JP2006008724A - 水性分散体及びその利用 - Google Patents
水性分散体及びその利用 Download PDFInfo
- Publication number
- JP2006008724A JP2006008724A JP2004183345A JP2004183345A JP2006008724A JP 2006008724 A JP2006008724 A JP 2006008724A JP 2004183345 A JP2004183345 A JP 2004183345A JP 2004183345 A JP2004183345 A JP 2004183345A JP 2006008724 A JP2006008724 A JP 2006008724A
- Authority
- JP
- Japan
- Prior art keywords
- meth
- acrylic acid
- aqueous dispersion
- copolymer
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000006185 dispersion Substances 0.000 title claims abstract description 75
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000002253 acid Substances 0.000 claims abstract description 41
- 239000000539 dimer Substances 0.000 claims abstract description 30
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229920001577 copolymer Polymers 0.000 claims abstract description 18
- 150000001341 alkaline earth metal compounds Chemical class 0.000 claims abstract description 10
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims abstract description 10
- 150000001339 alkali metal compounds Chemical class 0.000 claims abstract description 9
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 5
- 239000005977 Ethylene Substances 0.000 claims description 33
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 32
- 238000000576 coating method Methods 0.000 claims description 18
- 239000011248 coating agent Substances 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 11
- 239000002585 base Substances 0.000 claims description 8
- 239000000758 substrate Substances 0.000 claims description 8
- 239000011521 glass Substances 0.000 claims description 7
- 229910001413 alkali metal ion Inorganic materials 0.000 claims description 6
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 239000000155 melt Substances 0.000 claims description 2
- 229920005992 thermoplastic resin Polymers 0.000 claims description 2
- 239000007769 metal material Substances 0.000 abstract description 9
- 230000035699 permeability Effects 0.000 abstract description 8
- 238000007789 sealing Methods 0.000 abstract description 7
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- 229920005601 base polymer Polymers 0.000 description 23
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 19
- 239000007787 solid Substances 0.000 description 13
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 12
- 239000000203 mixture Substances 0.000 description 12
- 235000011114 ammonium hydroxide Nutrition 0.000 description 11
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- 239000008399 tap water Substances 0.000 description 10
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- 229920000642 polymer Polymers 0.000 description 9
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- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 8
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- 238000000034 method Methods 0.000 description 7
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- -1 methyl methacrylate Chemical class 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
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- 150000004665 fatty acids Chemical class 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
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- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 4
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 4
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 229920000554 ionomer Polymers 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
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- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
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- 150000002500 ions Chemical class 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
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- CFQZKFWQLAHGSL-FNTYJUCDSA-N (3e,5e,7e,9e,11e,13e,15e,17e)-18-[(3e,5e,7e,9e,11e,13e,15e,17e)-18-[(3e,5e,7e,9e,11e,13e,15e)-octadeca-3,5,7,9,11,13,15,17-octaenoyl]oxyoctadeca-3,5,7,9,11,13,15,17-octaenoyl]oxyoctadeca-3,5,7,9,11,13,15,17-octaenoic acid Chemical compound OC(=O)C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\OC(=O)C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\OC(=O)C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\C=C CFQZKFWQLAHGSL-FNTYJUCDSA-N 0.000 description 2
- 229920003067 (meth)acrylic acid ester copolymer Polymers 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000003851 corona treatment Methods 0.000 description 2
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 229920005669 high impact polystyrene Polymers 0.000 description 2
- 239000004797 high-impact polystyrene Substances 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
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- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
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- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
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- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
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- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
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- 244000043261 Hevea brasiliensis Species 0.000 description 1
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- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
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Abstract
【解決手段】 (メタ)アクリル酸含量が5〜30重量%のエチレン・(メタ)アクリル酸共重合体(A)と、該共重合体(A)100重量部に対し5〜500重量部の割合の酸価が100〜700mgKOH/gのダイマー酸又はその誘導体(B)と、水とを含有し、且つ、該共重合体(A)が、そのカルボキシル基を基準にして40〜500モル%の低級脂肪族アミン、アルカリ金属化合物又はアルカリ土類金属化合物等で水中に分散されてなる水性分散体。
【選択図】 なし
Description
工業的に入手可能なダイマー酸としては、例えばハリダイマー200、300(ハリマ化成(株)製)、パーサダイム228、216、エンボール1018、1019、1061、1062(コグニス(株)製)、水素添加ダイマー酸としては例えば、プリボール1029(Unichema社製)、エンボール1008(コグニス(株)製)などを挙げることができ、いずれも本発明において使用することができる。酸価が上記範囲のダイマー酸又はその誘導体を使用することにより、水分散性良好な水性分散体を得ることができ、しかもそのような水性分散体を疎水性重合体、例えばOPPフィルムなどに塗布した場合に濡れ性を高め、塗工性を改善することができ、またヒートシール強度が大きく、透湿性の低いシール層を形成させることができる。また金属材料に塗布した場合において、耐湿性能に優れる防錆塗膜を形成させることができる。ダイマー酸又はその誘導体としてはまた、水性分散体の使用目的によっても異なるが、環球法軟化点が、70〜150℃、とくに75〜140℃程度のものを使用するのが好ましい。
(1)ベースポリマー
BP−1:エチレン・メタクリル酸共重合体(メタクリル酸含量20重量%、メルトフローレート(MFR)300g/10分)
BP−2:エチレン・アクリル酸共重合体(アクリル酸含量20重量%、MFR300g/10分)
(2)イオン源
アンモニア水溶液:濃度29重量%(関東化学(株)製)
(3)ダイマー酸
DA−1:ダイマー酸(ハリマ化成(株)製HD270S、酸価193mgKOH/g)
DA−2:ダイマー酸(ハリマ化成(株)製HD700、酸価195mgKOH/g)
(1)pH
(株)堀場製作所製pH METER F−12を用いて測定した。
(2)粘度
Brookfield粘度計を用いて23℃で測定した。単位(mPa・s)
(3)粒径
(株)堀場製作所製LB−500を用いて測定した。メジアン径を粒径とした。単位(nm)
