JP2010111652A - 抗菌性組成物および抗菌性織物の加工方法 - Google Patents
抗菌性組成物および抗菌性織物の加工方法 Download PDFInfo
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- 239000000203 mixture Substances 0.000 title claims abstract description 86
- 239000004744 fabric Substances 0.000 title claims abstract description 73
- 230000000845 anti-microbial effect Effects 0.000 title claims abstract description 49
- 238000000034 method Methods 0.000 title claims abstract description 40
- 238000012545 processing Methods 0.000 title claims abstract description 28
- 239000003223 protective agent Substances 0.000 claims abstract description 56
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 claims abstract description 44
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 230000000844 anti-bacterial effect Effects 0.000 claims description 124
- 238000002845 discoloration Methods 0.000 claims description 35
- 238000003672 processing method Methods 0.000 claims description 21
- 239000004753 textile Substances 0.000 claims description 19
- 239000000835 fiber Substances 0.000 claims description 15
- 238000012360 testing method Methods 0.000 claims description 15
- 229910052709 silver Inorganic materials 0.000 claims description 14
- 239000004332 silver Substances 0.000 claims description 13
- 230000008569 process Effects 0.000 claims description 10
- -1 silver ions Chemical class 0.000 claims description 8
- 239000002759 woven fabric Substances 0.000 claims description 7
- 239000004840 adhesive resin Substances 0.000 claims description 6
- 229920006223 adhesive resin Polymers 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- 238000004043 dyeing Methods 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 4
- 239000000853 adhesive Substances 0.000 claims description 2
- 230000001070 adhesive effect Effects 0.000 claims description 2
- 239000004599 antimicrobial Substances 0.000 abstract description 9
- 238000004383 yellowing Methods 0.000 description 19
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 14
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Substances [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 12
- 230000000694 effects Effects 0.000 description 10
- 235000019641 whiteness Nutrition 0.000 description 9
- 238000002474 experimental method Methods 0.000 description 7
- 229920000742 Cotton Polymers 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 230000001580 bacterial effect Effects 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 241000191967 Staphylococcus aureus Species 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000011990 functional testing Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 1
- 229940006461 iodide ion Drugs 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 230000017074 necrotic cell death Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000036561 sun exposure Effects 0.000 description 1
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
