JP2017508714A - Method for producing hydrogen anion-containing material and hydrogen anion-containing material produced using the same - Google Patents
Method for producing hydrogen anion-containing material and hydrogen anion-containing material produced using the same Download PDFInfo
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- JP2017508714A JP2017508714A JP2016535013A JP2016535013A JP2017508714A JP 2017508714 A JP2017508714 A JP 2017508714A JP 2016535013 A JP2016535013 A JP 2016535013A JP 2016535013 A JP2016535013 A JP 2016535013A JP 2017508714 A JP2017508714 A JP 2017508714A
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- containing material
- hydrogen anion
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- oxide
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- 239000001257 hydrogen Substances 0.000 title claims abstract description 89
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 89
- -1 hydrogen anion Chemical class 0.000 title claims abstract description 83
- 239000000463 material Substances 0.000 title claims abstract description 70
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 28
- 230000001603 reducing effect Effects 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims abstract description 8
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 47
- 238000010304 firing Methods 0.000 claims description 37
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 26
- 239000011575 calcium Substances 0.000 claims description 26
- 229910052791 calcium Inorganic materials 0.000 claims description 26
- 235000010216 calcium carbonate Nutrition 0.000 claims description 23
- 239000000395 magnesium oxide Substances 0.000 claims description 20
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 20
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 20
- 150000007524 organic acids Chemical class 0.000 claims description 16
- 150000001341 alkaline earth metal compounds Chemical class 0.000 claims description 15
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 10
- 150000002681 magnesium compounds Chemical class 0.000 claims description 10
- 150000001450 anions Chemical class 0.000 claims description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 8
- LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- FRWYFWZENXDZMU-UHFFFAOYSA-N 2-iodoquinoline Chemical compound C1=CC=CC2=NC(I)=CC=C21 FRWYFWZENXDZMU-UHFFFAOYSA-N 0.000 claims description 6
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 6
- 239000000292 calcium oxide Substances 0.000 claims description 6
- 210000003278 egg shell Anatomy 0.000 claims description 5
- 102000002322 Egg Proteins Human genes 0.000 claims description 4
- 108010000912 Egg Proteins Proteins 0.000 claims description 4
- 241001474374 Blennius Species 0.000 claims description 3
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 3
- 150000001553 barium compounds Chemical class 0.000 claims description 3
- 150000001573 beryllium compounds Chemical class 0.000 claims description 3
- 229910001424 calcium ion Inorganic materials 0.000 claims description 3
- 239000000126 substance Substances 0.000 abstract description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 6
- 230000019522 cellular metabolic process Effects 0.000 abstract description 6
- 239000001301 oxygen Substances 0.000 abstract description 6
- 229910052760 oxygen Inorganic materials 0.000 abstract description 6
- 241000251468 Actinopterygii Species 0.000 abstract description 5
- 235000019688 fish Nutrition 0.000 abstract description 5
- 235000013399 edible fruits Nutrition 0.000 abstract description 4
- 235000013372 meat Nutrition 0.000 abstract description 4
- 235000013311 vegetables Nutrition 0.000 abstract description 4
- 230000003647 oxidation Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- 235000013305 food Nutrition 0.000 abstract description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 22
- 239000000047 product Substances 0.000 description 20
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 15
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 11
- 150000001342 alkaline earth metals Chemical class 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- 229910052500 inorganic mineral Inorganic materials 0.000 description 7
- 235000010755 mineral Nutrition 0.000 description 7
- 239000011707 mineral Substances 0.000 description 7
- 239000011777 magnesium Substances 0.000 description 6
- 230000000704 physical effect Effects 0.000 description 6
- 238000001354 calcination Methods 0.000 description 5
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- 230000003078 antioxidant effect Effects 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 239000008399 tap water Substances 0.000 description 4
- 235000020679 tap water Nutrition 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000012159 carrier gas Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000033116 oxidation-reduction process Effects 0.000 description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
- CSDQQAQKBAQLLE-UHFFFAOYSA-N 4-(4-chlorophenyl)-4,5,6,7-tetrahydrothieno[3,2-c]pyridine Chemical compound C1=CC(Cl)=CC=C1C1C(C=CS2)=C2CCN1 CSDQQAQKBAQLLE-UHFFFAOYSA-N 0.000 description 2
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- 206010019133 Hangover Diseases 0.000 description 2
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- 235000015165 citric acid Nutrition 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000001755 magnesium gluconate Substances 0.000 description 2
- 235000015778 magnesium gluconate Nutrition 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- 235000019341 magnesium sulphate Nutrition 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 235000015170 shellfish Nutrition 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 241000258957 Asteroidea Species 0.000 description 1
- 241000972773 Aulopiformes Species 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 1
- 241000237502 Ostreidae Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- MHJAJDCZWVHCPF-UHFFFAOYSA-L dimagnesium phosphate Chemical compound [Mg+2].OP([O-])([O-])=O MHJAJDCZWVHCPF-UHFFFAOYSA-L 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000003745 glyceroyl group Chemical group C(C(O)CO)(=O)* 0.000 description 1
- 235000013402 health food Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 229960003035 magnesium gluconate Drugs 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 1
- 229910000400 magnesium phosphate tribasic Inorganic materials 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 229940091250 magnesium supplement Drugs 0.000 description 1
- IAKLPCRFBAZVRW-XRDLMGPZSA-L magnesium;(2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanoate;hydrate Chemical compound O.[Mg+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O IAKLPCRFBAZVRW-XRDLMGPZSA-L 0.000 description 1
