JP2002224678A - Water quality improving agent and manufacturing method thereof and treated water treated by water quality improving agent - Google Patents
Water quality improving agent and manufacturing method thereof and treated water treated by water quality improving agentInfo
- Publication number
- JP2002224678A JP2002224678A JP2001024591A JP2001024591A JP2002224678A JP 2002224678 A JP2002224678 A JP 2002224678A JP 2001024591 A JP2001024591 A JP 2001024591A JP 2001024591 A JP2001024591 A JP 2001024591A JP 2002224678 A JP2002224678 A JP 2002224678A
- Authority
- JP
- Japan
- Prior art keywords
- water quality
- improving agent
- quality improving
- water
- shells
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、安全で安価な、有
害物質分解・除去効果に優れる水質改善剤、詳細には、
廃棄処理された鉱石類及び貝殻類から形成されてなる水
質改善剤に関する。TECHNICAL FIELD The present invention relates to a water quality improving agent which is safe and inexpensive and has an excellent effect of decomposing and removing harmful substances.
The present invention relates to a water quality improver formed from discarded ores and shells.
【０００２】[0002]
【従来の技術及び発明が解決しようとする課題】従来か
ら、環境改善の高まりの一端として、鉱石類から形成さ
れたセラミックス等を水質改善剤として用いることが知
られている。しかし、このような鉱石類単独で形成され
たセラミックスでは、浄化作用等の速効性がない等、そ
の効果に限度がある。2. Description of the Related Art It has been known that ceramics and the like formed from ores are used as a water quality improving agent as one of the increasing environmental improvements. However, such ceramics formed by ores alone have a limited effect, for example, there is no immediate effect such as purification action.
【０００３】一方、牡蛎殻、ホタテ貝の貝殻、北寄貝の
貝殻等、天然の貝殻には、抗菌作用があることが知られ
ている。特に、北寄貝の殻には、牡蛎殻の２０倍もの抗
菌作用があるとの報告もある。更に、この北寄貝の殻に
は、野菜等に付着した環境ホルモンや農薬を高率で除去
できるとの報告もある。これらの貝殻は、産業廃棄物と
なっているため、コスト面でも安く入手ができる。しか
し、このような貝殻類単独では、菌に対する効果につい
ては知られているが、環境ホルモンや農薬等の有害物質
に対する分解・除去効果については知見が得られていな
い。しかも、貝殻類を水質改善剤として応用する技術
は、未だ確立されていない。また、このような貝殻類を
単独で水に使用すれば、貝殻類が有するカルシウム成分
等のため、得られる水の成分に偏りが生じ、ミネラルの
バランスが良くないという問題もある。On the other hand, natural shells such as oyster shells, scallop shells, and northern shells are known to have an antibacterial effect. In particular, it has been reported that the shell of northern mussel has an antibacterial activity 20 times that of oyster shell. Furthermore, it has been reported that the shell of the northern shellfish can remove environmental hormones and pesticides attached to vegetables and the like at a high rate. Since these shells are industrial waste, they can be obtained at low cost. However, such shells alone are known for their effects on bacteria, but no information has been obtained on their decomposition / removal effects on harmful substances such as environmental hormones and pesticides. Moreover, the technology of using shells as a water quality improving agent has not yet been established. In addition, when such shells are used alone in water, there is a problem that the resulting water component is biased due to the calcium component of the shells and the like, and the mineral balance is not good.
【０００４】また、生野菜や果物を洗浄、消毒する際に
は、特に安全性を高めるため、毒性の強い病原性大腸菌
Ｏ−１５７に対しても効果があるといわれる次亜塩素酸
ナトリウムが使用されている。しかし、この場合、生野
菜や果物に付着した塩素臭を取り除くため、更に真水で
洗い流す手間がかかる。When washing and disinfecting fresh vegetables and fruits, sodium hypochlorite, which is also said to be effective against highly toxic pathogenic Escherichia coli O-157, is used to enhance the safety. Have been. However, in this case, in order to remove the chlorine odor adhering to the raw vegetables and fruits, it takes time and effort to wash out with fresh water.
【０００５】そこで、本発明は、安全で安価な、有害物
質分解・除去効果に優れる水質改善剤を提供することを
目的とする。[0005] Therefore, an object of the present invention is to provide a safe and inexpensive water quality improving agent having an excellent effect of decomposing and removing harmful substances.
【０００６】[0006]
【課題を解決するための手段】本発明者は、鋭意研究し
た結果、安価に入手し易い鉱石類と貝殻類とから形成し
た粉状物又はセラミックスが、前記目的を達成し得るこ
との知見を得た。Means for Solving the Problems As a result of intensive studies, the present inventor has found that powder or ceramics formed from ores and shells which are easily available at low cost can achieve the above object. Obtained.
【０００７】本発明は、前記知見に基づきなされたもの
で、廃棄処理された鉱石類と、廃棄処理された貝殻類と
から形成されてなる水質改善剤を提供することにより、
前記目的を達成したものである。[0007] The present invention has been made based on the above findings, and provides a water quality improving agent formed from discarded ore and discarded shells.
The above object has been achieved.
【０００８】また、本発明は、前記水質改善剤を製造す
る方法であって、鉱石類及び貝殻類を含む５φ前後迄の
粒状物を形成する破砕工程と、前記粒状物から１０００
メッシュの統一粒子を形成する粉砕工程と、５００〜９
００℃で、３〜８時間、前記統一粒子を焼成する焼成工
程と、を少なくとも含む水質改善剤の製造方法を提供す
るものである。The present invention also relates to a method for producing the water quality improving agent, comprising a crushing step of forming granules up to about 5φ including ores and shells,
A pulverizing step of forming uniform particles of a mesh;
And baking the unified particles at 00 ° C. for 3 to 8 hours.
【０００９】また、本発明は、前記水質改善剤を製造す
る方法であって、鉱石類及び貝殻類を含む５φ前後迄の
粒状物を形成する破砕工程と、前記粒状物から１０００
メッシュの統一粒子を形成する粉砕工程と、前記統一粒
子を含む粘土状物を形成する混練工程と、前記粘度状物
から成型物を形成する成型工程と、５５０〜１２００℃
で、６〜１５時間、前記成型物を焼成する焼成工程と、
を少なくとも含む水質改善剤の製造方法を提供するもの
である。The present invention also relates to a method for producing the water quality improving agent, which comprises a crushing step of forming granules up to about 5φ including ores and shells,
A pulverizing step of forming uniform particles of the mesh, a kneading step of forming a clay-like material containing the uniform particles, a molding step of forming a molded product from the viscous material, and 550 to 1200 ° C.
A firing step of firing the molded product for 6 to 15 hours;
It is intended to provide a method for producing a water quality improving agent containing at least:
【００１０】また、本発明は、前記水質改善剤を使用し
て処理された処理水を提供するものである。[0010] The present invention also provides a treated water treated using the water quality improving agent.
【００１１】[0011]
【発明の実施の形態】以下、本発明の水質改善剤をその
好ましい実施形態に基づいて詳細に説明する。本発明の
水質改善剤は、その原料として鉱石類及び貝殻類が用い
られる。これらの鉱石類及び貝殻類としては、何れも安
価に入手できる点で、廃棄処理されたものが使用され
る。BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the water quality improving agent of the present invention will be described in detail based on preferred embodiments. The ore and shellfish are used as raw materials for the water quality improving agent of the present invention. As these ores and shells, those that have been discarded are used because they can be obtained at low cost.
