JP2008545857A - ポリマーの使用による洗浄剤の清浄力向上 - Google Patents
ポリマーの使用による洗浄剤の清浄力向上 Download PDFInfo
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- JP2008545857A JP2008545857A JP2008515079A JP2008515079A JP2008545857A JP 2008545857 A JP2008545857 A JP 2008545857A JP 2008515079 A JP2008515079 A JP 2008515079A JP 2008515079 A JP2008515079 A JP 2008515079A JP 2008545857 A JP2008545857 A JP 2008545857A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Abstract
Description
に適合する4級化脂肪酸トリエタノールアミンエステル塩である。本発明の目的に使用し得るエステルクォートの典型的な例は、ヘキサン酸、オクタン酸、デカン酸、ラウリン酸、ミリスチン酸、パルミチン酸、イソステアリン酸、ステアリン酸、オレイン酸、エライジン酸、アラキジン酸、ベヘン酸、エルカ酸、並びにそれらの工業用混合物、例えば、天然の脂肪または油の高圧開裂で生じるようなものなど、に基づく生成物である。工業用C12/18ココナツ脂肪酸、および特に部分硬化したC16/18獸脂またはパーム脂肪酸、ならびにエライジン酸リッチC16/18脂肪酸カットを好ましく使用する。4級化エステルを調製するために、脂肪酸およびトリエタノールアミンを1.1:1〜3:1のモル比で通常使用し得る。エステルクォートの応用工学的特性に関して、1.2:1〜2.2:1、好ましくは1.5:1〜1.9:1の使用比が、特に有利であることが証明された。好ましく使用するエステルクォートは、1.5〜1.9の平均エステル化度を有するモノ−、ジ−およびトリ−エステルの工業用混合物に相当し、工業用C16/18獸脂またはパーム脂肪酸(ヨード価0〜40)から誘導される。R1COが、16〜18個の炭素原子を有するアシル基を意味し、R2がR1COを意味し、R3が水素原子であり、R4がメチル基であり、m、nおよびpがそれぞれ0であり、Xがメチルスルフェートを意味する式(I)の4級化脂肪酸トリエタノールアミンエステル塩が、特に有利であることが証明された。
のジエタノールアルキルアミンとの4級化エステル塩である。
スチレン、メタクリル酸、ヒドロキシエチルメタクリレートおよびメチルメタクリレートをラジカル重合させた。
洗浄機: Miele W 918 Novotronic
一次洗浄サイクル: 単一槽法、通常サイクル
洗浄温度: 40℃
測定: 3回
槽容積: 18リットル
水硬度: 16°ドイツ硬度(dH)
洗濯の量: 清潔な洗濯物3.5kg
織布: 綿(1.1.10)
汚れのない織布を、上記の条件で、ポリマーP1の添加の有無の場合で、洗浄剤(以下の組成を参照)を用いて3回洗浄し、各洗浄後に乾燥させた。3回の予備洗浄後、以下の汚れを用いて、手で織布を汚した。
黒い靴墨 0.10g
ほこり/皮脂 0.10g
FAEOS 5%
C12/14 7 EO 12%
APG 2%
C12−18 脂肪酸 5%
グリセロール 5%
Tinopal(登録商標)CBS−X 0.1%
クエン酸塩 1%
ポリアクリレート 2%
プロテアーゼ +
アミラーゼ +
水 100%まで
Claims (12)
- スチレン、メタクリル酸、ヒドロキシエチルメタクリレート、およびメチルメタクリレートのモノマーの重合によって得られる汚れ解離性ポリマーの、繊維製品を洗浄する際に洗浄剤の清浄性能を強化するための使用。
- スチレン、メタクリル酸、ヒドロキシエチルメタクリレート、およびメチルメタクリレートのモノマーの重合によって得られる汚れ解離性ポリマーの、汚れの付着前に、すでに前記ポリマーの存在下で洗浄および/または後処理された繊維製品を洗浄する際に、洗浄剤の清浄性能を強化するための使用。
- 繊維製品が綿製または綿を含有する、請求項1または2に記載の使用。
- 前記ポリマーが、1〜30mol%のスチレン、10〜40mol%のメチルメタクリレート、20〜60mol%のメタクリル酸および1〜20mol%のヒドロキシエチルメタクリレートの割合から得られる、請求項1〜3のいずれかに記載の使用。
- 前記ポリマーがブロックポリマーである、請求項1〜4のいずれかに記載の使用。
- スチレン、メタクリル酸、ヒドロキシエチルメタクリレート、およびメチルメタクリレートのモノマーの重合によって得られる汚れ解離性ポリマーと、ジカルボン酸、ならびにポリマージオール、またはモノマージオールとポリマージオールの混合物であってもよいジオールとのポリエステル活性汚れ解離性ポリマーとの組み合わせの、繊維製品を洗浄する際に洗浄剤の清浄性能を強化するための使用。
- スチレン、メタクリル酸、ヒドロキシエチルメタクリレート、およびメチルメタクリレートのモノマーの重合によって得られる前記ポリマーの平均分子量が、10000D未満、特に3000D〜8000Dである、請求項1〜6のいずれかに記載の使用。
- スチレン、メタクリル酸、ヒドロキシエチルメタクリレート、およびメチルメタクリレートのモノマーから得られる汚れ解離性ポリマーを含有する洗浄剤。
- 0.1重量%〜2重量%、特に0.4重量%〜1重量%の汚れ解離性ポリマーを含有する、請求項8に記載の剤。
- 汚れ解離性ポリマーを含有する粒子を、固体状で存在するさらなる洗浄剤成分と混合する、請求項8または9に記載の固形剤の製造方法。
- 噴霧乾燥工程を用いて、汚れ解離性ポリマーを含有する粒子を製造する、請求項10に記載の方法。
- 圧縮コンパウンド工程を用いて、汚れ解離性ポリマーを含有する粒子を製造する、請求項10に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102005026544.8 | 2005-06-08 | ||
DE102005026544A DE102005026544A1 (de) | 2005-06-08 | 2005-06-08 | Verstärkung der Reinigungsleistung von Waschmitteln durch Polymer |
PCT/EP2006/004750 WO2006131197A1 (de) | 2005-06-08 | 2006-05-19 | Verstärkung der reinigungsleistung von waschmittel durch polymer |
Publications (3)
Publication Number | Publication Date |
