JP2016511241A - ヘテロポリオキソメタレート - Google Patents
ヘテロポリオキソメタレート Download PDFInfo
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- JP2016511241A JP2016511241A JP2015556496A JP2015556496A JP2016511241A JP 2016511241 A JP2016511241 A JP 2016511241A JP 2015556496 A JP2015556496 A JP 2015556496A JP 2015556496 A JP2015556496 A JP 2015556496A JP 2016511241 A JP2016511241 A JP 2016511241A
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- Prior art keywords
- cation
- heteropolyoxometalate
- cations
- formula
- iii
- Prior art date
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- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 16
- 238000000576 coating method Methods 0.000 claims abstract description 16
- 238000002360 preparation method Methods 0.000 claims abstract description 14
- 239000003973 paint Substances 0.000 claims abstract description 10
- -1 quaternary ammonium cations Chemical class 0.000 claims description 79
- 150000001768 cations Chemical class 0.000 claims description 54
- 239000000758 substrate Substances 0.000 claims description 22
- 229910052750 molybdenum Inorganic materials 0.000 claims description 17
- 229910052721 tungsten Inorganic materials 0.000 claims description 16
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical group [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 claims description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 14
- 229930195733 hydrocarbon Natural products 0.000 claims description 11
- 150000002430 hydrocarbons Chemical class 0.000 claims description 11
- 229910052698 phosphorus Inorganic materials 0.000 claims description 11
- 238000004659 sterilization and disinfection Methods 0.000 claims description 11
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 10
- 239000011574 phosphorus Substances 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 10
- 239000002344 surface layer Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 229910052717 sulfur Inorganic materials 0.000 claims description 7
- 125000004434 sulfur atom Chemical group 0.000 claims description 7
- 230000003115 biocidal effect Effects 0.000 claims description 6
- 230000015556 catabolic process Effects 0.000 claims description 6
- 238000006731 degradation reaction Methods 0.000 claims description 6
- 230000001877 deodorizing effect Effects 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- 239000011368 organic material Substances 0.000 claims description 4
- BJQWBACJIAKDTJ-UHFFFAOYSA-N tetrabutylphosphanium Chemical compound CCCC[P+](CCCC)(CCCC)CCCC BJQWBACJIAKDTJ-UHFFFAOYSA-N 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 3
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 claims description 3
- YCBRTSYWJMECAH-UHFFFAOYSA-N tributyl(tetradecyl)phosphanium Chemical compound CCCCCCCCCCCCCC[P+](CCCC)(CCCC)CCCC YCBRTSYWJMECAH-UHFFFAOYSA-N 0.000 claims description 3
