリン酸ジエチルアミノエチルアミド、ミリスチン酸ジエチルアミノエチルアミド、パルミチン酸ジエチルアミノエチルアミド、ステアリン酸ジエチルアミノエチルアミド、ベヘニン酸ジエチルアミノエチルアミド、オレイン酸ジエチルアミノエチルアミド、ヤシ脂肪酸ジエチルアミノエチルアミド、パーム脂肪酸ジエチルアミノエチルアミド、牛脂脂肪酸ジエチルアミノエチルアミド、イソステアリン酸ジエチルアミノエチルアミド、ラウリン酸ジエチルアミノプロピルアミド、ミリスチン酸ジエチルアミノプロピルアミド、パルミチン酸ジエチルアミノプロピルアミド、ステアリン酸ジエチルアミノプロピルアミド、ベヘニン酸ジエチルアミノプロピルアミド、オレイン酸ジエチルアミノプロピルアミド、ヤシ脂肪酸ジエチルアミノプロピルアミド、パーム脂肪酸ジエチルアミノプロピルアミド、牛脂脂肪酸ジエチルアミノプロピルアミド、イソステアリン酸ジエチルアミノプロピルアミド等が挙げられる。これらの中でもＲ１が炭素数１７〜２１、Ｒ２がメチル基、ｎが３の整数であるベヘニン酸ジメチルアミノプロピルアミド、ステアリン酸ジメチルアミノプロピルアミドが特に好ましい。本発明では、これらの脂肪酸アミドアミンの中から１種又は２種以上を任意に用いることができ、その配合量は、好ましくは０．１〜７質量％、更に好ましくは、０．１〜５質量％の範囲である。
Of the component (B) used in the present invention, examples of the fatty acid amidoamine include the following general formula (I):
R 1 —CO—NH— (CH 2 ) n —N (R 2 ) 2 (I)
(In the formula, R 1 represents a linear or branched saturated or unsaturated fatty acid residue having 13 to 23 carbon atoms, R 2 represents an alkyl group having 1 to 3 carbon atoms, and n represents an integer of 1 to 5). The thing represented by is mentioned. Specific examples include lauric acid dimethylaminopropylamide, myristic acid dimethylaminopropylamide, palmitic acid dimethylaminopropylamide, stearic acid dimethylaminopropylamide, behenic acid dimethylaminopropylamide, oleic acid dimethylaminopropylamide, coconut fatty acid Dimethylaminopropylamide, palm fatty acid dimethylaminopropylamide, beef tallow fatty acid dimethylaminopropylamide, isostearic acid dimethylaminopropylamide, lauric acid diethylaminoethylamide, myristic acid diethylaminoethylamide, palmitic acid diethylaminoethylamide, stearic acid diethylaminoethylamide, Behenic acid diethylaminoethylamide, oleic acid diethylaminoethylamide, Fatty acid diethylaminoethylamide, palm fatty acid diethylaminoethylamide, beef tallow fatty acid diethylaminoethylamide, isostearic acid diethylaminoethylamide, lauric acid diethylaminopropylamide, myristic acid diethylaminopropylamide, palmitic acid diethylaminopropylamide, stearic acid diethylaminopropylamide, behenic acid diethylamino Examples include propylamide, oleic acid diethylaminopropylamide, coconut fatty acid diethylaminopropylamide, palm fatty acid diethylaminopropylamide, beef tallow fatty acid diethylaminopropylamide, and isostearic acid diethylaminopropylamide. Number R 1 is carbon Among these 17 to 21, R 2 is a methyl radical, n is behenic acid dimethylaminopropylamide is an integer of 3, dimethylaminopropyl amide stearic acid is particularly preferred. In this invention, 1 type (s) or 2 or more types can be arbitrarily used from these fatty acid amidoamines, The compounding quantity becomes like this. Preferably it is 0.1-7 mass%, More preferably, it is 0.1-5 mass % Range.
