JP2006167580A - Particulate for catalyst - Google Patents
Particulate for catalyst Download PDFInfo
- Publication number
- JP2006167580A JP2006167580A JP2004363036A JP2004363036A JP2006167580A JP 2006167580 A JP2006167580 A JP 2006167580A JP 2004363036 A JP2004363036 A JP 2004363036A JP 2004363036 A JP2004363036 A JP 2004363036A JP 2006167580 A JP2006167580 A JP 2006167580A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- fine particles
- particles
- metal
- crystalline carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 112
- 239000002245 particle Substances 0.000 claims abstract description 96
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 69
- 229910052751 metal Inorganic materials 0.000 claims abstract description 60
- 239000002184 metal Substances 0.000 claims abstract description 60
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 51
- 239000011164 primary particle Substances 0.000 claims abstract description 8
- 239000010419 fine particle Substances 0.000 claims description 98
- 229910045601 alloy Inorganic materials 0.000 claims description 37
- 239000000956 alloy Substances 0.000 claims description 37
- 229910052763 palladium Inorganic materials 0.000 claims description 16
- 229910052737 gold Inorganic materials 0.000 claims description 8
- 229910052697 platinum Inorganic materials 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 7
- 229910052709 silver Inorganic materials 0.000 claims description 7
- 229910052721 tungsten Inorganic materials 0.000 claims description 7
- 229910052720 vanadium Inorganic materials 0.000 claims description 7
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 150000001722 carbon compounds Chemical class 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 229910052787 antimony Inorganic materials 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 229910052738 indium Inorganic materials 0.000 claims description 4
- 229910052703 rhodium Inorganic materials 0.000 claims description 4
- 229910052715 tantalum Inorganic materials 0.000 claims description 4
- 229910052718 tin Inorganic materials 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 3
- 229910001111 Fine metal Inorganic materials 0.000 claims description 3
- 239000006230 acetylene black Substances 0.000 claims description 3
- 239000004917 carbon fiber Substances 0.000 claims description 3
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 3
- 239000002041 carbon nanotube Substances 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 239000002923 metal particle Substances 0.000 claims description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 3
- 239000002116 nanohorn Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 79
- 238000011282 treatment Methods 0.000 abstract description 37
- 238000006243 chemical reaction Methods 0.000 abstract description 10
- 239000002612 dispersion medium Substances 0.000 abstract description 8
- 239000007791 liquid phase Substances 0.000 abstract description 5
- 230000010802 Oxidation-Reduction Activity Effects 0.000 abstract description 3
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 description 32
- 239000006185 dispersion Substances 0.000 description 24
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 23
- 230000000694 effects Effects 0.000 description 16
- 238000011156 evaluation Methods 0.000 description 14
- 239000007788 liquid Substances 0.000 description 14
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 239000007864 aqueous solution Substances 0.000 description 12
- 238000002360 preparation method Methods 0.000 description 12
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 8
- 239000010949 copper Substances 0.000 description 8
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- 229910002668 Pd-Cu Inorganic materials 0.000 description 7
- 239000006229 carbon black Substances 0.000 description 7
- 229910052802 copper Inorganic materials 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 239000003638 chemical reducing agent Substances 0.000 description 6
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 6
- 239000012298 atmosphere Substances 0.000 description 5
- 239000010931 gold Substances 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000003273 ketjen black Substances 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 238000006722 reduction reaction Methods 0.000 description 5
- 239000010944 silver (metal) Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000007809 chemical reaction catalyst Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000011790 ferrous sulphate Substances 0.000 description 4
- 235000003891 ferrous sulphate Nutrition 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 4
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 4
- 238000011068 loading method Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000012299 nitrogen atmosphere Substances 0.000 description 3
- JUBNUQXDQDMSKL-UHFFFAOYSA-N palladium(2+);dinitrate;dihydrate Chemical compound O.O.[Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O JUBNUQXDQDMSKL-UHFFFAOYSA-N 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 229910052707 ruthenium Inorganic materials 0.000 description 3
- 229910001961 silver nitrate Inorganic materials 0.000 description 3
- 239000001509 sodium citrate Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 3
- 229940038773 trisodium citrate Drugs 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910017827 Cu—Fe Inorganic materials 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- 229910018883 Pt—Cu Inorganic materials 0.000 description 2
- 229910003481 amorphous carbon Inorganic materials 0.000 description 2
- SXTLQDJHRPXDSB-UHFFFAOYSA-N copper;dinitrate;trihydrate Chemical compound O.O.O.[Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O SXTLQDJHRPXDSB-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000004108 freeze drying Methods 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229910021065 Pd—Fe Inorganic materials 0.000 description 1
- 229910002839 Pt-Mo Inorganic materials 0.000 description 1
- 229910018885 Pt—Au Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000010335 hydrothermal treatment Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
- YJVFFLUZDVXJQI-UHFFFAOYSA-L palladium(ii) acetate Chemical compound [Pd+2].CC([O-])=O.CC([O-])=O YJVFFLUZDVXJQI-UHFFFAOYSA-L 0.000 description 1
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- OJLCQGGSMYKWEK-UHFFFAOYSA-K ruthenium(3+);triacetate Chemical compound [Ru+3].CC([O-])=O.CC([O-])=O.CC([O-])=O OJLCQGGSMYKWEK-UHFFFAOYSA-K 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- 229910001379 sodium hypophosphite Inorganic materials 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- -1 trihydrate salt Chemical class 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Abstract
Description
本発明は、金属微粒子を炭素粒子に担持させた触媒用微粒子であって、特に、水処理用触媒、電極触媒、アルコール、べンゼン等の酸化反応触媒として好適な触媒用微粒子に関する。 The present invention relates to catalyst fine particles in which metal fine particles are supported on carbon particles, and particularly to catalyst fine particles suitable as an oxidation reaction catalyst for water treatment catalysts, electrode catalysts, alcohols, benzene, and the like.
従来、酸化還元反応用の触媒成分として、種々の金属、合金が用いられており、これらの金属、合金は単独で、または担体に担持して用いられている。金属や合金を比表面積の高い担体に担持すれば金属が高分散し、活性の高い触媒が得られることは良く知られている。また、金属と単体の組み合わせによっては、選択性、触媒寿命等が向上することがあることも知られている。
液相で触媒が用いられる場合には、触媒自体が高活性であることに加えて、活性金属成分が溶媒に溶出しないことや、高分散することが求められている。
Conventionally, various metals and alloys have been used as catalyst components for oxidation-reduction reactions, and these metals and alloys are used alone or supported on a carrier. It is well known that when a metal or alloy is supported on a carrier having a high specific surface area, the metal is highly dispersed and a highly active catalyst can be obtained. It is also known that selectivity, catalyst life, etc. may be improved depending on the combination of a metal and a simple substance.
When a catalyst is used in a liquid phase, in addition to the high activity of the catalyst itself, it is required that the active metal component does not elute into the solvent and is highly dispersed.
べンゼンの酸化反応触媒としては、例えば、K.Otsuka etal., Catal.Today, 57, 71 (2000)に、電極触媒が記載されている。
また、アリル型アルコールの酸化反応触媒としては、例えば、K.Ebitani et al.,Langmuir,15,3562(1999)に、金属クラスター触媒が記載されている。
As an oxidation reaction catalyst for benzene, an electrode catalyst is described in, for example, K. Otsuka etal., Catal. Today, 57, 71 (2000).
Moreover, as an oxidation reaction catalyst of an allylic alcohol, a metal cluster catalyst is described in, for example, K. Ebitani et al., Langmuir, 15, 3562 (1999).
また、本願出願人は、水処理用触媒として、特開２００４−９７８９３号公報（特許文献１）において、無機酸化物担体および／またはカーボン担体に、Ｐｔ、Ａｕ、Ａｇ、Ｐｄ、Ｒｕ、Ｃｕ、Ｎｉ、Ｗ、Ｖ、Ｍｏ、Ｆｅから選ばれる１種または２種以上の金属微粒子および／または合金微粒子が担持されてなる、平均粒子径が５ｎｍ〜２０μｍの範囲にある硝酸性窒素含有水処理用触媒を開示している。
しかしながら、前記した各触媒はさらに活性の向上が求められている。
However, each catalyst described above is required to have further improved activity.
本発明は、酸化還元活性が高く、かつ、水処理等の液相反応に用いた場合には分散媒から容易に分離することのできる触媒用微粒子を提供することを目的としている。 An object of the present invention is to provide fine particles for a catalyst that have high redox activity and can be easily separated from a dispersion medium when used in a liquid phase reaction such as water treatment.
