JP2000265226A - Manufacture of titanium alloy in high efficiency by mechanical alloying - Google Patents
Manufacture of titanium alloy in high efficiency by mechanical alloyingInfo
- Publication number
- JP2000265226A JP2000265226A JP11069578A JP6957899A JP2000265226A JP 2000265226 A JP2000265226 A JP 2000265226A JP 11069578 A JP11069578 A JP 11069578A JP 6957899 A JP6957899 A JP 6957899A JP 2000265226 A JP2000265226 A JP 2000265226A
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- Prior art keywords
- powder
- alloy
- magnesium
- mechanical alloying
- titanium
- Prior art date
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Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、機械的合金化によ
るチタン合金の作製方法に関する。さらに詳しくは、本
発明は、チタンを主成分とする合金材料を合金を構成す
る金属あるいは非金属の粉末にマグネシウムを添加して
機械的合金化処理法により合金化し、高効率でチタン合
金粉末を作製する方法であって、マグネシウムを添加す
ることによって合金粉末を高効率に回収するとともに、
該粉末を加圧下で成形することによって混入したマグネ
シウムを除去して緻密な成形体を作製する方法に関す
る。The present invention relates to a method for producing a titanium alloy by mechanical alloying. More specifically, the present invention provides an alloy material containing titanium as a main component, which is alloyed by adding a magnesium to a metal or non-metal powder constituting the alloy and mechanically alloying the alloy material, thereby producing a titanium alloy powder with high efficiency. A method of producing, while recovering the alloy powder with high efficiency by adding magnesium,
The present invention relates to a method for producing a dense compact by removing the mixed magnesium by molding the powder under pressure.
【０００２】[0002]
【従来の技術】チタンを主成分とする合金は活性である
ため、雰囲気や耐火材料からの汚染が激しく、溶解によ
る作製は特殊な設備を必要とする。一方、機械的合金化
法によるチタン合金の合成では、容器やボールへの付着
が多く、粉末回収量が少ないという問題があった。2. Description of the Related Art Since an alloy containing titanium as a main component is active, it is heavily contaminated from the atmosphere or a refractory material, and production by melting requires special equipment. On the other hand, in the synthesis of a titanium alloy by a mechanical alloying method, there is a problem that adhesion to a container or a ball is large, and the amount of recovered powder is small.
【０００３】また、機械的合金化法で得られた粉末は粗
い粉末が多く含まれ、粉末の成形性が悪いという問題が
ある。Further, the powder obtained by the mechanical alloying method has a problem that it contains a large amount of coarse powder and the powder has poor moldability.
【０００４】[0004]
【発明が解決しようとする課題】本発明は、チタンを主
成分とする合金を機械的合金化法により高効率に作製す
るとともに、緻密な成形体を得るためになされたもので
ある。本発明者らは、上記の問題点を解決するため鋭意
研究した結果、チタンを主成分とする合金を構成する金
属あるいは非金属の粉末に１０重量％以下のマグネシウ
ムの粉末を添加して機械的合金化処理を行うことにより
微細な合金粉末を高効率で回収できることおよび加圧下
にて成形することによりマグネシウムを除去した緻密な
成形体を作製できることを見いだし、本発明を完成し
た。本発明は従来の溶解法では雰囲気や耐火材料からの
汚染が大きかったチタン合金を機械的合金化法により高
効率で粉末を合成するとともに緻密な成形体を得ること
を目的とするものである。DISCLOSURE OF THE INVENTION The present invention has been made to produce an alloy containing titanium as a main component with high efficiency by a mechanical alloying method and to obtain a dense compact. The present inventors have conducted intensive studies to solve the above-mentioned problems, and as a result, added 10% by weight or less of magnesium powder to a metal or non-metal powder constituting an alloy containing titanium as a main component to obtain a mechanical effect. The present inventors have found that a fine alloy powder can be recovered with high efficiency by performing an alloying treatment, and that a dense molded body from which magnesium has been removed can be produced by molding under pressure, thereby completing the present invention. SUMMARY OF THE INVENTION An object of the present invention is to synthesize a powder of a titanium alloy, which is largely contaminated from the atmosphere or a refractory material by a conventional melting method, with a high efficiency by a mechanical alloying method and to obtain a dense compact.
