JP2007525562A - 低臭気淡色の使い捨て物品構成用接着剤 - Google Patents
低臭気淡色の使い捨て物品構成用接着剤 Download PDFInfo
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- JP2007525562A JP2007525562A JP2006520419A JP2006520419A JP2007525562A JP 2007525562 A JP2007525562 A JP 2007525562A JP 2006520419 A JP2006520419 A JP 2006520419A JP 2006520419 A JP2006520419 A JP 2006520419A JP 2007525562 A JP2007525562 A JP 2007525562A
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- Prior art keywords
- adhesive
- ethylene
- copolymer
- polymer
- resin
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Abstract
Description
好ましいEVAは、高流動性の酢酸ビニル18〜25重量%のコポリマーである。
他の好ましいEVAは、酢酸ビニル27.5重量%のコポリマーである。
石油炭化水素樹脂
ESCOREZ5600系樹脂は、非常に淡い色の芳香族改質された脂環式炭化水素樹脂である。
本発明の物品は少なくとも、支持体に接着剤により結合しているフィルム層または透過層を有する。透過層は、セルロースティッシュ、織布または不織布もしくは他の薄いか、柔軟か、多孔性か、濡れてもよいシート様材料を含む。このティッシュ層はよく知られており、通常は、高多孔性または透過性の緩く形成されたセルロースシートである。布層は、親水性または疎水性線維成分から製造されていてよい流体透過性の柔軟な材料から成る。この布を含む織布および不織布ウェブは、天然または合成繊維もしくはこれらの混合物を含んでよい。織布および不織布材料はよく知られており、その構成方法は、長年にわたって実施されている。織布は通常、線維の格子メッシュを生じて層を形成する織機で製造される。不織布は、機械的、化学的に、または熱により形成されるウェブを生じさせるためのカーディングプロセス、エアレイングプロセスまたはスパンボンドプロセスでのドライレイドまたはウェットレイド方法を介して製造することができる。本発明の成形材料および物品で使用するための布層は通常、平方ヤード当たり約10から25、好ましくは14から18グラムの範囲の秤量、機械方向で1cm2当たり少なくとも800グラムおよび交差機械方向で1cm2当たり少なくとも200グラムの最小乾燥引張強さを有する。布トップシートを形成する際に通常使用される合成材料には、レーヨン、ポリエステル、ポリプロピレン、ポリエチレン、ナイロンなどが含まれる。
下記の表は、これらの製品で生じたデータのまとめである。ライトニングミキサー(lightning mixer)中、華氏300度で溶融物をブレンドすることにより、それぞれ約2000gバッチを製造した。ブルックフィールドサーモセル(Thermosel)粘度およびメトラー(Mettler)軟化点を測定した。Nordsonらせんスプレーヘッドを使用して、ポリエチレンおよび不織フィルムを積層させた。スパイラルスプレーと細線パターンの両方を使用した。不織/ポリエチレン積層体を、初期Tピール接着に関して試験した。
下記の表は、エチレンオレフィン製品で生じたデータのまとめである。ライトニングミキサー中、華氏300度で溶融物をブレンドすることにより、それぞれ約2000gバッチを製造した。ブルックフィールドサーモセル粘度およびメトラー軟化点を測定した。Nordsonらせんスプレーヘッドを使用して、ポリエチレンおよび不織フィルムを積層させた。スパイラルスプレーと細線パターンの両方を使用した。不織/ポリエチレン積層体を、華氏120度で初期Tピール付着に関して試験した。
Claims (16)
- ホットメルト接着剤組成物であって、
(a) 約40重量%を上回るエチレンコモノマーコポリマー組成物と、
(b) 有効量の、120℃を上回る軟化点を有する水素化炭化水素粘着性樹脂と、から成り、
前記コモノマーはα−オレフィンまたはその混合物を含有し、前記コポリマー組成物は800gm−10分−1を上回るメルトインデックスを有し、前記ポリマー組成物と前記樹脂との重量比は、約1:1を上回ることを特徴とする組成物。 - 前記粘着性樹脂は、約125℃未満の軟化点を有する、請求項1に記載の組成物。
- 前記エチレンαオレフィンコポリマーは、エチレン/オクテンコポリマーを含む、請求項1に記載の組成物。
- 前記コポリマーと前記樹脂との重量比は、1.8:1を上回る、請求項1に記載の組成物。
- 前記エチレン/α−オレフィンコポリマーは、第2のポリマーとは異なるメルトインデックスを有する第1のポリマーのブレンドを含む、請求項1に記載の接着剤。
- 前記エチレン/α−オレフィンコポリマーは、ポリマーと樹脂との重量比少なくとも2:1で前記接着剤中に存在する、請求項1に記載の接着剤。
- 前記エチレン/α−オレフィンコポリマーは、約60から85重量%の量で存在する、請求項1に記載の接着剤。
- 前記エチレン/α−オレフィンコポリマーは、950gm−10分−1を上回るメルトインデックスを有する、請求項7に記載の接着剤。
- 前記樹脂は、20から40重量%の量で前記接着剤中に存在する、請求項7に記載の接着剤。
- 前記コポリマーは、エチレン酢酸ビニルポリマーを含み、前記接着剤は、第1の粘着付与剤および第2の粘着付与剤を含み、ここで、前記第1の粘着付与剤は、第2の粘着付与剤とは5℃異なる融点を有する、請求項1に記載の接着剤。
- 前記接着剤は、約850から1250gm−10分−1のメルトインデックスを有するエチレン/オクテンコポリマー62から75重量%および約125℃を上回る軟化点を有する水素化炭化水素粘着性樹脂25から50重量%を主に含有し;ここで、前記コポリマーと前記樹脂との重量比は、約1:1を上回り、前記接着剤は、約95℃未満の軟化点を有する、請求項1に記載の接着剤。
