JP2013502061A - 熱磁気材料からなる熱交換器床 - Google Patents
熱磁気材料からなる熱交換器床 Download PDFInfo
- Publication number
- JP2013502061A JP2013502061A JP2012524183A JP2012524183A JP2013502061A JP 2013502061 A JP2013502061 A JP 2013502061A JP 2012524183 A JP2012524183 A JP 2012524183A JP 2012524183 A JP2012524183 A JP 2012524183A JP 2013502061 A JP2013502061 A JP 2013502061A
- Authority
- JP
- Japan
- Prior art keywords
- heat exchanger
- range
- thermomagnetic
- compounds
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F7/00—Elements not covered by group F28F1/00, F28F3/00 or F28F5/00
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28C—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA COME INTO DIRECT CONTACT WITHOUT CHEMICAL INTERACTION
- F28C3/00—Other direct-contact heat-exchange apparatus
- F28C3/10—Other direct-contact heat-exchange apparatus one heat-exchange medium at least being a fluent solid, e.g. a particulate material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23P—METAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
- B23P15/00—Making specific metal objects by operations not covered by a single other subclass or a group in this subclass
- B23P15/26—Making specific metal objects by operations not covered by a single other subclass or a group in this subclass heat exchangers or the like
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B21/00—Machines, plants or systems, using electric or magnetic effects
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/012—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials adapted for magnetic entropy change by magnetocaloric effect, e.g. used as magnetic refrigerating material
- H01F1/015—Metals or alloys
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2321/00—Details of machines, plants or systems, using electric or magnetic effects
- F25B2321/002—Details of machines, plants or systems, using electric or magnetic effects by using magneto-caloric effects
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B30/00—Energy efficient heating, ventilation or air conditioning [HVAC]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/4935—Heat exchanger or boiler making
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/4935—Heat exchanger or boiler making
- Y10T29/49352—Repairing, converting, servicing or salvaging
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Power Engineering (AREA)
- Hard Magnetic Materials (AREA)
- Powder Metallurgy (AREA)
- Soft Magnetic Materials (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Laminated Bodies (AREA)
- Silicon Compounds (AREA)
Abstract
【選択図】なし
Description
−個々の流路の断面積が0.001〜0.2mm2の範囲、より好ましくは0.01〜0.03mm2、特に0.015〜0.025mm2の範囲にある、
−壁厚が50〜300μmの範囲、より好ましくは50−150μm、特に85〜115μmの範囲にある、
−空隙率が10〜60%の範囲、より好ましくは15〜35%、特に20〜30%の範囲にある、
−表面/体積比率が3000〜50000m2/m3の範囲、より好ましくは5000〜15000m2/m3の範囲にある。
(AyBy-1)2+δCwDxEz (I)
式中、
Aは、MnまたはCoであり、
Bは、Fe、CrまたはNiであり、
CとDとE:CとDとEの少なくとも二つは異なり、常にゼロ濃度でなく、PとB、Se、Ge、Ga、Si、Sn、N、As、Sbから選ばれ、CとDとEのうち少なくとも一つはGeまたはSiであり、
δは、−0.1〜0.1の範囲の数字であり、
wとxとyとzは、0〜1の範囲の数字であり、w+x+z=1である;
La(FexAl1-x)13HyまたはLa(FexSi1-x)13Hy (II)
式中、
xは、0.7〜0.95の数字であり、
yは、0〜3の、好ましくは0〜2の数字である;
La(FexAlyCoz)13またはLa(FexSiyCoz)13 (III)
式中、
xは、0.7〜0.95の数字であり、
yは、0.05〜1−xの数字であり、
zは、0.005〜0.5の数字である;
LaMnxFe2-xGe (IV)
式中、
xは、1.7〜1.95の数字である;
Gd5(SixGe1-x)4 (V)
式中、xは、0.2〜1の数字である;
Tb5(Si4-xGex) (VI)
式中、x=0、1、2、3又は4である;
XTiGe (VII)
式中、X=Dy、Ho又はTmである;
Mn2-xZxSb (VIII)
Mn2ZxSb1-x (IX)
式中、
Zは、Cr、Cu、Zn、Co、V、As又はGeであり、
xは0.01〜0.5であり、
ZがAsでないとき、SbはAsで置き換えられていてもよい。
Gd5(SixGe1-x)4
式中、Xは、0.2〜1の数字である;
は、例えば、Gd5(Si0.5Ge0.5)4、Gd5(Si0.425Ge0.575)4、Gd5(Si0.45Ge0.55)4、Gd5(Si0.365Ge0.635)4、Gd5(Si0.3Ge0.7)4、Gd5(Si0.25Ge0.75)4である。
a)その金属系材料に相当する化学量の化学元素及び/又は合金を、固体及び/又は液相で反応させ、
b)適当ならこの工程a)からの反応生成物を固化させ、
c)工程a)またはb)からの固体を焼成及び/又は熱処理し、
d)工程c)からの焼成及び/又は熱処理後の固体を少なくとも100K/sの冷却速度で急冷することからなる熱磁気材料の製造方法が好ましい。
