JP2001354893A - Ink composition - Google Patents
Ink compositionInfo
- Publication number
- JP2001354893A JP2001354893A JP2000216658A JP2000216658A JP2001354893A JP 2001354893 A JP2001354893 A JP 2001354893A JP 2000216658 A JP2000216658 A JP 2000216658A JP 2000216658 A JP2000216658 A JP 2000216658A JP 2001354893 A JP2001354893 A JP 2001354893A
- Authority
- JP
- Japan
- Prior art keywords
- ink
- eraser
- erased
- pigment
- rubber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
Description
【０００１】[0001]
【産業上の利用分野】 本発明は、紙、布、木材などの
上に筆記後、その筆跡を消しゴムで消去出来る筆記具に
関し、さらし詳しくは、その筆記具用の油性インキに関
する。このような消去可能なインキを含む筆記具として
は、いわゆるペイントマーカーがあるが、本発明のイン
キは特定の筆記具に限定されるものではない。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a writing implement capable of erasing a handwriting with an eraser after writing on paper, cloth, wood, or the like, and more particularly to an oil-based ink for the writing implement. There is a so-called paint marker as a writing instrument containing such erasable ink, but the ink of the present invention is not limited to a specific writing instrument.
【０００２】[0002]
【従来の技術】 現在市販されている油性ペイントマー
カーを用いて、たとえば紙に筆記した場合その筆跡を、
例えば消しゴムを用いて消去する事は出来ない。本来、
ペイントマーカーはその筆跡を消去出来ないように設計
されたインキを含有しているのである。但し、水性イン
キに関しては消しゴムで消去可能なインキの開発の試み
がなされている（特開平８−１９９１０３、特開平１０
−３３０６７３等）2. Description of the Related Art For example, when handwriting is performed on paper using an oil-based paint marker currently on the market,
For example, it cannot be erased using an eraser. Originally,
The paint marker contains ink designed so that the handwriting cannot be erased. However, with respect to water-based inks, attempts have been made to develop inks that can be erased with an eraser (JP-A-8-199103, JP-A-10-103103).
-333067)
【０００３】[0003]
【発明が解決しようとしている課題】 筆跡を消しゴム
を用いて消去出来るような油性インキに設計変更する事
が課題である。The problem to be solved is to change the design to an oil-based ink that can erase handwriting by using an eraser.
【０００４】[0004]
【課題を解決するための手段】 ペイントマーカー等に
用いられる油性インキには、例えばアクリル樹脂のよう
な合成樹脂等を筆跡の接着剤として用いているために、
その筆跡は消しゴムでは消去出来ない。Means for Solving the Problems In oil-based ink used for paint markers and the like, for example, a synthetic resin such as an acrylic resin is used as an adhesive for handwriting.
The handwriting cannot be erased with an eraser.
【０００５】例えばアクリル樹脂は、本来接着力を大き
くするように設計されているので、このような接着力の
大きな樹脂を用いれば必然的に消しゴムでは消去出来な
い。従って、接着力の小さな樹脂を用いるのが好まし
い。我々は鋭意研究を重ねた結果、この目的にはゴム系
の樹脂が好ましい事を発見した。本発明に用いることが
出来るゴム系の樹脂は、ごく一例を挙げると、スチレン
ブタジェンゴム、ポリブタジェンゴム、ブチルゴム、ス
チレン熱可塑性エラストマーなどがあるが、これらの具
体例に制限されるものではなく、要は有機溶剤に溶ける
ゴム系の樹脂であれば何でも良い。[0005] For example, acrylic resin is originally designed to increase the adhesive strength. Therefore, if such a resin having a large adhesive strength is used, it cannot be erased by an eraser. Therefore, it is preferable to use a resin having a small adhesive force. As a result of our intensive studies, we have found that a rubber-based resin is preferable for this purpose. Rubber-based resins that can be used in the present invention include, for example, styrene-butadiene rubber, polybutadiene rubber, butyl rubber, styrene thermoplastic elastomers, and the like, but are not limited to these specific examples. In other words, any rubber-based resin that is soluble in an organic solvent may be used.
【０００６】ゴム系の樹脂の使用量は、インキ中０．１
〜１０．０％である。０．１より少ないと消去性が悪
く、１０．０％より多いとインキの粘度が上昇するので
不都合な場合がある。The amount of the rubber-based resin used is 0.1% in the ink.
１10.0%. If it is less than 0.1, the erasability is poor, and if it is more than 10.0%, the viscosity of the ink increases, which may be inconvenient.