本発明は、結晶性炭素粒子に金属微粒子が担持された触媒用微粒子であって、該触媒用微粒子の平均粒子径が５ｎｍ〜１０μｍの範囲にあり、触媒用微粒子中の金属微粒子の担持量が金属として１〜５０重量％の範囲にあることを特徴とするものである。
前記金属がＰt、Ａu、Ａg、Ｐd、Ｒu、Ｃu、Ｎi、Ｗ、Ｖ、Ｍo、Ｆe、Ｒh、Ｃo、Ｓn、Ｔi、Ｉn、Ａl、Ｔa、Ｓb、Ｃrから選ばれる１種または２種以上の金属または合金であることが好ましく、前記金属微粒子の平均粒子径が１〜５０ｎｍの範囲にあることが好ましい。
前記結晶性炭素粒子の平均粒子径（一次粒子径）が５〜５００ｎｍの範囲にあることが好ましく、前記結晶性炭素粒子の比表面積が２０〜３０００ｍ2／ｇの範囲にあることが好ましい。
The present invention provides catalyst fine particles in which metal fine particles are supported on crystalline carbon particles, the average particle diameter of the catalyst fine particles is in the range of 5 nm to 10 μm, and the amount of metal fine particles supported in the catalyst fine particles is The metal is in the range of 1 to 50% by weight.
The metal is one or two selected from Pt, Au, Ag, Pd, Ru, Cu, Ni, W, V, Mo, Fe, Rh, Co, Sn, Ti, In, Al, Ta, Sb, Cr The above metal or alloy is preferable, and the average particle size of the metal fine particles is preferably in the range of 1 to 50 nm.
The average particle diameter (primary particle diameter) of the crystalline carbon particles is preferably in the range of 5 to 500 nm, and the specific surface area of the crystalline carbon particles is preferably in the range of 20 to 3000 m 2 / g.
前記結晶性炭素粒子の結晶構造がグラファイト構造であり、結晶子間距離が１〜３０ｎｍの範囲にあることが好ましい。
前記結晶性炭素粒子が、カーボンブラック、アセチレンブラック、カーボンナノチューブ、カーボンナノホーン、カーボンファイバー、黒鉛から選ばれる１種または２種以上の結晶性炭素化合物からなることが好ましい。
It is preferable that the crystalline structure of the crystalline carbon particles is a graphite structure and the distance between crystallites is in the range of 1 to 30 nm.
The crystalline carbon particles are preferably composed of one or more crystalline carbon compounds selected from carbon black, acetylene black, carbon nanotube, carbon nanohorn, carbon fiber, and graphite.
本発明の触媒用微粒子は、比表面積の高い結晶性炭素粒子に平均粒子径の小さい金属微粒子が担持されているので、酸化還元活性が高い。また、前記結晶性炭素粒子が疎水性を有していれば、水処理触媒等として用いた場合、処理水と容易に分離することができる。 The fine particles for a catalyst of the present invention have high redox activity because metal fine particles having a small average particle diameter are supported on crystalline carbon particles having a high specific surface area. If the crystalline carbon particles have hydrophobicity, they can be easily separated from treated water when used as a water treatment catalyst or the like.
以下、本発明に係る触媒用微粒子の最良の形態について説明する。
本発明に係る触媒用微粒子は、金属微粒子が結晶性炭素粒子に担持されてなり、平均粒子径が５ｎｍ〜１０μｍの範囲にある。
金属微粒子
本発明における金属微粒子としては、Ｐt、Ａu、Ａg、Ｐd、Ｒu、Ｃu、Ｎi、Ｗ、Ｖ、Ｍo、Ｆe、Ｒh、Ｃo、Ｓn、Ｔi、Ｉn、Ａl、Ｔa、Ｓb、Ｃrから選ばれる１種または２種以上の金属または合金であることが好ましい。
水処理用触媒の金属微粒子なら、Ｐt、Ａu、Ａg、Ｐd、Ｒu、Ｃu、Ｎi、Ｗ、Ｖ、Ｍo、またはＦeが好ましい。電極触媒の金属微粒子なら、Ａu、Ａg、Ｐd、Ｐt、Ｒh、Ｃu、Ｆe、Ｎi、Ｃo、Ｓn、Ｔi、Ｉn、Ａl、Ｔa、Ｓb、Ｒu、Ｍo、Ｃrが好ましい。アルコール、べンゼン等の酸化反応触媒の金属微粒子なら、Ｐd,Ｒu,Ｐt等が好ましい。
Hereinafter, the best mode of the catalyst fine particles according to the present invention will be described.
The catalyst fine particles according to the present invention have metal fine particles supported on crystalline carbon particles and have an average particle diameter in the range of 5 nm to 10 μm.
Metal fine particles The metal fine particles in the present invention include Pt, Au, Ag, Pd, Ru, Cu, Ni, W, V, Mo, Fe, Rh, Co, Sn, Ti, In, Al, Ta, Sb, and Cr. It is preferable that it is 1 type, or 2 or more types of metals or alloys chosen.
Pt, Au, Ag, Pd, Ru, Cu, Ni, W, V, Mo, or Fe are preferable for the metal fine particles of the water treatment catalyst. For the metal fine particles of the electrode catalyst, Au, Ag, Pd, Pt, Rh, Cu, Fe, Ni, Co, Sn, Ti, In, Al, Ta, Sb, Ru, Mo, and Cr are preferable. Pd, Ru, Pt and the like are preferable for metal fine particles of an oxidation reaction catalyst such as alcohol and benzene.
好ましい２成分以上の組み合わせとしては、Ｐd-Ｃu、Ｐd-Ａu、Ｐd-Ｗ、Ｐd-Ｖ、Ｐd-Ｍo、Ｐd-Ｆe、Ｐd-Ｃu／Ｐd、Ｐd-Ｃu-Ｒu、Ｐd-Ｃu-Ｆe、Ｐd-Ｃu-Ａu、Ｐt-Ｃu、Ｐt-Ａu、Ｐt-Ｗ、Ｐt-Ｖ、Ｐt-Ｍo、Ｐt-Ｆe、Ｐt-Ｃu／Ｐd、Ｐt-Ｃu-Ｒu、Ｐt-Ｃu-Ｆe、Ｐt-Ｃu-Ａu等が挙げられる。
なお、ここで合金とは、２種以上の金属成分が均一に混合しているもの（上記において例えば「Ｐd-Ｃu」と表記）に限らず、混合物であるもの（上記において「Ｃu／Ｐd」と表記）も含んで意味している。また、これらの金属成分は結晶性であっても非晶質であってもよい。
Preferred combinations of two or more components include Pd-Cu, Pd-Au, Pd-W, Pd-V, Pd-Mo, Pd-Fe, Pd-Cu / Pd, Pd-Cu-Ru, Pd-Cu-Fe , Pd-Cu-Au, Pt-Cu, Pt-Au, Pt-W, Pt-V, Pt-Mo, Pt-Fe, Pt-Cu / Pd, Pt-Cu-Ru, Pt-Cu-Fe, Pt -Cu-Au and the like.
Here, the alloy is not limited to an alloy in which two or more kinds of metal components are uniformly mixed (for example, expressed as “Pd—Cu” in the above), but an alloy (in the above, “Cu / Pd”). This also includes These metal components may be crystalline or amorphous.
金属微粒子の平均粒子径は１〜５０ｎｍ、さらには１〜１０ｎｍの範囲にあることが好ましい。平均粒子径が１ｎｍ未満の場合は、初期性能は高いが、再生等を繰り返すことによって移動して他の金属微粒子と凝集する傾向があり、長期にわたって初期性能を維持することが困難である。平均粒子径が５０ｎｍを越えると、反応物、酸化剤あるいは還元剤等の吸着量が低下するとともに活性化能も低下し、酸化還元活性が低下する。
金属微粒子の粒子径は、例えば、ＦＥ-ＴＥＭ（ＳＴＥＭ-ＨＡＡＤＦ法）により測定することができる。
The average particle diameter of the metal fine particles is preferably in the range of 1 to 50 nm, more preferably 1 to 10 nm. When the average particle size is less than 1 nm, the initial performance is high, but it tends to move and aggregate with other metal fine particles by repeating regeneration and the like, and it is difficult to maintain the initial performance over a long period of time. When the average particle diameter exceeds 50 nm, the amount of adsorbed reactants, oxidizing agent, reducing agent, etc. decreases, the activation ability also decreases, and the oxidation-reduction activity decreases.
The particle diameter of the metal fine particles can be measured by, for example, FE-TEM (STEM-HAADF method).