脂肪酸アミドアミンは、通常、酸を添加して中和して配合することが好ましく、中和により乳化剤としての機能がより発揮される。中和剤としては有機酸を用いることが好ましい。有機酸としては、例えば、グリコール酸、乳酸、グリセリン酸、グルコン酸、パントテン酸等のヒドロキシモノカルボン酸；リンゴ酸、酒石酸等のヒドロキシジカルボン酸；クエン酸等のヒドロキシトリカルボン酸、シュウ酸、マロン酸、マレイン酸、コハク酸、グルタル酸等のジカルボン酸；Ｌ−グルタミン酸、Ｌ−アスパラギン酸等の酸性アミノ酸；ピログルタミン酸、；安息香酸、ｐ−トルエンスルホン酸等の芳香族酸等が挙げられる。これらの中でも、乳化性の点から、ヒドロキモノカルボン酸、ヒドロキシジカルボン酸、ヒドロキシトリカルボン酸が好ましく、その中でも特に乳酸がより好ましい。脂肪酸アミドプロピルジメチルアミンと有機酸の中和は、乳化工程中で行っても、或いは予め脂肪酸アミドプロピルジメチルアミンと有機酸の塩を形成させてから配合しても良い。また、有機酸は、１種又は２種以上を組み合わせて用いることができ、その配合量は、脂肪酸アミドアミドアミンに対して、好ましくは０．５〜２モル倍、更に好ましくは０．７〜１．５モル倍の範囲である。 The fatty acid amidoamine is usually preferably added and neutralized by adding an acid, and the function as an emulsifier is more exhibited by neutralization. It is preferable to use an organic acid as the neutralizing agent. Examples of the organic acid include hydroxy monocarboxylic acids such as glycolic acid, lactic acid, glyceric acid, gluconic acid and pantothenic acid; hydroxydicarboxylic acids such as malic acid and tartaric acid; hydroxytricarboxylic acids such as citric acid, oxalic acid and malonic acid Dicarboxylic acids such as maleic acid, succinic acid and glutaric acid; acidic amino acids such as L-glutamic acid and L-aspartic acid; pyroglutamic acid; aromatic acids such as benzoic acid and p-toluenesulfonic acid. Among these, from the viewpoint of emulsification, hydroxymonocarboxylic acid, hydroxydicarboxylic acid, and hydroxytricarboxylic acid are preferable, and lactic acid is more preferable among them. Neutralization of the fatty acid amidopropyldimethylamine and the organic acid may be carried out in the emulsification step, or may be added after a salt of the fatty acid amidopropyldimethylamine and the organic acid is formed in advance. Moreover, an organic acid can be used 1 type or in combination of 2 or more types, The compounding quantity becomes like this. Preferably it is 0.5-2 mol times with respect to fatty-acid amide amide amine, More preferably, it is 0.7-1. .5 mol times range.
本発明で用いられる（Ｂ）成分のうち、第４級アンモニウム塩としては、例えば塩化アルキルトリメチルアンモニウム、塩化ジアルキルジメチルアンモニウム、塩化ステアリルトリメチルアンモニウム、エチル硫酸ラノリン脂肪酸アミノプロピルエチルジメチルアンモニウム、ジココイルエチルヒドロキシエチルモニウムメトサルフェート、ステアロキシプロピルジメチルアミン、ステアロキシプロピルトリモニウムクロリド、ステアリルＰＧ
ジメチルアミン、ステアリルＰＧトリモニウムクロリド、ベヘニルＰＧトリモニウムクロリドなどが挙げられる。その中でも塩化アルキルトリメチルアンモニウム、塩化ジアルキルジメチルアンモニウム、及びベヘニルＰＧトリモニウムクロリドから選ればれる少なくとも一種を用いることが好ましい。
Of the component (B) used in the present invention, examples of the quaternary ammonium salt include alkyltrimethylammonium chloride, dialkyldimethylammonium chloride, stearyltrimethylammonium chloride, ethyl lanolin sulfate fatty acid aminopropylethyldimethylammonium, and cocoylethylhydroxy. Ethylmonium methosulphate, stearoxypropyldimethylamine, stearoxypropyltrimonium chloride, stearyl PG
Examples include dimethylamine, stearyl PG trimonium chloride, and behenyl PG trimonium chloride. Among them, it is preferable to use at least one selected from alkyltrimethylammonium chloride, dialkyldimethylammonium chloride, and behenyl PG trimonium chloride.