OA紙(王子製紙(株)製上質紙、製品名Golden、厚さ50μm)上に、水性分散体を厚さの目標 μでNo.18バーコーターを用いて塗布し、100℃で2分乾燥した。得られた塗工紙につき、JIS K7129に準じ、湿度90%、温度50℃の条件で透湿性の評価を実施した。単位(g/m2・h)
コロナ処理した厚さ50μmのOPPフィルムに、水性分散体を厚さの目標10μでNo.18バーコーターを用いて塗布し、100℃で3分乾燥した。得られたOPPフィルム2枚を、塗布面同士が接触するように重ね合わせ、温度120℃、圧力2kg/cm2、シール時間0.5秒の条件でヒートシールしてからヒートシール強度を測定した。単位(g/15mm)
ベースポリマー(BP−1)63g、ダイマー酸(DA−1)7g、イオン交換水272g、アンモニア水溶液12.0gをオートクレーブに加え、温度150℃、攪拌速度1200rpmで1.5時間攪拌した。その後水道水で冷却し、固形分濃度20重量%の水性分散体1を得た。
ベースポリマー(BP−1)49g、ダイマー酸(DA−1)21g、イオン交換水272g、アンモニア水溶液12.0gをオートクレーブに加え、温度150℃、攪拌速度1200rpmで1.5時間攪拌した。その後水道水で冷却し、固形分濃度20重量%の水性分散体2を得た。
ベースポリマー(BP−1)63g、ダイマー酸(DA−2)7g、イオン交換水272g、アンモニア水溶液12.0gをオートクレーブに加え、温度150℃、攪拌速度1200rpmで1.5時間攪拌した。その後水道水で冷却し、固形分濃度20重量%の水性分散体3を得た。
ベースポリマー(BP−1)49g、ダイマー酸(DA−1)21g、イオン交換水272g、アンモニア水溶液12.0gをオートクレーブに加え、温度150℃、攪拌速度1200rpmで1.5時間攪拌した。その後水道水で冷却し、固形分濃度20重量%の水性分散体4を得た。
ベースポリマー(BP−2)63g、ダイマー酸(DA−1)7g、イオン交換水270g、アンモニア水溶液14.3gをオートクレーブに加え、温度150℃、攪拌速度1200rpmで1.5時間攪拌した。その後水道水で冷却し、固形分濃度20重量%の水性分散体5を得た。
ベースポリマー(BP−2)49g、ダイマー酸(DA−1)21g、イオン交換水270g、アンモニア水溶液14.3gをオートクレーブに加え、温度150℃、攪拌速度1200rpmで1.5時間攪拌した。その後水道水で冷却し、固形分濃度20重量%の水性分散体6を得た。
ベースポリマー(BP−2)63g、ダイマー酸(DA−2)7g、イオン交換水270g、アンモニア水溶液14.3gをオートクレーブに加え、温度150℃、攪拌速度1200rpmで1.5時間攪拌した。その後水道水で冷却し、固形分濃度20重量%の水性分散体7を得た。
ベースポリマー(BP−2)49g、ダイマー酸(DA−2)21g、イオン交換水270g、アンモニア水溶液14.3gをオートクレーブに加え、温度150℃、攪拌速度1200rpmで1.5時間攪拌した。その後水道水で冷却し、固形分濃度20重量%の水性分散体8を得た。
ベースポリマー(BP−1)70g、イオン交換水272g、アンモニア水溶液12.0gをオートクレーブに加え、温度150℃、攪拌速度1200rpmで1.5時間攪拌した。その後水道水で冷却し、固形分濃度20重量%の水性分散体9を得た。
ベースポリマー(BP−2)70g、イオン交換水270g、アンモニア水溶液14.3gをオートクレーブに加え、温度150℃、攪拌速度1200rpmで1.5時間攪拌した。その後水道水で冷却し、固形分濃度20重量%の水性分散体10を得た。
Claims (8)
- (メタ)アクリル酸含量が5〜30重量%のエチレン・(メタ)アクリル酸共重合体(A)と、該共重合体(A)100重量部に対し5〜100重量部の割合の酸価が100〜700mgKOH/gのダイマー酸又はその誘導体(B)と、水とを含有し、且つ、該共重合体(A)が、該共重合体(A)のカルボキシル基を基準にして40〜500モル%の低級脂肪族アミン、アルカリ金属化合物もしくはアルカリ金属イオン又はアルカリ土類金属化合物もしくはアルカリ土類金属イオンで水中に分散されてなる水性分散体。
- エチレン・(メタ)アクリル酸共重合体(A)のメルトフローレート(JIS K7210−1999、190℃、2160g荷重)が1〜2000g/10分である請求項1記載の水性分散体。
- エチレン・(メタ)アクリル酸共重合体(A)が2種以上のエチレン・(メタ)アクリル酸共重合体混合成分からなり、その平均(メタ)アクリル酸含量が10〜30重量%である請求項1又は2記載の水性分散体。
- 2種以上のエチレン・(メタ)アクリル酸共重合体混合成分が、(メタ)アクリル酸含量が8重量%以上15重量%未満のエチレン・(メタ)アクリル酸共重合体と(メタ)アクリル酸含量が15〜30重量%のエチレン・(メタ)アクリル酸共重合体の混合成分である請求項3記載の水性分散体。
- 低級脂肪族アミンが、一般式RmNH3−m(式中、RはCnH2n+1−基又はHO−CkH2k−基、但しnは1、2、3又は4、kは1、2又は3、mは0、1、2又は3)で示されるものである請求項1〜4記載の水性分散体。
- 請求項1〜5の水性分散体を塗布、乾燥して得られる塗膜層。
- 基材に請求項1〜5の水性分散体を塗布、乾燥してなる積層体。
- 基材が、熱可塑性樹脂、金属又はガラスである請求項7記載の積層体。
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JP2006282968A (ja) * | 2005-04-05 | 2006-10-19 | Mitsui Chemicals Inc | 水分散型ヒートシール剤用組成物 |
JP2011046113A (ja) * | 2009-08-27 | 2011-03-10 | Toyo-Morton Ltd | 積層体及び包装材 |
WO2011043271A1 (ja) * | 2009-10-09 | 2011-04-14 | 三井・デュポンポリケミカル株式会社 | アイオノマー組成物並びに成形体及びその製造方法 |
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JP2012187134A (ja) * | 2011-03-08 | 2012-10-04 | Du Pont Mitsui Polychem Co Ltd | ゴルフボール材料用アイオノマー組成物及びゴルフボール |
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JP2015151494A (ja) * | 2014-02-17 | 2015-08-24 | 三井・デュポンポリケミカル株式会社 | 難燃性樹脂組成物及び成形体 |
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JP2003276126A (ja) * | 2002-03-25 | 2003-09-30 | Du Pont Mitsui Polychem Co Ltd | 積層体及び水分散体 |
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JP2011046113A (ja) * | 2009-08-27 | 2011-03-10 | Toyo-Morton Ltd | 積層体及び包装材 |
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