結晶性炭素粒子
本発明における結晶性炭素粒子としては、カーボンブラック、アセチレンブラック、カーボンナノチューブ、カーボンナノホーン、カーボンファイバー、黒鉛などが挙げられる。このような結晶性炭素粒子は金属微粒子との結合力が強く、処理中の金属の処理液への溶出を抑制することができ、また担体から容易に脱離することがなく、このため長期処理が可能である。
一方、活性炭のような無定形炭素粒子（非結晶性炭素粒子）は、化学的安定性、機械的強度（安定性）が低い上に、粒子径が大きく親水性が高い場合があり、本発明の触媒用微粒子の担体としては、不適当である。
Crystalline carbon particles Examples of the crystalline carbon particles in the present invention include carbon black, acetylene black, carbon nanotube, carbon nanohorn, carbon fiber, and graphite. Such crystalline carbon particles have a strong binding force with the metal fine particles, can suppress elution of the metal being processed into the processing solution, and do not easily desorb from the carrier, and thus can be treated for a long time. Is possible.
On the other hand, amorphous carbon particles (non-crystalline carbon particles) such as activated carbon have low chemical stability and mechanical strength (stability) and may have a large particle size and high hydrophilicity. It is unsuitable as a catalyst fine particle support.
結晶性炭素粒子の平均粒子径（一次粒子径）は５〜５００ｎｍ、さらには１０〜１００ｎｍの範囲にあることが好ましい。平均粒子径（一次粒子径）が５ｎｍ未満の場合は、結晶性が低いためか、前記結晶性炭素粒子を用いる効果が不充分となる傾向がある。平均粒子径（一次粒子径）が５００ｎｍを超えると、比表面積が低く、金属微粒子を高分散した状態に担持することができないために、即ち、担体表面で金属微粒子が凝集した状態となるため充分な活性が得られないことがある。
なお、ここで結晶性炭素粒子の平均粒子径を一次粒子径と規定したのは、触媒用微粒子の担体として用いる結晶性炭素粒子は、概ね触媒用微粒子の粒子径と同じく平均粒子径が５ｎｍ〜１μｍの範囲にあれば凝集体であっても非凝集体であってもよく、このときの非凝集体を一次粒子として意味したものである。
The average particle diameter (primary particle diameter) of the crystalline carbon particles is preferably in the range of 5 to 500 nm, more preferably 10 to 100 nm. When the average particle size (primary particle size) is less than 5 nm, the effect of using the crystalline carbon particles tends to be insufficient because of low crystallinity. When the average particle diameter (primary particle diameter) exceeds 500 nm, the specific surface area is low, and the metal fine particles cannot be supported in a highly dispersed state, that is, the metal fine particles are aggregated on the support surface. Activity may not be obtained.
Here, the average particle diameter of the crystalline carbon particles is defined as the primary particle diameter because the crystalline carbon particles used as the carrier for the catalyst fine particles have an average particle diameter of about 5 nm to about the same as the particle diameter of the catalyst fine particles. If it exists in the range of 1 micrometer, it may be an aggregate or a non-aggregate, and the non-aggregate at this time is meant as a primary particle.
結晶性炭素粒子の比表面積は２０〜３０００ｍ2／ｇ、さらには５００〜２０００ｍ2／ｇの範囲にあることが好ましい。比表面積が２０ｍ2／ｇ未満の場合は、所定量の金属微粒子を担持した場合、金属微粒子が結晶性炭素粒子の表面で凝集した状態となるため充分な活性が得られないことがある。比表面積が３０００ｍ2／ｇを超えるものは、微粒子の集合体であり、結晶性が低く、酸化還元活性や後述する疎水性等の結晶性炭素粒子を用いる効果が不充分となる傾向がある。 The specific surface area of crystalline carbon particles 20~3000m 2 / g, more preferably in the range of 500~2000m 2 / g. When the specific surface area is less than 20 m 2 / g, when a predetermined amount of metal fine particles is supported, the metal fine particles are aggregated on the surface of the crystalline carbon particles, so that sufficient activity may not be obtained. Those having a specific surface area exceeding 3000 m 2 / g are aggregates of fine particles, have low crystallinity, and tend to have insufficient effects of using crystalline carbon particles such as redox activity and hydrophobicity described later.
前記結晶性炭素粒子は、触媒用微粒子が液相反応に用いられる場合において、当該分散媒や溶媒との親和性が低いものであることが好ましい。即ち、分散媒や溶媒が水あるいは水と相溶性の高い分散媒等であれば、結晶性炭素粒子は疎水性であることが好ましく、他方、分散媒や溶媒が親油性であれば、結晶性炭素粒子は親水性であることが好ましい。本発明の触媒用微粒子の担体として先に列挙したものは、疎水性の結晶性炭素粒子である。
例えば、担体としての結晶性炭素粒子が疎水性であると、反応終了後あるいは必要に応じて反応を停止した後、処理水表面に触媒が分離して浮遊するから、セラミックスフィルター等の特別の装置を用いることなく、触媒を分離することが可能である。特に、微細な粒子の場合には、通常の方法で分離が困難であっても、容易に分離することができる。
なお、結晶性炭素粒子の粒子径が大きく、通常の方法で容易に分離できる場合には、結晶性炭素粒子を硝酸などの酸で処理して親水性にして用いることも可能である。
The crystalline carbon particles preferably have a low affinity with the dispersion medium or solvent when the catalyst fine particles are used in a liquid phase reaction. That is, if the dispersion medium or solvent is water or a dispersion medium highly compatible with water, the crystalline carbon particles are preferably hydrophobic. On the other hand, if the dispersion medium or solvent is lipophilic, the crystalline carbon particles are crystalline. The carbon particles are preferably hydrophilic. What has been enumerated above as the carrier for the catalyst fine particles of the present invention is hydrophobic crystalline carbon particles.
For example, if the crystalline carbon particles as the support are hydrophobic, the catalyst separates and floats on the surface of the treated water after the reaction is completed or after the reaction is stopped if necessary. It is possible to separate the catalyst without using. In particular, fine particles can be easily separated even if separation by a normal method is difficult.
In addition, when the particle diameter of the crystalline carbon particles is large and can be easily separated by a usual method, the crystalline carbon particles can be treated with an acid such as nitric acid to be made hydrophilic.
本発明に用いる結晶性炭素粒子はグラファイト構造を有し、結晶子径が２〜１００ｎｍの範囲にあり、結晶子間距離が１〜３０ｎｍ、さらには１〜１０ｎｍの範囲にあることが好ましい。
結晶子間距離が１ｎｍ未満となることはなく、結晶子間距離が３０ｎｍを超えるものは結晶性が不充分で、酸化還元活性や後述する疎水性等の結晶性炭素粒子を用いる効果が不充分となる傾向がある。
The crystalline carbon particles used in the present invention have a graphite structure, a crystallite diameter in the range of 2 to 100 nm, and a distance between crystallites in the range of 1 to 30 nm, more preferably 1 to 10 nm.
When the distance between crystallites is not less than 1 nm, and the distance between crystallites exceeds 30 nm, the crystallinity is insufficient, and the effect of using crystalline carbon particles such as redox activity and hydrophobicity described later is insufficient. Tend to be.
触媒用微粒子
本発明に係る触媒用微粒子は、平均粒子径が５ｎｍ〜１μｍ、さらには１０ｎｍ〜０．５μｍの範囲にあることが好ましい。
触媒用微粒子の平均粒子径が５ｎｍ未満のものは、凝集する傾向が強く、触媒の調製が困難であったり、得られたとしても凝集して分散性が低下し、充分な性能を発揮できないことがある。平均粒子径が１μｍを越えると、液相反応等で用いる場合、分散媒等の循環あるいは撹拌が弱くなると沈降することがあり、さらに反応物との接触効率が低下して充分な酸化還元活性が得られないことがある。
Catalyst fine particles The catalyst fine particles according to the present invention preferably have an average particle size in the range of 5 nm to 1 μm, more preferably 10 nm to 0.5 μm.
If the average particle size of the catalyst fine particles is less than 5 nm, the tendency to agglomerate is strong, and it is difficult to prepare the catalyst, or even if obtained, it agglomerates and the dispersibility is lowered, so that sufficient performance cannot be exhibited. There is. When the average particle diameter exceeds 1 μm, when used in a liquid phase reaction or the like, it may settle when the circulation or stirring of the dispersion medium or the like is weakened, and the contact efficiency with the reactants is further reduced, resulting in sufficient redox activity. It may not be obtained.