本発明で用いられる（Ｃ）成分である清涼化剤としては、特に限定されるものではないが、例えば速やかに清涼感の得られるメントール、カンファー、ミント、ユーカリ油等や、遅効性のメントール誘導体であるメンチルラクテート、メントキシプロパンジオール、メンチルヒドロキシブチレート、メントキシフラン、メンチルグルコシド等を挙げることができる。これら清涼剤の中では特にメント−ルを用いることが好ましく、Ｌ−メントール及びＤＬ−メントールを用いることが更に好ましい。また、これら清涼剤の配合量は、好ましくは０．０１〜３．０％、更に好ましくは０．１〜１．０％である。この配合量の範囲であれば、十分な清涼感と、すっきりとした感触が得られる。 The refreshing agent that is the component (C) used in the present invention is not particularly limited. For example, menthol, camphor, mint, eucalyptus oil, etc. that can quickly obtain a refreshing feeling, and slow-acting menthol derivatives Menthyl lactate, menthoxypropanediol, menthyl hydroxybutyrate, menthoxyfuran, menthyl glucoside and the like. Among these refreshing agents, menthol is particularly preferably used, and L-menthol and DL-menthol are more preferably used. Moreover, the compounding quantity of these refreshing agents becomes like this. Preferably it is 0.01 to 3.0%, More preferably, it is 0.1 to 1.0%. If it is the range of this compounding quantity, sufficient refreshing feeling and a refreshing feeling will be acquired.
本発明の洗浄及びコンディショニング用の組成物は、アニオン界面活性剤、両性界面活性剤及びシリコーン化合物を実質的に含有しない。ここで、「実質的に含有しない」とは、不純物として等、意図せずに含有される場合を除いて含有しないことを意味するものである。 The cleaning and conditioning composition of the present invention is substantially free of anionic surfactants, amphoteric surfactants and silicone compounds. Here, “substantially does not contain” means that it is not contained unless it is intentionally contained as an impurity or the like.
本発明の毛髪の洗浄及びコンディショニング用の組成物の使用方法としては、お湯で十分に濡らした頭皮及び毛髪に対し塗布し、頭皮を中心に手指を使ってマッサージした後洗い流す方法が挙げられ、泡立たずに洗浄とコンディショニングを１度で完結することができる処理剤、すなわちクレンジングコンディショナー等に用いることができる。また本発明の毛髪の洗浄及びコンディショニング用の組成物は、常法により製造することができ、その剤型は特に限定されず、例えばクリーム状、乳液状等の乳化物、液状、ジェル状、ムース状等の適宜な剤型にして用いることができる。 Examples of the method of using the composition for washing and conditioning hair of the present invention include a method of applying to the scalp and hair sufficiently wet with hot water, massaging with the fingers around the scalp and washing off, and then lathering. Without being used, it can be used as a treatment agent that can complete cleaning and conditioning at one time, that is, a cleansing conditioner. The composition for washing and conditioning the hair of the present invention can be produced by a conventional method, and its dosage form is not particularly limited. For example, emulsions such as cream and emulsion, liquids, gels, mousses It can be used in an appropriate dosage form such as a shape.
また、本発明の毛髪の洗浄及びコンディショニング用の組成物には、本発明の効果を損なわない範囲で公知の成分を適宜配合することができる。公知の成分としては、例えば、ヒドロキシエチルセルロース、ポリ（塩化ジアリルジメチルアンモニウム）、高重合ポリエチレングリコール等の高分子化合物；グリセリン、プロピレングリコール、ブチレングリコール、ジプロピレングリコール等の湿潤剤；ステアリン酸、ベヘニン酸、オレイン酸等の高級脂肪酸；流動イソパラフィン、ワセリン、スクワラン等の炭化水素；ジンクピリチオン、塩化ベンザルコニウム等の抗フケ成分；エタノール、メタノール、プロピルアルコール、イソプロピルアルコール等の低級アルコール；Ｌ−アスパラギン酸、Ｌ−アスパラギン酸ナトリウム、ＤＬ−アラニン、Ｌ−アルギニン、グリシン、Ｌ−グルタミン酸、Ｌ−システイン、Ｌスレオニン等のアミノ酸；その他紫外線吸収剤、防腐剤、糖類、香料、色剤、金属イオン封鎖剤、酸化防止剤、各種薬剤、水等が挙げられる。 Moreover, a well-known component can be suitably mix | blended with the composition for washing | cleaning and conditioning of hair of this invention in the range which does not impair the effect of this invention. Known components include, for example, polymer compounds such as hydroxyethyl cellulose, poly (diallyldimethylammonium chloride) and highly polymerized polyethylene glycol; wetting agents such as glycerin, propylene glycol, butylene glycol and dipropylene glycol; stearic acid, behenic acid Higher fatty acids such as oleic acid; hydrocarbons such as liquid isoparaffin, petrolatum and squalane; anti-dandruff components such as zinc pyrithione and benzalkonium chloride; lower alcohols such as ethanol, methanol, propyl alcohol and isopropyl alcohol; L-aspartic acid; Amino acids such as L-sodium aspartate, DL-alanine, L-arginine, glycine, L-glutamic acid, L-cysteine, L-threonine; other UV absorbers, preservatives, sugars, fragrances , Colorant, sequestering agents, antioxidants, various drugs, water and the like.