- OVGXLJDWSLQDRT-CEOVSRFSSA-L magnesium;(2s)-2-hydroxypropanoate Chemical compound [Mg+2].C[C@H](O)C([O-])=O.C[C@H](O)C([O-])=O OVGXLJDWSLQDRT-CEOVSRFSSA-L 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000005677 organic carbonates Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 235000019515 salmon Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 235000011044 succinic acid Nutrition 0.000 description 1
- FKHIFSZMMVMEQY-UHFFFAOYSA-N talc Chemical compound [Mg+2].[O-][Si]([O-])=O FKHIFSZMMVMEQY-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/38—Other non-alcoholic beverages
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
- A23L33/16—Inorganic salts, minerals or trace elements
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P17/00—Drugs for dermatological disorders
- A61P17/02—Drugs for dermatological disorders for treating wounds, ulcers, burns, scars, keloids, or the like
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P17/00—Drugs for dermatological disorders
- A61P17/18—Antioxidants, e.g. antiradicals
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- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nutrition Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Mycology (AREA)
- Inorganic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Public Health (AREA)
- General Chemical & Material Sciences (AREA)
- Dermatology (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Organic Chemistry (AREA)
- Pharmacology & Pharmacy (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Veterinary Medicine (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Biochemistry (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Non-Alcoholic Beverages (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
Abstract
【課題】本発明は、水素陰イオン含有物の製造方法及びこれを用いて製造された水素陰イオン含有物に関する。【解決手段】前記水素陰イオン含有物は、細胞の新陳代謝を促進し、体内の活性酸素を除去することができる。そして、前記製造方法で製造された水素陰イオン含有物は、周辺環境、例えば、温度の変化に敏感ではなく、空気に露出しても変性しなくて保存が容易であるので、各種飲料又は各種食資材に添加され、前記機能を発揮することができる。また、前記水素陰イオン含有物は、果物、野菜、魚類及び肉類などの食資材に添加され、これらの酸化を防止し、高い新鮮度を長い間維持させることができる。また、前記水素陰イオン含有物は、酸化された皮膚と外傷を負った皮膚を還元作用で回復させることができる。【選択図】図1The present invention relates to a method for producing a hydrogen anion-containing material and a hydrogen anion-containing material produced using the method. The hydrogen anion-containing substance promotes cell metabolism and can remove active oxygen in the body. Since the hydrogen anion-containing product produced by the production method is not sensitive to changes in the surrounding environment, for example, temperature, and is not denatured even when exposed to air, it can be stored easily. It is added to food materials and can exhibit the above functions. Moreover, the said hydrogen anion containing material is added to foodstuffs, such as fruit, vegetables, fish, and meats, These oxidation can be prevented and high freshness can be maintained for a long time. The hydrogen anion-containing material can restore oxidized skin and injured skin by a reducing action. [Selection] Figure 1
Description
本発明は、水素陰イオン含有物の製造方法及びこれを用いて製造した水素陰イオン含有物に関し、より具体的には、細胞の新陳代謝を促進し、体内の活性酸素を除去できる水素陰イオン含有物の製造方法及びこれを用いて製造した水素陰イオン含有物に関する。 The present invention relates to a method for producing a hydrogen anion-containing material and a hydrogen anion-containing material produced using the method, and more specifically, a hydrogen anion-containing material that promotes cell metabolism and removes active oxygen in the body. The present invention relates to a method for producing a product and a hydrogen anion-containing product produced using the method.
最近、陰イオンの抗酸化作用により、多様な形態の陰イオン製品が販売されている。例えば、室内空気を浄化できるイオン発生器、水道水における石灰の臭いを除去し、ミネラル化できる陰イオン製品が開発されている。 Recently, various forms of anionic products have been marketed due to the antioxidant action of anions. For example, an ion generator that can purify indoor air and an anion product that can remove mineral lime from tap water and mineralize it have been developed.
また、前記のように単純に生活環境の改善水準に留まっていた陰イオンは、既に食用製品にも開発されており、食用の陰イオン製品が市販されている。しかし、市販される陰イオン製品は、水に対する溶解度が劣悪であり、体内で円滑な抗酸化作用を図ることができない。また、市販される陰イオン製品の長時間保存が容易でなく、陰イオン製品を製造するために使用される小麦粉などによって多くの副作用をもたらしている。よって、摂取可能な陰イオン製品に対しては、未だに多くの研究が必要な実情にある。 In addition, as described above, anions that have simply remained at the level of improvement in the living environment have already been developed in edible products, and edible anion products are commercially available. However, commercially available anion products have poor water solubility and cannot achieve a smooth antioxidant effect in the body. In addition, it is not easy to store a commercially available anion product for a long time, and many side effects are caused by flour used to produce an anion product. Therefore, there is still much need for research on ingestible anion products.
本発明の目的は、細胞の新陳代謝を促進し、体内の活性酸素を除去できる水素陰イオン含有物の製造方法を提供することにある。 An object of the present invention is to provide a method for producing a hydrogen anion-containing material that can promote cell metabolism and remove active oxygen in the body.
本発明の他の目的は、前記製造方法によって製造された水素陰イオン含有物を提供することにある。 Another object of the present invention is to provide a hydrogen anion-containing material produced by the production method.
前記目的を達成するために、本発明の一実施例に係る水素陰イオン含有物の製造方法は、有機炭酸カルシウムを含むアルカリ土金属化合物を焼成することによって第1焼成体を製造する第1焼成段階;前記第1焼成体を含むアルカリ土金属酸化物を焼成することによって第2焼成体を製造する第2焼成段階;及び前記第2焼成体と有機酸を配合する段階;を含む。 In order to achieve the above object, a method for producing a hydrogen anion-containing material according to an embodiment of the present invention is a first firing in which a first fired body is produced by firing an alkaline earth metal compound containing organic calcium carbonate. A second firing step of producing a second fired body by firing an alkaline earth metal oxide containing the first fired body; and a step of blending the second fired body with an organic acid.
前記第1焼成段階は、アルカリ土金属化合物を300℃〜1000℃で2時間以上焼成することを含むことができる。 The first firing step may include firing the alkaline earth metal compound at 300 ° C. to 1000 ° C. for 2 hours or more.
前記アルカリ土金属化合物は、ベリリウム化合物、マグネシウム化合物、バリウム化合物又はこれらの混合物をさらに含むことができる。 The alkaline earth metal compound may further include a beryllium compound, a magnesium compound, a barium compound, or a mixture thereof.
前記第2焼成段階において、ベリリウム酸化物、マグネシウム酸化物、バリウム酸化物又はこれらの混合物を添加することを含むことができる。そして、前記アルカリ土金属酸化物は、カルシウム酸化物100モルに対して1モル〜60モルのベリリウム酸化物、マグネシウム酸化物、バリウム酸化物又はこれらの混合物を含むことができる。 In the second firing step, beryllium oxide, magnesium oxide, barium oxide, or a mixture thereof may be added. The alkaline earth metal oxide may contain 1 to 60 mol of beryllium oxide, magnesium oxide, barium oxide or a mixture thereof with respect to 100 mol of calcium oxide.
前記第2焼成段階は、アルカリ土金属酸化物を水素雰囲気下で300℃〜1000℃で2時間以上焼成することを含むことができる。 The second firing step may include firing the alkaline earth metal oxide at 300 ° C. to 1000 ° C. for 2 hours or more in a hydrogen atmosphere.