触媒用微粒子中の金属微粒子の担持量は、金属として１〜５０重量％、さらには２〜２０重量％の範囲にあることが好ましい。担持量が１重量％未満の場合は、酸化還元活性が不充分となる。担持量が５０重量％を越えると、担持することが困難であるとともに、仮に担持できても酸化還元活性がさらに向上することもないので、経済性が低下する。また、担持した金属微粒子同士が互いに合体して粒子成長することがあり、活性が低下することがある。 The amount of the metal fine particles supported in the catalyst fine particles is preferably in the range of 1 to 50% by weight, more preferably 2 to 20% by weight as the metal. When the loading is less than 1% by weight, the redox activity is insufficient. If the loading amount exceeds 50% by weight, it is difficult to carry, and even if it can be carried, the oxidation-reduction activity is not further improved, so the economic efficiency is lowered. In addition, the supported metal fine particles may coalesce with each other to grow particles, which may reduce the activity.
触媒用微粒子の製造方法
本発明に係る触媒用微粒子は、前記した粒子径範囲にあり、分散媒に分散した場合でも沈降等することなく反応物と効率的に接触し、充分な酸化還元活性が得られれば、特に制限はなく従来公知の方法を用いて製造することができる。
以下、本発明の触媒用微粒子の製造方法を３つ例示的に説明する。
Production method of catalyst fine particles The catalyst fine particles according to the present invention are in the above-mentioned particle size range, and even when dispersed in a dispersion medium, they efficiently contact with the reactants without being settled, and have sufficient redox activity. If it is obtained, there is no particular limitation, and it can be produced using a conventionally known method.
Hereinafter, three examples of the method for producing catalyst fine particles of the present invention will be described.
第１の製造方法
前記した結晶性炭素粒子の分散液を調製する。これに、所定量の１種または２種以上の金属塩水溶液を加え、結晶性炭素粒子に金属塩水溶液を吸収させ、次いで乾燥し、その後２００〜８００℃の温度で、還元ガス例えばＨ2、ＮＨ3雰囲気下で通常０．５〜６時間程度還元処理することによって触媒用微粒子を得ることができる。
金属塩としては、硝酸パラジウム、塩化パラジウム、酢酸パラジウム、テトラアンミンパラジウム、塩化白金、硝酸銀、塩化銅、硝酸ニッケル、酢酸ルテニウムなど、前記した金属の塩で水に可溶な塩を用いることができる。
乾燥方法としては、凍結乾燥、噴霧乾燥、静置乾燥、ロータリーエバポレーター等、従来公知の方法を採用することができる。
上記において、還元温度が２００℃未満の時は、金属塩の還元が不充分となり、金属微粒子の生成が不充分となる。還元温度が８００℃を越えると、金属微粒子が粒子成長しすぎたり、触媒用微粒子が強く凝集して分散性が低下することがあり、充分な酸化還元活性が得られないことがある。好ましい還元温度は２５０〜６００℃の範囲である。
First Production Method A dispersion of crystalline carbon particles described above is prepared. A predetermined amount of one or more metal salt aqueous solutions are added thereto, the crystalline carbon particles absorb the metal salt aqueous solution, and then dried, and then at a temperature of 200 to 800 ° C., a reducing gas such as H 2 , The fine particles for catalyst can be obtained by reducing treatment for about 0.5 to 6 hours under NH 3 atmosphere.
As the metal salt, water-soluble salts such as palladium nitrate, palladium chloride, palladium acetate, tetraammine palladium, platinum chloride, silver nitrate, copper chloride, nickel nitrate, and ruthenium acetate can be used.
As a drying method, conventionally known methods such as freeze drying, spray drying, stationary drying, and rotary evaporator can be employed.
In the above, when the reduction temperature is less than 200 ° C., the reduction of the metal salt is insufficient and the generation of metal fine particles is insufficient. If the reduction temperature exceeds 800 ° C., the metal fine particles may grow too much, or the catalyst fine particles may be strongly aggregated and the dispersibility may be lowered, and sufficient redox activity may not be obtained. A preferable reduction temperature is in the range of 250 to 600 ° C.
第２の製造方法
前記した結晶性炭素粒子の分散液を調製する。これに、所定量の１種または２種以上の金属塩水溶液を加え、ついで還元剤（水素化硼素ナトリウム（ＮaＢＨ4）、次亜リン酸ソーダ、ヒドラジン、硫酸第一鉄等）を加え、結晶性炭素粒子上に金属を析出させる。ついで、必要に応じてオートクレーブ処理（１００〜３００℃で水熱処理）する。オートクレーブ処理により、溶液中に析出した金属微粒子を結晶性炭素粒子上に析出させることができる。
最後に金属微粒子が担持された結晶性炭素粒子を濾過分離し、第１の方法と同様にして乾燥した後、加熱処理（好ましくは不活性ガスまたは還元ガス雰囲気下で加熱処理）することによって触媒用微粒子を得る。
Second Production Method A dispersion of crystalline carbon particles as described above is prepared. To this, a predetermined amount of one or more metal salt aqueous solutions are added, followed by a reducing agent (sodium borohydride (NaBH 4 ), sodium hypophosphite, hydrazine, ferrous sulfate, etc.) Metal is deposited on the conductive carbon particles. Then, autoclaving (hydrothermal treatment at 100 to 300 ° C.) is performed as necessary. By the autoclave treatment, the metal fine particles deposited in the solution can be deposited on the crystalline carbon particles.
Finally, the crystalline carbon particles carrying the metal fine particles are separated by filtration, dried in the same manner as in the first method, and then heat-treated (preferably heat-treated in an inert gas or reducing gas atmosphere). Fine particles are obtained.
第３の製造方法
例えば、パラジウム−銅合金の微粒子であれば、硝酸パラジウムと硝酸銅との混合水溶液に、生成する金属微粒子の分散安定化剤としてのクエン酸の水溶液に還元剤として硫酸第一鉄を溶解した溶液を添加して、Ｐd-Ｃu合金微粒子分散液を調製する。このＰd-Ｃu合金微粒子分散液に結晶性炭素粒子の分散液を混合してＰd-Ｃu合金微粒子を結晶性炭素粒子担体に担持した触媒用微粒子分散液を調製する。なお、このときの担持は、互いの粒子のゼータ電位の差により、結晶性炭素粒子の表面にＰd-Ｃu合金微粒子が担持されるものであって、金属微粒子のゼータ電位は負、結晶性炭素粒子のゼータ電位は正である。
最後に金属微粒子が担持された結晶性炭素粒子を濾過分離し、第１の方法と同様にして乾燥し、ついで加熱処理（好ましくは不活性ガスまたは還元ガス雰囲気下で加熱処理）することによって触媒用微粒子を得る。
Third production method For example, in the case of fine particles of a palladium-copper alloy, a mixed aqueous solution of palladium nitrate and copper nitrate, an aqueous solution of citric acid as a dispersion stabilizer of the generated fine metal particles, a first sulfuric acid as a reducing agent A solution in which iron is dissolved is added to prepare a Pd—Cu alloy fine particle dispersion. A dispersion of crystalline carbon particles is mixed with this Pd—Cu alloy fine particle dispersion to prepare a fine particle dispersion for catalyst in which Pd—Cu alloy fine particles are supported on a crystalline carbon particle carrier. In this case, the loading is such that the Pd—Cu alloy fine particles are supported on the surface of the crystalline carbon particles due to the difference in zeta potential between the particles, and the zeta potential of the metal fine particles is negative, the crystalline carbon The zeta potential of the particles is positive.
Finally, the crystalline carbon particles carrying the metal fine particles are separated by filtration, dried in the same manner as in the first method, and then heat-treated (preferably heat-treated in an inert gas or reducing gas atmosphere). Fine particles are obtained.
上記各製造方法によって、平均粒子径が５ｎｍ〜１μｍ、さらには１０ｎｍ〜０．５μｍの範囲にある触媒用微粒子が得られる。
また、触媒用微粒子中の金属微粒子の含有量は１〜５０重量％、さらには２〜２０重量％の範囲とすることができる。
以下に示す実施例により、本発明をさらに具体的に説明するが、本発明はこれら実施例に限定されるものではない。
By the above production methods, fine particles for catalyst having an average particle diameter in the range of 5 nm to 1 μm, and further 10 nm to 0.5 μm are obtained.
Further, the content of the metal fine particles in the catalyst fine particles can be in the range of 1 to 50% by weight, more preferably 2 to 20% by weight.
The present invention will be described more specifically with reference to the following examples, but the present invention is not limited to these examples.