【０００５】[0005]
【課題を解決するための手段】上記課題を解決するため
の本発明は、以下の技術的手段から構成される。 （１）合金を構成する金属あるいは非金属の粉末にマグ
ネシウム粉末を５重量％以下添加して機械的合金化処理
により５０原子％以上のチタンを含む合金粉末を合成す
ることを特徴とするチタン合金の作製方法。 （２）前記（１）で作製した粉末を減圧雰囲気にて加圧
下で成形することによりマグネシウムを除去した緻密な
成形材料。 （３）前記（２）で作製した材料を融点以下の温度で不
活性ガスあるいは減圧雰囲気にて熱処理した材料。The present invention for solving the above-mentioned problems comprises the following technical means. (1) A titanium alloy characterized in that magnesium powder is added to a metal or nonmetal powder constituting the alloy in an amount of 5% by weight or less, and an alloy powder containing 50% by atom or more of titanium is synthesized by mechanical alloying treatment. Method of manufacturing. (2) A compact molding material from which magnesium is removed by molding the powder produced in (1) under a reduced pressure atmosphere under pressure. (3) A material obtained by subjecting the material prepared in (2) to a heat treatment at a temperature equal to or lower than the melting point in an inert gas or reduced pressure atmosphere.
【０００６】[0006]
【発明の実施の形態】次に、本発明について更に詳細に
説明する。本発明に用いる材料には、市販のチタン粉末
および目的の合金を構成する金属あるいは非金属の粉末
を利用できる。これらの金属あるいは非金属の粉末の混
合粉末の総重量の５重量％以下のマグネシウム粉末を添
加し、機械的合金化法により合金化処理を行う。マグネ
シウム粉末としては市販されている試薬特級程度の純度
の粉末が利用できる。５重量％より多いマグネシウム粉
末を添加すると、機械的合金化粉末が粗大化するととも
に、焼結時の除去が困難になる。Next, the present invention will be described in more detail. As the material used in the present invention, commercially available titanium powder and metal or non-metal powder constituting the target alloy can be used. Magnesium powder of 5% by weight or less of the total weight of the mixed powder of these metal or nonmetal powders is added, and alloying is performed by a mechanical alloying method. As the magnesium powder, a commercially available powder having a reagent grade purity can be used. If more than 5% by weight of magnesium powder is added, the mechanical alloying powder becomes coarse and difficult to remove during sintering.
【０００７】合金を構成するチタン粉末、金属粉末、非
金属粉末の割合はチタン粉末が５０原子％以上含まれて
いることが望ましい。チタン粉末が５０原子％未満の場
合には機械的合金化処理時に添加したマグネシウムと金
属粉末あるいは非金属粉末の反応が促進され、粉末が微
細化しない場合がある。それぞれの粉末の性状について
は特に指定しないが、５００ミクロン以下の微細な粉末
が好ましい。It is desirable that the ratio of titanium powder, metal powder, and nonmetal powder constituting the alloy should be 50 atomic% or more. If the titanium powder content is less than 50 atomic%, the reaction between the magnesium powder added during the mechanical alloying process and the metal powder or nonmetal powder is promoted, and the powder may not be finely divided. The properties of each powder are not particularly specified, but a fine powder of 500 microns or less is preferable.
【０００８】機械的合金化処理には乾式の粉砕機が利用
でき、振動型ボールミル、遊星型ボールミル、転動型ボ
ールミル、アトライターなどが利用できる。機械的合金
化時の雰囲気は、大気圧以下のアルゴンガス雰囲気にし
なければならない。大気圧より高い圧力では粉末の混合
状態が悪く、焼結時にマグネシウムを除去することが難
しい。For the mechanical alloying treatment, a dry pulverizer can be used, and a vibrating ball mill, a planetary ball mill, a rolling ball mill, an attritor, and the like can be used. The atmosphere during mechanical alloying must be an argon gas atmosphere at or below atmospheric pressure. At a pressure higher than the atmospheric pressure, the mixing state of the powder is poor, and it is difficult to remove magnesium during sintering.
