JP2015514142A - カルボキシレート染料 - Google Patents
カルボキシレート染料 Download PDFInfo
- Publication number
- JP2015514142A JP2015514142A JP2015501853A JP2015501853A JP2015514142A JP 2015514142 A JP2015514142 A JP 2015514142A JP 2015501853 A JP2015501853 A JP 2015501853A JP 2015501853 A JP2015501853 A JP 2015501853A JP 2015514142 A JP2015514142 A JP 2015514142A
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- JP
- Japan
- Prior art keywords
- dye
- composition
- group
- acid
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000007942 carboxylates Chemical class 0.000 title claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 293
- 239000000975 dye Substances 0.000 claims abstract description 132
- 125000000217 alkyl group Chemical group 0.000 claims description 51
- 229910052739 hydrogen Inorganic materials 0.000 claims description 30
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 20
- 125000003118 aryl group Chemical group 0.000 claims description 18
- 229910052799 carbon Inorganic materials 0.000 claims description 14
- 229920001577 copolymer Polymers 0.000 claims description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- 230000008033 biological extinction Effects 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 9
- 125000005647 linker group Chemical group 0.000 claims description 9
- 150000001408 amides Chemical class 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 8
- 239000000987 azo dye Substances 0.000 claims description 7
- 150000001768 cations Chemical class 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- VILAVOFMIJHSJA-UHFFFAOYSA-N dicarbon monoxide Chemical compound [C]=C=O VILAVOFMIJHSJA-UHFFFAOYSA-N 0.000 claims description 6
- 125000000623 heterocyclic group Chemical group 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 125000003342 alkenyl group Chemical group 0.000 claims description 5
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 5
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims description 4
- 150000004056 anthraquinones Chemical class 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 229920000233 poly(alkylene oxides) Polymers 0.000 claims description 4
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 claims description 4
- 229930192627 Naphthoquinone Natural products 0.000 claims description 3
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 claims description 3
- XJHABGPPCLHLLV-UHFFFAOYSA-N benzo[de]isoquinoline-1,3-dione Chemical compound C1=CC(C(=O)NC2=O)=C3C2=CC=CC3=C1 XJHABGPPCLHLLV-UHFFFAOYSA-N 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims description 3
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 claims description 3
- 150000002791 naphthoquinones Chemical class 0.000 claims description 3
- QQBPIHBUCMDKFG-UHFFFAOYSA-N phenazopyridine hydrochloride Chemical group Cl.NC1=NC(N)=CC=C1N=NC1=CC=CC=C1 QQBPIHBUCMDKFG-UHFFFAOYSA-N 0.000 claims description 3
- 229910001414 potassium ion Inorganic materials 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 claims description 2