触媒(1)の調製
純水１００ｇに、合金微粒子を構成するパラジウムと銅の重量比が７０／３０となるように硝酸パラジウム２水和塩7.4ｇ及び硝酸銅３水和塩４.９ｇを溶解した金属塩水溶液に、安定化剤として濃度30重量％のクエン酸三ナトリウム水溶液２６５ｇと還元剤として濃度２５重量％の硫酸第一鉄水溶液１２９ｇ（硝酸パラジウムと硝酸銅の合計モル数の2倍量のモル数に相当）を加え、窒素雰囲気下で２０時間攪拌して合金微粒子の分散液を得た。合金微粒子の平均粒子径は４ｎｍであった。
得られた分散液を遠心分離器により水洗して不純物を除去した後、水に分散させ、濃度１０重量％の合金微粒子(1)の分散液とし、これに結晶性炭素化合物としてカーボンブラック（キャボット（株）製：Vulcan XC-72R、平均粒子径３1ｎｍ、比表面積２３０ｍ2／ｇ、結晶子径３．３ｎｍ）５ｇを純水４９５ｇに均一に混合した分散液を添加し、この混合液のｐＨを６に調整して１時間撹拌した。ついで、この混合液を１００℃で乾燥させ触媒(1)を調製した。触媒(1)の金属担持量は２０重量であった。
Preparation of catalyst (1) In 100 g of pure water, 7.4 g of palladium nitrate dihydrate and 4.9 g of copper nitrate trihydrate are dissolved so that the weight ratio of palladium and copper constituting the alloy fine particles is 70/30. 265 g of a 30 wt% trisodium citrate aqueous solution as a stabilizer and 129 g of a 25 wt% ferrous sulfate aqueous solution as a reducing agent (twice the total number of moles of palladium nitrate and copper nitrate) The mixture was stirred for 20 hours under a nitrogen atmosphere to obtain a dispersion of alloy fine particles. The average particle size of the alloy fine particles was 4 nm.
The obtained dispersion was washed with water by a centrifugal separator to remove impurities, and then dispersed in water to obtain a dispersion of alloy fine particles (1) having a concentration of 10% by weight, and carbon black (cabot) as a crystalline carbon compound. Co., Ltd .: Vulcan XC-72R, average particle size of 31 nm, specific surface area of 230 m 2 / g, crystallite size of 3.3 nm) was added to a dispersion in which 5 g of pure water was uniformly mixed with 495 g of pure water. Was adjusted to 6 and stirred for 1 hour. Next, this mixed solution was dried at 100 ° C. to prepare catalyst (1). The metal loading of catalyst (1) was 20 weight.
撥水浮遊性（１）の評価
得られた触媒(1)５ｇを１００ｍｌの水に分散させ、２００ｒｐｍで５分間撹拌した後、撹拌を停止し、触媒(1)の浮遊状態を観察し、以下の基準により評価した。結果を表１に示す。
触媒(1)が全量水面上に浮遊していた。 ：◎
触媒(1)の８０％以上が水面上に浮遊し、他は水中に分散していた。 ：○
触媒(1)の５０％〜８０％未満が水面上に浮遊し、他は水中に分散していた。 ：△
触媒(1)の５０未満が水面上に浮遊し、他は水中に分散あるいは沈降していた。：×
Evaluation of water repellency floatability (1) 5 g of the obtained catalyst (1) was dispersed in 100 ml of water, stirred at 200 rpm for 5 minutes, then the stirring was stopped, and the floating state of the catalyst (1) was observed. It was evaluated according to the criteria. The results are shown in Table 1.
The entire amount of catalyst (1) was floating on the water surface. : ◎
More than 80% of the catalyst (1) floated on the water surface and the others were dispersed in water. : ○
50% to less than 80% of the catalyst (1) floated on the water surface, and the others were dispersed in water. : △
Less than 50 of catalyst (1) floated on the surface of the water, and the others were dispersed or settled in water. : ×
硝酸性窒素含有水の処理
硝酸ナトリウム(関東化学(株)製：特級)６１.３ｇを純水に溶解して硝酸性窒素含有水２５ｋｇを調製した。このときの硝酸性窒素の含有量はＮとして４００ｐｐｍであった。
ついで、水処理槽に硝酸性窒素含有水を投入し、硝酸性窒素含有水を循環させながらこれに触媒(1)１０００ｇを分散させた。このときの硝酸性窒素含有水中の触媒(1)の分散濃度は３．８重量％である。
ついで水素ガスを水処理槽の下部から注入し、水処理槽を２００ｒｐｍで攪拌しながら硝酸性窒素含有水を処理した。処理条件は、液温２５℃、液循環量７０Ｌ／ｍｉｎ、液圧力０.４５ＭＰa、水素圧力０.４５ＭＰa 、水素の注入流量０.４８ＮＬ／ｍｉｎである。なお、水処理中は濃度１重量％の硫酸にて、硝酸性窒素含有水のｐＨを５〜６の範囲に調整した。
Treatment of nitrate nitrogen-containing water 61.3 g of sodium nitrate (manufactured by Kanto Chemical Co., Ltd .: special grade) was dissolved in pure water to prepare 25 kg of nitrate nitrogen-containing water. At this time, the content of nitrate nitrogen was 400 ppm as N.
Next, nitrate nitrogen-containing water was introduced into the water treatment tank, and 1000 g of catalyst (1) was dispersed in the water while circulating the nitrate nitrogen-containing water. At this time, the dispersion concentration of the catalyst (1) in nitrate nitrogen-containing water is 3.8% by weight.
Next, hydrogen gas was injected from the lower part of the water treatment tank, and the nitrate nitrogen-containing water was treated while stirring the water treatment tank at 200 rpm. The processing conditions are a liquid temperature of 25 ° C., a liquid circulation rate of 70 L / min, a liquid pressure of 0.45 MPa, a hydrogen pressure of 0.45 MPa, and a hydrogen injection flow rate of 0.48 NL / min. During the water treatment, the pH of the nitrate nitrogen-containing water was adjusted to a range of 5 to 6 with sulfuric acid having a concentration of 1% by weight.
水素ガスの供給開始後、５分毎に処理液を採取し、窒素分析装置（ブランルーベ（株）製：ＡＡＳ−III）により硝酸性窒素（ＮＯ3＋ＮＯ2）およびＮＨ3の分析を行った。
硝酸性窒素の還元は８５分（ＮＯ3＋ＮＯ2が０ｐｐｍとなった時点）で終了し、このときの副生ＮＨ3濃度、水素の供給量、および水素利用率（Ｎ2生成、ＮＨ3副生）、水素未利用率を表１に示した。
The treatment liquid was sampled every 5 minutes after the start of the supply of hydrogen gas, and nitrate nitrogen (NO 3 + NO 2 ) and NH 3 were analyzed using a nitrogen analyzer (Blanlube Co., Ltd .: AAS-III).
The reduction of nitrate nitrogen was completed in 85 minutes (when NO 3 + NO 2 became 0 ppm). At this time, the concentration of by-product NH 3 , the supply amount of hydrogen, and the hydrogen utilization rate (N 2 production, NH 3 Table 1 shows the hydrogen unused rate.
触媒(2)の調製
実施例１において、結晶性炭素化合物としてカーボンブラック（ケッチェンブラックインターナショナル（株）製：ケッチェンブラックＥＣ、平均粒子径３０ｎｍ、比表面積８２０ｍ2／ｇ、結晶子径３．０ｎｍ）を用いた以外は同様にして、触媒(2)を調製した。
硝酸性窒素含有水の処理
実施例１において、触媒(2)を用いた以外は同様の条件で硝酸性窒素含有水の処理を実施した。これらの処理の結果および撥水浮遊性（１）の評価結果を表1に示した。
Preparation of catalyst (2) In Example 1, carbon black (manufactured by Ketjen Black International Co., Ltd .: Ketjen Black EC, average particle size 30 nm, specific surface area 820 m 2 / g, crystallite size 3. Catalyst (2) was prepared in the same manner except that 0 nm) was used.
Treatment of nitrate nitrogen-containing water The nitrate nitrogen-containing water was treated under the same conditions as in Example 1 except that the catalyst (2) was used. The results of these treatments and the evaluation results of water repellency floatability (1) are shown in Table 1.
触媒(3)の調製
実施例１において、結晶性炭素化合物としてカーボンブラック（ケッチェンブラックインターナショナル（株）製：ケッチェンブラックＥＣ６００ＪＤ、平均粒子径３１ｎｍ、比表面積１２８０ｍ2／ｇ、結晶子径３．１ｎｍ）を用いた以外は同様にして触媒(3)を調製した。
硝酸性窒素含有水の処理
実施例１において、触媒(3)を用いた以外は同様の条件で硝酸性窒素含有水の処理を実施した。これらの処理の結果および撥水浮遊性（１）の評価結果を表1に示した。
Preparation of catalyst (3) In Example 1, carbon black (manufactured by Ketjen Black International Co., Ltd .: Ketjen Black EC600JD, average particle size 31 nm, specific surface area 1280 m 2 / g, crystallite size 3. Catalyst (3) was prepared in the same manner except that 1 nm) was used.