【０００９】機械的合金化に供する時間は特に指定しな
いが、５０時間から３００時間が一般的である。また、
圧力伝達媒体としては鉄を主成分とする鋼球が利用でき
る。なお、機械的合金化時には一般的に添加されるステ
アリン酸やアルコールなどの潤滑剤は使用してはいけな
い。The time for mechanical alloying is not specified, but is generally 50 to 300 hours. Also,
Steel balls containing iron as a main component can be used as the pressure transmission medium. Note that lubricants such as stearic acid and alcohol which are generally added during mechanical alloying should not be used.
【００１０】機械的合金化法により合成された粉末は、
マグネシウムが微細に分散した状態の粉末であり、合成
する合金組成によらず５０ミクロン以下の微細な粉末を
形成する。一般に、機械合金化法で得られた粉末は粗い
粉末が多く含まれ、粉末の成形性が悪いという問題があ
るが、本発明により、上記微細な粉末を形成できるの
で、上記のような問題がない。The powder synthesized by the mechanical alloying method is as follows:
This is a powder in which magnesium is finely dispersed, and forms a fine powder of 50 μm or less regardless of the alloy composition to be synthesized. Generally, the powder obtained by the mechanical alloying method contains a large amount of coarse powder and has a problem that the formability of the powder is poor. However, according to the present invention, the above-described problem can be solved because the fine powder can be formed. Absent.
【００１１】得られた粉末は、加圧下にて焼結すること
により緻密な成形体を得ることができる。加熱方法は特
に指定しないが、加圧を容易に行える通電加熱、ホット
プレス、赤外線イメージ炉、高周波加熱などが利用でき
る。焼結温度は合成する合金組成によって変化するが、
およそ６００℃から１３００℃で焼結することができ
る。添加したマグネシウムは、１０００℃まで加熱する
とほぼ完全に除去することができる。The obtained powder is sintered under pressure to obtain a dense compact. The heating method is not particularly specified, but electric heating, hot press, infrared image furnace, high frequency heating, etc., which can easily pressurize, can be used. The sintering temperature varies depending on the alloy composition to be synthesized.
It can be sintered at about 600 to 1300 ° C. The added magnesium can be almost completely removed by heating to 1000 ° C.
【００１２】焼結の雰囲気は、粉末の酸化を防止するた
め１０Ｔｏｒｒ以下の真空もしくは大気圧以下の不活性
ガス雰囲気にする必要がある。また、焼結用の治具には
黒鉛や炭化物セラミックス材料など非酸化物系材料が利
用できる。焼結時の加圧力は特に指定しないが、一般的
には２０ＭＰａ以上である。The sintering atmosphere must be a vacuum of 10 Torr or less or an inert gas atmosphere of not more than atmospheric pressure in order to prevent oxidation of the powder. Further, non-oxide-based materials such as graphite and carbide ceramic materials can be used for the sintering jig. The pressure during sintering is not particularly specified, but is generally 20 MPa or more.
【００１３】得られた成形体にはほとんど気孔が残存し
ておらず、マグネシウムも０．５重量％以下しか残存し
ていない。この成形体は組織の調整あるいは真密度化の
ために合成した合金の融点より低い温度で熱処理を行う
ことができる。合金中の残存するマグネシウム量が少な
いため、加熱速度や加熱温度の制限を受けずに熱処理を
行うことができる。なお、熱処理時の雰囲気は、合金の
酸化あるいは窒化を防止するため、真空中や不活性ガス
雰囲気が好ましい。[0013] In the obtained molded body, almost no pores remain, and only 0.5% by weight or less of magnesium remains. This compact can be subjected to a heat treatment at a temperature lower than the melting point of the alloy synthesized for the purpose of adjusting the structure or increasing the true density. Since the amount of magnesium remaining in the alloy is small, heat treatment can be performed without being limited by the heating rate or the heating temperature. The atmosphere during the heat treatment is preferably in a vacuum or an inert gas atmosphere in order to prevent oxidation or nitridation of the alloy.
