JP2009068324A5 - - Google Patents
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- JP2009068324A5 JP2009068324A5 JP2008083902A JP2008083902A JP2009068324A5 JP 2009068324 A5 JP2009068324 A5 JP 2009068324A5 JP 2008083902 A JP2008083902 A JP 2008083902A JP 2008083902 A JP2008083902 A JP 2008083902A JP 2009068324 A5 JP2009068324 A5 JP 2009068324A5
- Authority
- JP
- Japan
- Prior art keywords
- coating material
- layer
- antibacterial
- substance
- inorganic porous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000463 material Substances 0.000 claims description 123
- 239000011248 coating agent Substances 0.000 claims description 111
- 238000000576 coating method Methods 0.000 claims description 106
- 239000011148 porous material Substances 0.000 claims description 52
- 239000000126 substance Substances 0.000 claims description 46
- 230000000844 anti-bacterial Effects 0.000 claims description 41
- 239000011941 photocatalyst Substances 0.000 claims description 33
- 239000011230 binding agent Substances 0.000 claims description 29
- 239000010457 zeolite Substances 0.000 claims description 25
- 239000000383 hazardous chemical Substances 0.000 claims description 24
- 239000002131 composite material Substances 0.000 claims description 23
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 18
- OGIDPMRJRNCKJF-UHFFFAOYSA-N TiO Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 14
- 229910001929 titanium oxide Inorganic materials 0.000 claims description 14
- 230000001965 increased Effects 0.000 claims description 7
- 238000005342 ion exchange Methods 0.000 claims description 7
- 238000005336 cracking Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- 230000003197 catalytic Effects 0.000 claims description 2
- 231100000614 Poison Toxicity 0.000 claims 1
- 239000003440 toxic substance Substances 0.000 claims 1
- 239000010410 layer Substances 0.000 description 98
- 235000019645 odor Nutrition 0.000 description 29
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 23
- 239000007789 gas Substances 0.000 description 19
- 238000002156 mixing Methods 0.000 description 16
- 239000002994 raw material Substances 0.000 description 15
- 239000000843 powder Substances 0.000 description 13
- 239000000835 fiber Substances 0.000 description 11
- 239000005909 Kieselgur Substances 0.000 description 9
- 239000004566 building material Substances 0.000 description 8
- AXCZMVOFGPJBDE-UHFFFAOYSA-L Calcium hydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 7
- 239000000920 calcium hydroxide Substances 0.000 description 7
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 7
- 235000011116 calcium hydroxide Nutrition 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 239000004568 cement Substances 0.000 description 7
- 238000000354 decomposition reaction Methods 0.000 description 7
- 229910052680 mordenite Inorganic materials 0.000 description 7
- 239000011505 plaster Substances 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 238000010276 construction Methods 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 230000002829 reduced Effects 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 description 5
- 239000004113 Sepiolite Substances 0.000 description 5
- 239000003610 charcoal Substances 0.000 description 5
- 238000003795 desorption Methods 0.000 description 5
- TUKQLEWOUPCTOS-UHFFFAOYSA-N dimagnesium;dioxido(oxo)silane;hydroxy-oxido-oxosilane;hydrate Chemical compound O.[Mg+2].[Mg+2].O[Si]([O-])=O.O[Si]([O-])=O.[O-][Si]([O-])=O TUKQLEWOUPCTOS-UHFFFAOYSA-N 0.000 description 5
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 description 5
- 229920002620 polyvinyl fluoride Polymers 0.000 description 5
- 229910052624 sepiolite Inorganic materials 0.000 description 5
- 235000019355 sepiolite Nutrition 0.000 description 5
- 239000000741 silica gel Substances 0.000 description 5
- 229910002027 silica gel Inorganic materials 0.000 description 5
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L Calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- 229910001583 allophane Inorganic materials 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000010419 fine particle Substances 0.000 description 4
- 239000010440 gypsum Substances 0.000 description 4
- 229910052602 gypsum Inorganic materials 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 238000002336 sorption--desorption measurement Methods 0.000 description 4
- 239000002023 wood Substances 0.000 description 4
- PZZYQPZGQPZBDN-UHFFFAOYSA-N Aluminium silicate Chemical group O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 3
- 229920000049 Carbon (fiber) Polymers 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive Effects 0.000 description 3
- 239000003242 anti bacterial agent Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000011362 coarse particle Substances 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 230000003993 interaction Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000011120 plywood Substances 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- -1 shirasu Chemical compound 0.000 description 3
- 230000001629 suppression Effects 0.000 description 3