- AHCKRTXGDNIJSK-UHFFFAOYSA-N methyl(trioctyl)phosphanium Chemical compound CCCCCCCC[P+](C)(CCCCCCCC)CCCCCCCC AHCKRTXGDNIJSK-UHFFFAOYSA-N 0.000 claims description 2
- SWMBQMGPRYJSCI-UHFFFAOYSA-N octylphosphane Chemical compound CCCCCCCCP SWMBQMGPRYJSCI-UHFFFAOYSA-N 0.000 claims 1
- 239000000543 intermediate Substances 0.000 abstract description 6
- 230000000845 anti-microbial effect Effects 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 23
- 239000000243 solution Substances 0.000 description 21
- 150000001875 compounds Chemical class 0.000 description 19
- 150000001450 anions Chemical class 0.000 description 14
- 238000000034 method Methods 0.000 description 14
- 239000007788 liquid Substances 0.000 description 11
- 239000000463 material Substances 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 10
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 8
- 238000011109 contamination Methods 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 7
- 239000002253 acid Substances 0.000 description 7
- 230000000813 microbial effect Effects 0.000 description 7
- 239000011733 molybdenum Substances 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 125000005842 heteroatom Chemical group 0.000 description 6
- 239000010937 tungsten Substances 0.000 description 6
- 239000002351 wastewater Substances 0.000 description 6
- 229910004298 SiO 2 Inorganic materials 0.000 description 5
- 239000000499 gel Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 238000000113 differential scanning calorimetry Methods 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 229910052814 silicon oxide Inorganic materials 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000002411 thermogravimetry Methods 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000012456 homogeneous solution Substances 0.000 description 3
- 238000010030 laminating Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
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- 238000000746 purification Methods 0.000 description 3
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- 239000011541 reaction mixture Substances 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- SYZCZDCAEVUSPM-UHFFFAOYSA-M tetrahexylazanium;bromide Chemical compound [Br-].CCCCCC[N+](CCCCCC)(CCCCCC)CCCCCC SYZCZDCAEVUSPM-UHFFFAOYSA-M 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000000259 anti-tumor effect Effects 0.000 description 2
- 230000000840 anti-viral effect Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003125 aqueous solvent Substances 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 229910001431 copper ion Inorganic materials 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000003651 drinking water Substances 0.000 description 2