【００１４】成形体あるいは熱処理した材料は、マグネ
シウム含有量がきわめて少ないため、チタン合金と同じ
加工や組織制御を行うことができる。また、合成した合
金が機能性材料の場合にもその性能はほとんど劣化しな
い。Since the compact or the heat-treated material has an extremely low magnesium content, the same processing and structure control as the titanium alloy can be performed. Also, when the synthesized alloy is a functional material, its performance hardly deteriorates.
【００１５】[0015]
【実施例】以下実施例で本発明をさらに詳細に説明す
る。しかし、該実施例は本発明の好適な例を示すもので
あり、本発明は該実施例によって限定されるものではな
い。 実施例１ チタン粉末（ナカライテスク製試薬）１３．８ｇに還元
鉄粉末（和光純薬製試薬）１６．２ｇ、マグネシウム粉
末（和光純薬製試薬）０．６ｇを添加して遊星型ボール
ミルによる１００時間の機械的合金化処理を施した。機
械的合金化の雰囲気は５００Ｔｏｒｒの減圧アルゴンと
し、粉末とボール重量比が約０．１になるようにした。
容器と１０ｍｍ径の粉砕球にはクロム鋼を用いた。回収
できた粉末は２５ｇであり、マグネシウムを添加しなか
った場合の７倍以上であった。The present invention will be described in more detail with reference to the following examples. However, the embodiment shows a preferred example of the present invention, and the present invention is not limited by the embodiment. Example 1 16.2 g of reduced iron powder (reagent made by Wako Pure Chemical) and 0.6 g of magnesium powder (reagent made by Wako Pure Chemical) were added to 13.8 g of titanium powder (reagent made by Nacalai Tesque), and 100 g was added by a planetary ball mill. Time mechanical alloying treatment was applied. The atmosphere for the mechanical alloying was argon under a reduced pressure of 500 Torr so that the weight ratio between the powder and the ball was about 0.1.
Chromium steel was used for the container and the crushing balls having a diameter of 10 mm. The recovered powder weighed 25 g, which was 7 times or more that when no magnesium was added.
【００１６】得られた粉末を１５φ×３（ｍｍ）の試験
片がとれる黒鉛型に充填し、０．０１Ｔｏｒｒの真空中
で通電加熱により８００℃で５分保持することにより固
化成形した。得られた成形体にはマグネシウムが０．３
重量％残存しており、成形体は主にＴｉＦｅ相で構成さ
れていた。The obtained powder was filled into a graphite mold from which a test piece of 15φ × 3 (mm) could be taken, and was solidified by heating at 800 ° C. for 5 minutes by heating in a vacuum of 0.01 Torr. The obtained molded body contains 0.3% of magnesium.
% By weight, and the compact was mainly composed of a TiFe phase.
【００１７】実施例２ チタン粉末（ナカライテスク製試薬）１２．８ｇにアル
ミニウム粉末（和光純薬製試薬）７．２ｇとマグネシウ
ム粉末（和光純薬製試薬）０．４ｇを添加して遊星型ボ
ールミルによる１５０時間の機械的合金化処理を施し
た。機械的合金化の雰囲気は１００Ｔｏｒｒの減圧アル
ゴンガスとし、粉末とボールの重量比が約０．０５にな
るようにした。容器と１０ｍｍ径の粉砕球にはクロム鋼
を用いた。回収された粉末は１６ｇであり、マグネシウ
ムを添加しなかった場合の３倍以上であった。Example 2 A planetary ball mill was prepared by adding 7.2 g of aluminum powder (Wako Pure Chemical Reagent) and 0.4 g of magnesium powder (Wako Pure Chemical Reagent) to 12.8 g of titanium powder (Nacalai Tesque reagent). For 150 hours. The atmosphere for the mechanical alloying was an argon gas under a reduced pressure of 100 Torr, and the weight ratio between the powder and the ball was about 0.05. Chromium steel was used for the container and the crushing balls having a diameter of 10 mm. The recovered powder weighed 16 g, which was more than three times that when no magnesium was added.