前記第2焼成体は、第2焼成体に含まれたカルシウムイオン100モルに対して0.5モル〜10モルの有機酸と配合することができる。 The second fired body can be blended with 0.5 to 10 moles of organic acid with respect to 100 moles of calcium ions contained in the second fired body.
本発明の他の一実施例に係る水素陰イオン含有物は、前記製造方法で製造されたものであり得る。 The hydrogen anion containing material according to another embodiment of the present invention may be manufactured by the above manufacturing method.
前記水素陰イオン含有物は、水に溶解した直後、pHが6〜12であるか;水に溶解した直後、−0.1mV〜−900mVの酸化還元電位を有するか;又は1時間〜150時間の還元力持続時間を有するものであり得る。 The hydrogen anion-containing material has a pH of 6 to 12 immediately after being dissolved in water; has a redox potential of −0.1 mV to −900 mV immediately after being dissolved in water; or 1 to 150 hours And having a reducing power duration of.
本発明の一実施例に係る水素陰イオン含有物は、細胞の新陳代謝を促進し、体内の活性酸素を除去することができる。そして、本発明の一実施例に係る製造方法で製造された水素陰イオン含有物は、周辺環境、例えば、温度の変化に敏感ではなく、空気に露出しても変性しなくて保存が容易であるので、各種飲料又は各種食資材に添加され、前記機能を発揮することができる。また、前記水素陰イオン含有物は、果物、野菜、魚類及び肉類などの食資材に添加され、これらの酸化を防止し、高い新鮮度を長い間維持させることができる。また、前記水素陰イオン含有物は、酸化された皮膚と外傷を負った皮膚を還元作用で回復させることができる。 The hydrogen anion-containing material according to one embodiment of the present invention can promote cell metabolism and remove active oxygen in the body. The hydrogen anion-containing material produced by the production method according to an embodiment of the present invention is not sensitive to changes in the surrounding environment, for example, temperature, and is not denatured even when exposed to air and can be stored easily. Since it exists, it can be added to various drinks or various foodstuffs, and can exhibit the said function. Moreover, the said hydrogen anion containing material is added to foodstuffs, such as fruit, vegetables, fish, and meats, These oxidation can be prevented and high freshness can be maintained for a long time. The hydrogen anion-containing material can restore oxidized skin and injured skin by a reducing action.
以下、本発明をより詳細に説明する。 Hereinafter, the present invention will be described in more detail.
本発明の一実施例に係る水素陰イオン含有物の製造方法は、有機炭酸カルシウムを含むアルカリ土金属化合物を焼成することによって第1焼成体を製造する第1焼成段階;前記第1焼成体を含むアルカリ土金属酸化物を焼成することによって第2焼成体を製造する第2焼成段階;及び前記第2焼成体と有機酸を配合する段階;を含む。 A method for producing a hydrogen anion-containing material according to an embodiment of the present invention includes a first firing step of producing a first fired body by firing an alkaline earth metal compound containing organic calcium carbonate; A second firing step of producing a second fired body by firing the alkaline earth metal oxide containing; and a step of blending the second fired body with an organic acid.
前記有機炭酸カルシウムは、炭酸カルシウムを含む有機物であって、鉱物などの無機物から採取する炭酸カルシウムとは区別される。有機炭酸カルシウムは、鉱物などの無機物から採取する炭酸カルシウムに比べて非常に微量の重金属を含むか、又は重金属を全く含まない。また、有機炭酸カルシウムは、鉱物などの無機物から採取する炭酸カルシウムに比べて豊かなミネラルを含んでいる。よって、有機炭酸カルシウムは、食用の水素陰イオン含有物を製造するのに非常に適している。 The organic calcium carbonate is an organic substance containing calcium carbonate, and is distinguished from calcium carbonate collected from an inorganic substance such as a mineral. Organic calcium carbonate contains a very small amount of heavy metals or no heavy metals at all compared to calcium carbonate collected from inorganic substances such as minerals. Organic calcium carbonate contains rich minerals compared to calcium carbonate collected from inorganic materials such as minerals. Thus, organic calcium carbonate is very suitable for producing edible hydrogen anion-containing materials.
前記有機炭酸カルシウムとしては、例えば、卵殻カルシウム、真珠カルシウム、貝殻カルシウム及び海藻カルシウムからなる群から選ばれる1種以上を使用することができる。 As said organic calcium carbonate, 1 or more types chosen from the group which consists of eggshell calcium, pearl calcium, shellfish calcium, and seaweed calcium, for example can be used.
前記卵殻カルシウムは、卵の殻などから得ることができ、貝殻カルシウムは、牡蠣、貝、アワビ又は魚類の骨などから得ることができ、前記海藻カルシウムは、ヒトデ又は珊瑚などから得ることができる。これらのうち、入手容易性の面で、卵殻カルシウム、貝殻カルシウム及びこれらの混合物を有機炭酸カルシウムとして使用することができる。 The eggshell calcium can be obtained from egg shells, the shell calcium can be obtained from oysters, shellfish, abalone or fish bones, and the seaweed calcium can be obtained from starfish or salmon. Of these, eggshell calcium, shell calcium, and mixtures thereof can be used as organic calcium carbonate in terms of availability.
前記水素陰イオン含有物の製造方法は、大きく二つの方式で行うことができる。第1実施形態では、アルカリ土金属化合物として、有機炭酸カルシウム及びカルシウムを除いたアルカリ土金属を含む化合物を物理的に配合したものを使用し、第2実施形態では、アルカリ土金属化合物として有機炭酸カルシウムを使用する。 The method for producing the hydrogen anion-containing material can be roughly performed in two ways. In the first embodiment, as the alkaline earth metal compound, organic calcium carbonate and a compound containing an alkaline earth metal excluding calcium are used physically. In the second embodiment, the organic carbonate is used as the alkaline earth metal compound. Use calcium.
前記第1実施形態において、前記アルカリ土金属化合物は、有機炭酸カルシウムの他に、ベリリウム化合物、マグネシウム化合物、バリウム化合物又はこれらの混合物をさらに含むことができる。前記カルシウム以外の他のアルカリ土金属を含む化合物は、製造された水素陰イオン含有物の還元力に影響を及ぼすので、適切な化合物を採用することによって水素陰イオン含有物の還元力を調節することができる。 In the first embodiment, the alkaline earth metal compound may further include a beryllium compound, a magnesium compound, a barium compound, or a mixture thereof in addition to the organic calcium carbonate. The compounds containing other alkaline earth metals other than calcium affect the reducing power of the produced hydrogen anion-containing material, and thus the reducing power of the hydrogen anion-containing material is adjusted by adopting an appropriate compound. be able to.