次に本発明の毛髪の洗浄及びコンディショニング用の組成物について実施例を用いて詳細に説明するが、本発明はこれにより限定されるものではない。実施例に先立ち、各実施例で採用した評価試験法を説明する。 Next, the hair washing and conditioning composition of the present invention will be described in detail with reference to examples, but the present invention is not limited thereto. Prior to the examples, the evaluation test methods employed in each example will be described.
（１）使用感評価試験法
２０名のパネルが、本発明の実施例及び比較例に係る試料を毛髪及び頭皮に塗布し、頭皮へのマッサージを行いながら剤を全体にいきわたらせた後、剤を良くすすぎ流した。その際の使用時の操作のしやすさ、指通り（すすぎ時のきしみ）、清涼感について「良い」、「普通」、「悪い」の３段階で判定し、判定結果を「良い」と回答した人数により判断した。また、頭皮刺激について、刺激が「ある」、「ない」で判定し、「ない」と回答した
人数により判断した。
判断基準は以下の通りである。
（頭皮刺激以外）
◎：大変優れている・・・「良い」と答えた人数が１６名以上
○：優れている ・・・「良い」と答えた人数が１１〜１５名
△：劣っている ・・・「良い」と答えた人数が６〜１０名
×：大変劣っている・・・「良い」と答えた人数が５名以下
（頭皮刺激）
◎：大変優れている・・・「ない」と答えた人数が１６名以上
○：優れている ・・・「ない」と答えた人数が１１〜１５名
△：劣っている ・・・「ない」と答えた人数が６〜１０名
×：大変劣っている・・・「ない」と答えた人数が５名以下
(1) Usability Evaluation Test Method After a panel of 20 persons applied the samples according to the examples and comparative examples of the present invention to the hair and scalp and spread the agent throughout the scalp while massaging the agent, Rinse well. At that time, the ease of operation during use, fingering (squeak when rinsing), and refreshing feeling are judged in three stages, “good”, “normal”, and “bad”, and the judgment result is “good” Judgment by the number of people. In addition, the scalp stimulation was determined based on the number of respondents who answered “No” or “No” for the stimulation.
Judgment criteria are as follows.
(Other than scalp stimulation)
◎: Very good ... more than 16 people answered "good" ○: Excellent ... 11-15 people answered "good" △: Inferior ... "Good The number of people who answered “6” to 10 people ×: Very inferior ... The number of people who answered “good” is 5 or less (scalp stimulation)
◎: Very good ... more than 16 people answered "No" ○: Excellent ... 11-15 people answered "No" △: Inferior ... "No The number of people who answered “6” to 10 people ×: Very inferior ...
（２）使用後の毛髪の仕上がり感評価試験法
２０名のパネルが上記の使用感評価試験に引き続き毛髪を乾燥させた後、使用後の毛髪のしっとり感、まとまり、さっぱり感について「良い」、「普通」、「悪い」の３段階で判定し、判定結果を「良い」と回答した人数により判断した。
判断基準は以下の通りである。
◎：大変優れている・・・「良い」と答えた人数が１６名以上
○：優れている ・・・「良い」と答えた人数が１１〜１５名
△：劣っている ・・・「良い」と答えた人数が６〜１０名
×：大変劣っている・・・「良い」と答えた人数が５名以下
(2) Hair finish feeling evaluation test method after use After 20 panels dried the hair following the above feeling evaluation test, the hair feels moist, cohesive and refreshed after use. Judgment was made in three stages, “normal” and “bad”, and the judgment result was judged by the number of people who answered “good”.
Judgment criteria are as follows.