- 235000020188 drinking water Nutrition 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 239000013505 freshwater Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052732 germanium Inorganic materials 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- ZUZLIXGTXQBUDC-UHFFFAOYSA-N methyltrioctylammonium Chemical compound CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC ZUZLIXGTXQBUDC-UHFFFAOYSA-N 0.000 description 2
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920000447 polyanionic polymer Polymers 0.000 description 2
- 239000013460 polyoxometalate Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000002352 surface water Substances 0.000 description 2
- WFIYFFUAOQKJJS-UHFFFAOYSA-N tetraoctylphosphanium Chemical compound CCCCCCCC[P+](CCCCCCCC)(CCCCCCCC)CCCCCCCC WFIYFFUAOQKJJS-UHFFFAOYSA-N 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical group [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- COSSPXYCRNRXRX-UHFFFAOYSA-N 1-benzyl-3-methylimidazol-3-ium Chemical compound C1=[N+](C)C=CN1CC1=CC=CC=C1 COSSPXYCRNRXRX-UHFFFAOYSA-N 0.000 description 1
- XUAXVBUVQVRIIQ-UHFFFAOYSA-N 1-butyl-2,3-dimethylimidazol-3-ium Chemical compound CCCCN1C=C[N+](C)=C1C XUAXVBUVQVRIIQ-UHFFFAOYSA-N 0.000 description 1
- IQQRAVYLUAZUGX-UHFFFAOYSA-N 1-butyl-3-methylimidazolium Chemical compound CCCCN1C=C[N+](C)=C1 IQQRAVYLUAZUGX-UHFFFAOYSA-N 0.000 description 1
- JRRNETAQGVDLRW-UHFFFAOYSA-N 1-hexadecyl-3-methyl-2h-imidazole Chemical compound CCCCCCCCCCCCCCCCN1CN(C)C=C1 JRRNETAQGVDLRW-UHFFFAOYSA-N 0.000 description 1
- SIKJAQJRHWYJAI-UHFFFAOYSA-O 1H-indol-1-ium Chemical compound C1=CC=C2[NH2+]C=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-O 0.000 description 1
- ATVJJNGVPSKBGO-UHFFFAOYSA-N 3,4-dihydro-2h-thiopyran Chemical compound C1CSC=CC1 ATVJJNGVPSKBGO-UHFFFAOYSA-N 0.000 description 1
- WXMVWUBWIHZLMQ-UHFFFAOYSA-N 3-methyl-1-octylimidazolium Chemical compound CCCCCCCCN1C=C[N+](C)=C1 WXMVWUBWIHZLMQ-UHFFFAOYSA-N 0.000 description 1
- VUFOTXYLUWEYFC-UHFFFAOYSA-N 4-phenoxybenzenethiol Chemical class C1=CC(S)=CC=C1OC1=CC=CC=C1 VUFOTXYLUWEYFC-UHFFFAOYSA-N 0.000 description 1
- KDCGOANMDULRCW-UHFFFAOYSA-N 7H-purine Chemical compound N1=CNC2=NC=NC2=C1 KDCGOANMDULRCW-UHFFFAOYSA-N 0.000 description 1
- 101710134784 Agnoprotein Proteins 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Chemical group CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 description 1
- NQRYJNQNLNOLGT-UHFFFAOYSA-O Piperidinium(1+) Chemical compound C1CC[NH2+]CC1 NQRYJNQNLNOLGT-UHFFFAOYSA-O 0.000 description 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-O Pyrazolium Chemical compound C1=CN[NH+]=C1 WTKZEGDFNFYCGP-UHFFFAOYSA-O 0.000 description 1
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 1
- RWRDLPDLKQPQOW-UHFFFAOYSA-O Pyrrolidinium ion Chemical compound C1CC[NH2+]C1 RWRDLPDLKQPQOW-UHFFFAOYSA-O 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- YTPLMLYBLZKORZ-UHFFFAOYSA-O Thiophenium Chemical compound [SH+]1C=CC=C1 YTPLMLYBLZKORZ-UHFFFAOYSA-O 0.000 description 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 238000004887 air purification Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- ZSIQJIWKELUFRJ-UHFFFAOYSA-N azepane Chemical compound C1CCCNCC1 ZSIQJIWKELUFRJ-UHFFFAOYSA-N 0.000 description 1