一つの例示において、アルカリ土金属化合物は、有機炭酸カルシウムの他に、マグネシウム化合物をさらに含むことができる。前記マグネシウム化合物は、水素陰イオン含有物の還元力を効率的に制御することができる。そして、カルシウムとの相互作用を通じてナトリウムの体外排出を助け、酸化窒素の生成を促進し、血流の増加を助けることができ、アセトアルデヒドなどを減少させることによって二日酔い及び疲れを解消させることができる。 In one example, the alkaline earth metal compound may further include a magnesium compound in addition to the organic calcium carbonate. The magnesium compound can efficiently control the reducing power of the hydrogen anion-containing material. In addition, sodium can be excreted through interaction with calcium, promote the production of nitric oxide, help increase blood flow, and can reduce hangover and fatigue by reducing acetaldehyde and the like.
前記マグネシウム化合物の種類は、第1焼成段階を経てマグネシウム酸化物を生成できるものであれば特に制限されない。このようなマグネシウム化合物としては、マグネシウム(Mg)、塩化マグネシウム(MgCl2)、ステアリン酸マグネシウム(Mg(C18H35O2)2)、炭酸マグネシウム(MgCO3)、硫酸マグネシウム(MgSO4)、水酸化マグネシウム(Mg(OH)2)、第3リン酸マグネシウム(Mg3(PO4)2)、第2リン酸マグネシウム(MgHPO4)、ケイ酸マグネシウム(MgSiO3)、グルコン酸マグネシウム(C12H22MgO14)、L―乳酸マグネシウム(Mg(C3H5O3)2・2H2O)、酸化マグネシウム(MgO)又はこれらの混合物などを例示することができる。 The kind of the magnesium compound is not particularly limited as long as it can produce a magnesium oxide through the first firing step. Such magnesium compounds include magnesium (Mg), magnesium chloride (MgCl2), magnesium stearate (Mg (C18H35O2) 2), magnesium carbonate (MgCO3), magnesium sulfate (MgSO4), magnesium hydroxide (Mg (OH)) 2), tertiary magnesium phosphate (Mg3 (PO4) 2), secondary magnesium phosphate (MgHPO4), magnesium silicate (MgSiO3), magnesium gluconate (C12H22MgO14), L-magnesium lactate (Mg (C3H5O3) 2. 2H2O), magnesium oxide (MgO), or a mixture thereof.
前記カルシウムを除いたアルカリ土金属を含む化合物は、目的とする水素陰イオン含有物の還元力、還元力の持続時間及び/又は水素陰イオンの濃度を考慮して適切な含量で使用することができる。一つの例示において、前記化合物は、有機炭酸カルシウムに含有されている炭酸カルシウム100モルに対して1モル〜60モル、1.6モル〜57モル、1.6モル〜50モル、1.6モル〜40モル、1.6モル〜30モル、5モル〜20モル又は5モル〜15モルで含ませることができる。前記化合物の含量が前記範囲未満である場合は、水素陰イオン含有物の還元力が過度に弱いか、又は還元力持続時間が過度に短い。一方、前記化合物の含量が前記範囲を超える場合は、服用するのに適切でない程度に過度に大きな還元力を有する水素陰イオン含有物が得られ、このような水素陰イオン含有物が体内の代謝作用を妨害し得る。 The compound containing an alkaline earth metal excluding calcium may be used in an appropriate content in consideration of the reducing power of the target hydrogen anion-containing substance, the duration of the reducing power and / or the concentration of hydrogen anion. it can. In one example, the compound is used in an amount of 1 mol to 60 mol, 1.6 mol to 57 mol, 1.6 mol to 50 mol, 1.6 mol with respect to 100 mol of calcium carbonate contained in the organic calcium carbonate. It can be included at -40 mol, 1.6 mol-30 mol, 5 mol-20 mol, or 5 mol-15 mol. When the content of the compound is less than the above range, the reducing power of the hydrogen anion-containing material is too weak, or the reducing power duration is too short. On the other hand, when the content of the compound exceeds the above range, a hydrogen anion-containing material having an excessively large reducing power that is not suitable for taking can be obtained, and such a hydrogen anion-containing material is metabolized in the body. May interfere with action.
一つの例示において、カルシウムを除いたアルカリ土金属を含む化合物としてマグネシウム化合物を使用する場合、有機炭酸カルシウムに含有されている炭酸カルシウム80重量部〜99.5重量部に対してマグネシウム化合物を0.5重量部〜20重量部で使用することができる。その結果、上述した効果を示す水素陰イオン含有物を提供することができる。 In one example, when a magnesium compound is used as the compound containing an alkaline earth metal excluding calcium, the magnesium compound is added in an amount of 0.8 to 99.5 parts by weight with respect to 80 parts by weight to 99.5 parts by weight of calcium carbonate. 5 to 20 parts by weight can be used. As a result, it is possible to provide a hydrogen anion-containing material that exhibits the effects described above.
前記第1焼成段階は、アルカリ土金属化合物を約300℃〜1000℃、約400℃〜900℃、約500℃〜800℃、約600℃〜800℃、約650℃〜800℃、約600℃〜750℃又は約650℃〜750℃で焼成することを含むことができる。また、前記アルカリ土金属化合物の焼成は、約2時間以上、約3時間以上又は約4時間以上間進行することができる。焼成時間の上限は、特に制限されなく、例えば、10時間以下に調節することができる。前記焼成が前記範囲未満の温度で前記範囲未満の時間の間行われる場合は、アルカリ土金属化合物が目的とする水準に酸化されないおそれがあり、前記焼成が前記範囲を超える温度で前記範囲以上の時間の間行われる場合は、莫大なエネルギーの浪費をもたらし得る。 In the first firing step, the alkaline earth metal compound is about 300 ° C to 1000 ° C, about 400 ° C to 900 ° C, about 500 ° C to 800 ° C, about 600 ° C to 800 ° C, about 650 ° C to 800 ° C, about 600 ° C. Calcination at about 750 ° C or about 650 ° C to 750 ° C. In addition, the firing of the alkaline earth metal compound can proceed for about 2 hours or more, about 3 hours or more, or about 4 hours or more. The upper limit of the firing time is not particularly limited, and can be adjusted to 10 hours or less, for example. When the calcination is performed at a temperature below the range for a time less than the range, the alkaline earth metal compound may not be oxidized to a target level, and the calcination is at a temperature exceeding the range above the range. If done for hours, it can result in enormous energy waste.