◎: Very good ... more than 16 people answered "good" ○: Excellent ... 11-15 people answered "good" △: Inferior ... "Good The number of people who answered “6” to 10 people ×: Very inferior ... The number of people who answered “good” is 5 or less
（３）頭皮・毛髪の状態観察（ハーフヘッド法）
洗髪前の毛髪及び頭皮をマイクロスコープ（キーエンス社製 VHX-1000）で観察し、次いで頭髪を左右半々に分け、一方にコントロールとして以下に記載のリンスインシャンプーを塗布し、他方に本発明の実施例及び比較例に係る試料をそれぞれ塗布し、頭皮へのマッサージを行いながら剤を全体にいきわたらせた後、剤を良くすすぎ流した。毛髪を乾燥させた後の毛髪及び頭皮を前記マイクロスコープで観察し、使用前後の毛髪及び頭皮の状態を比較し、頭皮・毛髪の汚れ落ち、頭皮保湿性を４段階で評価した。
(3) Scalp / hair condition observation (half-head method)
The hair and scalp before shampooing were observed with a microscope (VHX-1000 manufactured by Keyence Co., Ltd.), then the hair was divided into left and right halves, and the rinse in shampoo described below was applied to one side as a control, and the examples of the present invention to the other side And the sample which concerns on a comparative example was apply | coated, respectively, and after carrying out the massage to a scalp, the agent was spread over the whole, and the agent was rinsed well. The hair and scalp after the hair was dried were observed with the microscope, the state of the hair and scalp before and after use were compared, and the scalp / hair was cleaned and the moisturizing property of the scalp was evaluated in four stages.
コントロール（リンスインシャンプー）
質量％
ラウレス硫酸ナトリウム １０
パーム核油脂肪酸アミドプロピルベタイン ３
ジメチコン １．２５
塩化ナトリウム 適量
クエン酸 適量
純水 残量
合計 １００
Control (rinse in shampoo)
mass%
Sodium laureth sulfate 10
Palm kernel oil fatty acid amidopropyl betaine 3
Dimethicone 1.25
Sodium chloride Appropriate amount Citric acid Appropriate amount Pure water Total remaining amount 100
判断基準は以下の通りである。
（頭皮・毛髪の汚れ落ち）
◎：大変優れている・・・残存皮脂がコントロールよりも少ない場合
○：優れている ・・・残存皮脂は見られるが、コントロールと同等の場合
△：劣っている ・・・残存皮脂が洗浄前より減っているが、コントロールと比較し多い場合
×：大変劣っている・・・残存皮脂が洗浄前と同様の場合
（頭皮保湿性）
◎：大変優れている・・・乾燥によるフケがみられずしっとりとした頭皮状態の場合
○：優れている ・・・コントロールと同等かそれ以下の乾燥によるフケがみられる場合
△：劣っている ・・・頭皮にコントロールより多い、乾燥によるフケが見られる場合×：大変劣っている・・・頭皮に乾燥による頭皮のめくれ、フケが多く見られる場合
Judgment criteria are as follows.
(Scalp and hair stains removed)
◎: Very good ... When residual sebum is less than control ○: Excellent ... Residual sebum is seen, but equivalent to control △: Inferior ... Residual sebum before washing Although it is less, but more compared to the control ×: very poor ... When the residual sebum is the same as before washing (scalp moisturizing)
◎: Extremely excellent ... When dandruff due to drying is not seen and moist scalp condition ○: Excellent ・ ・ ・ When dandruff due to drying equal to or less than control is observed △: Inferior・ ・ ・ When there is more dandruff due to dryness than the control on the scalp ×: very poor. When the scalp is turned over due to dryness and many dandruff is seen
実施例１〜９及び比較例１〜５（クレンジングコンディショナー）
表１に記載の配合組成によるクレンジングコンディショナーを調製し、使用感、使用後の毛髪の仕上がり感、使用後の頭皮・毛髪の状態について調べ、その結果を表１に示した。なお、以下の実施例の組成における配合量は質量％である。
Examples 1-9 and Comparative Examples 1-5 (cleansing conditioner)
A cleansing conditioner having the composition shown in Table 1 was prepared, and the feeling of use, the finish of the hair after use, and the condition of the scalp and hair after use were examined. The results are shown in Table 1. In addition, the compounding quantity in the composition of a following example is the mass%.
表１より明らかなように、本発明の成分を用いた実施例のクレンジングコンディショナーはいずれも優れた性能を見出した。一方、比較例１〜５では、前記の評価試験法におけるいずれかの評価項目で劣っており、本発明の目的を達成できなかった。 As is clear from Table 1, all of the cleansing conditioners of Examples using the components of the present invention found excellent performance. On the other hand, in Comparative Examples 1-5, it was inferior in any evaluation item in the said evaluation test method, and the objective of this invention was not able to be achieved.
以下、本発明の毛髪の洗浄及びコンディショニング用の組成物のその他の処方例を実施例１０として挙げる。なお、実施例１０のクレンジングコンディショナーについても、上記の操作時使用感評価、仕上がり感評価、頭皮・毛髪の状態、の各項目を検討したところ、いずれも優れた特性を有しており良好であった。 Hereinafter, other formulation examples of the hair cleaning and conditioning composition of the present invention will be described as Example 10. In addition, the cleansing conditioner of Example 10 was also examined for each of the above-described operational feeling evaluation during operation, finished feeling evaluation, and scalp / hair condition. It was.