脱気したMnFePGeのプレス品を含む石英アンプルを1100℃で10時間維持して、この粉末を焼成した。この焼成後に650℃で60時間熱処理して均一化させた。炉中で室温までゆっくり冷却するのでなく、直ちに室温の水中で急冷した。この水中での急冷により、試料表面である程度の酸化が起こった。表面の酸化層を希酸で溶解除去した。XRDパターンから、すべての試料がFe2P型構造で結晶化していることがわかった。
Mn1.1Fe0.9P0.81Ge0.19、Mn1.1Fe0.9P0.78Ge0.22、Mn1.1Fe0.9P0.75Ge0.25、Mn1.2Fe0.8P0.81Ge0.19。これらの試料の熱ヒステリシスの測定値は、この順序でそれぞれ7K、5K、2K、3Kであった。徐冷した試料の熱ヒステリシスは10Kを超え、これに較べると、熱ヒステリシスが大幅に減少した。
MnFeP(GeSb)の溶融紡糸
WO2004/068512とJ. Appl. Phys. 99,08 Q107 (2006)に記載のようにして、ボールミル中で高エネルギー下での固相反応法で多結晶性MnFePC(Ge,Sb)合金を製造した。これらの材料を、次いでノズルを備えた石英チューブに入れた。内部を10-2mbarの真空とし、高純度アルゴンガスで満たした。高周波加熱で試料を溶融し、回転銅ドラムを含んでいる槽中に、差圧でノズルから噴出させた。この銅ホイールの表面速度は制御可能であり、約105K/sの冷却速度を得ることができた。次いで、得られたリボンを900℃で1時間熱処理した。
積層状の磁気熱量材料からなる充填床または構造床と磁石と熱移動流体とからなる簡単な磁気熱量発電器を評価し、次の結果を得た:
以下の表には、異なる運転周波数での正味電力(冷却電力−熱移動流体を動かすのに必要な電力)をまとめて示す。
Claims (12)
- 平均粒径が50μm〜1mmの範囲にあり、充填床における空隙率を30〜45%の範囲とする熱磁気材料粒子からなる充填熱交換器床。
- 上記材料粒子の平均粒径が200〜400μmの範囲にある請求項1に記載の熱交換器床。
- 前記材料粒子が、球状、ペレット状、シート状または円柱状である請求項1または2に記載の熱交換器床。
- 前記充填床における空隙率が36〜40%である請求項1〜3のいずれか一項に記載の熱交換器床。
- 個々の流路の断面積が0.001〜0.2mm2の範囲であり、壁厚が50〜300μmであり、空隙率が10〜60%の範囲であり、表面/体積比率が3000〜50000m2/m3の範囲である連続流路を有する、あるいはシート厚が0.1〜2mmでシート間隔が0.05〜1mmである複数の平行シートを有する熱磁気材料モノリスからなる熱交換器床。
- 前記空隙率が20〜30%である請求項5に記載の熱交換器床。
- 前記個々の流路の断面積が0.01〜0.03mm2であり、壁厚が50〜150μmである請求項5または6に記載の熱交換器床。
- 前記熱磁気材料が、
(1)一般式(I)の化合物:
(AyBy-1)2+δCwDxEz (I)
式中、
Aは、MnまたはCoであり、
Bは、Fe、CrまたはNiであり、
C、D及びEは、C、D及びEの少なくとも2種は異なり、ゼロ濃度になることはなく、P、B、Se、Ge、Ga、Si、Sn、N、As及びSbから選ばれ、C、D及びEのうち少なくとも1種はGe又はSiであり、
δは、−0.1〜0.1の範囲の数字であり、
w、x、y、zは、0〜1の範囲の数字であり、w+x+z=1である;
(2)一般式(II)及び/又は(III)及び/又は(IV)のLa系及びFe系化合物:
La(FexAl1-x)13HyまたはLa(FexSi1-x)13Hy (II)
式中、
xは、0.7〜0.95の数字であり、
yは、0〜3の数字である;
La(FexAlyCoz)13またはLa(FexSiyCoz)13 (III)
式中、
xは、0.7〜0.95の数字であり、
yは、0.05〜1−xの数字であり、
zは、0.005〜0.5の数字である;
LaMnxFe2-xGe (IV)
式中、
xは、1.7〜1.95の数字である;
(3)MnTP型(式中、Tは遷移金属であり、Pは、原子当りの電子数e/aが7〜8.5の範囲であるp−ドープ金属である)のホイスラー合金:
(4)一般式(V)のGd系およびSi系化合物:
Gd5(SixGe1-x)4 (V)
式中、xは、0.2〜1の数字である;
(5)Fe2P系化合物:
(6)ペロブスカイト型マンガナイト:
(7)希土類元素を含む一般式(VI)及び(VII)の化合物:
Tb5(Si4-xGex) (VI)
式中、x=0、1、2、3又は4である;
XTiGe (VII)
式中、X=Dy、Ho又はTmである;
(8)一般式(VIII)及び(IX)のMn及びSb系、あるいはMn及びAs系化合物:
Mn2-xZxSb (VIII)
Mn2ZxSb1-x (IX)
式中、
Zは、Cr、Cu、Zn、Co、V、As又はGeであり、
xは0.01〜0.5であり、
ZがAsでないとき、SbはAsで置き換えられていてもよい;
から選ばれる請求項1〜7のいずれか一項に記載の熱交換器床。 - 前記熱磁気材料が、Mn、Fe、P及び任意にSbに加えて、更にGe又はSi又はAs、又はGe及びSi、又はGe及びAs、又はSi及びAs、又はGe、Si及びAsを含む一般式(I)の少なくとも四元の化合物から選ばれる請求項8に記載の熱交換器床。
- 請求項1〜4のいずれか一項に記載の熱交換器床を製造する方法であって、
熱磁気材料の粉末を成形して熱磁気材料粒子を形成する工程、及び次いでこの材料粒子を充填して前記熱交換器床を形成する工程を含む製造方法。 - 請求項5〜7のいずれか一項に記載の熱交換器床を製造する方法であって、
前記熱磁気材料を押出成型、射出成型または成型によりモノリスを形成する製造方法。 - 請求項1〜9のいずれか一項に記載の熱交換器床の冷蔵庫や空調装置、熱ポンプ中での、あるいは熱の直接変換による発電における使用方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP09167550.4 | 2009-08-10 | ||
EP09167550 | 2009-08-10 | ||
PCT/EP2010/061026 WO2011018348A2 (de) | 2009-08-10 | 2010-07-29 | Wärmetauscherbetten aus thermomagnetischem material |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016057061A Division JP6185621B2 (ja) | 2009-08-10 | 2016-03-22 | 熱磁気材料からなる熱交換器床 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2013502061A true JP2013502061A (ja) | 2013-01-17 |
JP2013502061A5 JP2013502061A5 (ja) | 2013-09-19 |
Family
ID=42629291
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012524183A Pending JP2013502061A (ja) | 2009-08-10 | 2010-07-29 | 熱磁気材料からなる熱交換器床 |
JP2012524182A Pending JP2013501910A (ja) | 2009-08-10 | 2010-07-29 | 積層状の磁気熱量材料からなる熱交換器床 |
JP2015204260A Pending JP2016040512A (ja) | 2009-08-10 | 2015-10-16 | 積層状の磁気熱量材料からなる熱交換器床 |
JP2016057061A Expired - Fee Related JP6185621B2 (ja) | 2009-08-10 | 2016-03-22 | 熱磁気材料からなる熱交換器床 |
Family Applications After (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012524182A Pending JP2013501910A (ja) | 2009-08-10 | 2010-07-29 | 積層状の磁気熱量材料からなる熱交換器床 |
JP2015204260A Pending JP2016040512A (ja) | 2009-08-10 | 2015-10-16 | 積層状の磁気熱量材料からなる熱交換器床 |