Treatment of nitrate nitrogen-containing water In Example 1, the nitrate nitrogen-containing water was treated under the same conditions except that the catalyst (3) was used. The results of these treatments and the evaluation results of water repellency floatability (1) are shown in Table 1.
触媒(4)の調製
実施例１において、結晶性炭素化合物としてカーボンブラック（電気化学工業（株）製：デンカブラック ＦＸ−３５、平均粒子径２６ｎｍ、比表面積１３３ｍ2／ｇ、結晶子径４．３ｎｍ）を用いた以外は同様にして触媒(4)を調製した。
硝酸性窒素含有水の処理
実施例１において、触媒(4)を用いた以外は同様の条件で硝酸性窒素含有水の処理を実施した。これらの処理の結果および撥水浮遊性（１）の評価結果を表1に示した。
Preparation of Catalyst (4) In Example 1, as a crystalline carbon compound, carbon black (manufactured by Denki Kagaku Kogyo Co., Ltd .: Denka Black FX-35, average particle size 26 nm, specific surface area 133 m 2 / g, crystallite size 4. Catalyst (4) was prepared in the same manner except that 3 nm) was used.
Treatment of nitrate nitrogen-containing water In Example 1, the nitrate nitrogen-containing water was treated under the same conditions except that the catalyst (4) was used. The results of these treatments and the evaluation results of water repellency floatability (1) are shown in Table 1.
触媒(5)の調製
実施例１において、結晶性炭素化合物としてカーボンブラック（電気化学工業（株）製：デンカブラック ＯＡＢ−１００、平均粒子径３７ｎｍ、比表面積８８ｍ2／ｇ、結晶子径５．７ｎｍ）を用いた以外は同様にして触媒(5)を調製した。
硝酸性窒素含有水の処理
実施例１において、触媒(5)を用いた以外は同様の条件で硝酸性窒素含有水の処理を実施した。これらの処理の結果および撥水浮遊性（１）の評価結果を表1に示した。
Preparation of catalyst (5) In Example 1, carbon black (manufactured by Denki Kagaku Kogyo Co., Ltd .: Denka Black OAB-100, average particle size 37 nm, specific surface area 88 m 2 / g, crystallite size 5. Catalyst (5) was prepared in the same manner except that 7 nm) was used.
Treatment of nitrate nitrogen-containing water The nitrate nitrogen-containing water was treated under the same conditions as in Example 1 except that the catalyst (5) was used. The results of these treatments and the evaluation results of water repellency floatability (1) are shown in Table 1.
触媒(6)の調製
実施例３において、合金微粒子を構成するパラジウムと銅の重量比が９０／１０となるように硝酸パラジウムおよび硝酸銅を加えた以外は同様にして、濃度１０重量％の合金微粒子(2)の分散液とした。合金微粒子の平均粒子径は３ｎｍであった。
ついで、合金微粒子(2)の分散液を用いた以外は同様にして触媒(6)を調製した。
硝酸性窒素含有水の処理
実施例１において、触媒(6)を用いた以外は同様の条件で硝酸性窒素含有水の処理を実施した。これらの処理の結果および撥水浮遊性（１）の評価結果を表1に示した。
Preparation of catalyst (6) In Example 3, in the same manner except that palladium nitrate and copper nitrate were added so that the weight ratio of palladium to copper constituting the alloy fine particles was 90/10, the concentration was 10. A dispersion of weight percent alloy fine particles (2) was obtained. The average particle size of the alloy fine particles was 3 nm.
Next, a catalyst (6) was prepared in the same manner except that the dispersion of alloy fine particles (2) was used.
Treatment of nitrate nitrogen-containing water In Example 1, the nitrate nitrogen-containing water was treated under the same conditions except that the catalyst (6) was used. The results of these treatments and the evaluation results of water repellency floatability (1) are shown in Table 1.
触媒(7)の調製
実施例３において、合金微粒子を構成するパラジウムと銅の重量比が５０／５０となるように硝酸パラジウムおよび硝酸銅を加えた以外は同様にして、濃度１０重量％の合金微粒子(3)の分散液とした。合金微粒子の平均粒子径は５ｎｍであった。
ついで、合金微粒子(3)の分散液を用いた以外は同様にして触媒(7)を調製した。
硝酸性窒素含有水の処理
実施例１において、触媒(7)を用いた以外は同様の条件で硝酸性窒素含有水の処理を実施した。これらの処理の結果および撥水浮遊性（１）の評価結果を表1に示した。
Preparation of catalyst (7) In Example 3, in the same manner except that palladium nitrate and copper nitrate were added so that the weight ratio of palladium to copper constituting the alloy fine particles was 50/50, the concentration was 10. A dispersion of the alloy fine particles (3) by weight% was obtained. The average particle size of the alloy fine particles was 5 nm.
Next, a catalyst (7) was prepared in the same manner except that the dispersion of alloy fine particles (3) was used.
Treatment of nitrate nitrogen-containing water The nitrate nitrogen-containing water was treated under the same conditions as in Example 1 except that the catalyst (7) was used. The results of these treatments and the evaluation results of water repellency floatability (1) are shown in Table 1.
触媒(8)の調製
純水１００ｇに、合金微粒子を構成するパラジウムと銅の重量比が７０／３０となるように硝酸パラジウム２水和塩７.４ｇ及び硝酸銅３水和塩４.９ｇを溶解した金属塩水溶液に、安定化剤として濃度３０重量％のクエン酸三ナトリウム水溶液２６５ｇと還元剤として濃度２５重量％の硫酸第一鉄水溶液２５８ｇ（硝酸パラジウムと硝酸銅の合計モル数の４倍量のモル数に相当）を加え、窒素雰囲気下で２０時間攪拌して合金微粒子の分散液を得た。合金微粒子の平均粒子径は１０ｎｍであった。
得られた分散液を遠心分離器により水洗して不純物を除去した後、水に分散させ、濃度１０重量％の合金微粒子(4)の分散液を得た。ついで、合金微粒子(4)の分散液を用いた以外は実施例３と同様にして触媒(8)を調製した。
硝酸性窒素含有水の処理
実施例１において、触媒(8)を用いた以外は同様の条件で硝酸性窒素含有水の処理を実施した。これらの処理の結果および撥水浮遊性（１）の評価結果を表1に示した。
Preparation of catalyst (8) In 100 g of pure water, 7.4 g of palladium nitrate dihydrate and 4.9 g of copper nitrate trihydrate were added so that the weight ratio of palladium and copper constituting the alloy fine particles was 70/30. In a dissolved metal salt aqueous solution, 265 g of a trisodium citrate aqueous solution having a concentration of 30% by weight as a stabilizer and 258 g of a ferrous sulfate aqueous solution having a concentration of 25% by weight as a reducing agent (four times the total number of moles of palladium nitrate and copper nitrate) The resulting mixture was stirred under a nitrogen atmosphere for 20 hours to obtain a dispersion of alloy fine particles. The average particle size of the alloy fine particles was 10 nm.
The obtained dispersion was washed with water using a centrifugal separator to remove impurities, and then dispersed in water to obtain a dispersion of alloy fine particles (4) having a concentration of 10% by weight. Next, a catalyst (8) was prepared in the same manner as in Example 3 except that the dispersion liquid of alloy fine particles (4) was used.
Treatment of nitrate nitrogen-containing water The nitrate nitrogen-containing water was treated under the same conditions as in Example 1 except that the catalyst (8) was used. The results of these treatments and the evaluation results of water repellency floatability (1) are shown in Table 1.
触媒(9)の調製
純水１００ｇに、合金微粒子を構成するパラジウムと銅と銀の重量比が６３／２７／１０となるように硝酸パラジウム２水和塩７.４ｇ、硝酸銅３水和塩４.９ｇ、硝酸銀１.８ｇを溶解した金属塩水溶液に、安定化剤として濃度３０重量％のクエン酸三ナトリウム水溶液２６５ｇと還元剤として濃度２５重量％の硫酸第一鉄水溶液１２９ｇ（硝酸パラジウムと硝酸銅と硝酸銀の合計モル数の１.９倍量のモル数に相当）を加え、窒素雰囲気下で２０時間攪拌して合金微粒子の分散液を得た。合金微粒子の平均粒子径は５ｎｍであった。
得られた分散液を遠心分離器により水洗して不純物を除去した後、水に分散させ、濃度１０重量％の合金微粒子(5)の分散液を得た。ついで、合金微粒子(5)の分散液を用いた以外は実施例３と同様にして触媒(9)を調製した。
硝酸性窒素含有水の処理
実施例１において、触媒(9)を用いた以外は同様の条件で硝酸性窒素含有水の処理を実施した。これらの処理の結果および撥水浮遊性（１）の評価結果を表1に示した。
Preparation of catalyst (9) In 100 g of pure water, 7.4 g of palladium nitrate dihydrate salt and copper nitrate were added so that the weight ratio of palladium, copper and silver constituting the alloy fine particles was 63/27/10. In a metal salt aqueous solution in which 4.9 g of trihydrate salt and 1.8 g of silver nitrate are dissolved, 265 g of a trisodium citrate aqueous solution with a concentration of 30% by weight as a stabilizer and 129 g of an aqueous ferrous sulfate solution with a concentration of 25% by weight as a reducing agent. (Corresponding to 1.9 times the total number of moles of palladium nitrate, copper nitrate and silver nitrate) was added and stirred for 20 hours under a nitrogen atmosphere to obtain a dispersion of alloy fine particles. The average particle size of the alloy fine particles was 5 nm.