【００１２】本発明に使用される鉱石類としては、半導
体等の用途に使用された後に産業廃棄物となったもの等
が用いられる。そのような鉱石類としては、長石群、黒
雲母、ゼオライト、金紅石、角閃石類、電気石、活性白
土、珪藻類、ラジウム、ゲルマニウム、カリウム、白金
等を含む鉱石類等が挙げられる。これらの各成分は、鉱
石類中に一種単独で含まれていても良く、二種以上混合
されて含まれていても良い。As the ores used in the present invention, those which have become industrial waste after being used for applications such as semiconductors are used. Examples of such ores include ores including feldspars, biotite, zeolite, auburnite, amphibolite, tourmaline, activated clay, diatoms, radium, germanium, potassium, platinum, and the like. Each of these components may be contained alone in the ore, or may be contained as a mixture of two or more.
【００１３】前記成分を含む鉱石類としては、例えば、
花崗岩類等が好ましく挙げられ、これを原料として使用
する際には、焼成した花崗岩類や、原石の花崗岩類等と
して用いられる。尚、この花崗岩類中には電気石の含有
割合が少ないため、該花崗岩類を使用する場合には、電
気石を更に添加することが好ましい。また、鉱石類に
は、二酸化チタンを添加することも好ましい。Examples of ores containing the above components include, for example,
Granites and the like are preferably mentioned, and when they are used as a raw material, they are used as calcined granites or raw stone granites. Incidentally, since the content of tourmaline in the granites is small, it is preferable to further add tourmaline when using the granites. It is also preferable to add titanium dioxide to ores.
【００１４】本発明に使用される貝殻類としては、食品
等の用途に使用された後に産業廃棄物となったもの等が
用いられる。そのような貝殻類としては、牡蛎の貝殻、
ホタテの貝殻、北寄貝の貝殻等の貝殻類が挙げられる。
これらの貝殻類は、一種単独で使用されても良く、二種
又は三種を混合して使用されても良い。貝殻類として
は、特に、抗菌効果、有害物質分解・除去効果を向上さ
せる点で、北寄貝の貝殻を使用することが好ましい。As the shells used in the present invention, those used as industrial waste after being used for foods and the like are used. Such shells include oyster shells,
Shells such as scallop shells and northern shells.
These shells may be used alone or in a combination of two or three. As shells, it is particularly preferable to use shells of northern shellfish from the viewpoint of improving the antibacterial effect and the effect of decomposing and removing harmful substances.
【００１５】また、本発明の水質改善剤には、必要に応
じて、多孔質の土（粘土）等を添加することができる。The water quality improving agent of the present invention may optionally contain a porous soil (clay) or the like.
【００１６】前記鉱石類及び前記貝殻類及びその他の添
加物を原料として形成された本発明の水質改善剤中にお
ける各成分の配合割合は、その用途に応じて適宜調整さ
れる。特に、本発明の水質改善剤を飲料水用として使用
する場合には、水質改善剤中、鉱石類成分を２０〜４５
重量％、貝殻類成分を３〜９重量％含有することが好ま
しい。この場合、水質改善剤には、他の成分として、粘
土等のバインダーが含まれる。また、この場合、通常固
形状セラミックスの形態で使用される。また、本発明の
水質改善剤を地下水処理や廃水処理用等として使用する
場合には、水質改善剤中、鉱石類成分を８５〜９５重量
％、貝殻類成分を５〜１５重量％含有することが好まし
い。この場合、通常粉状物の形態で使用される。The mixing ratio of each component in the water quality improving agent of the present invention formed using the ores, the shells and other additives as raw materials is appropriately adjusted according to the use. In particular, when the water quality improver of the present invention is used for drinking water, the ore component in the water quality improver is 20 to 45%.
% By weight, and preferably 3 to 9% by weight of shellfish components. In this case, the water quality improving agent contains a binder such as clay as another component. In this case, it is usually used in the form of a solid ceramic. When the water quality improving agent of the present invention is used for groundwater treatment or wastewater treatment, the water quality improving agent contains 85 to 95% by weight of an ore component and 5 to 15% by weight of a shell component. Is preferred. In this case, it is usually used in the form of a powder.
【００１７】本発明の水質改善剤は、その用途等に応じ
て、種々の形態として使用される。本発明の水質改善剤
の形態としては、粉状物や、固形状セラミックス等の形
態が挙げられる。粉状物としては、原料を粉末した後に
焼成して得られるパウダーセラミックス等が挙げられ、
特に、本発明の水質改善剤を有害物質除去剤として使用
する場合に有用である。一方、固形状セラミックスとし
ては、球体状のセラミックス（セラミックスボール）等
が挙げられる。特に、本発明の水質改善剤を使用して飲
料用の水を得ようとする場合には、本発明の水質改善剤
を、複数種の固形状セラミックスの形態として組み合わ
せて使用することが好ましい。The water quality improver of the present invention is used in various forms depending on the use and the like. Examples of the form of the water quality improver of the present invention include forms such as powdery substances and solid ceramics. Examples of the powdery material include powder ceramics obtained by powdering and firing the raw material,
It is particularly useful when the water quality improver of the present invention is used as a harmful substance remover. On the other hand, examples of the solid ceramics include spherical ceramics (ceramic balls). In particular, when water for drinking is to be obtained using the water quality improving agent of the present invention, it is preferable to use the water quality improving agent of the present invention in combination as a plurality of types of solid ceramics.
【００１８】本発明の水質改善剤は、その製造方法に特
に制限されないが、次の方法により製造されることが好
ましい。即ち、本発明の水質改善剤を粉状物の形態とし
て使用する場合には、塵芥除去、洗浄、乾燥、破砕、粉
砕及び混合それぞれの工程を経て、粉状物を製造する。
また、本発明の水質改善剤を固形状セラミックスの形態
として使用する場合には、前記各工程に加えて更に、混
錬、圧縮、成型、乾燥及び焼成それぞれの工程を経て、
固形状セラミックスを製造する。Although the method for producing the water quality improving agent of the present invention is not particularly limited, it is preferably produced by the following method. That is, when the water quality improving agent of the present invention is used in the form of a powder, the powder is produced through the steps of dust removal, washing, drying, crushing, crushing and mixing.
Further, when the water quality improver of the present invention is used in the form of a solid ceramic, in addition to the above steps, further kneading, compression, molding, drying and firing each step,
Manufacture solid ceramics.
【００１９】以下、前記製造方法における各工程につい
て詳述する。塵芥除去工程においては、廃棄処理された
鉱石類及び廃棄処理された貝殻類の中から適切なものを
選別し、原料としての鉱石類及び貝殻類それぞれが有す
る不用物を除去する。Hereinafter, each step in the above-mentioned manufacturing method will be described in detail. In the garbage removal step, appropriate ones are selected from the ore and the shells that have been discarded, and the ores and shells that are used as raw materials are removed.
【００２０】洗浄工程においては、不用物を除去した原
料について、数回に渡り十分な洗浄を行う。その後、検
品し、所定の基準を満たしたものを原料として扱う。In the cleaning step, the raw material from which the unnecessary substances have been removed is sufficiently cleaned several times. After that, they are inspected and those satisfying the predetermined criteria are handled as raw materials.
