JP2009518526A - 歪み応答性粘稠液体ポリマーを有する多軸布帛 - Google Patents
歪み応答性粘稠液体ポリマーを有する多軸布帛 Download PDFInfo
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/24—Resistant to mechanical stress, e.g. pierce-proof
- A41D31/245—Resistant to mechanical stress, e.g. pierce-proof using layered materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/12—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by the relative arrangement of fibres or filaments of different layers, e.g. the fibres or filaments being parallel or perpendicular to each other
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F41—WEAPONS
- F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
- F41H5/00—Armour; Armour plates
- F41H5/02—Plate construction
- F41H5/04—Plate construction composed of more than one layer
- F41H5/0471—Layered armour containing fibre- or fabric-reinforced layers
- F41H5/0485—Layered armour containing fibre- or fabric-reinforced layers all the layers being only fibre- or fabric-reinforced layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0261—Polyamide fibres
- B32B2262/0269—Aromatic polyamide fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2571/00—Protective equipment
- B32B2571/02—Protective equipment defensive, e.g. armour plates, anti-ballistic clothing
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24058—Structurally defined web or sheet [e.g., overall dimension, etc.] including grain, strips, or filamentary elements in respective layers or components in angular relation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2369—Coating or impregnation improves elasticity, bendability, resiliency, flexibility, or shape retention of the fabric
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2615—Coating or impregnation is resistant to penetration by solid implements
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2615—Coating or impregnation is resistant to penetration by solid implements
- Y10T442/2623—Ballistic resistant
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- Aiming, Guidance, Guns With A Light Source, Armor, Camouflage, And Targets (AREA)
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- Nonwoven Fabrics (AREA)
- Professional, Industrial, Or Sporting Protective Garments (AREA)
Abstract
Description
第2の方向に実質的に平行で第1の糸に対して斜行しまたは片寄っている複数の第2の糸を含んでなる第2の層、および
層内で横断的に交絡し層をまとめる横断糸
を含んでなり、各層が約−40〜約0℃の範囲内のTg、および20℃で約2×106〜約1013ポアズのゼロ剪断粘度を有する高粘度ポリマーで被覆される、多軸布帛が提供される。
第1の方向に実質的に平行である複数の第1の糸を含んでなる第1の層、