- 125000002837 carbocyclic group Chemical group 0.000 claims description 2
- 150000002118 epoxides Chemical class 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 229910001415 sodium ion Inorganic materials 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 52
- -1 ethylene, trimethylene Chemical group 0.000 description 82
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- 238000000034 method Methods 0.000 description 50
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- 239000000463 material Substances 0.000 description 37
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- 239000003599 detergent Substances 0.000 description 35
- 239000004094 surface-active agent Substances 0.000 description 33
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- 102000004190 Enzymes Human genes 0.000 description 27
- 108090000790 Enzymes Proteins 0.000 description 27
- 229940088598 enzyme Drugs 0.000 description 26
- 150000003839 salts Chemical class 0.000 description 26
- 230000003750 conditioning effect Effects 0.000 description 22
- 239000002253 acid Substances 0.000 description 21
- 239000000243 solution Substances 0.000 description 21
- 238000005406 washing Methods 0.000 description 21
- 230000015572 biosynthetic process Effects 0.000 description 19
- 108090001060 Lipase Proteins 0.000 description 18
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- 102000035195 Peptidases Human genes 0.000 description 18
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- 235000019421 lipase Nutrition 0.000 description 18
- 238000003786 synthesis reaction Methods 0.000 description 18
- 239000004365 Protease Substances 0.000 description 17
- 229920002451 polyvinyl alcohol Polymers 0.000 description 16
- 239000002904 solvent Substances 0.000 description 16
- 239000004372 Polyvinyl alcohol Substances 0.000 description 15
- 125000002091 cationic group Chemical group 0.000 description 15
- 239000006260 foam Substances 0.000 description 15
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 14
- 239000003054 catalyst Substances 0.000 description 14
- 239000002245 particle Substances 0.000 description 14
- 239000002304 perfume Substances 0.000 description 14
- 239000007787 solid Substances 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N EtOH Substances CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
- 239000004927 clay Substances 0.000 description 13
- 159000000000 sodium salts Chemical class 0.000 description 13
- 239000000126 substance Substances 0.000 description 13
- 239000012190 activator Substances 0.000 description 12
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- 239000003921 oil Substances 0.000 description 12
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- 150000004965 peroxy acids Chemical class 0.000 description 12
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- 125000004432 carbon atom Chemical group C* 0.000 description 11