- 229960003563 Calcium Carbonate Drugs 0.000 description 2
- JHLNERQLKQQLRZ-UHFFFAOYSA-N Calcium silicate Chemical compound [Ca+2].[Ca+2].[O-][Si]([O-])([O-])[O-] JHLNERQLKQQLRZ-UHFFFAOYSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 229940113118 Carrageenan Drugs 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 229940068984 Polyvinyl Alcohol Drugs 0.000 description 2
- 208000008842 Sick Building Syndrome Diseases 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N Silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 229940005550 Sodium alginate Drugs 0.000 description 2
- 229920002978 Vinylon Polymers 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229940009868 aluminum magnesium silicate Drugs 0.000 description 2
- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 description 2
- 229960000892 attapulgite Drugs 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000000378 calcium silicate Substances 0.000 description 2
- 229910052918 calcium silicate Inorganic materials 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 239000000679 carrageenan Substances 0.000 description 2
- 235000010418 carrageenan Nutrition 0.000 description 2
- 229920001525 carrageenan Polymers 0.000 description 2
- QBWCMBCROVPCKQ-UHFFFAOYSA-M chlorite Chemical group [O-]Cl=O QBWCMBCROVPCKQ-UHFFFAOYSA-M 0.000 description 2
- 229910052619 chlorite group Inorganic materials 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 229910001603 clinoptilolite Inorganic materials 0.000 description 2
- 230000003247 decreasing Effects 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- KARVSHNNUWMXFO-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane;hydrate Chemical compound O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O KARVSHNNUWMXFO-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 150000002484 inorganic compounds Chemical class 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052622 kaolinite Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 229910052901 montmorillonite Inorganic materials 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229910052625 palygorskite Inorganic materials 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 230000001699 photocatalysis Effects 0.000 description 2
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 2
- 238000009738 saturating Methods 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 229910000269 smectite group Inorganic materials 0.000 description 2
- MSXHSNHNTORCAW-UHFFFAOYSA-M sodium 3,4,5,6-tetrahydroxyoxane-2-carboxylate Chemical compound [Na+].OC1OC(C([O-])=O)C(O)C(O)C1O MSXHSNHNTORCAW-UHFFFAOYSA-M 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 230000001954 sterilising Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 238000009423 ventilation Methods 0.000 description 2
- 239000010455 vermiculite Substances 0.000 description 2
- 229910052902 vermiculite Inorganic materials 0.000 description 2
- 235000019354 vermiculite Nutrition 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 208000006673 Asthma Diseases 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241000257303 Hymenoptera Species 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 230000000172 allergic Effects 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000003373 anti-fouling Effects 0.000 description 1
- 230000000843 anti-fungal Effects 0.000 description 1
- 230000002421 anti-septic Effects 0.000 description 1
- 201000008937 atopic dermatitis Diseases 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 201000009910 diseases by infectious agent Diseases 0.000 description 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 230000002708 enhancing Effects 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 230000001678 irradiating Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910052813 nitrogen oxide Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 238000007539 photo-oxidation reaction Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000000717 retained Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000036962 time dependent Effects 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
Description
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Claims (4)
- è¡šé¢å¡æãšããŠã®æèã»æ害ç©å解æ§ç©è³ªãå«æãã第ïŒå±€å¡æãšãå é¢å¡æãšããŠã®åžçåžæŸæ¹¿èœãæããç¡æ©å€å質ç©è³ªãå«æãã第ïŒå±€å¡æãšããããªã建é ç©çšè€åå è£ å¡æã§ãã£ãŠã
第ïŒå±€å¡æäžã®ç¡æ©å€å質ç©è³ªã¯ãç©çåžçèœåã³ã€ãªã³äº€æèœãæãã现ç²ãšç²ç²ã®å€©ç¶ãŒãªã©ã€ãã®æ··åç©ãäž»æåãšãããã®ã§ãã建é ç©çšè€åå è£ å¡æã - 第ïŒå±€å¡æã¯ãæèã»æ害ç©å解æ§ç©è³ªãšããã€ã³ããŒãšããããªããã®ã§ãããåèšæèã»æ害ç©å解ç©è³ªã¯ã宀å ç §æã§è§Šåªæ©èœãçºæ®ããå¯èŠå å¿çåé žåãã¿ã³å 觊åªã§ããè«æ±é ïŒã«èšèŒã®å»ºé ç©çšè€åå è£ å¡æã
- 第ïŒå±€å¡æãæèã»æ害ç©å解æ§ç©è³ªãšããŠã®ç¡æ©è³ªæèæãå«æããè«æ±é ïŒèšèŒã®å»ºé ç©çšè€åå è£ å¡æã
- 第ïŒå±€å¡æäžã«å¯å¡æ§ãäžããŠã²ã³å²ããé²æ¢ããå¡æã®ç£šè匷床ãåäžãããããã®ãã€ã³ããŒãå«æããŠããè«æ±é ïŒèšèŒã®å»ºé ç©çšè€åå è£ å¡æã
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CN105113730B (zh) * | 2015-07-21 | 2018-03-20 | å¹³æ±å¿é¿å建çå·¥çšæéå ¬åž | é²è£ä¿è²é¶vocé¶æ³ç¢±æ°Žæ§å¹²ç²å»ºç圩è²æ¶æå€å¢æœå·¥æ¹æ³ |
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