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JP2008545857A true JP2008545857A (ja) | 2008-12-18 |
JP2008545857A5 JP2008545857A5 (ja) | 2009-07-02 |
JP5113043B2 JP5113043B2 (ja) | 2013-01-09 |
Family
ID=36756679
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2008515079A Expired - Fee Related JP5113043B2 (ja) | 2005-06-08 | 2006-05-19 | ポリマーの使用による洗浄剤の清浄力向上 |
Country Status (8)
Country | Link |
---|---|
US (1) | US8034123B2 (ja) |
EP (1) | EP1888732B1 (ja) |
JP (1) | JP5113043B2 (ja) |
AT (1) | ATE461991T1 (ja) |
DE (2) | DE102005026544A1 (ja) |
ES (1) | ES2341672T3 (ja) |
PL (1) | PL1888732T3 (ja) |
WO (1) | WO2006131197A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007231262A (ja) * | 2006-01-31 | 2007-09-13 | Nippon Shokubai Co Ltd | (メタ)アクリル酸系共重合体、その製造方法およびこれを用いてなる洗剤組成物 |
JP2008542509A (ja) * | 2005-06-08 | 2008-11-27 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン | ポリマーによる洗濯洗浄剤の清浄力向上 |
Families Citing this family (5)
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US8383751B2 (en) * | 2011-06-29 | 2013-02-26 | Fina Technology, Inc. | High melt strength polystyrene and methods of making same |
DE102011112777A1 (de) * | 2011-09-09 | 2013-03-14 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Die Primärwaschkraft verbessernde polymere Wirkstoffe |
DE102012024440A1 (de) * | 2012-12-14 | 2014-06-18 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Die Primärwaschkraft verbessernde polymere Wirkstoffe |
DE102013207778A1 (de) | 2013-04-29 | 2014-10-30 | Cht R. Beitlich Gmbh | Kammpolymere als Waschkraftverstärker für Wasch- und Reinigungsmittel |
US9890350B2 (en) | 2015-10-28 | 2018-02-13 | Ecolab Usa Inc. | Methods of using a soil release polymer in a neutral or low alkaline prewash |
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- 2006-05-19 WO PCT/EP2006/004750 patent/WO2006131197A1/de not_active Application Discontinuation
- 2006-05-19 EP EP06742985A patent/EP1888732B1/de not_active Not-in-force
- 2006-05-19 DE DE502006006513T patent/DE502006006513D1/de active Active
- 2006-05-19 JP JP2008515079A patent/JP5113043B2/ja not_active Expired - Fee Related
- 2006-05-19 PL PL06742985T patent/PL1888732T3/pl unknown
- 2006-05-19 ES ES06742985T patent/ES2341672T3/es active Active
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2007
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JP2008542509A (ja) * | 2005-06-08 | 2008-11-27 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン | ポリマーによる洗濯洗浄剤の清浄力向上 |
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Also Published As
Publication number | Publication date |
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JP5113043B2 (ja) | 2013-01-09 |
US20080301883A1 (en) | 2008-12-11 |
ES2341672T3 (es) | 2010-06-24 |
EP1888732B1 (de) | 2010-03-24 |
EP1888732A1 (de) | 2008-02-20 |
PL1888732T3 (pl) | 2010-08-31 |
DE102005026544A1 (de) | 2006-12-14 |
ATE461991T1 (de) | 2010-04-15 |
WO2006131197A1 (de) | 2006-12-14 |
DE502006006513D1 (de) | 2010-05-06 |
US8034123B2 (en) | 2011-10-11 |
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