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- 210000003000 inclusion body Anatomy 0.000 description 11
- 239000000049 pigment Substances 0.000 description 11
- MHOFGBJTSNWTDT-UHFFFAOYSA-M 2-[n-ethyl-4-[(6-methoxy-3-methyl-1,3-benzothiazol-3-ium-2-yl)diazenyl]anilino]ethanol;methyl sulfate Chemical compound COS([O-])(=O)=O.C1=CC(N(CCO)CC)=CC=C1N=NC1=[N+](C)C2=CC=C(OC)C=C2S1 MHOFGBJTSNWTDT-UHFFFAOYSA-M 0.000 description 10
- 125000000129 anionic group Chemical group 0.000 description 10
- 125000003710 aryl alkyl group Chemical group 0.000 description 10
- 125000001309 chloro group Chemical group Cl* 0.000 description 10
- 238000007789 sealing Methods 0.000 description 10
- 239000002689 soil Substances 0.000 description 10
- 0 *c(cc1*)cc(*)c1N=Nc(cc1*)c(*)cc1N(*)I* Chemical compound *c(cc1*)cc(*)c1N=Nc(cc1*)c(*)cc1N(*)I* 0.000 description 9
- 150000008051 alkyl sulfates Chemical class 0.000 description 9
- 239000002738 chelating agent Substances 0.000 description 9
- 235000014113 dietary fatty acids Nutrition 0.000 description 9
- 239000000194 fatty acid Substances 0.000 description 9
- 229930195729 fatty acid Natural products 0.000 description 9
- 230000007062 hydrolysis Effects 0.000 description 9
- 238000006460 hydrolysis reaction Methods 0.000 description 9
- 238000000465 moulding Methods 0.000 description 9
- 229920000058 polyacrylate Polymers 0.000 description 9
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 description 9
- 101000740449 Bacillus subtilis (strain 168) Biotin/lipoyl attachment protein Proteins 0.000 description 8
- 150000001413 amino acids Chemical group 0.000 description 8
- 239000003945 anionic surfactant Substances 0.000 description 8
- 238000004061 bleaching Methods 0.000 description 8
- 239000011162 core material Substances 0.000 description 8
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 8
- 239000000835 fiber Substances 0.000 description 8
- 239000003205 fragrance Substances 0.000 description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 8
- 239000003112 inhibitor Substances 0.000 description 8
- 238000002844 melting Methods 0.000 description 8
- 230000008018 melting Effects 0.000 description 8
- 229920002689 polyvinyl acetate Polymers 0.000 description 8
- 239000011118 polyvinyl acetate Substances 0.000 description 8
- 239000004753 textile Substances 0.000 description 8
- 239000010457 zeolite Substances 0.000 description 8
- 108010065511 Amylases Proteins 0.000 description 7
- 102000013142 Amylases Human genes 0.000 description 7
- 241000193830 Bacillus <bacterium> Species 0.000 description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 7
- 229910021536 Zeolite Inorganic materials 0.000 description 7
- 150000004996 alkyl benzenes Chemical class 0.000 description 7
- 150000001412 amines Chemical class 0.000 description 7
- 235000019418 amylase Nutrition 0.000 description 7
- 125000004093 cyano group Chemical group *C#N 0.000 description 7
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 7
- 238000011049 filling Methods 0.000 description 7
- 238000009472 formulation Methods 0.000 description 7
- 239000008187 granular material Substances 0.000 description 7
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 7
- 229910000271 hectorite Inorganic materials 0.000 description 7
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 7
- 239000002736 nonionic surfactant Substances 0.000 description 7
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 7
- 229910000275 saponite Inorganic materials 0.000 description 7
- 238000011282 treatment Methods 0.000 description 7
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 6
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 6
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- 125000003545 alkoxy group Chemical group 0.000 description 6
- 230000029936 alkylation Effects 0.000 description 6
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
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- VRVDFJOCCWSFLI-UHFFFAOYSA-K trisodium 3-[[4-[(6-anilino-1-hydroxy-3-sulfonatonaphthalen-2-yl)diazenyl]-5-methoxy-2-methylphenyl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].COc1cc(N=Nc2cc(c3cccc(c3c2)S([O-])(=O)=O)S([O-])(=O)=O)c(C)cc1N=Nc1c(O)c2ccc(Nc3ccccc3)cc2cc1S([O-])(=O)=O VRVDFJOCCWSFLI-UHFFFAOYSA-K 0.000 description 6
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- 208000026197 X-linked hydrocephalus with stenosis of the aqueduct of Sylvius Diseases 0.000 description 3
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- AXMCIYLNKNGNOT-UHFFFAOYSA-M sodium;3-[[4-[(4-dimethylazaniumylidenecyclohexa-2,5-dien-1-ylidene)-[4-[ethyl-[(3-sulfonatophenyl)methyl]amino]phenyl]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 AXMCIYLNKNGNOT-UHFFFAOYSA-M 0.000 description 1
- RWVGQQGBQSJDQV-UHFFFAOYSA-M sodium;3-[[4-[(e)-[4-(4-ethoxyanilino)phenyl]-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]-2-methylcyclohexa-2,5-dien-1-ylidene]methyl]-n-ethyl-3-methylanilino]methyl]benzenesulfonate Chemical compound [Na+].C1=CC(OCC)=CC=C1NC1=CC=C(C(=C2C(=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C)C=2C(=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C)C=C1 RWVGQQGBQSJDQV-UHFFFAOYSA-M 0.000 description 1
- IXNUVCLIRYUKFB-UHFFFAOYSA-M sodium;3-[[4-[[4-(diethylamino)-2-methylphenyl]-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]cyclohexa-2,5-dien-1-ylidene]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].CC1=CC(N(CC)CC)=CC=C1C(C=1C=CC(=CC=1)N(CC)CC=1C=C(C=CC=1)S([O-])(=O)=O)=C(C=C1)C=CC1=[N+](CC)CC1=CC=CC(S([O-])(=O)=O)=C1 IXNUVCLIRYUKFB-UHFFFAOYSA-M 0.000 description 1
- NTOOJLUHUFUGQI-UHFFFAOYSA-M sodium;4-(4-acetamidoanilino)-1-amino-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].C1=CC(NC(=O)C)=CC=C1NC1=CC(S([O-])(=O)=O)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O NTOOJLUHUFUGQI-UHFFFAOYSA-M 0.000 description 1
- WQZNLMYQHGWSHK-UHFFFAOYSA-M sodium;5-[[4-(dimethylamino)phenyl]-(4-dimethylazaniumylidenecyclohexa-2,5-dien-1-ylidene)methyl]-4-ethoxy-2-(4-methyl-2-sulfonatoanilino)benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(C)C)C(OCC)=CC=1NC1=CC=C(C)C=C1S([O-])(=O)=O WQZNLMYQHGWSHK-UHFFFAOYSA-M 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- LJFWQNJLLOFIJK-UHFFFAOYSA-N solvent violet 13 Chemical compound C1=CC(C)=CC=C1NC1=CC=C(O)C2=C1C(=O)C1=CC=CC=C1C2=O LJFWQNJLLOFIJK-UHFFFAOYSA-N 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 150000001629 stilbenes Chemical class 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 239000002426 superphosphate Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 108010038851 tannase Proteins 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000005207 tetraalkylammonium group Chemical group 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- JADVWWSKYZXRGX-UHFFFAOYSA-M thioflavine T Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C1=[N+](C)C2=CC=C(C)C=C2S1 JADVWWSKYZXRGX-UHFFFAOYSA-M 0.000 description 1
- 150000003573 thiols Chemical group 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- QQOWHRYOXYEMTL-UHFFFAOYSA-N triazin-4-amine Chemical class N=C1C=CN=NN1 QQOWHRYOXYEMTL-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- OHOTVSOGTVKXEL-UHFFFAOYSA-K trisodium;2-[bis(carboxylatomethyl)amino]propanoate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C(C)N(CC([O-])=O)CC([O-])=O OHOTVSOGTVKXEL-UHFFFAOYSA-K 0.000 description 1
- 239000012588 trypsin Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- YKSGNOMLAIJTLT-UHFFFAOYSA-N violanthrone Chemical compound C12=C3C4=CC=C2C2=CC=CC=C2C(=O)C1=CC=C3C1=CC=C2C(=O)C3=CC=CC=C3C3=CC=C4C1=C32 YKSGNOMLAIJTLT-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000001018 xanthene dye Substances 0.000 description 1
- 229940030186 xpect Drugs 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- GAWWVVGZMLGEIW-GNNYBVKZSA-L zinc ricinoleate Chemical compound [Zn+2].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O.CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O GAWWVVGZMLGEIW-GNNYBVKZSA-L 0.000 description 1
- 229940100530 zinc ricinoleate Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/0003—Monoazo dyes prepared by diazotising and coupling from diazotized anilines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/0003—Monoazo dyes prepared by diazotising and coupling from diazotized anilines
- C09B29/0007—Monoazo dyes prepared by diazotising and coupling from diazotized anilines containing acid groups, e.g. CO2H, SO3H, PO3H2, OSO3H, OPO2H2; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/06—Monoazo dyes prepared by diazotising and coupling from coupling components containing amino as the only directing group
- C09B29/08—Amino benzenes
- C09B29/0801—Amino benzenes containing acid groups, e.g. COOH, SO3H, PO3H2, OSO3H, OPO3H2; SO2NHSO2R or salts thereof, R being hydrocarbonyls
- C09B29/0802—Amino benzenes containing acid groups, e.g. COOH, SO3H, PO3H2, OSO3H, OPO3H2; SO2NHSO2R or salts thereof, R being hydrocarbonyls containing COOH
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/06—Monoazo dyes prepared by diazotising and coupling from coupling components containing amino as the only directing group
- C09B29/08—Amino benzenes
- C09B29/0805—Amino benzenes free of acid groups
- C09B29/0807—Amino benzenes free of acid groups characterised by the amino group
- C09B29/0809—Amino benzenes free of acid groups characterised by the amino group substituted amino group
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/045—Multi-compartment
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Dispersion Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Lは、有機連結基であって、好ましくは14〜1000ダルトンまたは14〜600または28〜300の分子量を有し、好ましくは本質的にC、Hに加えて任意にOおよび/またはNのみからなる有機連結基であり、C(O)OM基のカルボニル炭素から始まり染料部分で終わる結合のシーケンスの中に、任意の−(Ca(O)−Ob)−基が、カルボニル炭素Caの前に酸素原子Obが見られるように組み込まれ、好ましくはLは、その中にエーテル(−O−)および/またはエステルおよび/またはアミド連結を任意に有するC1〜20アルキレン鎖であり、前記鎖は、たとえば−OH、−CN、−NO2、−SO2CH3、−Cl、−Brで任意に置換されていてもよく;Mは任意の適切な対イオンであり、典型的には、水素、ナトリウムまたはカリウムイオンである)。
ここで使用される場合、用語「アルコキシ」には、C1〜C8アルコキシ、および反復単位、たとえばブチレンオキシド、グリシドールオキシド、エチレンオキシドまたはプロピレンオキシドを有する、ポリオールのアルコキシ誘導体が含まれることが意図される。
Lは、有機連結基であって、好ましくは14〜1000ダルトンまたは14〜600または28〜300の分子量を有し、好ましくは本質的にC、Hに加えて任意にOおよび/またはNのみからなる有機連結基であり、C(O)OM基のカルボニル炭素から始まり染料部分で終わる結合のシーケンスの中に、任意の−(Ca(O)−Ob)−基が、カルボニル炭素Caの前に酸素原子Obが見られるように組み込まれ、好ましくはLは、その中にエーテル(−O−)および/またはエステルおよび/またはアミド連結を任意に有するC1〜20アルキレン鎖であり、該鎖は、たとえば−OH、−CN、−NO2、−SO2CH3、−Cl、−Brで任意に置換されていてもよく;Mは任意の適切な対イオンであり、典型的には、水素、ナトリウムまたはカリウムイオンである)。
a)R1およびR2は独立に、[(CH2CR’HO)x(CH2CR”HO)yH]から選択することができ、R’は、H、CH3、CH2O(CH2CH2O)zH、およびそれらの混合物からなる群から選択され;R”は、H、CH2O(CH2CH2O)zH、およびそれらの混合物からなる群から選択され;x+y≦10、好ましくは≦5であり;y≧1であり;z=0から5である;
b)R1=C1〜12アルキル、C6〜10アリール、C7〜C22アリールアルキル、およびR2=[(CH2CR’HO)x(CH2CR”HO)yH]であり、R’およびR”は上で定義される通りであり;x+y≦20、好ましくは≦10であり;y≧1;z=0から5である;
c)R1およびR2は独立に、1つ以上のエーテル、エステル、シアノ、またはアミド部分を任意に含む直鎖または分枝C1〜C12アルキル、C6〜10アリール、1つ以上のエーテル、エステル、シアノ、またはアミド部分を任意に含むC7〜C22アリールアルキル、および式6からなる群から選択される:
(a)R1およびR2は独立に、H、C6H11、または任意に置換されていてもよいC2〜C12アルキル鎖であって、その中にエーテル(−O−)またはエステル連結を任意に有し、Cl、Br、OH、CN、NO2、SO2CH3で任意に置換されていてもよいC2〜C12アルキル鎖、およびそれらの混合物からなる群から選択されるが、R1およびR2の両方がHではないことを要件とする;
(b)R1はCH2CH2R7、R2はCH2CH2R8であり、R7およびR8は独立に、H、CN、OH、C6H5、−OCOR9および−COOR9からなる群から選択され、各R9は独立に、アリールおよびアルキル、好ましくはC6H5もしくはC10H7アリールまたはC1〜C8アルキルから選択される。
適切な補助剤は、たとえば、洗浄性能を支援するもしくは強化するためのもの、たとえば柔軟化するもしくはフレッシュニングすることによって清浄にしようとする素材を処理するためのもの、または香料、着色剤、非布地シェーディング染料などを用いる場合は、組成物の美観を改変するためのものであってもよい。適切な補助剤材料には、それだけには限らないが、界面活性剤、ビルダー、キレート化剤、移染防止剤、分散剤、酵素、および酵素安定剤、触媒系材料、漂白活性化剤、過酸化水素、過酸化水素供給源、予備形成された過酸、ポリマー分散剤、土汚れ除去剤(clay soil removal agent)/再染着防止剤、増白剤、抑泡剤、染料、色相染料、香料、香料送達系、構造弾性化剤(structure elasticizing agent)、布地柔軟剤、キャリヤー、ヒドロトロープ、加工助剤、溶剤、追加的な染料および/または顔料が含まれ、そのうち幾つかは、以降でさらに詳細に考察する。下の開示に加え、かかる他の補助剤および使用のレベルの適切な例は、米国特許第5,576,282号、第6,306,812B1号および第6,326,348B1号に見出され、それらは参照により組み込まれる。
a) [(CH2CR’HO)x(CH2CR”HO)yH](式中、R’は、H、CH3、CH2O(CH2CH2O)zH、およびそれらの混合物からなる群から選択され;R”は、H、CH2O(CH2CH2O)zH、およびそれらの混合物からなる群から選択され;x+y≦5であり;y≧1であり;z=0から5である);
b) R1=アルキル、アリールまたはアリールアルキル、およびR2=[(CH2CR’HO)x(CH2CR”HO)yH]
(式中、R’は、H、CH3、CH2O(CH2CH2O)zH、およびそれらの混合物からなる群から選択され;R”は、H、CH2O(CH2CH2O)zH、およびそれらの混合物からなる群から選択され;x+y≦10であり;y≧1であり;z=0から5である);
c) R1=[CH2CH(OR3)CH2OR4]およびR2=[CH2CH(OR3)CH2OR4]
(式中、R3は、H、(CH2CH2O)zH、およびそれらの混合物からなる群から選択され;z=0から10であり;
R4は、(C1〜C16)アルキル、アリール基、およびそれらの混合物からなる群から選択される);ならびに
d) R1およびR2は独立に、スチレンオキシド、グリシジルメチルエーテル、イソブチルグリシジルエーテル、イソプロピルグリシジルエーテル、t−ブチルグリシジルエーテル、2−エチルヘキシルギシジルエーテル、およびグリシジルヘキサデシルエーテルのアミノ付加生成物に、続いて1から10個のアルキレンオキシド単位を付加したものから選択されてもよい。
(VI) −[(OCHR1−CHR2)a−O−OC−Ar−CO−]d
(VII) −[(OCHR3−CHR4)b−O−OC−sAr−CO−]e
(VIII) −[(OCHR5−CHR6)c−OR7]f
式中:
a、bおよびcは、1から200であり;
d、eおよびfは、1から50であり;
Arは、1,4−置換フェニレンであり;
sArは、5位がSO3Meで置換された1,3−置換フェニレンであり;
Meは、Li、K、Mg/2、Ca/2、Al/3、アンモニウム、モノ−、ジ−、トリ−、またはテトラアルキルアンモニウムであり、アルキル基はC1〜C18アルキルもしくはC2〜C10ヒドロキシアルキル、またはそれらの混合物であり;
R1、R2、R3、R4、R5およびR6は独立に、HまたはC1〜C18のn−もしくはイソ−アルキルから選択され;
R7は、直鎖状もしくは分枝C1〜C18アルキル、または直鎖状もしくは分枝C2〜C30アルケニル、または5から9個の炭素原子を有するシクロアルキル基、またはC8〜C30アリール基、またはC6〜C30アリールアルキル基である。
(a)サブチリシン(EC3.4.21.62)、それには、Bacillus、たとえば、US6,312,936B1、US5,679,630、US4,760,025、US7,262,042およびWO09/021867に記載される、Bacillus lentus、B.alkalophilus、B.subtilis、B.amyloliquefaciens、Bacillus pumilusおよびBacillus gibsoniiに由来するものが含まれる。
(a)WO94/02597、WO94/18314、WO96/23874およびWO97/43424に記載されるバリアント、とりわけ、WO96/23874で配列番号2としてリストされる酵素に対して、次の位置の1つ以上に置換を有するバリアント:15、23、105、106、124、128、133、154、156、181、188、190、197、202、208、209、243、264、304、305、391、408および444。
26、30、33、82、37、106、118、128、133、149、150、160、178、182、186、193、203、214、231、256、257、258、269、270、272、283、295、296、298、299、303、304、305、311、314、315、318、319、339、345、361、378、383、419、421、437、441、444、445、446、447、450、461、471、482、484であり、好ましくはD183*およびG184*の欠失も含有するもの。
(1)光漂白剤、たとえば、スルホン化亜鉛フタロシアニン、スルホン化アルミニウムフタロシアニン、キサンテン染料およびそれらの混合物;
(2)予備形成された過酸:適切な予備形成された過酸には、それだけには限らないが、予備形成された過酸またはその塩、典型的には、過カルボン酸および塩、過炭酸および塩、過イミド酸および塩、過硫酸および塩、たとえばOxone(登録商標)、ならびにそれらの混合物からなる群から選択される化合物が含まれる。適切な例には、ペルオキシカルボン酸もしくはその塩、またはペルオキシスルホン酸(peroxysulphonic acid)もしくはその塩が含まれる。ここでの使用に適した典型的なペルオキシカルボン酸塩は、次の化学式に相当する化学構造を有する:
(4)R−(C=O)−Lを有する漂白活性化剤、式中、Rはアルキル基であり、任意に分枝でもよく、漂白活性化剤が疎水性であるとき、6から14個の炭素原子、または8から12個の炭素原子を有し、漂白活性化剤が親水性であるとき、6個未満の炭素原子またはさらに4個未満の炭素原子を有し;Lは脱離基である。適切な脱離基の例は、安息香酸およびその誘導体、とりわけベンゼンスルホネートである。適切な漂白活性化剤には、ドデカノイルオキシベンゼンスルホネート、デカノイルオキシベンゼンスルホネート、デカノイルオキシ安息香酸またはそれらの塩、3,5,5−トリメチルヘキサノイルオキシベンゼンスルホネート、テトラアセチルエチレンジアミン(TAED)およびノナノイルオキシベンゼンスルホネート(NOBS)が含まれる。適切な漂白活性化剤は、WO98/17767にも開示されている。任意の適切な漂白活性化剤が採用されてもよいが、本発明の一側面では、主題組成物は、NOBS、TAEDまたはそれらの混合物を含んでもよい。
(6)組成物は、好ましくは触媒金属錯体を含んでもよい。金属含有漂白触媒の1つの好ましいタイプは、触媒系であって、所定の漂白触媒活性を持つ遷移金属カチオン、たとえば、銅、鉄、チタン、ルテニウム、タングステン、モリブデン、またはマンガンカチオンと;漂白触媒活性をほとんどまたはまったく有していない補助金属カチオン、たとえば、亜鉛またはアルミニウムカチオンと;触媒金属カチオンおよび補助金属カチオンに対する所定の安定度定数を有する金属イオン封鎖剤、特に、エチレンジアミン四酢酸、エチレンジアミンテトラ(メチレンホスホン酸)およびそれらの水溶性の塩とを含む触媒系である。かかる触媒は、U.S.4,430,243に開示されている。
(R)(R1)(R2)(R3)N+X-
式中、Rは、直鎖状または分枝の、置換または無置換の、C6〜18アルキルまたはアルケニル部分であり、R1およびR2は独立に、メチルまたはエチル部分から選択され、R3は、ヒドロキシル、ヒドロキシメチルまたはヒドロキシエチル部分であり、Xは電気的中性をもたらすアニオンであり、適切なアニオンには、ハロゲン化物、たとえば塩化物、サルフェート、およびスルホネートが含まれる。適切なカチオン性洗浄界面活性剤は、モノC6〜18アルキルモノヒドロキシエチルジメチル第四級アンモニウムクロリドである。非常に適切なカチオン性洗浄界面活性剤は、モノC8〜10アルキルモノヒドロキシエチルジメチル第四級アンモニウムクロリド、モノC10〜12アルキルモノヒドロキシエチルジメチル第四級アンモニウムクロリドおよびモノC10アルキルモノヒドロキシエチルジメチル第四級アンモニウムクロリドである。
本発明の組成物は、上述の通りの任意の有用な形態であってもよい。それらは、配合者によって選択される任意のプロセスによって作製されてもよく、その非限定的な例は、例、およびU.S.4,990,280;U.S.20030087791A1;U.S.20030087790A1;U.S.20050003983A1;U.S.20040048764A1;U.S.4,762,636;U.S.6,291,412;U.S.20050227891A1;EP1070115A2;U.S.5,879,584;U.S.5,691,297;U.S.5,574,005;U.S.5,569,645;U.S.5,565,422;U.S.5,516,448;U.S.5,489,392;U.S.5,486に記載されている。
パウチ形態の本発明の組成物は、任意の適切な機器および方法を使用して作製されてもよい。しかし、多区画パウチは、好ましくは水平型充填プロセスを使用して作製される。フィルムは好ましくは湿潤させ、より好ましくは加熱してその展性を増大させる。さらにより好ましくは、方法は、真空を使用してフィルムを適切な型に引き入れることも含む。型内へのフィルムの真空引きは、フィルムが表面の水平部分の上に置かれた後、0.2から5秒間、好ましくは0.3から3秒間、さらにより好ましくは0.5から1.5秒間施すことができる。この真空は、好ましくは、それが−100ミリバールから−1000ミリバール、またはさらには−200ミリバールから−600ミリバールの負圧をもたらしてもよい。
a)第1の区画を形成する工程(上述の通り);
b)工程(a)で形成された密閉区画の一部または全部の内部にくぼみを形成し、第1の区画上に重ね合わされる第2の成形区画を生ずる工程;
c)第2の区画を充填し、第3のフィルムによって密閉する工程;
d)前記第1、第2および第3フィルムを封止する工程;ならびに
e)フィルムを切断し、多区画パウチを生成する工程
を含むプロセスに従って作成される。
a)第1の成形機上で第1のフィルムを使用し、任意に熱および/または真空を使用して、第1の区画を形成する工程;
b)前記第1の区画に第1の組成物を充填する工程;
c)第2の成形機上で、任意に熱および真空を使用して第2のフィルムを変形させて、第2のおよび任意に第3の成形区画を作製する工程;
d)第2のおよび任意に第3の区画を充填する工程;
e)第3のフィルムを使用して、第2のおよび任意に第3の区画を封止する工程;
f)封止された第2のおよび任意に第3の区画を、第1の区画上に配置する工程;
g)第1の、第2の、および任意に第3の区画を封止する工程;ならびに
h)フィルムを切断して、多区画パウチを生成する工程
を含む。
次の例において、式1の染料は、式1の染料またはそれらの混合物のいずれか、特に上の染料合成例に示した染料1から13またはそれらの混合物のいずれかであり得る。
この例は、一回用量洗濯洗剤用の様々な配合物を示す。かかる一回用量配合物は、単一区画または多区画を含むことができる。
本発明の多区画一回用量の洗濯洗剤配合物を以下に示す。これらの例では、一回用量は3区画を有するが、同様の組成物を、2、4または5区画で作製することができる。区画を封入するために使用されるフィルムは、ポリビニルアルコールである。
LASは、Stepan(米国イリノイ州ノースフィールド)、またはHuntsman Corpによって供給される、平均脂肪族炭素鎖長C9〜C15を有する直鎖状アルキルベンゼンスルホネートである(HLASは酸型である)。
ここに開示する寸法および値は、記載された正確な数値に厳密に限定されるものとして理解されるべきでない。むしろ、別段の指定がない限り、かかる寸法はそれぞれ、記載された値およびその値周辺の機能的に同等の範囲の両方を意味することが意図される。たとえば、「40mm」として開示された寸法は、「約40mm」を意味することが意図される。
Claims (3)
- 式Iの構造を有するカルボキシレート染料:
- 前記染料がアントラキノンまたはアゾ染料である、請求項1に記載のカルボキシレート染料。
- 前記カルボキシレート染料が次の構造を有する、請求項1または請求項2に記載のカルボキシレート染料:
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US9187717B2 (en) | 2015-11-17 |
EP2828339B1 (en) | 2018-10-31 |
TR201900214T4 (tr) | 2019-02-21 |
EP2828339A1 (en) | 2015-01-28 |
BR112014023153B1 (pt) | 2021-02-23 |
WO2013142495A1 (en) | 2013-09-26 |
CN104350106A (zh) | 2015-02-11 |
JP2015514141A (ja) | 2015-05-18 |
MX2014011154A (es) | 2014-12-10 |
EP2828340A1 (en) | 2015-01-28 |
CN104220535B (zh) | 2017-03-22 |
CA2867714A1 (en) | 2013-09-26 |
IN2014DN07573A (ja) | 2015-04-24 |
JP6203812B2 (ja) | 2017-09-27 |
US20150099869A1 (en) | 2015-04-09 |
CN104350106B (zh) | 2017-03-08 |
MX361441B (es) | 2018-12-06 |
JP5911996B2 (ja) | 2016-04-27 |
US20150000048A1 (en) | 2015-01-01 |
CA2867361C (en) | 2017-07-25 |
WO2013142486A1 (en) | 2013-09-26 |
MX2014011169A (es) | 2016-05-26 |
CN104220535A (zh) | 2014-12-17 |
US20160075977A1 (en) | 2016-03-17 |
CA2867361A1 (en) | 2013-09-26 |
IN2014DN07763A (ja) | 2015-05-15 |
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