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- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/59—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with ammonia; with complexes of organic amines with inorganic substances
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Abstract
【解決手段】銀ナノ粒子、保護剤および水を含む抗菌性組成物。銀ナノ粒子の保護剤に対するモル比は1:0.995から1であり、保護剤はMCl、MBr、MI、MS2O3およびNH4OHからなる群から選択され、ここでMはIAまたはIIA族の元素を表す、2つの抗菌性織物の加工方法。
【選択図】図1
Description
Claims (20)
- 銀ナノ粒子、
保護剤、ここで銀ナノ粒子の保護剤に対するモル比は1:0.995から1であり、保護剤はMCl、MBr、MI、MS2O3およびNH4OHからなる群から選択され、MはIAまたはIIA族元素を表し、および
水を含む抗菌性組成物。 - 保護剤がMCl、MBr、MI、MS2O3およびNH4OHから選択される少なくとも2つ以上の成分を含む、請求項1に記載の抗菌性組成物。
- 抗菌性組成物中の銀ナノ粒子によって放出される遊離の活性銀イオン濃度が0から2ppmである、請求項1に記載の抗菌性組成物。
- 抗菌性組成物中の銀ナノ粒子濃度が30から100ppmである、請求項1に記載の抗菌性組成物。
- 低変色抗菌性織物の加工方法であって、
織物生地を用意し、
抗菌性組成物を準備し、
抗菌性組成物は銀ナノ粒子、
保護剤、ここで銀ナノ粒子の保護剤に対するモル比は1:0.995から1であり、保護剤はMCl、MBr、MI、MS2O3およびNH4OHからなる群から選択され、MはIAまたはIIA族元素を表し、および
水を含み、さらに、
抗菌性組成物を織物生地の表面に施す加工方法。 - 保護剤がMCl、MBr、MI、MS2O3およびNH4OHから選択される少なくとも2つ以上の成分を含む、請求項5に記載の低変色抗菌性織物の加工方法。
- 抗菌性組成物中の銀ナノ粒子によって放出される遊離の活性銀イオン濃度が0から2ppmである、請求項6に記載の低変色抗菌性織物の加工方法。
- 抗菌性組成物中の銀ナノ粒子濃度が30から100ppmである、請求項6に記載の低変色抗菌性織物の加工方法。
- 抗菌性組成物がさらに接着樹脂を2から5%の濃度で含む、請求項6に記載の低変色抗菌性織物の加工方法。
- 抗菌性組成物を織物生地の表面上に施す方法が浸染、コーティング、パディングまたは捺染を含む、請求項6に記載の低変色抗菌性織物の加工方法。
- さらに洗浄処理を行い、および
抗菌性機能試験処理を行う、請求項6に記載の低変色抗菌性織物の加工方法。 - さらに織物色度試験処理を行う、請求項6に記載の低変色抗菌性織物の加工方法。
- 低変色抗菌性織物の加工方法であって、
抗菌性組成物を準備し、
抗菌性組成物は銀ナノ粒子、
保護剤、ここで銀ナノ粒子の保護剤に対するモル比は1:0.995から1であり、保護剤はMCl、MBr、MI、MS2O3およびNH4OHからなる群から選択され、MはIAまたはIIA族元素を表し、および
水を含み、
織物繊維を用意し、および
抗菌性組成物を織物繊維の表面上に施す加工方法。 - 保護剤がMCl、MBr、MI、MS2O3およびNH4OHから選択される少なくとも2つ以上の成分を含む、請求項13に記載の低変色抗菌性織物の加工方法。
- 抗菌性組成物中の銀ナノ粒子によって放出される遊離の活性銀イオン濃度が0から2ppmである、請求項13に記載の低変色抗菌性織物の加工方法。
- 抗菌性組成物中の銀ナノ粒子濃度が30から100ppmである、請求項13に記載の低変色抗菌性織物の加工方法。
- 抗菌性組成物がさらに接着剤を2から5%の濃度で含む、請求項13に記載の低変色抗菌性織物の加工方法。
- 抗菌性組成物を織物繊維の表面上に施す方法が浸染、コーティング、パディングまたは捺染を含む、請求項13に記載の低変色抗菌性織物の加工方法。
- さらに洗浄処理を行い、および
抗菌性機能試験処理を行う、請求項13に記載の低変色抗菌性織物の加工方法。 - さらに織物色度試験処理を行う、請求項13に記載の低変色抗菌性織物の加工方法。
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US8293267B2 (en) * | 2009-06-12 | 2012-10-23 | AG Biotech, LLC | Method for preparing an antimicrobial cotton of cellulose matrix having chemically and/or physically bonded silver and antimicrobial cotton prepared therefrom |
CN102669179B (zh) * | 2012-05-30 | 2014-03-12 | 北京崇高纳米科技有限公司 | 一种抗菌抗病毒处理剂及其制备方法与它的用途 |
US9332855B2 (en) | 2014-03-13 | 2016-05-10 | John Robert BAXTER | Personal cellular tissue repair, recovery and regeneration enhancement sleep system |
CN105127072A (zh) * | 2015-07-31 | 2015-12-09 | 浙江宇立新材料有限公司 | 一种高清高反光投影幕布的生产工艺 |
IT202000016534A1 (it) * | 2020-07-08 | 2022-01-08 | Carteria S R L | Procedimento di trattamento di un prodotto con una miscela di inchiostro alimentare e particelle di argento e prodotto così ottenuto |
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US20100112884A1 (en) | 2010-05-06 |
TW201018761A (en) | 2010-05-16 |
US8414659B2 (en) | 2013-04-09 |
TWI388706B (zh) | 2013-03-11 |
JP5323470B2 (ja) | 2013-10-23 |
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