前記第1焼成段階は、特に限定されないが、例えば、大気下で進行することができる。 The first firing step is not particularly limited, and may be performed in the atmosphere, for example.
前記水素陰イオン含有物の製造方法は、第1焼成段階以後に第1焼成体を冷却させる段階をさらに含むことができる。第1焼成体を冷却させる方法としては、特に限定されないが、例えば、自然冷却が可能である。前記自然冷却は、加熱された容器に入った第1焼成体を常温又は目的とする温度に到逹するまで放置して行うことができる。本明細書において、常温は、加温又は減温されてない自然そのままの温度を意味する。 The method for producing a hydrogen anion-containing material may further include a step of cooling the first fired body after the first firing step. Although it does not specifically limit as a method to cool a 1st sintered body, For example, natural cooling is possible. The natural cooling can be performed by leaving the first fired body in a heated container until it reaches room temperature or a target temperature. In this specification, normal temperature means the natural temperature which has not been heated or reduced.
第1実施形態によって第1焼成段階を経ると、第1焼成体は、有機炭酸カルシウムから得られたカルシウム酸化物(CaO)、カルシウムを除いたアルカリ土金属を含む化合物から得られたベリリウム酸化物(BeO)、マグネシウム酸化物(MgO)、バリウム酸化物(BaO)又はこれらの混合物を含むことができる。 When the first firing step is performed according to the first embodiment, the first fired body is a calcium oxide (CaO) obtained from organic calcium carbonate, a beryllium oxide obtained from a compound containing an alkaline earth metal excluding calcium. (BeO), magnesium oxide (MgO), barium oxide (BaO) or mixtures thereof.
一つの例示において、カルシウムを除いたアルカリ土金属を含む化合物としてマグネシウム化合物を使用した場合、第1焼成体は、カルシウム酸化物及びマグネシウム酸化物を含むことができる。 In one example, when a magnesium compound is used as a compound including an alkaline earth metal excluding calcium, the first fired body can include calcium oxide and magnesium oxide.
その一方、第2実施形態によって第1焼成段階を経ると、第1焼成体は、有機炭酸カルシウムから得られたカルシウム酸化物(CaO)を含む。よって、この場合は、第1実施形態によって製造された第1焼成体と同一の構成を有するように、第2焼成段階でカルシウムを除いたアルカリ土金属を含む酸化物を添加することができる。前記カルシウムを除いたアルカリ土金属を含む酸化物は、ベリリウム酸化物(BeO)、マグネシウム酸化物(MgO)、バリウム酸化物(BaO)又はこれらの混合物であり得る。 On the other hand, when the first firing stage is performed according to the second embodiment, the first fired body contains calcium oxide (CaO) obtained from organic calcium carbonate. Therefore, in this case, an oxide containing an alkaline earth metal excluding calcium can be added in the second firing stage so as to have the same configuration as that of the first fired body manufactured according to the first embodiment. The oxide containing an alkaline earth metal excluding calcium may be beryllium oxide (BeO), magnesium oxide (MgO), barium oxide (BaO), or a mixture thereof.
一つの例示において、カルシウムを除いたアルカリ土金属を含む酸化物はマグネシウム酸化物であり得る。すなわち、第2実施形態では、第1焼成体とマグネシウム酸化物をアルカリ土金属酸化物として使用することができる。よって、第1実施形態と第2実施形態のいずれにおいても、アルカリ土金属酸化物は同一の構成を有することができる。 In one example, the oxide containing an alkaline earth metal excluding calcium can be magnesium oxide. That is, in the second embodiment, the first fired body and the magnesium oxide can be used as the alkaline earth metal oxide. Therefore, the alkaline earth metal oxide can have the same configuration in both the first embodiment and the second embodiment.
前記アルカリ土金属酸化物は、カルシウム酸化物100モルに対して1モル〜60モル、1.6モル〜57モル、1.6モル〜50モル、1.6モル〜40モル、1.6モル〜30モル、5モル〜20モル又は5モル〜15モルのカルシウムを除いたアルカリ土金属を含む酸化物を含むことができる。その結果、適切な還元力を有する水素陰イオン含有物を製造することができる。 The alkaline earth metal oxide is 1 mol to 60 mol, 1.6 mol to 57 mol, 1.6 mol to 50 mol, 1.6 mol to 40 mol, 1.6 mol with respect to 100 mol of calcium oxide. An oxide containing an alkaline earth metal excluding ˜30 mol, 5 mol˜20 mol, or 5 mol˜15 mol calcium can be included. As a result, a hydrogen anion-containing material having an appropriate reducing power can be produced.
また、第1実施形態及び第2実施形態の第1焼成体は、上述した成分の他に、有機炭酸カルシウムから由来する各種ミネラルを含む。その結果、最終生成物である水素陰イオン含有物も、有機炭酸カルシウムから由来する各種ミネラルを含むことができる。 Moreover, the 1st baking body of 1st Embodiment and 2nd Embodiment contains the various minerals derived from organic calcium carbonate other than the component mentioned above. As a result, the hydrogen anion-containing product as the final product can also contain various minerals derived from organic calcium carbonate.
前記第2焼成段階は、アルカリ土金属酸化物を約300℃〜1000℃、約300℃〜900℃、約400℃〜900℃、約400℃〜800℃、約500℃〜800℃、約500℃〜700℃又は約600℃〜700℃で焼成することを含むことができる。また、前記アルカリ土金属酸化物の焼成は、約2時間以上、約3時間以上又は約4時間以上間進行することができる。焼成時間の上限は、特に制限されなく、例えば、10時間以下に調節することができる。前記焼成が前記範囲未満の温度で前記範囲未満の時間の間行われる場合は、アルカリ土金属酸化物が目的とする程度に還元されないおそれがあり、前記焼成が前記範囲を超える温度で前記範囲以上の時間の間行われる場合は、莫大なエネルギーの浪費をもたらし得る。 In the second firing step, the alkaline earth metal oxide is about 300 ° C to 1000 ° C, about 300 ° C to 900 ° C, about 400 ° C to 900 ° C, about 400 ° C to 800 ° C, about 500 ° C to 800 ° C, about 500 ° C. Firing at from about 700 ° C. to about 700 ° C. or about 600 ° C. to 700 ° C. can be included. Further, the firing of the alkaline earth metal oxide can proceed for about 2 hours or more, about 3 hours or more, or about 4 hours or more. The upper limit of the firing time is not particularly limited, and can be adjusted to 10 hours or less, for example. When the calcination is performed at a temperature less than the above range for a time less than the above range, the alkaline earth metal oxide may not be reduced to the desired extent, and the above calcination is performed at a temperature exceeding the above range within the above range. Can be enormously wasteful of energy if done for a period of time.