【０００７】本発明に使用出来る有機溶剤は、ゴム系の
樹脂が溶けるものに限られる。一例を挙げるとキシレ
ン、トルエン、メチルシクロヘキサンその他がある。[0007] The organic solvent that can be used in the present invention is limited to those in which the rubber-based resin is soluble. Examples include xylene, toluene, methylcyclohexane and others.
【０００８】本発明に使用出来る顔料は、その粒子径が
１ミクロン〜５０ミクロンのものに限られる。例えば、
日本触媒化学製の「エポカラー」（約３ミクロン）、大
日精化製の「ラブコロール」（約３ミクロン）、東洋ア
ルムニウム製の「アルミニウムペースト顔料」（約１４
ミクロン）、東洋アルミニウム製の「極薄ガラスフレー
ク顔料」（約４０ミクロン）等がある。その粒子径が１
ミクロンより細かいと顔料が紙等の繊維の間隙に侵入し
て消しゴムで消去出来なくなるので好ましくない。５０
ミクロンより大きいと、インキの詰まりが生じて好まし
くない。The pigment which can be used in the present invention is limited to those having a particle size of 1 to 50 microns. For example,
Nippon Shokubai Kagaku's “Epocolor” (approx. 3 microns), Dainichi Seika's “Rabcolor” (approximately 3 microns), and Toyo Alumnium's “Aluminum paste pigment” (approx.
Micron) and "ultra-thin glass flake pigment" (about 40 microns) made by Toyo Aluminum. The particle size is 1
If the particle size is smaller than micron, the pigment penetrates into the space between fibers of paper or the like and cannot be erased by the eraser, which is not preferable. 50
If it is larger than micron, clogging of the ink occurs, which is not preferable.
【０００９】本発明のインキの作り方は常法に従って、
樹脂を有機溶剤に溶かし、これに顔料を分散させて作
る。必要に応じて、分散剤、湿潤剤、粘度調製剤、沈降
防止剤等を加えることが出来る。[0009] The ink of the present invention is prepared according to a conventional method.
It is made by dissolving a resin in an organic solvent and dispersing the pigment in it. If necessary, a dispersing agent, a wetting agent, a viscosity adjusting agent, an antisettling agent and the like can be added.
【００１０】[0010]
【実施例】次ぎに、実施例を挙げて更に詳しく説明す
る。Next, the present invention will be described in more detail with reference to examples.
【００１１】[0011]
【実施例１】 メチルシクロヘキサン８５部にＪＳＲ製
ブタジェンスチレン樹脂１５０２を４部溶かし、続い
て、東洋アルミニウム製アルミニウム顔料「アルペース
ト５６４０ＮＳ」１０部および日本触媒化学製「エポス
ターＭＳ」１部を分散して、インキを得た。このインキ
をペイントマーカーに充填し紙に筆記後消しゴムで消去
したところ良好な消去性を示した。Example 1 4 parts of JSR butadiene styrene resin 1502 were dissolved in 85 parts of methylcyclohexane, and then 10 parts of Toyo Aluminum aluminum pigment "Alpaste 5640NS" and 1 part of Nippon Shokubai Chemical's "Eposter MS" were dispersed. Thus, an ink was obtained. This ink was filled in a paint marker, and after writing on paper, it was erased with an eraser.
【００１２】[0012]
【実施例２】 メチルシクロヘキサン８０部に、ＪＳＲ
製スチレンブタジェン樹脂１５０２を４部溶かし、続い
て、メルクジャパン製パール顔料「イリオジン３２３」
を１５部分散させ、これに楠本化成製「ディスパロン６
９００−２０Ｘ」を１部加えて、インキを得た。このイ
ンキをペイントマーカーに充填し紙に筆記後消しゴムで
消去したところ良好な消去性を示した。Example 2 JSR was added to 80 parts of methylcyclohexane.
4 parts of styrene-butadiene resin 1502 manufactured by Merck Japan, followed by pearl pigment “Iriodin 323” manufactured by Merck Japan
And disperse 15 parts of this into “Kusumoto Kasei” Dispalon 6
"900-20X" was added to obtain an ink. This ink was filled in a paint marker, and after writing on paper, it was erased with an eraser.
【００１３】[0013]
【実施例３】 メチルシクロヘキサン９０部に、ＪＳＲ
製スチレン系熱可塑性エラストマー「ＴＲ２０００］を
３部溶かし、これに、東洋アルミニウム製ガラスフレー
ク「ＲＥＦＳＸ−２０２５ＰＳ」を７部分散してインキ
を得た。このインキを、ペイントマーカーに充填して、
紙に筆記後消しゴムで消去したところ、良好な消去性を
示した。Example 3 JSR was added to 90 parts of methylcyclohexane.