【００１８】得られた粉末を１５φ×３（ｍｍ）の試験
片がとれる黒鉛型に充填し、０．０１Ｔｏｒｒの真空中
で通電加熱により８００℃で５分保持することにより固
化成形した。得られた成形体を１０００℃にてＨＩＰ処
理を施すと、マグネシウムを０．１重量％含有するＴｉ
Ａｌ相を主成分とする固化成形体が得られた。The obtained powder was filled in a graphite mold from which a test piece of 15φ × 3 (mm) could be taken and solidified and formed by heating at 800 ° C. for 5 minutes by heating in a vacuum of 0.01 Torr. When the obtained molded body is subjected to HIP treatment at 1000 ° C., Ti containing 0.1% by weight of magnesium is obtained.
A solidified compact having an Al phase as a main component was obtained.
【００１９】実施例３ チタン粉末（ナカライテスク製試薬）３．７ｇにシリコ
ン粉末（和光純薬製試薬）１．３ｇとマグネシウム粉末
（和光純薬製試薬）０．０５ｇを添加して振動型ボール
ミルによる１００時間の機械的合金化処理を施した。機
械的合金化の雰囲気は大気圧のアルゴンガスとし、粉末
とボールの重量比が約０．１になるようにした。容器に
はステンレス鋼を用い、１０ｍｍ径の粉砕球にはクロム
鋼を用いた。回収された粉末は３．９ｇであり、マグネ
シウムを添加しなかった場合の２倍弱であった。Example 3 A vibration type ball mill was prepared by adding 1.3 g of silicon powder (reagent made by Wako Pure Chemical Industries) and 0.05 g of magnesium powder (reagent made by Wako Pure Chemical Industries) to 3.7 g of titanium powder (reagent made by Nacalai Tesque). For 100 hours. The atmosphere for the mechanical alloying was argon gas at atmospheric pressure, and the weight ratio between the powder and the ball was about 0.1. Stainless steel was used for the container, and chrome steel was used for the crushing balls having a diameter of 10 mm. The recovered powder weighed 3.9 g, which was slightly less than twice that when no magnesium was added.
【００２０】得られた粉末を１５φ×３（ｍｍ）の試験
片がとれる黒鉛型に充填し、０．０１Ｔｏｒｒの真空中
で通電加熱を行った。焼結は８００℃で５分間保持し、
３５ＭＰａの加圧力で成形した。The obtained powder was filled in a graphite mold from which a test piece of 15 mm × 3 (mm) could be taken, and was heated by applying electric current in a vacuum of 0.01 Torr. Sintering is held at 800 ° C for 5 minutes,
Molding was performed at a pressure of 35 MPa.
【００２１】得られた成形体をアルゴンガス雰囲気中で
７５０℃に加熱し、１時間保持した。得られた熱処理材
は、マグネシウムを０．２重量％含有するＴｉ−Ｓｉ系
金属間化合物相で構成されていた。The obtained compact was heated to 750 ° C. in an argon gas atmosphere and kept for 1 hour. The obtained heat-treated material was composed of a Ti-Si-based intermetallic compound phase containing 0.2% by weight of magnesium.
【００２２】[0022]
【発明の効果】以上詳述したように、本発明は、合金を
構成する金属あるいは非金属の粉末にマグネシウム粉末
を５重量％以下添加して機械的合金化処理により５０原
子％以上のチタンを含む合金粉末を合成することを特徴
とするチタン合金の作製方法に係るものであり、本発明
の機械的合金化による高効率なチタン合金の作製方法を
用いることにより、１）従来合成が困難であった高機能
性を有するチタン合金粉末を大量に作製することができ
る、２）実用レベルでの機械的合金化方法を提案できる
とともに、実用部材形状に固化成形できる粉末を作製す
ることができる、３）本発明で得られる成形体には添加
したマグネシウムがほとんど残存しておらず、チタン合
金の特性を損なうことがないうえ、添加したマグネシウ
ムは回収することが可能でありクローズドシステムとし
て、環境融合型の製造プロセスとすることができる、
４）固化成形時には液化したマグネシウムが粉末の焼結
を促進する役割をはたすため、一般に難加工性とされる
チタン合金の焼結性を改善することができる、５）本技
術は形状記憶合金や水素吸蔵合金などのエネルギー、環
境材料を含めた広い産業分野において、展開することが
できる、という効果が奏される。As described above in detail, according to the present invention, magnesium powder is added to a metal or non-metal powder constituting an alloy in an amount of 5% by weight or less, and mechanically alloying treatment is performed to add 50% by atom or more of titanium. The present invention relates to a method for producing a titanium alloy characterized by synthesizing an alloy powder containing the same. By using the highly efficient method for producing a titanium alloy by mechanical alloying of the present invention, 1) conventional synthesis is difficult. It is possible to produce a large amount of titanium alloy powder having high performance, and 2) it is possible to propose a mechanical alloying method at a practical level, and to produce a powder which can be solidified and molded into a practical member shape. 3) The added magnesium hardly remains in the molded article obtained by the present invention, so that the properties of the titanium alloy are not impaired and the added magnesium is recovered. As possible and closed system can be a environmental fused manufacturing process,
4) During solidification and molding, liquefied magnesium plays a role in promoting sintering of powder, so that it is possible to improve the sinterability of titanium alloy, which is generally difficult to process. The present invention has an effect that it can be applied to a wide range of industrial fields including energy and environmental materials such as hydrogen storage alloys.