前記第2焼成段階は、水素雰囲気下で進行することができる。よって、アルカリ土金属酸化物の焼成が進行される間、水素ガスを供給することができる。前記水素ガスは、単独で注入することもでき、又は他の搬送ガスと共に注入することもできる。前記搬送ガスとしては、前記焼成温度範囲で反応性がないものであれば特に制限されなく、通常的に使用されるガスが全て使用可能である。前記搬送ガスとしては、窒素、ヘリウム又はアルゴンなどを例示することができる。 The second firing step may proceed under a hydrogen atmosphere. Therefore, hydrogen gas can be supplied while the firing of the alkaline earth metal oxide proceeds. The hydrogen gas can be injected alone or with other carrier gases. The carrier gas is not particularly limited as long as it is not reactive in the firing temperature range, and any gas that is normally used can be used. Examples of the carrier gas include nitrogen, helium, and argon.
前記水素陰イオン含有物の製造方法は、第2焼成段階以後にも第2焼成体を冷却させる段階をさらに含むことができる。第2焼成体を冷却させる方法としては、特に限定されなく、第1焼成体を冷却させた方法と同一の冷却が可能である。 The method for producing a hydrogen anion-containing material may further include a step of cooling the second fired body after the second firing step. The method for cooling the second fired body is not particularly limited, and the same cooling as the method for cooling the first fired body is possible.
前記水素陰イオン含有物の製造方法は、第2焼成段階以後に第2焼成体と有機酸を配合する段階を含む。 The method for producing the hydrogen anion-containing material includes a step of blending the second fired body and the organic acid after the second firing step.
前記第2焼成体は、カルシウム水素化物(CaH2)及びカルシウムを除いたアルカリ土金属の水素化物(MH2、Mは、Be、Mg又はBaである。)を含む。本明細書において、「第2焼成体」と「有機酸と配合された第2焼成体」とを区別するために、前者は第2焼成体と称し、後者は水素陰イオン含有物と称する。 The second fired body includes a calcium hydride (CaH2) and an alkaline earth metal hydride excluding calcium (MH2, M is Be, Mg, or Ba). In the present specification, in order to distinguish between the “second calcined product” and the “second calcined product blended with an organic acid”, the former is referred to as a second calcined product, and the latter is referred to as a hydrogen anion-containing product.
このような第2焼成体に有機酸を配合することは、第2焼成体を入れた容器に有機酸を添加し、これらを物理的に混合して行うことができる。 Mixing an organic acid with such a second fired body can be performed by adding the organic acid to a container containing the second fired body and physically mixing them.
前記有機酸としては、例えば、ギ酸(formic acid)、酢酸(acetic acid)、クエン酸(citric acid)、乳酸(lactic acid)、酒石酸(tartaric acid)、コハク酸(succinic acid)からなる群から選ばれた1種以上であるものを使用することができる。一つの例示において、有機酸としては、常温で固体であるものを使用し、粉末状の水素陰イオン含有物を製造することができる。よって、有機酸としては、クエン酸、乳酸、酒石酸、コハク酸又はこれらの混合物を使用することができる。 Examples of the organic acid include a group consisting of formic acid, acetic acid, citric acid, lactic acid, tartaric acid, and succinic acid. One or more selected from the above can be used. In one example, an organic acid that is solid at room temperature can be used to produce a powdered hydrogen anion-containing product. Therefore, citric acid, lactic acid, tartaric acid, succinic acid, or a mixture thereof can be used as the organic acid.
前記第2焼成体と有機酸を配合する段階において、前記第2焼成体は、第2焼成体に含まれているカルシウムイオン100モルに対して0.5モル〜10モル、0.88モル〜10モル、1モル〜9モル、2モル〜8モル、3モル〜8モル、3モル〜7モル又は3モル〜6モルの有機酸と配合することができる。このような範囲で、水素陰イオン含有物は、体内で適切な抗酸化作用を起こす適切な還元力及び適切な還元力持続時間を有する。前記還元力の持続時間は、水素陰イオン含有物を溶解させた水溶液が負の値の酸化還元電位(Oxidation―Reduction Potential、ORP)を示す間の時間を意味する。 In the step of blending the second fired body and the organic acid, the second fired body is 0.5 mole to 10 moles, 0.88 moles to 100 moles of calcium ions contained in the second fired body. It can be blended with 10 mol, 1 mol-9 mol, 2 mol-8 mol, 3 mol-8 mol, 3 mol-7 mol or 3 mol-6 mol organic acid. In such a range, the hydrogen anion-containing substance has an appropriate reducing power that causes an appropriate antioxidant action in the body and an appropriate duration of reducing power. The duration of the reducing power means a time during which an aqueous solution in which a hydrogen anion-containing material is dissolved exhibits a negative value of oxidation-reduction potential (ORP).
また、水素陰イオン含有物は、前記範囲の含量で有機酸を含み、体内に適したpHを有することができる。一つの例示において、第2焼成体400mgを水300mLに入れて測定されたpHが約10〜12程度である場合、このような第2焼成体に有機酸を前記範囲で配合し、pHを約6〜11程度に低下させることができる。よって、体内に無理を与えず、本発明の目的とする効果を発揮する水素陰イオン含有物を提供することができる。 Further, the hydrogen anion-containing material contains an organic acid with a content in the above range, and can have a pH suitable for the body. In one example, when 400 mg of the second fired body is measured in 300 mL of water and the measured pH is about 10 to 12, an organic acid is added to the second fired body in the above range, and the pH is about It can be reduced to about 6-11. Therefore, it is possible to provide a hydrogen anion-containing substance that exerts the intended effect of the present invention without exerting excessive force on the body.
本発明の他の一実施例は、前記方法で製造された水素陰イオン含有物を提供する。 Another embodiment of the present invention provides a hydrogen anion-containing material produced by the above method.