- HONIICLYMWZJFZ-UHFFFAOYSA-O azetidin-1-ium Chemical compound C1C[NH2+]C1 HONIICLYMWZJFZ-UHFFFAOYSA-O 0.000 description 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-O aziridinium Chemical compound C1C[NH2+]1 NOWKCMXCCJGMRR-UHFFFAOYSA-O 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 230000032770 biofilm formation Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 238000009388 chemical precipitation Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
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- YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Chemical compound C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical class NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
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- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ZURJOAUBHGQPEJ-UHFFFAOYSA-N heptyl(trihexyl)phosphanium Chemical compound CCCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC ZURJOAUBHGQPEJ-UHFFFAOYSA-N 0.000 description 1
- 125000001072 heteroaryl group Chemical group 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- NGSJXIKNXLTUDE-UHFFFAOYSA-N hexadecyl(trihexyl)azanium Chemical compound CCCCCCCCCCCCCCCC[N+](CCCCCC)(CCCCCC)CCCCCC NGSJXIKNXLTUDE-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- ZCQWOFVYLHDMMC-UHFFFAOYSA-O hydron;1,3-oxazole Chemical compound C1=COC=[NH+]1 ZCQWOFVYLHDMMC-UHFFFAOYSA-O 0.000 description 1
- CZPWVGJYEJSRLH-UHFFFAOYSA-O hydron;pyrimidine Chemical compound C1=CN=C[NH+]=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-O 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- NDNHNDHVEAHYRC-UHFFFAOYSA-N methyl(tripentyl)azanium Chemical compound CCCCC[N+](C)(CCCCC)CCCCC NDNHNDHVEAHYRC-UHFFFAOYSA-N 0.000 description 1
- CLFBUVMLHRUTNJ-UHFFFAOYSA-N methyl-tri(nonyl)azanium Chemical compound CCCCCCCCC[N+](C)(CCCCCCCCC)CCCCCCCCC CLFBUVMLHRUTNJ-UHFFFAOYSA-N 0.000 description 1
- XJPLVFCEZXTPJP-UHFFFAOYSA-N methyl-tri(tetradecyl)azanium Chemical compound CCCCCCCCCCCCCC[N+](C)(CCCCCCCCCCCCCC)CCCCCCCCCCCCCC XJPLVFCEZXTPJP-UHFFFAOYSA-N 0.000 description 1
- CUVNYGRZKFAAOQ-UHFFFAOYSA-N methyl-tri(tridecyl)azanium Chemical compound CCCCCCCCCCCCC[N+](C)(CCCCCCCCCCCCC)CCCCCCCCCCCCC CUVNYGRZKFAAOQ-UHFFFAOYSA-N 0.000 description 1
- VSXHVMSXOIVJCR-UHFFFAOYSA-N methyl-tri(undecyl)azanium Chemical compound CCCCCCCCCCC[N+](C)(CCCCCCCCCCC)CCCCCCCCCCC VSXHVMSXOIVJCR-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
Description
式中、
Zは、MoまたはWから選択され、
指数q=0、1、2、または3であり、
Aは、自己洗浄、ストリッピング、殺菌、自己消毒、殺生物、抗菌、及び/または脱臭特性を、基材もしくは基材の表面の少なくとも一部にまたはコーティングに提供するために、あるいは有機物質の分解及び/または減成のために、1つ以上のカチオンから選択され、かつ四級アンモニウムカチオン、四級ホスホニウムカチオン、及び三級スルホニウムカチオンから成る群から選択される少なくとも1つのカチオンを含む。