The obtained dispersion was washed with water using a centrifugal separator to remove impurities, and then dispersed in water to obtain a dispersion of alloy fine particles (5) having a concentration of 10% by weight. Next, a catalyst (9) was prepared in the same manner as in Example 3 except that the dispersion liquid of alloy fine particles (5) was used.
Treatment of nitrate nitrogen-containing water The nitrate nitrogen-containing water was treated under the same conditions as in Example 1 except that the catalyst (9) was used. The results of these treatments and the evaluation results of water repellency floatability (1) are shown in Table 1.
触媒(10)の調製
実施例３において、予めカーボンブラック（ケッチェンブラックインターナショナル（株）製：ケッチェンブラックＥＣ６００ＪＤ、平均粒子径３１ｎｍ、比表面積１２８０ｍ2／ｇ、結晶子径３．１ｎｍ）を硝酸に分散させ６０℃で１２時間攪拌した後、遠心分離器により水洗し、乾燥して親水性化したカーボンブラック（平均粒子径３１ｎｍ、比表面積１２５０ｍ2／ｇ、結晶子径３．０ｎｍ）を結晶性炭素化合物として用いた以外は同様にして触媒(10)を調製した。
硝酸性窒素含有水の処理
実施例１において、触媒(10)を用いた以外は同様の条件で硝酸性窒素含有水の処理を実施した。これらの処理の結果および撥水浮遊性（１）の評価結果を表1に示した。
Preparation of catalyst (10) In Example 3, carbon black (manufactured by Ketjen Black International Co., Ltd .: Ketjen Black EC600JD, average particle size 31 nm, specific surface area 1280 m 2 / g, crystallite size 3.1 nm) After stirring at 60 ° C. for 12 hours, the mixture was washed with water using a centrifugal separator and dried to make it hydrophilic (average particle size 31 nm, specific surface area 1250 m 2 / g, crystallite size 3.0 nm). A catalyst (10) was prepared in the same manner except that it was used as a functional carbon compound.
Treatment of nitrate nitrogen-containing water The nitrate nitrogen-containing water was treated under the same conditions as in Example 1 except that the catalyst (10) was used. The results of these treatments and the evaluation results of water repellency floatability (1) are shown in Table 1.
アリルアルコールの酸化反応
実施例１０と同様にして調製した触媒(10)９．０ｇを酢酸１５０ｍｌとサイナミルアルコール６．１ｇ（0.045mol）が入った反応容器に添加し、６０℃で３時間、酸素雰囲気下攪拌しながら反応させた。反応後に攪拌を停止したところ触媒は液面に浮遊した。反応液をガスクロマトグラフィーにより分析し、生成したサイナムアルデヒドを定量した。生成したサイナムアルデヒドは４７.８ｇで、収率は８１％であった。これらの評価結果を表２に示した。
Oxidation reaction of allyl alcohol 9.0 g of the catalyst (10) prepared in the same manner as in Example 10 was added to a reaction vessel containing 150 ml of acetic acid and 6.1 g (0.045 mol) of sinamyl alcohol, and at 60 ° C. for 3 hours. The reaction was allowed to stir in an oxygen atmosphere. When the stirring was stopped after the reaction, the catalyst floated on the liquid surface. The reaction solution was analyzed by gas chromatography, and the produced cynamaldehyde was quantified. The produced cynamaldehyde was 47.8 g, and the yield was 81%. The evaluation results are shown in Table 2.
撥油浮遊性（２）の評価
触媒(10)５ｇを１００ｍｌのベンゼンに分散させ、２００ｒｐｍで５分間撹拌した後、撹拌を停止し、触媒(10)の浮遊状態を観察し、以下の基準により評価した。結果を表２に示す。
触媒(10)が全量液面上に浮遊していた。 ：◎
触媒(10)の８０％以上が液面上に浮遊し、他は液中に分散していた。 ：○
触媒(10)の５０％〜８０％未満が液面上に浮遊し、他は液中に分散していた。 ：△
触媒(10)の５０未満が液面上に浮遊し、他は液中に分散あるいは沈降していた。：×
Evaluation of oil repellency floatability (2) Disperse 5 g of catalyst (10) in 100 ml of benzene, stir at 200 rpm for 5 minutes, stop stirring, observe the floating state of catalyst (10), and observe the following criteria evaluated. The results are shown in Table 2.
The entire amount of the catalyst (10) was floating on the liquid surface. : ◎
More than 80% of the catalyst (10) floated on the liquid surface, and the others were dispersed in the liquid. : ○
50% to less than 80% of the catalyst (10) floated on the liquid surface, and the others were dispersed in the liquid. : △
Less than 50 of the catalyst (10) floated on the liquid surface, and the others were dispersed or settled in the liquid. : ×
触媒(R1)の調製
実施例１において、カーボンブラックの代わりに活性炭（和光純薬工業（株）製：活性炭素粉末、平均粒子径５０μｍ、比表面積１１５５ｍ2／ｇ、結晶子径２ｎｍ以下）を用いた以外は同様にして触媒(R1)を調製した。
硝酸性窒素含有水の処理
実施例１において、触媒(R1)を用いた以外は同様の条件で硝酸性窒素含有水の処理を実施した。これらの処理の結果および撥水浮遊性（１）の評価結果を表1に示した。
Preparation of catalyst (R1) In Example 1, instead of carbon black, activated carbon (manufactured by Wako Pure Chemical Industries, Ltd .: activated carbon powder, average particle size 50 μm, specific surface area 1155 m 2 / g, crystallite size 2 nm or less) A catalyst (R1) was prepared in the same manner except that it was used.
Treatment of nitrate nitrogen-containing water In Example 1, the nitrate nitrogen-containing water was treated under the same conditions except that the catalyst (R1) was used. The results of these treatments and the evaluation results of water repellency floatability (1) are shown in Table 1.
触媒(R2)の調製
純水１００ｇに、金属換算で濃度が１０重量％となり、合金微粒子を構成する銅とパラジウムの重量比が２／１となるように硝酸銅および硝酸パラジウムを加え、これに、無定形炭素微粒子（御国色素（株）製：平均粒子径１０９ｎｍ）１９０ｇを加えて１時間撹拌した。次いで、凍結乾燥した後、Ｈ2−Ｎ2混合ガス雰囲気下、２５０℃で２時間加熱処理して触媒(R2)を調製した。
硝酸性窒素含有水の処理
実施例１において、触媒(R2)を用いた以外は同様の条件で硝酸性窒素含有水の処理を実施した。これらの処理の結果および撥水浮遊性（１）の評価結果を表1に示した。
Preparation of catalyst (R2) To 100 g of pure water, copper nitrate and palladium nitrate were added so that the concentration in terms of metal was 10% by weight and the weight ratio of copper and palladium constituting the alloy fine particles was 2/1. Then, 190 g of amorphous carbon fine particles (manufactured by Mikuni Dyeing Co., Ltd .: average particle size 109 nm) were added and stirred for 1 hour. Next, after lyophilization, a catalyst (R2) was prepared by heat treatment at 250 ° C. for 2 hours in an H 2 —N 2 mixed gas atmosphere.
Treatment of nitrate nitrogen-containing water In Example 1, the nitrate nitrogen-containing water was treated under the same conditions except that the catalyst (R2) was used. The results of these treatments and the evaluation results of water repellency floatability (1) are shown in Table 1.
アリルアルコールの酸化反応
比較例１と同様にして調製した触媒(R1)を用いた以外は実施例１１と同様にしてアリルアルコールの酸化反応を行い、結果を表２に示した。また、撥油浮遊性（２）の評価を行い、結果を表２に示した。
Allyl alcohol oxidation reaction Allyl alcohol oxidation reaction was carried out in the same manner as in Example 11 except that the catalyst (R1) prepared in the same manner as in Comparative Example 1 was used. The results are shown in Table 2. The oil repellency floatability (2) was evaluated and the results are shown in Table 2.