第2の方向に実質的に平行で第1の糸に対して斜行しまたは片寄っている複数の第2の糸を含んでなる第2の層、および
層内で横断的に交絡し層をまとめる横断糸
を含んでなり、各層が約−40〜約0℃の範囲内であるTg、および20℃で約2×106〜約1013ポアズのゼロ剪断粘度を有する高粘度ポリマーで被覆される、多軸布帛に関する。
比較例1では、E.I.デュポン・ドゥ・ヌムール・アンド・カンパニー(E.I.du Pont de Nemours and Company)から登録商標ケブラー(Kevlar)(登録商標)129の下に入手できる、フィラメントあたり線密度が1.66dtexである、930dtexの高引張り強さポリ(p−フェニレンテレフタルアミド)連続フィラメント糸から多軸布帛の層が作られる。布帛の各層は、異なる角度で配列され、低デニールおよび低引張り強さのループ形成ポリエチレン糸の組によって共に結合される、1インチあたり18末端の4組の平行糸で構築される。各多軸布帛層の面密度は約0.27kg/m2である。多軸布帛で使用される4組の糸の引張り強さは24.3グラム/dtexであり、繊維密度は1.44グラム/cm3である。多軸布帛層は安定性が良くない。多軸布帛層中の糸は、鋭器の貫通によって歪んで押しのけられる。約15”×15”サイズの17層の多軸布帛を縁周辺で縫い合わせて、千鳥掛けして総面密度約4.6kg/m2の複合構造を形成する。次にレベルIIのためのNIJ防弾基準0101.04による357マグナム銃弾に対して、アセンブリーを防弾V50および背面変形の双方について試験する。結果、特に実施例の複合構造の背面変形は、布帛層の低い構造安定性のために不良であることが予期される。
本発明の実施例1では、E.I.デュポン・ドゥ・ヌムール・アンド・カンパニー(E.I.du Pont de Nemours and Company)から登録商標ケブラー(Kevlar)(登録商標)129の下に入手できる、フィラメントあたり線密度が1.66dtexである、930dtexの高引張り強さポリ(p−フェニレンテレフタルアミド)連続フィラメント糸から多軸布帛の層が作られる。布帛の各層は、異なる角度で配列され、低デニールおよび低引張り強さのループ形成ポリエチレン糸の組によって共に結合される、1インチあたり18末端の4組の平行糸で構築される。各多軸布帛層の面密度は約0.27kg/m2である。多軸布帛で使用される4組の糸の引張り強さは24.3グラム/dtexであり、繊維密度は1.44グラム/cm3である。−40℃〜約10℃の範囲内のTgを有して、20℃におけるゼロ剪断溶融粘度が2×106〜約1013ポアズであり、分子量が約20,000〜100,000である、約5重量%の高粘度ポリマーで、多軸布帛層をさらに被覆する。被覆された各多軸布帛層の面密度は、約0.284kg/m2である。本発明の多軸布帛層の構造安定性は、非常に良好である。
Claims (20)
- 第1の方向に実質的に平行である複数の第1の糸を含んでなる第1の層、
第2の方向に実質的に平行で第1の糸に対して斜行しまたは片寄っている複数の第2の糸を含んでなる第2の層、および
層内で横断的に交絡し層をまとめる横断糸
を含んでなり、各層が約−40〜約0℃の範囲内のTg、および20℃で約2×106〜約1013ポアズのゼロ剪断粘度を有する高粘度ポリマーで被覆される多軸布帛。 - 少なくとも1つの複数の糸がアラミド繊維を含んでなる請求項1に記載の布帛。
- 少なくとも1つの複数の糸がポリビスピリダゾール繊維を含んでなる請求項1に記載の布帛。
- ポリビスピリダゾールがポリ[2,6−ジイミダゾ[4,5−b:4,5−e]−ピリジニレン−1,4(2,5−ジヒドロキシ)フェニレン)である請求項3に記載の布帛。
- 高粘度ポリマーが、1つもしくはそれ以上のシアノアクリレート接着剤、ウレタン接着剤、脂肪族アミンエポキシ樹脂、芳香族アミンエポキシ樹脂、ポリ(ビニルプロピオネート)、ポリ(ヘキシルメタクリレート)、ポリ(イソプロピルアクリレート)、およびエチレン/メチルアクリレート共重合体である請求項1に記載の布帛。
- 高粘度ポリマーが、1つもしくはそれ以上のシアノアクリレート接着剤、ウレタン接着剤、脂肪族アミンエポキシ樹脂、芳香族アミンエポキシ樹脂、ポリ(ビニルプロピオネート)、ポリ(ヘキシルメタクリレート)、ポリ(イソプロピルアクリレート)、およびエチレン/メチルアクリレート共重合体である請求項4に記載の布帛。
- 横断糸が、ポリエステル、ポリエチレン、ポリアミド、アラミド、ポリアレーンアゾール、ポリピリダゾール、またはポリピリドビスイミダゾールの繊維を含んでなる請求項1に記載の布帛。
- 第3の方向に実質的に平行で第1の糸および第2の糸に対して斜行しまたは片寄っている複数の第3の糸を含んでなる第3の糸層をさらに含んでなる請求項1に記載の布帛。
- 少なくとも1つの複数の糸がアラミド繊維を含んでなる請求項8に記載の布帛。
- 少なくとも1つの複数の糸がポリビスピリダゾール繊維を含んでなる請求項8に記載の布帛。
- ポリビスピリダゾールがポリ[2,6−ジイミダゾ[4,5−b:4,5−e]−ピリジニレン−1,4(2,5−ジヒドロキシ)フェニレン)である請求項10に記載の布帛。
- 高粘度ポリマーが、1つもしくはそれ以上のシアノアクリレート接着剤、ウレタン接着剤、脂肪族アミンエポキシ樹脂、芳香族アミンエポキシ樹脂、ポリ(ビニルプロピオネート)、ポリ(ヘキシルメタクリレート)、ポリ(イソプロピルアクリレート)、およびエチレン/メチルアクリレート共重合体である請求項8に記載の布帛。
- 第4の方向に実質的に平行で、第1、第2、および第3の糸に対して斜行しまたは片寄っている複数の第4の糸を含んでなる第4の糸層をさらに含んでなる請求項8に記載の布帛。