式中、Zは、MoまたはWから選択され、Aは、1つ以上のカチオンから選択され、少なくとも1つの四級アンモニウムカチオン、四級ホスホニウムカチオン、または三級スルホニウムカチオンを含み、四級アンモニウム及びホスホニウムカチオンが好ましい。別の好ましい例は、A5PMo10V2O40である。
式中、残基R1、R2、R3、及びR4は、独立して選択され得る。好ましくは、残基R1、R2、R3、及びR4は、独立して、ポリマーを含む炭化水素から選択される。好ましくは、炭化水素は、C1〜C20炭化水素、より好ましくはC1〜C16炭化水素、特にC2〜C8炭化水素、例えばC4〜C6炭化水素またはC4〜C16炭化水素である。炭化水素は、好ましくは、分岐または直鎖、飽和または不飽和の、アルキル基、アリール基、またはヘテロアリール基である。例は、メチル、エチル、プロピル、ブチル、ペンチル、へキシル、へプチル、オクチル、ノニル、デシル、ウンデシル、ドデシル、トリデシル、テトラデシル、ペンタデシル、ヘキサデシル、ヘプタデシル、及びオクタデシル残基である。任意で、残基R1、R2、R3、及び存在する場合R4のうちの2つは、任意で中央窒素、リン、または硫黄原子と一緒に、環の一部であり、例えば一緒に環を形成する。環は、芳香族等の飽和または不飽和であり得る。
式中、
Zは、MoまたはWから選択され、
指数q=0、1、2、または3であり、
A′は1つ以上のカチオンから選択され、かつ以下から選択される少なくとも1つのカチオンを含み、
式中、残基R1、R2、R3、及びR4は、独立して、C1〜C20炭化水素から選択され、残基R1、R2、R3、及びR4のうちのいずれもがポリマーでない場合、R1、R2、R3、及び存在する場合R4のうちの少なくとも2つが、窒素、リン、または硫黄原子と一緒に環を形成する。
a)q=1である場合、[PZ11O39]7−アニオンを含む塩、
q=2である場合、[PZ10O36]7−アニオンを含む塩、
q=3である場合、[PZ9O34]9−アニオンを含む塩、または、
[PO4]3−アニオンを含む塩、任意でVO3 −アニオンを含む塩、及びZO4 2−アニオンを含む塩であって、
式中、
ZがMoまたはWから選択される、塩を、
水性溶剤、好ましくは水中で溶解して、溶液を得ることと、
b)工程a)の後で得られる溶液のpHを低減するために、酸を加えることと、
c)四級アンモニウムカチオン、四級ホスホニウムカチオン、及び三級スルホニウムカチオンから成る群から選択される少なくとも1つのカチオンを含む化合物を加えることと、を含む。
a)[PZ12O40]3−を含む塩または酸であって、式中、ZがMoまたはWである、塩または酸を、過酸化水素の水溶液内で溶解させて、溶液を得ることと、
b)工程a)の溶液のpHを低減するために酸を加えることと、
c)四級アンモニウムカチオン、四級ホスホニウムカチオン、及び三級スルホニウムカチオンから成る群から選択される少なくとも1つのカチオンを含む化合物を加えることと、を含む。
式中、残基R1、R2、R3、及びR4は、上記に定義される通りであり、Xは、硫酸またはハロゲンイオン、好ましくは塩化物または臭化物であり、Xが硫酸である場合、pは2であり、Xがハロゲンイオンである場合、pは1である。好ましくは、上記のプロセスにおいて使用される四級アンモニウムカチオン含有化合物は、臭化テトラブチルアンモニウム及び/または硫酸テトラブチルアンモニウム及び/または臭化テトラへキシルアンモニウムを含み、四級ホスホニウムカチオン含有化合物は、臭化テトラブチルホスホニウム及び/または硫化テトラブチルホスホニウム及び/または臭化テトラへキシルホスホニウムを含み、三級スルホニウムカチオン含有化合物は、臭化トリブチルスルホニウム及び/または硫化トリブチルスルホニウム及び/または臭化トリへキシルスルホニウムを含む。
式中、
Zは、MoまたはWから選択され、
qは、0、1、2、または3であり、
mは、20を超えて40未満の数であり、
nは、31を超えて62未満の数であり、
oは、12を超えて24未満の数であり、
少なくとも1つのカチオンAは、上記に定義される通りである。
24.4gのNaV03+100mLの沸騰しているH2Oを、7.1gのNa2HPO4+100mLのH2Oに添加し、室温まで冷却し、その後、5mLの濃縮H2SO4を添加し、200mLのH2O中の121gのNa2MoO4×2H2Oを添加し、激しく撹拌し、その後、85mLの濃縮H2SO4を、得られた均一溶液の半分に緩徐に添加し、19.5gのTBA−Brを添加して橙色のTBA5[PMo10V2O40]を得て、これを水で完全に洗浄し、得られた粉末を最小量のアセトン中に溶解し、10gのSiO2をその溶液に添加した。結果として生じた混合物を激しく撹拌し、ペトリ皿上に積層することによって移し、24時間空気乾燥させた。
物質の重量:27g
分子量:158.8g/モル
モル数:170ミリモル
70mLの30%H2O2中の10gのH3PW12O40に、10mLのH3PO4を添加した。この溶液を40℃で4時間撹拌し、得られた均質溶液に12gのTBA−SO4を添加し、白色のTBA3[PW4O24]を得て、これを水で完全に洗浄し、得られた粉末を最小量のアセトン中に溶解し、10gのSiO2を溶液に添加した。結果として生じた混合物を激しく撹拌し、ペトリ皿上に積層することによって移し、24時間空気乾燥させた。
物質の重量:27g
分子量:158.4g/モル
モル数:170ミリモル
70mLの30%H2O2中の10gのH3PW12O40に、10mLのH3PO4を添加した。この溶液を40℃で4時間撹拌し、得られた均質溶液に12gのTHA−CIを添加して、白色のTHA3[PW4O24]を得て、これを水で完全に洗浄し、得られた粉末を最小量のアセトン中に溶解し、10gのSiO2を溶液に添加した。結果として生じた混合物を激しく撹拌し、ペトリ皿上に積層することによって移し、24時間空気乾燥させた。
物質の重量:27g
分子量:158.7g/モル
モル数:170ミリモル
リンタングステン酸(10g、3.47ミリモル)を、70mlの30%H2O2中に溶解し。10mlの5モル濃度のH3PO4を添加し、この溶液を40℃で4時間撹拌した。その後、反応混合物を室温まで冷却した。(反応混合物A)
NaVO3(0.7g、6.0ミリモル)と5.0gのNa10[α−SiW9O34]*xH2O(2.0ミリモル)を乾燥粉末として混合し、50mlの室温のH2Oに添加した。この溶液を30分間激しく撹拌し、その後、6モル濃度のHClを滴加してpHを1.5にし、透明なワインレッド色の溶液を得た。結果として生じた溶液を濾過し、15.0gの臭化テトラへキシルアンモニウム(THABr)を添加した。橙色のゲルを上部水層を除去して分離し、H2Oで完全に洗浄した。