JP2016057061A Expired - Fee Related JP6185621B2 (ja) | 2009-08-10 | 2016-03-22 | 熱磁気材料からなる熱交換器床 |
Country Status (11)
Country | Link |
---|---|
US (3) | US9147511B2 (ja) |
EP (3) | EP3128520B1 (ja) |
JP (4) | JP2013502061A (ja) |
KR (4) | KR20170054541A (ja) |
CN (2) | CN102511067B (ja) |
AU (1) | AU2010283855A1 (ja) |
BR (2) | BR112012003125A2 (ja) |
CA (1) | CA2770862A1 (ja) |
RU (2) | RU2012108924A (ja) |
TW (2) | TW201111731A (ja) |
WO (2) | WO2011018347A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015149464A (ja) * | 2014-02-05 | 2015-08-20 | 株式会社三徳 | 磁気冷凍デバイスおよび磁気冷凍システム |
JP2016514360A (ja) * | 2013-01-24 | 2016-05-19 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 材料配列の最適化による磁気熱量カスケードの性能改良 |
Families Citing this family (75)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4703699B2 (ja) * | 2008-09-04 | 2011-06-15 | 株式会社東芝 | 磁気冷凍用磁性材料、磁気冷凍デバイスおよび磁気冷凍システム |
TW201101345A (en) * | 2009-04-08 | 2011-01-01 | Basf Se | Heat carrier medium for magnetocaloric materials |
US9476617B2 (en) | 2010-10-04 | 2016-10-25 | Basf Se | Thermoelectric modules for an exhaust system |
JP2014521050A (ja) * | 2011-07-19 | 2014-08-25 | アストロノーティックス コーポレイション オブ アメリカ | 磁気熱量材料の逆劣化のためのシステム及び方法 |
CN103090583B (zh) * | 2011-10-31 | 2016-03-09 | 台达电子工业股份有限公司 | 磁制冷装置及其磁热模块 |
TWI453365B (zh) * | 2011-10-31 | 2014-09-21 | Delta Electronics Inc | 磁製冷裝置及其磁熱模組 |
CN103137281B (zh) * | 2011-11-22 | 2016-06-01 | 中国科学院物理研究所 | 粘结La(Fe,Si)13基磁热效应材料及其制备方法和用途 |
EP2833085A4 (en) * | 2012-03-30 | 2015-12-02 | Toshiba Kk | MATERIAL FOR MAGNETIC REFRIGERATION AND MAGNETIC REFRIGERATION DEVICE |
US20130319012A1 (en) * | 2012-05-29 | 2013-12-05 | Delta Electronics, Inc. | Magnetic cooling device |
FR2999013B1 (fr) * | 2012-12-03 | 2014-12-26 | Schneider Electric Ind Sas | Dispositif magnetothermique de limitation de courant |
US9245673B2 (en) | 2013-01-24 | 2016-01-26 | Basf Se | Performance improvement of magnetocaloric cascades through optimized material arrangement |
FR3004795A1 (fr) * | 2013-04-19 | 2014-10-24 | Erasteel | Plaque magnetocalorique pour un element magnetique refrigerant et son procede de fabrication, bloc pour element magnetique refrigerant la comportant et leurs procedes de fabrication, et element magnetique refrigerant comportant ces blocs |
KR20160042433A (ko) * | 2013-08-09 | 2016-04-19 | 바스프 에스이 | B를 함유하는 자기열량 물질 |
KR20160042047A (ko) * | 2013-08-09 | 2016-04-18 | 바스프 에스이 | B를 함유하는 자기열량 물질 |
US20160189835A1 (en) * | 2013-08-09 | 2016-06-30 | Basf Se | Magnetocaloric materials containing b |
KR101575861B1 (ko) | 2014-02-13 | 2015-12-10 | 충북대학교 산학협력단 | 자기 열량 금속 산화물 및 이의 제조방법 |
US11384966B2 (en) | 2014-03-21 | 2022-07-12 | The Charles Stark Draper Laboratory, Inc. | Cooler with remote heat sink |
DE102014107294B4 (de) * | 2014-05-23 | 2017-02-09 | Andreas Hettich Gmbh & Co. Kg | Zentrifuge |
JP6369299B2 (ja) * | 2014-11-20 | 2018-08-08 | 株式会社デンソー | 磁気熱量素子および熱磁気サイクル装置 |
WO2016096509A1 (en) | 2014-12-18 | 2016-06-23 | Basf Se | Magnetocaloric cascade and method for fabricating a magnetocaloric cascade |
JP2017538018A (ja) * | 2014-12-18 | 2017-12-21 | ローム アンド ハース エレクトロニック マテリアルズ エルエルシーRohm and Haas Electronic Materials LLC | 負の光弾性定数を有するポリマー材料 |
EP3341126A1 (en) * | 2015-08-28 | 2018-07-04 | Haldor Topsøe A/S | Induction heating of endothermic reactions |
US10541070B2 (en) | 2016-04-25 | 2020-01-21 | Haier Us Appliance Solutions, Inc. | Method for forming a bed of stabilized magneto-caloric material |
US10299655B2 (en) | 2016-05-16 | 2019-05-28 | General Electric Company | Caloric heat pump dishwasher appliance |
WO2018011189A1 (en) | 2016-07-11 | 2018-01-18 | Basf Se | Magnetocaloric regenerators comprising materials containing cobalt, manganese, boron and carbon |
US10222101B2 (en) | 2016-07-19 | 2019-03-05 | Haier Us Appliance Solutions, Inc. | Linearly-actuated magnetocaloric heat pump |