─────────────────────────────────────────────────────
────────────────────────────────────────────────── ───
【手続補正書】[Procedure amendment]
【提出日】平成１２年３月２７日（２０００．３．２
７）[Submission date] March 27, 2000 (2003.
7)
【手続補正１】[Procedure amendment 1]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】特許請求の範囲[Correction target item name] Claims
【補正方法】変更[Correction method] Change
【補正内容】[Correction contents]
【特許請求の範囲】[Claims]
【手続補正２】[Procedure amendment 2]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】０００５[Correction target item name] 0005
【補正方法】変更[Correction method] Change
【補正内容】[Correction contents]
【０００５】[0005]
【課題を解決するための手段】上記課題を解決するため
の本発明は、以下の技術的手段から構成される。 （１）マグネシウムが微細に分散した５０ミクロン以下
の微細な合金粉末を形成した後、得られた粉末を固化成
形して上記マグネシウムを０．５重量％以下に除去した
緻密なチタン合金成形材料を作製する方法であって、次
の工程；チタンを主成分とする合金を構成する金属ある
いは非金属の粉末にマグネシウム粉末を５重量％以下添
加して機械的合金化処理により５０原子％以上のチタン
を含む合金粉末を合成する工程、上記合金粉末を１０Ｔ
ｏｒｒ以下の真空もしくは大気圧以下の不活性ガス雰囲
気中で加圧焼結して固化成形することによりマグネシウ
ムを除去した成形体を作製する工程、からなることを特
徴とするチタン合金成形材料の作製方法。 （２）前記（１）に記載の方法で作製したマグネシウム
を０．５重量％以下に除去した緻密なチタン合金成形材
料。 （３）前記（２）に記載のチタン合金成形材料を該チタ
ン合金の融点以下の温度で不活性ガスあるいは減圧雰囲
気にて熱処理した材料。The present invention for solving the above-mentioned problems comprises the following technical means. (1) 50 microns or less in which magnesium is finely dispersed
After forming a fine alloy powder, the obtained powder is solidified
To remove the above magnesium to 0.5% by weight or less
A method for producing a dense titanium alloy molding material, comprising:
Step; step of synthesizing the alloy powder containing 50 atomic% or more titanium by alloy powder magnesium powder metal or nonmetal constituting added 5 wt% or less mechanical alloying process mainly comprising titanium , 10T of the above alloy powder
Vacuum below orr or inert gas atmosphere below atmospheric pressure
Magnesium by pressure sintering in the air and solidifying and forming
The method for manufacturing a titanium alloy molding material characterized by comprising the step, to prepare a molded body to remove beam. (2) the dense titanium alloy molding material was removed magnesium to 0.5% by weight or less prepared by the method described in (1). (3) a titanium alloy molding material according to (2) the Chita
A material that has been heat-treated in an inert gas or reduced-pressure atmosphere at a temperature below the melting point of the alloy .