物質の重量:29.8g
分子量:175.3g/モル
モル数:174ミリモル
実施例1〜3及び比較例1のヘテロポリオキソメタレートを、それらの殺菌情動性について試験した。家庭用洗濯機から得られた洗濯廃水を、それぞれのヘテロポリオキソメタレートで覆われたペトリ皿内で、保存前、かつ100分間及び5日間の保存後のその合計好気性細菌数を試験した。結果を以下の表に要約する。
実施例3及び4のヘテロポリオキソメタレートの熱安定性を、TGA(熱重量分析)及びDSC(示差走査熱量測定)によって決定した。
Claims (15)
- 式(I)の前記ヘテロポリオキソメタレートにおいて、ZがMoであり、q=2である、請求項1に記載の使用。
- 式(III)の前記ヘテロポリオキソメタレートにおいて、ZがWである、請求項1に記載の使用。
- 前記ヘテロポリオキソメタレートにおいて、Aが四級アンモニウムカチオン及び四級ホスホニウムカチオンから選択され、好ましくはAがこれらのカチオンのうちの少なくとも2つの異なるカチオンを含む、請求項1〜3のいずれか一項に記載の使用。
- 前記ヘテロポリオキソメタレートにおいて、Aが少なくとも1つの四級アンモニウムカチオンを含む、請求項1〜3のいずれか一項に記載の使用。
- 前記ヘテロポリオキソメタレートにおいて、Aが少なくとも2つの異なる四級アンモニウムカチオンを含む、請求項5に記載の使用。
- 前記ヘテロポリオキソメタレートにおいて、Aが、テトラブチルアンモニウムカチオン、テトラへキシルアンモニウムカチオン、テトラオクチルアンモニウムカチオン、メチルトリオクチルアンモニウムカチオン、トリブチルテトラデシルアンモニウムカチオン、テトラブチルホスホニウムカチオン、テトラへキシルホスホニウムカチオン、テトラオクチルホスホニウムカチオン、メチルトリオクチルホスホニウムカチオン、及び/またはトリブチルテトラデシルホスホニウムカチオンを含む、請求項1〜7のいずれか一項に記載の使用。
- 前記ヘテロポリオキソメタレートが、[(CH3(CH2)5)4N]3[PW4O24]、[(CH3(CH2)7)4N]3[PW4O24]、[(CH3(CH2)7)3N(CH3)]3[PW4O24]、及び[(CH3(CH2)3)3P((CH2)13CH3)]3[PW4O24]から選択される、請求項1に記載の使用。
- 請求項1で定義される式(I)、(II)、または(III)のヘテロポリオキソメタレートの調製における、請求項10に記載の式(I′)、(ΙI′)、または(III′)のヘテロポリオキソメタレートの使用。
- 自己洗浄、ストリッピング、殺菌、自己消毒、殺生物、抗菌、及び/または脱臭特性を、基材もしくは基材の表面の少なくとも一部にまたはコーティングに提供するための、あるいは有機物質の分解及び/または減成のための、請求項10に記載のヘテロポリオキソメタレートの使用。
- 請求項1〜10のいずれか一項で定義されるヘテロポリオキソメタレートまたはそれらの混合物を含む、基材、表面層、塗料、またはコーティング。
- [(CH3(CH2)5)4N]3[PW4O24]、[(CH3(CH2)7)4N]3[PW4O24]、及び[(CH3(CH2)3)3P((CH2)13CH3)]3[PW4O24]から選択されるヘテロポリオキソメタレート。
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CN102295603A (zh) * | 2011-06-08 | 2011-12-28 | 东南大学 | 基于过氧杂多酸的离子液体及其制备方法 |
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2014
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- 2014-02-06 PL PL14705487T patent/PL2953956T3/pl unknown
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- 2014-02-06 BR BR112015017818A patent/BR112015017818A2/pt not_active IP Right Cessation
- 2014-02-06 US US14/766,279 patent/US10531665B2/en active Active
- 2014-02-06 KR KR1020157020889A patent/KR20150115759A/ko not_active Application Discontinuation
- 2014-02-06 CN CN201480007713.9A patent/CN104981475B/zh active Active
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- 2014-02-06 RU RU2015137760A patent/RU2667894C2/ru active
- 2014-02-06 CA CA2900143A patent/CA2900143A1/en not_active Abandoned
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EP2953956B1 (en) | 2016-12-28 |
WO2014122225A1 (en) | 2014-08-14 |
ES2615347T3 (es) | 2017-06-06 |
RU2015137760A (ru) | 2017-03-13 |
US20150373987A1 (en) | 2015-12-31 |
BR112015017818A2 (pt) | 2017-07-11 |
CA2900143A1 (en) | 2014-08-14 |
RU2667894C2 (ru) | 2018-09-25 |
CN104981475B (zh) | 2018-10-26 |
EP2953956A1 (en) | 2015-12-16 |
PL2953956T3 (pl) | 2017-05-31 |
CN104981475A (zh) | 2015-10-14 |
US20170150725A9 (en) | 2017-06-01 |
KR20150115759A (ko) | 2015-10-14 |
US10531665B2 (en) | 2020-01-14 |
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