【００２１】乾燥工程においては、洗浄した原料を天日
と乾燥設備とで乾燥し、含有水分を最大限除去する。特
に、貝殻類に関しては、洗浄、乾燥工程において、内蔵
を除去し、洗浄を十分に行った後、第１層の外皮部分を
剥離し、洗浄、乾燥し、“ガラ洗浄器”にて洗浄し、貝
殻全体に有する不純物を完全に除去する。In the drying step, the washed raw material is dried between the sun and a drying facility to remove the contained water to the maximum. In particular, regarding shells, in the washing and drying steps, after removing the internal parts and performing sufficient washing, the outer layer of the first layer is peeled off, washed, dried, and washed with a “glass washer”. , And completely remove impurities contained in the whole shell.
【００２２】破砕工程においては、鉱石類については、
その粒状に応じ、加工機械等の内容と工程数が変動する
が、数段階で５０〜１００φ位の形状のものを５φ前後
迄の形状とする。鉱石類の粒状によっては、４段階以上
で、５φ前後迄の形状とする場合もある。一方、貝殻類
についても、鉱石類と同様に、前記の３段階で５φ前後
迄の形状とする。貝殻類は、その粒状がほぼ一定の形状
であるため、通常３段階で５φ前後迄の形状とすること
が可能である。In the crushing step, ores are
Depending on the granularity, the contents of the processing machine and the number of steps vary, but the shape of about 50 to 100 φ is changed to about 5 φ in several steps. Depending on the granularity of the ore, the shape may be up to about 5φ in four or more stages. On the other hand, shells also have a shape of up to around 5φ in the above three stages, similarly to ores. Since shells have a substantially uniform grain shape, they can be generally formed into a shape of about 5φ in three stages.
【００２３】粉砕工程は、前記破砕工程で所定の形状と
した原料としての鉱石類及び貝殻類を、全て同一形状の
粒子とすることを目的とする。この粉砕工程において
は、１０００メッシュを統一粒子として選別する。尚、
その粒子にならないものは、再度繰り返し加工機械を通
し、統一粒子とする。The purpose of the pulverizing step is to make ores and shells as raw materials of a predetermined shape in the crushing step into particles of the same shape. In this pulverization step, 1000 meshes are selected as unified particles. still,
Those that do not become particles are repeatedly passed through a processing machine again to be unified particles.
【００２４】混合工程においては、得られた統一粒子を
混合する。この際、統一粒子をそのまま混合しても良
く、また統一粒子を焼成した後に混合しても良い。ここ
で、統一粒子を焼成する場合、焼成温度は、好ましくは
５００〜９００℃、更に好ましくは５５０〜８００℃で
ある。また、統一粒子の焼成時間は、好ましくは３〜８
時間、更に好ましくは４〜６時間である。尚、この焼成
温度及び焼成時間については、使用する統一粒子の種類
等に応じて適宜調整する。本発明の水質改善剤を粉状物
として使用する場合には、以上の工程で終了する。In the mixing step, the obtained unified particles are mixed. At this time, the unified particles may be mixed as they are, or may be mixed after firing the unified particles. Here, when baking the unified particles, the baking temperature is preferably from 500 to 900C, more preferably from 550 to 800C. The firing time of the unified particles is preferably 3 to 8
Time, more preferably 4 to 6 hours. The sintering temperature and the sintering time are appropriately adjusted according to the type of the unified particles to be used and the like. When the water quality improving agent of the present invention is used as a powder, the above steps are completed.
【００２５】以下の工程は、特に、本発明の水質改善剤
を固形状セラミックスの形態として使用する場合に適用
される。混錬工程においては、元素比重がそれぞれ異な
る各種の粒子を平均混合するために、黒砂糖約４重量
％、布海苔約５．５重量％を含有する精製水（塩素除
去、ミネラル水）を液剤として徐々に粒子に注入しなが
ら、これらを混錬する。この際、粒子に粘土その他の添
加物も徐々に添加しながら混錬する。これらを混錬する
ことにより、粘土状物を得る。The following steps are applied particularly when the water quality improver of the present invention is used in the form of a solid ceramic. In the kneading step, purified water (chlorine removal, mineral water) containing about 4% by weight of brown sugar and about 5.5% by weight of cloth is used as a liquid agent in order to averagely mix various particles having different element specific gravities. These are kneaded while being slowly injected into the particles. At this time, kneading is performed while gradually adding clay and other additives to the particles. By kneading these, a clay-like material is obtained.
【００２６】圧縮工程においては、混錬された粘土状物
を圧縮し、密度を高める。In the compression step, the kneaded clay is compressed to increase its density.
【００２７】成型工程においては、一般には、圧縮した
粘土状物を、造粒機械によって粒径３φ〜３０φ程度の
球状体とする。成型による成型物の形状は、使用する型
に応じて如何様にも制作することが可能である。In the molding step, generally, the compressed clay-like material is formed into a spherical body having a particle size of about 3 to 30 φ by a granulating machine. The shape of a molded product by molding can be produced in any manner according to the mold used.
【００２８】例えば、パイナップルを輪切りしたような
円盤形の型で、混錬された前記粘土状物をプレス圧縮し
て２５ｍｍ厚のものにすることもできる。また、本発明
の水質改善剤を外出携帯用として使用する場合には、前
記粘土状物を約８ｍｍφで長さ１２０ｍｍ程度の棒状体
とすることもできる。For example, the kneaded clay-like material may be press-compressed to a thickness of 25 mm in a disk-shaped mold obtained by cutting a pineapple into a circle. When the water quality improving agent of the present invention is used for going out and carrying, the clay-like material may be a rod having a diameter of about 8 mm and a length of about 120 mm.
【００２９】乾燥工程においては、得られた成型物を２
週間から４週間かけて乾燥する。この乾燥期間は、成型
物の混合内容や、季節、天候等に応じて適宜調整する。In the drying step, the obtained molded product is
Dry for 4 to 4 weeks. The drying period is appropriately adjusted according to the mixing content of the molded product, the season, the weather, and the like.
【００３０】焼成工程においては、乾燥した成型物につ
いて１回乃至２回焼成加工する。成型物の焼成温度は、
好ましくは５５０〜１２００℃、更に好ましくは６００
〜１１５０℃である。また、成型物の焼成時間は、好ま
しくは６〜１５時間、更に好ましくは８〜１２時間であ
る。尚、この焼成温度及び焼成時間については、使用す
る成型物の種類等に応じて適宜調整する。In the firing step, the dried molded product is fired once or twice. The firing temperature of the molded product is
Preferably 550-1200 ° C., more preferably 600
１1150 ° C. The firing time of the molded product is preferably 6 to 15 hours, more preferably 8 to 12 hours. The firing temperature and the firing time are appropriately adjusted according to the type of the molded article used.
【００３１】本発明においては、特に、前述した温度で
焼成することにより、抗菌作用を向上させた水質改善剤
を得ることができる。これは、本発明の水質改善剤の原
料となる貝殻類の主成分である炭酸カルシウムが、前述
の焼成温度によって、酸化カルシウムに変化することに
起因する。即ち、同じアルカリ強度の水酸化ナトリウム
溶液よりも抗菌力が強い酸化カルシウムの強力なアルカ
リ性が、鉱石類の成分と相俟って、本発明の水質改善剤
に相乗効果をもたらすものと考えられる。In the present invention, a water quality improver having improved antibacterial action can be obtained by baking at the above-mentioned temperature. This is because calcium carbonate, which is a main component of shells, which is a raw material of the water quality improving agent of the present invention, changes into calcium oxide by the above-mentioned firing temperature. That is, it is considered that the strong alkalinity of calcium oxide, which has a stronger antibacterial activity than a sodium hydroxide solution having the same alkali strength, brings a synergistic effect to the water quality improving agent of the present invention in combination with the ore components.
【００３２】本発明の水質改善剤によれば、従来から消
毒剤として使用されている次亜塩素酸ナトリウムを用い
た場合のように塩素臭を取り除くための真水での洗浄の
必要がない。しかも、本発明の水質改善剤は、天然の貝
殻類を使用しているため、食品に残ってもカルシウム源
となり有用で、人体等に悪影響を殆ど及ぼさないもので
ある。According to the water quality improving agent of the present invention, there is no need to wash with fresh water to remove chlorine odor unlike the case of using sodium hypochlorite which has been conventionally used as a disinfectant. Moreover, since the water quality improver of the present invention uses natural shells, it remains useful as a calcium source even in foods, and has almost no adverse effect on human bodies and the like.
【００３３】また、本発明の水質改善剤によれば、約６
００℃の温度まで除菌効果の発現が可能となり、約３０
０℃まで消臭効果の発現が可能となる。According to the water quality improving agent of the present invention, about 6
The sterilization effect can be exhibited up to a temperature of 00 ° C,
The deodorizing effect can be exhibited up to 0 ° C.
【００３４】また、本発明の水質改善剤は、生体に適し
たミネラル（バランスのとれたミネラル）、マイナスイ
オン、遠赤外線等を水中に溶出し、ｐＨ、ＯＲＰ等が安
定で、有害塩素その他の有害物質を除去し、除菌効果を
発揮することにより、無味・無臭である飲料水を始め、
生活水等の全てに活かされる。The water quality improving agent of the present invention elutes minerals (balanced minerals), negative ions, far-infrared rays, etc. suitable for living bodies into water, and has stable pH, ORP, etc., and harmful chlorine and other substances. By removing harmful substances and demonstrating the bactericidal effect, including tasteless and odorless drinking water,
It is used for all kinds of living water.
【００３５】本発明の水質改善剤によれば、主として産
業廃棄物を再利用し、大規模な設備や費用を必要としな
い安全な環境改善剤を安価に提供することができる。According to the water quality improving agent of the present invention, it is possible to provide a safe environmental improving agent which does not require large-scale facilities and costs, mainly by recycling industrial waste.
【００３６】本発明の水質改善剤は、特に、農薬分解
等により農場の活性化や、工場跡地等における有害物質
の分解浄化等の機能を有する土壌改善剤として、水道
水の改善、生活水の改善（消臭、防菌、防腐、活性
化）、地下水中の環境ホルモン等の分解・除去、河川・
湖・沼水の改善、工業使用水の改善等の機能を有する水
質改善剤として、含有有害物質除去作用を有する水質
改善剤として、抗菌・消臭・防腐作用、食中毒阻止、
院内感染撲滅、鮮度保持期間の延長、農作物・魚貝類及
び海藻の活性化等の機能を有する食物改善剤として、
草木の活性化等の機能を有する水質改善剤等として、有
用である。The water quality improving agent of the present invention is particularly useful as a soil improving agent having a function of activating a farm by decomposing pesticides, decomposing and purifying harmful substances at a site of a factory, etc. Improvement (deodorization, antibacterial, preservative, activation), decomposition and removal of environmental hormones in groundwater,
Anti-bacterial, deodorant, antiseptic, anti-food poisoning, as a water quality improver with the function of improving lake / marsh water, industrial use water, etc.
As a food improver with functions such as eradication of nosocomial infections, extension of freshness retention period, and activation of crops, fish and shellfish, and seaweed.
It is useful as a water quality improving agent having a function of activating plants and the like.
【００３７】また、本発明の水質改善剤によって水を処
理すれば、有害物質等が分解・除去され、従来なかった
安全な水を得ることができる。本発明は、このような新
規な処理水をも提供するものである。本発明の処理水
は、飲料水としては勿論、水質改善剤が利用される前述
したような種々の分野においても提供することが可能で
ある。Further, when water is treated with the water quality improving agent of the present invention, harmful substances and the like are decomposed and removed, and safe water which has never existed before can be obtained. The present invention also provides such a novel treated water. The treated water of the present invention can be provided not only as drinking water but also in various fields as described above where a water quality improving agent is used.
【００３８】本発明の処理水は、前述した水質改善水を
水中０．５〜５．５重量％、特に１．０〜５．０重量
％、とりわけ１．０〜４．０重量％、就中１．５〜３．
５重量％となる範囲で使用して処理したものが好まし
い。前記水質改善剤の使用量の最も好ましいのは１．８
〜２．５重量％である。前記水質改善剤を前記範囲の使
用量で処理した水は、特に抗菌効果が顕著に優れたもの
である。The treated water of the present invention is obtained by adding the above-mentioned water-improving water to water in an amount of 0.5 to 5.5% by weight, particularly 1.0 to 5.0% by weight, particularly 1.0 to 4.0% by weight. Medium 1.5-3.
It is preferable to use one treated in a range of 5% by weight. The most preferable amount of the water quality improving agent is 1.8.
~ 2.5% by weight. Water obtained by treating the water quality improver with the use amount in the above range has particularly excellent antibacterial effect.
【００３９】[0039]
【実施例】以下、実施例を挙げて、本発明を更に詳細に
説明する。しかしながら、本発明はこれらの実施例に何
等限定されるものではない。尚、特に詳述しない限り、
％は重量％を意味する。EXAMPLES Hereinafter, the present invention will be described in more detail with reference to examples. However, the present invention is not limited to these examples. Unless otherwise specified,
% Means% by weight.
【００４０】（実施例１）廃棄処理された鉱石類として
花崗岩類を用い、廃棄処理された貝殻類として北寄貝を
用いて、前述した塵芥除去、洗浄、乾燥、破砕、粉砕、
混合、混練、圧縮、成型、乾燥及び焼成の各工程を経
て、固形状セラミックスからなる水質改善剤を作成し
た。この際、混合工程の前に、粉砕工程で粉砕した花崗
岩類の粒子を６００℃で、３時間、焼成した。次いで、
混合工程で、焼成花崗岩及び北寄貝それぞれの粒子に、
電気石（粒子）及び二酸化チタン（粒子）を添加して、
混合した。そして、混練工程で、これら粒子の混合物
に、液剤〔黒砂糖約４重量％、布海苔約５．５重量％を
含有する精製水（塩素除去、ミネラル水）〕及び多孔質
土を添加し、粘土状物を得た。この粘土状物から成型物
を形成し、これを９２５℃で、９時間、焼成し、球状の
水質改善剤（固形状セラミックス）を得た。得られた水
質改善剤の組成は、花崗岩類１６．７％、北寄貝８．３
％、電気石５．０％、二酸化チタン３．３％、及び多孔
質土６６．７％であった。(Example 1) Granites were used as discarded ores, and northern shellfish were used as discarded shells. The above-mentioned dust removal, washing, drying, crushing, crushing,
Through each of the steps of mixing, kneading, compression, molding, drying and firing, a water quality improver composed of solid ceramics was prepared. At this time, before the mixing step, the granite particles pulverized in the pulverization step were fired at 600 ° C. for 3 hours. Then
In the mixing process, the particles of calcined granite and northern shellfish,
Add tourmaline (particles) and titanium dioxide (particles)
Mixed. Then, in a kneading step, a liquid agent [purified water (chlorine removal, mineral water) containing about 4% by weight of brown sugar and about 5.5% by weight of cloth seaweed) and porous soil are added to the mixture of these particles, and clay is added. A product was obtained. A molded product was formed from this clay-like material, which was baked at 925 ° C. for 9 hours to obtain a spherical water quality improver (solid ceramic). The composition of the obtained water quality improving agent was 16.7% for granites and 8.3 for northern clams.
%, Tourmaline 5.0%, titanium dioxide 3.3%, and porous soil 66.7%.
【００４１】この水質改善剤を容器に入れた水中に３．
５重量％入れ、１５０分間放置した後の水中の有害物質
その他（水質）を調べた。その結果、得られた水の水質
（測定項目欄参照）は下記の通りであり（測定値欄参
照）、水道法の水質基準（基準値欄参照）に適合してい
ることが判った。従って、本実施例１の水質改善剤は、
飲料水用として好適に提供することができる。[0041] This water quality improver is placed in water in a container.
After 5% by weight and left for 150 minutes, harmful substances and other (water quality) in the water were examined. As a result, the water quality of the obtained water (see the measurement item column) was as follows (see the measurement value column), and was found to conform to the water quality standard of the Water Supply Law (see the reference value column). Therefore, the water quality improving agent of Example 1 is
It can be suitably provided for drinking water.
【００４２】 〔水質結果〕 （測定項目） （測定値） （基準値） 一般細菌 ０（個／ｍｌ） １００以下 大腸菌群 不検出 硝酸性窒素及び亜硝酸性窒素 １．３（ｍｇ／ｌ） １０以下 塩素イオン １２．４（ｍｇ／ｌ） ２００以下 有機物等（過マンガン酸カリウム消費量） １．３（ｍｇ／ｌ） １０以下 ｐH値 ７．６ 5.8〜8.6 味 異常なし 異常でないこと 臭気 異常なし 異常でないこと 色度 ３（度） ５以下 濁度 ２（度） ２以下 残留塩素 ０．１（ｍｇ／ｌ）未満[Water quality results] (Measurement items) (Measurement values) (Reference values) General bacteria 0 (cells / ml) 100 or less Escherichia coli group not detected Nitrate nitrogen and nitrite nitrogen 1.3 (mg / l) 10 Chlorine ion 12.4 (mg / l) 200 or less Organic substances (potassium permanganate consumption) 1.3 (mg / l) 10 or less pH value 7.6 5.8-8.6 Taste No abnormality No abnormality Odor No abnormality Not abnormal Chromaticity 3 (degrees) 5 or less Turbidity 2 (degrees) 2 or less Residual chlorine Less than 0.1 (mg / l)
【００４３】（実施例２）廃棄処理された鉱石類として
花崗岩類を用い、廃棄処理された貝殻類として北寄貝を
用いて、前述した塵芥除去、洗浄、乾燥、破砕、粉砕及
び混合の各工程を経て、粉状物からなる水質改善剤を作
成した。この際、混合工程の前に、粉砕工程で粉砕した
花崗岩類の粒子及び北寄貝の粒子と共に電気石を粉砕し
たものを、それぞれ６００℃で、５時間、焼成した。そ
して、混合工程で、焼成花崗岩、焼成北寄貝及び焼成電
気石を混合し、水質改善剤（粉状物）を得た。得られた
水質改善剤の組成は、花崗岩類８３．４０％、北寄貝
８．０％、及び電気石８．０％であった。(Example 2) Using granites as discarded ores and northern shellfish as discarded shells, the above-described steps of dust removal, washing, drying, crushing, crushing and mixing were performed. After that, a water quality improving agent composed of a powdery material was prepared. At this time, before the mixing step, the crushed tourmaline together with the granite particles and the northern shellfish particles crushed in the crushing step were each fired at 600 ° C. for 5 hours. Then, in the mixing step, the calcined granite, the calcined northern shellfish and the calcined tourmaline were mixed to obtain a water quality improving agent (powder). The composition of the obtained water quality improving agent was 83.40% of granites, 8.0% of northern clam, and 8.0% of tourmaline.
【００４４】この水質改善剤についての殺菌効果試験を
次のようにして行った。フラスコに水（汚水）１００ｍ
ｌを入れ、この水の中に、得られた前記水質改善剤を２
重量％添加し、アルミホイルで蓋をして予め１日汲み置
きしておいた。供試菌株としてEscherichia coli NRI
C 1999（大腸菌）を使用し、この菌を、Ｌ−ｂｒｏｔ
ｈ培地〔Ｐｅｐｔｏｎｅ；１．０重量％、Ｙｅａｓｔ
ｅｘｔｒａｃｔ；０．５重量％、ＮａＣｌ；０．５重量
％、Ｄ．Ｗ．１００重量％の培地組成、ｐＨ６．８に調
整、１２１℃で１５分間オートクレーブ使用〕に植え維
ぎ、３７℃で１日静置培養（前培養）した。この前培養
により活性を上げた菌を試験に使用した。前培養した大
腸菌液を１．０ｍｌ取り、生理食塩水を用いて菌体洗浄
を２回行った（１０，０００ｒｐｍ、５分間）。洗浄
後、菌体をフラスコに取り、汲み置きした前記の水１０
０ｍｌ中に添加した。生残菌の確認のため、水への接種
直後及び３０分後にそれぞれその液を１ｍｌ取り、その
原液とその１ｍｌを１０倍に希釈した液と同１００倍に
希釈した液とをＤＥＳＯ培地（デソキシコレート培地；
大腸菌の選択確認培地）にプレートした。その後、大腸
菌の増殖に最適である３７℃の条件で２４時間培養し、
コロニー数を数えて培養液１ｍｌあたりの菌体数を計測
した。また、水質改善剤の使用量を１重量％及び５重量
％それぞれとした以外は前記の２重量％使用した場合と
同様にした試験も行った。さらに、対照として、水質改
善剤を添加せずに１日汲み置きした以外は前記と同様に
した試験も行った（この場合は、２、６及び１２時間後
まで調べた）。それらの結果（１ｍｌ中の菌体数）を次
に示す。A bactericidal effect test was conducted on the water quality improving agent as follows. 100m of water (sewage) in the flask
and the obtained water quality improving agent is added to the water.
% By weight, covered with aluminum foil, and previously pumped for one day. Escherichia coli NRI as the test strain
Using C 1999 (Escherichia coli), this bacterium was
h medium [Peptone; 1.0% by weight, Yeast
extract; 0.5% by weight, NaCl; 0.5% by weight, W. 100% by weight of the medium, adjusted to pH 6.8, using an autoclave at 121 ° C. for 15 minutes], and cultured at 37 ° C. for one day by static culture (pre-culture). The bacteria whose activity was increased by this pre-culture were used for the test. 1.0 ml of the pre-cultured E. coli solution was taken, and the cells were washed twice using physiological saline (10,000 rpm, 5 minutes). After washing, the cells were collected in a flask, and the water 10
Added in 0 ml. Immediately after and 30 minutes after the inoculation into water, 1 ml of the solution was taken to confirm the survival of bacteria. Culture medium;
E. coli selection confirmation medium). After that, the cells were cultured for 24 hours at 37 ° C., which is optimal for the growth of E. coli,
The number of colonies was counted, and the number of cells per 1 ml of the culture solution was counted. In addition, a test was performed in the same manner as in the case where 2% by weight was used except that the amount of the water quality improver used was 1% by weight and 5% by weight, respectively. Further, as a control, a test was conducted in the same manner as described above except that the sample was pumped for one day without adding the water quality improving agent (in this case, the test was performed after 2, 6, and 12 hours). The results (number of cells in 1 ml) are shown below.
【００４５】 〔菌体数結果〕 ・水質改善剤２重量％を添加した水 （菌体液接種後の時間） （菌体液原液） （１０倍希釈）（１００倍希釈） 直後 ∞ ∞ ２５ ３０分後 ０ ０ ０ ・水質改善剤１重量％を添加した水 （菌体液接種後の時間） （菌体液原液） （１０倍希釈）（１００倍希釈） 直後 ∞ ∞ ８６ ３０分後 ０ ０ ０ ・水質改善剤５重量％を添加した水 （菌体液接種後の時間） （菌体液原液） （１０倍希釈）（１００倍希釈） 直後 ∞ ∞ ３９５ ３０分後 ０ ０ ０ ・水質改善剤無添加の水（対照） （菌体液接種後の時間） （菌体液原液） （１０倍希釈）（１００倍希釈） ２時間後 ∞ ∞ ∞ ６時間後 ∞ ∞ ７０ １２時間後 ∞ ４３６ ５１[Results of bacterial cell count]-Water to which 2% by weight of water quality improving agent was added (time after inoculation of bacterial cell fluid) (stock solution of bacterial cell fluid) (10-fold dilution) (100-fold dilution) Immediately 0 0 ・ Water with 1% by weight of water quality improver added (Time after inoculation of bacterial cell liquid) (Bacterial cell liquid stock solution) (10-fold dilution) (100-fold dilution) Immediately after ∞ ８６ 86 30 minutes later 00 0 Water added with 5% by weight of the agent (time after inoculation of the bacterial cell liquid) (Stock solution of the bacterial cell liquid) (10-fold dilution) (100-fold dilution) Immediately after 分 395 After 30 minutes 00 0-Water without water quality improver ( (Control) (Time after inoculation of bacterial cell fluid) (Stock solution of bacterial cell fluid) (10-fold dilution) (100-fold dilution) After 2 hours ∞ ∞ 時間 After 6 hours ∞ ∞ 70 After 12 hours ∞ 436 51
【００４６】以上の結果から明らかなように、本発明の
水質改善剤を使用した処理水は全て３０分後には菌を全
く確認できず、本発明の水質改善剤が殺菌効果に優れて
いることが判る。特に、本発明の水質改善剤を２重量％
使用した処理水は、菌体液（１００倍希釈液）接種直後
でも菌を２５個しか確認できないというように、２重量
％での本発明の水質改善剤の使用は殺菌効果に極めて優
れていることが判る。このような本実施例２の各水質改
善剤は、汚水用として好適に提供することができる。こ
れに対し、水質改善剤を添加しない場合（対照）には、
殺菌効果がないことが明らかである。As is evident from the above results, no germs could be confirmed in all of the treated water using the water quality improver of the present invention after 30 minutes, indicating that the water quality improver of the present invention has an excellent bactericidal effect. I understand. In particular, 2% by weight of the water quality improver of the present invention
As for the treated water used, the use of the water quality improver of the present invention at 2% by weight is extremely excellent in the bactericidal effect, such that only 25 bacteria can be confirmed immediately after inoculation of the bacterial cell liquid (100-fold diluted solution). I understand. Such water quality improving agents of the present Example 2 can be suitably provided for sewage. In contrast, when no water quality improver was added (control),
It is clear that there is no germicidal effect.
【００４７】（実施例３）廃棄処理された鉱石類として
花崗岩類を用い、廃棄処理された貝殻類として北寄貝を
用いて、前述した塵芥除去、洗浄、乾燥、破砕、粉砕、
混合、混練、圧縮、成型、乾燥及び焼成の各工程を経
て、固形状セラミックスからなる水質改善剤を作成し
た。この際、混合工程の前に、粉砕工程で粉砕した花崗
岩類の粒子の一部を６００℃で、３時間、焼成した。次
いで、混合工程で、焼成花崗岩、花崗岩（未焼成）及び
北寄貝それぞれの粒子に、二酸化チタン（粒子）を添加
して、混合した。そして、混練工程で、これら粒子の混
合物に、液剤〔黒砂糖約４重量％、布海苔約５．５重量
％を含有する精製水（塩素除去、ミネラル水）〕及び多
孔質土を添加し、粘土状物を得た。この粘土状物から成
型物を形成し、これを１１５０℃で、８時間、焼成し、
球状の水質改善剤（固形状セラミックス）を得た。得ら
れた水質改善剤の組成は、花崗岩類（焼成分）１１．７
６％、花崗岩類（原石分）１３．７３％、北寄貝．５．
８８％、二酸化チタン０．９８％、及び多孔質土６６．
６７％であった。(Example 3) Granites were used as discarded ores, and northern mussel was used as discarded shells. The above-mentioned dust removal, washing, drying, crushing, crushing,
Through each of the steps of mixing, kneading, compression, molding, drying and firing, a water quality improver composed of solid ceramics was prepared. At this time, before the mixing step, part of the granite particles pulverized in the pulverization step was fired at 600 ° C. for 3 hours. Next, in a mixing step, titanium dioxide (particles) was added to and mixed with the particles of the fired granite, the granite (unfired), and the northern shellfish. Then, in a kneading step, a liquid agent [purified water (chlorine removal, mineral water) containing about 4% by weight of brown sugar and about 5.5% by weight of cloth seaweed) and porous soil are added to the mixture of these particles, and clay is added. A product was obtained. A molded product is formed from the clay-like material, which is baked at 1150 ° C. for 8 hours.
A spherical water quality improver (solid ceramic) was obtained. The composition of the obtained water quality improving agent was 11.7 in granites (burning component).
6%, granites (raw ore) 13.73%, Kitayorai. 5.
88%, titanium dioxide 0.98%, and porous soil
67%.
【００４８】この水質改善剤を水道水（残留塩素０．５
ｐｐｍ）１リットル中に１０ｇ（１重量％）を入れ、５
分間放置した。放置後、Ｏ−トリジン法により、残留塩
素を測定した。その結果、水中の塩素は全く検出されな
かった。従って、本実施例３の水質改善剤は、飲料水用
として十分な効果を有することが判る。The water quality improving agent was added to tap water (residual chlorine 0.5
ppm) 1 liter and 10 g (1% by weight)
Let stand for minutes. After standing, the residual chlorine was measured by the O-tolidine method. As a result, no chlorine in the water was detected. Therefore, it is found that the water quality improving agent of Example 3 has a sufficient effect for drinking water.
【００４９】（実施例４）廃棄処理された鉱石類として
花崗岩類を用い、廃棄処理された貝殻類として北寄貝を
用いて、前述した塵芥除去、洗浄、乾燥、破砕、粉砕及
び混合の各工程を経て、粉状物からなる水質改善剤を作
成した。この際、混合工程の前に、粉砕工程で粉砕した
花崗岩類の粒子の一部及び北寄貝の粒子を、それぞれ５
９０℃で、５時間、焼成した。そして、混合工程で、焼
成花崗岩、花崗岩（未焼成）及び焼成北寄貝を混合し、
水質改善剤（粉状物）を得た。得られた水質改善剤の組
成は、花崗岩類（焼成分）６．０％、花崗岩類（原石
分）９１．０％、及び北寄貝３．０％であった。(Example 4) Using granites as discarded ores and northern shellfish as discarded shells, the above-described steps of dust removal, washing, drying, crushing, crushing, and mixing are performed. After that, a water quality improving agent composed of a powdery material was prepared. At this time, before the mixing step, a part of the granite particles and the particles of the northern clam, which were pulverized in the pulverization step, were separated by 5 parts each.
It baked at 90 degreeC for 5 hours. Then, in the mixing process, the calcined granite, granite (unfired) and calcined northern clam are mixed,
A water quality improver (powder) was obtained. The composition of the obtained water quality improver was 6.0% of granites (burning component), 91.0% of granites (raw material), and 3.0% of northern clam.
【００５０】水田水に、鉛標準液（Ｐｂ；１０００ｐｐ
ｍ）５ｍｇ、水銀標準液標準液（Ｈｇ；１０００ｐｐ
ｍ）５ｍｇ、ひ素標準液（Ａｓ；１０００ｐｐｍ）５ｍ
ｇ、カドミウム標準液（Ｃｄ；１０００ｐｐｍ）５ｍｇ
及びクロム標準液（Ｃｒ；１０００ｐｐｍ）５ｍｇを全
て混入し、５００ｍｌ（約２０倍）の溶液とした。この
溶液（有害物質混入水田水）５００ｍｌ中に、前記水質
改善剤を２０ｇ（４重量％）入れ、攪拌し、７日間放置
した。放置後の溶液中の有害物質量を調べたところ、下
記の通りであった。また、対照として、前記有害物質混
入水田水に水質改善剤を添加せず、その溶液をそのまま
７日間放置したものについても同様に有害物質量を調べ
た。それらの結果を次に示す。In a paddy water, a lead standard solution (Pb; 1000 pp)
m) 5 mg, mercury standard solution standard solution (Hg; 1000 pp)
m) 5 mg, arsenic standard solution (As; 1000 ppm) 5 m
g, cadmium standard solution (Cd; 1000 ppm) 5 mg
And 5 mg of a standard chromium solution (Cr; 1000 ppm) were all mixed to prepare a 500 ml (about 20-fold) solution. 20 g (4% by weight) of the water quality improver was placed in 500 ml of this solution (paddy water mixed with harmful substances), stirred, and left for 7 days. When the amount of harmful substances in the solution after standing was examined, it was as follows. Further, as a control, the amount of harmful substances was similarly examined for the paddy water mixed with the harmful substances without adding a water quality improver and leaving the solution as it was for 7 days. The results are shown below.
【００５１】〔有害物質量結果〕 ・水質改善剤を４重量％添加した水田水 （計量の対象） （計量の結果） 鉛 ０．５０ｍｇ／ｌ 全水銀 １．４ｍｇ／ｌ ひ素 ０．０２ｍｇ／ｌ カドミウム ０．０１ｍｇ／ｌ未満 全クロム １．７ｍｇ／ｌ ・水質改善剤無添加の水田水（対照） （計量の対象） （計量の結果） 鉛 ５．３ｍｇ／ｌ 全水銀 ２．６ｍｇ／ｌ ひ素 ２．０ｍｇ／ｌ カドミウム ８．１ｍｇ／ｌ 全クロム ４．９ｍｇ／ｌ[Results of Amount of Hazardous Substances]-Paddy water to which 4% by weight of a water quality improver was added (Object of measurement) (Result of measurement) Lead 0.50 mg / l Total mercury 1.4 mg / l Arsenic 0.02 mg / l Cadmium Less than 0.01 mg / l Total chromium 1.7 mg / l-Paddy water without water quality improver (control) (Target) (Result of measurement) Lead 5.3 mg / l Total mercury 2.6 mg / l Arsenic 2.0mg / l Cadmium 8.1mg / l Total chromium 4.9mg / l
【００５２】以上の結果から明らかなように、本発明の
水質改善剤を使用した処理水は、水質改善剤無添加の処
理水（対照）に比して、有害物質除去・分解効果に優れ
ていることが判る。このことから、本実施例４の水質改
善剤は、地下水改善剤、土壌改善剤等として特に有用で
あることが判る。As is clear from the above results, the treated water using the water quality improver of the present invention has a superior harmful substance removal / decomposition effect as compared with the treated water without the water quality improver (control). It turns out that there is. This indicates that the water quality improver of Example 4 is particularly useful as a groundwater improver, a soil improver, and the like.
【００５３】[0053]
【発明の効果】本発明によれば、安全で安価な、有害物
質分解・除去効果に優れた水質改善剤を提供することが
できる。また、本発明によれば、前記水質改善剤を容易
に且つ安価に製造することができる水質改善剤の製造方
法を提供することができる。さらに、本発明によれば、
前記水質改善剤を使用することにより、飲料水をはじ
め、あらゆる水に対して改善処理した安全な水を提供す
ることができる。According to the present invention, it is possible to provide a safe and inexpensive water quality improving agent having an excellent effect of decomposing and removing harmful substances. Further, according to the present invention, it is possible to provide a method for producing a water quality improving agent that can easily and inexpensively produce the water quality improving agent. Furthermore, according to the present invention,
By using the water quality improving agent, it is possible to provide safe water obtained by improving all kinds of water including drinking water.
─────────────────────────────────────────────────────
────────────────────────────────────────────────── ───
【手続補正書】[Procedure amendment]
【提出日】平成１４年２月１日（２００２．２．１）[Submission date] February 1, 2002 (2002.2.1)
【手続補正１】[Procedure amendment 1]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】特許請求の範囲[Correction target item name] Claims
【補正方法】変更[Correction method] Change
【補正内容】[Correction contents]
【特許請求の範囲】[Claims]
【手続補正２】[Procedure amendment 2]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】０００７[Correction target item name] 0007
【補正方法】変更[Correction method] Change
【補正内容】[Correction contents]
【０００７】本発明は、前記知見に基づきなされたもの
で、特定の鉱石類と、特定の貝殻類とから形成されてな
る水質改善剤を提供することにより、前記目的を達成し
たものである。[0007] The present invention has been made based on the findings, by providing a particular ore, water quality improving agent comprising formed from the particular shells such is obtained by achieving the above object.
【手続補正３】[Procedure amendment 3]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００１２[Correction target item name] 0012
【補正方法】変更[Correction method] Change
【補正内容】[Correction contents]
【００１２】本発明に使用される鉱石類としては、半導
体の用途に使用された後の廃棄物としての、長石群、黒
雲母及び角閃石類を含む花崗岩が用いられる。これらの
各成分は、鉱石類中に、混合されて含まれている。The ores used in the present invention are semiconductive
As waste after being used for the body of the application, feldspar group, Black
Granite containing mica and amphibole compounds is Ru is used. Each component of these are in the ores, that contains is engaged mixed.
【手続補正４】[Procedure amendment 4]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００１３[Correction target item name] 0013
【補正方法】変更[Correction method] Change
【補正内容】[Correction contents]
【００１３】前記花崗岩は、焼成した花崗岩や、原石の
花崗岩等として用いられる。尚、この花崗岩中には電気
石の含有割合が少ないため、電気石を更に添加すること
が好ましい。また、この花崗岩には、二酸化チタンを添
加することも好ましい。[0013] The granite, and fired granite used as <br/> granite etc. ore. Incidentally, because the content was less tourmaline in this granite rocks, it is preferable to further add an electric stone. It is also preferable to add titanium dioxide to the granite .
【手続補正５】[Procedure amendment 5]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００１４[Correction target item name] 0014
【補正方法】変更[Correction method] Change
【補正内容】[Correction contents]
【００１４】本発明に使用される貝殻類としては、食品
等の用途に使用された後の産業廃棄物としての北寄貝殻
が用いられる。特に、抗菌効果、有害物質分解・除去効
果の点で、北寄貝の貝殻が使用される。[0014] shells such as used in the present invention, Hokkigai shells <br/> as industrial waste after it has been used in applications such as food is Ru is used. In particular, antibacterial effect, in terms of pollutant decomposition and removal effect, shells Hokkigai is used.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ テーマコート゛(参考） Ｃ０２Ｆ 1/68 ５２０ Ｃ０２Ｆ 1/68 ５２０Ｎ ５２０Ｓ ５４０ ５４０Ｂ 1/50 ５１０ 1/50 ５１０Ａ ５２０ ５２０Ｂ ５３１ ５３１Ａ Ｃ０４Ｂ 35/00 Ｃ０４Ｂ 35/00 Ｖ ──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) C02F 1/68 520 C02F 1/68 520N 520S 540 540B 1/50 510 1/50 510A 520 520B 531 531A C04B 35 / 00 C04B 35/00 V
Claims (9)
貝殻類とから形成されてなる水質改善剤。1. A water quality improving agent formed from discarded ore and discarded shells.
イト、金紅石、角閃石類、電気石、活性白土、珪藻類、
ラジウム、ゲルマニウム、カリウム、及び白金からなる
群より選択される一種以上を含む請求項１記載の水質改
善剤。2. The ore comprises feldspars, biotite, zeolite, auburnite, amphibolite, tourmaline, activated clay, diatom,
The water quality improving agent according to claim 1, comprising at least one selected from the group consisting of radium, germanium, potassium, and platinum.
び北寄貝殻からなる群より選択される一種以上を含む請
求項１又は２記載の水質改善剤。3. The water quality improving agent according to claim 1, wherein the shells include at least one selected from the group consisting of oyster shells, scallop shells, and northern shells.
載の水質改善剤。4. The water quality improver according to claim 1, which is a powdery substance.
の何れかに記載の水質改善剤。5. A solid ceramic as claimed in claim 1, wherein
The water quality improving agent according to any one of the above.
剤を製造する方法であって、 鉱石類及び貝殻類を含む５φ前後迄の粒状物を形成する
破砕工程と、 前記粒状物から１０００メッシュの統一粒子を形成する
粉砕工程と、 ５００〜９００℃で、３〜８時間、前記統一粒子を焼成
する焼成工程と、を少なくとも含む水質改善剤の製造方
法。6. A method for producing the water quality improving agent according to claim 1, wherein a crushing step of forming granules up to about 5φ including ores and shells, and the granules are carried out. A method for producing a water quality improving agent, comprising at least a pulverizing step of forming uniform particles of 1000 to 1000 mesh and a firing step of firing the uniform particles at 500 to 900 ° C. for 3 to 8 hours.
質改善剤を製造する方法であって、 鉱石類及び貝殻類を含む５φ前後迄の粒状物を形成する
破砕工程と、 前記粒状物から１０００メッシュの統一粒子を形成する
粉砕工程と、 前記統一粒子を含む粘土状物を形成する混練工程と、 前記粘土状物から成型物を形成する成型工程と、 ５５０〜１２００℃で、６〜１５時間、前記成型物を焼
成する焼成工程と、を少なくとも含む水質改善剤の製造
方法。7. A method for producing a water quality improving agent according to claim 1, wherein a crushing step of forming a granular material of up to about 5φ including ores and shells, A pulverizing step of forming unified particles of 1000 mesh from the granules, a kneading step of forming a clay-like substance containing the unified particles, a molding step of forming a molded article from the clay-like substance, And a firing step of firing the molded product for 6 to 15 hours.
剤を使用して処理された処理水。8. Treated water treated with the water quality improver according to claim 1.
〜５．５重量％である請求項８記載の処理水。9. The use amount of the water quality improving agent is 0.5 in water.
The treated water according to claim 8, wherein the amount is from 5.5 to 5.5% by weight.
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|---|---|---|---|
| JP2001024591A JP3327542B2 (en) | 2001-01-31 | 2001-01-31 | Water quality improving agent, method for producing the same, and treated water treated with the water quality improving agent |
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|---|---|---|---|
| JP2001024591A JP3327542B2 (en) | 2001-01-31 | 2001-01-31 | Water quality improving agent, method for producing the same, and treated water treated with the water quality improving agent |
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|---|---|---|---|
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| JP (1) | JP3327542B2 (en) |
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|---|---|---|---|---|
| JP2002316862A (en) * | 2001-04-13 | 2002-10-31 | Murakamu:Kk | Ceramic block |
| WO2004032630A1 (en) * | 2002-10-08 | 2004-04-22 | Kazuyuki Aso | Agent for controlling protist and/or harmful substance comprising fired product of shell powder |
| JP2008036540A (en) * | 2006-08-07 | 2008-02-21 | Toshiaki Saito | Water modifying agent and deodorant |
| JPWO2006057287A1 (en) * | 2004-11-25 | 2008-06-05 | 楠 敏明 | Activated sludge production inhibitor |
| JP2008171176A (en) * | 2007-01-11 | 2008-07-24 | Sony Computer Entertainment Inc | Object collision processing method, object collision processing program and object collision processing device |
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| KR101260381B1 (en) * | 2008-07-16 | 2013-05-07 | 박하춘 | A liquid product for removing green-tide and odor and a removing method using thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002316862A (en) * | 2001-04-13 | 2002-10-31 | Murakamu:Kk | Ceramic block |
| WO2004032630A1 (en) * | 2002-10-08 | 2004-04-22 | Kazuyuki Aso | Agent for controlling protist and/or harmful substance comprising fired product of shell powder |
| JPWO2004032630A1 (en) * | 2002-10-08 | 2006-02-02 | 和幸 阿曽 | Protozoan and / or harmful substance inhibitor made of fired shell powder |
| JPWO2006057287A1 (en) * | 2004-11-25 | 2008-06-05 | 楠 敏明 | Activated sludge production inhibitor |
| KR100948996B1 (en) | 2005-09-01 | 2010-03-23 | 이제훈 | Method for purifying acidic sewage and wastewater |
| JP2008036540A (en) * | 2006-08-07 | 2008-02-21 | Toshiaki Saito | Water modifying agent and deodorant |
| JP2008171176A (en) * | 2007-01-11 | 2008-07-24 | Sony Computer Entertainment Inc | Object collision processing method, object collision processing program and object collision processing device |
| KR101260381B1 (en) * | 2008-07-16 | 2013-05-07 | 박하춘 | A liquid product for removing green-tide and odor and a removing method using thereof |
| KR101260380B1 (en) * | 2008-07-16 | 2013-05-07 | 박하춘 | A liquid product for removing mud and red-tide and a removing method using thereof |
| JP2010174162A (en) * | 2009-01-30 | 2010-08-12 | Kansai Kagaku Co Ltd | Functional ore powder composition |
| TWI409241B (en) * | 2010-09-17 | 2013-09-21 | ||
| CN108178278A (en) * | 2018-01-04 | 2018-06-19 | 清华大学 | Using tourmaline powder synthesis except ammonia cladded type piezoelectric material and preparation method thereof |
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