Three parts of a styrene-based thermoplastic elastomer “TR2000” manufactured were dissolved, and 7 parts of Toyo Aluminum glass flake “REFSX-2025PS” was dispersed therein to obtain an ink. Fill this paint marker with this ink,
When the paper was erased with an eraser after writing, good erasability was shown.
【００１４】[0014]
【比較例】 実施例３において、「ＲＥＦＳＸ−２０２
５ＰＳ」７部のかわりに、三菱化学製カーボンブラック
ＭＡ１００（０．１ミクロン以下）を０．５グラム加え
て、これを分散してインキを得た。このインキをペイン
トマーカーに充填して紙に筆記後、消しゴムで消去した
ところ、消去性は不良であった。Comparative Example In Example 3, “REFSX-202
Instead of 7 parts of 5PS, 0.5 g of carbon black MA100 (0.1 micron or less) manufactured by Mitsubishi Chemical was added and dispersed to obtain an ink. After filling the ink into a paint marker and writing on paper, the ink was erased with an eraser, and the erasability was poor.
【００１５】[0015]
【発明の効果】 本発明のインキを充填した筆記具は、
その筆跡を、消しゴムを用いて消去出来るのが特徴であ
る。The writing implement filled with the ink of the present invention is
The feature is that the handwriting can be erased using an eraser.
Claims (1)
を含む系において、該顔料の粒子径が１〜５０ミクロン
であることを特徴とする消しゴムで消去可能な油性イン
キ組成物。1. An oil-based ink composition erasable with an eraser, wherein the pigment has a particle diameter of 1 to 50 microns in a system containing at least a pigment, a rubber-based resin and an organic solvent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000216658A JP2001354893A (en) | 2000-06-12 | 2000-06-12 | Ink composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000216658A JP2001354893A (en) | 2000-06-12 | 2000-06-12 | Ink composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2001354893A true JP2001354893A (en) | 2001-12-25 |
Family
ID=18711891
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000216658A Pending JP2001354893A (en) | 2000-06-12 | 2000-06-12 | Ink composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2001354893A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004502822A (en) * | 2000-07-03 | 2004-01-29 | ベロル・コーポレイション | Pearl ink, writing utensils, and methods |
| JP2008050484A (en) * | 2006-08-25 | 2008-03-06 | Pilot Corporation | Erasable ink composition for writing tool and writing tool using the same |
| US7981210B2 (en) | 2003-09-19 | 2011-07-19 | Sanford, L.P. | Capillary-action, glitter markers and ink compositions for same |
| US8617646B2 (en) | 2011-12-29 | 2013-12-31 | Sanford, L.P. | Metallic ink composition and writing instrument containing same |
| US8846797B2 (en) | 2012-12-31 | 2014-09-30 | Sanford, L.P. | Metallic ink composition and writing instrument containing same |
| US9163153B2 (en) | 2013-03-15 | 2015-10-20 | Sanford, L.P. | Metallic ink composition and writing instrument containing same |
-
2000
- 2000-06-12 JP JP2000216658A patent/JP2001354893A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004502822A (en) * | 2000-07-03 | 2004-01-29 | ベロル・コーポレイション | Pearl ink, writing utensils, and methods |
| US7981210B2 (en) | 2003-09-19 | 2011-07-19 | Sanford, L.P. | Capillary-action, glitter markers and ink compositions for same |
| JP2008050484A (en) * | 2006-08-25 | 2008-03-06 | Pilot Corporation | Erasable ink composition for writing tool and writing tool using the same |
| US8617646B2 (en) | 2011-12-29 | 2013-12-31 | Sanford, L.P. | Metallic ink composition and writing instrument containing same |
| US9096769B2 (en) | 2011-12-29 | 2015-08-04 | Sanford, L.P. | Metallic ink composition and writing instrument containing same |
| US8846797B2 (en) | 2012-12-31 | 2014-09-30 | Sanford, L.P. | Metallic ink composition and writing instrument containing same |
| US9163153B2 (en) | 2013-03-15 | 2015-10-20 | Sanford, L.P. | Metallic ink composition and writing instrument containing same |
| USRE49400E1 (en) | 2013-03-15 | 2023-01-31 | Sanford, L.P. | Metallic ink composition and writing instrument containing same |
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