- 使い捨て物品を組み付ける方法であって、
(a) フィルムと不織シートとを組み付けるステップと、
(b) 有効量のホットメルト構成接着剤を、前記不織シートに施与して、前記シートと前記フィルムとを結合させるステップと、から成り、
前記構成接着剤は、
(i) 約40重量%を上回る、900を上回るメルトインデックスを有するエチレン/α−オレフィンコポリマーと、
(ii) 有効量の、120℃を上回る軟化点を有する水素化炭化水素粘着性樹脂と、
を含有し、前記ポリマーと前記樹脂との重量比は、1:1を上回り、前記接着剤は、約95℃未満の軟化点を有することを特徴とする組み付け方法。 - ホットメルト接着剤組成物であって、
(a) 約40重量%を上回る、1000gm−10分−1を上回るメルトインデックスを有するエチレン酢酸ビニルコポリマー組成物と、
(b) 有効量の、125℃を上回る軟化点を有する水素化炭化水素粘着性樹脂と、
を含有し、前記EVAポリマーと前記樹脂との重量比は、約1:1を上回ることを特徴とするホットメルト接着剤組成物。 - 前記エチレン酢酸ビニルコポリマーは、酢酸ビニル約25から35重量%の酢酸ビニル含分を有し、前記エチレン酢酸ビニルコポリマーは、少なくとも2:1のポリマーと樹脂との重量比で前記接着剤中に存在する、請求項13に記載の接着剤。
- 前記エチレン酢酸ビニルコポリマーは、2700gm−10分−1を上回るメルトインデックスを有する、請求項13に記載の接着剤。
- 前記接着剤は、約2650から3000gm−10分−1のメルトインデックスを有するエチレン酢酸ビニルコポリマー42から85重量%および約125℃を上回る軟化点を有する水素化炭化水素粘着性樹脂約30から50重量%を主に含有し;ここで、前記EVAコポリマーと前記樹脂との重量比は、約1:1を上回り、前記接着剤は、約95℃未満の軟化点を有する、請求項13に記載の接着剤。
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US10/673,385 US6846876B1 (en) | 2003-07-16 | 2003-09-25 | Low odor, light color, disposable article construction adhesive |
PCT/US2004/023356 WO2005014673A1 (en) | 2003-07-16 | 2004-07-13 | Low odor, light color, disposable article construction adhesive |
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- 2004-07-13 EP EP04778729A patent/EP1644424A4/en not_active Ceased
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- 2004-07-13 JP JP2006520419A patent/JP2007525562A/ja active Pending
- 2004-07-13 WO PCT/US2004/023356 patent/WO2005014673A1/en active Application Filing
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Cited By (7)
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US9328271B2 (en) | 2010-04-16 | 2016-05-03 | Kaneka Corporation | Adhesive resin composition and molded products |
JP2014043520A (ja) * | 2012-08-28 | 2014-03-13 | Henkel Japan Ltd | ホットメルト接着剤 |
JP2015534593A (ja) * | 2012-09-14 | 2015-12-03 | ヘンケル アイピー アンド ホールディング ゲゼルシャフト ミット ベシュレンクテル ハフツング | 接着剤組成物およびその使用 |
JP2014198806A (ja) * | 2013-03-31 | 2014-10-23 | 日本ゼオン株式会社 | 炭化水素樹脂およびホットメルト粘接着剤組成物 |
JP2016528333A (ja) * | 2013-07-11 | 2016-09-15 | ボスティック,インコーポレイテッド | 低いブロッキング力を示す、水素化スチレン系ブロック共重合体およびエチレン酢酸ビニル共重合体を含有するホットメルト接着剤 |
WO2020066791A1 (ja) * | 2018-09-27 | 2020-04-02 | 日本ゼオン株式会社 | ホットメルト粘接着剤組成物 |
JP7468348B2 (ja) | 2018-09-27 | 2024-04-16 | 日本ゼオン株式会社 | ホットメルト粘接着剤組成物 |
Also Published As
Publication number | Publication date |
---|---|
US20070207299A1 (en) | 2007-09-06 |
US20050056367A1 (en) | 2005-03-17 |
US6846876B1 (en) | 2005-01-25 |
CN101695879A (zh) | 2010-04-21 |
EP1644424A1 (en) | 2006-04-12 |
US20050014891A1 (en) | 2005-01-20 |
WO2005014673A1 (en) | 2005-02-17 |
BRPI0412517A (pt) | 2006-09-19 |
US20060068672A1 (en) | 2006-03-30 |
US7445838B2 (en) | 2008-11-04 |
EP1644424A4 (en) | 2006-12-06 |
US20070060700A1 (en) | 2007-03-15 |
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