US10281177B2 (en) | 2016-07-19 | 2019-05-07 | Haier Us Appliance Solutions, Inc. | Caloric heat pump system |
US10047979B2 (en) | 2016-07-19 | 2018-08-14 | Haier Us Appliance Solutions, Inc. | Linearly-actuated magnetocaloric heat pump |
US10274231B2 (en) | 2016-07-19 | 2019-04-30 | Haier Us Appliance Solutions, Inc. | Caloric heat pump system |
US10047980B2 (en) | 2016-07-19 | 2018-08-14 | Haier Us Appliance Solutions, Inc. | Linearly-actuated magnetocaloric heat pump |
US10295227B2 (en) | 2016-07-19 | 2019-05-21 | Haier Us Appliance Solutions, Inc. | Caloric heat pump system |
US10443585B2 (en) | 2016-08-26 | 2019-10-15 | Haier Us Appliance Solutions, Inc. | Pump for a heat pump system |
CN106344017A (zh) * | 2016-08-31 | 2017-01-25 | 刘奎杰 | 一种用于普外科医学诊断的磁共振成像装置 |
EP3507814A1 (en) | 2016-08-31 | 2019-07-10 | Basf Se | Controlled variation of parameters of magnetocaloric materials |
DE102017126803B4 (de) | 2016-11-18 | 2022-02-03 | Leibniz-Institut Für Festkörper- Und Werkstoffforschung Dresden E.V. | Vorrichtung und verfahren zur umwandlung thermischer energie in elektrische energie |
US10288326B2 (en) | 2016-12-06 | 2019-05-14 | Haier Us Appliance Solutions, Inc. | Conduction heat pump |
US10386096B2 (en) | 2016-12-06 | 2019-08-20 | Haier Us Appliance Solutions, Inc. | Magnet assembly for a magneto-caloric heat pump |
CN110088224A (zh) * | 2016-12-22 | 2019-08-02 | 株式会社三德 | 蓄冷材料及其制造方法、蓄冷器以及制冷机 |
DE102017102163B4 (de) | 2017-02-03 | 2020-10-01 | Leibniz-Institut Für Festkörper- Und Werkstoffforschung Dresden E.V. | Magnetokalorischer Wärmeübertrager und Verfahren zu seiner Herstellung |
US10527325B2 (en) | 2017-03-28 | 2020-01-07 | Haier Us Appliance Solutions, Inc. | Refrigerator appliance |
EP3601915A4 (en) * | 2017-03-28 | 2020-12-23 | John Barclay | ACTIVE MAGNETIC REGENERATIVE PROCEDURES AND SYSTEMS USING HYDROGEN HEAT TRANSFER LIQUID |
US11009282B2 (en) | 2017-03-28 | 2021-05-18 | Haier Us Appliance Solutions, Inc. | Refrigerator appliance with a caloric heat pump |
FR3065063A1 (fr) | 2017-04-11 | 2018-10-12 | Centre National De La Recherche Scientifique (Cnrs) | Procede d'obtention d'un materiau a effet magnetocalorique geant par irradiation d'ions |
WO2018197612A1 (en) | 2017-04-27 | 2018-11-01 | Basf Se | Preparation of powders of nitrided inorganic materials |
US10451320B2 (en) | 2017-05-25 | 2019-10-22 | Haier Us Appliance Solutions, Inc. | Refrigerator appliance with water condensing features |
US10422555B2 (en) | 2017-07-19 | 2019-09-24 | Haier Us Appliance Solutions, Inc. | Refrigerator appliance with a caloric heat pump |
US10451322B2 (en) | 2017-07-19 | 2019-10-22 | Haier Us Appliance Solutions, Inc. | Refrigerator appliance with a caloric heat pump |
DE102017120371B3 (de) | 2017-09-05 | 2019-01-24 | Deutsches Zentrum für Luft- und Raumfahrt e.V. (DLR) | Verfahren zum Betreiben einer magnetokalorischen Wärmepumpe und magnetokalorische Wärmepumpenanordnung |
US10520229B2 (en) | 2017-11-14 | 2019-12-31 | Haier Us Appliance Solutions, Inc. | Caloric heat pump for an appliance |
US11022348B2 (en) | 2017-12-12 | 2021-06-01 | Haier Us Appliance Solutions, Inc. | Caloric heat pump for an appliance |
WO2019121766A1 (en) | 2017-12-18 | 2019-06-27 | Basf Se | Building unit for magnetocaloric heat exchanger |
US10830506B2 (en) | 2018-04-18 | 2020-11-10 | Haier Us Appliance Solutions, Inc. | Variable speed magneto-caloric thermal diode assembly |
US10557649B2 (en) | 2018-04-18 | 2020-02-11 | Haier Us Appliance Solutions, Inc. | Variable temperature magneto-caloric thermal diode assembly |
US10648706B2 (en) | 2018-04-18 | 2020-05-12 | Haier Us Appliance Solutions, Inc. | Magneto-caloric thermal diode assembly with an axially pinned magneto-caloric cylinder |
US10648704B2 (en) | 2018-04-18 | 2020-05-12 | Haier Us Appliance Solutions, Inc. | Magneto-caloric thermal diode assembly |
US10782051B2 (en) | 2018-04-18 | 2020-09-22 | Haier Us Appliance Solutions, Inc. | Magneto-caloric thermal diode assembly |
US10648705B2 (en) | 2018-04-18 | 2020-05-12 | Haier Us Appliance Solutions, Inc. | Magneto-caloric thermal diode assembly |
US10551095B2 (en) | 2018-04-18 | 2020-02-04 | Haier Us Appliance Solutions, Inc. | Magneto-caloric thermal diode assembly |
US10641539B2 (en) | 2018-04-18 | 2020-05-05 | Haier Us Appliance Solutions, Inc. | Magneto-caloric thermal diode assembly |
US10876770B2 (en) | 2018-04-18 | 2020-12-29 | Haier Us Appliance Solutions, Inc. | Method for operating an elasto-caloric heat pump with variable pre-strain |
US11015842B2 (en) | 2018-05-10 | 2021-05-25 | Haier Us Appliance Solutions, Inc. | Magneto-caloric thermal diode assembly with radial polarity alignment |
US11054176B2 (en) | 2018-05-10 | 2021-07-06 | Haier Us Appliance Solutions, Inc. | Magneto-caloric thermal diode assembly with a modular magnet system |
US10989449B2 (en) | 2018-05-10 | 2021-04-27 | Haier Us Appliance Solutions, Inc. | Magneto-caloric thermal diode assembly with radial supports |
US11092364B2 (en) | 2018-07-17 | 2021-08-17 | Haier Us Appliance Solutions, Inc. | Magneto-caloric thermal diode assembly with a heat transfer fluid circuit |
US10684044B2 (en) | 2018-07-17 | 2020-06-16 | Haier Us Appliance Solutions, Inc. | Magneto-caloric thermal diode assembly with a rotating heat exchanger |
US11149994B2 (en) | 2019-01-08 | 2021-10-19 | Haier Us Appliance Solutions, Inc. | Uneven flow valve for a caloric regenerator |
US11168926B2 (en) | 2019-01-08 | 2021-11-09 | Haier Us Appliance Solutions, Inc. | Leveraged mechano-caloric heat pump |
US11274860B2 (en) | 2019-01-08 | 2022-03-15 | Haier Us Appliance Solutions, Inc. | Mechano-caloric stage with inner and outer sleeves |
US11193697B2 (en) | 2019-01-08 | 2021-12-07 | Haier Us Appliance Solutions, Inc. | Fan speed control method for caloric heat pump systems |
US11112146B2 (en) | 2019-02-12 | 2021-09-07 | Haier Us Appliance Solutions, Inc. | Heat pump and cascaded caloric regenerator assembly |
US11015843B2 (en) | 2019-05-29 | 2021-05-25 | Haier Us Appliance Solutions, Inc. | Caloric heat pump hydraulic system |
CN110556221B (zh) * | 2019-08-13 | 2021-09-10 | 北京工业大学 | 一种具有大磁熵变和宽工作温区的类单晶异质结室温磁制冷材料及其制备工艺 |
DE102020118370B3 (de) | 2020-07-13 | 2021-11-04 | Leibniz-Institut für Festkörper- und Werkstoffforschung Dresden e.V. (IFW Dresden e.V.) | Vorrichtung und Verfahren zur Umwandlung von thermischer Energie in elektrische Energie |
US11889661B2 (en) | 2020-09-17 | 2024-01-30 | Rolls-Royce North American Technologies Inc. | Integrated circuit thermal management system |
CN115798856B (zh) * | 2023-01-31 | 2023-08-25 | 苏州赛特锐精密机械配件有限公司 | 软磁热电复合材料、无线充电构件及制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004068512A1 (en) * | 2003-01-29 | 2004-08-12 | Stichting Voor De Technische Wetenschappen | A magnetic material with cooling capacity, a method for the manufacturing thereof and use of such material |
JP2005015911A (ja) * | 2003-03-28 | 2005-01-20 | Toshiba Corp | 複合磁性材料及びその製造方法 |
JP2005120391A (ja) * | 2003-10-14 | 2005-05-12 | Hitachi Metals Ltd | 磁性材料の製造方法 |
JP2007291437A (ja) * | 2006-04-24 | 2007-11-08 | Hitachi Metals Ltd | 磁気冷凍作業ベッド用の焼結体およびその製造方法 |
Family Cites Families (62)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US364631A (en) * | 1887-06-14 | bey an | ||
US364540A (en) * | 1887-06-07 | Burglar-alarm | ||
GB655088A (en) | 1945-12-19 | 1951-07-11 | Constantin Chilowsky | Method and apparatus for producing electrical and mechanical energy from thermal energy |
US2589775A (en) | 1948-10-12 | 1952-03-18 | Technical Assets Inc | Method and apparatus for refrigeration |
US4332135A (en) * | 1981-01-27 | 1982-06-01 | The United States Of America As Respresented By The United States Department Of Energy | Active magnetic regenerator |
JPS60204852A (ja) * | 1984-03-30 | 1985-10-16 | Tokyo Inst Of Technol | 磁気冷凍用磁性材料 |
JPS60260468A (ja) * | 1984-06-07 | 1985-12-23 | ティーディーケイ株式会社 | 複合感温フエライト材料 |
JP2582753B2 (ja) * | 1986-04-15 | 1997-02-19 | 巍洲 橋本 | 積層磁性体の製造方法 |
US4702090A (en) * | 1986-10-24 | 1987-10-27 | Astronautics Corporation Of America | Magnetic refrigeration apparatus with conductive heat transfer |
DE3800098A1 (de) * | 1987-09-25 | 1989-07-13 | Heinz Munk | Magnetokalorischer induktor mit kompensationskern fuer die erzeugung elektrischer energie |
US6758046B1 (en) * | 1988-08-22 | 2004-07-06 | Astronautics Corporation Of America | Slush hydrogen production method and apparatus |
US5332029A (en) * | 1992-01-08 | 1994-07-26 | Kabushiki Kaisha Toshiba | Regenerator |
US5249424A (en) * | 1992-06-05 | 1993-10-05 | Astronautics Corporation Of America | Active magnetic regenerator method and apparatus |
DE4242642C2 (de) * | 1992-12-17 | 1996-10-17 | Deutsche Forsch Luft Raumfahrt | Wärmepumpverfahren sowie Wärmepumpe, insbesondere zur Erzeugung kryogener Temperaturen |
JPH0745411A (ja) * | 1993-07-26 | 1995-02-14 | Fuji Elelctrochem Co Ltd | ペロブスカイト型複合酸化物磁性材料、それを用いた温度スイッチ及び温度変化検出素子 |
US5887449A (en) * | 1996-07-03 | 1999-03-30 | Iowa State University Research Foundation, Inc. | Dual stage active magnetic regenerator and method |
US5893275A (en) * | 1997-09-04 | 1999-04-13 | In-X Corporation | Compact small volume liquid oxygen production system |
US5934078A (en) * | 1998-02-03 | 1999-08-10 | Astronautics Corporation Of America | Reciprocating active magnetic regenerator refrigeration apparatus |
JP2000020937A (ja) * | 1998-07-03 | 2000-01-21 | Hitachi Ltd | 磁気記録媒体およびこれを用いた磁気記憶装置 |
WO2000038831A1 (en) * | 1998-12-31 | 2000-07-06 | Hexablock, Inc. | Magneto absorbent |
US7114340B2 (en) | 2000-03-08 | 2006-10-03 | Iowa State University Research Foundation, Inc. | Method of making active magnetic refrigerant materials based on Gd-Si-Ge alloys |
US6589366B1 (en) * | 2000-03-08 | 2003-07-08 | Iowa State University Research Foundation, Inc. | Method of making active magnetic refrigerant, colossal magnetostriction and giant magnetoresistive materials based on Gd-Si-Ge alloys |
US6293106B1 (en) * | 2000-05-18 | 2001-09-25 | Praxair Technology, Inc. | Magnetic refrigeration system with multicomponent refrigerant fluid forecooling |
DE60128361T2 (de) * | 2000-08-09 | 2008-01-17 | Astronautics Corp. Of America, Milwaukee | Magnetisches kältegerät mit drehbett |
US6676772B2 (en) * | 2001-03-27 | 2004-01-13 | Kabushiki Kaisha Toshiba | Magnetic material |
JP4622179B2 (ja) * | 2001-07-16 | 2011-02-02 | 日立金属株式会社 | 磁気冷凍作業物質および蓄冷式熱交換器ならびに磁気冷凍装置 |
US6502404B1 (en) * | 2001-07-31 | 2003-01-07 | Praxair Technology, Inc. | Cryogenic rectification system using magnetic refrigeration |
JP3967572B2 (ja) * | 2001-09-21 | 2007-08-29 | 株式会社東芝 | 磁気冷凍材料 |
US6453677B1 (en) * | 2002-04-05 | 2002-09-24 | Praxair Technology, Inc. | Magnetic refrigeration cryogenic vessel system |
US20030154865A1 (en) * | 2002-10-16 | 2003-08-21 | Zornes David A. | Nano coupling magnetoadsorbent |
TW575158U (en) * | 2003-03-20 | 2004-02-01 | Ind Tech Res Inst | Heat transfer structure for magnetic heat energy |
US7168255B2 (en) * | 2003-03-28 | 2007-01-30 | Kabushiki Kaisha Toshiba | Magnetic composite material and method for producing the same |
US20040261420A1 (en) * | 2003-06-30 | 2004-12-30 | Lewis Laura J. Henderson | Enhanced magnetocaloric effect material |
JP2005090921A (ja) * | 2003-09-19 | 2005-04-07 | Canon Inc | 磁性体を用いた温度調節装置 |
US7988947B2 (en) * | 2004-11-23 | 2011-08-02 | E. I. Du Pont De Nemours And Company | Mesoporous oxide of titanium |
US7601327B2 (en) * | 2004-11-23 | 2009-10-13 | E.I. Du Pont De Nemours And Company | Mesoporous oxide of hafnium |
US20060263291A1 (en) * | 2004-11-23 | 2006-11-23 | Carmine Torardi | Mesoporous amorphous oxide of titanium |
US7601326B2 (en) * | 2004-11-23 | 2009-10-13 | E. I. Du Pont De Nemours And Company | Mesoporous oxide of zirconium |
US7578892B2 (en) * | 2005-03-31 | 2009-08-25 | Hitachi Metals, Ltd. | Magnetic alloy material and method of making the magnetic alloy material |
EP1736717A1 (en) | 2005-06-20 | 2006-12-27 | Haute Ecole d'Ingénieurs et de Gestion du Canton | Continuously rotary magnetic refrigerator and heat pump and process for magnetic heating and/or cooling with such a refrigerator or heat pump |
DE112006001628B4 (de) * | 2005-06-27 | 2011-06-16 | Japan Science And Technology Agency, Kawaguchi | Ferromagnetische Formgedächtnislegierung und deren Anwendung |
DE102006006326B4 (de) * | 2006-02-11 | 2007-12-06 | Bruker Biospin Ag | Hybrid-Wärmepumpe/Kältemaschine mit magnetischer Kühlstufe |
JP4481949B2 (ja) * | 2006-03-27 | 2010-06-16 | 株式会社東芝 | 磁気冷凍用磁性材料 |
JP4282707B2 (ja) * | 2006-09-29 | 2009-06-24 | 株式会社東芝 | 合金および磁気冷凍材料粒子の製造方法 |
CN102637886B (zh) * | 2006-12-16 | 2014-10-15 | 克里斯多佛·J·帕皮雷 | 由碳氢化合物沉积物发电同时捕获二氧化碳 |
JP2010516042A (ja) * | 2007-02-12 | 2010-05-13 | ヴァキュームシュメルツェ ゲーエムベーハー ウント コンパニー カーゲー | 磁気熱交換用構造体及びその製造方法 |
GB2459066B (en) * | 2007-02-12 | 2012-02-15 | Vacuumschmelze Gmbh & Co Kg | Article for magnetic heat exchange and method of manufacturing the same |
JP4987514B2 (ja) * | 2007-03-08 | 2012-07-25 | 株式会社東芝 | 磁気冷凍材料、及び磁気冷凍装置 |
JP2008270677A (ja) * | 2007-04-25 | 2008-11-06 | National Institute For Materials Science | ドープド・ペロブスカイト・マンガナイト単結晶を用いた巨大異方性磁気抵抗素子 |
US20080276623A1 (en) * | 2007-05-11 | 2008-11-13 | Naushad Ali | Magnetic refrigerant material |
US8104293B2 (en) | 2007-06-19 | 2012-01-31 | General Electric Company | Magneto-caloric cooling device and method of operation |
WO2009090442A1 (en) * | 2007-12-27 | 2009-07-23 | Vacuumschmelze Gmbh & Co. Kg | Composite article with magnetocalorically active material and method for its production |
JP4950918B2 (ja) * | 2008-02-28 | 2012-06-13 | 株式会社東芝 | 磁気冷凍装置用磁性材料、熱交換容器および磁気冷凍装置 |
JP4643668B2 (ja) | 2008-03-03 | 2011-03-02 | 株式会社東芝 | 磁気冷凍デバイスおよび磁気冷凍システム |
TW201003024A (en) * | 2008-04-28 | 2010-01-16 | Basf Se | Open-cell porous shaped bodies for heat exchangers |
GB2490820B (en) * | 2008-05-16 | 2013-03-27 | Vacuumschmelze Gmbh & Co Kg | Article for magnetic heat exchange and methods for manufacturing an article for magnetic heat exchange |
JP4703699B2 (ja) * | 2008-09-04 | 2011-06-15 | 株式会社東芝 | 磁気冷凍用磁性材料、磁気冷凍デバイスおよび磁気冷凍システム |
FR2936364B1 (fr) * | 2008-09-25 | 2010-10-15 | Cooltech Applications | Element magnetocalorique |
US9739510B2 (en) * | 2009-09-17 | 2017-08-22 | Charles N. Hassen | Flow-synchronous field motion refrigeration |
US20110154832A1 (en) * | 2009-12-29 | 2011-06-30 | General Electric Company | Composition and method for producing the same |
US9702594B2 (en) * | 2010-06-07 | 2017-07-11 | Aip Management, Llc | Magnetocaloric refrigerator |
JP5449104B2 (ja) * | 2010-09-29 | 2014-03-19 | 株式会社東芝 | 熱交換容器ユニット、および熱サイクルユニット |
-
2010
- 2010-07-29 WO PCT/EP2010/061025 patent/WO2011018347A1/de active Application Filing
- 2010-07-29 AU AU2010283855A patent/AU2010283855A1/en not_active Abandoned
- 2010-07-29 KR KR1020177011939A patent/KR20170054541A/ko not_active Application Discontinuation
- 2010-07-29 CN CN201080042428.2A patent/CN102511067B/zh not_active Expired - Fee Related
- 2010-07-29 JP JP2012524183A patent/JP2013502061A/ja active Pending
- 2010-07-29 EP EP16185963.2A patent/EP3128520B1/de not_active Not-in-force
- 2010-07-29 BR BR112012003125A patent/BR112012003125A2/pt not_active IP Right Cessation
- 2010-07-29 KR KR1020127006318A patent/KR101789341B1/ko active IP Right Grant
- 2010-07-29 JP JP2012524182A patent/JP2013501910A/ja active Pending
- 2010-07-29 KR KR1020177018047A patent/KR101848592B1/ko active IP Right Grant
- 2010-07-29 WO PCT/EP2010/061026 patent/WO2011018348A2/de active Application Filing
- 2010-07-29 KR KR1020127006314A patent/KR20120053033A/ko not_active Application Discontinuation
- 2010-07-29 EP EP10737567.7A patent/EP2465118B1/de not_active Not-in-force
- 2010-07-29 RU RU2012108924/07A patent/RU2012108924A/ru not_active Application Discontinuation
- 2010-07-29 CN CN201080042427.8A patent/CN102549679B/zh not_active Expired - Fee Related
- 2010-07-29 RU RU2012108925/07A patent/RU2012108925A/ru not_active Application Discontinuation
- 2010-07-29 BR BR112012003133A patent/BR112012003133A2/pt not_active IP Right Cessation
- 2010-07-29 CA CA2770862A patent/CA2770862A1/en not_active Abandoned
- 2010-07-29 EP EP10737904.2A patent/EP2465119B2/de not_active Not-in-force
- 2010-08-04 TW TW099125986A patent/TW201111731A/zh unknown
- 2010-08-05 US US12/850,891 patent/US9147511B2/en not_active Expired - Fee Related
- 2010-08-09 US US12/852,813 patent/US8763407B2/en not_active Expired - Fee Related
- 2010-08-10 TW TW099126666A patent/TW201120387A/zh unknown
-
2015
- 2015-07-30 US US14/813,351 patent/US20150330721A1/en not_active Abandoned
- 2015-10-16 JP JP2015204260A patent/JP2016040512A/ja active Pending
-
2016
- 2016-03-22 JP JP2016057061A patent/JP6185621B2/ja not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004068512A1 (en) * | 2003-01-29 | 2004-08-12 | Stichting Voor De Technische Wetenschappen | A magnetic material with cooling capacity, a method for the manufacturing thereof and use of such material |
JP2006514158A (ja) * | 2003-01-29 | 2006-04-27 | スティッチング ヴォール デ テクニッシェ ヴェッテンシャッペン | 冷却容量を有する磁気材料、当該材料の製造方法および当該材料の使用方法 |
JP2005015911A (ja) * | 2003-03-28 | 2005-01-20 | Toshiba Corp | 複合磁性材料及びその製造方法 |
JP2005120391A (ja) * | 2003-10-14 | 2005-05-12 | Hitachi Metals Ltd | 磁性材料の製造方法 |
JP2007291437A (ja) * | 2006-04-24 | 2007-11-08 | Hitachi Metals Ltd | 磁気冷凍作業ベッド用の焼結体およびその製造方法 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016514360A (ja) * | 2013-01-24 | 2016-05-19 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 材料配列の最適化による磁気熱量カスケードの性能改良 |
JP2015149464A (ja) * | 2014-02-05 | 2015-08-20 | 株式会社三徳 | 磁気冷凍デバイスおよび磁気冷凍システム |
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6185621B2 (ja) | 熱磁気材料からなる熱交換器床 | |
JP5713889B2 (ja) | 熱交換器用の連続気泡多孔性成型物 | |
US9915447B2 (en) | Performance improvement of magnetocaloric cascades through optimized material arrangement | |
JP5793074B2 (ja) | 熱磁気発生機 | |
JP6285463B2 (ja) | 材料配列の最適化による磁気熱量カスケードの性能改良 | |
KR20190028473A (ko) | 코발트, 망간, 붕소 및 탄소를 함유하는 물질을 포함하는 자기열량 축열기 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130726 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20130726 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140304 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20140527 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20140603 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20140626 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20140703 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20140724 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20140731 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140827 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20140828 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20150106 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20150406 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20150501 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150508 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20150605 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150706 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20151124 |