前記製造方法によって製造された水素陰イオン含有物は、水に溶解した直後、pHが6〜12、7〜12、8〜12、8〜11又は9〜11であり得る。また、前記水素陰イオン含有物は、水に溶解した直後、−0.1mV〜−900mV、−0.1mV〜−800mV、−0.1mV〜−700mV、−0.1mV〜−600mV、−0.1mV〜−500mV、−10mV〜−450mV、−100mV〜−400mV、−150mV〜−300mV、−180mV〜−250mV、−190mV〜−230mVの酸化還元電位を示し、適切な還元力を有することができる。そして、前記還元力の持続時間は、1時間〜150時間、5時間〜120時間、10時間〜100時間、30時間〜100時間、50時間〜100時間又は70時間〜100時間であり得る。前記各物性は、水300mLに水素陰イオン含有物400mgを添加して測定したものである。 The hydrogen anion-containing material produced by the production method may have a pH of 6 to 12, 7 to 12, 8 to 12, 8 to 11, or 9 to 11 immediately after being dissolved in water. Further, the hydrogen anion-containing material is immediately after being dissolved in water, -0.1 mV to -900 mV, -0.1 mV to -800 mV, -0.1 mV to -700 mV, -0.1 mV to -600 mV, -0 It has a redox potential of 1 mV to -500 mV, -10 mV to -450 mV, -100 mV to -400 mV, -150 mV to -300 mV, -180 mV to -250 mV, -190 mV to -230 mV, and has an appropriate reducing power. it can. The duration of the reducing power may be 1 hour to 150 hours, 5 hours to 120 hours, 10 hours to 100 hours, 30 hours to 100 hours, 50 hours to 100 hours, or 70 hours to 100 hours. Each physical property is measured by adding 400 mg of a hydrogen anion-containing material to 300 mL of water.
一つの例示において、前記製造方法によって製造された水素陰イオン含有物は、水に溶解した直後、pHが9〜11であり得る。また、前記水素陰イオン含有物は、水に溶解した直後、酸化還元電位が−190mV〜−230mVであり得る。そして、還元力の持続時間は、50時間〜100時間であり得る。このような物性を有する水素陰イオン含有物は、体内に無理なく摂取することができ、細胞の新陳代謝を促進し、体内で活性酸素を円滑に除去することができる。前記物性を有する水素陰イオン含有物は、適切な含量のアルカリ土金属化合物又は酸化物を使用して生成することができる。 In one example, the hydrogen anion-containing material produced by the production method may have a pH of 9 to 11 immediately after being dissolved in water. The hydrogen anion-containing material may have a redox potential of -190 mV to -230 mV immediately after being dissolved in water. The duration of the reducing power can be 50 hours to 100 hours. The hydrogen anion-containing material having such physical properties can be taken in the body without difficulty, promotes the metabolism of cells, and can smoothly remove active oxygen in the body. The hydrogen anion-containing material having the physical properties can be generated using an appropriate amount of an alkaline earth metal compound or oxide.
前記製造方法によって製造される水素陰イオン含有物は、周囲環境の変化に敏感でないので、抗酸化作用を必要とする多様な分野に活用可能である。前記水素陰イオン含有物は、例えば、果物、野菜、魚類及び肉類の酸化作用を防止するのに使用可能である。また、水素陰イオン含有物は、酸化された皮膚と外傷を負った皮膚を還元作用で回復させることができる。その他に、水素陰イオン含有物は、美容材料、健康食品及び二日酔い解消飲料などの分野で多様に活用することができる。 Since the hydrogen anion-containing product produced by the production method is not sensitive to changes in the surrounding environment, it can be used in various fields that require an antioxidant action. The hydrogen anion-containing material can be used, for example, to prevent the oxidizing action of fruits, vegetables, fish and meat. In addition, the hydrogen anion-containing substance can recover oxidized skin and injured skin by a reducing action. In addition, the hydrogen anion-containing material can be used in various fields such as beauty materials, health foods, and hangover drinks.
以下、本発明の属する技術分野で通常の知識を有する者が容易に実施できるように、本発明の実施例に対して詳細に説明する。しかし、本発明は、様々な異なる形態に具現することができ、ここで説明する実施例に限定されない。 Hereinafter, embodiments of the present invention will be described in detail so that those skilled in the art to which the present invention pertains can easily carry out. However, the present invention can be embodied in various different forms and is not limited to the embodiments described herein.
<製造例:水素陰イオン含有物の製造> <Production example: Production of hydrogen anion-containing product>
洗浄した牡蠣の殻100gを大気雰囲気下で700℃の温度で4時間焼成し、第1焼成体を得た。前記第1焼成体には、カルシウム酸化物56.08gが含まれていた。 100 g of the washed oyster shell was fired at 700 ° C. for 4 hours in an air atmosphere to obtain a first fired body. The first fired body contained 56.08 g of calcium oxide.
続いて、前記第1焼成体が入った反応容器に4.45gのマグネシウム酸化物(CaO:MgO=92.6重量%:7.4重量%=100mol:11mol)を添加した。その後、第1焼成体及びマグネシウム酸化物を含むアルカリ土金属酸化物を水素雰囲気下で650℃の温度で4時間以上焼成し、第2焼成体を得た。 Subsequently, 4.45 g of magnesium oxide (CaO: MgO = 92.6 wt%: 7.4 wt% = 100 mol: 11 mol) was added to the reaction vessel containing the first fired body. Thereafter, the first fired body and the alkaline earth metal oxide containing magnesium oxide were fired at a temperature of 650 ° C. for 4 hours or more in a hydrogen atmosphere to obtain a second fired body.
続いて、前記第2焼成体に全体の水素陰イオン含有物に対して17.5重量%の比率でクエン酸を混合し、粉末状の水素陰イオン含有物を製造した。 Subsequently, citric acid was mixed in the second fired body at a ratio of 17.5% by weight with respect to the entire hydrogen anion-containing material to produce a powdered hydrogen anion-containing material.
下記の表1のように、前記実施例1におけるマグネシウム酸化物の含量を0.66gに変更したことを除いては、実施例1と同一に水素陰イオン含有物を製造した。 As shown in Table 1 below, a hydrogen anion-containing material was produced in the same manner as in Example 1, except that the magnesium oxide content in Example 1 was changed to 0.66 g.
下記の表1のように、前記実施例1におけるマグネシウム酸化物の含量を9.53gに変更したことを除いては、実施例1と同一に水素陰イオン含有物を製造した。 As shown in Table 1 below, a hydrogen anion-containing material was produced in the same manner as in Example 1 except that the magnesium oxide content in Example 1 was changed to 9.53 g.
下記の表1のように、前記実施例1におけるマグネシウム酸化物の含量を22.95gに変更したことを除いては、実施例1と同一に水素陰イオン含有物を製造した。 As shown in Table 1 below, a hydrogen anion-containing material was produced in the same manner as in Example 1 except that the magnesium oxide content in Example 1 was changed to 22.95 g.