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ テーマコート゛(参考） Ｂ２２Ｆ 3/10 Ｆ (72)発明者 松本 章宏 愛知県名古屋市名東区平和が丘１丁目70番 地 猪子石住宅６棟401号 (72)発明者 西尾 敏幸 愛知県名古屋市名東区平和が丘１丁目70番 地 猪子石住宅１棟501号 (72)発明者 尾崎 公洋 愛知県名古屋市名東区平和が丘１丁目70番 地 猪子石住宅６棟503号 Ｆターム(参考） 4K017 AA04 BA09 BA10 BB11 EA04 EA05 EK08 4K018 AA06 AC01 BA03 BA20 BC16 CA01 CA12 DA12 DA31 DA32 EA01 EA11 EA21 KA56 KA70──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) B22F 3/10 F (72) Inventor Akihiro Matsumoto 1-70 Heiwagaoka, Meito-ku, Nagoya City, Aichi Prefecture Inokoishi 6th building 401 (72) Inventor Toshiyuki Nishio 1-70 Heiwagaoka, Meito-ku, Nagoya City, Aichi Prefecture Inokoishi House 1 Building 501 (72) Inventor Kimihiro Ozaki 1-Heiwagaoka, Meito-ku, Nagoya City, Aichi Prefecture No. 70 Inokoishi House 6 Building 503 F-term (reference) 4K017 AA04 BA09 BA10 BB11 EA04 EA05 EK08 4K018 AA06 AC01 BA03 BA20 BC16 CA01 CA12 DA12 DA31 DA32 EA01 EA11 EA21 KA56 KA70
Claims (3)
末にマグネシウム粉末を５重量％以下添加して機械的合
金化処理により５０原子％以上のチタンを含む合金粉末
を合成することを特徴とするチタン合金の作製方法。1. An alloy powder containing 50 atomic% or more of titanium by mechanical alloying treatment by adding 5% by weight or less of magnesium powder to metal or non-metal powder constituting an alloy. How to make titanium alloy.
て加圧下で成形することによりマグネシウムを除去した
緻密な成形材料。2. A dense molding material from which magnesium has been removed by molding the powder produced in claim 1 under pressure in a reduced-pressure atmosphere.
度で不活性ガスあるいは減圧雰囲気にて熱処理した材
料。3. A material obtained by subjecting the material prepared in claim 2 to a heat treatment at a temperature not higher than the melting point in an inert gas or reduced pressure atmosphere.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11069578A JP3089300B1 (en) | 1999-03-16 | 1999-03-16 | Highly efficient method for producing titanium alloy by mechanical alloying |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11069578A JP3089300B1 (en) | 1999-03-16 | 1999-03-16 | Highly efficient method for producing titanium alloy by mechanical alloying |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP3089300B1 JP3089300B1 (en) | 2000-09-18 |
| JP2000265226A true JP2000265226A (en) | 2000-09-26 |
Family
ID=13406837
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11069578A Expired - Lifetime JP3089300B1 (en) | 1999-03-16 | 1999-03-16 | Highly efficient method for producing titanium alloy by mechanical alloying |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3089300B1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012124661A1 (en) * | 2011-03-16 | 2012-09-20 | 学校法人日本大学 | Titanium-magnesium material having high strength and low elasticity |
| ITMO20130084A1 (en) * | 2013-03-29 | 2014-09-30 | K4Sint S R L | METAL MECHANICAL ALLOCATION PROCEDURE |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103341631B (en) * | 2013-07-25 | 2015-12-09 | 丹阳市裕桥精密元件有限公司 | A kind of manufacture craft of optic communication three-way connection |
-
1999
- 1999-03-16 JP JP11069578A patent/JP3089300B1/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012124661A1 (en) * | 2011-03-16 | 2012-09-20 | 学校法人日本大学 | Titanium-magnesium material having high strength and low elasticity |
| ITMO20130084A1 (en) * | 2013-03-29 | 2014-09-30 | K4Sint S R L | METAL MECHANICAL ALLOCATION PROCEDURE |
| WO2014155359A1 (en) * | 2013-03-29 | 2014-10-02 | K4Sint S.R.L. | Procedure for the mechanical alloying of metals |
| US9919362B2 (en) | 2013-03-29 | 2018-03-20 | K4Sint S.R.L. | Procedure for the mechanical alloying of metals |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3089300B1 (en) | 2000-09-18 |
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