Claims (7)
Catalyst fine particles in which fine metal particles are supported on crystalline carbon particles, the average particle diameter of the fine catalyst particles is in the range of 5 nm to 10 μm, and the supported amount of the fine metal particles in the fine catalyst particles is 1 to Fine particles for catalyst, characterized by being in the range of 50% by weight.
The metal is one or two selected from Pt, Au, Ag, Pd, Ru, Cu, Ni, W, V, Mo, Fe, Rh, Co, Sn, Ti, In, Al, Ta, Sb, Cr The fine particle for catalyst according to claim 1, which is the metal or alloy described above.
The fine particles for catalyst according to claim 1 or 2, wherein the metal fine particles have an average particle diameter in the range of 1 to 50 nm.
The fine particles for catalyst according to any one of claims 1 to 3, wherein the crystalline carbon particles have an average particle size (primary particle size) in the range of 5 to 500 nm.
5. The catalyst fine particles according to claim 1, wherein the crystalline carbon particles have a specific surface area in the range of 20 to 3000 m 2 / g.
The fine particles for catalyst according to any one of claims 1 to 5, wherein the crystalline carbon particles have a graphite structure and a crystallite distance is in the range of 1 to 30 nm.
The said crystalline carbon particle consists of 1 type, or 2 or more types of crystalline carbon compounds chosen from carbon black, acetylene black, a carbon nanotube, carbon nanohorn, a carbon fiber, and graphite. Fine particles for catalyst.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004363036A JP4707382B2 (en) | 2004-12-15 | 2004-12-15 | Nitrate nitrogen-containing water treatment catalyst and method for producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004363036A JP4707382B2 (en) | 2004-12-15 | 2004-12-15 | Nitrate nitrogen-containing water treatment catalyst and method for producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2006167580A true JP2006167580A (en) | 2006-06-29 |
| JP4707382B2 JP4707382B2 (en) | 2011-06-22 |
Family
ID=36668882
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004363036A Active JP4707382B2 (en) | 2004-12-15 | 2004-12-15 | Nitrate nitrogen-containing water treatment catalyst and method for producing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4707382B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009172574A (en) * | 2007-12-25 | 2009-08-06 | Jgc Catalysts & Chemicals Ltd | Metal particle carrying catalyst and its manufacturing method |
| JP2011101880A (en) * | 2009-11-10 | 2011-05-26 | Korea Inst Of Energy Research | Cellulose catalyst with metal catalyst nanoparticle supported on the surface of surface-treated native cellulose fiber, and method of manufacturing the same |
| JP2011177646A (en) * | 2010-03-01 | 2011-09-15 | Japan Atomic Energy Agency | Catalyst for decomposing nitrate ion reductively |
| JP2012050924A (en) * | 2010-08-31 | 2012-03-15 | National Institute Of Advanced Industrial Science & Technology | Catalyst and method for gasifying lignin with supercritical water used as reaction field |
| CN103545536A (en) * | 2013-10-22 | 2014-01-29 | 上海交通大学 | Carbon fiber supported metal catalyst as well as preparation method and application thereof |
| JP2015009224A (en) * | 2013-07-01 | 2015-01-19 | 荏原工業洗浄株式会社 | Treatment method for chemical cleaning waste liquid |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09183614A (en) * | 1995-11-10 | 1997-07-15 | Dsm Nv | Preparation of hydroxyl ammonium salt |
| JP2002159851A (en) * | 2000-11-24 | 2002-06-04 | Japan Science & Technology Corp | Adsorbent, catalyst, and catalyst carrier comprising single-layer carbon nanohorn |
| JP2003036859A (en) * | 2001-07-24 | 2003-02-07 | Asahi Glass Co Ltd | Solid polymer type fuel cell and its fabrication method |
-
2004
- 2004-12-15 JP JP2004363036A patent/JP4707382B2/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09183614A (en) * | 1995-11-10 | 1997-07-15 | Dsm Nv | Preparation of hydroxyl ammonium salt |
| JP2002159851A (en) * | 2000-11-24 | 2002-06-04 | Japan Science & Technology Corp | Adsorbent, catalyst, and catalyst carrier comprising single-layer carbon nanohorn |
| JP2003036859A (en) * | 2001-07-24 | 2003-02-07 | Asahi Glass Co Ltd | Solid polymer type fuel cell and its fabrication method |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009172574A (en) * | 2007-12-25 | 2009-08-06 | Jgc Catalysts & Chemicals Ltd | Metal particle carrying catalyst and its manufacturing method |
| JP2011101880A (en) * | 2009-11-10 | 2011-05-26 | Korea Inst Of Energy Research | Cellulose catalyst with metal catalyst nanoparticle supported on the surface of surface-treated native cellulose fiber, and method of manufacturing the same |
| US9254483B2 (en) | 2009-11-10 | 2016-02-09 | Korea Institute Of Energy Research | Catalysts having metal nano-particle catalyst supported on surface-treated natural cellulose fibers and preparation method thereof |
| US9259728B2 (en) | 2009-11-10 | 2016-02-16 | Korea Institute Of Energy Research | Catalysts having metal nano-particle catalyst supported on surface-treated natural cellulose fibers and preparation method thereof |
| JP2011177646A (en) * | 2010-03-01 | 2011-09-15 | Japan Atomic Energy Agency | Catalyst for decomposing nitrate ion reductively |
| JP2012050924A (en) * | 2010-08-31 | 2012-03-15 | National Institute Of Advanced Industrial Science & Technology | Catalyst and method for gasifying lignin with supercritical water used as reaction field |
| JP2015009224A (en) * | 2013-07-01 | 2015-01-19 | 荏原工業洗浄株式会社 | Treatment method for chemical cleaning waste liquid |
| CN103545536A (en) * | 2013-10-22 | 2014-01-29 | 上海交通大学 | Carbon fiber supported metal catalyst as well as preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4707382B2 (en) | 2011-06-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5105602B2 (en) | Method for producing noble metal alloy catalyst and catalyst prepared thereby | |
| JP5628225B2 (en) | Metal-containing colloidal particle-supported carrier and method for producing the same | |
| JP4649281B2 (en) | Treatment method for nitrate-containing water | |
| JP6653875B2 (en) | Method for producing platinum catalyst and fuel cell using the same | |
| JP5665743B2 (en) | Continuous production method of catalyst | |
| JP3870282B2 (en) | Dispersed and stabilized liquid containing catalyst nanoparticles | |
| CN109482177A (en) | A kind of nano-noble metal catalyst preparation method | |
| JP2007123195A (en) | Method of manufacturing catalyst | |
| JP7157456B2 (en) | PdRu Solid Solution Nanoparticles, Manufacturing Method and Catalyst Therefor, Method for Controlling Crystal Structure of PtRu Solid Solution Nanoparticles, and AuRu Solid Solution Nanoparticles and Manufacturing Method Therefor | |
| JP5539091B2 (en) | Method for producing metal particle supported catalyst, metal particle supported catalyst and reaction method. | |
| JP5398082B2 (en) | Method for preparing ruthenium catalyst for cycloolefin production, method for producing cycloolefin, and production apparatus | |
| JP4707382B2 (en) | Nitrate nitrogen-containing water treatment catalyst and method for producing the same | |
| JP5506075B2 (en) | Platinum ordered lattice catalyst for fuel cell and method for producing the same | |
| JP5548548B2 (en) | Method for producing metal particle supported catalyst, metal particle supported catalyst and reaction method. | |
| CN112186199B (en) | Catalyst for solid polymer fuel cell and preparation method thereof | |
| JP2010089032A (en) | Metal-particle supporting catalyst, and method of producing the same | |
| JP2003320249A (en) | Metal-carrying catalyst and production of the same and solid polymer electrolyte type fuel cell using the same | |
| JP2002001095A (en) | Colloidal solution and method for producing colloidal solution | |
| JP2002248350A (en) | Method for preparing alloy catalyst and method for manufacturing solid high polymer type fuel cell | |
| RU2446009C1 (en) | Method of preparing platinum-ruthenium electrocatalysts | |
| WO2016143784A1 (en) | Method for manufacturing platinum catalyst, and fuel cell using same | |
| JP3978470B2 (en) | Cathode catalyst for fuel cell and fuel cell using the same | |
| CN114937782B (en) | Supported metal-based catalyst and preparation method thereof | |
| CN115555017B (en) | Dechlorination type carbon five petroleum resin hydrogenation catalyst and preparation method thereof | |
| CN114150342B (en) | Superfine platinum-based alloy nanowire, preparation method and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20071106 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20100104 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20101012 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20101210 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20110315 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20110315 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 4707382 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |