CN1907872A

CN1907872A - Water quality modifying agent

Info

Publication number: CN1907872A
Application number: CN 200510043058
Authority: CN
Inventors: 郝继斌
Original assignee: SHANXI HONGYANG ZHENHAI ORGANISM PROTECTION CO Ltd
Current assignee: SHANXI HONGYANG ZHENHAI ORGANISM PROTECTION CO Ltd
Priority date: 2005-08-05
Filing date: 2005-08-05
Publication date: 2007-02-07

Abstract

This invention involves a water conditioner for restoration and protection of aquaculture ecological environment. To overcome the problems in the existing technology, the water conditioner comprises plaster stone 8-12 parts, alum 8-12 parts, Eucommia ulmoides leaf extract 12-18 parts, Platycladus orientalis extract 3-8 parts, and zeolite powders 50-70 parts. The products can not only improve the water quality, but also prevent shrimp from discomfort symptom of high temperature in summer. Moreover the experiments show that the product is safe, reliable, stable, non-toxic, and without side effects and residues, fit for animal feed, can not induce mutagens response, and has long durability, easy storage and low cost.

Description

A kind of improver of water quality

Affiliated technical field:

The present invention relates to a kind of improver of water quality that is used to improve, repair, protect the aquaculture ecotope.

Background technology:

In recent years, along with developing rapidly of industrial or agricultural, the ecotope in waters has been subjected to serious destruction, and pollute mainly from the following aspects: 1. industrial pollution is the greatest factor that causes water pollution.Various industrial wastes, waste water become the arch-criminal of water pollution already.2. the waste that discharges in a large amount of agricultural chemicals in the agricultural and the people's daily life pollution that the waters is caused also can not be ignored.3. fish production self pollution that the waters is caused is serious just day by day.Along with the rapid expansion of aquaculture scale, culture residual bait, residual medicine and drainage waste in a large number and assemble in the water, cause water pollution, not only worsened water quality virus is wreaked havoc.The aquatic product quality of producing under this environment that has worsened has been well imagined.Because the excess load of water body not only greatly reduces the detergent power of water body self, and has formed vicious cycle.This water area ecological environment is seriously unbalance, cause the forfeiture of waters ecological functions, make useful hydrobiont adult reproductivity and larvae survival power sharply weaken, the fishing resources storage descends year by year, serious threat the safety and the Sustainable development of China's fishery, and a series of environmental problems that therefore produce also will cause regional, national and even global ecological safety and have a strong impact on and even serious threat.

The pollution problem of China's water environment has caused the great attention of the national parties concerned, has been put on the improvement schedule.Although China had strengthened the dynamics and the input of ecological protection in the last few years, improvement of the ecological environment obtains bigger progress, and ecological situation still allows of no optimist.Monitoring materials shows: in 1200 rivers of China in 2003, more than 850 pollution that is subjected in various degree arranged; In 407 emphasis monitoring sections of seven big water systems, 38.1% section satisfies I～III class water quality requirement, 32.2% section belongs to IV, V class water quality, 29.7% section belongs to the bad water quality of V class, only the monitoring section of less than 1/3rd satisfies III class water quality requirement, there is half (river) section to be subjected to Organic pollutants, wherein 2400 kilometers river section fishes and shrimps disappearances; In the storehouse, 28 emphasis lakes of the monitoring same period, the Hu Ku that satisfies I～III class water quality only has 7, accounts for 25.0%, and the eutrophication degree of lake integral body is very serious.

In the world, the Japan in some flourishing state-owned Denmark of Europe, Holland, Italy, Asia, Korea S etc. all develop biological protection net, the biological protection agent that purifies water, and the protection area reaches more than 90%.But these modify-water Item Costs are higher, and subject range is narrow, and difficulty adapts to China's cheap aquaculture big area modify-water and uses.The treating chemicals of present domestic use has pharmaceutical chemicals, microbial preparation etc., but they all have significant disadvantages, and pharmaceutical chemicals is very big to environment damage, and microbial preparation is subjected to the influence of environment very big, and their action time is all slower, and comprehensive treatment effect is undesirable.How comprehensively to address this problem and become one of China's aquaculture difficult problem.

Summary of the invention:

The present invention will overcome the unfavorable problem of comprehensive treatment effect that prior art exists.

For overcoming the problem that prior art exists, technical scheme of the present invention is: a kind of improver of water quality is mixed by proportioning by following composition, 8～12 parts of plaster stone, 8～12 parts in alum, 12～18 parts of Folium Eucommiae extracts, 3～8 parts of Cacumen Platycladi extracts, 50～70 parts of zeolite powders.

Each composition all passes through following processing in the such scheme: plaster stone, dispel impurity, and micro mist to 200 order is standby; Alum: food grade, pulverize 200 orders; Folium Eucommiae extract: Folium Eucommiae is through alcoholic extraction, and the extract gum level reaches 60%, pulverizes through 200 orders; Cacumen Platycladi extract: Leafy twigs of Oriental Arborvitae obtains through alcohol extracting, and micro mist is broken; Zeolite: after the natural crystal mining, behind selected, first powder, the sodium chloride solution through 3.8% soaks 5～8h, after the filtration, heats in advance 80 ℃～90 ℃ and soaks, and the zeolite after the oven dry is through 300～350 ℃ dynamic heat, and after the cooling, sealing is preserved fast.

The compatibility of above component makes this product have powerful ammonia nitrogen is adsorbed fast; Under agitation condition, gelationus in the extract of the throwing out of alum, Folium Eucommiae and Leafy twigs of Oriental Arborvitae helps the effect of coagulating, can make the mineral plasmid of absorption harmful element form the colloid macrobead rapidly and sedimentation, the medicinal ingredients of plaster stone, Folium Eucommiae, Leafy twigs of Oriental Arborvitae has clearing heat and detoxicating and certain bacteriostatic action to aquaculture organism.The comprehensive treatment effect ideal.

Compared with prior art, advantage of the present invention is:

1, effect is obvious: the present invention can active adsorption, the complexing water surface is floating and water in suspended matter (purify water and be beneficial to airborne oxygen and dissolve in the water) active adsorption, complexing, chemical decomposition pollute and poison and fish and shrimp poisoning material that drug use improper (wrong medicine, excess medication or unexpected dispensing accident) causes, can effectively prevent and treat and alleviate the fish and shrimp poisoning that poisonous algae (Sargassum horneri, red tide, Primnesium saltans etc.) causes; Objectionable impuritiess such as adsorbing heavy metal in water, and complexing becomes at the bottom of the nontoxic cured article settling tank; All kinds of poisonings etc. there is quick detoxifcation first aid effect,, can effectively increases dissolved oxygen in water and transparency once use, use after 24 hours, ammonia nitrogen and heavy metal reduce by 50%, use the nuisance that can make in three days in the water body to reduce by 85% continuously, reach the aquaculture water quality standard;

2, can not produce secondary pollution: this product has overcome domestic and international light and bacterium modify-water agent is subject to the pH value interference, disadvantage because of unslaked lime, sterilant damage inactivation, the purification that adapts to multiple water pollution kind improves, and compares with domestic and international modify-water agent to have unique advantage;

3, function is many: this product not only is used to improve water quality, and experiment shows that this product can also prevent the uncomfortable disease (middle summer-heat disease) of fishes and shrimps summer high temperature, can and treat 48 hours inner control, and this is the unique function that other modify-water agent do not possess;

4, safe and reliable, stable performance: this product have nontoxic, have no side effect, the advantage of noresidue, can reach the requirement of animal-feed level, can the mutagenesis reaction, this product structure is stable simultaneously, long quality-guarantee period is convenient to store;

5, cost is low: this product is to be raw material with nontoxic, non-harmful herbal medicine and ore class Chinese medicine, therefore raw materials cost is lower, preparation technology is simple simultaneously, production cost is low, this product domestic and international market demand is big, raw material is cheap, technology is easy, market outlook and economic benefit are good, and large-scale industrial production is easily realized.

Embodiment:

The present invention is raw materials used to be comprised:

1, zeolite: food grade, 200 orders, through sieve, after the activation treatment, pre-sealing, hermetically drying, zeolite oxygen carrying capacity after treatment and absorption and ion-exchange capacity are 10-15 times of undressed zeolite.

Its concrete treatment process is:

(1) selects raw material: dig up mine in natural crystal factory.

(2) pre-treatment: after the natural crystal mining, behind selected, the first powder, the sodium chloride solution through 3.8% soaks 5-8h.

(3) chemical treatment: after the filtration, heat in advance 80 ℃-90 ℃ and soak again.Reach Co in the zeolite ⁺⁺With Na ⁺⁺Abundant exchange;

(4) oven dry, packing: the zeolite after the oven dry is through 300-350 ℃ dynamic heat, and after the cooling, sealing is preserved fast.

2, plaster stone: select the plaster stone in the special place of production, dispel impurity, micro mist 200 orders, plaster stone have please the thermal detoxification function.To ask the visitor in the thermal detoxification of the biology in the polluted water, invigorate and sedative effect.

3, alum: food grade, pulverize 200 orders, alum is the flocculation agent of using always.Alum can form flocculent substance by hydrolysis and other reactions, makes in the water coagulation together such as organic substance, bacterium, reduces organic loading in the water, plays the effect of improvement water quality.

4, Folium Eucommiae extract: containing multiple effective traditional Chinese medicine ingredients in the Folium Eucommiae is 60% through its gum level of Folium Eucommiae extract of alcoholic extraction, pulverize through 200 orders, be a kind of coagulant aids efficiently, can form more greatly with zeolite, plaster stone and the sedimentation of particle acceleration closely.Folium Eucommiae extract is nontoxic, but and natural decomposition.

5, Cacumen Platycladi extract: nontoxic, to unwanted bacteria common in the water body as: streptococcus aureus, intestinal bacteria have the obvious suppression effect.Intestinal tract infections effect to organism in water is obvious.Its alcohol extract is broken through micro mist simultaneously also is a kind of coagulant aids preferably, and the gum level of extract is 50%.

Embodiment 1:

8 parts of plaster stone, 8 parts in alum, 12 parts of Folium Eucommiae extracts, 3 parts of Cacumen Platycladi extracts, 69 parts of zeolite powders.

The concrete treatment process of zeolite is:

(1) selects raw material; (2) pre-treatment: after the natural crystal mining, behind selected, the first powder, the sodium chloride solution through 3.8% soaks 5h; (3) chemical treatment: after the filtration, heat in advance 80 ℃ and soak again, reach Co in the zeolite ⁺⁺With Na ⁺⁺Abundant exchange; (4) oven dry, packing: the zeolite after the oven dry is through 300-350 ℃ dynamic heat, and after the cooling, sealing is preserved fast.

Embodiment 2:

9 parts of plaster stone, 10 parts in alum, 12 parts of Folium Eucommiae extracts, 3 parts of Cacumen Platycladi extracts, 66 parts of zeolite powders.

The treatment process of zeolite is:

(1) selects raw material; (2) pre-treatment: after the natural crystal mining, behind selected, the first powder, the sodium chloride solution through 3.8% soaks 8h; (3) chemical treatment: after the filtration, heat in advance 90 ℃ and soak again, reach Co in the zeolite ⁺⁺With Na ⁺⁺Abundant exchange; (4) oven dry, packing: the zeolite after the oven dry is through 300-350 ℃ dynamic heat, and after the cooling, sealing is preserved fast.

Embodiment 3:

10 parts of plaster stone, 9 parts in alum, 13 parts of Folium Eucommiae extracts, 7 parts of Cacumen Platycladi extracts, 61 parts of zeolite powders.

Embodiment 4:

11 parts of plaster stone, 12 parts in alum, 18 parts of Folium Eucommiae extracts, 7 parts of Cacumen Platycladi extracts, 52 parts of zeolite powders.

Embodiment 5:

12 parts of plaster stone, 11 parts in alum, 17 parts of Folium Eucommiae extracts, 8 parts of Cacumen Platycladi extracts, 54 parts of zeolite powders.

Finished product is an oyster white powder.

In 1: 100 abundant diluted mixture of ratio water, the water surface of evenly splashing experimentized with the product in the foregoing description 3, and experimental result shows:

1, the toxic substance of chelating chemical pollution in the planar water, pesticide residue harm fish reaches national water quality standard.

2, for example: cause the Sargassum horneri of " red tide ", Prymnesium parvum Carter causes fish and shrimp poisoning to poisonous algae, but first aid detoxifcation in 5 days, and make toxic content be lower than national standard, detoxifcation efficient reaches 88.8%.

3, the ammonia nitrogen in the water is eliminated in absorption, and efficient can reach 93.1%, and hydrogen sulfide, carbonic acid gas adsorption rate can reach 80.9%, reach national water quality standard for fishery.

4, to sudden drug intoxication (medication of acid rain, excess, misuse medicine or accident poison pollute etc.) quick rescue function is arranged, the rescue rate reaches more than 80% in general 3 days.

5, suspended substance in the water and floater matter are effectively cleared up eliminate efficient and can reach 73%, reach national water quality standard for fishery.

6, can prevent and treat the uncomfortable disease (heatstroke) of fishes and shrimps high temperature, can and treat 48 hours inner control.

Claims

1, a kind of improver of water quality is mixed by proportioning by following composition, 8～12 parts of plaster stone, 8～12 parts in alum, 12～18 parts of Folium Eucommiae extracts, 3～8 parts of Cacumen Platycladi extracts, 50～70 parts of zeolite powders.

2, a kind of improver of water quality as claimed in claim 1 is characterized in that: the treating processes of described composition is respectively, and plaster stone is dispeled impurity, and micro mist to 200 order is standby; Alum: food grade, pulverize 200 orders; Folium Eucommiae extract: Folium Eucommiae is through alcoholic extraction, and the extract gum level reaches 60%, pulverizes through 200 orders; Cacumen Platycladi extract: Leafy twigs of Oriental Arborvitae obtains through alcohol extracting, and micro mist is broken; Zeolite: after the natural crystal mining, behind selected, first powder, the sodium chloride solution through 3.8% soaks 5～8h, after the filtration, heats in advance 80 ℃～90 ℃ and soaks, and the zeolite after the oven dry is through 300～350 ℃ dynamic heat, and after the cooling, sealing is preserved fast.