下記の表1のように、前記実施例1における第2焼成体に配合されるクエン酸の含量を全体の水素陰イオン含有物に対して12.5重量%の比率に変更したことを除いては、実施例1と同一に水素陰イオン含有物を製造した。 As shown in Table 1 below, except that the content of citric acid compounded in the second fired body in Example 1 was changed to a ratio of 12.5% by weight with respect to the total content of hydrogen anions. Produced a hydrogen anion-containing material in the same manner as in Example 1.
下記の表1のように、前記実施例1における第2焼成体に配合されるクエン酸の含量を全体の水素陰イオン含有物に対して25.0重量%の比率に変更したことを除いては、実施例1と同一に水素陰イオン含有物を製造した。 As shown in Table 1 below, except that the content of citric acid blended in the second fired body in Example 1 was changed to a ratio of 25.0% by weight with respect to the entire hydrogen anion-containing material. Produced a hydrogen anion-containing material in the same manner as in Example 1.
<実験例:水素陰イオン含有物の物性測定> <Experimental example: measurement of physical properties of hydrogen anion-containing material>
前記実施例で製造した水素陰イオン含有物の酸化還元電位(ORP)変化、pH変化及び還元力持続時間を測定し、前記水素陰イオン含有物が溶解された水溶液の濁度を観察した。そして、実施例の水素陰イオン含有物の物性を水道水(比較例1)及び第1焼成体(比較例2:実施例1の第1焼成体使用)の物性と比較し、その結果を表2に示した。 The oxidation-reduction potential (ORP) change, pH change, and reducing power duration of the hydrogen anion-containing material prepared in the above example were measured, and the turbidity of the aqueous solution in which the hydrogen anion-containing material was dissolved was observed. And the physical property of the hydrogen anion containing material of an Example is compared with the physical property of a tap water (Comparative example 1) and a 1st baking body (Comparative example 2: The 1st baking body of Example 1), The result is shown. It was shown in 2.
(1)ORP(単位:mV)及びpHの変化:8個のビーカーに水道水300mLをそれぞれ投入し、一つのビーカーには何も添加しておらず(比較例1)、他の一つのビーカーには実施例1で製造した第1焼成体400mgを溶解させ(比較例2)、残りの6個のビーカーにはそれぞれ実施例1〜6の水素陰イオン含有物400mgを溶解させた(実施例1〜6)。何も添加されていない水道水と前記製造した各水溶液に対して、第1焼成体又は水素陰イオン含有物を溶解した時刻(初期値)、この時刻から4時間、20時間、40時間、60時間、80時間、100時間が経過した時点におけるORP及びpHを測定した。 (1) ORP (unit: mV) and pH change: 300 mL of tap water was put into 8 beakers, nothing was added to one beaker (Comparative Example 1), and the other one beaker First, 400 mg of the first fired body produced in Example 1 was dissolved (Comparative Example 2), and 400 mg of the hydrogen anion-containing material of Examples 1 to 6 was dissolved in the remaining six beakers (Examples). 1-6). The time (initial value) at which the first calcined product or the hydrogen anion-containing material was dissolved in tap water to which nothing was added and each of the produced aqueous solutions, 4 hours, 20 hours, 40 hours, 60 hours from this time The ORP and pH at the time when 80 hours and 100 hours passed were measured.
(2)還元力の持続時間:前記製造した水溶液が負の値の酸化還元電位を維持する間の時間を還元力の持続時間と規定し、第1焼成体又は水素陰イオン含有物を溶解した時刻から酸化還元電位が0の値になるまでの時間を測定した。 (2) Duration of reducing power: The time during which the produced aqueous solution maintains a negative redox potential is defined as the duration of reducing power, and the first calcined product or the hydrogen anion-containing material is dissolved. The time from the time until the oxidation-reduction potential became a value of 0 was measured.
(3)水溶液の濁度:第1焼成体又は水素陰イオン含有物を溶解させた水溶液を肉眼で観察し、濁ったように観察されると「混濁」と表記し、透明に観察されると「透明」と表記した。代表的に、実施例1の水溶液の写真を図1に開示した。 (3) Turbidity of aqueous solution: When the first fired body or an aqueous solution in which a hydrogen anion-containing material is dissolved is observed with the naked eye, when it is observed to be cloudy, it is described as “turbid” and is observed transparently. It was written as “transparent”. Typically, a photograph of the aqueous solution of Example 1 is disclosed in FIG.
以上、本発明の好ましい実施例に対して詳細に説明したが、本発明の権利範囲は、これに限定されなく、次の特許請求の範囲で定義している本発明の基本概念を用いた当業者の様々な変形及び改良形態も本発明の権利範囲に属するものである。 The preferred embodiments of the present invention have been described in detail above. However, the scope of the present invention is not limited thereto, and the basic concept of the present invention defined in the following claims is used. Various modifications and improvements of the traders are also within the scope of the present invention.
本発明によると、細胞の新陳代謝を促進し、体内の活性酸素を除去することができる。そして、周辺環境、例えば、温度の変化に敏感ではなく、空気に露出しても変性しなくて保存が容易であるので、各種飲料又は各種食資材に添加され、前記機能を発揮することができる。また、果物、野菜、魚類及び肉類などの食資材に添加され、これらの酸化を防止し、高い新鮮度を長い間維持させることができる。また、酸化された皮膚と外傷を負った皮膚を還元作用で回復させることができる。 According to the present invention, cell metabolism can be promoted and active oxygen in the body can be removed. And since it is not sensitive to changes in the surrounding environment, for example, temperature, is not denatured even when exposed to air and can be stored easily, it can be added to various beverages or various food materials to exert the above functions. . Moreover, it is added to foodstuffs, such as fruit, vegetables, fish, and meat, These oxidation can be prevented and a high freshness can be maintained for a long time. In addition, the oxidized skin and the injured skin can be recovered by a reducing action.
Claims (9)
前記第1焼成体を含むアルカリ土金属酸化物を水素雰囲気下で焼成することによって第2焼成体を製造する第2焼成段階;及び
前記第2焼成体と有機酸を配合する段階;を含む水素陰イオン含有物の製造方法。 A first firing stage for producing a first fired body by firing an alkaline earth metal compound containing one or more organic calcium carbonates selected from the group consisting of eggshell calcium, pearl calcium, shell calcium, and seaweed calcium;
Hydrogen comprising: a second firing step of producing a second fired body by firing the alkaline earth metal oxide containing the first fired body in a hydrogen atmosphere; and a step of blending the second fired body with an organic acid. A method for producing an anion-containing material.
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KR101405431B1 (en) | 2014-06-11 |
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