JP2008207535A - 化粧シートおよび化粧材 - Google Patents
化粧シートおよび化粧材 Download PDFInfo
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- JP2008207535A JP2008207535A JP2007107859A JP2007107859A JP2008207535A JP 2008207535 A JP2008207535 A JP 2008207535A JP 2007107859 A JP2007107859 A JP 2007107859A JP 2007107859 A JP2007107859 A JP 2007107859A JP 2008207535 A JP2008207535 A JP 2008207535A
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Abstract
【解決手段】 少なくとも絵柄インキ層と透明熱可塑性ポリエステル系樹脂層がこの順に積層されてなる化粧シートにおいて、該透明熱可塑性ポリエステル系樹脂層が少なくともポリ乳酸を含み、且つ、ガラス転移点が50℃以上90℃以下、引っ張り弾性率が2GPa以上3.5GPa以下、引っ張り破断伸び率が100%以上200%以下であることを特徴とする化粧シートを提供する。前記透明熱可塑性ポリエステル系樹脂層が、2軸延伸されたシートであることを特徴とする化粧シートを提供する。
【選択図】 図1
Description
トップコート層9:ウレタン系コート剤 9μm
透明熱可塑性ポリエステル系樹脂層1:ポリ乳酸樹脂(ガラス転移点58℃)100μm
ドライラミネート接着剤層5:ウレタン系2液硬化型 10μm
印刷インキ2,4:ウレタン系2液硬化型 0〜2μm
熱可塑性樹脂シート基材3:ポリ乳酸系ポリエステル樹脂 80μm
トップコート層9:ウレタン系コート剤 6μm
透明熱可塑性ポリエステル系樹脂層1:
2軸延伸ポリ乳酸樹脂(ガラス転移点58℃) 80μm
ドライラミネート接着剤層5:ウレタン系2液硬化型 10μm
印刷インキ2,4:ウレタン系2液硬化型 0〜2μm
熱可塑性樹脂シート基材:ポリプロピレン 70μm
透明熱可塑性樹脂としてガラス転移点が78℃、引っ張り弾性率2GPa、引っ張り破断伸び率が170%の厚さ100μmの無延伸の非晶性ポリエチレンテレフタレート樹脂を使用し、その他の材料および製造方法は実施例1同じ化粧シートを作成した。
トップコート層9:ウレタン系コート剤 9μm
透明熱可塑性ポリエステル系樹脂層1:
非晶性ポリエチレンテレフタレート樹脂 100μm
ドライラミネート接着剤層5:ウレタン系2液硬化型 10μm
印刷インキ2,4:ウレタン系2液硬化型 0〜2μm
熱可塑性樹脂シート基材3:ポリ乳酸系ポリエステル樹脂 80μm
透明熱可塑性樹脂としてガラス転移点が70℃、引っ張り弾性率4GPa、引っ張り破断伸び率が150%の厚さ80μmの2軸延伸ポリエチレンテレフタレート樹脂を使用し、その他の材料および製造方法は実施例2と同じ化粧シートを作成した。
トップコート層9:ウレタン系コート剤 6μm
透明熱可塑性ポリエステル系樹脂層1:
2軸延伸ポリエチレンテレフタレート樹脂 80μm
ドライラミネート接着剤層5:ウレタン系2液硬化型 10μm
印刷インキ2,4:ウレタン系2液硬化型 0〜2μm
熱可塑性樹脂シート基材:ポリプロピレン 70μm
透明熱可塑性樹脂としてガラス転移点が140℃、引っ張り弾性率0.8GPa、引っ張り破断伸び率が600%の厚さ80μmの無延伸ポリプロピレン樹脂を使用し、その他の材料および製造方法は実施例2と同じ化粧シートを作成した。
トップコート層9:ウレタン系コート剤 6μm
透明熱可塑性ポリエステル系樹脂層1:無延伸ポリプロピレン樹脂 80μm
ドライラミネート接着剤層5:ウレタン系2液硬化型 10μm
印刷インキ2,4:ウレタン系2液硬化型 0〜2μm
熱可塑性樹脂シート基材:ポリプロピレン 70μm
上記の実施例1と比較例1は厚さ9mmで端部が曲面R加工が施されたMDF基材に真空成形貼合した状態で、また実施例2と比較例2および比較例3は厚さ3mmのMDF板に貼合した化粧ボードの状態にして、化粧シートの評価を行った。
