GB851772A - Cross-linked polyesters of dicyclopentadiene dicarboxylic acids - Google Patents

Cross-linked polyesters of dicyclopentadiene dicarboxylic acids

Info

Publication number
GB851772A
GB851772A GB2717358A GB2717358A GB851772A GB 851772 A GB851772 A GB 851772A GB 2717358 A GB2717358 A GB 2717358A GB 2717358 A GB2717358 A GB 2717358A GB 851772 A GB851772 A GB 851772A
Authority
GB
United Kingdom
Prior art keywords
dicarboxylic acid
glycol
cross
pentadiene
mixtures
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2717358A
Inventor
Joseph Kern Mertzweiller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US568940A priority Critical patent/US2870112A/en
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Priority to GB2717358A priority patent/GB851772A/en
Priority to DEE16381A priority patent/DE1105165B/en
Publication of GB851772A publication Critical patent/GB851772A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/199—Acids or hydroxy compounds containing cycloaliphatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/423—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing cycloaliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/60—Polyamides or polyester-amides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/68—Unsaturated polyesters
    • C08G18/683—Unsaturated polyesters containing cyclic groups
    • C08G18/686—Unsaturated polyesters containing cyclic groups containing cycloaliphatic groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

A resinous composition comprises the reaction product of a dicyclo-pentadiene dicarboxylic acid or an alkyl or hydrogenated derivatives thereof and a dihydric alcohol, diamine, amino alcohol or mixtures thereof, and a minor proportion of cross-linking agent consisting of an organic diisocyanate or an organic diisothiocyanate, or mixtures thereof. For reaction with the dicarboxylic acid there can be used glycol, diethylene glycol, triethylene glycol, propylene glycol, 1, 2-, 1, 3-, 1, 4 or 2, 3-butane-diol, ethanolamine, aminobutanol, amino octanol, diglycol phthalate and ethylene diamine. Hexamethylene, phenylene and diphenylmethane diisocyanates or diisothiocyanates are suitable cross-linking agents. In Examples (1) a polyester obtained by heating dicyclopentadiene 3, 7 dicarboxylic acid and glycol at reduced pressure, while passing a stream of natural gas to remove moisture is heated with diphenyl methane diisocyanate; (2) dihydrocyclo-pentadiene 3, 7 dicarboxylic acid, 2,3-butanediol and p-phenylene diisothiocyanate are reacted similarly. The resins can be dissolved (with cobalt naphthenate) in mineral spirits, naphthas, cracked gas oil fractions, kerosenes, gasolenes, heptane, hexane, iso-octane, benzene, toluene and cyclohexane to p give varnishes.
GB2717358A 1956-03-01 1958-08-25 Cross-linked polyesters of dicyclopentadiene dicarboxylic acids Expired GB851772A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US568940A US2870112A (en) 1956-03-01 1956-03-01 Cross-linked polyesters of dicyclopentadiene dicarboxylic acids
GB2717358A GB851772A (en) 1958-08-25 1958-08-25 Cross-linked polyesters of dicyclopentadiene dicarboxylic acids
DEE16381A DE1105165B (en) 1958-08-25 1958-09-03 Process for the production of synthetic resins suitable for paint production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2717358A GB851772A (en) 1958-08-25 1958-08-25 Cross-linked polyesters of dicyclopentadiene dicarboxylic acids

Publications (1)

Publication Number Publication Date
GB851772A true GB851772A (en) 1960-10-19

Family

ID=10255388

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2717358A Expired GB851772A (en) 1956-03-01 1958-08-25 Cross-linked polyesters of dicyclopentadiene dicarboxylic acids

Country Status (1)

Country Link
GB (1) GB851772A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1914253A2 (en) * 2006-10-21 2008-04-23 Bayer MaterialScience AG UV hardening polyurethane dispersions
WO2017112680A1 (en) 2015-12-21 2017-06-29 Myriant Corporation Dicyclopentadiene modified ester oligomers useful in coating applications
CN110128618A (en) * 2019-05-20 2019-08-16 北京化工大学 The thermal reversion cross-linked polyurethane of the crosslinking bridged bond containing dicyclopentadiene, preparation method and applications

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1914253A2 (en) * 2006-10-21 2008-04-23 Bayer MaterialScience AG UV hardening polyurethane dispersions
EP1914253A3 (en) * 2006-10-21 2009-11-25 Bayer MaterialScience AG UV hardening polyurethane dispersions
WO2017112680A1 (en) 2015-12-21 2017-06-29 Myriant Corporation Dicyclopentadiene modified ester oligomers useful in coating applications
EP3383959A4 (en) * 2015-12-21 2019-01-16 PTTGC Innovation America Corporation Dicyclopentadiene modified ester oligomers useful in coating applications
AU2016377580B2 (en) * 2015-12-21 2021-05-13 Ptt Global Chemical Public Company Limited Dicyclopentadiene modified ester oligomers useful in coating applications
CN110128618A (en) * 2019-05-20 2019-08-16 北京化工大学 The thermal reversion cross-linked polyurethane of the crosslinking bridged bond containing dicyclopentadiene, preparation method and applications
CN110128618B (en) * 2019-05-20 2020-09-01 北京化工大学 Thermally reversible crosslinked polyurethane containing dicyclopentadiene crosslinking bridge bond, preparation method and application thereof

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