- 少なくとも1つの複数の糸がアラミド繊維を含んでなる請求項13に記載の布帛。
- 少なくとも1つの複数の糸がポリビスピリダゾール繊維を含んでなる請求項13に記載の布帛。
- ポリビスピリダゾールがポリ[2,6−ジイミダゾ[4,5−b:4,5−e]−ピリジニレン−1,4(2,5−ジヒドロキシ)フェニレン)である請求項15に記載の布帛。
- 高粘度ポリマーが、1つもしくはそれ以上のシアノアクリレート接着剤、ウレタン接着剤、脂肪族アミンエポキシ樹脂、芳香族アミンエポキシ樹脂、ポリ(ビニルプロピオネート)、ポリ(ヘキシルメタクリレート)、ポリ(イソプロピルアクリレート)、およびエチレン/メチルアクリレート共重合体である請求項13に記載の布帛。
- 請求項1に記載の布帛を含んでなる被服。
- 請求項1に記載の布帛を含んでなる物品。
- 第1の方向に実質的に平行である複数の第1の糸を含んでなる第1の層と、第2の方向に実質的に平行で第1の糸に対して斜行しまたは片寄っている複数の第2の糸を含んでなる第2の層とを接触させるステップと、
糸を層に横断的に交絡して多軸布帛を形成するステップと
を含んでなり、各層が約−40〜約0℃の範囲内のTg、および20℃で約2×106〜約1013ポアズのゼロ剪断粘度を有する高粘度ポリマーで被覆される布帛の製造方法。
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US74914705P | 2005-12-08 | 2005-12-08 | |
US60/749,147 | 2005-12-08 | ||
PCT/US2006/061739 WO2007067950A1 (en) | 2005-12-08 | 2006-12-07 | Multiaxial fabric with strain-responsive viscous liquid polymers |
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JP2009518526A5 JP2009518526A5 (ja) | 2010-01-28 |
JP5102775B2 JP5102775B2 (ja) | 2012-12-19 |
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JP (1) | JP5102775B2 (ja) |
KR (1) | KR101337052B1 (ja) |
CN (1) | CN101321618B (ja) |
BR (1) | BRPI0620574A2 (ja) |
CA (1) | CA2630153A1 (ja) |
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Cited By (2)
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JP2011504940A (ja) * | 2007-08-01 | 2011-02-17 | ハネウェル・インターナショナル・インコーポレーテッド | 硬質防護製品のための複合弾道布帛構造物 |
JP2014532162A (ja) * | 2011-09-06 | 2014-12-04 | ハネウェル・インターナショナル・インコーポレーテッド | 剛性構造及び低背面衝撃痕の防弾ud/物品及びその製造方法 |
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CN101325887B (zh) * | 2005-12-08 | 2011-05-18 | 纳幕尔杜邦公司 | 防弹用多轴向纺织品 |
US8166569B1 (en) * | 2006-11-29 | 2012-05-01 | E. I. Du Pont De Nemours And Company | Multiaxial polyethylene fabric and laminate |
BR112013017815B1 (pt) | 2011-01-12 | 2020-05-12 | Compagnie Chomarat | Estruturas de compósito laminado e métodos para fabricar e usar as mesmas |
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Also Published As
Publication number | Publication date |
---|---|
CA2630153A1 (en) | 2007-06-14 |
KR20080081957A (ko) | 2008-09-10 |
KR101337052B1 (ko) | 2013-12-05 |
US8171569B2 (en) | 2012-05-08 |
CN101321618A (zh) | 2008-12-10 |
JP5102775B2 (ja) | 2012-12-19 |
WO2007067950A1 (en) | 2007-06-14 |
EP1965975B1 (en) | 2015-11-11 |
CN101321618B (zh) | 2012-07-18 |
EP1965975A1 (en) | 2008-09-10 |
BRPI0620574A2 (pt) | 2011-11-16 |
US20090136706A1 (en) | 2009-05-28 |
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