実施例１０（クレンジングコンディショナー） 配合量（質量％）（１）ステアリルアルコール ２．４０
（２）ジステアリン酸ペンタエリスチル ２．００
（３）グリセリン １．５０
（４）ベヘナミドプロピルジメチルアミン １．３０
（５）コハク酸ジ２−エチルヘキシル １．００
（６）ジカプリン酸ネオペンチルグリコール １．００
（７）ベヘニルＰＧトリモニウムクロリド ０．７０
（８）乳酸 ０．５５
（９）パラフィン ０．５０
（１０）ベヘニルアルコール ０．３５
（１１）ソルビトール ２．１０
（１２）ヒドロキシエチルセルロース ０．２０
（１３）ベヘンジモニウムエチルリン酸ステアリル ０．０３
（１４）（メタクリル酸グリセリルアミドエチル／
メタクリル酸ステアリル）コポリマー ０．０１
（１５）ＰＰＧ−３カプリリルエーテル １．００
（１６）メントール ０．１５
（１７）精製水 全量を１００とする
Example 10 (cleansing conditioner) Blending amount (% by mass) (1) Stearyl alcohol 2.40
(2) Pentaerystyl distearate 2.00
(3) Glycerin 1.50
(4) Behenamidopropyldimethylamine 1.30
(5) Di-2-ethylhexyl succinate 1.00
(6) Neopentyl glycol dicaprate 1.00
(7) Behenyl PG trimonium chloride 0.70
(8) Lactic acid 0.55
(9) Paraffin 0.50
(10) Behenyl alcohol 0.35
(11) Sorbitol 2.10
(12) Hydroxyethyl cellulose 0.20
(13) Behendimonium ethyl stearyl phosphate 0.03
(14) (Glyceryl amidoethyl methacrylate /
Stearyl methacrylate) copolymer 0.01
(15) PPG-3 caprylyl ether 1.00
(16) Menthol 0.15
(17) Total amount of purified water is 100
（製法）（１）〜（１０）を８０℃にて均一に混合溶解し、６０℃に加温した（１７）に（１１）〜（１４）を分散したものを加え、乳化を行う。ホモミキサーで混合分散し徐々に冷却を行い、６０℃にて（１５）〜（１６）を添加し、室温まで冷却して、クレンジングコンディショナーを調製した。
(Production method) (1) to (10) are uniformly mixed and dissolved at 80 ° C., and (17) heated at 60 ° C. is added with (11) to (14) dispersed therein, followed by emulsification. A cleansing conditioner was prepared by mixing and dispersing with a homomixer and gradually cooling, adding (15) to (16) at 60 ° C., and cooling to room temperature.
Claims (2)
（Ａ）２０℃において液状のエステル油
（Ｂ）下記一般式（Ｉ）で表される脂肪酸アミドアミン及び／又は第４級アンモニウム塩
Ｒ１−ＣＯ−ＮＨ−（ＣＨ２）ｎ−Ｎ（Ｒ２）２ ・・・（Ｉ）
（式中、Ｒ１は、直鎖又は分岐した炭素数１３〜２３の飽和又は不飽和脂肪酸残基、Ｒ２は炭素数１〜３のアルキル基、ｎは１〜５の整数を示す。）
（Ｃ）清涼化剤 A composition for washing and conditioning hair, comprising the following components (A) to (C) and substantially free of an anionic surfactant, an amphoteric surfactant and a silicone compound.
(A) ester oil which is liquid at 20 ° C. (B) fatty acid amidoamine and / or quaternary ammonium salt represented by the following general formula (I)
R 1 —CO—NH— (CH 2 ) n —N (R 2 ) 2 (I)
(In the formula, R 1 represents a linear or branched saturated or unsaturated fatty acid residue having 13 to 23 carbon atoms, R 2 represents an alkyl group having 1 to 3 carbon atoms, and n represents an integer of 1 to 5).
(C) Coolant
A method for washing and conditioning hair, wherein the composition for washing and conditioning hair according to claim 1 is applied to wet hair and then washed away.
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| JP2007332046A (en) * | 2006-06-13 | 2007-12-27 | Ogawa & Co Ltd | Hair shampoo |
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| JP2013155162A (en) * | 2012-01-31 | 2013-08-15 | Mandom Corp | Liquid hair cleanser |
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