エンボス加工性:エンボス加工を施した化粧シートのエンボス形状を外観目視評価によりそのエンボス転写性を評価した。エンボス柄のエッジ形状まで転写されていれば○、エンボス柄のエッジ形状が転写されていないならば×とした。
成形性:実施例1および比較例1について、端部が曲面R加工が施されたMDF基材に真空成形貼合するときの成形加工の行い易さを、曲面Rに化粧シートが追従して皺や割れの発生がなければ○、曲面R部分に皺が発生したり、化粧シートの割れが発生したならば×とした。
寸法安定性:MDF基材またはMDF板に貼合した後の化粧シートの形状変化を測定し、形状に変化がなかったものは○、反りやたわみが生じたものは×とした。
表面強度: 鉛筆硬度により比較した。H以上を○、BからFを△、B未満を×とした。
耐久性: 促進試験として60℃オーブンに10日間投入し、化粧シート層間のデラミネーションや変色の有無(有→×不良,無→○良)
かつ、化粧シート貼合した木質樹脂組成物をサンシャインウェザーメータ1000時間投入(照射は化粧シート貼合面側)し表面劣化および内部劣化の有無(有→×不良,無→○良)を観察し、いずれか一つでも満足できなかったものは×不良とした。
バイオマス度: バイオマス原料としては、実施例1と実施例2に記載のポリ乳酸樹脂および実施例1と比較例1に記載のポリ乳酸系ポリエステル樹脂に含有されるポリ乳酸樹脂が対象となる。その他の接着樹脂およびポリプロピレン樹脂、ウレタン系コート剤などは対象とならない。化粧シートを構成する材料のうち、化粧シート全体に対してバイオマスプラスチックが占める重量比率(%)を、各材質の厚みと比重より算出した。50%以上ならば○、20%以上50%未満ならば△、20%に満たない場合は×とした。
以下に結果を示す。
2 絵柄インキ層
3 熱可塑性樹脂シート基材
4 隠蔽層
5 接着剤層
6、6’アンカー層
7 エンボス
8 着色剤
9 トップコート層
10 プライマー層
Claims (7)
- 少なくとも絵柄インキ層と熱可塑性ポリエステル系樹脂層がこの順に積層されてなる化粧シートにおいて、該熱可塑性ポリエステル系樹脂層が、少なくともポリ乳酸を含み、且つ、該熱可塑性ポリエステル系樹脂層のガラス転移点が50℃以上90℃以下、引っ張り弾性率が2GPa以上3.5GPa以下、引っ張り破断伸び率が100%以上200%以下であることを特徴とする化粧シート。
- 熱可塑性樹脂シート基材上に、少なくとも絵柄インキ層と透明熱可塑性ポリエステル系樹脂層がこの順に積層されてなる化粧シートにおいて、該透明熱可塑性ポリエステル系樹脂層が、少なくともポリ乳酸を含み、且つ、該透明熱可塑性ポリエステル系樹脂層のガラス転移点が50℃以上90℃以下、引っ張り弾性率が2GPa以上3.5GPa以下、引っ張り破断伸び率が100%以上200%以下であることを特徴とする化粧シート。
- 前記熱可塑性ポリエステル系樹脂層または透明熱可塑性ポリエステル系樹脂層が、2軸延伸されたシートであることを特徴とする請求項1または2に記載の化粧シート。
- 前記熱可塑性樹脂シート基材が、少なくともポリ乳酸樹脂を含有してなるポリエステル系樹脂からなることを特徴とする請求項2または3に記載の化粧シート。
- 前記熱可塑性樹脂シート基材が、少なくともポリオレフィン系樹脂を含有することを特徴とする請求項2または3に記載の化粧シート。
- 少なくとも請求項1から5のいずれか1項に記載の化粧シートを貼合してなることを特徴とする化粧材。
- 少なくとも請求項1から5のいずれか1項に記載の化粧シートを木質基材に貼合してなることを特徴とする化粧材。
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JP2000094609A (ja) * | 1998-09-21 | 2000-04-04 | Tokuyama Corp | 化粧シート用被覆フィルムおよび化粧シート |
JP2004293005A (ja) * | 2003-03-28 | 2004-10-21 | Lonseal Corp | 生分解性壁装材 |
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